Abstract:
Some lithium-ion batteries are assembled using a plurality of electrically interconnected battery pouches to obtain the electrical potential and power requirements of the battery application. In this disclosure, such battery pouches are prepared to contain a stacked grouping of inter-layered and interconnected anodes, cathodes, and separators, each wetted with a liquid electrolyte. A pair of reference electrodes is combined in a specific arrangement with other cell members to enable accurate assessment of both anode group and cathode group performance, and to validate and regenerate reference electrode capability.

Description:
TECHNICAL FIELD 
       [0001]    Some lithium-ion batteries are assembled using a selected number and arrangement of electrically interconnected battery pouches, each pouch containing a like, stacked, grouping of inter-layered and interconnected anodes, cathodes, and separators, and permeated with a liquid electrolyte. In accordance with this disclosure, a pair of reference electrodes is combined in a specific arrangement with other cell members to enable accurate assessment of pouch performance, and to validate and regenerate reference electrode capability. 
       BACKGROUND OF THE INVENTION 
       [0002]    Assemblies of lithium-ion battery cells are finding increasing applications in providing motive power in automotive vehicles. Lithium-sulfur cells are also candidates for such applications. Each lithium-ion cell of the battery is capable of providing an electrical potential of about three to four volts and a direct electrical current based on the composition and mass of the electrode materials in the cell. The cell is capable of being discharged and re-charged over many cycles. A battery is assembled for an application by combining a suitable number of individual cells in a combination of electrical parallel and series connections to satisfy voltage and current requirements for a specified electric load, such as a traction motor for a vehicle. In a lithium-ion battery application for an electrically powered vehicle, the assembled battery may, for example, comprise up to three hundred cells that are electrically interconnected to provide forty to four hundred volts and sufficient electrical power to an electrical traction motor to drive a vehicle. Sometimes, groups of lithium-ion cells are placed in like-shaped pouches or packages for assembly and interconnection in forming a specified battery voltage and power requirement. The direct current produced by the battery may be converted into an alternating current for more efficient motor operation. 
         [0003]    The batteries may be used as the sole motive power source for electric motor driven electric vehicles or as a contributing power source in various types of hybrid vehicles, powered by a combination of an electric motor(s) and hydrocarbon-fueled engine. There is a desire to reduce the cost of producing the respective elements of each lithium-ion electrochemical cell. And there is a continual desire to improve the function and reliability of each element of the battery. 
         [0004]    A lithium-ion cell, or a group of such cells, may also require the addition of a reference electrode, composed for use in assessing the performance of the cell during its repeated discharge/re-charge cycling. There is a need for improved design, placement, and employment of a reference electrode in lithium-ion batteries. And there is a need for the improved design, placement, and employment of a reference electrode in some association with pouches or other packages of assembled cells that are combined and interconnected in the assembly of a battery. 
       SUMMARY OF THE INVENTION 
       [0005]    This invention provides an arrangement of a grouping of lithium-ion anode and cathode cell units, with a reference electrode and an auxiliary reference electrode, for incorporation into a self-contained battery pouch. The two reference electrodes are strategically located in proximity to a specifically constructed anode of the grouping of cell units, and to share contact with a common liquid electrolyte. 
         [0006]    The battery pouch may, for example, be rectangular in shape with an anode group terminal, a cathode group terminal, a first reference electrode tab, and an auxiliary reference electrode tab, each extending outwardly from the top or other selected side of the pouch. The battery pouch may be combined with other like pouches in the assembly of a battery with specified electrical potential and power requirements for a vehicle application or other electrical load application. In the assembly of such a battery, a selected number of like pouches may be placed in a suitable container and appropriate electrical connections made between anode and cathode terminals of the pouches. The connector tabs for the reference electrode and auxiliary electrode in each pouch are used, as described herein, to assess the performance of the electrically parallel connected anodes and parallel connected cathodes in the pouch to manage their contribution to the performance of the battery. Typically, a computer-based control system is used to manage the discharging and re-charging of the electrochemical cells of the battery. Such a computer-based control system may be programmed and used to manage high impedance connections (that draw a very low current) between a reference electrode and the anode and cathode terminals of each battery pouch. 
         [0007]    In accordance with embodiments of this invention, a plurality of cell elements are prepared as like-shaped sheets for grouping, stacking, and placement in like-shaped, thin, flexible wall pouches, formed of aluminum foil and coated on each side with an electrically insulating layer of a suitable polymer composition. In many embodiments of the invention it is preferred that the cell element sheets and pouch container be of complementary rectangular shapes. 
         [0008]    Each lithium-ion cell typically comprises a negative electrode layer (anode, during cell discharge), a positive electrode layer (cathode, during cell discharge), a thin porous separator layer that is interposed in face-to-face contact between parallel faces of electrode layers, and a liquid, lithium ion-containing, electrolyte solution infiltrating, permeating, and filling the pores of the separator and contacting porous facing surfaces of the electrode layers for transport of lithium ions during repeated cell discharge and re-charge cycles. Each electrode is prepared to contain a layer of an electrode material, deposited on one or both sides of a thin layer (e.g., a foil) of a metallic current collector. The current collector is formed with an uncoated tab, often located on the intended top side of the metal foil, for electrically connecting the electrode to another electrode in the assembly of the cell members of a lithium-ion battery pouch. 
         [0009]    In an illustrative example, negative electrode material may be formed by depositing a thin layer of graphite particles, often mixed with conductive carbon black, and, optionally, a suitable polymeric binder onto one side or both sides of a thin foil of copper that serves as the current collector for the electrons flowing from the negative electrode during cell discharge. The positive electrode also comprises a thin layer of resin-bonded, porous, particulate lithium-metal-oxide composition bonded to a thin foil of aluminum that serves as the current collector for the positive electrode. Thus, the respective electrodes may be made by fixing, depositing, or bonding suitable electrode particles to their respective current collector surfaces. Depending on an intended arrangement in an assembled stack-up of electrodes, it is often desired to apply thin layers of electrode material to both sides of a metal current collector foil. 
         [0010]    In preferred embodiments of the invention, a plurality of lithium-ion cell units are assembled in the form of a stack of thin, complementarily-sized and like-shaped sheet members for placement in a polymer-coated, metal pouch. By way of illustrative example, fourteen rectangular sheets of graphite/carbon anode material layers applied on both faces of non-porous copper current collector foil and fourteen, slightly smaller, rectangular sheets of lithium (cobalt-manganese-nickel) oxide cathode material layers applied on both faces of non-porous aluminum current collector foil may be used. The copper foils are often used in thicknesses of about ten micrometers (suitably six to twenty micrometers), the aluminum foils in thicknesses of about twenty micrometers (suitably ten to thirty micrometers), and the respective active electrode material is typically applied to a uniform thickness of about sixty micrometers to one or both faces of each foil. Typically, the anode layers are required to “cover” the cathode layers and so the heights and lengths of the rectangular anodes are slightly greater than the corresponding dimensions of the cathodes. A pouch may, for example, comprise five to thirty pairs of such anodes and cathodes. 
         [0011]    The predetermined number of pairs of two-side coated anodes and cathodes may be varied depending on the desired electrical potential and electrical power of the stack. The two-sided anode sheets and cathode sheets are stacked alternately with coextensive rectangular porous separator sheet layers between each electrode and lying against an active material-coated face of each electrode. Often, the separator sheet is prepared as a strip of suitable length, which is folded back and forth between the coated faces of the anode sheets and cathode sheets assembled in the stack. The separator sheet may, for example, be formed of a porous polyolefin (polyethylene, polypropylene, or mixtures or copolymers). Thus, in this initial stack, a two-side coated cathode sheet occupies one end of the linear stack and a two-side coated anode sheet occupies the other end of the stack. Where, for example, this initial stack is to include fourteen two-sided anode sheets and fourteen two-sided cathode sheets, there will be a separator sheet strip with twenty-seven folded separator surfaces included in the assembled stack with a separator sheet surface between each facing anode and cathode surface. But in order to utilize two reference electrodes, in accordance with this invention, additional cell members are included in the stack before it is ready for placement in its pouch container. 
         [0012]    A separator sheet is placed against the two-sided cathode sheet at one end of the preliminary stack. And a copper current collector foil, coated only on one side or face with anode material is placed with its coated side lying against the separator sheet and facing toward the two-side coated cathode member located at the end of the preliminary stack. But this copper current collector foil is prepared with small holes or pores extending through the thickness of the foil from one face through its opposing face. The small pores or holes are distributed over the facial area of the copper foil in a proportion of hole or pore area to the rectangular outline area of the foil so as to provide pathways over the face of the foil suitable for infiltration and permeation with a liquid lithium-ion containing electrolyte. The diameter of the holes or pores is suitably in the range of about (0.001 mm to 1 mm). The area of the holes or pores may be up to about ninety-eight percent of the outline area or superficial area of the foil surface. This arrangement of stacked lithium-ion cell member layers is devised to accommodate a reference electrode member and an auxiliary reference electrode member at the end of the stack with its one-side coated anode member. 
         [0013]    In embodiments of this invention, two substantially identical reference electrodes are prepared using either lithium iron phosphate (empirical formula, Li 0.5 FePO 4 ) or lithium titanate (empirical formula, Li 5.5 Ti 5 O 12 ) as the reference electrode material in both reference electrodes. The composition of the lithium iron phosphate may vary as Li 1−x FePO 4 , where 0&lt;x&lt;1, as long as the electrochemical potential of the reference electrode is in a flat voltage plateau. It is preferred that each reference electrode display a flat voltage plateau during operation of the pouch cell so as to enhance variations in the potentials of the anodes and cathodes in the cell. The composition of the lithium titanate may vary as Li 4+x Ti 5 O 12 , where 0&lt;x&lt;3, as long as the electrochemical potential of the reference electrode is in a flat voltage plateau. The reference electrode layer is applied in a porous layer (permeable by liquid electrolyte) of substantially uniform thickness (e.g., about 60 micrometers) to both faces of a porous copper or aluminum foil of substantially the same size and shape as the rest of the stack of cell materials. When the reference electrodes are both Li 1−x FePO 4 , a porous aluminum foil is used. When the reference electrodes are both Li 4+x T 5 O 12 , a porous aluminum or a porous copper current collector foil is used for both reference electrodes. A first such reference electrode member is placed against and coextensive with the porous separator member and opposing, one-side coated anode member. Another porous separator sheet is placed against the outer coated side of the first reference electrode and a second (auxiliary), like coated and sized, electrode is placed against the separator. The porous copper or aluminum sheets, carrying the same reference electrode material on both sides, have tabs at their top sides for interconnection with anode group and cathode group terminal elements of the stack of cell materials. 
         [0014]    The upstanding tab members of each of the assembled stack of anode members (fifteen anode members in this example) may be joined in electrical parallel connection to an anode group terminal strip. The tab members of the cathode members (fourteen cathode members in this example) may likewise be separately joined to a cathode group terminal strip. The respective tab members are of predetermined length to accommodate the joining of the several tabs and it may be preferred to accomplish the joining and the attachment of the group electrode terminal near the middle of the stack. 
         [0015]    The upstanding connector tabs on the main and auxiliary reference electrodes stand alone, but within a connectable distance to the anode group terminal and the cathode group terminal. The dry assembled stack may now be placed in a suitable pouch with the electrode groups&#39; terminals and reference electrode tabs extending in a parallel attitude, out of the unclosed opening of the pouch. A volume of liquid lithium-ion containing electrolyte is carefully placed or loaded into the pouch so as to fully wet the active material of each electrode (active and reference electrodes) and separator in the assembled stack. The electrolyte is applied so as to suitably infiltrate, permeate, and wet all intended electrode and separator surfaces without an unwanted excess of liquid. The pouch is suitably evacuated of unwanted gas or vapor, and closed and sealed over the cell materials and around the extending anode and cathode group terminals and the tabs of the two reference electrodes. Four conductive connector strips are thus exposed at a selected side of the sealed pouch. 
         [0016]    Thus, the pouch of a predetermined plurality of cell units also contains two reference cell elements, located side-by-side with an intervening separator, wetted by a common electrolyte, and positioned for suitable testing of the anode group and cathode group members of the cell. The two identical reference cells are situated for use to validate each other. And the auxiliary reference electrode can be charged or discharged, using the active cell members, to regenerate the principal reference electrode. The location of the reference electrodes in close proximity to the one-side coated anode member is important in using the reference electrode to obtain accurate measurement of the anode group potential or the cathode group potential of the pouch elements. 
         [0017]    Other objects and advantages of this invention will be apparent from a detailed description of preferred embodiments which follow in this specification. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0018]      FIG. 1  is an oblique view of a stack of active electrode elements with interposed separator elements, as viewed from the right end toward the left end of the illustration, with two reference electrode elements at the front or left end of the stack. The illustration is expanded at a central location within the active electrode portion of the stack to show the construction of a cathode, separator and an anode. And the illustration is expanded at the left end of the stack to better describe the construction and positioning of the reference electrodes. Thus,  FIG. 1  illustrates a stack of lithium-ion cell members with both expanded and un-expanded portions of the stack. Of course, in use, no portion of the stack is expanded. 
           [0019]      FIG. 2  is an illustration of the stack of  FIG. 1  with the members of the stack lying in their face-to-face positions.  FIG. 2  shows the elements of stack with one example of the positioning of active cell terminals and reference cell tabs. An anode member and cathode member at the center of the stack are shown in more detail than adjacent anodes and cathodes in the stack. The anode member at one end of the stack and the reference electrodes are also shown in some detail. The stack is illustrated as ready for placing in a pouch container and for infiltration with a liquid, lithium-ion cell electrolyte. 
           [0020]      FIG. 3  is an illustration of a pouch container, filled with the stack elements of  FIGS. 1 and 2 , and a liquid electrolyte. The pouch may be combined and assembled with other like pouch cell containers in the making of a lithium-ion battery. The anode group and cathode group connector terminals extend from the top of the pouch for connection with other terminals in a battery assembly. The reference electrode tabs are positioned for connection with an electrode terminal of the pouch container or with each other. 
       
    
    
     DESCRIPTION OF PREFERRED EMBODIMENTS 
       [0021]    Some types of relatively large lithium-ion batteries are made by preparing packages or pouches of, for example, ten to fifteen pairs of alternating anode members and cathode members, separated from direct electrical contact by porous, electrically insulating, separators. A suitable number of such pouches are assembled in a battery container and electrically connected to form a desired battery. It is typically desired to provide reference electrodes to assess the performance of the individual pouches and of the assembled battery. In accordance with practices of this invention, the organization and arrangement of the reference electrodes and the active members of lithium-ion cells in a pouch is important. 
         [0022]      FIG. 1  illustrates a preferred embodiment of this invention. In a typical battery pouch of this illustration, the ten to fifteen pairs of the respective cell members are of generally flat, rectangular shape (like playing cards) and assembled face-to-face like a stack of playing cards. Such an arrangement is illustrated in  FIGS. 2 and 3 , which will be described in more detail in later paragraphs of this specification. But in  FIG. 1  some of the members of stack  10  of cell members are spaced-apart for illustration of their structure, while other members are placed in their normal stack position. The expanded illustrations of portions of stack  10  as illustrated in  FIG. 1  is for purposes of better illustrating the structures and locations of certain members in a stack arranged in accordance with this invention. 
         [0023]    At the right end of stack  10  is an anode  12 . In this example, anode  12  has a rectangular shape. It is formed of a non-porous cupper foil  14  which serves as a current collector for the anode. The copper foil current collector  14  is typically about ten micrometers thick. The copper current collector foil  14  is coextensively coated on both sides with an active anode material  16  (such as commercially available MesoCarbon MicroBeads graphite, MCMB) that is suitable for a lithium-ion cell anode. The thickness of each layer of active anode material may be about sixty micrometers. Copper foil current collector  14  would also have an upstanding, uncoated, tab which is not illustrated in the drawing figures to simplify the figures, but which enables anode  12  to be electrically connected in parallel connection to the other anodes in the stack  10 . 
         [0024]    Proceeding from right to left in  FIG. 1 , next to anode  12  is a porous single layer separator  18  which separates anode  12  from an adjacent cathode in the stack. Numeral  20  refers to a stack portion of a cathode, a separator, an anode, a separator, etc. proceeding to the left in  FIG. 1 . Each cell member is placed, face to face, against a complementary cell member. The stack represented by numeral  20  may represent six or so groups of cell member groupings with the last cell member in that illustrated stack portion  20  being a separator  18 . Following right-to-left from stack portion  20 , is another anode  12 , which is located in a generally central position in the stack of active electrode members. Anode  12 , located centrally in the stack, is substantially identical in size, shape, and composition to anode  12  located at the right end of the stack  10  as illustrated in  FIG. 1 . Anode  12 , located centrally in the stack, comprises a copper foil current collector  14  which is coated on both sides with active anode material  16 . And anode  12  has an uncoated tab  22  for joining in an electrical connection with the other anodes in the overall stack. Since there are, for example, fourteen anodes  12  coated on both sides with anode material  16 , most of the uncoated anode connector tabs have not been illustrated in the drawing figures. But each connector tab may be of the same length, long enough for each tab to be bent to reach and be joined to the connector tab  22  of the anode  12  which is placed near the center of the overall stack. The joining of each of the anode current collector tabs to a central tab constitutes a terminal for the anode group in the overall stack. 
         [0025]    As illustrated in the stack  10  of  FIG. 1 , separator  18  is positioned to the left of centrally located anode  12 . And to the left of separator  18  in this expanded portion of stack  10  is cathode  24 . While this expanded portion of stack  10  permits the illustration of a centrally located cathode  24 , it is to be understood that each cathode  24  is substantially identical in size, shape, and structure, except, perhaps for the retained length of their uncoated connector tabs  30 . Each cathode  24  comprises a thin, non-porous aluminum foil  26  as its current collector substrate. Each side of the aluminum current collector foil  26  is coated or covered suitable active cathode materials  28 . A suitable cathode material is Li(Ni 1/3 Mn 1/3 Co 1/3 )O 2 . In general, examples of suitable cathode materials include particles of lithium-metal-oxide compounds or compositions, such as lithium-manganese-oxide, lithium-nickel-oxide, and/or lithium-cobalt-oxide. 
         [0026]    Again, the uncoated cathode connector tabs on most of the fourteen cathodes are not illustrated to simplify  FIG. 1 . But the respective cathode connector tabs  30  are trimmed or sized to be connected to a centrally located tab  30  to interconnect each of the cathodes  24  and to form a cathode group terminal. 
         [0027]    Proceeding to the left in  FIG. 1  from the expanded central portion of stack  10 , illustrating the two-side coated anode  12  and cathode  24 , is another smaller stack portion  32 , starting with a separator, continuing with combinations of anode, separator, and cathode, and ending with a cathode and a separator  18 . This is the portion of the overall stack of lithium ion cell members in which two reference electrodes are to be positioned. 
         [0028]    Positioned to separator  18  at the left side of small stack portion  32  is a special anode structure  40 . Anode structure  40  consists of a porous copper current collector foil  42  that is coated on only one side with an anode material  16 . Preferably, anode material  16  is identical in composition to the anode material applied to the other anodes  12  in the stack. And, as illustrated in  FIG. 1 , the anode material  16  is positioned next to the separator  18  at the end of stack portion  32 . But, importantly, in anode  40 , the anode material  16  is applied to only one side of the porous copper current collector  42 . 
         [0029]    Porous copper foils and aluminum foils are commercially available for other applications. 
         [0030]    The porous copper current collector foil  42  may, for example, be formed by forming laser-cut holes or by punching holes in a dense copper foil. A laser beam can cut holes as small as about one micrometer in copper foil that is about ten micrometers thick. Holes as large as 0.1 to about one millimeter may be punched. The sizes of the holes may be in the range of about one micrometer to about one millimeter. The porosity of the copper current collector is to enable liquid electrolyte to flow through the current collector foil  42 , just as the electrolyte permeates the anode material  16 . Suitably, the pore area of current collector foil  42  is in the range of about 0%&lt;x&lt;98% of the outline rectangular face area of the copper current collector foil  42 . 
         [0031]    As illustrated in  FIG. 1 , a separator  18  is placed against the porous copper current collector foil  42  of anode  40 . A reference electrode  50  is then stacked against that separator  18 . It is important that this main reference electrode be placed near an end of the linear stack and separated by a single layer separator  18  from the anode member ( 40  in  FIG. 1 ) in which the layer of anode material is placed on one side of a porous copper current collector foil. 
         [0032]    As stated above in this specification, two substantially identical reference electrodes are prepared using either lithium iron phosphate (empirical formula, Li 0.5 FePO 4 ) or lithium titanate (empirical formula, Li 5.5 Ti 5 O 12 ) as the reference electrode material in both reference electrodes. If the reference and auxiliary electrodes use lithium iron phosphate as the electrode material a porous aluminum current collector foil may be used. If both electrodes use lithium titanate as the electrode material, either a porous aluminum or a porous copper current collector foil may be used. Thus, reference electrode  50  may comprise a porous aluminum current collector foil  52  which may be of substantially the same size and shape and porosity as the current collector foil used in anode  40 . But the porous aluminum current collector foil  52  for reference electrode  50  is coated on both sides with a porous layer  54  of either lithium iron phosphate or lithium titanate as the active reference electrode material. A porous separator layer  18  lies against each of outer surfaces of the porous layers  54  of the reference electrode  50 . The porous aluminum foil current collector  52  comprises a tab  56  for enabling an electrical connection to an anode terminal (e.g.,  22  or  22 ′ in  FIGS. 2 and 3 ) or a cathode terminal (e.g.,  30  or  30 ′ in  FIGS. 2 and 3 ) during evaluation of the performance of the anode group or cathode group of the stack. 
         [0033]    An auxiliary reference electrode  60 , which is substantially identical in shape and composition to reference electrode  50 , is placed at the end of the stack against a separator  18  (at the left end of stack  10 ). Thus, auxiliary electrode  60  also comprises a porous aluminum current collector foil  52  (or optionally copper, if a lithium titanate reference electrode material is used) which is coated on both sides with a porous layer  54  of the same active reference electrode material as used in reference electrode  50 . Although auxiliary reference electrode  60  is substantially identical to reference electrode  50 , it usually serves a different, but complementary, function with respect to the function of reference electrode  50 . Electrical connector tab  56  on reference electrode  50  is available for connection to either the terminal ( 22 ′ in  FIGS. 2 and 3 ) for the parallel connected anodes or the terminal ( 30 ′ in  FIGS. 2 and 3 )—one at a time. Such a connection could be made by use of a connector and electrical meter provided in a fully assembled lithium-ion battery containing several pouches of cell elements and apparatus for managing charging and discharging of the battery. 
         [0034]    Connector tab  58  on auxiliary reference electrode  60  is typically connected to reference electrode tab  56  when it is desired to calibrate or regenerate reference electrode  50 . Such calibration or regeneration actions are often undertaken in an assembled battery, under use, by a computer controlled system for managing discharging and re-charging of the battery and its pouch members. 
         [0035]      FIG. 2  illustrates the cell members of the stack  10  as illustrated in  FIG. 1  as an unexpanded stack  100 . The members of the lithium-ion cell stack are illustrated in their intended and proper face-to face positions in the stack for assembly into a pouch container. However, the unexpanded stack  100  of  FIG. 2  illustrates the multilayer structure of the anode  12  and cathode  24  members which are located centrally in the stack. Associated at the location of the current collector foil  14  of this specific anode  12  is an anode group terminal  22 ′ and associated with the current collector foil  26  of this specific cathode  24  is a cathode group terminal  30 ′. And the illustration of the unexpanded stack  100  of  FIG. 2  also illustrates the multilayer structure of the reference electrode  50  and the auxiliary reference electrode  60  at the end of the stack (the left end from the perspective illustrated in  FIGS. 1, 2, and 3  of this specification). 
         [0036]    After the respective active electrodes, reference electrodes, and interposed one-layer separators have been arranged in a stack as specified in this text, the stack is placed in a pouch container. The insertion of the stack into a pouch may be carried out in a managed air environment of ambient temperature, less than five percent relative humidity, and less than one bar pressure to accommodate suitable filling of the pouch and insertion of the selected electrolyte into the stack so that the lithium-ion containing liquid infiltrates, permeates, and fills all the intended pores and interstices of each member of the stack with no retained air or other unwanted gas in the stack. While still in this packaging environment, the pouch is closed around the lithium-ion cell members stack with the anode group terminal, the cathode group terminal, the reference electrode tab, and the auxiliary reference electrode tab extending though a surface pouch, with a suitable seal between the pouch wall and each of the electrical connectors to the stack within the pouch. 
         [0037]      FIG. 3  is an illustration of the filled pouch  90 . The stack  100  (as illustrated in  FIG. 2  has been placed within pouch  80 , and the top of the pouch  80  has been closed and sealed around anode group terminal  22 ′, cathode group terminal  30 ′, reference electrode tab  56 , and auxiliary reference electrode tab  58 . A portion of the pouch material is broken away and the dashed lines in  FIG. 3  represent the presence of a liquid lithium-ion containing electrolyte  82  that wets surfaces of each active electrode member, each reference electrode member, and each separator in the stack  100 . Suitable pouch containers are commercially available. A suitable and preferred pouch material is polymer coated aluminum foil. The polymer coating comprises multiple layers and is applied to both sides of the aluminum foil in the pouch container. 
         [0038]    The electrolyte for the lithium-ion cell is often a lithium salt dissolved in one or more organic liquid solvents. Examples of salts include lithium hexafluorophosphate (LiPF 6 ), lithium tetrafluoroborate (LiBF 4 ), lithium perchlorate (LiClO 4 ), lithium hexafluoroarsenate (LiAsF 6 ), and lithium trifluoroethanesulfonimide. Some examples of solvents that may be used to dissolve the electrolyte salt include ethylene carbonate, dimethyl carbonate, methylethyl carbonate, propylene carbonate. There are other lithium salts that may be used and other solvents. But a combination of lithium salt and solvent is selected for providing suitable mobility and transport of lithium ions in the operation of the cell. The electrolyte is carefully dispersed into and between closely spaced layers of the electrode elements and separator layers. 
         [0039]    In the above illustrated embodiments of the invention, each cell member of the stacked elements is rectangular in shape. In accordance with general practices of the invention the members of the stack do not have to be rectangular. But a rectangular stack in a rectangular pouch is a convenient shape for the assembly of a lithium-ion battery in many applications. 
         [0040]    By way of illustration, without intention to limit the invention, a rectangular anode 57 mm in height and 52 millimeters in width may be used. Its connector tab would be located at the top side of its copper current collector foil near one vertical side to facilitate the electrical parallel connection of each of the anode foils in a stack. Typically, the thickness of the copper foil is in the range of about 6-20 micrometers, and the thickness of each coating of active material is about sixty micrometers. The thickness of the anode material is dependent on the electrochemical capacity required of it, and is typically in the range of about 10 micrometers to about 150 micrometers. 
         [0041]    It is generally preferred that each anode layer “cover” the adjacent cathode layer and that the separator strip cover both electrodes. So each anode layer is slightly larger than the cathode layer and the separator strip is wider than the height of the anode. A complementary, suitable cathode, for example, may have a height of 55 millimeters and a width of 50 mm. Its connector tab would be located at the top side of its aluminum current collector foil near the other vertical side to facilitate the electrical parallel connection of each of the cathode foils in a stack. Typically, the thickness of the aluminum current collector foil for the cathode is in the range of about ten to thirty micrometers, and the thickness of each coating of active cathode material is about sixty micrometers. In this example, the separator strip is about 60 mm wide, so as to cover both the anode and cathode, and about 25 micrometers thick. The thickness of the cathode material is dependent on the electrochemical capacity required of it, and is typically in the range of about 10 micrometers to about 150 micrometers. 
         [0042]    The height and width of rectangular anodes and cathodes is suitably in the range from ten millimeters to five hundred millimeters and the height and width of the anodes in a stack is slightly larger than the corresponding dimensions of the cathodes in the stack so that the anodes cover the cathodes. As stated the separator layer is sized to cover both the anode and cathode faces. 
         [0043]    The invention has been described using specific examples. The examples are intended to illustrate preferred embodiments of the invention and not to limit its scope.