Abstract:
An apparatus for performing continuous flow chemical reactions such as oxidation, oxidative dehydrogenation and partial oxidation processes involving a reactor design characterized by controlled/optimized addition of a reactant with the objective of: (i) avoiding the explosion regime of the reactant mixture (e.g., hydrocarbon/oxidant mixture); (ii) maximizing the selectivity of the reaction to the desired product; (iii) limiting the reactor temperature gradient and therefore the threat of reaction runaway; and (iv) controlling the operating temperature of the reaction zone so that desirable temperature range is maintained over the entire zone.

Description:
BACKGROUND OF THE INVENTION  
       [0001]     1. Field of the Invention  
         [0002]     The present invention relates to an improved continuous flow chemical reaction apparatus wherein the introduction of at least one reactant feed into the reaction zone is optimized. The invention also relates to improved chemical reactions achieved using the continuous flow chemical reaction apparatus.  
         [0003]     2. Description of Related Art  
         [0004]     Several publications are referenced in this application. The references describe the state of the art to which this invention pertains, and are hereby incorporated by reference.  
         [0005]     An oxidative dehydrogenation, or partial oxidation, process is a one step conversion of light hydrocarbons to olefins and carboxylic acids. The process potentially offers many advantages over cracking and pure dehydrogenation which are extremely capital intensive and energy intensive. The conversion of saturated hydrocarbons into olefins and carboxylic acids over low temperature catalysts was disclosed by Thorstienson et al. in a report published in  Journal of Catalysis,  vol. 52, pp. 116-132 (1978).  
         [0006]     U.S. Pat. No. 4,250,346 discloses a process for oxidative dehydrogenation of ethane to ethylene suggesting different low temperature catalyst systems. European Patent No. EP 0 518 548 A2 discloses a process for making acetic acid which comprises oxidizing ethane with molecular oxygen in a reaction zone at a pressure at least 100 psig while the reactants are in contact with a solid catalyst containing vanadium and phosphorous oxides (VPO system).  
         [0007]     The oxidative dehydrogenation reaction, however, raises problems such as: (a) removal of the exothermic heat of reaction, (b) possible associated temperature runaway, (c) control of selectivity to desired product, and (d) limiting the formation of undesired oxygenated by-products and carbon oxides.  
         [0008]     Another problem which is associated with oxydehydrogenation processes, as well as oxidation processes, is the limitation on the oxidant to hydrocarbon feed ratios which is imposed by the explosive mixture formation constraint. This problem compromises the ability of the process to achieve optimality of feed compositions that satisfy the stoichiometric and kinetic requirements of the reaction, yet avoid compositions which can lead to autoignition, deflagration, and detonation.  
         [0009]     These problems have been addressed in a number of patents. Each tried to overcome one or more of the difficulties mentioned above by proposing a modified reactor system or different reactor arrangement.  
         [0010]     U.S. Pat. No. 4,899,003 issued to Union Carbide relates to multi-staging the reactor system where a feed gas comprising ethane and oxygen is converted over an oxydehydrogenation catalyst to a product gas comprising ethylene, acetic acid, water, ethane, and carbon oxides. The product gas from each stage (other than the last stage) is cooled and a portion of the acetic acid and water is separated and oxygen is added before passing the product gas stream to the next reaction stage. Total oxygen content in the feed stream to any of the reactors was maintained below 6 mole percent with respect to the total input gaseous stream in that stage.  
         [0011]     U.S. Pat. No. 5,583,240 issued to SRI relates to a reactor with porous membranes to provide for the continuous addition of one reactant all along the reactor and mixing in the entire volume of the reactor to minimize or eliminate local high concentration gradients and hot spots. The other reactant is flowed through the inside of the permeation tube, which contains mixing elements. Those mixing elements were claimed to increase the yield of desired product by increasing the heat and mass transfer rates.  
         [0012]     European Patent No. EP 546 677 A1 relates to a fluidized bed for ethane oxidation to acetic acid. The disclosed process included three key steps: (1) cooling the gaseous effluent from the reaction zone; (2) separating most of the acetic acid in liquid form from the effluent gases, leaving a gaseous stream containing nearly all of the carbon oxide contained in the effluent; (3) purging a small portion of said gaseous stream and recycling most of the gaseous stream as part of the feed to the reaction zone. Purging is intended to prevent build-up of carbon oxides in the reaction zone, while recycling serves to maintain a high proportion of carbon oxides in the reaction zone gases, thus aiding in moderating the temperature elevating effect of the highly exothermic oxidation reaction.  
         [0013]     U.S. Pat. No. 5,723,094 relates to a chemical reactor design which provides improved micro-mixing conditions and reduced localized zones of concentration to increase reaction selectivity to desired products. The design includes a capillary tubelet positioned within and along the length of flow tubes positioned in a shell reactor and one or more distributors for distributing a first reactant into the flow tubes and a second reactant into the capillary tubes.  
         [0014]     European Patent Publication No. 0 532 325 relates to a method and apparatus for the production of ethylene oxide. European Patent Publication No. 0 383 224 relates to a shell-and-tube reactor and method of using the same.  
         [0015]     It would be desirable to provide a continuous flow chemical reaction system which provides optimality of feed compositions along a substantial portion of the reaction zone and satisfies the stoichiometric and kinetics requirements of the reaction while maintaining the reaction mixture within the explosive mixture formation constraint and thus avoid reactant mixtures which can lead to autoignition, deflagration, and detonation.  
       OBJECTS OF THE INVENTION  
       [0016]     It is an object of the invention to overcome the above-identified deficiencies.  
         [0017]     It is another object of the invention to provide an improved continuous flow chemical reaction apparatus and method of using the same.  
         [0018]     It is another object of the invention to provide an improved continuous flow chemical reaction system where a controlled amount of at least one fluid reactant is introduced into the reaction zone at more than one location.  
         [0019]     It is another object of the invention to provide an improved continuous flow chemical reaction where a controlled, optimized amount of at least one fluid reactant is introduced into the reaction zone at more than one location.  
         [0020]     It is a further object of the invention to provide an improved continuous flow chemical system for performing a catalytic reaction where at least one fluid reactant is introduced into the reaction zone at more than one location.  
         [0021]     It is a still further object of the invention to provide an apparatus in which one or more of the reactants is fed in an optimized distributed fashion to meet certain safety and performance requirements.  
         [0022]     It is yet another object of the invention to provide a reactor which achieves a catalyst bed temperature profile controlled by means of non-uniform reactant(s) distribution so that desired operating temperature range is achieved along the entire length of the reactor tube.  
         [0023]     It is a still further object of the invention to provide an improved continuous flow chemical reaction system which provides optimality of reacting mixture compositions along a substantial portion of the reaction zone and satisfies the stoichiometric and kinetics requirements of the reaction.  
         [0024]     It is a still further object of the invention to provide a reactor and reaction process wherein the total overall inventory of the reacting mixture falls within an unsafe/explosive composition region, while at any given point or region within the reactor the compositional mixture is within the domain of safe/non-explosive compositions.  
         [0025]     The foregoing and other objects and advantages of the invention will be set forth in or apparent from the following description.  
       SUMMARY OF THE INVENTION  
       [0026]     The present invention relates to a process and apparatus for the controlled/optimized addition of reactant(s) in continuous flow chemical reactions, preferably oxidative dehydrogenation, partial oxidation, or oxidation reactions. More specifically, the invention deals with the shortcomings of these high potential processes by the controlled addition of a reactant which is achieved by means of an injection member (tube) along the length of the reaction zone. The injection member (tube) is provided with injector(s) capable of introducing a controlled amount of reactant at the injector site into the reaction zone. Preferably, the injection member (tube) is provided with wall penetrations, holes, perforations, spargers, capable of performing two functions: (1) pressure drop control and (2) flow control. According to one preferred embodiment, the injectors allow for the introduction of a controlled amount of reactant into the reaction zone without allowing any reactant(s) to flow into the injector member (tube) from the reaction zone.  
         [0027]     The present design offers a high degree of controllability over the quantity of reactant injection and the locations of the points of injection by adjusting the distance between the injection points. Therefore, injection can be optimized in such a way that only the sufficient and kinetically required amount of reactant is supplied at each point and this is controlled to respond to the spatial variation of the reaction conditions (i.e., temperature, pressure and reaction mixture composition).  
         [0028]     According to another embodiment, an intermediate or co-feed may be injected which enhances catalyst performance or suppresses a certain poisoning effect. This provides yet another utility of the present invention.  
         [0029]     The benefits achievable by using the present invention include the accurate control of the temperature profile along the catalyst bed by controlling the reaction extent and heat release via the quantitative and positional control of reactant addition.  
         [0030]     The invention also enhances the catalyst productivity by introducing reactants in proportions which are not possible in conventional reactors due to the explosion regime limitation and the reaction runaway limitation.  
         [0031]     The invention also provides a tool for designing the reaction in such a way that the production of the desired product is optimized.  
         [0032]     The invention also allows for the adjustment of the reactant mixture composition at every point inside the reactor, as well as the reactor entrance, so that reactant mixtures within the explosion regimes can be avoided.  
         [0033]     Furthermore, the invention improves catalyst performance by the delayed addition of a component which reverts its reduction/oxidation state or a component which remedies a catalyst poisoning situation. 
     
    
     BRIEF DESCRIPTION OF THE FIGURES  
       [0034]     The following detailed description, given by way of example but not intended to limit the invention solely to the specific embodiments described, may best be understood in conjunction with the accompanying drawings in which:  
         [0035]      FIG. 1  is a schematical representation of an improved reaction zone according to one embodiment of the invention.  
         [0036]      FIG. 2  is a schematical representation of an improved reaction zone according to another embodiment of the invention.  
         [0037]      FIG. 3  is a schematical drawing of a reaction system according to one embodiment of the invention.  
         [0038]      FIG. 4  is a schematical drawing of a reaction system according to another embodiment of the invention.  
         [0039]      FIG. 5  is a schematical drawing of a reaction system according to yet another embodiment of the invention.  
         [0040]      FIG. 6  is an enlarged schematical drawing of the pressure drop control means shown in  FIG. 5 .  
         [0041]      FIG. 7  is a schematical drawing of a reaction system according to another embodiment of the invention.  
         [0042]      FIG. 8  is a schematical drawing of a reaction system according to yet another embodiment of the invention.  
         [0043]      FIG. 9  is a schematical drawing of a reaction system according to another embodiment of the invention.  
         [0044]      FIG. 10  is a graphical representation of the oxygen distribution pattern for a continuous flow chemical reaction zone according to one embodiment of the invention where the vertical axis represents oxygen flow (SLPH) and the horizontal axis represents the reaction tube coordinate along the length of the reaction zone (m).  
         [0045]      FIG. 11  is a graphical representation of the reaction temperature profile for a continuous flow chemical reaction zone according to one embodiment of the invention and according to two comparative continuous flow chemical reaction zones where the vertical axis represents reaction temperature (° C.) and the horizontal axis represents the reaction tube coordinate along the length of the reaction zone (m).  
         [0046]      FIG. 12  is a graphical representation of the oxygen concentration profile for a continuous flow chemical reaction zone according to one embodiment of the invention and according to two comparative continuous flow chemical reaction zones where the vertical axis represents oxygen concentration (mole %) and the horizontal axis represents the reaction tube coordinate along the length of the reaction zone (m).  
         [0047]      FIG. 13  is a schematical drawing of a reaction system according to another embodiment of the invention. 
     
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS  
       [0048]     One aspect of the invention relates to improved continuous flow reaction systems.  
         [0049]     One preferred embodiment of the invention relates to multi-tubular fixed bed catalytic reactors with the novel feature of a non-uniform distribution member such as the one described in  FIG. 1 . The first reactant feed is fed into a reaction zone via an inlet at one end of the reaction zone, while the second reactant feed is introduced into the reaction zone at a multiplicity of points along the length of the reaction zone via a central tube or distribution member. The distribution member preferably satisfies two important criteria at each point along the length of the catalyst bed: (1) pressure drop control; and (2) flow control.  
         [0050]     Another embodiment of the invention is depicted in  FIG. 2  which shows a continuous flow chemical reaction apparatus  10  comprising a reaction zone  11 , preferably a tubular reaction which optionally contains catalyst  12 . Reaction zone  11  also having a length and having a first fluid reactant feed inlet  13  for introducing first fluid reactant feed  14  into tubular reaction zone  11  at a first end  17  and a product outlet  15  for product stream  16  at a second end  18 . The first fluid reactant feed  14  comprises the first fluid reactant and, preferably, a portion of second fluid reactant. The tubular reaction zone  11  also includes an interior conduit  20  extending lengthwise within tubular reaction zone  10 . Conduit  20  having a second feed inlet  21  for introducing a second fluid reactant feed (e.g., containing a second fluid reactant) into tubular reaction zone  11  and, optionally, a second fluid feed outlet  23  for second fluid reactant exit stream  25 . Conduit  20  also having a multiplicity of injectors  30  spaced apart along the length of conduit  20 , each of injectors  30  capable of introducing a controlled amount of a second fluid feed into tubular reaction zone  11 . As shown in  FIG. 2 , conduit  20  may pass through the entire length of tubular reaction zone  11 . Alternatively, conduit  20  may end within tubular reaction zone  11  (see  FIG. 3  described below).  
         [0051]     According to one embodiment, the second fluid reactant is advantageously mixed with the first fluid reactant in the first fluid feed  14  so that an injector  30  is not required in the first segment of reaction zone  11 . The composition containing the second reactant provided in the first fluid feed may be the same or different from the composition containing the second reactant provided by the second feed. For example, the first feed may include pure oxygen (which is an oxygen-containing composition) as the second reactant and the second feed may contain air (which is also an oxygen-containing composition) also as the second reactant. Alternatively, the first and second feed may contain the same second reactant composition such as each containing air or pure oxygen.  
         [0052]     According to another embodiment, first fluid reactant feed  14  includes the first reactant (without any second reactant) and second fluid reactant feed  22  includes the second reactant. According to this embodiment, the apparatus preferably includes an injector  30  proximate the first end  17  of the reaction zone  11  to provide second reactant at the front end of the reaction zone.  
         [0053]     Yet another embodiment of the invention, depicted in  FIG. 3 , relates to a continuous flow chemical reaction apparatus  40  comprising a plurality of tubular reaction zones  11 , optionally containing catalyst  12 , within a heat transfer vessel  41  including at least one heat transfer zone  42 , each of the heat transfer zones  42  having a heat transfer fluid inlet  43  and a heat transfer fluid outlet  44 . Reactor apparatus  40  also having a first reaction feed inlet  45  for first reaction feed  14 . Reactor apparatus  40  also having a second reaction feed inlet  47  for a second reaction feed  22  and a reactor product outlet  46  for product stream  16 . According to one embodiment, first reaction feed  14  contains a first reactant (e.g., ethane, ethylene) and preferably a portion of a second reactant (e.g., air, oxygen). Each of tubular reaction zones  11  having a length, a first fluid reactant feed inlet  13  at a first end, a product outlet  15  at a second end and an interior conduit  20  extending lengthwise within tubular reaction zone  11 . Interior conduits  20  having a multiplicity of injectors  30  spaced apart along the length of the conduits  20  and along the length of the tubular reaction zone  11  and each of injectors  30  being adapted to introduce a controlled amount of second fluid reaction feed  22  into tubular reaction zones  11 .  
         [0054]     Preferably, as depicted in  FIG. 4 , heat transfer vessel  41  comprises a plurality of heat transfer zones  42 . According to one preferred embodiment, heat transfer vessel  41  is a cylindrical vessel.  
         [0055]     In another preferred embodiment, depicted in  FIG. 5 , the continuous flow chemical reaction apparatus  40  of  FIG. 3  has interior conduits  20  which do not dead end in tubular reactor zone  11  but rather extend through tubular reaction zone  11  to outlet header  48  to exit the reaction apparatus  40  through second reactant feed outlet  49 . In this embodiment of the invention, second feed exit stream  25  (containing excess, unreacted second reactant) can be passed through reaction apparatus  40  and thereby assist in removing the heat of reaction. Preferably, second feed exit stream  25  is recycled into reaction zone  11  via inlet  47 .  
         [0056]     Preferably, the apparatus further comprises a catalyst  12  within the tubular reaction zone(s)  11 . Advantageously, the apparatus further comprises a catalyst bed(s) within the tubular reaction zone(s) and surrounding the interior conduit(s).  
         [0057]     According to one preferred embodiment, interior conduit(s)  20  is concentric with the tubular reaction zone(s)  11 . Preferably, the tubular reaction zone(s)  11  has a cross-section which is a substantially circular, interior conduit  20  is concentric with tubular reaction zone  11  and tubular reaction zone  11  comprises a catalyst bed  12  surrounding the interior conduit  20 .  
         [0058]     The apparatus of the invention comprises a plurality of injectors  30 , preferably between 2 and 40 injectors, more preferably between 4 and 25 injectors and most preferred between 6 and 15 injectors. Advantageously, injectors  30  are selected from the group consisting of wall penetrations, holes, perforations, spargers, or combinations thereof.  
         [0059]     According to another preferred embodiment, also depicted in  FIG. 5 , the apparatus further comprises a pressure drop control means  50  in conduit(s)  20  proximate to at least one of or each of injectors  30 . Pressure drop control means  50  can be packing, pellets or any other flow restricting devices.  FIG. 6  illustrates an enlarged schematical representation of a pressure drop control means  50  (pellets) according to one embodiment of the invention.  
         [0060]     Another embodiment of the invention relates to a continuous flow chemical reaction fluidized bed apparatus  60  as shown in  FIG. 7 . Apparatus  60  comprises a fluidized bed reaction zone  55  having a height and having a first fluid reaction feed inlet  13  at a lower end for first fluid reaction feed  14  and a product outlet  15  for product stream  16  at an upper end. The first fluid reaction feed  14  includes a first reactant and preferably a portion of second fluid reactant. Fluidized bed reaction zone  55  also includes an interior conduit  20  extending vertically within the fluidized bed reaction zone  55 , the conduit  20  having a multiplicity of injectors  30  spaced apart along the length of the conduit, each of the injectors  30  capable of introducing a controlled amount of a second fluid reaction feed  22  into the fluidized bed reaction zone  55 . Preferably, conduit  20  also includes pressure drop control means  50  proximate injectors  30 . Second fluid reaction feed  22  preferably comprises a second reactant.  
         [0061]     Yet another embodiment of the invention, shown in  FIG. 8 , relates to a continuous flow chemical reaction apparatus  70  comprising a plurality of fluidized bed reaction zones  55  within a heat transfer vessel  41  having at least one heat transfer zone  42 , each of the heat transfer zones  42  having a heat transfer fluid inlet  43  and a heat transfer fluid outlet  44  and each of the tubular reaction zones  55  having a height. The tubular reaction zones  55  also having a first fluid feed inlet  45  for first fluid feed  14  at a lower end, a product feed outlet  46  for product feed  16  at an upper end and an interior conduit  20  extending vertically within each of fluidized bed reaction zones  55 . The interior conduits  20  having a multiplicity of injectors  30  spaced apart along the length of the fluidized bed reaction zones  55  and each of the injectors  30  being adapted to introduce a controlled amount of a portion of second fluid feed reactant  22  into the fluidized bed reaction zone  55 .  
         [0062]      FIG. 9  illustrates a partial schematical view of another embodiment of the invention where apparatus where second reactant feed  22  is introduced into a fluidized bed reaction zone  81  via conduits  82 , wherein the conduits  82  are perpendicular to the flow of first reaction feed  14  and each conduit  82  introduces different or the same amounts of second reaction feed  22  at each point along reaction zone  81 .  
         [0063]     Preferably, the fluidized bed apparatus is capable of operating in the bubbling regime. According to one embodiment, the reaction zone is a circulating fluidized bed.  
         [0064]     Another aspect of the invention relates to improved chemical reactions. Using the present invention, chemical reactions can be performed achieving improved yields and selectivity. The fluid flowing through the distribution member can be a single reactant component, a mixture of reacting components or a mixture of reacting component(s) and inert component(s).  
         [0065]     One embodiment of the invention relates to a method of performing a continuous chemical reaction between at least one first fluid reactant and at least one second fluid reactant to form a reaction product comprising:  
         [0066]     (a) continuously introducing a first fluid reaction feed containing the first reactant and, preferably, the second fluid reactant, into a first end of a tubular reaction zone having a length whereby the first and second fluid reactants continuously flow towards a second end of the tubular reaction zone; and  
         [0067]     (b) continuously introducing a second fluid reaction feed containing the second fluid phase reactant into an interior conduit which extends lengthwise within the tubular reaction zone, the interior conduit having a multiplicity of injectors spaced apart lengthwise along the conduit;  
         [0068]     (c) introducing the second fluid reaction feed into the tubular reaction zone at a multiplicity of points along the length of the tubular reaction zone by passing controlled amounts of the second reaction feed containing the second reactant through the multiplicity of injectors into the tubular reaction zone; and  
         [0069]     (d) providing conditions conducive to the chemical reaction in the tubular reaction zone whereby the chemical reaction proceeds and the reaction product is formed.  
         [0070]     Another embodiment of the invention relates to a method of performing a catalytic chemical reaction comprising reacting a first fluid reactant with a second fluid reactant to form a reaction product in a catalyst bed, wherein  
         [0071]     (a) a first fluid reaction feed is introduced into a first end of a tubular reaction zone having a length and containing the catalyst bed, the first fluid reaction feed containing the first and second fluid reactants flowing towards a second end of the tubular reaction zone;  
         [0072]     (b) a second fluid reaction feed containing the second reactant is introduced into a conduit within and concentric to the tubular reaction zone, the conduit having a multiplicity of injectors spaced apart lengthwise along it and each of the injectors introduces a controlled amount of the second reactant into the tubular reaction zone; and  
         [0073]     (c) providing conditions conducive to the chemical reaction within the tubular reaction zone whereby the chemical reaction proceeds and the reaction product is formed.  
         [0074]     Preferably, the tubular reaction zone(s) contains a catalyst and the first fluid reactant flows through the catalyst along with the second fluid reactant.  
         [0075]     According to one preferred embodiment, the chemical reaction has a selected reaction temperature and the temperature in the tubular reaction zone(s) is maintained within 15° C. of the selected reaction temperature through at least 50% of the length of the tubular reaction zone(s). Preferably, the reaction temperature is maintained within 10° C., advantageously within 6° C. of the selected reaction temperature through at least 50% of the length of the tubular reaction zone(s).  
         [0076]     According to another preferred embodiment, the chemical reaction has an explosive regime when the concentration of the second fluid reactant in the tubular reaction zone is at an explosive concentration and the invention further comprises controlling the amount of the second fluid reactant introduced into the tubular reaction zone so that the concentration of the second fluid reactant is at least 70%, preferably at least 80%, more preferably at least 90%, of the explosive concentration through at least 50% of the length of the tubular reaction zone and does not exceed the explosive concentration at any point throughout the length of the tubular reaction zone.  
         [0077]     According to one preferred embodiment, the total overall inventory of the reacting mixture falls within an unsafe/explosive composition region, while at any given point or region within the reactor the compositional mixture is within the domain of safe/non-explosive compositions.  
         [0078]     According to one embodiment, the chemical reaction is the partial oxidation of ethane to ethylene and acetic acid, and wherein the first fluid reactant comprises ethane and the second fluid reactant comprises oxygen. (e.g., pure O 2 , air, etc.).  
         [0079]     According to another embodiment, the chemical reaction is the partial oxidation of ethane to ethylene and acetic acid, wherein the first fluid reactant comprises ethane and the second fluid reactant comprises oxygen, and at least 10% of the ethane in the first fluid reactant is reacted to form acetic acid per single pass through the tubular reaction zone.  
         [0080]     Another embodiment of the invention relates to a method of performing a continuous chemical reaction in a fluidized bed between at least one first fluid reactant and at least one second fluid reactant to form a reaction product comprising:  
         [0081]     (a) continuously introducing the first fluid reactant and preferably a portion of the second fluid reactant into a lower end of a fluidized bed reaction zone having a height whereby the reactant(s) continuously flows towards an upper end of the fluidized bed reaction zone; and  
         [0082]     (b) continuously introducing the second fluid phase reactant into an interior conduit which extends vertically within the fluidized bed reaction zone, the interior conduit having a multiplicity of injectors spaced apart lengthwise along the conduit;  
         [0083]     (c) introducing the second fluid phase reactant into the first fluid phase reactant at a multiplicity of points along the height of the fluidized bed reaction zone by passing controlled amounts of the second reactant through the multiplicity of injectors into the fluidized bed reaction zone; and  
         [0084]     (d) providing conditions conducive to the chemical reaction in the fluidized bed reaction zone whereby the chemical reaction proceeds and the reaction product is formed.  
         [0085]     Another embodiment relates to a method of performing a catalytic chemical reaction comprising reacting a first fluid reactant with a second fluid reactant to form a reaction product in a catalyst bed, wherein:  
         [0086]     (a) the first fluid reactant, along with a portion of second fluid reactant, is introduced into a lower end of a fluidized bed reaction zone having a height and containing the catalyst bed, the first and second fluid reactants flowing towards an upper end of the fluidized bed reaction zone;  
         [0087]     (b) the second fluid reactant is introduced into a conduit within the fluidized bed reaction zone, the conduit having a multiplicity of injectors spaced apart lengthwise along it and each of the injectors introduces a controlled amount of the second reactant into the fluidized bed reaction zone; and  
         [0088]     (c) providing conditions conducive to the chemical reaction within the fluidized bed reaction zone whereby the chemical reaction proceeds and the reaction product is formed.  
         [0089]     Preferably, the chemical reaction in the fluidized bed proceeds in the bubbling regime.  
         [0090]     A full range of industrially important reactions can benefit from the current inventions especially those suffering from: temperature run-away limitations and explosive mixtures composition limitation such as ethylene oxide, maleic anhydride, phalic anhydride, etc.  
         [0091]     Additional reactions which may be performed using the present invention are set forth in Table I below.  
                           TABLE I                                   Reaction   Catalyst                           Hydrogenation               Cyclopropane + H 2 C 3 H 8 C 2 H 6  +   Pt, Pd, Rh, Ru           H 2 2CH 4             3H 2  + N 2 2NH 3     Fe           2H 2  + COCH 3 OH   Cu + /ZnO           Heptane toluene + 4H 2     Pt           Acetone + H 2  2-propanol   Pt, Copper chromite           H 2  + aldehyde alcohol   Pt, Pd, Rh, Ru           Oxi-chlorination           Halogenation           Oxidation           CH 3 OH + ½O 2 CH 2 O + H 2 O   Fe 2 O 3 .MoO 3             H 2 O + COH 2  + CO 2     Fe 3 O 4 , Ni, CuO/ZnO           ½O 2  + CH 2 CH 2 CH 3 CHO   PdCl and similar salts of               noble metals           RCH 2 OHRCHO + H 2     Pt           Glucose d-glucuronic acid   Pt                      
 
       EXAMPLES  
       [0092]     The invention is further described in the following examples. The examples are illustrative of some of the products and methods of making the same falling within the scope of the present invention. They are, of course, not to be considered in any way limitative of the invention. Numerous changes and modifications can be made with respect to the invention.  
       Example 1  
       [0093]     Partial oxidation of ethane to ethylene and acetic acid is utilized here as a model reaction to demonstrate the benefit of the present invention. Kinetics developed by Thorstienson et al.,  Journal of Catalysis,  vol. 52, pp. 116-132 (1978) are used to describe the rates of reactions involved on this partial oxidation process, those reactions are: 
 
C 2 H 6 +0.5 O 2 →C 2 H 4 +H 2 O
 
C 2 H 4 +O 2 →CH 3 COOH
 
C 2 H 6 +3.5 O 2 →2CO 2 +3H 2 O
 
C 2 H 4 +2O 2 →2CO+2H 2 O
 
CH 3 COOH+O 2 →2CO+2H 2 O
 
CO+0.5 O 2 →CO 2 
 
C 2 H 4 +3.0 O 2 →2CO 2 +2H 2 O
 
         [0094]     Model equations have been developed for the catalyst tube resulting in a system of non-linear ordinary differential equations which were solved numerically to predict the non-isothermal behavior of the reaction. This is to calculate the reacting mixture compositions, pressure and temperature at each point along the length of the reactor tube.  
         [0095]     The model was then used to simulate operating scenarios where the target in each one was to maximize the production of ethylene and acetic acid without having a oxygen concentration higher than that of the lower explosion limit of the ethane-oxygen mixture (estimated as 8% oxygen in ethane under the elected operating conditions).  
         [0096]     Operating variables and design parameters for the three cases (Cases I, II and III) which were studied using the model are provided in Table II. The predicted performance is also given in the same table.  
                                                 TABLE II                                   Case I   Case II   Case III                                    Ethane Flow, SLPH   8280   8280   8280       Oxygen Flow at entrance, SLPH   720   720   720       Oxygen Flow Distributed, SLPH   —   400   1000       Feed Temperature, C.   120   120   120       Coolant Temperature, C.   256   254   254       Feed Press, Barg.   26   26   26       Catalyst Tube ID mm   24.3   24.3   24.3       Catalyst Tube OD mm   33.4   33.4   33.4       Catalyst Tube Length, mm   1250   1250   1250       Central Tube OD, mm   —   6   6       Ethane conversion, %   4.0   5.6   7.6       Oxygen Conversion, %   92.8   85.0   77.6       Selectivity to (Ethylene + Acetic Acid)   72.8   70.1   68.0       Overall Performance in STY (Tons of   593   803   1058       desired products per ton Catalyst per Year)                  
 
         [0097]     In Case I, the reactor is of the conventional fixed bed type, and the feed composition is constrained by the explosion limit of 8% O 2  in the mixture.  
         [0098]     The second scenario (Case II) employs a reactor of the type proposed by Tonkovich et al. (1996) in  Chem. Eng. Science,  vol. 51, in which the distribution of more oxygen than that allowed in the main feed is carried out continuously along the catalyst bed by means of a porous central tube. The amount of oxygen flowed through the central tube was limited by the oxygen concentration at intermediate points in the catalyst bed.  
         [0099]     The third scenario (Case III) has a special oxygen flow distribution pattern, as shown in  FIG. 10 . The same constraint of 8% oxygen concentration was used for this case. However, the non-uniform/controlled distribution pattern gave rise to a much superior reactor performance, as it allowed for much more oxygen to be fed to the reaction system, thus increasing the ethane conversion and the catalyst tube productivity. The preferred embodiment of the invention (Case III) provides a performance improvement of 78% over the conventional reactor and 32% over the uniform oxidant distribution option (Case II).  
         [0100]     Moreover, the invention provides for better control over the catalyst bed temperature as shown in  FIG. 11 , maintaining the catalyst and reaction mixture in a preferred operating temperature range, while this advantage was not achievable neither by conventional reactor nor by the uniform distribution option.  
         [0101]     Another reason for the superior performance demonstrated is the ability of the novel reactor to maintain the oxygen concentration within a favorable range along the length of the reaction zone, as can be seen in  FIG. 12 .  
       Example 2  
       [0102]     The reaction of ethane oxidation was performed using a pilot scale testing unit illustrated in  FIG. 13 . The following is a description of the testing rig:  
         [0103]     A. Feed Section  
         [0104]     The feed section consisted mainly of clusters of compressed gas cylinders with manifolds and mass flow controllers. The feed section was constructed to feed into the reactor the following reactants: ethane, air, oxygen, carbon dioxide and nitrogen. Mass flow controllers on each gas feed line were operated from a remote location. A forward pressure regulator on each gas feed line maintained the desired pressure of the reactants.  
         [0105]     B. Reactor Section  
         [0106]     The prototype multi-injection reactor was constructed from 316 stainless steel with a length of 12.5 m. It was bent into a U-shape to keep the structure within a reasonable height. The reactor consisted of an inner (distribution) tube, a thermowell, an outer tube and a shell. The inner tube and the thermowell were situated inside the outer tube, which was filled with a catalyst of the type described in the U.S. Pat. No. 6,030,920, U.S. Pat. No. 6,013,597 and U.S. Pat. No. 5,907,056. The shell surrounded the outer tube. The dimensions of the tubes and the shell are as follows:  
                                                                     Outer diameter, mm   Thickness, mm                                        Inner tube   12   1.5           Thermowell   8   1.5           Outer tube   44.5   2.6           Shell   88.9   4.0                      
 
         [0107]     The inner tube had distribution points along its length equipped with custom-built injectors. The size and number of injector holes were designed to provide the following flow pattern:  
                                                                                                   Location from tube entrance, mm                2000   4000   6000   8000   10500                        Percentage of the total   8   11   30   28   23       flow to the inner tube                  
 
         [0108]     Steam was circulated in the shell of the reactor counter currently to accomplish the required heat removal. A differential pressure transmitter (“DPT”) was installed to monitor the total pressure drop along the reactor catalyst bed. A provision for sampling the reaction mixture was made at four different points along the catalyst bed.  
         [0109]     C. Product Handling  
         [0110]     The product gases from the reactor were then transferred to a shell and tube heat exchanger, where product condensation was achieved by a chilled water being circulated on the shell side. The two phase flow exiting the exchanger was sent to a gas liquid separator, from which gases were vented and liquids were collected in a receiving tank. Both condensation and separation of the product took place under the system pressure by means of a back pressure regulator installed on the vent gas line leaving the condensate separator.  
         [0111]     D. Heat Transfer System  
         [0112]     The heat transfer system included a steam drum and an air blower. The steam drum was located at a point above the reactor and was connected to the shell side of the reactor. The air blower was connected to the jacket of the drum to cool the steam. The system was instrumented with a level transmitter to indicate the level of water in the drum, a temperature transmitter, a pressure transmitter and safety relief valve.  
         [0113]     E. Results  
         [0114]     A comparison is given below in Table III for two experimental runs, where in the first run the oxygen feed was introduced according to the distribution scheme given earlier. While in the second run the inner tube was replaced by a dummy tube and only the allowable oxygen due to the explosion limit was introduced with the hydrocarbon at the reactor entrance (e.g., single oxygen inlet with hydrocarbon feed). All other conditions (coolant temperature, reaction peak temperature, hydrocarbon flow, system pressure, etc.) were kept the same.  
                                             TABLE III                                   Run #1   Run #2                                        Total flow, m 3 /h   33.28   33.3           Percentage ethane   44.95   45.05           Oxygen injected   3.3   0.0           Pressure, barg   26.0   26.0           Coolant Temperature, C.   251.0   251.0           Peak Temperature, C.   278.0   278.0           Ethane conversion, %   13.02   8.69           Oxygen Outlet, %   5.51   0.52           Acetic Acid Selectivity, %   59.24   48.12           Ethylene Selectivity, %   16.38   25.38           CO 2  Selectivity, %   23.34   25.74           Acetic Acid Productivity, kg   1171.7   636.9           Acid/kg Catalyst/year                      
 
         [0115]     As shown in Table III, the present invention (Run #1) provides a productivity to acetic acid at least 80% greater than the productivity provided by the comparative embodiment (Run #2). Moreover, both the ethane conversion and acetic acid selectivity is improved using the invention.  
         [0116]     Reference is also made to copending U.S. application Ser. No. ______ (Attorney Reference Number 0080577-0090) by Adris et al. and entitled “Tubular Reactor with Gas Injector For Gas Phase Catalytic Reactions” filed on even date herewith, herein incorporated by reference.  
         [0117]     The above description of the invention is intended to illustrative and not limiting. Various changes or modifications in the embodiments described may occur to those skilled in the art. These can be made without departing from the spirit or scope of the invention.