Abstract:
The present invention provides a batch type atomic layer deposition. Particularly, the batch type ALD apparatus and an in-situ cleaning method thereof supplies a cleaning gas to a central region of an upper plate in a radial form, thereby improving an efficiency on the in-situ cleaning of the batch type ALD apparatus.

Description:
FIELD OF THE INVENTION  
         [0001]    The present invention relates to an atomic layer deposition (ALD) apparatus; and more particularly, to a batch type ALD apparatus and an in-situ cleaning method thereof.  
         DESCRIPTION OF THE PRIOR ART  
         [0002]    Recently, an atomic layer deposition (ALD) technique using a surface reaction is applied to a structure having a high aspect ratio due to a limitation of a chemical vapor deposition (CVD) technique to overcome high aspect ratio.  
           [0003]    [0003]FIG. 1 is a schematic diagram showing an apparatus for an atomic layer deposition adopting a traveling wave method in accordance with a prior art.  
           [0004]    As shown in FIG. 1, the apparatus includes: a chamber  10  using the traveling wave method and having a channel-like shape; a wafer  11  is loaded on a bottom of the chamber  10 ; first and second channels  12 A and  12 B for injecting a source gas, a reaction gas and a purge gas being formed on one side of the chamber  10 ; and a pump for exhausting the gases being equipped on other side of the chamber  10  even if not illustrated.  
           [0005]    In performing the atomic layer deposition adopting the traveling wave method, a series of the following processing steps are proceeded; the wafer  11  is loaded into the chamber  10 ; a process for a chemical absorption of a source gas is carried out on the wafer  11 ; the remnant source gas is exhausted by injecting a purge gas like an inert gas; an atomic layer is deposited by injecting a reaction gas and subsequently inducing a surface reaction between the chemically absorbed source gas on the wafer and the reaction gas; and the above inert gas is injected again in order to exhaust the remnant gas and. a by-product produced by the surface reaction.  
           [0006]    The above series of the processing steps constitute one cycle, and this cycle is repeatedly carried out until obtaining an intended thickness of the atomic layer.  
           [0007]    According to the prior art, it is possible to obtain a conformal and uniform film. It is also possible to suppress more effectively a particle generation elicited by a gas phase reaction compared to a CVD technique because the source gas and the reaction gas are separated from each other by the inert gas and then, the separated source/reaction gases are supplied into the chamber  10 . In addition, induction of multi-collision between the source gas and the wafer improves efficiency on use of the source gas and reduces a cycle duration period.  
           [0008]    However, the above-mentioned prior art of which throughput ranges between about 3 wafer per hour (WPH) and about 4 WPH is not suitable for applying it to a mass production system because lots of equipment, an huge space, and a maintenance expense are needed to maintain such system and the above mentioned throughput is not relatively remarkable.  
           [0009]    The Korean patent application No. 10-2002-27614 discloses a batch type atomic layer deposition to overcome the above problems (refer to FIG. 2).  
           [0010]    As shown in FIG. 2, the batch type atomic layer deposition apparatus consists of the following parts: a reaction chamber  30  including a sidewall  31 C, an upper plate  31 A, and a lower plate  31 B; a hole type shower head  33  for injecting a source gas, a reaction gas, and a purge gas including a cleaning gas by passing through a channeled central region of the upper plate  31 A; a heating plate  33  being attached to the lower plate  31 B and being able to control a temperature of any area on a wafer; a rotating axis  34  penetrating through the lower plate  31 B and a central region of the heating plate  33 ; a rotating plate  35  on which a plurality of wafers are loaded with an identical distance from its center and of witch bottom side is fixed to the rotating axis  34 ; and a baffle structured exhaust  37  which exhausts the gases injected from the hole-type shower head  32  by passing through the lower plate  31 B along the sidewall  31 C adjacent to an edge area of the rotating plate  35 . A groove  35 A used for loading the wafer is formed on a surface of the rotating plate  35 , wherein the groove prevents an atomic layer from being deposited on a bottom side of the wafer and tightens the wafer so as not to be shaken during the rotation. Herein, TiCl 4 , NH 3 , Ar and Cl 2  are used as a source gas, a reaction gas, a purge gas and a cleaning gas, respectively.  
           [0011]    In addition, the heating plate  33  is divided into three heating zones, that is, Z 1 , Z 2  and Z 3  on which wafers are symmetrically loaded around the central region of the heating plate  33 . Each of the heating zones has a ring type arc lamp  33 A arranged with a constant distance.  
           [0012]    More specifically, the heating plate  33  is located right under the rotating plate  35 , a first heating zone (Z 1 ) most closely adjacent to the shower head  32  among the three heating zones has three arc lamps  33 A, a third heating zone (Z 3 ) most closely adjacent to the rotating plate  35  has one arc lamp, and the second heating zone Z 2  existing between the first heating zone Z 1  and the third heating zone Z 3  has two arc lamps  33 A.  
           [0013]    The batch type atomic layer deposition apparatus shown in FIG. 2 has some advantages in terms of an atomic layer deposition rate and uniformity. In case of reducing the cycle period, a process throughput of a TiN layer deposition increases by about 12 WPH.  
           [0014]    A process for cleaning an inside surface of the reaction chamber is carried out after the TiN deposition is performed by using the atomic layer deposition apparatus. In more detail, the cleaning of the inside surface of the reaction chamber, namely in-situ cleaning, is proceeded from a center hole of the shower head  32  by using a gas supplier which rapidly inject Cl 2  gas supplied through a TiCl 4  gas line  32 A. This in-situ cleaning of the batch type atomic layer deposition apparatus impedes an underside of the loaded wafer from being deposited with the TiN layer and prevent a particle generation within the groove  35 A, commonly named as susceptor, for tightening the loaded wafer. Therefore, the in-situ cleaning process is a requisite, of the atomic layer deposition apparatus for a mass production.  
           [0015]    [0015]FIG. 3A shows an in-situ cleaning method in accordance with the prior art.  
           [0016]    Referring to FIG. 3A, Cl 2 /Ar gas continuously flows into a central area of the reaction chamber through the hole type shower head  32  from a first and a second gas line  32 A and  32 B. At this time, a flow quantity of each Cl 2  and Ar gas is about 800 sccm. Furthermore, the Cl 2  gas is more densely distributed around a center area of a body of the Cl 2  gas and cleans the TiN layer deposited on the rotating plate  35  and the susceptor  35 A by thermally dissolving it while the Cl 2  gas spreads out in an radial form. Another gas line is prepared for forcing Ar gas to flow along an underside surface of the rotating plate  45 . The flowing Ar gas prevents the deposition from being taken place at the underside surface.  
           [0017]    As shown in FIG. 3B, a peripheral area of the rotating plate  35  and the susceptor  35 A is easily cleaned while the in-situ cleaning is carried out, however a TiN layer deposited on the center area of the rotating plate is not easily cleaned because the deposited TiN layer has a topologically different thickness. Also, a ring pattern formed on the deposited TiN layer due to the topologically different thickness still remains during the in-situ cleaning process.  
           [0018]    According to an X-ray examination of the remnant layer having the ring pattern, there is no peak of any other crystal structure as well as Tin crystal structure. From this, it is known that the deposited TiN layer may have an amorphous structure.  
           [0019]    Actually, a reaction between the TiN layer and Cl 2  gas should be elicited and the TiN layer should be dissolved into by-products of the reaction, that is, TiCl 4  and N 2 . Thereafter, the by-products should be detached and pumped out. However, as a matter of a fact, a bamboo or tall grass type by-product is formed and remains on the central area of the rotating plate  35 .  
           [0020]    The ring pattern is not removed even though the rotating plate  35  is heated to about 450□ and ALD process parameters such as an amount of TiCl 4 /Ar/NH 3  gas, a cycle period, and a distance between the rotating plate  35  and the upper plate  31 A are adjusted. Actually, these treatments remove a partial portion of the ring pattern, not the whole pattern.  
           [0021]    There are several factors causing this technical problem. First of all, the Cl 2  gas is supplied only to the central area of the rotating plate, and the excessive Cl 2  gas supply to the central area prevents the generated by-products from being detached. As a result, the by-products are re-deposited. Compared with a shower head type apparatus supplying gas uniformly on an entire surface of a wafer, the batch type atomic layer deposition apparatus supplies all gases from the central area of the upper plate.  
           [0022]    Therefore, a level of impurities, usually metal elements formed on the central area of the loaded wafer, is higher than on other areas. Consequently, the generated by-products are not easily removed even though there occurs the reaction between the Cl 2  gas and the by-products.  
         SUMMARY OF THE INVENTION  
         [0023]    It is, therefore, an object of the present invention to provide a batch type atomic layer deposition (ALD) apparatus capable of improving a cleaning efficiency by supplying a cleaning gas to a central area of an upper plate in an radial form and an in-situ cleaning method thereof.  
           [0024]    In accordance with an aspect of the present invention, there is provided the batch type atomic layer deposition apparatus, including: a reaction chamber having a predetermined volume constituted with an upper plate, a lower plate and sidewalls; a rotating plate loaded with a plurality of wafers, wherein each wafer is located in the reaction chamber and loaded radially at a predetermined position disposed in an identical distance from a center of the rotating plate; a radial shower head for forcing a gas to flow toward an upper surface of the wafer as passing through a center of the upper plate, wherein the radial shower head faces a center of an upper surface of the rotating plate; a heating plate having a heating zone capable of controlling a temperature of any area and being located on the lower plate with a predetermined distance of the rotating plate; a cooling plate attached to an upper surface of the upper plate; and a plasma excitement electrode encompassing an entrance of the radial shower head by being located between the cooling plate and the entrance of the radial shower head. 
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0025]    The above and other objects and features of the instant invention will become apparent from the following description of preferred embodiments taken in conjunction with the accompanying drawings, in which:  
         [0026]    [0026]FIG. 1 is a schematic diagram showing an atomic layer deposition adopting a traveling wave method according to a prior art;  
         [0027]    [0027]FIG. 2 is a schematic diagram showing a batch type atomic layer deposition apparatus according to a prior art;  
         [0028]    [0028]FIG. 3A is a diagram illustrating an in-situ cleaning method using the batch type atomic layer deposition apparatus shown in FIG. 2;  
         [0029]    [0029]FIG. 3B is a diagram showing a result of the in-situ cleaning according to the in-situ cleaning method shown in FIG. 3A;  
         [0030]    [0030]FIG. 4 is a diagram showing a structure of a batch type atomic layer deposition apparatus in accordance with an first preferred embodiment of the present invention;  
         [0031]    [0031]FIG. 5 is a diagram showing a structure of a batch type atomic layer deposition apparatus in accordance with a second preferred embodiment of the present invention;  
         [0032]    [0032]FIG. 6 is a diagram illustrating an in-situ cleaning method of the batch type atomic layer deposition apparatus shown in FIG. 4; and  
         [0033]    [0033]FIG. 7 is a diagram illustrating an in-situ cleaning method of the batch type atomic layer deposition apparatus shown in FIG. 5. 
     
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS  
       [0034]    Hereinafter, a batch type atomic layer deposition (ALD) apparatus in accordance with the present invention will be described in detail referring to the accompanying drawings.  
         [0035]    [0035]FIG. 4 is a diagram showing a structure of a batch type atomic layer deposition (ALD) apparatus according an embodiment of the present invention.  
         [0036]    Referring to FIG. 4, the batch type ALD apparatus includes: a reaction chamber  40  containing sidewalls  41 C, an upper plate  41 A, and a lower plate  41 B; a radial shower head  42  penetrating a center area of the upper plate  41 A of the reaction chamber  40  and radially injecting a source gas, a reaction gas, a purge gas, wherein the gases are supplied through a first and a second gas injection line  42 A and.  42 B; a heating plate  43  attached to the lower plate  41 B; a rotating axis  44  penetrating a center of the lower plate  41 B and the heating plate  43  simultaneously; a rotating plate  45  on which a plurality of wafers  46  are loaded in an radial form with an identical distance from a center of the rotating plate  45 , wherein a center of bottom surface of the rotating plate  45  is fixed at the rotating axis  44 ; a baffle structured exhaust  47  for exhausting the gases injected from the radial shower head  42 , wherein the, exhaust penetrates the heating plate  43  and the lower plate  41   b  along the sidewall most closely adjacent to an edge area of the rotating plate  45 ; a cooling plate  48  attached to the upper plate  41 A; and a plasma excitement electrode  49  having a ring shape and encompassing an entrance of the radial shower head by being located between the cooling plate  48  and the entrance of the radial shower head  42 . Herein, the plasma excitement electrode  49  is supplied with a radio frequency (RF) power. Also, the plasma excitement electrode  49  excites Cl 2 /Ar cleaning gas to plasma and forms a Cl 2  radical. Consequently, a reaction between the Cl 2  radical containing activated molecules and a deposited TiN layer is expedited.  
         [0037]    [0037]FIG. 5 is a diagram showing a batch type ALD apparatus according to a second embodiment of the present invention.  
         [0038]    Referring to FIG. 5, the batch type ALD apparatus includes: a reaction chamber  40  containing sidewalls  41 C, an upper plate  41 A, and a lower plate  41 B; a radial shower head  42  penetrating a central area of the upper plate  41 A of the reaction chamber  40  and radially injecting a source gas, a reaction gas, a purge gas, wherein the gases are supplied through a first and a second gas injection line  42 A and  42 B; a rotating axis  44  on which a plurality of wafers  46  are loaded in a radial form with an identical distance from a center of the rotating plate  45 , wherein a center of bottom surface of the rotating plate  45  is fixed at the rotating axis  44 ; a baffle structured exhaust  47  for exhausting the gases injected from the radial shower head  42 , the exhaust  47  penetrates the heating plate  43  and the lower plate  41 B along the sidewall  41 C most closely adjacent to an edge area of the rotating plate  45 ; a cooling plate  48  attached to the upper plate  41 A; a plasma excitement electrode  49  having a ring shape and encompassing an entrance of the radial shower head  42  by being located between the cooling plate  48  and the entrance of the radial shower head  42 ; an ion extraction electrode  53  encompassing an discharging vent of the radial shower head  42  by being located between the upper plate  41 A and the discharging vent of the radial shower head  42 . Herein, the plasma excitement electrode is supplied with a radio frequency (RF) power; and an ion extraction electrode  53  encompassing discharging vent of the radial shower head  42  by being located between the upper plate  41 A and the discharging vent of the radial shower head  42 . Herein, the ion extraction electrode  53  is used for extracting Cl −  ions from Cl 2  molecules injected through a gas injection line  42 B.  
         [0039]    In conclusion, the plasma excitement electrode  49  and the ion extraction electrode  53  are aids for cleaning a remnant TiN layer, owing to a fact that both of the plasma excitement electrode  49  and the ion extraction electrode  53  ionize the Cl 2  molecules and the formed Cl −  ions are used for the cleaning process.  
         [0040]    The radial shower head  42  or corn typed shower head improves uniformity of the deposition compared to the hole typed shower head, and the cooling plate  48  prevents the upper plate  41 A from being deposited by any gas.  
         [0041]    In addition, the heating plate  42  includes three heating zones, that is, a wafer heating area for depositing the atomic layer is divided into three heating zones Z 1 , Z 2 , Z 3 . Each of the heating zones has an arrangement of a ring typed arc lamp  43 A with a constant distance.  
         [0042]    In more detail, the heating plate  43  is located right under the rotating plate  45 . Among the three heating zones, a first heating zone Z 1  most closely adjacent to the radial shower head  42  has three arc lamps  43 A. A third heating zone Z 3  most closely adjacent to an edge area of the rotating plate  45  has one arc lamp  43 A, and a second heating zone Z 2  has two arc lamps is located between the first heating zone Z 1  and the third heating zone Z 3 .  
         [0043]    Accordingly, a temperature of each heating zone is varied by controlling a power rate of the arc lamps  43 A. For example, the power rate of the arc lamp of the first heating zone (Z 1 ) is increased more than that of the arc lamp of the second heating zone Z 2  while the power rate of the arc lamp of the third heating zone Z 3  is decreased more than that of the arc lamp of the second heating zone Z 2 . Contrarily, the power rate of the arc lamp  43 A of the first heating zone Z 1  may be decreased while the power rate of the arc lamp  43 A of the third heating zone Z 3  may be increased. Furthermore, the power rate of the arc lamp  43 A is a parameter for deciding a deposition temperature of the wafer when an atomic layer is deposited on the wafer  46  and a setting temperature of the arc lamp is a target temperature at which the atomic layer is deposited on the wafer  46 .  
         [0044]    A groove  45 A, commonly named as susceptor for loading and tightening the wafer  46  on the rotating plate  45  is prepared for preventing the atomic layer from being deposited on an underside of the wafer  46  and tightening the wafer  46  to prevent it from being shaken when the rotating plate  45  is rotated.  
         [0045]    When the source gas, reaction gas, purge gas, and cleaning gas are supplied from the center of the upper plate  41 A, that is, the radial shower head  42 , a traveling wave flow of the supplied gas is formed in outward direction from the rotating plate  45 , and eventually, the gases are pumped out from the reaction chamber  40  through the exhaust  47  of the rotating plate  45 .  
         [0046]    In addition, the rotating plate  45  is rotated so as to obtain enhanced deposition uniformity and load the wafer thereon, and an inert gas, that is, Ar gas, always flows along the bottom surface of the rotating plate  45  to prevent the atomic layer from being deposited thereon. At this time, the inert gas flowing along the bottom surface of the rotating plate  45  is supplied externally through an extra gas injection line even if not illustrated.  
         [0047]    As mentioned above, uniformity of sheet resistance of a TiN layer is obtained through the followings: the gases are supplied from the center of the reaction chamber  40  through the radial shower head  42 ; a plurality of wafers are loaded on the rotating plate; and the wafer  46 , on which the atomic layer is deposited, is divided into the three heating zones Z 1 , Z 2  and Z 3  and each temperature of the three heating zones is controlled.  
         [0048]    Instead of maintaining a temperature consistently throughout the whole region of the wafer  46 , the heating plate  43  arranged with the ring type arc lamp  43 A controls the power rate of each heating zone to be varied to have a different temperature distribution.  
         [0049]    [0049]FIG. 6 is a diagram showing a method for an in-situ cleaning of the batch type ALD apparatus illustrated in FIG. 4.  
         [0050]    Referring to FIG. 6, after depositing a TiN layer  50 A on the wafer  46 , a process for cleaning a remnant TiN layer  50 B remaining on a central area of the rotating plate  45  is carried out.  
         [0051]    First, cleaning gases are injected through the first and the second gas injection line  42 A and  42 B for injecting the source gas, reaction gas, and purge gas. Herein, the cleaning gas are Ar and Cl 2  and each of the cleaning gases is injected through each gas injection line separately. In more detail, the Ar gas is injected at a flow rate of about 500 sccm to about 1000 sccm while Cl 2  gas is injected at a flow rate of about 200 sccm to about 800 sccm. It is also possible to control each gas flow rate according to a stability condition of plasma.  
         [0052]    After that, a RF power ranging from about 100 W to about 600 W and having a frequency of 13.56 MHz is applied to the plasma excitement electrode when the cleaning gases pass through the radial shower head  42  and a plasma state is created by the cleaning gases being excited at a pressure of about 1 torr to about 20 torr. Consequently, Cl 2  radicals, that is, the Cl 2  radicals mean activated Cl 2  molecules, are formed.  
         [0053]    The activated Cl 2  molecules  51  are supplied in an radial form and intensively react with the remnant TiN layer  50 B deposited on the central area of the rotating plate  45 .  
         [0054]    In other words, the reaction between the activated Cl 2  molecules  51  and the remnant TiN layer  50 B is expedited by the activated Cl 2  molecules  51 , and some by-products such as TiCl 4  and N 2  are generated by the reaction. Eventually, the by-products are pumped out without any difficulty because the by-products are easily detached from the center area of the rotating plate  45 .  
         [0055]    As mentioned above, the by-products are easily detached because the activated Cl 2  molecules  51  are injected in the radial form through the radial shower head  42  and the injected activated Cl 2  molecules are supplied broadly to the central area of the rotating plate  45  broadly and uniformly  42  during the cleaning process as shown in FIG. 6. In short, the generated by-products are easily detached because the activated Cl 2  molecules are not supplied intensively only to the central area of the rotating plate  45 . Moreover, the above-described characteristic gas flow prevents the re-deposition phenomenon.  
         [0056]    [0056]FIG. 7 is a diagram showing a method for the in-situ cleaning of the ALD apparatus illustrated in FIG. 5.  
         [0057]    Referring to FIG. 7, the cleaning process for removing a remnant TiN layer  50 B remaining on the central area of the rotating plate  45  is carried out after depositing the TiN layer  50 A on the wafer  46 .  
         [0058]    First, the cleaning gas is injected through the first and second gas injection line  42 A and  42 B for injecting the source, reaction, and purge gas. At this time, Ar and Cl 2  are used as the cleaning gas, and injected through each gas injection line  42 A and  42 B separately. Specifically, the Ar gas and the Cl 2  gas are injected at a flow rate of about 500 sccm to about 1000 sccm and about 200 sccm to about 800 sccm respectively. It is also possible to control each flow rate according to a stability state of plasma.  
         [0059]    Next, a large quantity of Cl −  ions are generated by applying a DC voltage, that is, ion extraction voltage, of about 500 V to about −50 V to the ion extraction electrode  53 . Meanwhile, an electrical lens effect  54  occurs when the Cl −  ions, which are generated by the ion extraction electrode  53  located in the radial shower head  42 , starts flowing, and an accelerated ion trajectory  55  of the Cl −  ions is formed by the electrical lens effect  54 .  
         [0060]    In short, the Cl −  ions are accelerated toward the rotating plate  45  along the accelerated ion trajectory  55  and the accelerated Cl −  ions remove the remnant TiN layer  50 B easily. Herein, the removal of the TiN layer  50 A is caused by a sputtering effect of the Cl −  ions.  
         [0061]    Consequently, the in-situ cleaning method using the Cl 2  gas shows an improvement because both of a chemical etching and a physical, etching are carried out simultaneously. To obtain the sputtering effect mentioned above, in other words, to broaden a sputtering target area, an angle α of the exhaust  47  of the radial shower head  42  is increased and a distance d between the upper plate  41 A and the rotating plate  45  is adjusted.  
         [0062]    For example, an angle of about 120° to about 160° is most suitable for the exhaust  47  of the shower head  42 , and a target area of the in-situ cleaning is adjusted by controlling the accelerated ion trajectory  55  of the Cl −  ions extracted by applying the DC voltage to the ion extraction electrode  52 .  
         [0063]    If the angle of the exhaust  47  of the shower head  42  is more than about 160°, the accelerated ion trajectory  55  of the extracted Cl −  ions becomes broad and the sputtering target area is also broadened. However, an efficiency on the in-situ cleaning is reduced because a density of the accelerated ions is decreased. In contrary, if the angle of the exhaust  47  of the shower head  42  becomes less than about 120°, the accelerated ion trajectory  55  of the extracted Cl −  ions becomes narrow and the sputtering target area also becomes narrow. However, the efficiency on the in-situ cleaning is also reduced because the sputtering target area is too narrow.  
         [0064]    In addition, the distance D between the radial shower head  42  and the rotating plate  45  is kept up at about 3.5 mm to about 7 mm. In conclusion, the efficiency on the in-situ cleaning is considerably improved by adjusting the angle of the exhaust  47  of the radial shower head  42  and the distance D between the radial shower head  42  and the rotating plate  45  on condition that these adjustments do not affect properties of the TiN layer  50 A such as sheet resistance Rs and thickness uniformity.  
         [0065]    The above preferred embodiments describe the in-situ cleaning performed after finishing the TiN layer deposition. The present invention can be also applied to a case of depositing other material such as SiN, NbN, TiN, TaN, Ya 3 N5, AlN, GaN, WN, BN, WBN, WSiN, TiSiN, TaSiN, AlSiN, AlTiN, Al 2 O 3 , TiO 2 , HfO 2 , Ta 2 O 5 , Nb 2 O 5 , CeO 2 , Y 2   0   3 , SiO 2 , In 2 O 3 , RuO 2 , IrO 2 , SrTiO 3 , PbTiO 3 , SrRuO 3 , CaRuO 3 , Al, Cu, Ti, Ta, Mo, Pt, Ru, Ir, W, or Ag, wherein such nitrides, metal oxide and metal mentioned above are applied to form a gate oxide layer, a gate electrode, an upper/lower electrode for a capacitor, a dielectric layer, a diffusion barrier layer, a metal wire and so on.  
         [0066]    In addition, the batch type ALD deposition apparatus according to the present invention has a large volume of reaction chamber in which four 200 mm wafers can be loaded at once. In case of loading 300 mm wafer, it is possible to load three 300 mm wafers without changing any process parameter.  
         [0067]    Although the preferred embodiment of the invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that various modifications, additions and substitutions are possible, without departing from the scope and spirit of the invention as disclosed in the accompanying claims.