Abstract:
Herbicidal fluorovinyloxyacetamide compounds of formula (I) are useful for protecting crops from weeds:                            
     wherein: 
     R 1  is a phenyl group optionally having one or more substituents selected from the group consisting of C 1-6  alkyl, halogen-substituted C 1-6  alkyl, C 1-6  alkoxy and halogen; 
     R 2  is a C 1-6  alkyl; or 
     R 1  and R 2  together with the nitrogen atom to which they are bound form a 5-, 6- or 7-membered nitrogen heterocycle optionally having one or more ring oxygen atoms, double bonds and C 1-6  alkyl substituents; 
     R 3  is a phenyl or thiophen-2-yl group optionally having one or more substituents selected from the group consisting of C 1-6  alkyl, halogen-substituted C 1-6  alkyl, C 1-6  alkoxy, methylenedioxy and halogen; and 
     R 4 is a perfluoro C 1-6  alkyl group.

Description:
CROSS REFERENCE TO RELATED APPLICATION 
     This application is a continuation of international application number PCT/KR99/00116, filed on Mar. 15, 1999, which is pending. 
    
    
     FIELD OF THE INVENTION 
     The present invention relates to novel fluorovinyloxyacetamides, a process for preparing same and a highly selective and effective herbicidal composition comprising same. 
     DESCRIPTION OF THE PRIOR ART 
     Due to the perpetual emergence of weeds resistant to the herbicide in use, there always exists a need to develop a new class of effective herbicides that can protect crops without harming the environment. For example, the sulfonylurea-based herbicides that have been widely used in controlling rice-field weeds for the last two decades have now become less effective, particularly in controlling annual weeds. Accordingly, many attempts have been made to develop new rice-field herbicides of different chemical classes, including those based on amides and carbamates. 
     There has recently been reported a new class of herbicides based on heteroaryloxyacetamide derivatives (DE Patent No. 2903966; DE Patent No. 3038636; DE Patent No. 3323334; DE Patent No. 3344236; DE Patent No. 3418167; DE Patent No. 3422861; DE Patent No. 440596; WO 95/34560; WO 96/08488; WO 96/11575; WO 96/28434; and WO 97/08160). However, these heteroaryloxyacetamides have limited herbicidal activity against a narrow spectrum of weeds. 
     SUMMARY OF THE INVENTION 
     Accordingly, it is a primary object of the present invention to provide a novel compound having superior herbicidal activity against a wide spectrum of weeds. 
     It is another object of the present invention to provide a process for the preparation of said compound. 
     It is a further object of the present invention-to provide a herbicidal composition comprising said compound. 
     In accordance with one aspect of the present invention, there is provided a novel fluorovinyloxyacetamide compound of formula (I):                           
     wherein: 
     R 1  is a phenyl group optionally having one or more substituents selected from the group consisting of C 1-6  alkyl, halogen-substituted C 1-6  alkyl, C 1-6  alkoxy and halogen; 
     R 2  is a C 1-6  alkyl group; or 
     R 1  and R 2  together with the nitrogen atom to which they are bound form a 5-, 6- or 7-membered nitrogen heterocycle optionally having one or more ring oxygen atoms, double bonds and C 1-6  alkyl substituents; 
     R 3  is a phenyl or thiophen-2-yl group optionally having one or more substituents selected from the group consisting of C 1-6  alkyl, halogen-substituted C 1-6  alkyl, C 1-6  alkoxy, methylenedioxy and halogen; and 
     R 4  is a perfluoro C 1-6  alkyl group. 
     DETAILED DESCRIPTION OF THE INVENTION 
     The compound of formula (I) of the present invention may be in the form of the E isomer of formula (I-a), the Z isomer of formula (I-b), or a mixture thereof:                           
     wherein R 1 , R 2 , R 3  and R 4  have the same meanings as defined in formula (I) above. The two stereoisomers, E and X isomers, are defined according to the terminology of the Cahn-Ingold-Prelog system(J. March,  Advanced organic Chemistry , 3rd Ed., Wiley-Interscience) which is incorporated herein by way of reference. 
     Among the compounds of the present invention, preferred are: those wherein R 1  is a phenyl group optionally having a halogen, methyl or methoxy substituent, R 2  is a methyl or ipropyl group, R 3  is a phenyl group optionally substituted with a halogen or methoxy group and R 4  is CF 3  or CF 2 CF 3 ; and those wherein R 1  and R 2  together with the nitrogen atom to which they are bound form a piperidino, hexamethyleneimino, morphorino or 1,2,3,6-tetrahydropyridino ring optionally having one or two C 1-2  alkyl substituents, R 3  is a phenyl group optionally substituted with a halogen or methoxy group and R 4  is CF 3 . 
     The compound of the present invention may be prepared by reacting an alcoholic compound of formula (II) with a fluorovinyl compound of formula (III) in the presence of a base, as shown in Reaction Scheme A:                           
     wherein R 1 , R 2 , R 3  and R 4  have the same meanings as defined in formula (I) above. 
     An alcoholic compound of formula (II) may be prepared by substitution, acetylation and hydrolysis of an amine of formula (VI) according to a conventional method(Hamm, P. C.,  J. Amer. Chem. Soc ., 78, 2556 (1956); Hartman, W. W. et al.,  Org. Syn., Coll ., 3, 650 (1955); and Brasen, W. R. et al.,  Org. Syn. Coll ., 4, 582 (1963)), as shown in Reaction Scheme B:                           
     wherein R 1  and R 2  have the same meanings as defined in formula (I) above. 
     A difluorovinyl compound of formula (III) may be prepared form a halogen compound of formula (VIII) by Grignard and Wittig reactions(Herkes, F. E. et al.,  J. Org. Chem ., 32, 1311 (1967); and Wheaton, G. A. et al.,  J. Org. Chem ., 48, 917 (1983)), as shown in Reaction Scheme C:                           
     wherein X is Br or Cl; and R 3  and R 4  have the same meanings as defined in formula (I) above. 
     As shown in Reaction Scheme A, the fluorovinyloxyacetamide compound of the present invention may be prepared by reacting an alcoholic compound of formula (II) with a fluorovinyl compound of formula (III) in the presence of a base. Each of compounds of formula (II) and (III) may be used in equimolar amounts and the base may be used in one to two equivalent amounts. The base may be an inorganic base, e.g., sodium hydride, potassium hydride, potassium t-butoxide, sodium hydroxide, potassium hydroxide, sodium carbonate or potassium carbonate; or an organic base, e.g., triethylamine or pyridine. The solvent which may be used in the reaction is benzene, toluene, tetrahydrofuran, acetone, acetonitrile, dichloromethane, dimethylformamideor dimethylsulfoxide, individually or combined with water. The reaction may be conducted at a temperature ranging from room temperature to 100° C. The progress of the reaction is conveniently followed by measuring the disappearance of the compound of formula (II) with thin layer chromatography(TLC). 
     The compound of the present invention is obtained as a mixture of two isomers, i.e., the E and Z isomers. 
     For example, in the case of the compound of the present invention wherein R 1  is phenyl, R 2  is methyl, R 3  is phenyl and R 4  is CF 3 (Compound 1), a 2:1 mixture of the Z and F isomers is obtained, the isomer ratio being determined on the basis of both  1 H-NMR and  19 F-NMR analysis of the product. Namely, the peak area ratio of the  1 H-NMR peak for the methylene group of the Z isomer(a singlet at 4.30 ppm relative to CHCl 3 ) to that of E isomer(a singlet at 4.49 ppm) is about 2:1; and  19 F-NMR analysis(reference compound: CFCl 3 ) shows a peak area ratio of about 2:1 when the peaks for the fluorine and CF 3  substituents of the Z isomer(a quartet having a coupling constant of 24.08 Hz at −84.99 ppm and a doublet having a coupling constant of 25.07 Hz at −57.36 ppm, respectively) are compared with those of the E isomer(a quartet having a coupling constant of 12.43 Hz at −83.40 ppm and a doublet having a coupling constant of 12.66 Hz at −57.95 ppm, respectively). 
     Likewise, the preparation of the compound of the present invention wherein R 1  and R 2  together with the nitrogen atom to which they are attached form a piperidino group, R 3  is phenyl and R 4  is CF 3 (Compound 221) leads to a 2:1 mixture of the Z and E isomers. Namely, the peak area ratio of the 1H-NMR peak for the methylene group of the Z isomer(a singlet at 4.67 ppm) to that of the E isomer(a singlet 4.79 ppm) is about 2:1; and the  19 F-NMR analysis(reference compound: CFCl 3 ) shows a peak area ratio of 2:1 when the peaks for the fluorine and CF 3  substituent of the Z isomer(a quartet having a coupling constant of 25.15 Hz at −84.28 ppm and a doublet having a coupling constant of 24.85 Hz at −57.38 ppm, respectively) are compared with those of the E isomer(a quartet having a coupling constant of 12.46 Hz at −82.24 ppm and a doublet having a coupling constant of 12.32 Hz at −57.83 ppm, respectively). 
     The compound of the present invention has herbicidal activity against a broad spectrum of weeds, in particular, against those belonging to the Gramineae family, e.g., rice( Oryza sativa  L.), barnyardgrass( Echinochlora crus - galli  8P. BEAUV. var. oryzicola OHWI), bulrush( Scirpus juncoides  ROXB), umbrellaplant( Cyperus difformis  L.), flatsedge( Cyperus serotinus  ROTTB), dayflower( Aneilema keisak  HASSK), monochoria( Monochoria vaginalis  PRESL), toothcup( Rotala indica  KOEHE) and arrow head( Sagittaria pygmaea  MIQ). 
     Accordingly, the present invention also includes within its scope a herbicidal composition comprising one or more of the compounds of formula (I) as an active ingredient, in association with herbicidally acceptable carriers. 
     The herbicidal composition of the invention may be formulated in various forms such as an emulsion, aqueous dispersion, powder and granules which may contain herbicidally acceptable carriers and additives. The compound of the formula (I) may be used in an amount of 10 to 90% on the basis of the weight of an emulsion or aqueous dispersion, 0.1 to 10% on the basis of the weight of powder, 1 to 30 % on the basis of the weight of granules. 
     Herbicidally acceptable carrier that may be used in the composition of the present invention is a liquid carrier, e.g., water, an alcohol(ethanol, ethylene glycol, glycerine), ketone(acetone, methylethylketone), ether(dioxane, tetrahydrofuran, cellosolve), aliphatic hydrocarbon(gasoline, Kerosene), halogenated hydrocarbon(chloroform, carbon tetrachloride), amide(dimethylformamide), ester(ethyl acetate, butyl acetate, fatty glycerine ester) and acetonitrile; and a solid carrier, e.g., mineral particle(Kaoline, clay, bentonite, dolomite, talc, silica, sand) and vegetable powder(shrubs). 
     The additive that may be used in the herbicidal composition of the present invention includes an emulsifier, adhesive, dispersion agent or permeating agent, e.g., nonionic, anionic or cationic interface active agent(fatty acid sodium salt, polyoxy alkyl ester, alkyl sulfonate ester). Further, an agrochemically active ingredient, e.g., an insecticide, fungicide, plant growth regulator, germicide, and fertilizer, may be added in the composition of the present invention. 
    
    
     The following Preparations and Examples are given for the purpose of illustration only and are not intended to limit the scope of the invention. 
     PREPARATION 1 
     Preparation of L-Methyl-2-hydroxyacetanilide(II) 
     Step 1: Preparation of N-Methyl-2-chloroacetanilide(V) 
     10.7 g(0.1 mol) of N-methylaniline(VI) was dissolved in 150 ml of dichloromethane containing 10.12 g(0.1 mol) of triethylamine, and 13.55 g(0.12 mol) of chloroacetylchloride was added dropwise thereto while cooling. The resulting solution was stirred at room temperature for 1 hour, and washed three times with water. The organic layer was dried and recrystallized in n-hexane to obtain 17.6 g(yield 96%) of the title compound as a yellowish brown solid. 
       1 H-NMR (CDCl 3 , TMS) δ: 7.68-7.12(m, 5H), 3.92(s, 2H), 3.45(s, 3H); MS (m/e): 183(M + , 37), 134(51), 106(100), 90(52), 51(59). m.p.: 61-62° C. 
     Step 2 : Preparation of N-Methyl-2-acetoxyacetanilide(IV) 
     18.3 g(0.1 mol) of the compound obtained in Step 1 was added to 50 ml of dry dimethylformamide(DMF), and 9.8 g(0.12 mol) of sodium acetate was added thereto. The resulting solution was heated for 1 hour, cooled and 50 ml of water was added thereto. The resulting solution was extracted three times with ethyl acetate and the organic layer was dried. After removing the solvent, the residue was subjected to column chromatography using a mixture of n-hexane and ethyl acetate(9:1) as an eluent to obtain 19 g(yield 92%) of the title compound as a liquid. 
       1 H-NMR (CDCl 3 , TMS) δ: 7.78-7.21(m, 5H), 4.48(s, 2H), 3.36(s, 3H), 2.21(s, 3H); MS (m/e): 207(M + , 8), 107(61), 77(30), 43(100). 
     Step 3: Preparation of N-Methyl-2-hydroxyacetanilide(II) 
     20.7 g(0.1 mol) of the compound obtained in Step 2 was added to 100 ml of methanol, and 4.8 g(0.12 mol) of sodium hydroxide was added slowly thereto. The resulting solution was refluxed with heating for 1 hour. The solvent was removed under a reduced pressure and 50 ml of water was added thereto. The resulting solution was extracted three times with ethyl acetate. The organic layer was dried, the solvent was removed and the residue was recrystallized in n-hexane to obtain 14 g(yield 85%) of the title compound as a white solid. 
       1 H-NMR (CDCl 3 , TMS) δ: 7.54-7.15(m, 5H), 3.82(d, 2H), 3.38(t, 1H), 3.32(s, 3H); MS (m/e): 165(M + , 34), 134(41), 106(100), 77(81); m.p.: 41-42° C. 
     PREPARATIONS 2 to 31 
     The procedure of Preparation 1 was repeated to obtain compounds of formula (II) having various R 1  and R 2  groups, as in Table 1. The  1 H-NMR and MS analysis data and melting points of these compounds are also shown in Table 1. L in Table 1 represents liquid. 
     
       
         
               
               
             
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                 TABLE 1 
               
             
             
               
                   
               
               
                   
                 (II) 
               
               
                 
                   
                             
                     
                         
                         
                     
                   
                 
               
               
                   
               
             
          
           
               
                 Prep. 
                   
                   
                   
                   
                   
               
               
                 No. 
                 R 1   
                 R 2   
                 state(° C.) 
                 NMR (CDCl 3 , TMS) δ (ppm) 
                 MS (m/e) 
               
               
                   
               
             
          
           
               
                 1 
                 C 6 H 5   
                 CH 3   
                 41˜42 
                 7.54˜7.15(m, 5H), 3.82(d, 2H), 3.38(t, 1H), 3.32(s, 3H) 
                 165(34), 134(41), 106(100), 77(81) 
               
               
                 2 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 78˜79 
                 7.38˜6.88(m, 4H), 3.85(s, 3H), 3.81(d, 2H), 3.40(t, 1H), 
                 195(42), 136(100), 122(58) 
               
               
                   
                   
                   
                   
                 3.35(s, 3H) 
               
               
                 3 
                 4-F—C 6 H 4   
                 CH 3   
                 105˜106 
                 7.36˜7.04(m, 4H), 3.80(d, 2H), 3.40(t, 1H), 3.31(s, 3H) 
                 183(31), 152(45), 125(100), 95(28) 
               
               
                 4 
                 4-Cl-C 6 H 4   
                 CH 3   
                 80˜81 
                 7.54˜7.05(m, 4H), 3.84(d, 2H), 3.37(t, 1H), 3.34(s, 3H) 
                 199(41), 168(39), 140(100), 45(54) 
               
               
                 5 
                 2, 4-F 2 —C 6 H 3   
                 CH 3   
                 117˜118 
                 7.12˜6.78(m, 3H), 4.35(b, 1H), 3.82(s, 2H), 3.29(s, 3H) 
                 201(46), 170(42), 142(100), 59(82) 
               
               
                 6 
                 2, 4-Cl 2 —C 6 H 3   
                 CH 3   
                 58˜59 
                 7.67˜7.08(m, 3H), 3.81(d, 2H), 3.39(t, 1H), 3.38(s, 3H) 
                 233(23), 198(100), 174(79) 
               
               
                 7 
                 C 6 H 5   
                 C 2 H 5   
                 38˜39 
                 7.56˜7.02(m, 5H), 3.88(q, 2H), 3.83(d, 2H), 3.42(t, 1H), 
                 179(21), 120(100), 106(73), 77(87) 
               
               
                   
                   
                   
                   
                 1.20(t, 3H) 
               
               
                 8 
                 4-CH 3 -C 6 H 4   
                 C 2 H 5   
                 63˜64 
                 7.28˜6.96(m, 4H), 3.78(q, 2H), 3.72(d, 2H), 3.42(t, 1H), 
                 193(47), 162(37), 134(100), 
               
               
                   
                   
                   
                   
                 2.36(s, 3H), 1.12(t, 3H) 
                 120(68), 91(50) 
               
               
                 9 
                 4-CH 3 O-C 6 H 4   
                 C 2 H 5   
                 53˜54 
                 7.38˜6.78(m, 4H), 3.86(s, 3H), 3.84(q, 2H), 3.83(d, 2H), 
                 209(77), 150(100), 136(78) 
               
               
                   
                   
                   
                   
                 3.50(t, 1H), 1.18(t, 3H) 
               
               
                 10 
                 3-CF 3 -C 6 H 4   
                 C 2 H 5   
                 L 
                 7.95˜7.20(m, 4H), 3.95(q, 2H), 3.80(d, 2H), 3.51(t, 1H), 
                 247(31), 188(100), 174(92), 
               
               
                   
                   
                   
                   
                 1.18(t, 3H) 
                 145(47) 
               
               
                 11 
                 2-Cl-C 6 H 4   
                 C 2 H 5   
                 47˜48 
                 7.75˜7.05(m, 4H), 4.13(m, 1H), 3.82(m, 1H), 3.76(d, 2H), 
                 213(26), 178(100), 154(42), 
               
               
                   
                   
                   
                   
                 3.48(t, 1H), 1.20(t, 3H) 
                 140(42) 
               
               
                 12 
                 3-Cl-C 6 H 4   
                 C 2 H 5   
                 L 
                 7.51˜6.95(m, 4H), 3.86(q, 2H), 3.83(d, 2H), 3.53(t, 1H), 
                 213(38), 182(57), 154(100), 
               
               
                   
                   
                   
                   
                 1.20(t, 3H) 
                 140(79) 
               
               
                 13 
                 4-Cl—C 6 H 4   
                 C 2 H 5   
                 111˜112 
                 7.62˜7.00(m, 4H), 3.86(q, 2H), 3.84(d, 2H), 3.55(t, 1H), 
                 213(36), 154(100), 140(84) 
               
               
                   
                   
                   
                   
                 1.23(t, 3H) 
               
               
                 14 
                 C 6 H 5   
                 n-C 3 H 7   
                 58˜59 
                 7.62˜6.98(m, 5H), 3.86(t, 2H), 3.80(d, 2H), 3.45(t, 1H), 
                 193(23), 151(44), 106(100), 77(53) 
               
               
                   
                   
                   
                   
                 1.85˜1.20(m, 2H), 1.20(t, 3H) 
               
               
                 15 
                 4-CH 3 O—C 6 H 4   
                 n-C 3 H 7   
                 40˜41 
                 7.16˜6.85(m, 4H), 3.84(s, 3H), 3.71(d, 2H), 3.65(t, 2H), 
                 223(63), 150(40), 136(100), 43(47) 
               
               
                   
                   
                   
                   
                 3.46(t, 1H), 1.63-1.46(m, 2H), 0.90(t, 3H) 
               
               
                 16 
                 C 6 H 5   
                 i-C 3 H 7   
                 42˜43 
                 7.48-6.88(m, 5H), 5.05˜4.65(m, 1H), 3.64(d, 2H), 
                 193(24), 120(100), 77(52), 
               
               
                   
                   
                   
                   
                 3.52(t, 1H), 1.02(d, 6H) 
                 43(100) 
               
               
                 17 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 L 
                 7.48˜6.98(m, 4H), 5.12˜4.64(m, 1H), 3.62(d, 2H), 
                 207(47), 134(100), 45(89) 
               
               
                   
                   
                   
                   
                 3.34(t, 1H), 2.37(s, 3H), 1.28(d, 3H), 1.00(d, 3H) 
               
               
                 18 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 51˜52 
                 7.49˜6.85(m, 4H), 5.15˜4.72(m, 1H), 3.72(d, 2H), 
                 207(48), 134(94), 91(72), 45(100) 
               
               
                   
                   
                   
                   
                 3.55(t, 1H), 2.48(s, 3H), 1.08(d, 6H) 
               
               
                 19 
                 3-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 L 
                 7.41˜6.61(m, 4H), 5.08˜4.84(m, 1H), 3.84(s, 3H), 
                 223(18), 15O(100), 84(26), 45(38) 
               
               
                   
                   
                   
                   
                 3.69(d, 2H), 3.57(t, 1H), 1.08(d, 6H) 
               
               
                 20 
                 4-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 96˜97 
                 7.32˜6.78(m, 4H), 5.25˜4.76(m, 1H), 3.86(s, 3H), 
                 223(27), 181(47), 150(100), 
               
               
                   
                   
                   
                   
                 3.68(d, 2H), 3.51(t, 1H), 1.10(d, 6H) 
                 123(79), 107(65), 45(54) 
               
               
                 21 
                 3-CF 3 —C 6 H 4   
                 i-C 3 H 7   
                 48˜49 
                 7.87˜7.21(m, 4H), 5.18˜4.86(m, 1H), 3.76(d, 2H), 
                 261(26), 188(63), 43(100) 
               
               
                   
                   
                   
                   
                 3.51(t, 1H), 1.08(d, 6H) 
               
               
                 22 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 52˜53 
                 7.21˜7.03(m, 4H), 5.08˜4.86(m, 1H), 3.61(d, 2H), 
                 211(20), 138(100), 95(33), 43(86) 
               
               
                   
                   
                   
                   
                 3.45(t, 1H), 1.07(d, 6H) 
               
               
                 23 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 67˜68 
                 7.78˜7.23(m, 4H), 5.16˜4.85(m, 1H), 3.78(d, 2H), 
                 227(8), 192(69), 154(83), 45(100) 
               
               
                   
                   
                   
                   
                 3.50(t, 1H), 1.35(d, 3H), 1.20(d, 3H) 
               
               
                 24 
                 3-Cl—C 6 H 4   
                 i-C 3 H 7   
                 62˜63 
                 7.58˜6.95(m, 4H), 5.15˜4.85(m, 1H), 3.80(d, 2H), 
                 227(27), 154(100), 43(76) 
               
               
                   
                   
                   
                   
                 3.54(t, 1H), 1.08(d, 6H) 
               
               
                 25 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 51˜52 
                 7.51˜7.15(m, 3H), 5.14˜4.87(m, 1H), 3.78(d, 2H), 
                 245(19), 210(24), 172(28), 43(100) 
               
               
                   
                   
                   
                   
                 3.48(t, 1H), 1.32(d, 3H), 1.15(d, 3H) 
               
               
                 26 
                 3,4-Cl 2 —C 6 H 3   
                 i-C 3 H 7   
                 67˜68 
                 7.72˜6.97(m, 3H), 5.12˜4.84(m, 1H), 3.75(d, 2H), 
                 261(36), 188(28), 45(100) 
               
               
                   
                   
                   
                   
                 3.46(t, 1H), 1.16(d, 6H) 
               
               
                 27 
                 3-CH 3 —C 6 H 4   
                 CH 3   
                 L 
                 7.42˜6.84(m, 4H), 3.82(d, 2H), 3.41(t, 1H), 3.32(s, 3H), 
                 179(61), 120(100), 59(67) 
               
               
                   
                   
                   
                   
                 2.37(s, 3H) 
               
               
                 28 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 58 
                 7.38˜6.87(m, 4H), 3.81(d, 2H), 3.38(t, 1H), 3.31(s, 3H), 
                 179(47), 120(100), 59(86) 
               
               
                   
                   
                   
                   
                 2.35(s, 3H) 
               
               
                 29 
                 3,4- 
                 CH 3   
                 80 
                 7.37˜6.84(m, 3H), 3.82(d, 2H), 3.36(t, 1H), 3.33(s, 3H), 
                 193(57), 134(100) 
               
               
                   
                 (CH 3‘)   2‘—C   6 H 3   
                   
                   
                 2.25(s, 6H) 
               
               
                 30 
                 3-Cl—C 6 H 4   
                 CH 3   
                 66 
                 7.67˜7.01(m, 4H), 3.84(d, 2H), 3.53(t, 1H), 3.36(s, 3H) 
                 199(58), 140(100), 75(82) 
               
               
                 31 
                 3,4- 
                 i-C 3 H 7   
                 L 
                 7.43˜6.85(m, 3H), 5.32˜4.84(m, 1H), 3.70(d, 2H), 3.31(t, 1H), 
                 221(61), 162(100), 59(48) 
               
               
                   
                 (CH 3 ) 2 —C 6 H 3   
                   
                   
                 2.34(s, 6H), 1.18(d, 6H) 
               
               
                   
               
             
          
         
       
     
     PREPARATION 32 
     Preparation of N-2-Hydroxyacetylpiperidine(II) 
     Step 1: Preparation of N-2-Chloroacetylpiperidine(V) 
     The procedure of Step 1 of Preparation 1 was repeated except that 8.5 g of piperidine was used in place of N-methylaniline and that column chromatography using a mixture of n-hexane and ethyl acetate(4:1) as an eluent was conducted in place of recrystallization to obtain 14.8 g(yield 92%) of the title compound as a yellowish brown liquid. 
       1 H-NMR (CDCl 3 , TMS) δ: 4.08(s, 2H), 3.76-3.18(m, 4H), 1.98-1.21(m, 6H); MS (m/e): 161(M + , 26), 126(100), 69(37), 41(68). 
     Step 2: Preparation of N-2-Acetoxyacetylpiperidine(IV) 
     The procedure of Step 2 of Preparation 1 was repeated except that 16.1 g(0.1 mol) of the compound obtained in Step 1 was used and that column chromatography was conducted using a 4:1 mixture of n-hexane and ethyl acetate as an eluent to obtain 16.5 g(yield 89%) of the title compound as a liquid. 
       1 H-NMR (CDCl 3 , TMS) δ: 4.67(s, 2H), 3.68-3.10(m, 4H), 2.12(s, 3H), 1.68-1.38(m, 6H); MS (m/e): 185(M + , 21), 112(51), 69(73), 43(100). 
     Step 3: Preparation of N-2-Hydroxyacetylpiperidine(II) 
     The procedure of Step 3 of Preparation 1 was repeated except that 18.5 g of the compound obtained in Step 2 was used and that column chromatography using a 2:1 mixture of n-hexane and ethyl acetate as an eluent was conducted in place of recrystallization to obtain 11.7 g(yield 82%) of the title compound. 
       1 H-NMR (CDCl 3 , TMS) δ: 4.08(d, 2H), 3.97(t, 1H), 3.67-3.02(m, 4H), 1.75-1.15(m, 6H), MS (m/e): 143(M + , 35), 112(86), 69(77), 43(100). 
     PREPARATIONS 33 to 48 
     The procedure of Preparation 32 was repeated to obtain compounds of formula (II) having various R 1  and R 2  groups, as in Table 2. The  1 H-NMR and MS analysis data and melting points of these compounds are also shown in Table 2. L in Table 2 represents liquid. 
     
       
         
               
               
             
               
               
               
               
               
               
             
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                 TABLE 2 
               
             
             
               
                   
               
               
                   
                 (II) 
               
               
                 
                   
                             
                     
                         
                         
                     
                   
                 
               
               
                   
               
             
          
           
               
                 Prep. 
                   
                   
                 state 
                   
                   
               
               
                 No. 
                 R 1   
                 R 2   
                 (° C.) 
                 NMR (CDCl 3 , TMS) δ (ppm) 
                 MS (m/e) 
               
               
                   
               
             
          
           
               
                 32 
                 —(CH 2 ) 5 — 
                 L 
                 4.08(d, 2H), 3.97(t, 1H), 3.67˜3.02(m, 4H), 1.75˜1.15(m, 6H) 
                 143(35), 112(86), 69(77), 43(100) 
               
               
                 33 
                 —CH(CH 3 )(CH 2 ) 4 — 
                 L 
                 4.12(d, 2H), 3.85(t, 1H), 3.46˜2.67(m, 3H), 1.94˜1.46(m, 6H), 
                 157(37), 126(72), 84(100), 55(66) 
               
               
                   
                   
                   
                 1.23(d, 3H) 
               
               
                 34 
                 —CH(CH 3 CH 2 )(CH 2 ) 4 — 
                 L 
                 4.13(d, 2H), 4.08(t, 1H), 3.45˜2.64(m, 3H), 1.85˜1.38(m, 8H), 
                 171(16), 142(38), 84(100), 55(48) 
               
               
                   
                   
                   
                 0.86(t, 3H) 
               
               
                 35 
                 —CH(CH 3 )(CH 2 ) 3   
                 L 
                 4.71(b, 1H), 4.15(d, 2H), 3.98˜3.54(m, 2H), 1.97˜1.46(m, 6H), 
                 171(28), 98(97), 55(99), 41(100) 
               
               
                   
                 CH(CH 3 )— 
                   
                 1.25(d, 6H) 
               
               
                 36 
                 —(CH 2 ) 2 CH═CHCH 2 — 
                 77˜78 
                 5.86˜5.69(m, 2H), 4.16(d, 2H), 4.15(t, 1H), 3.75˜3.64(m, 2H), 
                 141(39), 82(57), 67(86), 54(83), 41 
               
               
                   
                   
                   
                 3.30(t, 2H), 2.27˜2.05(m, 2H) 
                 (100) 
               
               
                 37 
                 —(CH 2 ) 2 O(CH 2 ) 2 — 
                 52˜53 
                 4.13(d, 2H), 3.80˜3.48(m, 8H), 3.41(1, 1H) 
                 145(75), 100(67), 86(55), 42(100) 
               
               
                 38 
                 —(CH 2 ) 3 C(C 4 H 4 )C— 
                 78˜79 
                 7.28˜7.03(m, 4H), 4.18(d, 2H), 3.80(t, 1H), 3.78˜3.54(m, 2H), 
                 191(36), 132(100), 117(30), 77(49) 
               
               
                   
                   
                   
                 2.75(t, 2H), 1.98(t, 2H) 
               
               
                 39 
                 —(CH 2 ) 6 — 
                 L 
                 4.15(d, 2H), 3.84(t, 1H), 3.78˜3.12(m, 4H), 1.98˜1.28(m, 5H) 
                 157(11), 126(72), 84(100), 47(79) 
               
             
          
           
               
                 40 
                 C 2 H 5   
                 C 2 H 5   
                 L 
                 4.05(d, 2H), 3.78(t, 1H), 3.48(q, 2H), 3.23(q, 2H), 1.15(t, 6H) 
                 131(25), 100(71), 72(100), 44(86) 
               
               
                 41 
                 n-C 3 H 7   
                 n-C 3 H 7   
                 L 
                 4.06(d, 2H), 3.80(t, 1H), 3.42(q, 2H), 3.15(q, 2H), 1.85˜1.15 
                 159(23), 86(29), 72(100), 43(94) 
               
               
                   
                   
                   
                   
                 (m, 4H), 0.97(t, 6H) 
               
               
                 42 
                 i-C 3 H 7   
                 i-C 3 H 7   
                 63˜64 
                 4.08(d, 2H), 3.95(t, 1H), 3.84˜3.35(m, 2H), 1.42(d, 6H), 1.28 
                 159(45), 128(36), 86(94), 43(100) 
               
               
                   
                   
                   
                   
                 (d, 6H) 
               
               
                 43 
                 CH 2 ═CHCH 2   
                 CH 2‘═   
                 L 
                 6.12˜5.02(m, 6H), 4.12(d, 2H), 4.01˜3.94(m, 4H), 3.65(t, 1H) 
                 155(36), 124(27), 56(37), 41(100) 
               
               
                   
                   
                 CHCH 2   
               
               
                 44 
                 n-C 4 H 9   
                 n-C 4 H 9   
                 L 
                 4.14(d, 2H), 3.72(t, 1H), 3.36(t, 4H), 1.64˜1.19(m, 8H), 
                 187(21), 86(57), 57(100), 44(58) 
               
               
                   
                   
                   
                   
                 0.96(t, 6H) 
               
               
                 45 
                 i-C 4 H 9   
                 i-C 4 H 9   
                 L 
                 4.12(d, 2H), 3.74(t, 1H), 3.24(d, 4H), 2.13˜1.78(m, 2H), 
                 187(44), 144(31), 86(100), 57(69) 
               
               
                   
                   
                   
                   
                 0.87(d, 12H) 
               
               
                 46 
                 C 2 H 5   
                 i-C 3 H 7   
                 L 
                 4.14(d, 2H), 3.81(t, 1H), 3.75˜3.56(m, 1H), 3.27(q, 2H), 
                 145(11), 86(38), 72(97), 43(100) 
               
               
                   
                   
                   
                   
                 1.18(d, 6H), 1.15(t, 3H) 
               
               
                 47 
                 CH 3   
                 n-C 4 H 9   
                 L 
                 4.08(d, 2H), 3.79(t, 1H), 3.45(t, 2H), 2.85(s, 3H), 1.78˜1.08 
                 145(12), 114(21), 57(41), 44(100) 
               
               
                   
                   
                   
                   
                 (m, 4H), 0.98(t, 3H) 
               
               
                 48 
                 CH 3   
                 C 6 H 5 CH 2   
                 L 
                 7.25˜7.09(m, 5H), 5.45(t, 1H), 4.58(s, 2H), 4.38(d, 2H), 
                 179(48), 120(87), 59(100) 
               
               
                   
                   
                   
                   
                 2.98(s, 3H) 
               
               
                   
               
             
          
         
       
     
     PREPARATION 49 
     Preparation of 2,2-Difluoro-1-trifluoromethyl-4′-methoxy styrene(III) 
     Step 1: Preparation of 2,2,2-Trifluoromethyl-4′-methoxyphenylketone(VII) 
     5.1 g(0.21 g atom) of magnesium was placed in 300 ml of dry diethyl ether and 37.4 g(0.2 mol) of p-bromoanisole was added dropwise thereto under a nitrogen atmosphere to prepare a Grignard reagent. The Grignard reagent solution was cooled to −78° C. and 28.4 g(0.2 mol) of ethyl trif luoroacetate was added dropwise thereto. The resulting solution was stirred for 30 to 60 minutes, mixed with crushed ice, acidified with concentrated hydrochloric acid and then extracted three times with diethyl ether. The organic layer was dried over magnesium sulfate and the solvent was removed under a reduced pressure to obtain a residue. The residue was distilled at 72 to 73° C./20 mmHg to obtain 35.09 g (yield 86%) of the title compound as a colorless oil. 
       1 H-NMR (CDCl 3 , TMS) δ: 7.62-6.81(m, 4H), 3.86(s, 3H); MS (m/e): 204(M + , 56), 135(100), 107(86), 92(66), 77(92). 
     Step 2: Preparation of 2,2-Difluoro-1-trifluoromethyl-4′-methoxy Styrene(III) 
     26.2 g(0.1 mol) of triphenylphosphine was dissolved in 250 ml of dry THF and 25.2 g(0.12 mol) of dibromodifluoromethane was added dropwise thereto under a nitrogen atmosphere at a temperature below 10° C. The resulting solution was stirred for thirty minutes and 10.2 g(0.05 mol) of the compound obtained in Step 1 was added thereto. The resultant solution was refluxed for 12 hours, cooled and distilled under a reduced pressure. The product was redistilled at 72 to 74° C. at 10 mmHg to obtain 9.36 g(yield 78.7%) of the title compound as a colorless liquid. 
       1 H-NMR (CDCl 3 , TMS) δ: 7.48-6.79(m, 4H), 3.79(s, 3H); MS (m/e): 238(M + , 69), 195(14), 145(35), 74(33), 59(100). 
     PREPARATIONS 50 to 65 
     The procedure of Preparation 49 was repeated to obtain compounds of formulas (VII) and (III) having various R 3  and R 4  groups, as in Tables 3a and 3b, respectively. The  1 H-NMR and MS analysis data and melting points of these compounds are also shown in respective tables. 
     PREPARATION 66 
     Preparation of 2,2-Difluoro-1-pentafluoroethyl styrene(III) 
     The procedure of Preparation 49 was repeated except that bromobenzene and ethyl pentaf luoropropionate were used in place of bromoanisole and ethyl trifluoroacetate, respectively, to obtain the title compound. The  1 H-NMR and MS analysis data and melting points of the compounds of formulas (VII) and (III) are also shown in Tables 3a and 3b, respectively. 
     
       
         
               
               
             
               
               
               
               
               
               
             
           
               
                 TABLE 3a 
               
             
             
               
                   
               
               
                   
                 (VII) 
               
               
                 
                   
                             
                     
                         
                         
                     
                   
                 
               
               
                 Prep. Nos. 49-65: R 4  = CF 3   
               
               
                 Prep. No. 66: R 4  = CF 2 CF 3   
               
               
                   
               
             
          
           
               
                 Prep. 
                   
                   
                   
                   
                   
               
               
                 No. 
                 R 3   
                   1 H-NMR(CDCl 3 , TMS) δ (ppm) 
                 MS (m/e) 
                 yield (%) 
                 b.p. (mmHg) 
               
               
                   
               
               
                 49 
                 4-CH 3 O—C 6 H 4 — 
                 7.62˜6.81(m, 4H), 3.86(s, 3H) 
                 204(56), 135(100), 107(86), 92(66), 77(92) 
                 86 
                 72˜73 (20) 
               
               
                 50 
                 3-CH 3 —C 6 H 4 — 
                 7.52˜6.92(m, 4H), 2.25(s, 3H) 
                 188(16), 135(45), 119(96), 91(100), 65(45) 
                 61 
                 70˜71 (20) 
               
               
                 51 
                 4-CH 3 —C 6 H 4 — 
                 7.42˜6.92(m, 4H), 2.25(s, 3H) 
                 188(12), 119(100), 91(96), 65(45) 
                 68 
                 65˜66 (8) 
               
               
                 52 
                 4-C 2 H 3 —C 6 H 4 — 
                 7.46˜7.19(m, 4H), 2.68(q, 2H), 1.23(t, 3H) 
                 202(40), 133(91), 105(100), 76(64) 
                 62 
                 column 
               
               
                 53 
                 3,4-(CH 3 ) 2 —C 6 H 3 — 
                 7.52˜6.69(m, 3H), 2.23(s, 3H), 2.20(s, 3H) 
                 202(43), 133(98), 69(100) 
                 71 
                 column 
               
               
                 54 
                 3,5-(CH 3 ) 2 —C 6 H 3 — 
                 7.31˜7.01(m, 3H), 2.25(s, 6H) 
                 202(24), 133(100), 69(24) 
                 69 
                 column 
               
               
                 55 
                 3-CH 3 O—C 6 H 4 — 
                 7.41˜6.79(m, 4H), 3.79(s, 3H) 
                 204(36), 135(100), 107(56), 77(94) 
                 78 
                 64˜65 (33) 
               
               
                 56 
                 C 6 H 3 — 
                 7.52˜7.12(m, 5H) 
                 174(21), 105(100), 77(82), 69(54) 
                 71 
                 64˜65 (33) 
               
               
                 57 
                 4-C 2 H 3 O—C 6 H 4 — 
                 7.54˜6.76(m, 4H), 4.09(q, 2H), 1.32(t, 3H) 
                 218(16), 149(88), 121(62), 76(100) 
                 69 
                 column 
               
               
                 58 
                 3,4-OCH 2 O—C 6 H 4 — 
                 7.92˜7.43(m, 3H), 6.25˜6.01(s, 2H) 
                 218(42), 149(100), 65(49) 
                 73 
                 column 
               
               
                 59 
                 3-CF 3 —C 6 H 4 — 
                 8.60˜7.61(m, 4H) 
                 242(10), 173(68), 145(100), 76(62) 
                 67 
                 column 
               
               
                 60 
                 3-F—C 6 H 4 — 
                 7.56˜6.89(m, 4H) 
                 192(25), 123(100), 95(78), 75(31) 
                 54 
                 59˜60 (30) 
               
               
                 61 
                 4-F—C 6 H 4 — 
                 7.76˜6.92(m, 4H) 
                 192(16), 169(54), 123(100), 95(91), 75(76) 
                 59 
                 66˜67 (34) 
               
               
                 62 
                 3-Cl—C 6 H 4 — 
                 8.38˜7.45(m, 4H) 
                 208(10), 139(93), 111(100), 75(64) 
                 70 
                 58˜59 (10) 
               
               
                 63 
                 4-Cl—C 6 H 4 — 
                 7.51˜7.41(m, 4H) 
                 208(100), 173(92), 97(54), 69(24) 
                 61 
                 83˜84 (24) 
               
               
                 64 
                 3,5-Cl 2 —C 6 H 3 — 
                 8.12˜7.86(m, 3H) 
                 242(55), 173(100), 145(64), 109(32) 
                 45 
                 75˜76 (4) 
               
               
                 65 
                 C 4 H 3 S-2-yl- 
                 8.28˜7.28(m, 3H) 
                 180(23), 111(45), 84(100) 
                 76 
                 column 
               
               
                 66 
                 C 6 H 5   
                 7.48˜7.02(m, 5H) 
                 224(48), 205(100), 119(75) 
                 68 
                 62˜63(22) 
               
               
                   
               
             
          
         
       
     
     
       
         
               
               
             
               
               
               
               
               
               
             
           
               
                 TABLE 3b 
               
             
             
               
                   
               
               
                   
                 (III) 
               
               
                 
                   
                             
                     
                         
                         
                     
                   
                 
               
               
                 Prep. Nos. 49-65: R 4  = CF 3   
               
               
                 Prep. No. 66: R 4  = CF 2 CF 3   
               
               
                   
               
             
          
           
               
                 Prep. 
                   
                   
                   
                   
                   
               
               
                 No. 
                 R 3   
                   1 H-NMR(CDCl 3 , TMS) δ (ppm) 
                 MS (m/e) 
                 yield (%) 
                 b.p. (mmHg) 
               
               
                   
               
               
                 49 
                 4-CH 3 O—C 6 H 4 — 
                 7.48˜6.79(m, 4H), 3.79(s, 3H) 
                 238(69), 195(14), 145(35), 74(33), 59(100) 
                 79 
                 72˜74 (10) 
               
               
                 50 
                 3-CH 3 —C 6 H 4 — 
                 7.46˜6.98(m, 4H), 2.43(s, 3H) 
                 222(20), 203(70), 134(100) 
                 45 
                 column 
               
               
                 51 
                 4-CH 3 —C 6 H 4 — 
                 7.32˜7.18(m, 4H), 2.45(s, 3H) 
                 222(64), 203(23), 134(100) 
                 62 
                 column 
               
               
                 52 
                 4-C 2 H 3 —C 6 H 4 — 
                 7.38˜7.25(m, 4H), 2.68(q, 2H), 1.19(t, 3H) 
                 236(20), 145(100), 90(54) 
                 62 
                 column 
               
               
                 53 
                 3,4-(CH 3 ) 2 —C 6 H 4 — 
                 7.28˜7.02(m, 3H), 2.38(s, 3H), 2.32(s, 3H) 
                 236(18), 84(33), 45(100) 
                 78 
                 column 
               
               
                 54 
                 3,5-(CH 3 ) 2 —C 6 H 4 — 
                 7.32˜7.12(m, 3H), 2.41(s, 6H) 
                 236(29), 217(65), 148(100), 45(92) 
                 98 
                 column 
               
               
                 55 
                 3-CH 3 O—C 6 H 4 — 
                 7.48˜6.87(m, 4H), 3.81(s, 3H) 
                 238(42), 207(45), 188(37), 139(100), 69(94) 
                 54 
                 75 (10) 
               
               
                 56 
                 C 6 H 3 — 
                 7.59˜7.31(m, 5H) 
                 208(48), 84(83), 43(100) 
                 67 
                 column 
               
               
                 57 
                 4-C 2 H 5 O—C 6 H 4 — 
                 7.51˜6.85(m, 4H), 4.12(q, 2H), 1.29(t, 3H) 
                 252(47), 233(100), 84(64) 
                 73 
                 column 
               
               
                 58 
                 3,4-OCH 2 O—C 6 H 4 — 
                 7.01˜6.79(m, 3H), 6.01(s, 2H) 
                 252(46), 233(63), 164(82), 69(100) 
                 72 
                 column 
               
               
                 59 
                 3-CF 3 —C 6 H 4 — 
                 7.82˜7.18(m, 4H) 
                 276(52), 257(92), 188(100) 
                 52 
                 column 
               
               
                 60 
                 3-F—C 6 H 4 — 
                 7.53˜6.96(m, 4H) 
                 226(52), 207(25), 54(100) 
                 54 
                 column 
               
               
                 61 
                 4-F—C 6 H 4 — 
                 7.52˜6.83(m, 4H) 
                 226(20), 84(100) 
                 63 
                 column 
               
               
                 62 
                 3-Cl—C 6 H 4 — 
                 7.54˜7.23(m, 4H) 
                 242(26), 223(72), 188(49), 169(100) 
                 63 
                 column 
               
               
                 63 
                 4-Cl—C 6 H 4 — 
                 7.56˜7.21(m, 4H) 
                 242(35), 207(25), 174(70), 139(100), 60(79) 
                 45 
                 58 (10) 
               
               
                 64 
                 3,5-Cl 2 —C 6 H 5 — 
                 7.57˜7.19(m, 3H) 
                 276(100), 241(45) 
                 84 
                 85 (10) 
               
               
                 65 
                 C 4 H 3 S-2-yl- 
                 7.67˜6.92(m, 3H) 
                 214(42), 195(92), 126(100), 47(86) 
                 63 
                 column 
               
               
                 66 
                 C 6 H 5   
                 7.57˜6.89(m, 5H) 
                 246(67), 227(57), 127(100), 119(35) 
                 48 
                 138˜139(737) 
               
               
                   
               
             
          
         
       
     
     EXAMPLE 1 
     Preparation of N-Methyl-(2′-fluoro-1′-trifluoromethylstyryl-2′-oxy)acetanilide (Compound 1) 
     330 mg(2 mmol) of N-methyl-2-hydroxyacetanilide obtained in Preparation 1 was added to 10 ml of acetone and 0.22 ml of lOM sodium hydroxide solution(2.2 mmol) was added thereto. The resulting solution was stirred for 30 minutes and 416 mg(2 mmol) of 2,2-difluoro-1-trifluoromethyl styrene obtained in Preparation 56 was added slowly thereto. The resultant solution was stirred for 1 to 2 hours. Acetone was removed under a reduced pressure and the resulting solution was mixed with water and extracted with ethyl acetate. The organic layer was dried over magnesium sulfate and the solvent was removed under a reduced pressure. The residue was subjected to silica gel column chromatography using a mixture of n-hexane and ethyl acetate (9:1) as an eluent to obtain 655 mg(yield 92.8%) of the title compound having two isomers as a colorless liquid. 1H-NMR (CDCl 3 TMS) δ: 7.52-6.91(m, 10H), 4.49(E isomer) 4.30(Z isomer)(s, 2H), 3.30(s, 3H) 
     MS (m/e): 353(M + , 12), 177(42), 120(100), 91(72), 77(96)  19 F-NMR (CDCl 3 , CFCl 3 ) δ: −57.36(Z isomer) −57.95(E isomer)(d, 3F), −83.40(E, isomer) −84.99(Z isomer)(q, 1F) 
     EXAMPLE 2 
     Preparation of (E)-N-Methyl-(2′-fluoro-1′-trifluoromethylstyryl-2′-oxy)acetanilide (Compound 2) 
     The compound obtained in Example 1 was subjected to column chromatography using a mixture of n-hexane and ethyl acetate(9:1) as an eluent to isolate a pure form of the E isomer as a colorless solid. 
     E isomer;  1 H-NMR (CDCl 3 , TMS) δ: 7.54-6.90(m, 10H), 4.49(s, 2H), 3.31(s, 3H); MS (m/e): 353(M + , 43), 177(48), 120(100), 91(68), 7(82);  19 F-NMR (CDCl 3 , CFCl 3 ) δ: −57.95(d, 3F), −83.40(q, 1F) m.p.: 91-92° C. 
     EXAMPLE 3 
     Preparation of (Z)-N-Methyl-(2′-fluoro-1′-trifluoromethylstyryl-2′-oxy)acetanilide (Compound 3) 
     The compound obtained in Example 1 was subjected to column chromatography using a mixture of n-hexane and ethyl acetate(9:1) as an eluent to isolate a pure form of the Z isomer as a colorless oil. 
     Z isomer;  1 H-NMR (CDCl 3 , TMS) δ: 7.51-7.11(m, 10H), 4.30(s, 2H), 3.30(s, 3H); MS (m/e): 353(M + , 57), 177(40), 120(100), 91(70), 77(97);  19 F-NMR (CDCl 3 , CFCl 3 ) δ: −57.36(d, 3F), −84.99(q, 1F). 
     EXAMPLES 4 to 220 
     Using each of the alcoholic compounds obtained in Preparations 1 to 31 and each of the fluorovinyl compounds obtained in Preparations 49 to 66, the procedure of Example 1 was repeated to obtain 217 compounds(Compounds 4 to 220) of formula (I) of the present invention having various R 1 , R 2 , R 3  and R 4  groups listed in Table 4. The  1 H-NMR and MS data and melting points of these compounds are also shown in Table 4. L in Table 4 represents liquid. 
     
       
         
               
               
             
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
             
           
               
                 TABLE 4 
               
             
             
               
                   
               
               
                   
                 R 4  = CF 3   
               
               
                   
                 (I) 
               
               
                 
                   
                             
                     
                         
                         
                     
                   
                 
               
               
                   
               
             
          
           
               
                 Comp. No. 
                 R 1   
                 R 2   
                 R 3   
                 state (° C.) 
                 NMR (CDCl 3 , TMS) δ (ppm) 
                 MS (m/e) 
               
               
                   
               
             
          
           
               
                 1 
                 C 6 H 5   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.52˜6.91(m, 10H), 4.49(E) 4.30(Z) (s, 2H), 3.30(s, 3H) 
                 353(12), 177(42), 120(100), 
               
               
                   
                   
                   
                   
                   
                   
                 91(72), 77(96) 
               
               
                 2 
                 C 6 H 5   
                 CH 3   
                 C 6 H 5   
                 91-92 
                 7.54˜6.90(m, 10H), 4.49(s, 2H), 3.31(s, 3H) 
                 353(43), 177(48), 120(100), 
               
               
                   
                   
                   
                   
                   
                   
                 91(68), 77(82) 
               
               
                 3 
                 C 6 H 5   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.51˜7.11(m, 10H), 4.30(s, 2H), 3.30(s, 3H) 
                 353(57), 177(40), 120(100), 
               
               
                   
                   
                   
                   
                   
                   
                 91(70), 77(97) 
               
               
                 4 
                 C 6 H 5   
                 CH 3   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.51˜6.98(m, 9H), 4.48(E) 4.31(Z) (s, 2H), 3.31(s, 3H), 
                 367(45), 148(100), 120(54), 
               
               
                   
                   
                   
                   
                   
                 2.35(s, 3H) 
                 91(37) 
               
               
                 5 
                 C 6 H 5   
                 CH 3   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.54˜6.89(m, 9H), 4.49(E) 4.31(Z) (s, 2H), 3.32(s, 3H), 
                 367(28), 148(100), 120(68), 
               
               
                   
                   
                   
                   
                   
                 2.34(s, 3H)) 
                 92(52) 
               
               
                 6 
                 C 6 H 5   
                 CH 3   
                 4-C 2 H 3 —C 6 H 4   
                 L 
                 7.57˜7.01(m, 9H), 4.48(E) 4.30(Z) (s, 2H), 3.30(s, 3H), 
                 381(68), 148(100), 120(75), 
               
               
                   
                   
                   
                   
                   
                 2.64(q, 2H), 1.21(t, 3H) 
                 91(74), 77(76) 
               
               
                 7 
                 C 6 H 5   
                 CH 3   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.51˜7.02(m, 8H), 4.49(E) 4.31(Z) (s, 2H), 3.31(s, 3H), 
                 381(25), 148(92), 120(100), 
               
               
                   
                   
                   
                   
                   
                 2.30(s, 6H) 
                 91(46), 77(59) 
               
               
                 8 
                 C 6 H 5   
                 CH 3   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.58˜6.85(m, 8H), 4.48(E) 4.29(Z) (s, 2H), 3.32(s, 3H), 
                 381(25), 148(100), 120(59), 
               
               
                   
                   
                   
                   
                   
                 2.31(s, 6H) 
                 92(28) 
               
               
                 9 
                 C 6 H 5   
                 CH 3   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.65˜6.79(m, 9H), 4.49(E) 4.30(Z) (s, 2H), 3.85(s, 3H), 
                 383(46), 364(28), 148(100), 
               
               
                   
                   
                   
                   
                   
                 3.33(s, 3H) 
                 120(99) 
               
               
                 10 
                 C 6 H 5   
                 CH 3   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.66˜6.81(m, 9H), 4.49(E) 4.31(Z) (s, 2H), 3.86(s, 3H), 
                 383(51), 207(55), 148(100), 
               
               
                   
                   
                   
                   
                   
                 3.32(s, 3H) 
                 120(59) 
               
               
                 11 
                 C 6 H 5   
                 CH 3   
                 4-C 2 H 3 O—C 6 H 4   
                 L 
                 7.42˜6.80(m, 9H), 4.48(E) 4,30(Z) (s, 2H), 3.98(q, 2H), 
                 397(49), 249(30), 148(100), 
               
               
                   
                   
                   
                   
                   
                 3.32(s, 3H), 1.39(t, 3H) 
                 120(81) 
               
               
                 12 
                 C 6 H 5   
                 CH 3   
                 3,4-OCH 2 O—C 6 H 3   
                 L 
                 7.68˜6.82(m, 8H), 5.92(s, 2H), 4.49(E) 4.30(Z) (s, 2H), 
                 397(35), 148(100), 120(70), 
               
               
                   
                   
                   
                   
                   
                 3.33(s, 3H) 
                 77(43) 
               
               
                 13 
                 C 6 H 5   
                 CH 3   
                 3-CF 3 —C 6 H 4   
                 L 
                 7.68˜6.91(m, 9H), 4.48(E) 4.31(Z) (s, 2H), 3.31(s, 3H) 
                 421(35), 402(19), 148(100), 
               
               
                   
                   
                   
                   
                   
                   
                 120(99), 91(54) 
               
               
                 14 
                 C 6 H 5   
                 CH 3   
                 3-F—C 6 H 4   
                 L 
                 7.62˜6.99(m, 9H), 4.49(E) 4.31(Z) (s, 2H), 3.32(s, 3H) 
                 371(40), 148(100), 120(91), 
               
               
                   
                   
                   
                   
                   
                   
                 96(41), 77(37) 
               
               
                 15 
                 C 6 H 5   
                 CH 3   
                 4-F—C 6 H 4   
                 L 
                 7.68˜6.98(m, 9H), 4.48(E) 4.30(Z) (s, 2H), 3.33(s, 3H) 
                 371(30), 148(100), 120(78), 
               
               
                   
                   
                   
                   
                   
                   
                 77(42) 
               
               
                 16 
                 C 6 H 5   
                 CH 3   
                 3-Cl—C 6 H 4   
                 L 
                 7.72˜7.01(m, 9H), 4.49(E) 4.30(Z) (s, 2H), 3.34(s, 3H) 
                 387(62), 148(100), 120(45), 
               
               
                   
                   
                   
                   
                   
                   
                 77(47) 
               
               
                 17 
                 C 6 H 5   
                 CH 3   
                 4-Cl—C 6 H 4   
                 L 
                 7.65˜6.98(m, 9H), 4.48(E) 4.31(Z) (s, 2H), 3.35(s, 3H) 
                 387(59), 148(100), 120(95), 
               
               
                   
                   
                   
                   
                   
                   
                 91(46) 
               
               
                 18 
                 C 6 H 5   
                 CH 3   
                 3,5-Cl 2 —C 6 H 3   
                 L 
                 7.52˜7.09(m, 8H), 4.49(E) 4.32(Z) (s, 2H), 3.31(s, 3H) 
                 421(25), 148(100), 120(84), 
               
               
                   
                   
                   
                   
                   
                   
                 77(48) 
               
               
                 19 
                 C 6 H 5   
                 CH 3   
                 C 4 H 3 S-2-yl 
                 L 
                 7.62˜6.95(m, 8H), 4.49(E) 4.32(Z) (s, 2H), 3.32(s, 3H) 
                 359(10), 148(100), 120(58), 
               
               
                   
                   
                   
                   
                   
                   
                 77(15) 
               
               
                 20 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.52˜6.87(m, 9H), 4.49(E) 4.31(Z) (s, 2H), 3.85(s, 3H), 
                 383(12), 178(100), 144(81), 
               
               
                   
                   
                   
                   
                   
                 3.32(s, 3H) 
                 121(48) 
               
               
                 21 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.43˜6.76(m, 8H), 4.48(E) 4.29(Z) (s, 2H), 3.85(s, 3H), 
                 397(47), 178(100), 147(40) 
               
               
                   
                   
                   
                   
                   
                 3.31(s, 3H), 2.35(s, 3H) 
               
               
                 22 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.49˜6.79(m, 8H), 4.48(E) 4.28(Z) (s, 2H), 3.84(s, 3H), 
                 397(100), 372(33), 178(98), 
               
               
                   
                   
                   
                   
                   
                 3.31(s, 3H), 2.35(s, 3H) 
                 150(53) 
               
               
                 23 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 81˜82 
                 7.55˜6.79(m, 7H), 4.49(E) 4.29(Z) (s, 2H), 3.85(s, 3H), 
                 411(40), 178(100), 147(69) 
               
               
                   
                   
                   
                   
                   
                 3.33(s, 3H), 2.31(s, 6H) 
               
               
                 24 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.62˜6.78(m, 7H), 4.49(E) 4.30(Z) (s, 2H), 3.86(s, 3H), 
                 411(51), 178(100), 147(47), 
               
               
                   
                   
                   
                   
                   
                 3.32(s, 3H), 2.30(s, 6H) 
                 121(36) 
               
               
                 25 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.56˜6.72(m, 8H), 4.49(E) 4.32(Z) (s, 2H), 3.87(s, 3H), 
                 413(24), 178(100), 147(37) 
               
               
                   
                   
                   
                   
                   
                 3.85(s, 3H), 2.30(s, 3H) 
               
               
                 26 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 3,4-OCH 2 O—C 6 H 3   
                 L 
                 7.59˜6.52(m, 7H), 5.94(s, 2H), 4.49(E) 4.31(Z) (s, 2H), 
                 427(41), 178(100), 147(25), 
               
               
                   
                   
                   
                   
                   
                 3.86(s, 3H), 3.31(s, 3H) 
                 121(24) 
               
               
                 27 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 3,5-Cl—C 6 H 4   
                 L 
                 7.56˜6.85(m, 8H), 4.49(E) 4.30(Z) (s, 2H), 3.86(s, 3H), 
                 417(18), 178(100), 147(46), 
               
               
                   
                   
                   
                   
                   
                 3.34(s, 3H) 
                 121(41) 
               
               
                 28 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 4-Cl—C 6 H 4   
                 82˜83 
                 7.49˜6.87(m, 8H), 4.48(E) 4.30(Z) (s, 2H), 3.85(s, 3H), 
                 417(20), 178(100), 147(88), 
               
               
                   
                   
                   
                   
                   
                 3.42(s, 3H) 
                 121(58) 
               
               
                 29 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 3,5-Cl—C 6 H 4   
                 L 
                 7.71˜6.98(m, 7H), 4.49(E) 4.31(Z) (s, 2H), 3.85(s, 3H), 
                 451(35), 178(100), 147(82), 
               
               
                   
                   
                   
                   
                   
                 3.32(s, 3H) 
                 121(70) 
               
               
                 30 
                 4-F—C 6 H 4   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.54˜7.03(m, 9H), 4.49(E) 4.31(Z) (s, 2H), 3.53(s, 3H), 
                 371(41), 166(100), 138(84), 
               
               
                   
                   
                   
                   
                   
                   
                 109(78) 
               
               
                 31 
                 4-F—C 6 H 4   
                 CH 3   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.32˜7.02(m, 8H), 4.49(E) 4.30(Z) (s, 2H), 3.30(s, 3H), 
                 385(43), 166(100), 138(82), 
               
               
                   
                   
                   
                   
                   
                 2.35(s, 3H) 
                 109(79), 95(30) 
               
               
                 32 
                 4-F—C 6 H 4   
                 CH 3   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.36˜7.00(m, 8H), 4.49(E) 4.31(Z) (s, 2H), 3.32(s, 3H), 
                 385(21), 166(100), 138(94), 
               
               
                   
                   
                   
                   
                   
                 2.33(s, 3H) 
                 109(80) 
               
               
                 33 
                 4-F—C 6 H 4   
                 CH 3   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.30˜6.93(m, 7H), 4.49(E) 4.30(Z) (s, 2H), 3.31(s, 3H), 
                 399(50), 166(100), 138(76), 
               
               
                   
                   
                   
                   
                   
                 2.32(s, 6H) 
                 109(69) 
               
               
                 34 
                 4-F—C 6 H 4   
                 CH 3   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.31˜6.83(m, 8H), 4.48(E) 4.30(Z) (s, 2H), 3.86(s, 3H), 
                 401(57), 166(100), 138(67), 
               
               
                   
                   
                   
                   
                   
                 3.32(s, 3H) 
                 109(45) 
               
               
                 35 
                 4-F—C 6 H 4   
                 CH 3   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.35˜6.78(m, 8H), 4.49(E) 4.30(Z) (s, 2H), 3.84(s, 3H), 
                 401(42), 166(100), 138(52), 
               
               
                   
                   
                   
                   
                   
                 3.33(s, 3H) 
                 109(44) 
               
               
                 36 
                 4-F—C 6 H 4   
                 CH 3   
                 3-F—C 6 H 4   
                 L 
                 7.39˜6.94(m, 8H), 4.48(E) 4.31(Z) (s, 2H), 3.31(s, 3H) 
                 389(41), 166(89), 138(100), 
               
               
                   
                   
                   
                   
                   
                   
                 109(80), 95(30) 
               
               
                 37 
                 4-F—C 6 H 4   
                 CH 3   
                 4-F—C 6 H 4   
                 L 
                 7.46˜6.94(m, 8H), 4.49(E) 4.31(Z) (s, 2H), 3.32(s, 3H) 
                 389(56), 166(100), 138(91), 
               
               
                   
                   
                   
                   
                   
                   
                 109(76), 95(29) 
               
               
                 38 
                 4-F—C 6 H 4   
                 CH 3   
                 3-Cl—C 6 H 4   
                 L 
                 7.48˜7.06(m, 8H), 4.49(E) 4.32(Z) (s, 2H), 3.33(s, 3H) 
                 405(26), 166(60), 138(42), 
               
               
                   
                   
                   
                   
                   
                   
                 109(39), 43(100) 
               
               
                 39 
                 4-F—C 6 H 4   
                 CH 3   
                 4-Cl—C 6 H 4   
                 L 
                 7.45˜7.05(m, 8H), 4.48(E) 4.30(Z) (s, 2H), 3.32(s, 3H) 
                 405(41), 166(100), 138(84), 
               
               
                   
                   
                   
                   
                   
                   
                 109(73), 95(35) 
               
               
                 40 
                 4-F—C 6 H 4   
                 CH 3   
                 3.5-Cl 2 —C 6 H 3   
                 L 
                 7.34˜7.08(m, 7H), 4.49(E) 4.31(Z) (s, 2H), 3.30(s, 3H) 
                 439(46), 166(100), 138(89), 
               
               
                   
                   
                   
                   
                   
                   
                 109(90), 95(38) 
               
               
                 41 
                 4-Cl—C 6 H 4   
                 CH 3   
                 3,5-Cl 2 —C 6 H 3   
                 136˜137 
                 7.50˜7.05(m, 7H), 4.48(E) 4.30(Z) (s, 2H), 3.31(s, 3H) 
                 455(31), 182(56), 147(100), 
               
               
                   
                   
                   
                   
                   
                   
                 118(35), 77(24) 
               
               
                 42 
                 2,4-F 2 —C 6 H 3   
                 CH 3   
                 3-Cl—C 6 H 4   
                 L 
                 7.45˜6.85(m, 7H), 4.49(E) 4.31(Z) (s, 2H), 3.32(s, 3H) 
                 423(21), 184(34), 156(24), 
               
               
                   
                   
                   
                   
                   
                   
                 127(100) 
               
               
                 43 
                 2,4-Cl 2 —C 6 H 3   
                 CH 3   
                 4-F—C 6 H 4   
                 L 
                 7.79˜6.87(m, 7H), 4.48(E) 4.31(Z) (s, 2H), 3.33(s, 3H) 
                 439(34), 216(57), 181(100), 
               
               
                   
                   
                   
                   
                   
                   
                 145(50) 
               
               
                 44 
                 C 6 H 5   
                 C 2 H 5   
                 C 6 H 5   
                 L 
                 7.65˜7.09(m, 10H), 4.41(E) 4.28(Z) (s, 2H), 3.75(q, 2H), 
                 367(12), 162(100), 134(79), 
               
               
                   
                   
                   
                   
                   
                 1.13(t, 3H) 
                 106(57), 91(55) 
               
               
                 45 
                 C 6 H 5   
                 C 2 H 5   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.49˜7.01(m, 9H), 4.42(E) 4.29(Z) (s, 2H), 3.76(q, 2H), 
                 381(100), 363(10), 162(56), 
               
               
                   
                   
                   
                   
                   
                 2.39(s, 3H), 1.14(t, 3H) 
                 134(64) 
               
               
                 46 
                 C 6 H 5   
                 C 2 H 5   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.62˜6.81(m, 9H), 4.43(E) 4.28(Z) (s, 2H), 3.85(s, 3H), 
                 397(29), 378(16), 162(99), 
               
               
                   
                   
                   
                   
                   
                 3.74(q, 2H), 1.14(t, 3H) 
                 134(100), 106(78) 
               
               
                 47 
                 C 6 H 5   
                 C 2 H 5   
                 4-C 2 H 3 O—C 6 H 4   
                 L 
                 7.42˜6.75(m, 9H), 4.42(E) 4.28(Z) (s, 2H), 3.94(q, 2H), 
                 411(25), 221(54), 162(100), 
               
               
                   
                   
                   
                   
                   
                 3.72(q, 2H), 1.34(t, 3H), 1.13(t, 3H) 
                 134(72) 
               
               
                 48 
                 C 6 H 5   
                 C 2 H 5   
                 3-CF 3 —C 6 H 4   
                 L 
                 7.82˜7.02(m, 9H), 4.42(E) 4.29(Z) (s, 2H), 3.74(q, 2H), 
                 435(16), 162(100), 134(89), 
               
               
                   
                   
                   
                   
                   
                 1.14(t, 3H) 
                 106(46) 
               
               
                 49 
                 C 6 H 5   
                 C 2 H 5   
                 3-F—C 6 H 4   
                 L 
                 7.49˜6.90(m, 9H), 4.42(E) 4.28(Z) (s, 2H), 3.75(q, 2H), 
                 385(30), 162(100), 134(71), 
               
               
                   
                   
                   
                   
                   
                 1.13(t, 3H) 
                 106(43) 
               
               
                 50 
                 C 6 H 5   
                 C 2 H 5   
                 4-F—C 6 H 4   
                 L 
                 7.62˜6.92(m, 9H), 4.41(E) 4.29(Z) (s, 2H), 3.76(q, 2H), 
                 385(39), 162(100), 133(80), 
               
               
                   
                   
                   
                   
                   
                 1.14(t, 3H) 
                 91(53) 
               
               
                 51 
                 C 6 H 3   
                 C 2 H 5   
                 4-Cl—C 6 H 4   
                 L 
                 7.57˜6.98(m, 9H), 4.42(E) 4.29(Z) (s, 2H), 3.76(q, 2H), 
                 401(40), 162(100), 134(56) 
               
               
                   
                   
                   
                   
                   
                 1.14(t, 3H) 
               
               
                 52 
                 C 6 H 3   
                 C 2 H 5   
                 C 4 H 3 S-2-yl 
                 L 
                 7.68˜6.93(m, 8H), 4.42(E) 4.28(Z) (s, 2H), 3.75(q, 2H), 
                 373(31), 162(100), 134(32) 
               
               
                   
                   
                   
                   
                   
                 1.16(t, 3H) 
               
               
                 53 
                 4-CH 3 —C 6 H 4   
                 C 2 H 5   
                 C 6 H 3   
                 L 
                 7.49˜6.94(m, 9H), 4.43(E) 4.29(Z) (s, 2H), 3.74(q, 2H), 
                 381(55), 176(100, 105(44) 
               
               
                   
                   
                   
                   
                   
                 2.39(s, 3H), 1.13(t, 3H) 
               
               
                 54 
                 4-CH 3 —C 6 H 4   
                 C 2 H 5   
                 4-F—C 6 H 4   
                 L 
                 7.63˜6.89(m, 8H), 4.42(E) 4.29(Z) (s, 2H), 3.74(q, 2H), 
                 399(55), 176(100), 148(55) 
               
               
                   
                   
                   
                   
                   
                 2.38(s, 3H), 1.12(t, 3H) 
               
               
                 55 
                 4-CH 3 O—C 6 H 4   
                 C 2 H 5   
                 C 6 H 3   
                 L 
                 7.49˜6.85(m, 9H), 4.41(E) 4.27(Z) (s, 2H), 3.81(s, 3H), 
                 397(23), 378(12), 193(100), 
               
               
                   
                   
                   
                   
                   
                 3.72(q, 2H), 1.13(t, 3H) 
                 165(36) 
               
               
                 56 
                 4-CH 3 O—C 6 H 4   
                 C 2 H 5   
                 4-F—C 6 H 4   
                 L 
                 7.48˜6.84(m, 8H), 4.42(E) 4.28(Z) (s, 2H), 3.82(s, 3H), 
                 415(14), 192(100), 164(43), 
               
               
                   
                   
                   
                   
                   
                 3.75(q, 2H), 1.12(t, 3H) 
                 121(75) 
               
               
                 57 
                 3-CF 3 —C 6 H 4   
                 C 2 H 5   
                 C 6 H 3   
                 52˜53 
                 7.81˜7.23(m, 9H), 4.43(E) 4.29(Z) (s, 2H), 3.75(q, 2H), 
                 435(26), 221(100), 174(61), 
               
               
                   
                   
                   
                   
                   
                 1.13(t, 3H) 
                 159(69) 
               
               
                 58 
                 3-CF 3 —C 6 H 4   
                 C 2 H 5   
                 4-CH 3 —C 6 H 4   
                 48˜49 
                 7.86˜7.02(m, 8H), 4.41(E) 4.28(Z) (s, 2H), 3.72(q, 2H), 
                 449(10), 230(100), 202(36), 
               
               
                   
                   
                   
                   
                   
                 2.38(s, 3H), 1.12(t, 3H) 
                 174(27) 
               
               
                 59 
                 3-CF 3 —C 6 H 4   
                 C 2 H 5   
                 4-F—C 6 H 4   
                 L 
                 7.89˜6.85(m, 8H), 4.41(E) 4.29(Z) (s, 2H), 3.73(q, 2H), 
                 453(26), 231(100), 201(63) 
               
               
                   
                   
                   
                   
                   
                 1.14(t, 3H) 
               
               
                 60 
                 2-Cl—C 6 H 4   
                 C 2 H 3   
                 C 6 H 3   
                 L 
                 7.60˜7.12(m, 9H), 4.40(E) 4.28(Z) (s, 2H), 4.02(m, 1H), 
                 401(72), 382(15), 196(100), 
               
               
                   
                   
                   
                   
                   
                 3.48(m, 1H), 1.12(t, 3H) 
                 168(44), 146(35) 
               
               
                 61 
                 2-Cl—C 6 H 4   
                 C 2 H 5   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.62˜7.02(m, 8H), 4.40(E) 4.28(Z) (s, 2H), 4.06(m, 1H), 
                 415(26), 196(100), 118(35) 
               
               
                   
                   
                   
                   
                   
                 3.49(m, 1H), 2.39(s, 3H), 1.14(t, 3H) 
               
               
                 62 
                 3-Cl—C 6 H 4   
                 C 2 H 5   
                 C 6 H 3   
                 L 
                 7.49˜6.94(m, 9H), 4.41(E) 4.28(Z) (s, 2H), 3.73(q, 2H), 
                 401(14), 196(100), 168(24), 
               
               
                   
                   
                   
                   
                   
                 1.13(t, 3H) 
                 146(27) 
               
               
                 63 
                 4-Cl—C 6 H 4   
                 C 2 H 5   
                 C 6 H 5   
                 L 
                 7.50˜6.90(m, 9H), 4.40(E) 4.28(Z) (s, 2H), 3.74(q, 2H), 
                 401(10), 196(100), 146(37), 
               
               
                   
                   
                   
                   
                   
                 1.14(t, 3H) 
                 118(18) 
               
               
                 64 
                 4-Cl—C 6 H 4   
                 C 2 H 5   
                 4-CH 3 —C 6 H 4   
                 70˜71 
                 7.62˜6.95(m, 8H), 4.40(E) 4.29(Z) (s, 2H), 3.76(q, 2H), 
                 415(12), 196(81), 161(100), 
               
               
                   
                   
                   
                   
                   
                 2.39(s, 3H), 1.14(t, 3H) 
                 118(27) 
               
               
                 65 
                 C 6 H 5   
                 n-C 3 H 7   
                 C 6 H 3   
                 L 
                 7.50˜7.02(m, 10H), 4.40(E) 4.25(Z) (s, 2H), 3.65(t, 2H), 
                 381(11), 176(100), 134(84), 
               
               
                   
                   
                   
                   
                   
                 1.68˜1.41(m, 2H), 0.91(t, 3H) 
                 106(93), 77(62) 
               
               
                 66 
                 C 6 H 5   
                 n-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.62˜6.97(m, 9H), 4.40(E) 4.26(Z) (s, 2H), 3.64(t, 2H), 
                 395(20), 377(13), 176(100), 
               
               
                   
                   
                   
                   
                   
                 2.32(s, 3H), 1.67˜1.42(m, 2H), 0.91(t, 3H) 
               
               
                 67 
                 4-CH 3 O—C 6 H 4   
                 n-C 3 H 7   
                 C 6 H 3   
                 L 
                 7.53˜6.86(m, 9H), 4.40(E) 4.25(Z) (s, 2H), 3.81(s, 3H), 
                 411(24), 206(100), 178(35), 
               
               
                   
                   
                   
                   
                   
                 3.65(t, 2H), 1.65˜1.41(m, 2H), 0.91(t, 3H) 
                 164(48), 136(42) 
               
               
                 68 
                 4-CH 3 O—C 6 H 4   
                 n-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.62˜6.79(m, 8H), 4.39(E) 4.25(Z) (s, 2H), 3.83(s, 3H), 
                 425(29), 406(14), 203(100) 
               
               
                   
                   
                   
                   
                   
                 3.65(t, 2H), 2.32(s, 3H), 1.68˜1.42(m, 2H), 0.92(t, 3H) 
               
               
                 69 
                 C 6 H 3   
                 i-C 3 H 7   
                 C 6 H 3   
                 54˜55 
                 7.50˜7.01(m, 10H), 5.09˜4.87(m, 1H), 4.30(E) 4.14(Z) 
                 381(12), 176(59), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.08(d, 6H) 
                 106(97), 77(89) 
               
               
                 70 
                 C 6 H 3   
                 i-C 3 H 7   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.62˜6.82(m, 9H), 5.10˜4.89(m, 1H), 4.29(E) 4.16(Z) 
                 395(39), 176(34), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.39(s, 3H), 1.09(d, 6H) 
                 106(69) 
               
               
                 71 
                 C 6 H 3   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 67˜68 
                 7.62˜6.97(m, 9H), 5.28˜4.86(m, 1H), 4.29(E) 4.15(Z) 
                 395(65), 376(49), 176(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.46(s, 3H), 1.09(d, 6H) 
                 106(76) 
               
               
                 72 
                 C 6 H 3   
                 i-C 3 H 7   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.64˜6.85(m, 8H), 5.28˜4.88(m, 1H), 4.30(E) 4.16(Z) 
                 409(56), 134(100), 106(87), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.38(s, 6H), 1.09(d, 6H) 
                 77(52) 
               
               
                 73 
                 C 6 H 3   
                 i-C 3 H 7   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.51˜6.79(m, 9H), 5.19˜4.84(m, 1H), 4.28(E) 4.14(Z) 
                 411(30), 176(39), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.80(s, 3H), 1.08(d, 6H) 
                 106(50) 
               
               
                 74 
                 C 6 H 3   
                 i-C 3 H 7   
                 4-CH 3 O—C 6 H 3   
                 48˜49 
                 7.71˜6.95(m, 9H), 5.21˜4.85(m, 1H), 4.29(E) 4.15(Z) 
                 411(33), 176(57), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.81(s, 3H), 1.09(d, 6H) 
                 106(74) 
               
               
                 75 
                 C 6 H 3   
                 i-C 3 H 7   
                 4-C 2 H 3 O—C 6 H 4   
                 L 
                 7.48˜6.79(m, 9H), 5.10˜4.84(m, 1H), 4.28(E) 4.16(Z) 
                 425(70), 176(63), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 4.40(q, 2H), 1.38(t, 3H), 1.09(d, 6H) 
                 106(69), 84(55) 
               
               
                 76 
                 C 6 H 3   
                 i-C 3 H 7   
                 3,4-OCH 2 O—C 6 H 3   
                 L 
                 7.59˜6.75(m, 8H), 5.96(s, 2H), 5.11˜4.86(m, 1H), 
                 425(15), 219(30), 134(100), 
               
               
                   
                   
                   
                   
                   
                 4.29(E) 4.16(Z) (s, 2H), 1.08(d, 6H) 
                 106(60) 
               
               
                 77 
                 C 6 H 3   
                 i-C 3 H 7   
                 3-F—C 6 H 4   
                 L 
                 7.50˜6.91(m, 9H), 5.10˜4.82(m, 1H), 4.29(E) 4.14(Z) 
                 399(40), 134(100), 106(70) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.09(d, 6H) 
               
               
                 78 
                 C 6 H 3   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.54˜6.89(m, 9H), 5.09˜4.84(m, 1H), 4.28(E) 4.15(Z) 
                 399(35), 176(45), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.08(d, 6H) 
                 106(83) 
               
               
                 79 
                 C 6 H 3   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.69˜6.94(m, 9H), 5.11˜4.88(m, 1H), 4.29(E) 4.15(Z) 
                 415(45), 176(31), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.08(d, 6H) 
                 106(65) 
               
               
                 80 
                 C 6 H 3   
                 i-C 3 H 7   
                 4-Cl—C 6 H 4   
                 72˜73 
                 7.87˜6.87(m, 9H), 5.21˜4.87(m, 1H), 4.28(E) 4.14(Z) 
                 415(25), 176(28), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.09(d, 6H) 
                 106(73), 78(34) 
               
               
                 81 
                 C 6 H 3   
                 i-C 3 H 7   
                 C 4 H 3 S-2-yl 
                 63˜64 
                 7.50˜6.94(m, 8H), 5.18˜4.81(m, 1H), 4.29(E) 4.16(Z) 
                 387(22), 176(31), 134(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.08(d, 6H) 
                 106(85), 77(41), 43(46) 
               
               
                 82 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 3   
                 L 
                 7.61˜6.97(m, 9H), 5.00˜4.78(m, 1H), 4.28(E) 4.17(Z) 
                 395(46), 148(100), 120(47), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.32(s, 3H), 1.27(d, 3H), 1.02(d, 3H) 
                 45(23) 
               
               
                 83 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.48˜6.95(m, 8H), 4.95˜4.75(m, 1H), 4.29(E) 4.15(Z) 
                 409(9), 190(34), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.33(s, 3H), 2.31(s, 3H), 1.30(d, 3H), 
                 120(80), 118(30), 91(30), 
               
               
                   
                   
                   
                   
                   
                 1.00(d, 3H) 
                 45(42) 
               
               
                 84 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.42˜7.00(m, 7H), 4.96˜4.76(m, 1H), 4.28(E) 4.15(Z) 
                 423(15), 148(100), 120(49), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.33(s, 3H), 2.30(s, 6H), 1.30(d, 3H), 
                 45(22) 
               
               
                   
                   
                   
                   
                   
                 1.02(d, 3H) 
               
               
                 85 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.40˜6.85(m, 7H), 4.95˜4.76(m, 1H), 4.28(E) 4.16(Z) 
                 423(20), 148(100), 120(45), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.33(s, 3H), 2.31(s, 6H), 1.31(d, 3H), 
                 45(24) 
               
               
                   
                   
                   
                   
                   
                 1.01(d, 3H) 
               
               
                 86 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.46˜6.75(m. 8H), 4.90˜4.72(m, 1H), 4.28(E) 4.16(Z) 
                 425(R), 148(100), 120(82), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 3.82(s, 3H), 2.32(s, 3H), 1.28(d, 3H), 
                 45(39) 
               
               
                   
                   
                   
                   
                   
                 0.98(d, 3H) 
               
               
                 87 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.40˜6.80(m, 8H), 4.91˜4.75(m, 1H), 4.28(E) 4.15(Z) 
                 425(8), 148(100), 120(63), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 3.81(s, 3H), 2.31(s, 3H), 1.29(d, 3H), 
                 45(25) 
               
               
                   
                   
                   
                   
                   
                 0.99(d, 3H) 
               
               
                 88 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3-F—C 6 H 4   
                 L 
                 7.38˜6.87(m, 8H), 4.91˜4.72(m, 1H), 4.28(E) 4.16(Z) 
                 413(54), 148(100), 120(68), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.31(s, 3H), 1.29(d, 3H), 0.98(d, 3H) 
                 45(39) 
               
               
                 89 
                 2-CH 3 —-C 6 H 4   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.51˜6.95(m, 8H), 4.97˜4.78(m, 1H), 4.28(E) 4.15(Z) 
                 413(22), 190(89), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.30(s, 3H), 1.25(d, 3H), 1.01(d, 3H) 
                 120(94), 91(73) 
               
               
                 90 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.54˜7.00(m, 8H), 4.96˜4.74(m, 1H), 4.27(E) 4.16(Z) 
                 429(16), 148(100), 120(51), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.28(s, 3H), 1.30(d, 3H), 1.01(d, 3H) 
                 45(23) 
               
               
                 91 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-Cl—C 6 H 4   
                 L 
                 7.50˜7.00(m, 8H), 4.95˜4.76(m, 1H), 4.28(E) 4.15(Z) 
                 429(30), 148(100), 120(52), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.29(s, 3H), 1.28(d, 3H), 1.00(d, 3H) 
                 84(32), 45(36) 
               
               
                 92 
                 2-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3,5-Cl 2 —C 6 H 3   
                 L 
                 7.52˜7.00(m, 7H), 4.95˜4.75(m, 1H), 4.27(E) 4.15(Z) 
                 463(16), 148(100), 120(73), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 228(s, 3H), 1.30(d, 3H), 1.01(d, 3H) 
                 45(45) 
               
               
                 93 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 5   
                 64˜65 
                 7.45˜6.80(m, 9H), 5.02˜4.79(m, 1H), 4.30(E) 4.12(Z) 
                 395(14), 190(56), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.35(s, 3H), 1.08(d, 6H) 
                 120(95), 91(35) 
               
               
                 94 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.32˜6.79(m, 8H), 5.03˜4.80(m, 1H), 4.30(E) 4.15(Z) 
                 409(11), 190(28), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.34(s, 3H), 2.30(s, 3H), 1.09(d, 6H) 
                 120(51), 84(39) 
               
               
                 95 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-C 2 H 5 —C 6 H 4   
                 76˜77 
                 7.32˜6.80(m, 8H), 5.04˜4.83(m, 1H), 4.28(E) 4.14(Z) 
                 409(36), 190(60), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.38(s, 3H), 2.31(s, 3H), 1.05(d, 6H) 
                 120(54) 
               
               
                 96 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-C 2 H 5 —C 6 H 4   
                 66˜67 
                 7.40˜6.81(m, 8H), 5.04˜4.84(m, 1H), 4.30(E) 4.16(Z) 
                 423(41), 190(47), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.65(q, 2H), 2.38(s, 3H), 1.26(1, 3H), 
                 120(60), 91(21) 
               
               
                   
                   
                   
                   
                   
                 1.09(d, 6H) 
               
               
                 97 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.48˜6.81(m, 7H), 5.03˜4.85(m, 1H), 4.31(E) 4.17(Z) 
                 423(56), 190(39), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.39(s, 3H), 2.25(s, 6H), 1.08(d, 6H) 
                 120(52), 91(20) 
               
               
                 98 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 60˜61 
                 7.38˜6.80(m, 7H), 5.05˜4.85(m, 1H), 4.29(E) 4.15(Z) 
                 423(57), 190(69), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.35(s, 3H), 2.29(s, 6H), 1.07(d, 6H) 
                 120(63), 91(24) 
               
               
                 99 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3-CH 3 —C 6 H 4   
                 46˜47 
                 7.41˜6.82(m, 8H), 5.06˜4.86(m, 1H), 4.30(E) 4.16(Z) 
                 425(58), 190(37), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.80(s, 3H), 2.35(s, 3H), 1.10(d, 6H) 
                 120(53) 
               
               
                 100 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 O—C 6 H 4   
                 68˜69 
                 7.37˜6.79(m, 8H), 5.01˜4.80(m, 1H), 4.30(E) 4.15(Z) 
                 425(31), 190(11), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.82(s, 3H), 2.34(s, 3H), 1.07(d, 6H) 
                 1.20(79), 91(30) 
               
               
                 101 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3-F—C 6 H 4   
                 42˜43 
                 7.35˜6.81(m, 8H), 5.01˜4.78(m, 1H), 4.30(E) 4.14(Z) 
                 413(57), 190(37), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H) 2.35(s, 3H), 1.09(d, 6H) 
                 120(54) 
               
               
                 102 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.50˜6.85(m, 8H), 5.04˜4.85(m, 1H), 4.30(E) 4.16(Z) 
                 413(51), 148(100), 120(90) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.39(s, 3H), 1.09(d, 6H) 
               
               
                 103 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.48˜6.78(m, 8H), 5.04˜4.85(m, 1H), 4.31(E) 4.14(Z) 
                 429(25), 148(100), 120(83) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.38(s, 3H), 1.08(d, 6H) 
               
               
                 104 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-Cl—C 6 H 4   
                 56˜57 
                 7.40˜6.62(m, 8H), 5.02˜4.85(m, 1H), 4.30(E) 4.15(Z) 
                 429(55), 190(23), 148(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.38(s, 3H), 1.08(d, 6H) 
                 120(53) 
               
               
                 105 
                 3-CH 3 —C 6 H 4   
                 i-C 3 H 7   
                 3,5-Cl 2 —C 6 H 3   
                 58˜59 
                 7.35˜6.80(m, 7H), 5.00˜4.80(m, 1H), 4.31(E) 4.17(Z) 
                 463(51), 148(100), 120(37) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.35(s, 3H), 1.07(d, 6H) 
               
               
                 106 
                 3-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 5   
                 80˜81 
                 7.50˜6.58(m, 9H), 5.08˜4.85(m, 1H), 4.29(E) 4.14(Z) 
                 411(28), 208(100), 165(82), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.82(s, 3H), 1.09(d, 6H) 
                 137(36) 
               
               
                 107 
                 3-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 93˜94 
                 7.52˜6.53(m, 8H), 5.23˜4.78(m, 1H), 4.30(E) 4.15(Z) 
                 425(33), 375(100), 118(78) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.82(s, 3H), 2.41(s, 3H), 1.12(d, 6H) 
               
               
                 108 
                 3-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 50˜51 
                 7.45˜6.55(m, 8H), 5.02˜4.85(m, 1H), 4.31(E) 4.16(Z) 
                 429(52), 206(82), 164(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.80(s, 3H), 1.09(d, 6H) 
                 136(86), 45(24) 
               
               
                 109 
                 3,4-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.51˜6.76(m, 8H), 5.02˜4.82(m, 1H), 4.30(E) 4.14(Z) 
                 445(50), 206(50), 164(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.82(s, 3H), 1.02(d, 6H) 
                 136(68), 45(54) 
               
               
                 110 
                 3-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 4-Cl—C 6 H 4   
                 60˜61 
                 7.45˜6.58(m, 8H), 5.02˜4.85(m, 1H), 4.29(E) 4.14(Z) 
                 445(24), 206(66), 164(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.81(s, 3H), 1.10(d, 6H) 
                 136(92), 45(37) 
               
               
                 111 
                 3-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 3,5-Cl 2 —C 6 H 3   
                 L 
                 7.41˜6.61(m, 7H), 5.00˜4.84(m, 1H), 4.30(E) 4.15(Z) 
                 479(51), 206(54), 164(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.81(s, 3H), 1.09(d, 6H) 
                 137(74), 45(26) 
               
               
                 112 
                 4-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 3   
                 L 
                 7.49˜6.81(m, 9H), 5.04˜4.82(m, 1H), 4.29(E) 4.13(Z) 
                 411(56), 206(68), 164(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.81(s, 3H), 1.04(d, 6H) 
                 136(52), 121(74) 
               
               
                 113 
                 4-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.55˜6.88(m, 8H), 5.12˜4.79(m, 1H), 4.31(E) 4.16(Z) 
                 425(26), 210(81), 168(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.81(s, 3H), 2.38(s, 3H), 1.08(d, 6H) 
                 140(53), 133(49), 45(51) 
               
               
                 114 
                 4-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 87˜88 
                 7.62˜6.98(m, 8H), 5.21˜4.82(m, 1H), 4.29(E) 4.14(Z) 
                 425(14), 406(10), 203(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.82(s, 3H), 2.35(s, 3H), 1.08(d, 6H) 
                 69(27) 
               
               
                 115 
                 4-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.40˜6.81(m, 8H), 5.02˜4.83(m, 1H), 4.29(E) 4.15(Z) 
                 441(30), 206(76), 164(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.81(s, 3H), 3.79(s, 3H), 1.08(d, 6H) 
                 136(42), 121(47) 
               
               
                 116 
                 4-CH 3 O—C 6 H 4   
                 i-C 3 H 4   
                 4-F—C 6 H 4   
                 L 
                 7.49˜6.86(m, 8H), 5.03˜4.84(m, 1H), 4.30(E) 4.15(Z) 
                 429(57), 206(36), 164(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.82(s, 3H), 1.10(d, 6H) 
                 136(52) 
               
               
                 117 
                 4-CH 3 O—C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.49˜6.88(m, 8H), 5.03˜4.85(m, 1H), 4.29(E) 4.17(Z) 
                 445(62), 164(100), 121(42) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.82(s, 3H), 1.10(d, 6H) 
               
               
                 118 
                 3-CF 3 —C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 3   
                 L 
                 7.80˜7.23(m, 9H), 5.12˜4.89(m, 1H), 4.30(E) 4.15(Z) 
                 449(36), 430(19), 244(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.02(d, 6H) 
                 174(40) 
               
               
                 119 
                 3-CF 2 —C 6 H 4   
                 i-C 3 H 7   
                 3,4-OCH 2 O—C 6 H 3   
                 L 
                 7.95˜6.72(m, 7H), 5.95(s, 2H), 5.28˜4.84(m, 1H), 
                 493(35), 244(21), 202(100) 
               
               
                   
                   
                   
                   
                   
                 4.29(E) 4.14(Z) (s, 2H), 1.09(d, 6H) 
               
               
                 120 
                 3-CF 3 —C 6 H 4   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.81˜6.98(m, 8H), 5.05˜4.92(m, 1H), 4.29(E) 4.16(Z) 
                 467(30), 244(35), 203(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.12(d, 6H) 
                 174(78), 145(65) 
               
               
                 121 
                 3-CF 4 —C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.79˜7.18(m, 8H), 5.09˜4.89(m, 1H), 4.30(E) 4.14(Z) 
                 483(24), 202(100), 174(31) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.10(d, 6H) 
               
               
                 122 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 5   
                 75˜76 
                 7.51˜6.91(m, 9H), 5.15˜4.67(m, 1H), 4.29(E) 4.14(Z) 
                 399(70), 380(26), 194(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.02(d, 6H) 
                 152(94), 123(91), 109(36) 
               
               
                 123 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 68˜69 
                 7.46˜6.98(m, 8H), 5.21˜4.78(m, 1H), 4.30(E) 4.15(Z) 
                 413(45), 394(100), 109(36) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.46(s, 3H), 1.07(d, 6H) 
               
               
                 124 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.51˜6.91(m, 8H), 5.51˜4.67(m, 1H), 4.29(E) 4.17(Z) 
                 429(22), 410(15), 194(47), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 3.85(s, 3H), 1.02(d, 6H) 
                 152(100), 124(41) 
               
               
                 125 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 3-CF 3 —C 6 H 4   
                 L 
                 7.79˜7.05(m, 1H), 5.23˜4.82(m, 1H), 4.30(E) 4.14(Z) 
                 467(15), 194(51), 152(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.08(d, 6H) 
                 124(36) 
               
               
                 126 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.49˜6.98(m, 8H), 5.06˜4.87(m, 1H), 4.29(E) 4.16(Z) 
                 417(36), 194(92), 152(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 1.11(d, 6H) 
                 122(86) 
               
               
                 127 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.41˜7.01(m, 8H), 5.02˜4.85(m, 1H), 4.30(E) 4.14(Z) 
                 433(45), 152(100), 124(41) 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 1.02(d, 6H) 
               
               
                 128 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 C 4 H 3 S-2-yl 
                 L 
                 7.46˜6.97(m, 7H), 5.21˜4.75(m, 1H), 4.29(E) 4.15(Z) 
                 405(31), 194(36), 152(100) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.09(d, 6H) 
                 122(21), 109(24) 
               
               
                 129 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 3   
                 L 
                 7.58˜7.02(m, 9H), 4.98˜4.79(m, 1H), 4.29(E) 4.15(Z) 
                 415(25), 168(100), 140(64), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H, 1.24(d, 3H), 1.02(d, 3H) 
                 45(57) 
               
               
                 130 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.61˜7.02(m, 8H), 5.03˜4.79(m, 1H), 4.31(E) 4.14(Z) 
                 429(60), 168(100), 140(53), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.35(s, 3H), 1.24(d, 3H), 1.02(d, 3H) 
               
               
                 131 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.61˜7.08(m, 8H), 4.98˜4.79(m, 1H), 4.30(E) 4.15(Z) 
                 429(15), 168(100), 140(44) 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.35(s, 3H), 1.25(d, 3H), 1.02(d, 3H) 
               
               
                 132 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 4-C 2 H 5 —C 6 H 4   
                 L 
                 7.60˜7.08(m, 8H), 4.98˜4.78(m, 1H), 4.33(E) 4.14(Z) 
                 443(17), 210(59), 168(100), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.65(q, 2H), 1.32(t, 3H), 1.25(d, 3H), 
                 1.33(86), 45(78) 
               
               
                   
                   
                   
                   
                   
                 1.03(d, 3H) 
               
               
                 133 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.59˜7.02(m, 7H), 4.98˜4.79(m, 1H), 4.29(E) 4.16(Z) 
                 443(20), 170(59), 168(100), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H, 2.26(s, 6H), 1.23(d, 3H), 1.02(d, 3H) 
                 140(59) 
               
               
                 134 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 64˜65 
                 7.58˜6.89(m, 7H), 5.02˜4.78(m, 1H), 4.30(E) 4.15(Z) 
                 443(30), 168(100), 140(44) 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.28(s, 6H), 1.23(d, 3H), 1.00(d, 3H) 
               
               
                 135 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.60˜6.80(m, 8H), 5.00˜4.80(m, 1H), 4.29(E) 4.17(Z) 
                 445(30), 210(25), 168(100), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H) 3.79(s, 3H), 1.27(d, 3H), 1.01(d, 3H) 
                 140(68), 133(56), 45(36) 
               
               
                 136 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.59˜6.87(m, 8H), 4.99˜4.78(m, 1H), 4.32(E) 4.13(Z) 
                 445(25), 168(100), 140(49), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 3.79(s, 3H), 1.25(d, 3H), 1.03(d, 3H) 
                 45(78) 
               
               
                 137 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3-F—C 6 H 4   
                 L 
                 7.61˜6.91(m, 8H), 5.01˜4.78(m, 1H), 4.30(E) 4.18(Z) 
                 4.33(25), 210(57), 168(100), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.28(d, 3H), 1.02(d, 3H) 
                 140(81), 133(56) 
               
               
                 138 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.60˜6.98(m, 8H), 5.02˜4.79(m, 1H), 4.32(E) 4.19(Z) 
                 433(30), 168(100), 140(67), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.29(d, 3H), 1.03(d, 3H) 
                 133(47) 
               
               
                 139 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.59˜7.04(m, 8H), 4.99˜4.78(m, 1H), 4.33(E) 4.16(Z) 
                 449(20), 168(100), 140(64), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.25(d, 3H), 1.02(d, 3H) 
                 45(75) 
               
               
                 140 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 4-Cl—C 6 H 4   
                 L 
                 7.62˜7.15(m, 8H), 5.00˜4.75(m, 1H), 4.30(E) 4.17(Z) 
                 449(15), 168(100), 140(49), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.29(d, 3H), 1.02(d, 3H) 
                 133(37), 45(34) 
               
               
                 141 
                 2-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3,5-Cl 2 —C 6 H 3   
                 L 
                 7.57˜7.01(m, 7H), 4.97˜4.79(m, 1H), 4.30(E) 4.22(Z) 
                 483(25), 168(100), 140(77), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.23(d, 3H), 1.02(d, 3H) 
                 133(63) 
               
               
                 142 
                 3-Cl—C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 3   
                 L 
                 7.65˜6.98(m, 9H), 5.09˜4.84(m, 1H), 4.30(E) 4.15(Z) 
                 415(10), 211(45), 169(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.09(d, 6H) 
                 87(35) 
               
               
                 143 
                 3-Cl—C 6 H 4   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 79˜80 
                 7.52˜6.53(m, 8H), 5.24˜4.72(m, 1H), 4.29(E) 4.17(Z) 
                 429(15), 210(42), 168(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 2.34(s, 3H), 1.21(d, 6H) 
                 140(53), 133(41) 
               
               
                 144 
                 3-Cl—C 6 H 4   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.51˜6.90(m, 8H), 5.03˜4.83(m, 1H), 4.30(E) 4.16(Z) 
                 433(45), 210(42), 168(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.08(d, 6H) 
                 140(80), 133(52) 
               
               
                 145 
                 3-Cl—C 6 H 4   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.69˜6.95(m, 8H), 5.09˜4.85(m, 1H), 4.31(E) 4.18(Z) 
                 449(35), 168(100), 140(60), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.10(d, 6H) 
                 45(8H) 
               
               
                 146 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 4   
                 C 6 H 5   
                 L 
                 7.45˜6.92(m, 1), 5.00˜4.77(m, 1H), 4.32(E) 4.19(Z) 
                 433(56), 193(54), 168(65), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.29(d, 3H), 1.03(d, 3H) 
                 151(100), 45(46) 
               
               
                 147 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.34˜6.98(m, 7H), 5.00˜4.77(m, 1H), 4.32(E) 4.17(Z) 
                 447(35), 186(33), 84(100), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.32(s, 3H), 1.27(d, 3H), 1.01(d, 3H) 
                 45(49) 
               
               
                 148 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.41˜6.99(m, 7H), 5.01˜4.76(m, 1H), 4.30(E) 4.16(Z) 
                 447(55), 193(67), 186(78), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.33(s, 3H), 1.26(d, 3H), 1.04(d, 3H) 
                 151(100), 45(35) 
               
               
                 149 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.35˜6.97(m, 6H), 5.01˜4.78(m,1H), 4.30(E) 4.19(Z) 
                 461(56), 193(66), 186(88), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.33(s, 6H), 1.26(d, 3H), 1.02(d, 3H) 
                 151(100), 45(49) 
               
               
                 150 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 70˜71 
                 7.38˜6.82(m, 6H), 5.00˜4.76(m, 1H), 4.31(E) 4.16(Z) 
                 461(31), 193(64), 186(85), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 2.30(s, 6H), 1.27(d, 3H), 1.00(d, 3H) 
                 151(100), 45(54) 
               
               
                 151 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 3-F—C 6 H 4   
                 L 
                 7.40˜6.95(m, 7H), 5.00˜4.79(m, 1H), 4.31(E) 4.17(Z) 
                 451(40), 193(61), 186(66), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.27(d, 3H), 1.03(d, 3H) 
                 151(100), 45(48) 
               
               
                 152 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.47˜6.94(m, 7H), 5.00˜4.78(m, 1H), 4.32(E) 4.16(Z) 
                 451(22), 193(52), 186(73), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.26(d, 3H), 1.02(d, 3H) 
                 151(100), 45(53) 
               
               
                 153 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.45˜6.98(m, 7H), 5.00˜4.79(m, 1H), 4.32(E) 4.16(Z) 
                 467(39), 193(69), 186(74), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.28(d, 3H), 1.04(d, 3H) 
                 151(100), 45(53) 
               
               
                 154 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 4-Cl—C 6 H 4   
                 L 
                 7.44˜6.98(m, 7H), 4.98˜4.75(m, 1H), 4.30(E) 4.17(Z) 
                 467(35), 193(71), 186(72), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.27(d, 3H), 1.03(d, 3H) 
                 151(100), 45(60) 
               
               
                 155 
                 2-Cl-4-F—C 6 H 3   
                 i-C 3 H 7   
                 3,5-Cl 2 —C 6 H 3   
                 L 
                 7.45˜7.01(m, 6H), 5.00˜4.78(m, 1H), 4.32(E) 4.15(Z) 
                 501(41), 193(87), 186(76), 
               
               
                   
                   
                   
                   
                   
                 (dd, 2H), 1.27(d, 3H), 1.03(d, 3H) 
                 151(100), 45(68) 
               
               
                 156 
                 3,4-Cl 2 —C 6 H 3   
                 i-C 3 H 7   
                 C 6 H 3   
                 96˜97 
                 7.60˜6.87(m, 8H), 5.04˜4.84(m, 1H), 4.30(E) 4.15(Z) 
                 449(30), 244,(31), 202(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.07(d, 6H) 
                 167(83), 45(65) 
               
               
                 157 
                 3,4-Cl 2 —C 6 H 3   
                 i-C 3 H 7   
                 3-F—C 6 H 4   
                 74˜75 
                 7.61˜6.95(m, 7H), 5.05˜4.85(m, 1H), 4.29(E) 4.14(Z) 
                 467(36), 244(28), 202(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.12(d, 6H) 
                 174(51), 167(82), 45(68) 
               
               
                 158 
                 3,4-Cl 2 —C 6 H 3   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 L 
                 7.59˜6.87(m, 7H), 5.03˜4.84(m, 1H), 4.30(E) 4.16(Z) 
                 467(20), 202(98), 167(100) 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.09(d, 6H) 
               
               
                 159 
                 3,4-Cl 2 —C 6 H 3   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 L 
                 7.60˜6.92(m, 7H), 5.02˜4.82(m, 1H), 4.31(E) 4.15(Z) 
                 483(42), 244(65), 204(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.08(d, 6H) 
                 167(72) 
               
               
                 160 
                 3,4-Cl 2 —C 6 H 3   
                 i-C 3 H 7   
                 4-Cl—C 6 H 4   
                 44˜45 
                 7.70˜6.90(m, 7H), 5.02˜4.85(m, 1H), 4.30(E) 4.15(Z) 
                 483(12), 244(39), 202(100), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.07(d, 6H) 
                 167(54), 45(48) 
               
               
                 161 
                 3,4-Cl 2 —C 6 H 3   
                 i-C 3 H 7   
                 3,5-Cl 2 —C 6 H 3   
                 80˜81 
                 7.61˜6.95(m, 6H), 5.05˜4.86(m, 1H), 4.28(E) 4.14(Z) 
                 517(8), 202(99), 167(89), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 1.09(d, 6H) 
                 45(100) 
               
               
                 162 
                 3-CH 3 —C 6 H 4   
                 CH 3   
                 C 5 H 5   
                 L 
                 7.45˜6.90(m, 9H), 4.41(s, 2H), 3.27(s, 3H), 2.36(s, 3H) 
                 367(15), 162(100), 147(34), 
               
               
                   
                   
                   
                   
                   
                   
                 91(32) 
               
               
                 163 
                 3-CH 3 —C 6 H 4   
                 CH 3   
                 4-CH 3 —C 6 H 4   
                 54 
                 7.32˜6.90(m, 8H), 4.39(s, 2H), 3.26(s, 3H), 2.36(s, 3H), 
                 381(13), 162(100), 147(37), 
               
               
                   
                   
                   
                   
                   
                 2.34(s, 3H) 
                 91(34) 
               
               
                 164 
                 3-CH 3 —C 6 H 4   
                 CH 3   
                 4-CH 3 O—C 6 H 4   
                 69 
                 7.48˜6.79(m, 8H), 4.43(s, 2H), 3.82(s, 3H), 3.48(s, 3H), 
                 397(15), 162(100), 134(42), 
               
               
                   
                   
                   
                   
                   
                 2.64(s, 3H) 
                 91(42), 43(39) 
               
               
                 165 
                 3-CH 3 —C 6 H 4   
                 CH 3   
                 4-F—C 6 H 4   
                 L 
                 7.44˜6.93(m, 8H), 4.41(s, 2H), 3.27(s, 3H), 2.38(s, 3H) 
                 385(16), 162(100), 147(60), 
               
               
                   
                   
                   
                   
                   
                   
                 134(74), 91(65) 
               
               
                 166 
                 3-CH 3 —C 6 H 4   
                 CH 3   
                 3-CF 3 —C 6 H 4   
                 L 
                 7.82˜6.98(m, 8H), 4.49(s, 2H), 3.28(s, 3H), 3.39(s, 3H) 
                 435(25), 162(100), 147(69), 
               
               
                   
                   
                   
                   
                   
                   
                 134(64), 91(69) 
               
               
                 167 
                 3-CH 3 —C 6 H 4   
                 CH 3   
                 4-Cl—C 6 H 4   
                 L 
                 7.40˜6.97(m, 8H), 4.42(s, 2H), 3.28(s, 3H), 2.39(s, 3H) 
                 401(12), 162(100), 147(50), 
               
               
                   
                   
                   
                   
                   
                   
                 134(56), 91(48) 
               
               
                 168 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 C 6 H 4   
                 90 
                 7.44˜6.99(m, 9H), 4.40(s, 2H), 326(s, 3H), 2.38(s, 3H) 
                 367(15), 162(100), 147(48), 
               
               
                   
                   
                   
                   
                   
                   
                 134(46), 91(47) 
               
               
                 169 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.30˜6.99(m, 8H), 4.41(s, 2H), 3.27(s, 3H), 2.39(s, 3H), 
                 381(14), 162(100), 147(46), 
               
               
                   
                   
                   
                   
                   
                 2.36(s, 3H) 
                 134(36), 91(32) 
               
               
                 170 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 4-CH 3 —C 6 H 4   
                 108 
                 7.33˜6.99(m, 8H), 4.39(s, 2H), 3.28(s, 3H), 2.38(s, 3H), 
                 381(13), 162(100), 147(41), 
               
               
                   
                   
                   
                   
                   
                 2.35(s, 3H) 
                 134(36), 91(27) 
               
               
                 171 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 4-CH 3 O—C 6 H 4   
                 83 
                 7.36˜6.90(m, 8H), 4.38(s, 2H), 3.80(s, 3H), 3.28(s, 3H), 
                 397(25), 162(100), 147(42), 
               
               
                   
                   
                   
                   
                   
                 2.37(s, 3H) 
                 134(44), 91(43) 
               
               
                 172 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 4-F—C 6 H 4   
                 71 
                 7.44˜6.69(m, 8H), 3.27(s, 3H), 2.38(s, 3H) 
                 385(23), 162(100), 134(46), 
               
               
                   
                   
                   
                   
                   
                   
                 91(26) 
               
               
                 173 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 3-Cl—C 6 H 4   
                 L 
                 7.43˜7.02(m, 8H), 4.42(s, 2H), 3.27(s, 3H), 2.38(s, 3H) 
                 401(11), 162(100), 147(48), 
               
               
                   
                   
                   
                   
                   
                   
                 134(38), 91(36) 
               
               
                 174 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 3,5-Cl 2 —C 6 H 3   
                 L 
                 7.35˜7.04(m, 7H), 4.45(s, 2H), 3.28(s, 3H), 2.39(s, 3H) 
                 435(15), 162(100), 147(54), 
               
               
                   
                   
                   
                   
                   
                   
                 134(50) 
               
               
                 175 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 4-C 6 H 5 O—C 6 H 4   
                 80 
                 7.40˜6.94(m, 13H), 4.35(s, 2H), 3.27(s, 3H), 2.39(s, 3H) 
                 459(15), 162(100), 147(33), 
               
               
                   
                   
                   
                   
                   
                   
                 134(28) 
               
               
                 176 
                 4-CH 3 —C 6 H 4   
                 CH 3   
                 3,4-OCH 2 O—C 6 H 4   
                 68 
                 7.26˜6.77(m, 7H), 5.95(s, 2H), 4.40(s, 2H), 3.27(s, 3H), 
                 411(15), 162(100), 147(39), 
               
               
                   
                   
                   
                   
                   
                 2.38(s, 3H) 
                 134(32) 
               
               
                 177 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.45˜6.89(m, 8H), 4.42(s, 2H), 3.27(s, 3H), 2.28(s, 3H), 
                 381(13), 161(33), 86(72), 
               
               
                   
                   
                   
                   
                   
                 2.27(s, 3H) 
                 84(100) 
               
               
                 178 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 4-C 2 H 5 —C 6 H 4   
                 L 
                 7.34˜6.90(m, 7H), 4.41(s, 2H), 3.25(s, 3H), 2.30(s, 3H), 
                 395(12), 176(100), 161(96), 
               
               
                   
                   
                   
                   
                   
                 2.28(s, 3H), 2.26(s, 3H) 
                 43(49) 
               
               
                 179 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.24˜6.86(m, 6H), 4.37(s, 2H), 3.22(s, 3H), 2.28(s, 6H), 
                 409(19), 176(100), 161(65) 
               
               
                   
                   
                   
                   
                   
                 2.25(s, 3H), 2.31(s, 3H) 
               
               
                 180 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 4-C 2 H 5 —C 6 H 4   
                 L 
                 7.37˜6.88(m, 7H), 4.41(s, 2H), 3.26(s, 3H), 2.65(q, 2H), 
                 409(24), 176(100), 161(58) 
               
               
                   
                   
                   
                   
                   
                 2.30(s, 3H), 2.28(s, 3H), 1.26(t, 3H) 
               
               
                 181 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 4-F—C 6 H 4   
                 L 
                 7.43˜6.83(m, 7H), 4.41(s, 2H), 3.25(s, 3H), 2.26(s, 6H) 
                 399(18), 176(100), 161(99), 
               
               
                   
                   
                   
                   
                   
                   
                 132(22) 
               
               
                 182 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 4-CF 3 —C 6 H 4   
                 L 
                 7.69˜6.86(m, 7H), 4.39(s, 2H), 3.27(s, 3H), 2.89(s, 3H), 
                 449(61), 176(100), 161(84) 
               
               
                   
                   
                   
                   
                   
                 2.27(s, 3H) 
               
               
                 183 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 3-Cl—C 6 H 4   
                 L 
                 7.32˜6.81(m, 7H), 4.42(s, 2H), 3.26(s, 3H), 2.29(s, 3H), 
                 415(12), 176(97), 161(100), 
               
               
                   
                   
                   
                   
                   
                 2.28(s, 3H) 
                 84(42) 
               
               
                 184 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 CH 3   
                 4-C 6 H 5 O—C 6 H 4   
                 L 
                 7.40˜6.85(m, 12H), 4.42(s, 2H), 3.26(s, 3H), 2.28(s, 3H), 
                 473(25), 176(100), 161(76) 
               
               
                   
                   
                   
                   
                   
                 2.27(s, 3H) 
               
               
                 185 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 i-C 3 H 7   
                 C 6 H 5   
                 65 
                 7.46˜6.78(m, 8H), 4.96(m, 1H), 4.30(s, 2H), 2.31(s, 3H), 
                 409(36), 204(41), 162(100), 
               
               
                   
                   
                   
                   
                   
                 2.29(s, 3H), 1.06(d, 6H) 
                 134(40) 
               
               
                 186 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.27˜6.77(m, 7H), 4.95(m, 1H), 4.24(s, 2H), 2.35(s, 3H), 
                 423(48), 204(51), 162(100), 
               
               
                   
                   
                   
                   
                   
                 2.29(s, 3H), 2.27(s, 3H), 1.05(d, 6H) 
                 134(33) 
               
               
                 187 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 i-C 3 H 7   
                 4-F—C 6 H 4   
                 52 
                 7.45˜6.78(m, 7H), 4.93(m, 1H), 4.25(s, 2H), 2.28(s, 3H), 
                 427(14), 204(37), 162(100), 
               
               
                   
                   
                   
                   
                   
                 2.26(s, 3H), 1.06(d, 6H) 
                 134(34) 
               
               
                 188 
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 i-C 3 H 7   
                 3-Cl—C 6 H 4   
                 58 
                 7.43˜6.79(m, 7H), 4.94(m, 1H), 4.26(s, 2H), 2.29(s, 3H), 
                 443(18), 204(33), 162(100), 
               
               
                   
                   
                   
                   
                   
                 2.27(s, 3H), 1.06(d, 6H) 
                 134(35) 
               
               
                 189 
                 4-CH 3 O—C 6 H 4   
                 CH 3   
                 4-F—C 6 H 4   
                 L 
                 7.44˜6.90(m, 8H), 4.39(s, 2H), 3.82(s, 3H), 3.25(s, 3H) 
                 401(18), 178(100), 147(66), 
               
               
                   
                   
                   
                   
                   
                   
                 121(53) 
               
               
                 190 
                 3-Cl—C 6 H 4   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.42˜7.03(m, 9H), 4.41(s, 2H), 3.29(s, 3H) 
                 387(14), 182(51), 147(100), 
               
               
                   
                   
                   
                   
                   
                   
                 118(20) 
               
               
                 191 
                 3-Cl—C 6 H 4   
                 CH 3   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.43˜7.16(m, 8H), 4.34(s, 2H), 3.27(s, 3H), 2.35(s, 3H) 
                 401(14), 182(47), 147(100), 
               
               
                   
                   
                   
                   
                   
                   
                 118(20) 
               
               
                 192 
                 3-Cl—C 6 H 4   
                 CH 3   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.41˜7.01(m, 7H), 4.39(s, 2H), 3.27(s, 3H), 2.25(s, 6H) 
                 415(17), 182(64), 147(100) 
               
               
                 193 
                 3-Cl—C 6 H 4   
                 CH 3   
                 4-C 2 H 5 —C 6 H 4   
                 L 
                 7.42˜7.02(m, 8H), 4.40(s, 2H), 3.26(s, 3H), 2.64(q, 2H), 
                 415(21), 182(99), 147(100) 
               
               
                   
                   
                   
                   
                   
                 1.26(t, 3H) 
               
               
                 194 
                 3-Cl—C 6 H 4   
                 CH 3   
                 4-t-C 4 H 9 —C 6 H 4   
                 L 
                 7.42˜7.02(m, 8H), 4.41(s, 2H), 3.28(s, 3H), 1.31(s, 9H) 
                 443(18), 182(72), 147(100) 
               
               
                 195 
                 3-Cl—C 6 H 4   
                 CH 3   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.43˜6.87(m, 8H), 4.40(s, 2H), 3.81(s, 3H), 3.29(s, 3H) 
                 417(15), 182(52), 147(100), 
               
               
                   
                   
                   
                   
                   
                   
                 78(19) 
               
               
                 196 
                 3-Cl—C 6 H 4   
                 CH 3   
                 3-F—C 6 H 4   
                 L 
                 7.43˜7.02(m, 8H), 4.44(s, 2H), 3.30(s, 3H) 
                 405(17), 182(38), 147(100) 
               
               
                 197 
                 3-Cl—C 6 H 4   
                 CH 3   
                 4-F—C 6 H 4   
                 L 
                 7.43˜7.00(m, 8H), 4.36(s, 2H), 3.29(s, 3H) 
                 405(30), 147(46), 85(60), 
               
               
                   
                   
                   
                   
                   
                   
                 84(100), 43(51) 
               
               
                 198 
                 3-Cl—C 6 H 4   
                 CH 3   
                 4-Cl—C 6 H 4   
                 L 
                 7.42˜7.06(m, 8H), 4.43(s, 2H), 3.28(s, 3H) 
                 421(13), 182(40), 147(100), 
               
               
                   
                   
                   
                   
                   
                   
                 43(26) 
               
               
                 199 
                 4-Cl—C 6 H 4   
                 CH 3   
                 C 6 H 5   
                 95 
                 7.46˜7.09(m, 9H), 4.39(s, 2H), 3.29(s, 3H) 
                 387(10), 181(28), 147(100) 
               
               
                 200 
                 4-Cl—C 6 H 4   
                 CH 3   
                 3-CH 3 —C 6 H 4   
                 74 
                 7.47˜7.05(m, 8H), 4.39(s, 2H), 3.25(s, 3H), 2.35(s, 3H) 
                 401(19), 182(48), 147(100) 
               
               
                 201 
                 4-Cl—C 6 H 4   
                 CH 3   
                 4-CH 3 —C 6 H 4   
                 99 
                 7.48˜7.06(m, 8H), 4.38(s, 2H), 3.26(s, 3H), 2.34(s, 3H) 
                 401(18), 147(71), 84(100), 
               
               
                   
                   
                   
                   
                   
                   
                 47(83) 
               
               
                 202 
                 4-Cl—C 6 H 4   
                 CH 3   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 76 
                 7.43˜7.02(m, 7H), 4.35(s, 2H), 3.24(s, 3H), 2.22(s, 6H) 
                 415(15), 182(59), 147(100) 
               
               
                 203 
                 4-Cl—C 6 H 4   
                 CH 3   
                 4-C 2 H 5 —C 6 H 4   
                 85 
                 7.46˜7.04(m, 8H), 4.38(s, 2H), 3.25(s, 3H), 2.64(q, 2H), 
                 415(14), 182(47), 147(100), 
               
               
                   
                   
                   
                   
                   
                 1.22(t, 3H) 
                 118(24) 
               
               
                 204 
                 4-Cl—C 6 H 4   
                 CH 3   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.43˜6.85(m, 8H), 4.40(s, 2H), 3.81(s, 3H), 3.26(s, 3H) 
                 417(19), 182(23), 147(100) 
               
               
                 205 
                 4-Cl—C 6 H 4   
                 CH 3   
                 4-CH 3 O—C 6 H 4   
                 90 
                 7.43˜6.86(m, 8H), 4.31(s, 2H), 3.80(s, 3H), 3.26(s, 3H) 
                 417(16), 182(47), 147(100) 
               
               
                 206 
                 4-Cl—C 6 H 4   
                 CH 3   
                 3-F—C 6 H 4   
                 L 
                 7.47˜7.01(m, 8H), 4.42(s, 2H), 3.28(s, 3H) 
                 405(17), 182(42), 147(100) 
               
               
                 207 
                 4-Cl—C 6 H 4   
                 CH 3   
                 4-F—C 6 H 4   
                 72 
                 7.48˜7.00(m, 8H), 4.40(s, 2H), 3.26(s, 3H) 
                 405(18), 182(77), 147(100) 
               
               
                 208 
                 4-Cl—C 6 H 4   
                 CH 3   
                 3-Cl—C 6 H 4   
                 L 
                 7.47˜7.09(m, 8H), 4.41(s, 2H), 3.27(s, 3H) 
                 421(15), 182(45), 147(100) 
               
               
                 209 
                 4-Cl—C 6 H 4   
                 CH 3   
                 4-Cl—C 6 H 4   
                 66 
                 7.47˜7.09(m, 8H), 4.41(s, 2H), 3.28(s, 3H) 
                 421(18), 182(29), 147(100), 
               
               
                   
                   
                   
                   
                   
                   
                 118(29) 
               
               
                 210 
                 4-Cl—C 6 H 4   
                 CH 3   
                 thiophene-2-yl 
                 L 
                 7.47˜6.99(m, 7H), 4.45(s, 2H), 3.28(s, 3H) 
                 393(24), 182(62), 147(100) 
               
               
                 211 
                 C 6 H 5   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.51˜7.04(m, 10H), 4.32(s, 2H), 3.28(s, 3H) 
                 403(23), 147(100), 120(94), 
               
               
                   
                   
                   
                   
                   
                   
                 91(40) 
               
               
                 212 
                 C 6 H 5   
                 C 2 H 5   
                 C 6 H 5   
                 L 
                 7.49˜7.01(m, 10H), 4.28(s, 2H), 3.75(q, 2H), 1.10(t, 3H) 
                 417(24), 162(100), 134(94), 
               
               
                   
                   
                   
                   
                   
                   
                 106(71), 91(62), 77(57) 
               
               
                 213 
                 C 6 H 5   
                 n-C 3 H 7   
                 C 6 H 5   
                 L 
                 7.50˜7.02(m, 10H), 4.21(s, 2H), 3.67(t, 2H), 167˜1.45 
                 431(63), 180(65), 133(60), 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 0.91(t, 3H) 
                 106(100) 
               
               
                 214 
                 C 6 H 5   
                 i-C 3 H 7   
                 C 6 H 5   
                 L 
                 7.51˜7.00(m, 10H), 4.98(m, 1H), 4.10(s, 2H), 1.09(d, 6H) 
                 431(24), 176(62), 133(100), 
               
               
                   
                   
                   
                   
                   
                   
                 120(49) 
               
               
                 215 
                 4-CH 3 O—C 6 H 4   
                 C 2 H 5   
                 C 6 H 5   
                 L 
                 7.46˜6.84(m, 9H), 4.19(s, 2H), 3.81(s, 3H), 3.71(q, 2H), 
                 447(55), 324(53), 239(52), 
               
               
                   
                   
                   
                   
                   
                 1.11(t, 3H) 
                 149(100), 135(55), 120(41) 
               
               
                 216 
                 4-CH 3 O—C 6 H 4   
                 n-C 3 H 7   
                 C 6 H 5   
                 L 
                 7.47˜6.87(m, 9H), 4.26(s, 2H), 3.82(s, 3H), 3.65(t, 2H), 
                 461(43), 206(100), 136(37), 
               
               
                   
                   
                   
                   
                   
                 1.67˜1.45(m, 2H), 0.90(t, 3H) 
                 121(54) 
               
               
                 217 
                 3-CF 3 —C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 5   
                 L 
                 7.76˜7.16(m, 9H), 4.94(m, 1H), 4.08(s, 2H), 1.08(d, 6H) 
                 499(50), 244(46), 202(100), 
               
               
                   
                   
                   
                   
                   
                   
                 174(66), 145(26), 43(74) 
               
               
                 218 
                 4-F—C 6 H 4   
                 i-C 3 H 7   
                 C 6 H 5   
                 L 
                 7.46˜6.97(m, 9H), 4.97(m, 1H), 4.15(s, 2H), 1.02(d, 6H) 
                 449(21), 194(33), 152(100), 
               
               
                   
                   
                   
                   
                   
                   
                 124(45) 
               
               
                 219 
                 4-Cl—C 6 H 4   
                 C 2 H 5   
                 C 6 H 5   
                 L 
                 7.49˜7.01(m, 9H), 4.20(s, 2H), 3.74(q, 2H), 1.10(t, 3H) 
                 451(57), 324(47), 219(52), 
               
               
                   
                   
                   
                   
                   
                   
                 182(78), 154(100), 139(42) 
               
               
                 220 
                 2,4-Cl 2 —C 6 H 4   
                 CH 3   
                 C 6 H 5   
                 L 
                 7.54˜7.01(m, 8H), 4.20(s, 2H), 3.21(s, 3H) 
                 471(41), 436(73), 181(100) 
               
               
                   
               
             
          
         
       
     
     EXAMPLE 221 
     Preparation of N-2-(2′-Fluoro-1′-trifluoromethylstyryl-2′-oxy)acetylpiperidine (Compound 221) 
     The procedure of Example 1 was repeated except that 286 mg(2 mmol) of N-2-hydroxyacetylpiperidine obtained in Preparation 32 and 2,2-difluoro-1-trifluoromethyl styrene obtained in Preparation 56 were used and that silica gel column chromatography was conducted using a mixture of n-hexane and ethyl acetate(2:1) as an eluent to obtain 600 mg(yield 90.6%) of the title compound as a white solid. 
       1 H-NMR (CDCl 3 , TMS) δ: 7.58-7.17(m, 5H), 4.79(E isomer) 4.67(Z isomer)(s, 2H), 3.17-3.05(m, 4H), 1.78-1.35(m, 6H); MS (m/e): 331(M + , 40), 126(85), 98(76), 84(100);  19 F-NMR (CDCl 3 , CFCl 3 ) δ: −57.38(Z isomer) −57.83(E isomer)(d,3F), −82.24(E isomer) −84.28(Z isomer)(q, 1F); m.p.: 78-79° C. 
     EXAMPLES 222 to 294 
     Using each of the alcoholic compounds obtained in Preparations 32 to 48 and each of the fluorovinyl compounds obtained in Preparations 49 to 56 and 58 to 65, the procedure of Example 221 was repeated to obtain 73 compounds(Compounds 222 to 294) of formula (I) of the present invention having various R 1 , R 2  and R 3  groups listed in Table 5. The  1 H-NMR and MS data and melting points of these compounds are also shown in Table 5. L in Table 5 represents liquid. 
     
       
         
               
               
             
               
               
               
               
               
               
               
             
           
               
                 TABLE 5 
               
             
             
               
                   
               
               
                   
                 (I) 
               
               
                 
                   
                             
                     
                         
                         
                     
                   
                 
               
               
                 R 4  = CF 3   
               
               
                   
               
             
          
           
               
                 Comp. No. 
                 R 1   
                 R 2   
                 R 3   
                 state (° C.) 
                 NMR (CDCl 3 , TMS) δ (ppm) 
                 MS (m/e) 
               
               
                   
               
               
                 221 
                 —(CH 2 ) 5 — 
                   
                 C 6 H 5   
                 78˜79 
                 7.58˜7.17(m, 5H), 4.79(E) 4.67(Z) (s, 2H), 3.71˜3.05 
                 331(40), 126(85), 98(76), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.78˜1.35(m, 6H) 
                 84(100) 
               
               
                 222 
                 —(CH 2 ) 5 — 
                   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.31˜7.04(m, 4H), 4.78(E) 4.66(Z) (s, 2H), 3.64˜3.03 
                 345(26), 126(71), 98(70), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.37(s, 3H), 1.74˜1.38(m, 6H) 
                 84(100) 
               
               
                 223 
                 —(CH 2 ) 5 — 
                   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.43˜7.02(m, 4H), 4.79(E) 4.67(Z) (s, 2H), 3.64˜3.01 
                 345(23), 326(18), 126(34), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.43(s, 3H), 1.98˜1.17(m, 6H) 
                 98(100), 84(94) 
               
               
                 224 
                 —(CH 2 ) 5 — 
                   
                 4-C 2 H 5 —C 6 H 4   
                 L 
                 7.41˜7.13(m, 4H), 4.77(E) 4.68(Z) (s, 2H), 3.61˜3.06 
                 359(11), 126(100), 98(51), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.64(q, 2H), 1.72˜1.38(m, 6H), 1.25(t, 3H) 
                 84(61) 
               
               
                 225 
                 —(CH 2 ) 5 — 
                   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.21˜7.00(m, 3H), 4.79(E) 4.67(Z) (s, 2H), 3.60˜3.04 
                 359(36), 126(85), 98(41), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.23(s, 6H), 1.70˜1.37(m, 6H) 
                 84(100), 42(30) 
               
               
                 226 
                 —(CH 2 ) 5 — 
                   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.03˜6.87(m, 3H), 4.78(E) 4.66(Z) (s, 2H), 3.59˜3.01 
                 359(40), 126(55), 98(63), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.26(s, 6H), 1.69˜1.34(m, 6H) 
                 84(100), 42(57) 
               
               
                 227 
                 —(CH 2 ) 5 — 
                   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.48˜6.72(m, 4H), 4.78(E) 4.66(Z) (s, 2H), 3.82(s, 3H), 
                 361(23), 126(33), 98(83), 
               
               
                   
                   
                   
                   
                   
                 3.78˜2.98(m, 4H), 1.82˜1.43(m, 6H) 
                 84(100) 
               
               
                 228 
                 —(CH 2 ) 5 — 
                   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.52˜6.75(m, 4H), 4.79(E) 4.66(Z) (s, 2H), 3.84(s, 3H), 
                 361(50), 157(44), 126(100) 
               
               
                   
                   
                   
                   
                   
                 3.78˜3.01(m, 4H), 1.84˜1.36(m, 6H) 
                 98(92), 84(78), 55(69) 
               
               
                 229 
                 —(CH 2 ) 5 — 
                   
                 3,4-OCH 2 O—C 6 H 3   
                 L 
                 6.94˜6.75(m, 3H), 5.94(s, 2H), 4.78(E) 4.65(Z) (s, 2H), 
                 375(50), 126(53), 98(60), 
               
               
                   
                   
                   
                   
                   
                 3.63˜3.00(m, 4H), 1.70˜1.44(m, 6H) 
                 84(100), 43(90) 
               
               
                 230 
                 —(CH 2 ) 5 — 
                   
                 3-CF 3 —C 6 H 4   
                 L 
                 7.72˜7.32(m, 4H), 4.79(E) 4.65(Z) (s, 2H), 3.74˜3.02 
                 399(87), 212(47), 127(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.97˜1.18(m, 6H) 
               
               
                 231 
                 —(CH 2 ) 5 — 
                   
                 3-F—C 6 H 4   
                 L 
                 7.62˜6.89(m, 4H), 4.80(E) 4.68(Z) (s, 2H), 3.75˜3.04 
                 349(47), 126(64), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.78˜0.94(m, 6H) 
                 84(78) 
               
               
                 232 
                 —(CH 2 ) 5 — 
                   
                 4-F—C 6 H 4   
                 L 
                 7.51˜6.95(m, 4H), 4.79(E) 4.67(Z) (s, 2H), 3.62˜3.12 
                 349(60), 126(66), 98(56), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.73˜1.45(m, 6H) 
                 84(100), 42(55) 
               
               
                 233 
                 —(CH 2 ) 5 — 
                   
                 3-Cl—C 6 H 4   
                 L 
                 7.49˜7.17(m, 4H), 4.80(E) 4.67(Z) (s, 2H), 3.61˜3.07 
                 365(35), 126(32), 98(20), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.72˜1.42(m, 6H) 
                 84(100), 42(38) 
               
               
                 234 
                 —(CH 2 ) 5 — 
                   
                 4-Cl—C 6 H 4   
                 L 
                 7.78˜7.34(m, 4H), 4.79(E) 4.66(Z) (s, 2H), 3.85˜3.02 
                 365(20), 126(57), 98(41), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.83˜1.42(m, 6H) 
                 84(100), 45(69) 
               
               
                 235 
                 —(CH 2 ) 5 — 
                   
                 3,5-Cl 2 —C 6 H 3   
                 54˜55 
                 7.39˜7.15(m, 3H), 4.81(E) 4.70(Z) (s, 2H), 3.60˜3.08 
                 399(41), 126(60), 98(42), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.78˜1.36(m, 6H) 
                 84(100) 
               
               
                 236 
                 —(CH 2 ) 5 — 
                   
                 C 4 H 3 S-2-yl 
                 L 
                 7.47˜6.94(m, 3H), 4.80(E) 4.70(Z) (s, 2H), 3.82˜3.07 
                 337(10), 126(100), 98(74), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.81˜1.42(m, 6H) 
                 84(80) 
               
               
                 237 
                 —CH(CH 3 ) (CH 2 ) 4 — 
                   
                 C 6 H 5   
                 L 
                 7.63˜7.18(m, 5H), 4.83(E) 4.74(Z) (s, 2H), 3.25˜2.76 
                 345(46), 140(52), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.95˜1.48(m, 6H), 126(d, 3H) 
                 84(46), 55(63) 
               
               
                 238 
                 —CH(CH 3 ) (CH 2 ) 4 — 
                   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.44˜6.92(m, 4H), 4.82(E) 4.75(Z) (s, 2H), 3.18˜2.72 
                 359(65), 242(40), 98(78), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 2.35(s, 3H), 1.95˜1.46(m, 6H), 1.29(d, 3H) 
                 84(92), 56(100) 
               
               
                 239 
                 —CH(CH 3 ) (CH 2 ) 4 — 
                   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.44˜7.03(m, 4H), 4.80(E) 4.74(Z) (s, 2H), 3.82˜2.45 
                 359(15), 140(66), 98(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 2.42(s, 3H), 1.86˜1.42(m, 6H), 1.12(d, 3H) 
               
               
                 240 
                 —CH(CH 3 ) (CH 2 ) 4 — 
                   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.31˜7.03(m, 3H), 4.81(E) 4.74(Z) (s, 2H), 3.24˜2.75 
                 373(30), 140(86), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 2.28(s, 6H), 1.96˜1.45(m, 6H), 1.28(d, 3H) 
                 55(75) 
               
               
                 241 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.28˜6.83(m, 3H), 4.80(E) 4.75(Z) (s, 2H), 3.25˜2.74 
                 373(24), 140(89), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 2.29(s, 6H), 1.96˜1.44(m, 6H), 1.26(d, 3H) 
                 55(76) 
               
               
                 242 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 4-C 2 H 5 —C 6 H 4   
                 L 
                 7.52˜7.05(m, 4H), 4.81(E) 4.76(Z) (s, 2H), 3.24˜2.85 
                 373(45), 140(43), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 2.71(q, 2H), 1.95˜1.45(m, 6H), 1.28(t, 3H), 
                 55(43) 
               
               
                   
                   
                   
                   
                   
                 1.15(d, 3H) 
               
               
                 243 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.47˜6.74(m, 4H), 4.79(E) 4.74(Z) (s, 2H), 3.78(s, 3H), 
                 375(20), 140(97), 98(100), 
               
               
                   
                   
                   
                   
                   
                 3.24˜2.73(m, 3H), 1.95˜1.43(m, 6H), 1.24(d, 3H) 
                 55(84) 
               
               
                 244 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.54˜6.79(m, 4H), 4.80(E) 4.76(Z) (s, 2H), 3.87(s, 3H), 
                 375(20), 140(56), 98(100), 
               
               
                   
                   
                   
                   
                   
                 3.22˜2.91(m, 3H), 1.97˜1.48(m, 6H), 1.33(d, 3H) 
                 56(32) 
               
               
                 245 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 3,4-OCH 2 O—C 6 H 3   
                 L 
                 7.20˜6.62(m, 3H), 6.01(s, 2H), 4.79(E) 4.75(Z) (s, 2H), 
                 389(19), 219(40), 140(87), 
               
               
                   
                   
                   
                   
                   
                 3.23˜2.74(m, 3H), 1.97˜1.49(m, 6H), 1.29(d, 3H) 
                 112(74), 98(100), 55(77) 
               
               
                 246 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 3-CF 3 —C 6 H 4   
                 L 
                 7.76˜7.37(m, 4H), 4.78(E) 4.73(Z) (s, 2H), 3.25˜2.72 
                 413(51), 140(29), 98(62), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.96˜1.42(m, 6H), 1.23(d, 3H) 
                 84(69), 43(100) 
               
               
                 247 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 3-F—C 6 H 4   
                 L 
                 7.53˜6.78(m, 4H), 4.79(E) 4.74(Z) (s, 2H), 3.24˜2.75 
                 363(38), 140(38), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.96˜1.46(m, 6H), 1.25(d, 3H) 
                 55(45) 
               
               
                 248 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 4-F—C 6 H 4   
                 L 
                 7.65˜6.82(m, 4H), 4.81(E) 4.75(Z) (s, 2H), 3.28˜2.65 
                 363(50), 140(78), 112(46), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.95˜1.34(m, 6H), 1.16(d, 3H) 
                 98(100), 55(57) 
               
               
                 249 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 3-Cl—C 6 H 4   
                 L 
                 7.58˜7.28(m, 4H), 4.80(E) 4.75(Z) (s, 2H), 3.21˜2.94 
                 379(72), 140(44), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.98˜1.49(m, 6H), 1.32(d, 3H) 
                 56(57) 
               
               
                 250 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 4-Cl—C 6 H 4   
                 L 
                 7.57˜7.18(m, 4H), 4.81(E) 4.74(Z) (s, 2H), 3.18˜2.74 
                 379(35), 140(70), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.75˜1.35(m, 6H), 1.15(d, 3H) 
                 55(47) 
               
               
                 251 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 3,5-Cl 2 —C 5 H 3   
                 L 
                 7.64˜7.18(m, 3H), 4.80(E) 4.75(Z) (s, 2H), 3.24˜2.75 
                 413(35), 140(49), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.95˜1.44(m, 6H), 1.23(d, 3H) 
                 55(57) 
               
               
                 252 
                 —CH(CH 3 )(CH 2 ) 4 — 
                   
                 C 4 H 3 S-2-yl 
                 L 
                 7.45˜6.91(m, 3H), 4.79(E) 4.74(Z) (s, 2H), 3.26˜2.73 
                 351(20), 140(65), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.97˜1.41(m, 6H), 1.24(d, 3H) 
                 55(66), 41(47) 
               
               
                 253 
                 —CH(C 2 H 5 )(CH 2 ) 4 — 
                   
                 C 6 H 5   
                 L 
                 7.48˜7.22(m, 5H), 4.80(E) 4.75(Z) (s, 2H), 3.58˜2.62 
                 359(18), 154(100), 126(58), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 1.81˜1.21(m, 8H), 0.83(t, 3H) 
                 112(98) 
               
               
                 254 
                 —CH(C 2 H 5 )(CH 2 ) 4 — 
                   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.43˜7.02(m, 4H), 4.81(E) 4.76(Z) (s, 2H), 4.01˜2.52 
                 373(30), 354(15), 154(43), 
               
               
                   
                   
                   
                   
                   
                 (m, 3H), 2.41(s, 3H), 1.98˜1.12(m, 8H), 0.92(t, 3H) 
                 112(100) 
               
               
                 255 
                 —CH(C 2 H 5 )(CH 2 ) 4 — 
                   
                 3-Cl—C 6 H 4   
                 L 
                 7.59˜7.15(m, 4H), 4.80(E) 4.75(Z) (s, 2H), 4.54˜3.91 
                 393(71), 154(41), 112(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 3.43˜3.12(m, 3H), 1.95˜1.23(m, 6H), 
                 97(38), 55(61) 
               
               
                   
                   
                   
                   
                   
                 1.04(t, 3H) 
               
               
                 256 
                 —CH(CH 3 )(CH 2 ) 3 CH(CH 3 )— 
                   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.49˜7.01(m, 4H), 4.80(E) 4.74(Z) (s, 2H), 4.54˜3.96 
                 373(49), 354(21), 217(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 2.42(s, 3H), 1.98˜1.51(m, 6H), 1.42(d, 6H) 
                 153(48), 69(21) 
               
               
                 257 
                 —CH(CH 3 )(CH 2 ) 3 CH(CH 3 )— 
                   
                 3-Cl—C 6 H 4   
                 58˜59 
                 7.62˜7.18(m, 4H), 4.81(E) 4.75(2) (s, 2H), 3.75˜2.76 
                 393(60), 154(30), 112(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 1.98˜1.48(m, 6H), 1.42(d, 6H) 
                 69(45), 55(62) 
               
               
                 258 
                 —CH(CH 3 )(CH 2 ) 3 CH(CH 3 )— 
                   
                 3,5-Cl 2 —C 6 H 3   
                 98˜99 
                 7.45˜7.21(m, 3H), 4.80(E) 4.76(Z) (s, 2H), 3.78˜3.54 
                 427(20), 154(60), 112(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 1.98˜1.47(m, 6H), 1.28(d, 6H) 
                 69(64), 55(80) 
               
               
                 259 
                 —(CH 2 ) 2 CH═CHCH 2 — 
                   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.51˜7.10(m, 4H), 5.92˜5.62(m, 2H), 4.81(E) 4.74(Z) 
                 343(10), 324(48), 124(74), 
               
               
                   
                   
                   
                   
                   
                 (s, 2H), 4.18˜3.32(m, 4H), 2.43(s 3H), 
                 96(42), 82(100) 
               
               
                   
                   
                   
                   
                   
                 2.42˜1.91(m, 2H) 
               
               
                 260 
                 —(CH 2 ) 2 O(CH 2 ) 2 — 
                   
                 C 6 H 5   
                 L 
                 7.42˜7.23(m, 5H), 4.80(E) 4.75(Z) (s, 2H), 3.72˜3.10 
                 333(10), 129(69), 102(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 8H) 
                 87(30) 
               
               
                 261 
                 —(CH 2 ) 2 O(CH 2 ) 2 — 
                   
                 4-CH 3 —C 6 H 4   
                 75˜76 
                 7.43˜7.02(m, 4H), 4.81(E) 4.76(Z) (s, 2H), 4.02˜3.10 
                 347(15), 128(48), 100(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 8H), 2.41(s, 3H) 
               
               
                 262 
                 —(CH 2 ) 3 C(C 6 H 4 )C— 
                   
                 C 6 H 5   
                 72˜73 
                 7.45˜7.10(m, 9H), 4.80(E) 4.74(Z) (s, 2H), 3.79(t, 2H), 
                 379(14), 360(15), 174(70), 
               
               
                   
                   
                   
                   
                   
                 2.70(t, 2H), 2.06˜1.87(m, 2H) 
                 146(70), 118(100) 
               
               
                 263 
                 —(CH 2 ) 3 C(C 4 H 4 )C— 
                   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.49˜7.02(m, 8H), 4.81(E) 4.76(Z) (s, 2H), 3.78(t, 2H), 
                 393(38), 374(28), 174(89), 
               
               
                   
                   
                   
                   
                   
                 2.71(t, 2H), 2.42(s, 3H), 2.05˜1.86(m, 2H) 
                 146(96), 118(100) 
               
               
                 264 
                 —(CH 2 ) 6 — 
                   
                 C 6 H 5   
                 L 
                 7.50˜7.25(m, 5H), 4.80(E) 4.75(Z) (s, 2H), 3.60˜3.10 
                 345(16), 147(100), 112(46) 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.81˜1.45(m, 8H) 
                 99(26) 
               
               
                 265 
                 —(CH 2 ) 6 — 
                   
                 3-CH 3 —C 6 H 4   
                 L 
                 7.38˜7.08(m, 4H), 4.81(E) 4.76(Z) (s, 2H), 3.60˜3.13 
                 359(15), 140(44), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.31(s, 3H), 1.78˜1.38(m, 8H) 
                 43(63) 
               
               
                 266 
                 —(CH 2 ) 6 — 
                   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.40˜7.10(m, 4H), 4.80(E), 4.75(Z) (s, 2H), 3.61˜3.17 
                 359(13), 140(56), 97(53), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.38(s, 3H), 1.81˜1.48(m, 8H) 
                 55(53), 43(100) 
               
               
                 267 
                 —(CH 2 ) 6 — 
                   
                 4-C 2 H 3 —C 6 H 4   
                 L 
                 7.40˜7.12(m, 4H), 4.81(E) 4.75(Z) (s, 2H), 3.60˜3.15 
                 373(23), 140(100), 98(54) 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.65(q, 2H), 1.85˜1.48(m, 8H), 1.26(t, 3H) 
               
               
                 268 
                 —(CH 2 ) 6 — 
                   
                 3,4-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.24˜7.02(m, 3H), 4.79(E) 4.74(Z) (s, 2H), 3.58˜3.11 
                 373(71), 140(51), 98(100) 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.32(s, 6H), 1.77˜1.41(m, 8H) 
               
               
                 269 
                 —(CH 2 ) 6 — 
                   
                 3,5-(CH 3 ) 2 —C 6 H 3   
                 L 
                 7.06˜6.91(m, 3H), 4.80(E) 4.75(Z) (s, 2H), 3.60˜3.12 
                 373(31), 140(39), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 2.30(s, 6H), 1.80˜1.44(m, 8H) 
                 42(39) 
               
               
                 270 
                 —(CH 2 ) 6 — 
                   
                 3-CH 3 O—C 6 H 3   
                 L 
                 7.29˜6.76(m, 4H), 4.80(E) 4.75(Z) (s, 2H), 3.74(s, 3H), 
                 375(53), 140(55), 98(100), 
               
               
                   
                   
                   
                   
                   
                 3.54˜3.10(m, 4H), 1.78˜1.42(m, 8H) 
                 43(56) 
               
               
                 271 
                 —(CH 2 ) 6 — 
                   
                 4-CH 3 O—C 6 H 4   
                 L 
                 7.38˜6.80(m, 4H), 4.79(E) 4.74(Z) (s, 2H), 3.76(s, 3H), 
                 375(21), 140(29), 98(44), 
               
               
                   
                   
                   
                   
                   
                 3.58˜3.12(m, 4H), 1.81˜1.46(m, 8H) 
                 59(38), 43(100) 
               
               
                 272 
                 —(CH 2 ) 6 — 
                   
                 3,4-OCH 2 O—C 6 H 3   
                 L 
                 7.15˜6.78(m, 3H), 5.97(s, 2H), 4.80(E) 4.75(Z) (s, 2H), 
                 389(13), 140(70), 98(100) 
               
               
                   
                   
                   
                   
                   
                 3.75˜3.14(m, 4H), 1.98˜1.32(m, 8H) 
               
               
                 273 
                 —(CH 2 ) 6 — 
                   
                 3-F—C 6 H 4   
                 L 
                 7.40˜6.98(m, 4H), 4.79(E) 4.74(Z) (s, 2H), 3.61˜3.16 
                 363(51), 140(42), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.81˜1.48(m, 8H) 
                 55(54), 42(65) 
               
               
                 274 
                 —(CH 2 ) 6 — 
                   
                 4-F—C 6 H 4   
                 L 
                 7.50˜6.98(m, 4H), 4.80(E) 4.75(Z) (s, 2H), 3.60˜3.15 
                 363(51), 140(45), 98(96), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.81˜1.46(m, 8H) 
                 55(58), 42(100) 
               
               
                 275 
                 —(CH 2 ) 6 — 
                   
                 3-Cl—C 6 H 4   
                 L 
                 7.49˜7.18(m, 4H), 4.81(E) 4.74(Z) (s, 2H), 3.62˜3.20 
                 379(55), 140(52), 98(93), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.82˜1.50(m, 8H) 
                 55(73), 42(100) 
               
               
                 276 
                 —(CH 2 ) 6 — 
                   
                 4-Cl—C 6 H 4   
                 L 
                 7.50˜7.15(m, 4H), 4.80(E) 4.75(Z) (s, 2H), 3.61˜3.17 
                 379(56), 140(51), 98(82), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.83˜1.43(m, 8H) 
                 55(70), 42(100) 
               
               
                 277 
                 —(CH 2 ) 6 — 
                   
                 3,5-Cl 2 —C 6 H 3   
                 L 
                 7.43˜7.16(m, 3H), 4.80(E) 4.75(Z) (s, 2H), 3.63˜3.18 
                 413(45), 140(48), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.86˜1.47(m, 8H) 
                 42(53) 
               
               
                 278 
                 —(CH 2 ) 6 — 
                   
                 C 4 H 3 S-2-yl 
                 L 
                 7.40˜6.94(m, 3H), 4.79(E) 4.75(Z) (s, 2H), 3.61˜3.13 
                 351(11), 140(50), 98(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 4H), 1.82˜1.43(m, 8H) 
                 55(31), 42(41) 
               
               
                 279 
                 C 2 H 5   
                 C 2 H 5   
                 C 6 H 5   
                 L 
                 7.50˜7.21(m, 5H), 4.77(E) 4.64(Z) (s, 2H), 3.45(q, 411), 
                 319(28), 114(88), 86(62), 
               
               
                   
                   
                   
                   
                   
                 1.15(t, 6H) 
                 72(100) 
               
               
                 280 
                 C 2 H 5   
                 C 2 H 5   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.45˜6.98(m, 4H), 4.78(E) 4.65(Z) (s, 2H), 3.45(q, 4H), 
                 333(39), 314(75), 219(100), 
               
               
                   
                   
                   
                   
                   
                 2.38(s, 3H), 1.10(t, 6H) 
                 72(82) 
               
               
                 281 
                 n-C 3 H 7   
                 n-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.46˜6.97(m, 4H), 4.77(E) 4.65(Z) (s, 2H), 3.21(t, 4H), 
                 361(43), 342(52), 261(100), 
               
               
                   
                   
                   
                   
                   
                 2.37(s, 3H), 1.98˜1.23(m, 4H), 0.91(t, 6H) 
                 100(23), 69(58) 
               
               
                 282 
                 i-C 3 H 7   
                 i-C 3 H 7   
                 4-CH 3 —C 6 H 4   
                 73˜74 
                 7.45˜6.98(m, 4H), 4.78(E) 4.66(Z) (s, 2H), 3.82˜3.32 
                 361(52), 342(40), 261(100), 
               
               
                   
                   
                   
                   
                   
                 (m, 2H), 2.38(s, 3H), 1.38(d, 12H) 
                 158(49) 
               
               
                 283 
                 CH 2 ═CHCH 2   
                 CH 2 ═CHCH 2   
                 C 6 H 5   
                 L 
                 7.49˜7.19(m, 5H), 5.86˜5.59(m, 2H), 5.30˜5.02(m, 4H), 
                 343(19), 138(92), 110(63), 
               
               
                   
                   
                   
                   
                   
                 4.79(E) 4.66(Z) (s, 2H), 4.10˜3.62(m, 4H) 
                 55(100) 
               
               
                 284 
                 CH 2 ═CHCH 2   
                 CH 2 ═CHCH 2   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.51˜6.97(m, 4H), 5.89˜5.42(m, 2H), 5.39˜4.98(m, 4H), 
                 357(40), 138(54), 55(100) 
               
               
                   
                   
                   
                   
                   
                 4.77(E) 4.65(Z) (s, 2H), 4.18˜3.48(m, 4H), 2.38(s, 3H) 
               
               
                 285 
                 CH 2 ═CHCH 2   
                 CH 2 ═CHCH 2   
                 3-CH 3 O—C 6 H 4   
                 L 
                 7.51˜6.81(m, 4H), 6.10˜5.51(m, 2H), 5.49˜4.98(m, 4H), 
                 373(66), 354(23), 138(41), 
               
               
                   
                   
                   
                   
                   
                 4.79(E) 4.66(Z) (s, 2H), 4.10˜3.62(m, 4H), 3.82(s, 3H) 
                 56(100) 
               
               
                 286 
                 CH 2 ═CHCH 2   
                 CH 2 ═CHCH 2   
                 3-CF 3 —C 6 H 4   
                 L 
                 7.89˜7.21(m, 4H), 5.94˜5.42(m, 2H), 5.39˜4.96(m, 4H), 
                 411(69), 195(100), 138(80), 
               
               
                   
                   
                   
                   
                   
                 4.79(E) 4.65(Z) (s, 2H), 4.18˜3.48(m, 4H) 
                 110(51) 
               
               
                 287 
                 CH 2 ═CHCH 2   
                 CH 2 ═CHCH 2   
                 C 4 H 3 S-2-yl 
                 L 
                 7.50˜6.91(m, 3H), 6.11˜5.50(m, 2H), 5.50˜4.97(m, 4H), 
                 349(13), 183(30), 138(100), 
               
               
                   
                   
                   
                   
                   
                 4.78(E) 4.66(Z) (s, 2H), 4.12˜3.61(m, 4H) 
                 133(48) 
               
               
                 288 
                 n-C 4 H 9   
                 n-C 4 H 9   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.48˜6.97(m, 4H), 4.79(E) 4.66(Z) (s, 2H), 3.21(t, 4H), 
                 389(42), 370(21), 203(100), 
               
               
                   
                   
                   
                   
                   
                 2.38(s, 3H), 1.82˜1.10(m, 8H), 0.94(t, 6H) 
                 186(72), 69(48) 
               
               
                 289 
                 i-C 4 H 9   
                 i-C 4 H 9   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.45˜6.98(m, 4H), 4.79(E) 4.65(Z) (s, 2H), 2.83(d, 4H), 
                 389(14), 170(17), 128(100), 
               
               
                   
                   
                   
                   
                   
                 2.37(s, 3H), 2.04˜1.37(m, 2H), 0.89(d, 12H) 
                 72(34) 
               
               
                 290 
                 C 2 H 5   
                 (CH 3 ) 2 CH 
                 C 6 H 5   
                 L 
                 7.71˜7.28(m, 5H), 4.78(E) 4.64(Z) (s, 2H), 3.98˜3.63 
                 333(12), 205(40), 128(62), 
               
               
                   
                   
                   
                   
                   
                 (m, 1H), 3.12(q, 2H), 1.12(t, 3H), 1.10(d, 6H) 
                 86(100), 57(71) 
               
               
                 291 
                 CH 3   
                 n-C 4 H 9   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.44˜6.97(m, 4H), 4.79(E) 4.64(Z) (s, 2H), 3.35(t, 2H), 
                 347(28), 328(16), 203(100), 
               
               
                   
                   
                   
                   
                   
                 2.82(s, 3H), 2.28(s, 3H), 1.45˜1.30(m, 4H), 0.98(t, 3H) 
                 144(67), 69(21) 
               
               
                 292 
                 C 2 H 5   
                 n-C 4 H 9   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.45˜6.96(m, 4H), 4.79(E) 4.65(Z) (s, 2H), 3.40(t, 2H), 
                 361(27), 342(12), 203(100), 
               
               
                   
                   
                   
                   
                   
                 3.21(q, 2H), 2.28(s, 3H), 1.46˜1.31(m, 4H), 1.10(t, 3H), 
                 158(39), 69(13) 
               
               
                   
                   
                   
                   
                   
                 0.97(t, 3H) 
               
               
                 293 
                 CH 3   
                 (C 6 H 5 )CH 2   
                 C 6 H 5   
                 L 
                 7.49˜7.01(m, 10H), 4.80(E) 4.66(Z) (s, 2H), 4.41(s, 2H), 
                 367(32), 164(100), 93(54), 
               
               
                   
                   
                   
                   
                   
                 2.82(s, 3H) 
                 47(98) 
               
               
                 294 
                 CH 3   
                 (C 6 H 5 )CH 2   
                 4-CH 3 —C 6 H 4   
                 L 
                 7.48˜6.98(m, 9H), 4.81(E) 4.67(Z) (s, 2H), 4.43(s, 2H), 
                 381(25), 162(68), 91(100), 
               
               
                   
                   
                   
                   
                   
                 2.84(s, 3H), 2.42(s, 3H) 
                 44(28) 
               
               
                   
               
             
          
         
       
     
     Herbicidal Activity Test 
     Herbicidal activity tests were conducted using test plants planted in screening pots as follows. 
     Each of screening pots, having the shape of a cube and a top surface area of 140 cm 2 , was filled with a wet mixture of paddy soil and a suitable amount of fertilizer, and sowed thereto were 100 barnyardgrass seeds, 20 bulrush seeds, 50 monochoria seeds, 2 flat-sedge tubers and 2 arrow head tubers(see Table 6). Two rice plant seedlings at the 3-leaf stage were then transplanted thereto, followed by filling water to a depth of 3 cm and kept in a greenhouse for 2 days. 
     Added to each of the screening pots thus prepared was 4 ml of a 50% acetone solution containing 0.1% Tween-20 and a predetermined amount of each of the compounds listed in Tables 4 and 5 so that the amount of the compound applied would correspond to 4, 1, 0.25, 0.0625 or 0.015 kg/ha. Then, the pot was kept in a greenhouse for 2 to 3 weeks. 
     The herbicidal activity was determined according to the procedure of Table 7 which was described by Frans et al.,  In research methods in weed science , ed. by Camper, 29-70 (1986) and Cho, K. Y.,  Search Report by Korea Research Institute of Chemical Technology , 916 (1989))”. The results are shown in Table 8. 
     
       
         
               
               
               
               
             
           
               
                   
                 TABLE 6 
               
               
                   
                   
               
               
                   
                 Abbreviation 
                 Genus-species name 
                 General name 
               
               
                   
                   
               
             
             
               
                   
                 ORYSA 
                   Oryza sativa  L. 
                 Rice 
               
               
                   
                 ECHOR 
                 
                   Echinochlora crus-galli 
                 
                 Barnyardgrass 
               
               
                   
                   
                 8P. BEAUV. var. 
               
               
                   
                   
                   oryzicola  OHWI 
               
               
                   
                 SCPJU 
                   Scirpus juncoides  ROXB 
                 Bulrush 
               
               
                   
                 MOOVA 
                 
                   Monochoria vaginalis 
                 
                 Monochoria 
               
               
                   
                   
                 PRESL 
               
               
                   
                 CYPSE 
                   Cyperus serotinus  ROTTB 
                 Flat-sedge 
               
               
                   
                 SAGPY 
                   Sagittaria pygmaea  MIQ 
                 Arrow head 
               
               
                   
                   
               
             
          
         
       
     
     
       
         
               
               
               
               
             
               
               
               
               
               
             
           
               
                 TABLE 7 
               
               
                   
               
               
                   
                 General 
                   
                   
               
               
                 Score 
                 Description 
                 Rice 
                 Weed 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 0 
                 no effect 
                   
                 no damage 
                 no preventive effect 
               
               
                 10 
                 week 
                 week 
                 a slight damage 
                 a slight damage 
               
               
                 20 
                   
                 medium 
                 that can be 
                 but no preventive 
               
               
                 30 
                   
                 strong 
                 recovered; no 
                 effect 
               
               
                   
                   
                   
                 significant in- 
               
               
                   
                   
                   
                 fluence on the 
               
               
                   
                   
                   
                 harvest 
               
               
                 40 
                 medium 
                 week 
                 a visible damage 
                 a significant pre- 
               
               
                 50 
                   
                 medium 
                 that can be re- 
                 ventive effect 
               
               
                 60 
                   
                 strong 
                 covered but 
               
               
                   
                   
                   
                 would reduce 
               
               
                   
                   
                   
                 the harvest 
               
               
                 70 
                 strong 
                 week 
                 a severe damage 
                 a practically high 
               
               
                 80 
                   
                 medium 
                 that can not 
                 preventive effect, 
               
               
                 90 
                   
                 strong 
                 be recovered, 
                 and eradication at 
               
               
                   
                   
                   
                 and extinction 
                 a score of 80 
               
               
                   
                   
                   
                 at a score of 
                 or higher 
               
               
                   
                   
                   
                 80 or higher 
               
               
                 100 
                 complete 
                   
                 total 
                 complete 
               
               
                   
                   
                   
                 destruction 
                 eradication 
               
               
                   
               
             
          
         
       
     
     
       
         
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 8 
               
               
                   
               
               
                 Comp. 
                 amount 
                   
                   
                   
                   
                   
                   
               
               
                 No. 
                 (kg/ha) 
                 ORYSA 
                 ECHOR 
                 SCPJU 
                 MOOVA 
                 CYPSE 
                 SAGPY 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 1 
                 4.0000 
                 90 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 0.2500 
                 10 
                 100 
                 10 
                 90 
                 40 
                 50 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 80 
                 40 
                 20 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 40 
                 10 
                 0 
               
               
                 2 
                 1.0000 
                 90 
                 100 
                 100 
                 100 
                 — 
                 70 
               
               
                   
                 0.2500 
                 40 
                 100 
                 70 
                 90 
                 — 
                 60 
               
               
                   
                 0.0625 
                 0 
                 100 
                 40 
                 90 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 100 
                 20 
                 90 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 75 
                 0 
                 60 
                 — 
                 0 
               
               
                 3 
                 1.0000 
                 80 
                 100 
                 100 
                 100 
                 — 
                 70 
               
               
                   
                 0.2500 
                 10 
                 100 
                 90 
                 100 
                 — 
                 50 
               
               
                   
                 0.0625 
                 0 
                 100 
                 70 
                 80 
                 — 
                 20 
               
               
                   
                 0.0156 
                 0 
                 100 
                 20 
                 60 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 60 
                 0 
                 20 
                 — 
                 0 
               
               
                 4 
                 1.0000 
                 70 
                 100 
                 70 
                 100 
                 100 
                 20 
               
               
                   
                 0.2500 
                 10 
                 100 
                 70 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 70 
                 100 
                 80 
                 0 
               
               
                   
                 0.0156 
                 0 
                 100 
                 50 
                 100 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 5 
                 1.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
                 60 
               
               
                   
                 0.2500 
                 10 
                 100 
                 30 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 95 
                 0 
                 90 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 50 
                 0 
                 10 
                 0 
                 0 
               
               
                 6 
                 1.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
                 60 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 100 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 7 
                 1.0000 
                 10 
                 100 
                 100 
                 100 
                 — 
                 30 
               
               
                   
                 0.2500 
                 0 
                 100 
                 100 
                 100 
                 — 
                 30 
               
               
                   
                 0.0625 
                 0 
                 80 
                 30 
                 70 
                 — 
                 10 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 40 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 — 
                 0 
               
               
                 8 
                 1.0000 
                 0 
                 100 
                 20 
                 90 
                 30 
                 70 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 30 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 0 
                 10 
                 0 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 9 
                 4.0000 
                 80 
                 100 
                 100 
                 100 
                 0 
                 100 
               
               
                   
                 1.0000 
                 50 
                 100 
                 60 
                 100 
                 0 
                 60 
               
               
                   
                 0.2500 
                 30 
                 100 
                 0 
                 100 
                 0 
                 40 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 100 
                 0 
                 100 
                 0 
                 0 
               
               
                 10 
                 1.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 10 
                 100 
                 40 
                 70 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 30 
                 10 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 11 
                 4.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 80 
               
               
                   
                 1.0000 
                 10 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 90 
                 100 
                 10 
               
               
                   
                 0.0625 
                 0 
                 90 
                 10 
                 60 
                 100 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                 12 
                 1.0000 
                 0 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 0.2500 
                 0 
                 100 
                 10 
                 90 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 60 
                 10 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 13 
                 4.0000 
                 40 
                 100 
                 70 
                 100 
                 0 
                 100 
               
               
                   
                 1.0000 
                 30 
                 100 
                 40 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 100 
                 0 
                 100 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 80 
                 0 
                 100 
               
               
                   
                 0.0156 
                 0 
                 70 
                 0 
                 40 
                 0 
                 0 
               
               
                 14 
                 1.0000 
                 50 
                 100 
                 100 
                 100 
                 100 
                 70 
               
               
                   
                 0.2500 
                 10 
                 100 
                 40 
                 90 
                 100 
                 20 
               
               
                   
                 0.0625 
                 0 
                 100 
                 20 
                 70 
                 50 
                 0 
               
               
                   
                 0.0156 
                 0 
                 80 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                 15 
                 1.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 100 
                 100 
                 30 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 90 
                 100 
                 20 
               
               
                   
                 0.0156 
                 0 
                 90 
                 0 
                 30 
                 20 
                 0 
               
               
                   
                 0.0040 
                 0 
                 70 
                 0 
                 0 
                 0 
               
               
                 16 
                 1.0000 
                 30 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 0.2500 
                 10 
                 100 
                 50 
                 100 
                 50 
               
               
                   
                 0.0625 
                 0 
                 100 
                 50 
                 100 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 40 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 17 
                 1.0000 
                 30 
                 100 
                 20 
                 100 
                 100 
                 20 
               
               
                   
                 0.2500 
                 10 
                 100 
                 0 
                 100 
                 100 
                 20 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 100 
                 100 
                 20 
               
               
                   
                 0.0156 
                 0 
                 90 
                 0 
                 100 
                 40 
                 0 
               
               
                   
                 0.0040 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 18 
                 4.0000 
                 0 
                 100 
                 30 
                 90 
                 50 
                 20 
               
               
                   
                 1.0000 
                 0 
                 100 
                 70 
                 90 
                 0 
                 — 
               
               
                   
                 0.2500 
                 0 
                 70 
                 40 
                 80 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 10 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 19 
                 4.0000 
                 50 
                 100 
                 100 
                 100 
                 — 
                 100 
               
               
                   
                 1.0000 
                 40 
                 100 
                 100 
                 100 
                 — 
                 100 
               
               
                   
                 0.2500 
                 40 
                 100 
                 70 
                 100 
                 — 
                 0 
               
               
                   
                 0.0625 
                 20 
                 95 
                 — 
                 100 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 70 
                 0 
                 40 
                 — 
                 0 
               
               
                 20 
                 4.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 70 
               
               
                   
                 1.0000 
                 30 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 0.2500 
                 10 
                 100 
                 10 
                 90 
                 30 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 80 
                 20 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 30 
                 0 
                 0 
               
               
                 21 
                 1.0000 
                 45 
                 100 
                 80 
                 100 
                 100 
                 10 
               
               
                   
                 0.2500 
                 10 
                 100 
                 40 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 10 
                 60 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                 22 
                 4.0000 
                 20 
                 100 
                 50 
                 100 
                 100 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 30 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 90 
                 20 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 30 
                 60 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 40 
                 0 
                 0 
               
               
                 23 
                 1.0000 
                 30 
                 100 
                 0 
                 90 
                 60 
                 70 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 40 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 24 
                 1.0000 
                 30 
                 100 
                 40 
                 100 
                 0 
                 0 
               
               
                   
                 0.2500 
                 10 
                 100 
                 20 
                 70 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 90 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 10 
                 0 
                 0 
                 0 
                 0 
               
               
                 25 
                 1.0000 
                 10 
                 100 
                 40 
                 100 
                 100 
                 50 
               
               
                   
                 0.2500 
                 0 
                 90 
                 0 
                 50 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 0 
                 100 
                 0 
               
               
                   
                 0.0156 
                 0 
                 70 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
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                 26 
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                 50 
                 90 
                 0 
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                 40 
                 90 
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                 30 
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                 20 
                 50 
                 0 
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                 20 
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                 27 
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                 100 
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                 100 
                 100 
                 10 
               
               
                   
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                 50 
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                 80 
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                 30 
                 30 
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                 0 
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                 0 
               
               
                 28 
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                 100 
                 10 
                 100 
                 100 
                 30 
               
               
                   
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                 100 
                 0 
                 100 
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                 0 
               
               
                   
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                 100 
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                 100 
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                 0 
               
               
                   
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                 50 
                 0 
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                 0 
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                 0 
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                 0 
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                 30 
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                 100 
                 100 
                 100 
                 — 
                 100 
               
               
                   
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                 50 
                 100 
                 100 
                 100 
                 — 
                 60 
               
               
                   
                 0.0625 
                 40 
                 100 
                 30 
                 90 
                 — 
                 50 
               
               
                   
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                 80 
                 10 
                 70 
                 — 
                 0 
               
               
                   
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                 50 
                 0 
                 20 
                 — 
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                 31 
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                 100 
                 80 
                 100 
                 — 
                 30 
               
               
                   
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                 100 
                 50 
                 90 
                 — 
                 0 
               
               
                   
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                 95 
                 0 
                 80 
                 — 
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                 70 
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                 50 
                 — 
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                 10 
                 0 
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                 — 
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                 32 
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                 100 
                 100 
                 100 
                 — 
                 40 
               
               
                   
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                 100 
                 100 
                 100 
                 — 
                 20 
               
               
                   
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                 90 
                 20 
                 80 
                 — 
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                 60 
                 0 
                 20 
                 — 
                 0 
               
               
                   
                 0.0040 
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                 20 
                 0 
                 0 
                 — 
                 0 
               
               
                 33 
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                 100 
                 50 
                 100 
                 — 
                 30 
               
               
                   
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                 100 
                 30 
                 80 
                 — 
                 0 
               
               
                   
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                 0 
                 80 
                 0 
                 70 
                 — 
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                 40 
                 0 
                 20 
                 — 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 — 
                 0 
               
               
                 34 
                 1.0000 
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                 100 
                 100 
                 100 
                 — 
                 20 
               
               
                   
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                 100 
                 80 
                 100 
                 — 
                 10 
               
               
                   
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                 90 
                 10 
                 70 
                 — 
                 10 
               
               
                   
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                 70 
                 0 
                 50 
                 — 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 — 
                 0 
               
               
                 35 
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                 100 
                 100 
                 100 
                 — 
                 50 
               
               
                   
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                 100 
                 50 
                 90 
                 — 
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                 0.0625 
                 0 
                 80 
                 30 
                 70 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 50 
                 — 
                 0 
               
               
                   
                 0.0040 
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                 10 
                 0 
                 20 
                 — 
                 0 
               
               
                 36 
                 1.0000 
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                 100 
                 100 
                 100 
                 — 
                 60 
               
               
                   
                 0.2500 
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                 100 
                 20 
                 90 
                 — 
                 60 
               
               
                   
                 0.0625 
                 0 
                 90 
                 10 
                 80 
                 — 
                 20 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 50 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 20 
                 0 
                 20 
                 — 
                 0 
               
               
                 37 
                 1.0000 
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                 100 
                 100 
                 100 
                 — 
                 70 
               
               
                   
                 0.2500 
                 20 
                 100 
                 100 
                 100 
                 — 
                 50 
               
               
                   
                 0.0625 
                 0 
                 100 
                 50 
                 90 
                 — 
                 30 
               
               
                   
                 0.0156 
                 0 
                 80 
                 40 
                 80 
                 — 
                 30 
               
               
                   
                 0.0040 
                 0 
                 50 
                 20 
                 40 
                 — 
                 0 
               
               
                 38 
                 1.0000 
                 20 
                 100 
                 70 
                 100 
                 — 
                 30 
               
               
                   
                 0.2500 
                 10 
                 100 
                 60 
                 100 
                 — 
                 30 
               
               
                   
                 0.0625 
                 0 
                 80 
                 30 
                 80 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 40 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 — 
                 0 
               
               
                 39 
                 1.0000 
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                 100 
                 70 
                 100 
                 — 
                 10 
               
               
                   
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                 0 
                 100 
                 10 
                 100 
                 — 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 70 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 50 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 50 
                 0 
                 20 
                 — 
                 0 
               
               
                 40 
                 1.0000 
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                 80 
                 30 
                 100 
                 — 
                 10 
               
               
                   
                 0.2500 
                 0 
                 70 
                 30 
                 100 
                 — 
                 0 
               
               
                   
                 0.0625 
                 0 
                 30 
                 0 
                 30 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 30 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 — 
                 0 
               
               
                 42 
                 1.0000 
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                 100 
                 30 
                 100  
                 30 
                 20 
               
               
                   
                 0.2500 
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                 100 
                 30 
                 100 
                 30 
                 20 
               
               
                   
                 0.0625 
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                 80 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 80 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 10 
                 0 
                 0 
                 0 
                 0 
               
               
                 43 
                 1.0000 
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                 100 
                 0 
                 90 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 80 
                 30 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 40 
                 10 
                 0 
               
               
                   
                 0.0156 
                 0 
                 70 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0040 
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 44 
                 4.0000 
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                 100 
                 90 
                 100 
                 100 
                 100 
               
               
                   
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                 100 
                 50 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
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                 100 
                 30 
                 100 
                 100 
                 100 
               
               
                   
                 0.0625 
                 20 
                 100 
                 0 
                 70 
                 80 
                 50 
               
               
                   
                 0.0156 
                 0 
                 100 
                 0 
                 60 
                 30 
                 0 
               
               
                 45 
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                 100 
                 70 
                 100 
                 100 
                 100 
               
               
                   
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                 40 
                 100 
                 40 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 30 
                 100 
                 0 
                 90 
                 100 
                 100 
               
               
                   
                 0.0625 
                 20 
                 100 
                 0 
                 60 
                 50 
                 30 
               
               
                   
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                 0 
                 100 
                 0 
                 60 
                 0 
                 0 
               
               
                 46 
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                 100 
                 60 
                 100 
                 90 
                 0 
               
               
                   
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                 20 
                 100 
                 50 
                 100 
                 0 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 50 
                 90 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 30 
                 70 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 90 
                 0 
                 70 
                 0 
                 0 
               
               
                 47 
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                 100 
                 30 
                 90 
                 90 
                 50 
               
               
                   
                 0.2500 
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                 95 
                 10 
                 70 
                 90 
                 30 
               
               
                   
                 0.0625 
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                 80 
                 0 
                 30 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 48 
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                 100 
                 50 
                 100 
                 100 
                 80 
               
               
                   
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                 100 
                 40 
                 90 
                 60 
                 0 
               
               
                   
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                 100 
                 0 
                 90 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 50 
                 0 
                 0 
               
               
                   
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                 0 
                 30 
                 0 
                 20 
                 0 
                 0 
               
               
                 49 
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                 100 
                 100 
                 100 
                 0 
                 50 
               
               
                   
                 1.0000 
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                 100 
                 80 
                 100 
                 0 
                 30 
               
               
                   
                 0.2500 
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                 100 
                 70 
                 100 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 40 
                 100 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 95 
                 20 
                 50 
                 0 
                 0 
               
               
                 50 
                 1.0000 
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                 100 
                 70 
                 100 
                 100 
                 20 
               
               
                   
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                 100 
                 10 
                 90 
                 100 
                 0 
               
               
                   
                 0.0625 
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                 100 
                 0 
                 60 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 95 
                 0 
                 20 
                 0 
                 0 
               
               
                   
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                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 51 
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                 100 
                 30 
                 100 
                 100 
                 0 
               
               
                   
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                 100 
                 10 
                 50 
                 100 
                 0 
               
               
                   
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                 100 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 52 
                 4.0000 
                 30 
                 100 
                 100 
                 100 
                 — 
                 50 
               
               
                   
                 1.0000 
                 20 
                 100 
                 50 
                 100 
                 — 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 40 
                 0 
               
               
                   
                 0.0625 
                 0 
                 70 
                 0 
                 50 
                 30 
                 0 
               
               
                   
                 0.0156 
                 0 
                 70 
                 0 
                 0 
                 30 
                 0 
               
               
                 53 
                 4.0000 
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                 100 
                 30 
                 100 
                 100 
                 30 
               
               
                   
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                 10 
                 100 
                 0 
                 90 
                 70 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 80 
                 50 
                 0 
               
               
                   
                 0.0625 
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                 100 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 40 
                 0 
                 30 
                 0 
                 0 
               
               
                 54 
                 4.0000 
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                 100 
                 100 
                 100 
                 — 
                 20 
               
               
                   
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                 0 
                 100 
                 50 
                 100 
                 — 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 20 
                 70 
                 — 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 70 
                 — 
                 0 
               
               
                   
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                 75 
                 0 
                 0 
                 — 
                 0 
               
               
                 55 
                 4.0000 
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                 100 
                 100 
                 100 
                 100 
                 90 
               
               
                   
                 1.0000 
                 10 
                 100 
                 0 
                 100 
                 100 
                 40 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 80 
                 20 
                 20 
               
               
                   
                 0.0625 
                 0 
                 90 
                 0 
                 50 
                 10 
                 0 
               
               
                   
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                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                 56 
                 4.0000 
                 50 
                 100 
                 100 
                 100 
                 100 
                 70 
               
               
                   
                 1.0000 
                 10 
                 100 
                 10 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 10 
                 90 
                 50 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 10 
                 70 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 70 
                 0 
                 20 
                 0 
                 0 
               
               
                 57 
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                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
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                 0 
                 100 
                 0 
                 90 
                 40 
                 0 
               
               
                   
                 0.2500 
                 0 
                 80 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 58 
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                 100 
                 0 
                 80 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 70 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 95 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0625 
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                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 59 
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                 100 
                 20 
                 40 
                 100 
                 10 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 10 
                 50 
                 0 
               
               
                   
                 0.0625 
                 0 
                 10 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 60 
                 4.0000 
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                 100 
                 0 
                 100 
                 50 
                 60 
               
               
                   
                 1.0000 
                 10 
                 100 
                 0 
                 100 
                 50 
                 20 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 30 
                 0 
               
               
                   
                 0.0625 
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                 90 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 80 
                 0 
                 0 
                 0 
                 0 
               
               
                 61 
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                 100 
                 40 
                 100 
                 0 
                 0 
               
               
                   
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                 0 
                 100 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0625 
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                 100 
                 0 
                 40 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 62 
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                 30 
                 100 
                 100 
                 100 
                 100 
                 80 
               
               
                   
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                 10 
                 100 
                 0 
                 90 
                 60 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 30 
                 0 
               
               
                   
                 0.0625 
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                 80 
                 0 
                 10 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                 63 
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                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
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                 0 
                 100 
                 0 
                 100 
                 80 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 80 
                 40 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 64 
                 4.0000 
                 50 
                 100 
                 0 
                 100 
                 100 
                 30 
               
               
                   
                 1.0000 
                 20 
                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 70 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 30 
                 0 
                 0 
               
               
                 65 
                 4.0000 
                 10 
                 100 
                 30 
                 100 
                 0 
                 30 
               
               
                   
                 1.0000 
                 0 
                 100 
                 10 
                 80 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 60 
                 0 
                 10 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                 66 
                 4.0000 
                 0 
                 100 
                 30 
                 100 
                 40 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 90 
                 40 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0625 
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                 95 
                 0 
                 40 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 67 
                 4.0000 
                 10 
                 100 
                 40 
                 100 
                 30 
                 70 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 100 
                 20 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                 68 
                 4.0000 
                 0 
                 100 
                 40 
                 100 
                 80 
                 20 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 90 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 60 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 69 
                 4.0000 
                 50 
                 100 
                 0 
                 100 
                 100 
                 30 
               
               
                   
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                 10 
                 100 
                 0 
                 100 
                 20 
                 20 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 90 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 90 
                 0 
                 0 
                 0 
                 0 
               
               
                 70 
                 1.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 10 
                 100 
                 20 
                 70 
                 100 
                 0 
               
               
                   
                 0.0625 
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                 70 
                 0 
                 10 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 71 
                 4.0000 
                 20 
                 100 
                 50 
                 100 
                 100 
                 50 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 90 
                 100 
                 20 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 80 
                 50 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 40 
                 0 
                 0 
                 0 
                 0 
               
               
                 72 
                 1.0000 
                 0 
                 100 
                 30 
                 60 
                 0 
                 70 
               
               
                   
                 0.2500 
                 0 
                 95 
                 0 
                 50 
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                 0 
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                 0 
                 30 
                 0 
                 0 
               
               
                   
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                 0 
                 20 
                 0 
                 0 
               
               
                   
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                 0 
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                 10 
               
               
                   
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                 30 
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                 0 
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                 30 
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                 50 
               
               
                   
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                 95 
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                 30 
               
               
                   
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                 30 
               
               
                   
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                 0 
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                 0 
                 30 
                 50 
                 30 
               
               
                 123 
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                 0 
                 50 
                 0 
                 0 
               
               
                   
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                 20 
                 0 
                 20 
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                 40 
                 100 
                 0 
                 20 
               
               
                   
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                 30 
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                 127 
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                 30 
                 100 
                 10 
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                 0 
                 80 
               
               
                   
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                 0 
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                 0 
                 90 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 95 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0625 
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                 95 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                 128 
                 4.0000 
                 0 
                 100 
                 50 
                 100 
                 — 
                 — 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 100 
                 0 
                 — 
               
               
                   
                 0.2500 
                 0 
                 95 
                 0 
                 70 
                 0 
                 — 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 30 
                 0 
                 — 
               
               
                   
                 0.0156 
                 0 
                 70 
                 0 
                 0 
                 0 
                 — 
               
               
                 129 
                 1.0000 
                 0 
                 100 
                 10 
                 30 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 0 
                 0 
                 0 
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                 0 
                 0 
               
               
                 138 
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                 10 
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                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 90 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 142 
                 4.0000 
                 0 
                 100 
                 0 
                 100 
                 30 
                 80 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 90 
                 30 
                 30 
               
               
                   
                 0.2500 
                 0 
                 90 
                 0 
                 40 
                 20 
                 0 
               
               
                   
                 0.0625 
                 0 
                 70 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                 143 
                 4.0000 
                 0 
                 100 
                 0 
                 100 
                 60 
                 60 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 90 
                 0 
                 30 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 0 
                 30 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 50 
                 0 
                 20 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 40 
                 0 
                 0 
               
               
                 144 
                 4.0000 
                 30 
                 100 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                 145 
                 1.0000 
                 0 
                 90 
                 0 
                 70 
                 50 
                 20 
               
               
                   
                 0.2500 
                 0 
                 80 
                 0 
                 40 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 146 
                 1.0000 
                 0 
                 100 
                 0 
                 70 
                 40 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 147 
                 1.0000 
                 0 
                 100 
                 0 
                 0 
                 20 
                 30 
               
               
                   
                 0.2500 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 148 
                 1.0000 
                 0 
                 100 
                 0 
                 10 
                 0 
                 20 
               
               
                   
                 0.2500 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 151 
                 1.0000 
                 0 
                 100 
                 30 
                 0 
                 30 
                 0 
               
               
                   
                 0.2500 
                 0 
                 95 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 152 
                 1.0000 
                 0 
                 100 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 153 
                 1.0000 
                 0 
                 100 
                 0 
                 30 
                 20 
                 10 
               
               
                   
                 0.2500 
                 0 
                 70 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 156 
                 1.0000 
                 0 
                 100 
                 0 
                 60 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 70 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 162 
                 4.0000 
                 80 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.0625 
                 0 
                 100 
                 100 
                 80 
                 0 
               
               
                   
                 0.0157 
               
               
                 163 
                 4.0000 
                 60 
                 100 
                 70 
                 100 
               
               
                   
                 1.0000 
                 40 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 40 
                 100 
                 100 
                 100 
               
               
                   
                 0.0625 
                 10 
                 100 
                 0 
                 70 
               
               
                   
                 0.0157 
                 0 
                 95 
                 0 
                 0 
               
               
                 164 
                 4.0000 
                 60 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 50 
                 100 
                 30 
                 100 
               
               
                   
                 0.2500 
                 20 
                 100 
                 0 
                 100 
               
               
                   
                 0.0625 
                 10 
                 100 
                 0 
                 50 
               
               
                   
                 0.0157 
                 10 
                 70 
                 0 
                 20 
               
               
                 165 
                 4.0000 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 60 
                 100 
                 90 
                 100 
               
               
                   
                 0.2500 
                 40 
                 100 
                 50 
                 100 
               
               
                   
                 0.0625 
                 20 
                 100 
                 50 
                 100 
               
               
                   
                 0.0157 
                 0 
                 100 
                 0 
                 30 
               
               
                 166 
                 4.0000 
                 40 
                 100 
                 20 
                 100 
               
               
                   
                 1.0000 
                 30 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 20 
                 100 
                 0 
                 70 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 50 
               
               
                   
                 0.0157 
                 0 
                 80 
                 0 
                 0 
               
               
                 167 
                 4.0000 
                 50 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 50 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 40 
                 100 
                 0 
                 100 
               
               
                   
                 0.0625 
                 30 
                 100 
                 0 
                 80 
               
               
                   
                 0.0157 
                 20 
                 100 
                 0 
                 60 
               
               
                 168 
                 4.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 30 
               
               
                   
                 1.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
                 30 
               
               
                   
                 0.2500 
                 0 
                 100 
                 90 
                 90 
                 70 
                 0 
               
               
                   
                 0.0625 
                 0 
                 90 
                 80 
                 90 
                 20 
                 0 
               
               
                   
                 0.0157 
                 0 
                 70 
                 0 
                 50 
                 0 
                 0 
               
               
                 169 
                 4.0000 
                 40 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 90 
                 95 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 100 
               
               
                   
                 0.0625 
                 0 
                 99 
                 0 
                 50 
                 100 
               
               
                   
                 0.0157 
                 0 
                 80 
                 0 
                 30 
                 100 
               
               
                 170 
                 4.0000 
                 10 
                 100 
                 0 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 90 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 70 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 60 
                 0 
               
               
                   
                 0.0157 
                 0 
                 60 
                 0 
                 0 
                 0 
               
               
                 171 
                 4.0000 
                 10 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 70 
                 70 
                 40 
               
               
                   
                 0.0625 
                 0 
                 100 
                 50 
                 30 
                 0 
               
               
                   
                 0.0157 
                 0 
                 75 
                 0 
                 0 
                 0 
               
               
                 172 
                 4.0000 
                 50 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 1.0000 
                 20 
                 100 
                 60 
                 100 
                 100 
                 30 
               
               
                   
                 0.2500 
                 10 
                 100 
                 40 
                 90 
                 50 
                 20 
               
               
                   
                 0.0625 
                 0 
                 100 
                 30 
                 80 
                 50 
                 0 
               
               
                   
                 0.0157 
                 0 
                 100 
                 30 
                 60 
                 0 
                 0 
               
               
                 173 
                 4.0000 
                 30 
                 100 
                 70 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 60 
                 0 
               
               
                   
                 0.0157 
                 0 
                 40 
                 0 
                 0 
                 0 
               
               
                 174 
                 4.0000 
                 0 
                 100 
                 10 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 70 
                 100 
               
               
                   
                 0.0625 
                 0 
                 0 
                 0 
                 20 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 175 
                 4.0000 
                 40 
                 90 
                 10 
                 100 
                 100 
                 20 
               
               
                   
                 1.0000 
                 30 
                 90 
                 0 
                 70 
                 0 
                 10 
               
               
                   
                 0.2500 
                 30 
                 50 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0625 
                 10 
                 10 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 10 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 176 
                 4.0000 
                 50 
                 100 
                 30 
                 100 
               
               
                   
                 1.0000 
                 30 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 20 
                 100 
                 0 
                 100 
               
               
                   
                 0.0625 
                 20 
                 100 
                 0 
                 60 
               
               
                   
                 0.0157 
                 0 
                 100 
                 0 
                 30 
               
               
                 177 
                 4.0000 
                 30 
                 100 
                 80 
                 100 
                 100 
               
               
                   
                 1.0000 
                 10 
                 100 
                 80 
                 100 
                 100 
               
               
                   
                 0.2500 
                 10 
                 100 
                 60 
                 100 
                 100 
               
               
                   
                 0.0625 
                 0 
                 100 
                 30 
                 70 
                 0 
               
               
                   
                 0.0157 
                 0 
                 60 
                 30 
                 0 
                 0 
               
               
                 178 
                 4.0000 
                 30 
                 100 
                 50 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 50 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 90 
                 100 
               
               
                   
                 0.0625 
                 0 
                 95 
                 30 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 30 
                 0 
                 0 
                 0 
               
               
                 179 
                 4.0000 
                 0 
                 100 
                 30 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 30 
                 80 
                 100 
               
               
                   
                 0.2500 
                 0 
                 60 
                 0 
                 20 
                 100 
               
               
                   
                 0.0625 
                 0 
                 10 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 180 
                 4.0000 
                 20 
                 100 
                 30 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 90 
                 20 
                 50 
                 100 
               
               
                   
                 0.0625 
                 0 
                 20 
                 0 
                 0 
                 100 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 181 
                 4.0000 
                 10 
                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 98 
                 0 
                 90 
                 90 
                 0 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 60 
                 0 
                 40 
                 0 
                 0 
               
               
                 183 
                 4.0000 
                 30 
                 100 
                 20 
                 100 
                 70 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 10 
                 100 
               
               
                   
                 0.0625 
                 0 
                 30 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 185 
                 4.0000 
                 10 
                 100 
                 10 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 100 
               
               
                   
                 0.625 
                 0 
                 90 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
               
               
                 186 
                 4.0000 
                 10 
                 100 
                 0 
                 95 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 30 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 10 
                 0 
                 0 
               
               
                 187 
                 4.0000 
                 30 
                 100 
                 20 
                 90 
               
               
                   
                 1.0000 
                 20 
                 100 
                 0 
                 60 
               
               
                   
                 0.2500 
                 10 
                 100 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
               
               
                 189 
                 4.0000 
                 80 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 40 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 100 
                 100 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 100 
               
               
                   
                 0.0157 
                 0 
                 100 
                 0 
                 40 
               
               
                 190 
                 4.0000 
                 50 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 60 
                 100 
                 100 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 90 
                 100 
               
               
                   
                 0.0157 
                 0 
                 100 
                 0 
                 90 
                 0 
               
               
                 191 
                 4.0000 
                 40 
                 100 
                 70 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 50 
                 95 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 80 
                 100 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 80 
                 100 
               
               
                   
                 0.0157 
                 0 
                 85 
                 0 
                 0 
                 0 
               
               
                 192 
                 4.0000 
                 10 
                 100 
                 60 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 50 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 80 
                 20 
                 20 
                 0 
               
               
                   
                 0.0157 
                 0 
                 30 
                 0 
                 0 
                 0 
               
               
                 193 
                 4.0000 
                 20 
                 100 
                 10 
                 100 
               
               
                   
                 1.0000 
                 20 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 100 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 30 
               
               
                   
                 0.0157 
                 0 
                 10 
                 0 
                 0 
               
               
                 194 
                 4.0000 
                 20 
                 100 
                 0 
                 100 
               
               
                   
                 1.0000 
                 10 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 10 
                 70 
                 0 
                 20 
               
               
                   
                 0.0625 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
               
               
                 195 
                 4.0000 
                 40 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 20 
                 100 
                 60 
                 100 
                 100 
               
               
                   
                 0.2500 
                 20 
                 100 
                 0 
                 70 
                 100 
               
               
                   
                 0.625 
                 0 
                 95 
                 0 
                 0 
                 50 
               
               
                   
                 0.0157 
                 0 
                 30 
                 0 
                 0 
                 0 
               
               
                 196 
                 4.0000 
                 40 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 30 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 20 
                 100 
                 20 
                 100 
                 100 
               
               
                   
                 0.0625 
                 0 
                 100 
                 10 
                 40 
                 100 
               
               
                   
                 0.0157 
                 0 
                 60 
                 0 
                 20 
                 0 
               
               
                 197 
                 4.0000 
                 50 
                 100 
                 50 
                 100 
               
               
                   
                 1.0000 
                 30 
                 100 
                 30 
                 100 
               
               
                   
                 0.2500 
                 30 
                 100 
                 20 
                 100 
               
               
                   
                 0.0625 
                 20 
                 100 
                 0 
                 70 
               
               
                   
                 0.0157 
                 0 
                 100 
                 0 
                 50 
               
               
                 198 
                 4.0000 
                 0 
                 100 
                 40 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 40 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 100 
                 40 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 60 
                 0 
                 10 
                 0 
               
               
                   
                 0.0157 
                 0 
                 30 
                 0 
                 0 
                 0 
               
               
                 199 
                 4.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
                 40 
               
               
                   
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                 0 
                 100 
                 50 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 50 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 30 
                 80 
                 20 
                 0 
               
               
                   
                 0.0157 
                 0 
                 60 
                 30 
                 30 
                 0 
                 0 
               
               
                 200 
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                 0 
                 100 
                 0 
                 100 
                 100 
                 60 
               
               
                   
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                 0 
                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 50 
                 0 
               
               
                   
                 0.0625 
                 0 
                 70 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 50 
                 0 
                 40 
                 0 
                 0 
               
               
                 201 
                 4.0000 
                 0 
                 100 
                 30 
                 100 
                 100 
                 0 
               
               
                   
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                 0 
                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 80 
                 0 
                 80 
                 40 
                 0 
               
               
                   
                 0.0625 
                 0 
                 70 
                 0 
                 60 
                 40 
                 0 
               
               
                   
                 0.0157 
                 0 
                 60 
                 0 
                 40 
                 0 
                 0 
               
               
                 202 
                 4.0000 
                 20 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 100 
                 100 
               
               
                   
                 0.2500 
                 0 
                 80 
                 0 
                 60 
                 100 
               
               
                   
                 0.0625 
                 0 
                 60 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 203 
                 4.0000 
                 30 
                 100 
                 0 
                 100 
                 100 
                 20 
               
               
                   
                 1.0000 
                 20 
                 100 
                 0 
                 95 
                 50 
                 0 
               
               
                   
                 0.2500 
                 10 
                 75 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0625 
                 10 
                 30 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 204 
                 4.0000 
                 20 
                 100 
                 40 
                 100 
                 100 
                 20 
               
               
                   
                 1.0000 
                 0 
                 100 
                 40 
                 90 
                 100 
                 10 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 90 
                 100 
                 10 
               
               
                   
                 0.0625 
                 0 
                 85 
                 30 
                 70 
                 30 
                 0 
               
               
                   
                 0.0157 
                 0 
                 40 
                 0 
                 0 
                 0 
                 0 
               
               
                 205 
                 4.0000 
                 30 
                 100 
                 50 
                 100 
                 100 
                 20 
               
               
                   
                 1.0000 
                 30 
                 100 
                 0 
                 95 
                 100 
                 0 
               
               
                   
                 0.2500 
                 30 
                 100 
                 0 
                 95 
                 50 
                 0 
               
               
                   
                 0.0625 
                 20 
                 80 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0157 
                 10 
                 40 
                 0 
                 20 
                 0 
                 0 
               
               
                 206 
                 4.0000 
                 20 
                 100 
                 40 
                 100 
                 100 
                 30 
               
               
                   
                 1.0000 
                 0 
                 100 
                 30 
                 90 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 10 
                 90 
                 70 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 10 
                 80 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                 207 
                 4.0000 
                 0 
                 100 
                 20 
                 100 
                 100 
                 30 
               
               
                   
                 1.0000 
                 0 
                 100 
                 10 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 90 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 60 
                 0 
                 50 
                 0 
                 0 
               
               
                 208 
                 4.0000 
                 10 
                 100 
                 20 
                 100 
                 100 
                 20 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 90 
                 30 
                 0 
               
               
                   
                 0.2500 
                 0 
                 70 
                 10 
                 80 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 60 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 209 
                 4.0000 
                 0 
                 100 
                 10 
                 100 
                 50 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 10 
                 100 
                 50 
                 0 
               
               
                   
                 0.2500 
                 0 
                 70 
                 0 
                 70 
                 50 
                 0 
               
               
                   
                 0.0625 
                 0 
                 50 
                 0 
                 40 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 50 
                 0 
                 20 
                 0 
                 0 
               
               
                 210 
                 4.0000 
                 20 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 20 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 10 
                 80 
                 100 
                 95 
               
               
                   
                 0.0625 
                 0 
                 0 
                 0 
                 30 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 30 
               
               
                 211 
                 4.0000 
                 0 
                 90 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 1.0000 
                 0 
                 80 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 70 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 212 
                 4.0000 
                 40 
                 100 
                 40 
                 100 
                 100 
                 0 
               
               
                   
                 1.0000 
                 20 
                 100 
                 40 
                 90 
                 100 
                 0 
               
               
                   
                 0.2500 
                 10 
                 100 
                 30 
                 70 
                 70 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 20 
                 20 
                 70 
                 0 
               
               
                   
                 0.0157 
                 0 
                 80 
                 0 
                 0 
                 0 
                 0 
               
               
                 213 
                 4.0000 
                 0 
                 100 
                 30 
                 80 
                 30 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 70 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 90 
                 10 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 214 
                 4.0000 
                 0 
                 100 
                 10 
                 100 
                 0 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 0 
                 90 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 95 
                 0 
                 40 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 70 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 216 
                 4.0000 
                 0 
                 100 
                 40 
                 50 
                 0 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 0 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 60 
                 10 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 218 
                 4.0000 
                 10 
                 100 
                 40 
                 100 
                 0 
                 0 
               
               
                   
                 1.0000 
                 0 
                 100 
                 20 
                 80 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 10 
                 70 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 90 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                 219 
                 4.0000 
                 0 
                 100 
                 0 
                 10 
                 0 
                 0 
               
               
                   
                 1.0000 
                 0 
                 80 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.2500 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 220 
                 4.0000 
                 0 
                 100 
                 80 
                 100 
                 100 
                 60 
               
               
                   
                 1.0000 
                 0 
                 95 
                 0 
                 0 
                 90 
                 0 
               
               
                   
                 0.2500 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0157 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 221 
                 1.0000 
                 80 
                 100 
                 100 
                 100 
                 100 
                 90 
               
               
                   
                 0.2500 
                 0 
                 100 
                 100 
                 90 
                 100 
                 80 
               
               
                   
                 0.0625 
                 0 
                 100 
                 60 
                 90 
                 100 
                 0 
               
               
                   
                 0.0156 
                 0 
                 95 
                 20 
                 60 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 222 
                 1.0000 
                 80 
                 100 
                 100 
                 100 
                 — 
                 70 
               
               
                   
                 0.2500 
                 70 
                 100 
                 100 
                 100 
                 — 
                 60 
               
               
                   
                 0.0625 
                 20 
                 100 
                 40 
                 90 
                 — 
                 30 
               
               
                   
                 0.0156 
                 0 
                 70 
                 10 
                 80 
                 — 
                 0 
               
               
                   
                 0.0040 
                 0 
                 30 
                 0 
                 40 
                 — 
                 0 
               
               
                 223 
                 4.0000 
                 100 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 1.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 20 
                 100 
                 100 
                 100 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 50 
                 80 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 30 
                 0 
                 0 
               
               
                 224 
                 1.0000 
                 0 
                 100 
                 100 
                 90 
                 — 
                 50 
               
               
                   
                 0.2500 
                 0 
                 100 
                 60 
                 90 
                 — 
                 10 
               
               
                   
                 0.0625 
                 0 
                 95 
                 10 
                 80 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 40 
                 0 
                 50 
                 — 
                 0 
               
               
                   
                 0.0640 
                 0 
                 0 
                 0 
                 0 
                 — 
                 0 
               
               
                 225 
                 1.0000 
                 30 
                 100 
                 100 
                 90 
                 — 
                 50 
               
               
                   
                 0.2500 
                 30 
                 100 
                 100 
                 90 
                 80 
                 20 
               
               
                   
                 0.0625 
                 0 
                 80 
                 20 
                 80 
                 80 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 50 
                 70 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 20 
                 0 
                 0 
               
               
                 226 
                 1.0000 
                 70 
                 100 
                 100 
                 90 
                 — 
                 60 
               
               
                   
                 0.2500 
                 40 
                 100 
                 100 
                 80 
                 90 
                 30 
               
               
                   
                 0.0625 
                 0 
                 85 
                 30 
                 80 
                 40 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 10 
                 50 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 20 
                 0 
                 0 
               
               
                 227 
                 4.0000 
                 100 
                 100 
                 100 
                 100 
                 0 
                 100 
               
               
                   
                 1.0000 
                 50 
                 100 
                 100 
                 100 
                 0 
                 100 
               
               
                   
                 0.2500 
                 30 
                 100 
                 100 
                 90 
                 0 
                 100 
               
               
                   
                 0.0625 
                 0 
                 100 
                 100 
                 90 
                 0 
                 40 
               
               
                   
                 0.0156 
                 0 
                 90 
                 40 
                 70 
                 0 
                 0 
               
               
                 228 
                 1.0000 
                 40 
                 100 
                 100 
                 100 
                 100 
                 60 
               
               
                   
                 0.2500 
                 10 
                 100 
                 70 
                 90 
                 100 
                 40 
               
               
                   
                 0.0625 
                 0 
                 90 
                 0 
                 50 
                 0 
                 10 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 229 
                 1.0000 
                 65 
                 100 
                 100 
                 100 
                 — 
                 70 
               
               
                   
                 0.2500 
                 0 
                 100 
                 90 
                 90 
                 — 
                 50 
               
               
                   
                 0.0625 
                 0 
                 80 
                 30 
                 70 
                 — 
                 20 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 40 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 20 
                 0 
                 0 
               
               
                 230 
                 4.0000 
                 80 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 1.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 20 
                 100 
                 40 
                 90 
                 100 
                 0 
               
               
                   
                 0.0625 
                 20 
                 100 
                 0 
                 80 
                 20 
                 0 
               
               
                   
                 0.0156 
                 20 
                 90 
                 0 
                 50 
                 0 
                 0 
               
               
                 231 
                 4.0000 
                 90 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 90 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 70 
                 100 
                 100 
                 100 
                 100 
                 60 
               
               
                   
                 0.6250 
                 0 
                 100 
                 100 
                 100 
                 100 
                 30 
               
               
                   
                 0.0156 
                 0 
                 70 
                 40 
                 60 
                 0 
                 9 
               
               
                 232 
                 1.0000 
                 65 
                 100 
                 100 
                 100 
                 — 
                 50 
               
               
                   
                 0.2500 
                 30 
                 100 
                 100 
                 90 
                 — 
                 50 
               
               
                   
                 0.0625 
                 0 
                 100 
                 100 
                 90 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 90 
                 50 
                 80 
                 50 
                 0 
               
               
                   
                 0.0040  
                 0 
                 70 
                 10 
                 50 
                 0 
                 0 
               
               
                 233 
                 1.0000 
                 65 
                 100 
                 100 
                 90 
                 — 
                 80 
               
               
                   
                 0.2500 
                 20 
                 100 
                 50 
                 90 
                 60 
                 50 
               
               
                   
                 0.0625 
                 0 
                 95 
                 10 
                 70 
                 — 
                 0 
               
               
                   
                 0.0156 
                 0 
                 80 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 20 
                 0 
                 0 
               
               
                 234 
                 1.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 70 
               
               
                   
                 0.2500 
                 20 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 0.0625 
                 0 
                 100 
                 60 
                 100 
                 100 
                 20 
               
               
                   
                 0.0156 
                 0 
                 80 
                 10 
                 30 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 30 
                 0 
                 0 
                 0 
                 0 
               
               
                 235 
                 1.0000 
                 0 
                 100 
                 30 
                 100 
                 100 
                 50 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 90 
                 20 
                 20 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 30 
                 0 
                 10 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 236 
                 4.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
                 50 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 30 
                 100 
                 60 
                 100 
                 0 
                 100 
               
               
                   
                 0.0625 
                 10 
                 80 
                 40 
                 60 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 40 
                 0 
                 0 
               
               
                 237 
                 1.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 70 
               
               
                   
                 0.2500 
                 10 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 0.0625 
                 0 
                 100 
                 40 
                 100 
                 100 
                 30 
               
               
                   
                 0.0156 
                 0 
                 95 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 60 
                 0 
                 20 
                 0 
                 0 
               
               
                 238 
                 1.0000 
                 50 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
                 20 
                 100 
                 80 
                 100 
                 90 
                 60 
               
               
                   
                 0.0625 
                 0 
                 100 
                 30 
                 60 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 20 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 239 
                 4.0000 
                 100 
                 100 
                 100 
                 100 
                 100 
                 50 
               
               
                   
                 1.0000 
                 50 
                 100 
                 100 
                 100 
                 100 
                 30 
               
               
                   
                 0.2500 
                 20 
                 100 
                 30 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 90 
                 20 
                 60 
                 20 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 30 
                 0 
                 0 
               
               
                 240 
                 1.0000 
                 10 
                 100 
                 60 
                 100 
                 100 
                 60 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 90 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 90 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 241 
                 1.0000 
                 10 
                 100 
                 40 
                 90 
                 100 
                 60 
               
               
                   
                 0.2500 
                 0 
                 95 
                 10 
                 90 
                 10 
                 10 
               
               
                   
                 0.0625 
                 0 
                 90 
                 0 
                 90 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 10 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 242 
                 1.0000 
                 20 
                 100 
                 60 
                 100 
                 100 
                 60 
               
               
                   
                 0.2500 
                 10 
                 100 
                 0 
                 100 
                 80 
                 40 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 40 
                 0 
                 10 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 10 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 243 
                 1.0000 
                 40 
                 100 
                 100 
                 90 
                 100 
                 50 
               
               
                   
                 0.2500 
                 10 
                 100 
                 90 
                 90 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 10 
                 90 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 90 
                 0 
                 30 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 244 
                 1.0000 
                 20 
                 100 
                 60 
                 100 
                 70 
                 90 
               
               
                   
                 0.2500 
                 0 
                 100 
                 40 
                 50 
                 50 
                 0 
               
               
                   
                 0.0525 
                 0 
                 100 
                 0 
                 30 
                 40 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0040 
                 0 
                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 245 
                 1.0000 
                 20 
                 100 
                 100 
                 90 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 100 
                 90 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 30 
                 70 
                 80 
                 0 
               
               
                   
                 0.0156 
                 0 
                 60 
                 0 
                 0 
                 0 
                 0 
               
               
                   
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                 246 
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                 248 
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                 80 
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                 249 
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                 30 
               
               
                   
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                 50 
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                 0 
                 30 
               
               
                   
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                 250 
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                 80 
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                 30 
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                 251 
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                 252 
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                 80 
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                 80 
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                 80 
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                 30 
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                 253 
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                 80 
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                 50 
               
               
                   
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                 30 
                 0 
               
               
                   
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                 0 
                 40 
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                 254 
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                 100 
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                 100 
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                 100 
               
               
                   
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                 100 
                 50 
                 90 
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                 95 
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                 40 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
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                 0 
               
               
                 255 
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                 60 
               
               
                   
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                 100 
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                 90 
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                 0 
                 30 
                 0 
                 0 
               
               
                   
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                 0 
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                 256 
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                 0 
               
               
                   
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                 20 
                 0 
                 0 
               
               
                   
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                 257 
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                 40 
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                 40 
                 0 
                 10 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 0 
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                 258 
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                 95 
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                 0 
                 20 
               
               
                   
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                 40 
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                 10 
               
               
                   
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                 10 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                   
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                 0 
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                 0 
               
               
                 259 
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                 90 
               
               
                   
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                 100 
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                 60 
               
               
                   
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                 90 
                 40 
                 70 
                 0 
                 0 
               
               
                   
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                 80 
                 0 
                 30 
                 0 
                 0 
               
               
                   
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                 0 
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                 0 
               
               
                 260 
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                 80 
               
               
                   
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                 100 
                 90 
                 100 
                 100 
                 50 
               
               
                   
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                 100 
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                 40 
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                 0 
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                 261 
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                 90 
                 90 
                 60 
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                 20 
                 100 
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                 263 
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                 0 
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                 100 
                 0 
               
               
                   
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                 100 
                 50 
                 0 
               
               
                   
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                 0 
                 0 
               
               
                 264 
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                 100 
               
               
                   
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                 90 
               
               
                   
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                 100 
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                 90 
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                 80 
               
               
                   
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                 100 
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                 90 
                 30 
                 30 
               
               
                   
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                 20 
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                 0 
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                 265 
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                 100 
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                 90 
                 — 
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                 95 
                 10 
                 90 
                 — 
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                 — 
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                 0 
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                 90 
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                 10 
                 80 
                 0 
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                 0 
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                 267 
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                 100 
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                 40 
                 80 
                 — 
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                 95 
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                 80 
                 70 
                 0 
               
               
                   
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                 0 
                 50 
                 0 
                 0 
               
               
                   
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                 0 
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                 268 
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                 — 
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                 — 
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                 95 
                 10 
                 80 
                 60 
                 30 
               
               
                   
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                 65 
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                 70 
                 0 
                 0 
               
               
                   
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                 0 
                 50 
                 0 
                 0 
               
               
                 269 
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                 90 
                 100 
                 — 
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                 100 
                 30 
                 80 
                 — 
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                 95 
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                 80 
                 — 
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                 70 
                 0 
                 80 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 40 
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                 270 
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                 — 
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                 100 
                 30 
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                 — 
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                 100 
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                 80 
                 — 
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                 70 
                 10 
                 80 
                 0 
                 0 
               
               
                   
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                 20 
                 10 
                 60 
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                 271 
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                 — 
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                 50 
                 80 
                 — 
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                 60 
                 0 
               
               
                   
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                 0 
                 60 
                 — 
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                 0 
                 0 
                 50 
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                 0 
               
               
                 272 
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                 80 
                 20 
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                 20 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 0 
               
               
                 273 
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                 100 
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                 100 
                 — 
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                 100 
                 100 
                 90 
                 — 
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                 30 
                 90 
                 60 
                 20 
               
               
                   
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                 70 
                 20 
                 80 
                 30 
                 0 
               
               
                   
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                 30 
                 0 
                 30 
                 30 
                 0 
               
               
                 274 
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                 100 
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                 100 
                 — 
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                 100 
                 100 
                 100 
                 — 
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                 0.0625 
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                 100 
                 30 
                 90 
                 — 
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                 80 
                 30 
                 80 
                 80 
                 0 
               
               
                   
                 0.0040 
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                 60 
                 0 
                 50 
                 0 
                 0 
               
               
                 275 
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                 20 
                 100 
                 100 
                 100 
                 — 
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                 50 
                 90 
                 — 
                 50 
               
               
                   
                 0.0625 
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                 90 
                 10 
                 80 
                 50 
                 10 
               
               
                   
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                 70 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0040 
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                 0 
                 0 
                 30 
                 0 
                 0 
               
               
                 276 
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                 100 
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                 100 
                 — 
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                 0.2500 
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                 100 
                 30 
                 90 
                 — 
                 20 
               
               
                   
                 0.0625 
                 0 
                 95 
                 20 
                 80 
                 — 
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                 0.0156 
                 0 
                 75 
                 0 
                 50 
                 — 
                 0 
               
               
                   
                 0.0040 
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                 20 
                 0 
                 40 
                 0 
                 0 
               
               
                 277 
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                 100 
                 10 
                 100 
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                 50 
               
               
                   
                 02500 
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                 95 
                 0 
                 90 
                 0 
                 10 
               
               
                   
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                 30 
                 0 
                 70 
                 0 
                 0 
               
               
                   
                 0.0156 
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                 30 
                 0 
                 50 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 278 
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                 100 
                 90 
                 90 
                 50 
                 50 
               
               
                   
                 0.2500 
                 0 
                 80 
                 70 
                 90 
                 — 
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                 0.0625 
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                 75 
                 10 
                 70 
                 — 
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                 0.0156 
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                 50 
                 0 
                 50 
                 0 
                 0 
               
               
                   
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                 10 
                 0 
                 20 
                 0 
                 0 
               
               
                 279 
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                 100 
                 100 
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                 100 
               
               
                   
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                 100 
                 100 
                 100 
                 100 
                 70 
               
               
                   
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                 100 
                 90 
                 80 
                 100 
                 50 
               
               
                   
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                 40 
                 30 
               
               
                   
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                 0 
                 30 
                 0 
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                 280 
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                 100 
                 60 
               
               
                   
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                 40 
                 100 
                 100 
                 90 
                 100 
                 50 
               
               
                   
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                 100 
                 100 
                 90 
                 100 
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                 0.0625 
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                 30 
                 0 
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                 20 
                 0 
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                 281 
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                 70 
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                 100 
                 100 
                 100 
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                 0 
               
               
                   
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                 40 
                 0 
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                 0 
                 0 
                 0 
                 0 
               
               
                   
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                 20 
                 0 
                 0 
                 0 
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                 282 
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                 40 
                 90 
                 0 
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                 100 
                 0 
                 50 
                 0 
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                 0.2500 
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                 0 
                 0 
                 0 
               
               
                   
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                 40 
                 0 
                 0 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
                 0 
                 0 
                 0 
               
               
                 283 
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                 100 
                 0 
               
               
                   
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                 30 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 50 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
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                 90 
                 100 
                 0 
               
               
                   
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                 0 
                 20 
                 10 
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                 284 
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                 100 
                 100 
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                 40 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
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                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
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                 0 
                 80 
                 100 
                 0 
               
               
                   
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                 0 
                 0 
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                 0 
               
               
                 285 
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                 100 
               
               
                   
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                 50 
                 100 
                 100 
                 100 
                 100 
                 100 
               
               
                   
                 0.2500 
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                 100 
                 90 
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                 100 
               
               
                   
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                 60 
               
               
                   
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                 0 
                 50 
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                 286 
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                 100 
                 40 
                 100 
                 100 
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                 0.2500 
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                 100 
                 30 
                 90 
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                 80 
                 20 
                 0 
               
               
                   
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                 0 
                 50 
                 10 
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                 287 
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                 100 
                 100 
                 100 
                 100 
               
               
                   
                 1.0000 
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                 100 
                 80 
                 100 
                 100 
                 100 
               
               
                   
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                 100 
                 40 
                 100 
                 50 
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                 100 
                 30 
                 100 
               
               
                   
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                 80 
                 0 
                 60 
                 30 
                 50 
               
               
                 288 
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                 50 
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                 40 
                 90 
                 50 
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                 0 
                 40 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
               
               
                   
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                 50 
                 0 
                 0 
                 0 
                 0 
               
               
                   
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                 0 
                 0 
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                 289 
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                 80 
                 0 
                 40 
                 100 
                 60 
               
               
                   
                 1.0000 
               
               
                   
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                 100 
                 100 
                 100 
                 100 
                 80 
               
               
                   
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                 40 
                 100 
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                 100 
                 100 
                 80 
               
               
                   
                 0.2500 
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                 100 
                 100 
                 100 
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                 50 
               
               
                   
                 0.0625 
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                 50 
                 70 
                 40 
                 0 
               
               
                   
                 0.0155 
                 0 
                 70 
                 0 
                 20 
                 0 
                 0 
               
               
                 291 
                 4.0000 
                 100 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 1.0000 
                 40 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 10 
                 100 
                 0 
                 100 
                 100 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 80 
                 100 
                 0 
               
               
                   
                 0.0156 
                 0 
                 80 
                 0 
                 0 
                 0 
                 0 
               
               
                 292 
                 4.0000 
                 60 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 1.0000 
                 30 
                 100 
                 100 
                 100 
                 100 
                 0 
               
               
                   
                 0.2500 
                 0 
                 100 
                 0 
                 50 
                 0 
                 0 
               
               
                   
                 0.0625 
                 0 
                 95 
                 0 
                 0 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 20 
                 0 
                 0 
                 0 
                 0 
               
               
                 293 
                 4.0000 
                 70 
                 100 
                 100 
                 100 
                 100 
                 90 
               
               
                   
                 1.0000 
                 0 
                 100 
                 100 
                 100 
                 30 
                 90 
               
               
                   
                 0.2500 
                 0 
                 100 
                 100 
                 100 
                 30 
                 0 
               
               
                   
                 0.0625 
                 0 
                 100 
                 0 
                 80 
                 20 
                 0 
               
               
                   
                 0.0156 
                 0 
                 50 
                 0 
                 20 
                 0 
                 0 
               
               
                 294 
                 4.0000 
                 50 
                 100 
                 90 
                 100 
                 100 
                 40 
               
               
                   
                 1.0000 
                 20 
                 100 
                 60 
                 100 
                 20 
                 — 
               
               
                   
                 0.2500 
                 0 
                 100 
                 30 
                 80 
                 0 
                 — 
               
               
                   
                 0.0625 
                 0 
                 80 
                 0 
                 80 
                 0 
                 0 
               
               
                   
                 0.0156 
                 0 
                 0 
                 0 
                 70 
                 0 
                 0 
               
               
                   
               
             
          
         
       
     
     As can be seen from Table 8, the compounds of the present invention have high herbicidal activity against a wide spectrum of weeds and are very selective, e.g., they do not harm rice plants. 
     While the invention has been described with respect to the specific embodiments, it should be recognized that various modifications and changes may be made by those skilled in the art to the invention which also fall within the scope of the invention as defined by the appended claims.