Abstract:
A colorant-donor element for thermal colorant transfer comprising a support having thereon a colorant layer comprising a colorant dispersed in a binder, the colorant layer having associated therewith an infrared-absorbing cyanine colorant having a sulfonic acid group, the cyanine colorant having the following formula: ##STR1## wherein: each W independently represents the atoms necessary to form an optional 6-membered aromatic ring; 
     each X independently represents sulfur or C(CH 3 ) 2  ; 
     each Y independently represents an alkylene group having from about 2 to about 5 carbon atoms; and 
     Z is chlorine or an alkylsulfonyl group having from 1 to about 4 carbon atoms.

Description:
FIELD OF THE INVENTION 
     This invention relates to infrared-absorbing cyanine colorants used in laser-colorant transfer donor elements. In particular, the infrared colorants are useful in laser colorant-transfer systems designed for digital color halftone proofing. 
     BACKGROUND OF THE INVENTION 
     In order to approximate the appearance of continuous-tone (photographic) images via ink-on-paper printing, the commercial printing industry relies on a process known as halftone printing. In halftone printing, color density gradations are produced by printing patterns of dots or areas of varying sizes, but of the same color density, instead of varying the color density continuously as is done in photographic printing. 
     There is an important commercial need to obtain a color proof image before a printing press run is made. It is desired that the color proof will accurately represent at least the details and color tone scale of the prints obtained on the printing press. In many cases, it is also desirable that the color proof accurately represent the image quality and halftone pattern of the prints obtained on the printing press. In the sequence of operations necessary to produce an ink-printed, full-color picture, a proof is also required to check the accuracy of the color separation data from which the final three or more printing plates or cylinders are made. Traditionally, such color separation proofs have involved silver halide photographic, high-contrast lithographic systems or non-silver halide light-sensitive systems which require many exposure and processing steps before a final, full-color picture is assembled. 
     Colorants that are used in the printing industry are insoluble pigments. By virtue of their pigment character, the spectrophotometric curves of the printing inks are often unusually sharp on either the bathochromic or hypsochromic side. This can cause problems in color proofing systems in which colorants, as opposed to pigments, are being used. It is very difficult to match the hue of a given ink using a single colorant. 
     In U.S. Pat. No. 5,126,760, a process is described for producing a direct digital, halftone color proof of an original image on a colorant-receiving element. The proof can then be used to represent a printed color image obtained from a printing press. The process described therein comprises: 
     a) generating a set of electrical signals which is representative of the shape and color scale of an original image; 
     b) contacting a colorant-donor element comprising a support having thereon a colorant layer and an infrared-absorbing material with a first colorant-receiving element comprising a support having thereon a polymeric, colorant image-receiving layer; 
     c) using the signals to imagewise-heat by means of a diode laser the colorant-donor element, thereby transferring a colorant image to the first colorant-receiving element; and 
     d) retransferring the colorant image to a second colorant image-receiving element which has the same substrate as the printed color image. 
     In the above process, multiple colorant-donors are used to obtain a complete range of colors in the proof. For example, for a full-color proof, four colors: cyan, magenta, yellow and black are normally used. 
     By using the above process, the image colorant is transferred by heating the colorant-donor containing the infrared-absorbing material with the diode laser to volatilize the colorant, the diode laser beam being modulated by the set of signals which is representative of the shape and color of the original image, so that the colorant is heated to cause volatilization only in those areas in which its presence is required on the colorant-receiving layer to reconstruct the original image. 
     Similarly, a thermal transfer proof can be generated by using a thermal head in place of a diode laser as described in U.S. Pat. No. 4,923,846. Commonly available thermal heads are not capable of generating halftone images of adequate resolution but can produce high quality continuous tone proof images which are satisfactory in many instances. U.S. Pat. No. 4,923,846 also discloses the choice of mixtures of colorants for use in thermal imaging proofing systems. The colorants are selected on the basis of values for hue error and turbidity. The Graphic Arts Technical Foundation Research Report No. 38, &#34;Color Material&#34; (58-(5) 293-301, 1985) gives an account of this method. 
     An alternative and more precise method for color measurement and analysis uses the concept of uniform color space known as CIELAB in which a sample is analyzed mathematically in terms of its spectrophotometric curve, the nature of the illuminate under which it is viewed and the color vision of a standard observer. For a discussion of CIELAB and color measurement, see Principles of Color Technology, 2nd Edition, F. W. Billmeyer, p. 25-110, Wiley-Interscience and Optical Radiation Measurements, Volume 2, F. Grum, p. 33-145, Academic Press. 
     In using CIELAB, colors can be expressed in terms of three parameters: L*, a* and b*, where L* is a lightness function, and a* and b* define a point in color space. Thus, a plot of a* vs b* values for a color sample can be used to accurately show where that sample lies in color space, i.e., what its hue is. This allows different samples to be compared for hue if they have similar density and L* values. 
     In color proofing in the printing industry, it is important to be able to match the proofing ink references provided by the International Prepress Proofing Association. These ink references are density patches made with standard 4-color process inks and are known as SWOP® (Specifications Web Offset Publications) Color Aims. For additional information on color measurement of inks for web offset proofing, see &#34;Advances in Printing Science and Technology&#34;, Proceedings of the 19th International Conference of Printing Research Institutes, Eisenstadt, Austria, June 1987, J. T. Ling and R. Warner, p.55. 
     Infrared absorbing colorants are used in colorant-donor elements for laser-colorant transfer for the purpose of absorbing the laser energy and converting the radiant energy into thermal energy in order to cause colorant transfer to a receiver element. One problem encountered in the use of infrared colorants is that these colorants often exhibit some absorption in the visible spectrum. In the event that some or all of the infrared colorant is transferred along with the colorant, this absorption may spoil the color purity or hue of the transferred image colorant. 
     DESCRIPTION OF RELATED ART 
     U.S. Pat. No. 4,973,572 relates to infrared-absorbing cyanine colorants for a colorant-donor element used in laser-induced thermal colorant transfer. There is a problem with these colorants in that during processing, the infrared colorant may decompose into colored by-products during transfer, particularly at higher exposures over 300 mJ/ft 2 . This problem can be acute in the case of a cyan image colorant-donor element where yellow decomposition by-products transfer along with the cyan image colorant. In this case, a yellowish a&#34;stain&#34; is added to the transferred image colorant, resulting in an objectionable &#34;greenish&#34; hue. 
     It is an object of this invention to provide a colorant-donor element for laser-induced thermal colorant transfer containing a class of infrared absorbing colorants that substantially do not transfer at exposures over 300 mJ/ft 2 . It is another object of this invention to provide a colorant-donor element for laser-induced thermal colorant transfer containing a class of infrared absorbing colorants that produce decomposition products that are less colored or colorless. 
     SUMMARY OF THE INVENTION 
     These and other objects are obtained by this invention which relates to a colorant-donor element for thermal colorant transfer comprising a support having thereon a colorant layer comprising a colorant dispersed in a binder, the colorant layer having associated therewith an infrared-absorbing cyanine colorant having at least two sulfonic acid groups, the cyanine colorant having the following formula: ##STR2## wherein: each W independently represents the atoms necessary to form an optional 6-membered aromatic ring; 
     each X independently represents sulfur or C(CH 3 ) 2  ; 
     each Y independently represents an alkylene group having from about 2 to about 5 carbon atoms; and 
     Z is chlorine or an alkylsulfonyl group having from 1 to about 4 carbon atoms. 
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     In a preferred embodiment of the invention, the cyanine IR colorant containing at least two sulfonic acid groups may preferably be associated with tertiary alkyl amines as the sulfonic acid amine salt in order to enhance their solubility in organic solvents and in the coated polymer-colorant complex. 
     Examples of sulfonic acid-containing cyanine IR colorants useful in the invention include the following: ##STR3## 
     When coated from organic solvents, these colorants are preferably coated as their amine salts, where the associated amine may be any primary, secondary, or tertiary alkyl or aryl-alkyl amine, and where the alkyl chains may be linear, branched, or cyclic. Preferably, the alkyl groups contain from 2 to 6 carbon atoms. The preferred amines are triethyl, tripropyl, or tributyl amine. 
     The donor elements may optionally contain between the image colorant or pigment bearing layer and the support a sub or barrier sub such as those disclosed in U.S. Pat. Nos. 4,695,288 and 4,737,486 and may include layers formed from organo-titanates, silicates, or aluminates, and the like. Preferably, a layer formed from tetrabutyltitanate is used, available commercially as Tyzor TBT® (Du Pont Corp.). 
     Colorants useful in the invention include both pigments and dyes. Pigments which can be used in the invention include the following: organic pigments such as metal phthalocyanines, e.g., copper phthalocyanine, quinacridones, epindolidiones, Rubine F6B (C.I. No. Pigment 184); Cromophthal® Yellow 3G (C.I. No. Pigment Yellow 93); Hostaperm®) Yellow 3G (C.I. No. Pigment Yellow 154); Monastral® Violet R (C.I. No. Pigment Violet 19); 2,9-dimethylquinacridone (C.I. No. Pigment Red 122); Indofast® Brilliant Scarlet R6300 (C.I. No. Pigment Red 123); Quindo Magenta RV 6803; Monstral® Blue G (C.I. No. Pigment Blue 15); Monstral® Blue BT 383D (C.I. No. Pigment Blue 15); Monstral® Blue G BT 284D (C.I. No. Pigment Blue 15); Monstral® Green GT 751D (C.I. No. Pigment Green 7) or any of the materials disclosed in U.S. Pat. Nos.: 5,171,650, 5,672,458 or 5,516,622, the disclosures of which are hereby incorporated by reference. 
     Dyes useful in the invention include the following: Anthraquinone dyes, e.g., Sumikaron Violet RS® (product of Sumitomo Chemical Co., Ltd.), Dianix Fast Violet 3R-FS® (product of Mitsubishi Chemical Industries, Ltd.), and Kayalon Polyol Brilliant Blue N-BGM®. and KST Black 146® (products of Nippon Kayaku Co., Ltd.); azo dyes such as Kayalon Polyol Brilliant Blue BM®, Kayalon Polyol Dark Blue 2BM®, and KST Black KR® (products of Nippon Kayaku Co., Ltd.), Sumikaron Diazo Black 5G® (product of Sumitomo Chemical Co., Ltd.), and Miktazol Black 5GH® (product of Mitsui Toatsu Chemicals, Inc.); direct dyes such as Direct Dark Green B® (product of Mitsubishi Chemical Industries, Ltd.) and Direct Brown M® and Direct Fast Black D® (products of Nippon Kayaku Co. Ltd.); acid dyes such as Kayanol Milling Cyanine 5R® (product of Nippon Kayaku Co. Ltd.); basic dyes such as Sumiacryl Blue 6G® (product of Sumitomo Chemical Co., Ltd.), and Aizen Malachite Green® (product of Hodogaya Chemical Co., Ltd.); or any of the dyes disclosed in U.S. Pat. Nos.: 4,541,830; 4,698,651; 4,695,287; 4,701,439; 4,757,046; 4,743,582; 4,769,360 and 4,753,922, the disclosures of which are hereby incorporated by reference. The above dyes may be employed singly or in combination. Combinations of pigments and/or dyes can also be used. 
     The colorants used in the invention may be employed at a coverage of from about 0.02 to about 1 g/m 2 . 
     The process of obtaining an image with the colorant or pigment transfer donor elements of this invention has been described in U.S. Pat. No. 5,126,760 and is conveniently obtained on commercially available laser thermal proofing systems such as the Kodak Approval® system, or the Creo Trendsetter® Spectrum system. Typically, a receiver sheet is placed on a rotating drum followed by successive placements of the individual cyan, magenta, yellow and black donor elements whereby the image for each color is transferred by image-wise exposure of the laser beam through the backside of the donor element. 
     The colorants in the colorant-donor of the invention are dispersed in a polymeric binder such as a cellulose derivative, e.g., cellulose acetate hydrogen phthalate, cellulose acetate, cellulose acetate propionate, cellulose acetate butyrate, cellulose triacetate or any of the materials described in U.S. Pat. No. 4,700,207; polyvinyl butyrate; copolymers of maleic anhydride with vinyl ethers such as methyl vinyl ether; polycyanoacrylates; a polycarbonate; poly(vinyl acetate); poly(styrene-co-acrylonitrile); a polysulfone or a poly(phenylene oxide). The binder may be used at a coverage of from about 0.1 to about 5 g/m 2 . 
     The colorant layer of the colorant-donor element may be coated on the support or printed thereon by a printing technique such as a gravure process. 
     Any material can be used as the support for the colorant-donor element of the invention provided it is dimensionally stable and can withstand the heat of the laser. Such materials include polyesters such as poly(ethylene terephthalate); polyamides; polycarbonates; cellulose esters such as cellulose acetate; fluorine polymers such as poly(vinylidene fluoride) or poly(tetrafluoroethylene-co-hexafluoropropylene); polyethers such as polyoxymethylene; polyacetals; polyolefins such as polystyrene, polyethylene, polypropylene or methylpentene polymers; and polyimides such as polyimide-amides and polyether-imides. The support generally has a thickness of from about 5 to about 200 μm. 
     The receiving element that is used with the donor element of the invention usually comprises a support having thereon a colorant image-receiving layer. The support may be a transparent film such as a poly(ether sulfone), a polyimide, a cellulose ester such as cellulose acetate, a poly(vinyl alcohol-co-acetal) or a poly(ethylene terephthalate). The support for the colorant-receiving element may also be reflective such as baryta-coated paper, polyethylene-coated paper, an ivory paper, a condenser paper or a synthetic paper such as DuPont Tyvek®. Pigmented supports such as white polyester (transparent polyester with white pigment incorporated therein) may also be used. 
     The image-receiving layer may comprise, for example, a polycarbonate, a polyurethane, a polyester, poly(vinyl chloride), poly(styrene-co-acrylonitrile), polycaprolactone, a poly(vinyl acetal) such as poly(vinyl alcohol-co-butyral), poly(vinyl alcohol-co-benzal), poly(vinyl alcohol-co-acetal) or mixtures thereof. The image-receiving layer may be present in any amount which is effective for the intended purpose. In general, good results have been obtained at a concentration of from about 1 to about 5 g/m 2 . 
     As noted above, the donor elements of the invention are used to form a colorant transfer image. Such a process comprises imagewise-heating a colorant-donor element as described above and transferring a colorant image to a receiving element to form the colorant transfer image. 
     The colorant-donor element of the invention may be used in sheet form or in a continuous roll or ribbon. If a continuous roll or ribbon is employed, it may have only the colorants thereon as described above or may have alternating areas of other different colorants or pigments or combinations, such as sublimable cyan and/or yellow and/or black or other colorants. Such colorants are disclosed in U.S. Pat. No. 4,541,830, the disclosure of which is hereby incorporated by reference. Thus, one-, two-, three- or four-color elements (or higher numbers also) are included within the scope of the invention. 
     A laser is used to transfer colorant from the colorant-donor elements of the invention. It is preferred to use a diode laser since it offers substantial advantages in terms of its small size, low cost, stability, reliability, ruggedness, and ease of modulation 
     Lasers which can be used to transfer colorant from donors employed in the invention are available commercially. There can be employed, for example, Laser Model SDL-2420-H2 from Spectra Diode Labs, or Laser Model SLD 304 V/W from Sony Corp. 
     A thermal printer which uses the laser described above to form an image on a thermal print medium is described and claimed in U.S. Pat. No. 5,268,708, the disclosure of which is hereby incorporated by reference. 
     Spacer beads may be employed in a separate layer over the colorant layer of the colorant-donor in the above-described laser process in order to separate the donor from the receiver during colorant transfer, thereby increasing the uniformity and density of the transferred image. That invention is more fully described in U.S. Pat. No. 4,772,582, the disclosure of which is hereby incorporated by reference. Alternatively, the spacer beads may be employed in the receiving layer of the receiver as described in U.S. Pat. No. 4,876,235, the disclosure of which is hereby incorporated by reference. The spacer beads may be coated with a polymeric binder if desired. 
     The use of an intermediate receiver with subsequent retransfer to a second receiving element may also be employed in the invention as described in U.S. Pat. No. 5,126,760. A multitude of different substrates can be used to prepare the color proof (the second receiver) which is preferably the same substrate as that used for the printing press run. Thus, this one intermediate receiver can be optimized for efficient colorant uptake without colorant-smearing or crystallization. 
     Optionally, the paper may be pre-laminated or pre-coated with an image receiving or colorant barrier layer in a dual-laminate process such as that described in U.S. Pat. No. 5,053,381. In addition, the receiver sheet may be an actual paper proofing stock or a simulation thereof with an optional laminate overcoat to protect the final image. 
     Examples of substrates which may be used for the second receiving element (color proof) include the following: Flo Kote Cover® (S. D. Warren Co.), Champion Textweb® (Champion Paper Co.), Quintessence Gloss® (Potlatch Inc.), Vintage Gloss® (Potlatch Inc.), Khrome Kote® (Champion Paper Co.), Consolith Gloss® (Consolidated Papers Co.), Ad-Proof Paper® (Appleton Papers, Inc.) and Mountie Matte® (Potlatch Inc.). 
     As noted above, after the colorant image is obtained on a first colorant-receiving element, it may be retransferred to a second colorant image-receiving element. This can be accomplished, for example, by passing the two receivers between a pair of heated rollers. Other methods of retransferring the colorant image could also be used such as using a heated platen, use of pressure and heat, external heating, etc. 
     Also as noted above, in making a color proof, a set of electrical signals is generated which is representative of the shape and color of an original image. This can be done, for example, by scanning an original image, filtering the image to separate it into the desired additive primary colors, i.e., red, blue and green, and then converting the light energy into electrical energy. The electrical signals are then modified by computer to form the color separation data which are used to form a halftone color proof. Instead of scanning an original object to obtain the electrical signals, the signals may also be generated by computer. This process is described more fully in Graphic Arts Manual, Janet Field ed., Arno Press, New York 1980 (p. 358ff), the disclosure of which is hereby incorporated by reference. 
     A thermal colorant transfer assemblage of the invention comprises 
     a) a colorant-donor element as described above, and 
     b) a colorant-receiving element as described above, 
     the colorant-receiving element being in a superposed relationship with the colorant-donor element so that the colorant layer of the donor element is in contact with the colorant image-receiving layer of the receiving element. 
     The above assemblage comprising these two elements may be preassembled as an integral unit when a monochrome image is to be obtained. This may be done by temporarily adhering the two elements together at their margins. After transfer, the colorant-receiving element is then peeled apart to reveal the colorant transfer image. 
     When a three-color image is to be obtained, the above assemblage is formed three times using different colorant-donor elements. After the first colorant is transferred, the elements are peeled apart. A second colorant-donor element (or another area of the donor element with a different colorant area) is then brought in register with the colorant-receiving element and the process repeated. The third color is obtained in the same manner. A four color image may also be obtained using the colorant-donor element of the invention. 
    
    
     The following examples are provided to illustrate the invention. 
     EXAMPLES 
     Example 1 
     The following dyes were employed in the invention: ##STR4## 
     A set of cyan donor coatings, represented by coating examples I-1 to I-11 in Table 1 was prepared as follows: 
     On a 100 μm thick poly(ethylene terephthalate) (PET) support was coated a sub layer of 0.13 gm/m 2  tetrabutyltitanate (Tyzor® TBT, duPont) from a 85/15 (wt/wt) mixture of propyl acetate and n-butanol. The colorant-containing layer coated on the sub layer was comprised of 0.16 gm/m 2  cellulose acetate-propionate (CAP-20, Eastman Chemicals), 0.0314 gm/m 2  Cyan Dye-1, 0.134 gm/m 2  Cyan Dye-2, 0.005 gm/m 2  FC-431 surfactant (3M), and IR colorants 1-4 at levels listed in table 1 for each coating example. The coating solvent was an 85/15 mixture (wt/wt) of n-propyl acetate and n-propanol, which also included from 7 to 15 wt % methanol for the invention examples (see below). 
     For ease of experimentation, the amine salts in examples I-1 to I-11 were formed in the coating solution in situ. This was accomplished by first dissolving the free sulfonic acid form of the colorant in methanol at 2-5% solids, then adding the requisite amount of this concentrated IR colorant solution to the coating solution containing all the other ingredients, including the amine. In these examples, the amine was present at a molar excess of 10-50% relative to the IR colorant. Preliminary experiments had indicated that this method of introducing the IR amine salt gave imaging results identical to those produced by adding a pre-isolated sample of the amine salt at an equimolar ratio of amine to IR colorant. The transmission optical density at 830 nm of the donors prior to imaging was measured and the values listed in Table 1. 
     These cyan donors were imaged on a Creo Trendsetter® Plate Writer with 830 nm diode lasers and modified for digital halftone proofing. A Kodak Approval® Intermediate Receiver sheet Catalogue No. 831 5582, as described in U.S. Pat. Nos. 5,053,381 and 5,342,821, was mounted on the drum on an aluminum carrier plate, and the test donor sheet placed over the intermediate sheet with the coated side facing the Intermediate Receiver sheet. The prints were finished after imaging by laminating, in a Kodak Approval® Laminator, the imaged Intermediates to sheets of Champion 60-lb. Textweb® paper which were initially pre-laminated with Kodak Prelaminate sheets, Catalogue No. 173 9671, as described in U.S. Pat. Nos. 5,053,381 and 5,342,821, in the same laminator. 
     In all the prints made from examples I-1 to I-11, the laser-head power was set at 10 Watts, and a test pattern of transferred colorant was produced as a series of 12 solid area (100% dot) rectangular bars (2.3×19 cm), each imaged at a different and increasing rotational speed, varying from 40 to 150 rpm in 10 rpm increments. In this way, the laser exposure at the donor plane was estimated to vary, respectively, from 657.3 to 175.3 mJ/cm 2 . 
     The Status T Cyan density and the CIE L*a*b* values for each cyan solid area were measured by an X-Rite 938 spectrodensitometer, and a plot of cyan density vs. exposure was used to determine the donor sensitivity for each coating listed in Table 1. 
     This sensitivity is defined as the laser exposure in millijoules per square cm at the film plane required to produce a SWOP cyan density of 1.3. In a similar manner, plots of Status T cyan density vs. L*, a*, and b* produced a set of L*a*b* values at a cyan density of 1.3. The resulting b* values are listed in Table 1. 
     
                       TABLE 1______________________________________            Donor  IR                  Optical                             Exposure  COLORANT   Amine    Density @                             SensitivityElement  (g/m.sup.2)             Salt.sup.1                      830 nm mJ/ft.sup.2  @                                    CIE b*______________________________________I-1    IR-1 (0.032)             NONE     0.44   410    -37.3I-2    IR-1 (0.032             TEOLA*   0.268  610    -36.5I-3    IR-1 (0.032)             TEA*     0.544  210    -39.7I-4    IR-l (0.054)             ThA*     0.84   200    -36.8I-5    IR-1 (0.032)             TBA*     0.664  195    -39.7I-6    IR-l (0.032)             TDDA*    0.606  240    -38.6I-7    IR-2 (0.032)             TEA*     0.521  279    -38.2I-8    IR-2 (0.054)             TEA*     0.736  195    -37.2I-9    IR-2 (0.032)             TBA*     0.506  273    -39.3I-10   IR-2 (0.054)             TBA*     0.753  190    -37.8I-11   IR-3 (0.032)             TBA*     0.443  302    -39.2C-1    IR-C1 (0.022)             --       0.477  320    -34.5C-2    IR-C1 (0.027)             --       0.595  260    -33.2C-3    IR-C1 (0.032)             --       0.642  235    -32.0C-4    IR-C1 (0.043)             --       0.848  207    -30.8______________________________________ *TEA = Triethylamine, TEOLA = Triethanolamine, TBA = Tributylamine, TDDA Tridodecylamine 
    
     The above results show that higher optical density at the laser wavelength leads to lower exposure requirements (greater sensitivity) up to about an OD of 0.9, after which no further increases in sensitivity are observed. The data indicate that for both the comparative coatings C-1-C-4 (with colorant IR-1), and the invention coatings I-3-I-11 which used the colorants IR-2 through IR4, a film optical density of 0.5-0.9 was required in order to keep the exposure required for a 1.3 density under 300 mJ/cm 2 . This is desirable for the purpose of maintaining adequate image productivity rates. For invention examples I-1 and I-2, lower than expected optical densities were observed along with exposure requirements higher than 400 mJ/cm 2 . The reason for this was unknown, although it was presumably related to the lack of solubility of the free sulfonic acid colorant (I-1) or its salt with triethanolamine (I-2) in the coated polymer-colorant complex. 
     All of the invention examples, however, gave lower b* values (more negative) than all of the comparative examples which indicated significantly less IR colorant stain for coatings containing the sulfonic acid colorants. The CIE b* value is a sensitive measure of IR stain in a cyan because it represents the yellow/blue axis where a positive shift would indicate an increase in yellow components, and a negative shift indicates a decrease in yellow components. The cyan colorants coated in the invention examples gave b* values close to -40, thus demonstrating the great improvement in color purity provided by the anionic IR colorants and their amine salts cited in this invention. 
     Additional analysis of the results for two selected examples C-2 and I-9 was carried out by measuring the reflectance curves of transfers having equal measured Status T density and comparing their optical densities at 830 and 465 nm. 
     
                       TABLE 2______________________________________        Absorption at                   Absorption atElement      830 nm     465 nm______________________________________C-2          0.63       0.27I-9          0.24       0.21______________________________________ 
    
     The above results show that more IR colorant and/or decomposition products are transferred for the control sample than for the sample of the invention. 
     The invention has been described in detail with particular reference to preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the spirit and scope of the invention.