Abstract:
In order to improve a responsiveness of the radiation cooling and to switch a cooling position, an exposure apparatus for exposing an object includes a cooling mechanism for radiation-cooling the object, and a regulator for regulating a radiant heat transfer amount between said cooling mechanism and the object.

Description:
[0001]    This application claims a benefit of a foreign priority based on Japanese Patent Applications Nos. 2003-172862, filed on Jun. 18, 2003, and 2004-139681, filed on May 10, 2004, each of which is hereby incorporated by reference herein in its entirety as if fully set forth herein.  
         BACKGROUND OF THE INVENTION  
         [0002]    The present invention relates generally to an exposure apparatus for exposing a plate as an object, and more particularly to cooling of the object in the exposure apparatus that uses light in the X-ray and ultraviolet regions or electron beams as exposure light.  
           [0003]    In exposure, an exposure apparatus irradiates exposure light onto a wafer and causes wafer&#39;s thermal expansions. A wafer chuck usually restrains the wafer, and thus an offset between them seldom occurs.  
           [0004]    However, when the shearing force exceeds the chuck&#39;s restraint force, the wafer offsets from the wafer chuck. Cooling of the wafer is necessary to avoid the offset and to reduce the wafer&#39;s expansion.  
           [0005]    Conventional exposure apparatuses use an i-line lamp having a wavelength of about 365 nm, a KrF excimer laser having a wavelength of about 248 nm, and an ArF excimer laser having a wavelength of about 193 nm as a light source, and the light from the light sources with these wavelengths does not attenuate in the air and is applicable to exposure in the air.  
           [0006]    The exposure in the air enables the gas to be filled between the wafer and the chuck, the energy applied to the wafer to be transmitted to the chuck through the gas between them, and the heat to be collected by cooling the wafer held by the chuck with coolant. Cooling using heat transmissions through the air from a wafer surface is available. See, for example, Japanese Patent Application No. 09-306834, corresponding to U.S. Pat. No. 6,084,938.  
           [0007]    It is predicted the advanced fine processing of the recently promoted semiconductor integrated circuits advances will use a shorter wavelength of the exposure light down to the extremely ultraviolet light having a wave range between 5 and 20 nm.  
           [0008]    However, the EUV light attenuates greatly in the air and is viable only in the vacuum environment in which cooling using the heat transmissions through the air is not available. The temperature control becomes thus difficult in the vacuum environment.  
           [0009]    The electron beam also greatly attenuates its energy in the air, and faces similar difficulties when is used as the exposure light.  
           [0010]    Most conventional cooling methods in the vacuum are classified into a cooling method that uses heat conductions in the solid through coolant, and a method for controlling the temperature of a target by directly controlling the temperature of a radiation plate.  
           [0011]    The heat flux in the radiation heat transfer is very small between two objects with a small temperature difference between them. Efficient heat transfer needs a large heat flux, and therefore a large temperature difference between the wafer and the radiation plate is needed for efficient heat transfer. This condition requires the significantly lowered temperature of the radiation plate. On the other hand, it is difficult for such a temperature control means that directly controls the radiation plate using a Peltier element, etc. to suddenly change the radiation plate&#39;s temperature. When the thermal load turns on and off, as the exposure heat, the temperature control means cannot follow the temperature changes of the object to be controlled.  
           [0012]    In addition, a so-called scanner for scanning a reticle and a wafer relative to the exposure light, and for exposing a reticle pattern onto the wafer generally fixes an exposure position and moves a stage relative to the exposure position for exposure. Thus, as the stage moves, an exposed and heated area moves on the wafer. Therefore, fixing of a cooling position causes a distortion in the wafer when the stage&#39;s moving direction changes because unheated part is cooled.  
           [0013]    Responsive radiation cooling and switching of a cooling position have been thus demanded.  
         BRIEF SUMMARY OF THE INVENTION  
         [0014]    Accordingly, it is an exemplary object of the present invention to improve a responsiveness of the radiation cooling and to switch a cooling position.  
           [0015]    An exposure apparatus according to one aspect of the present invention for exposing an object includes a cooling mechanism for radiation-cooling the object, and a regulator for regulating a radiant heat transfer amount between the cooling mechanism and the object.  
           [0016]    An exposure apparatus according to another aspect of the present invention for exposing an object includes an optical system for introducing exposure light to the object, and a cooling mechanism for radiation-cooling the object, wherein a radiant heat transfer amount between the cooling mechanism and an unexposed area on the object to be cooled is smaller than a radiant heat amount between the cooling mechanism and an exposed area on the object to be cooled.  
           [0017]    An exposure apparatus according to still another aspect of the present invention for exposing an object using exposure light includes an optical system for introducing the exposure light to the object, and a cooling mechanism for radiation-cooling the object, wherein a radiant heat transfer amount between the cooling mechanism and a first area on the object to be cooled is smaller than a radiant heat transfer amount between the cooling mechanism and a second area on the object to be cooled, the first area and the second area opposing to each other with respect to an exposed area on the object along a scan direction, and the second area being located upstream in the scan direction viewed from the exposed area.  
           [0018]    An exposure apparatus according to still another aspect of the present invention for exposing an object includes a radiation plate for radiation-cooling the object, and a shutter, located between the radiation plate and the object, for preventing an unexposed area on the object from being cooled by the radiation plate.  
           [0019]    Other objects and advantages of the present invention will be apparent from the following description taken in conjunction with the accompanying drawings, in which like reference characters designate the same or similar parts throughout the figures thereof.  
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0020]    The accompanying drawings, which are incorporated in and constitute a part of the specification, illustrate embodiments of the invention and, together with the description serve to explain the principles of the invention.  
         [0021]    [0021]FIG. 1 is a schematic structure of an exposure apparatus of one aspect according to the present invention.  
         [0022]    [0022]FIG. 2 is a schematic structure of a wafer stage of a first embodiment according to the present invention.  
         [0023]    [0023]FIG. 3 is a view of a cooling mechanism part of a first embodiment according to the present invention.  
         [0024]    [0024]FIGS. 4A to  4 C show switching of a radiation cooling position of the first embodiment according to the present invention.  
         [0025]    [0025]FIGS. 5A and 5B show a cooling mechanism part of a second embodiment according to the present invention.  
         [0026]    [0026]FIG. 6 is a schematic structure of a third embodiment according to the present invention.  
         [0027]    [0027]FIG. 7 shows a cooling mechanism part of the third embodiment according to the present invention.  
         [0028]    [0028]FIG. 8 shows switching of a radiation cooling position of the third embodiment according to the present invention.  
         [0029]    [0029]FIG. 9 shows switching of a radiation cooling position of a fourth embodiment according to the present invention.  
         [0030]    [0030]FIG. 10 shows switching of a cooling mechanism of a fifth embodiment according to the present invention.  
         [0031]    [0031]FIG. 11 shows switching of a cooling mechanism of a fifth embodiment according to the present invention.  
         [0032]    [0032]FIG. 12 shows switching of a cooling mechanism of a sixth embodiment according to the present invention.  
         [0033]    [0033]FIG. 13 shows switching of a cooling mechanism of a sixth embodiment according to the present invention.  
         [0034]    [0034]FIG. 14 shows switching of a cooling mechanism of a seventh embodiment according to the present invention.  
         [0035]    [0035]FIG. 15 is a device manufacture flow.  
         [0036]    [0036]FIG. 16.is a wafer process shown in FIG. 15. 
     
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS  
       [0037]    Preferred embodiments of the present invention will now be described in detail in accordance with the accompanying drawings.  
       First Embodiment  
       [0038]    [0038]FIG. 1 is a schematic structure of one exemplary exposure apparatus of a first embodiment according to the present invention. The chamber  1  is to separate an exposure atmosphere from the air, and maintains vacuum by a pump (not shown). Exposure light L from a light source (not shown) is introduced into a reticle (or a mask)  2  by an illumination optical system (not shown). The instant embodiment uses a EUV light source as a light source. The EUV light source may use a discharge excitation plasma type EUV light source (or a discharge produced plasma light source), a laser excitation type plasma EUV light source, etc. The illumination optical system includes a mirror and a reflection integrator, and can use, for example, an illumination optical system disclosed in Japanese Patent Application No. 2003-045774 (corresponding to U.S. Pat. No. 2003-031017).  
         [0039]    The exposure light L reflected on the reflection reticle  2  is introduced into a wafer  102  as an object to be exposed, via a mirror  4  in the projection optical system, and a pattern on the reticle  2  is projected onto wafer  102 . The projection optical system may use, for example, six aspheric multilayer mirrors.  
         [0040]    The exposure apparatus of the instant embodiment is a so-called scanner, which scans the reticle  2  and the wafer  10  relative to the exposure light L, and transfers a pattern on the reticle  2  onto the wafer  102 .  
         [0041]    [0041]FIG. 2 is a schematic structure of the wafer stage of the exposure apparatus shown in FIG. 1. A radiation plate  106  is used to radiation-cool the local thermal load on the wafer. The radiation plate is temperature-controlled by Peltier elements, which are held by support members  103  and  108 . The Peltier elements  105 , the radiation plate  106 , and support members  103  and  108  constitute a cooling mechanism.  
         [0042]    A radiation shutter  104  for adjusting a radiant heat transfer amount (i.e., a heat exchange amount through radiation) between the radiation plate  106  and the wafer is located between them. The radiation shutter  104  is made from or covered with a low emissivity material. The radiation shutter  104  shields radiations from the radiation plate  106  so that radiations from the radiation plate  106  do not influence the wafer  102 . The radiation shutters  104   a  and  104   b  are configured independently slidable by a drive mechanism  107 , and two radiation plates  106  can independently turn on and off.  
         [0043]    [0043]FIG. 3 shows a part of cooling mechanism part in the exposure apparatus shown in FIG. 1. A control mechanism (not shown) controls the temperature of the radiation plate through feedback controls over the temperature measured by a temperature sensor  109 . On the rear surface of the Peltier element  105 , a pipe  120  for supplying the coolant is provided as a temperature control mechanism.  
         [0044]    The radiation shutter  104  is subject to the influence of the exposure light L irradiated onto the radiation plate  106  and the wafer  102 . The temperature variations of the radiation shutter  104  would affect the radiations from the radiation shutter  104  to the wafer. Accordingly, the pipe  121  for supplying the coolant to maintain the temperature of the radiation shutter  104  constant is provided as the temperature control part in the shutter  104 .  
         [0045]    [0045]FIGS. 4A, 4B and  4 C indicate a method of switching cooling positions in the scan direction. As the radiation shutter  104   a  (a radiation shutter  104   a  in FIG. 4A) opens, which is located at the moving direction A side of the stage  3  viewed from the exposed area, the exposed part moves to a position opposite to the radiation plate  106   a  and only the exposed part can be cooled just after the wafer  102  is exposed. When the moving direction A of the stage  3  is reversed (as shown in FIG. 4B), the radiation shutter  104   a  shuts and the radiation shutter  104   b  opens. Thereby, the exposed part moves to a position opposite to the radiation plate  106   b , and cools only the exposed part just after the wafer  102  is exposed. When the exposure light L is not irradiated, the radiation shutters  104   a ,  104   b  closes as shown in FIG. 4C to shield the influence of the radiation by the radiation plates  106   a  and  106   b . The predetermined exposure sequence can remove the irradiation energy applied to the wafer immediately after the exposure, through operations in FIGS. 4A, 4B and  4 C.  
         [0046]    Thus, the instant embodiment slides a radiation shutter between the radiation plate and the object to be exposed, and prevents the radiation plate from transmitting radiation to the object at the opposite side, and promptly creates the temperature control OFF state.  
         [0047]    Conversely, the temperature control is switched from an Off state to an On state by sliding the radiation shutter away from between the radiation plate and the object to not shield the radiation from the radiation plate. Thereby, the radiation cooling turns on and off with good responsiveness.  
         [0048]    In cooling the wafer, the instant embodiment does not cool the unexposed area on the wafer, and reduces the shrinkage of the wafer caused by the excessive cooling to the unexposed area on the wafer and the local distortion on the wafer.  
       Second Embodiment  
       [0049]    [0049]FIG. 5 shows a cooling mechanism for cooling a mirror in an exposure apparatus of a second embodiment according to the present invention. Those elements in FIG. 5 other than the cooling mechanism in the exposure apparatus of this embodiment are the same as those in the first embodiment, and a description thereof will be omitted. Those elements in FIG. 5, which are corresponding elements in the first embodiment, are designated by the same reference numerals.  
         [0050]    In order to cool the mirror  4 , the radiation plate  406   a  is provided opposing to the rear surface of the mirror  4 . The radiation shutter  404   a  is arranged between the mirror  4 &#39;s rear surface and the radiation plate. The radiation shutter  404   a  is made from or covered with the low emissivity material. The radiation shutter  404   a  shields radiation emitting from the radiation plate  406   a  so that the radiations by the radiation plate  406   a  do not influence the mirror  4 . As the temperature of the radiation shutter  404   a  changes, the radiation from the radiation shutter  404   a  affects the mirror  4 . Accordingly, the pipe  421   a  for supplying the coolant to maintain the temperature of the radiation shutter  404   a  constant is provided in the shutter  404   a . The temperature of the radiation plate is feedback-controlled based on the temperature measured by the temperature sensor  409 . A pipe  420  for supplying the coolant is provided on the rear surface of the Peltier element  405   a . The temperature of the radiation plate is adjusted using the Peltier element  405   a  by measuring the temperature of the radiation plate using the temperature sensor  409 . When the exposure light is irradiated onto the mirror  4 , the radiation shutter  404   a  opens and the radiation cooling turns on. When the exposure light is not irradiated onto the mirror  4 , the radiation shutter  404   a  shuts and the radiation cooling turns off. Thereby, a responsive radiation cooling method can be realized.  
       Third Embodiment  
       [0051]    [0051]FIG. 6 is a schematic structure around a peripheral of a wafer stage in an exposure apparatus of a third embodiment. Those elements in FIG. 6 other than the wafer stage in the exposure apparatus of this embodiment are the same as those in the first embodiment, and a description thereof will be omitted. Those elements in FIG. 6, which are corresponding elements in the first embodiment, are designated by the same reference numerals.  
         [0052]    A temperature control pipe  130  is formed in the radiation plate and two types of mediums, i.e., a low temperature material and a material that has an almost ambient temperature (“ambient temperature material”), are switched and flowed to turn on and off the radiation.  
         [0053]    [0053]FIG. 7 shows a cooling mechanism part of the third embodiment. A coolant switching valve  133  switches materials between the coolant and the ambient temperature material, and thereby provides responsive radiation cooling.  136  and  137  denote fluid collecting pipes.  134  denotes a coolant supply pipe.  135  denotes a pipe for the ambient temperature.  
         [0054]    [0054]FIG. 8 shows a method of switching cooling positions in the scan direction in the third embodiment. The coolant is supplied to the temperature control pipe  130   a  to the radiation plate  106   a  located at a side of the moving direction A viewed from the stage  3 . The ambient temperature material is supplied to the temperature control pipe  130   b  to turn off the radiation plate  106   b . As a result, the exposed part moves to a low temperature position opposing to the radiation plate  106   a , and only the exposed part can be cooled just after the wafer  102  is exposed. When the moving direction A of the stage  3  is reversed, a cooling position is switched by supplying the ambient temperature material to the temperature control pipe  130   a  and the coolant to the temperature control pipe  130   b . The radiation cooling stops when the exposure stops by supplying the ambient temperature material to the radiation plates  106   a  and  106   b.    
         [0055]    Thus, the instant embodiment flows the coolant in the radiation plate and controls the temperature of the object for radiation cooling. In addition, the instant embodiment flows the material having the almost ambient temperature to prevent heat flux between the radiation plate and the object, and to turn off the radiation cooling. The coolant switching valve regulates these actions, and provides a responsive temperature control.  
         [0056]    In cooling the wafer, the instant embodiment does not cool the unexposed area on the wafer, and reduces the shrinkage of the wafer and the local distortion on the wafer caused by the excessive cooling to the unexposed area on the wafer.  
       Fourth Embodiment  
       [0057]    [0057]FIG. 9 is a schematic structure of a cooling mechanism part in an exposure apparatus of a fourth embodiment. Those elements in FIG. 9 other than the wafer stage in the exposure apparatus of this embodiment are the same as those in the first embodiment, and a description thereof will be omitted. Those elements in FIG. 9, which are corresponding elements in the first embodiment, are designated by the same reference numerals.  
         [0058]    The temperature of the radiation plate  106   a  held by the holder  103  is controlled by always flowing the coolant and adjusting a heating value of the heater  140 .  
         [0059]    When the radiation cooling is not used, the heater heats the radiation plate up to the almost ambient temperature. On the other hand, during the radiation cooling, the heating value of the heater is reduced to cool the radiation plate.  
         [0060]    Similar to the above embodiments, this embodiment also provides effective cooling by arranging a radiation plate that is temperature-controlled by a heater in a scan direction and by removing the local thermal load irradiated onto the wafer when the scanner cools the wafer.  
         [0061]    When the radiation turns off, the instant embodiment maintains the radiation plate at the almost ambient temperature using the heater, and controls the temperature of the radiation plate in accordance with the states of the object, providing the responsive radiation cooling.  
         [0062]    The above embodiment uses the scanner (that follows a step-and-repeat manner). However, the present invention is not limited to this type, and is applicable to a step-and-repeat exposure apparatus that entirely exposes each shot on the object.  
         [0063]    While the exposure apparatuses of the above embodiments use the EUV light as exposure light, the electron beam can be used. Since the electron-beam exposure requires a longer time to expose the object than the exposure that uses the light, the object causes a large local distortion as the unexposed area is cooled on the object. An application of the present invention to the exposure apparatus has a larger effect.  
       Fifth Embodiment  
       [0064]    [0064]FIGS. 10 and 11 are schematic structures of a cooling mechanism part of a fifth embodiment. A Peltier element  105  controls the temperature of the radiation plate  106 . A rear surface of the Peltier element  105  is radiated by flowing the coolant (not shown). The radiation plate  106  in the instant embodiment opposes to the entire front surface of the wafer  102  and cools the entire surface of the wafer  102 . An arrow B indicates a moving direction of the wafer stage, while an arrow A indicates a moving direction of the wafer stage in the scan time. The shutter  104  shields radiation between the radiation plate and the wafer to restrain the thermal influence by the radiation plate  106  on an element other than the wafer  102 . In synchronization with movements of the wafer stage, a radiation plate driver (not shown) moves the shutter  104 . The arrow B′ indicates the shutter&#39;s moving direction. Synchronous movements between the wafer stage and the shutter can limit the area cooled by the radiation plate only to the wafer in the step direction.  
         [0065]    The scan direction also uses a similar mechanism and moves the radiation plate in synchronization with the wafer stage&#39;s scan so as to limit the area cooled by the radiation plate only to the wafer in the scan direction.  
       Sixth Embodiment  
       [0066]    [0066]FIGS. 12 and 13 are schematic structures of the cooling mechanism part of a sixth embodiment that steps the wafer stage  3  in almost one direction. Since the wafer is exposed in almost one direction from one end to the other end, the wafer&#39;s temperature rises not entirely but only on one side. When this wafer is entirely cooled, the exposure-light non-irradiated area is also cooled and its temperature lowers, causing a large temperature distribution on the entire wafer surface. Accordingly, the instant embodiment uses the shutter  104  to shield the exposure-light non-irradiated area to avoid cooling. The shutter  104  closes around the exposure-light irradiated area and stays there for the exposure-light non-irradiated area, whereas the shutter  104  opens the wafer to the end and moves in synchronization with the wafer stage  3  for the exposure-light irradiated area. This can limit the cooling area only to the exposure-light irradiated area for the step direction, and reduce the temperature distribution on the wafer surface.  
         [0067]    When the stage scans in the almost one direction, the scan direction use a similar mechanism and moves the radiation plate in synchronization with the wafer stage&#39;s scan so as to limit the area cooled by the radiation plate only to the exposure-light irradiated area in the scan direction.  
       Seventh Embodiment  
       [0068]    [0068]FIG. 14 is a schematic structure of the cooling mechanism part of a seventh embodiment. The seventh embodiment eliminates the cooling mechanism for the area that does not receive the exposure light in the sixth embodiment. An arrangement in which the scan direction and the step direction are set to always one direction provides the same effect as that of the fifth embodiment.  
       Eighth Embodiment  
       [0069]    Referring now to FIGS. 15 and 16, a description will be given of an embodiment of a device fabricating method using the above exposure apparatus. FIG. 15 is a manufacture flow of semiconductor devices, such as semiconductor chips, for example, ICs and LSIs, liquid crystal panels and CCDs. Step  1  (circuit design) designs a semiconductor device circuit. Step  2  (mask fabrication) forms a mask having a designed circuit pattern. Step  3  (wafer preparation) manufactures a wafer using materials such as silicon. Step  4  (wafer process), which is referred to as a pretreatment, forms actual circuitry on the wafer through photolithography using the mask and wafer. Step  5  (assembly), which is also referred to as a posttreatment, forms into a semiconductor chip the wafer formed in Step  4  and includes an assembly step (e.g., dicing, bonding), a packaging step (chip sealing), and the like. Step  6  (inspection) performs various tests for the semiconductor device made in Step  5 , such as a validity test and a durability test. Through these steps, a semiconductor device is finished and shipped (Step  7 ).  
         [0070]    [0070]FIG. 16 is a detailed flowchart of the wafer process. Step  11  (oxidation) oxidizes the wafer&#39;s surface. Step  12  (CVD) forms an insulating film on the wafer&#39;s surface. Step  13  (electrode formation) forms electrodes on the wafer by vapor disposition and the like. Step  14  (ion implantation) implants ions into the wafer. Step  15  (resist process) applies a photosensitive material onto the wafer. Step  16  (exposure) uses the exposure apparatus  200  to expose a circuit pattern on the mask onto the wafer. Step  17  (development) develops the exposed wafer. Step  18  (etching) etches parts other than a developed resist image. Step  19  (resist stripping) removes disused resist after etching. These steps are repeated, and multilayer circuit patterns are formed on the wafer. The device fabrication method of this embodiment may manufacture a higher quality device than the conventional method.  
         [0071]    As many apparently widely different embodiments of the present invention can be made without departing from the spirit and scope thereof, it is to be understood that the invention is not limited to the specific embodiments thereof except as defined in the claims.