Abstract:
The invention has an object of providing a method of the preparation of a sugar-like flavorous component which imparts a mellow feeling to beverages and flavorous compositions and retains a live flavor even if it is diluted thousands times. The method of the preparation of a sugar-like flavorous component includes steps of adding 1.5 to 3 parts by weight of ion exchange water and 0.02 to 0.05 parts by weight of ethanol to 1 part by weight of molasses in a feed tank, mixing and dissolving these components thoroughly with stirring, and introducing the resulting solution into a spinning cone column (SCC) to treat the solution in the following condition: the temperature in a column: 40 to 60° C., strip rate: 0.5 to 7% and the degree of pressure reduction: 70 to 100 kPa.

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a method of preparing a sugar-like flavorous component by specific treatment using molasses as starting material and to a method of preparing a perfumery composition or a beverage by adding the resulting sugar-like flavorous component. 
     2. Description of the Related Art 
     With regard to the flavor of molasses, the flavorous component is conventionally prepared by extraction using organic solvents. The resulting extract has a caramel-like form, an intensive color and a feature of a distinguished smell. No devised method of utilizing the flavorous component of the molasses has been found. 
     The separation of flavorous substances by using a spinning cone column (hereinafter simply referred to as “SCC”) used in the process of the present invention and mass-transfer equipment are explained in “1st Conference of Food Engineering, 1991, AlChE, Chicago, Ill.”. Also, it is disclosed in the specification of WO90/02493 that vegetables and fruits such as tomatoes, apples and pears are processed using the SCC to obtain a high viscosity component having a low flavor. There are detailed descriptions concerning the design of a column of the SCC in “I. Chem. E. Symp. Series, A128, 167-179, 1992”. The SCC is also used in a process of the recovery of volatile components such as flavors wherein a volatile component (ethanol) is recovered at lower temperatures from a culture solution of fermented yeast (see Process Biochemistry, Vol. 31, No. 7, pp.651-658, 1995). 
     A spinning cone column and a method of removing volatile components from a solution are disclosed in JP-B-7-22646. There is a report that in the recovery of the flavorous components of apples and red berry fruits, the level of the content of free and combined sulfurous acid is lowered to 5 ppm or less (Food and Container, Vol. 39, No. 7, pp.406-408, 1988). In the recovery of flavorous components in Flavourtech (see the specification of U.S. Pat. No. 4,996,945), high recovery rates are obtained in the processing of beer flavors, apples, oranges, grapes, apricots or strawberries flavors. 
     SUMMARY OF THE INVENTION 
     When flavorous components are extracted using an organic solvent like in the conventional method, even a dye of molasses is extracted and contained in the extract, which eventually exhibits a caramel-like color. Because of this unacceptable caramel-like color, the extract is only used for products which demand no special care to the color. Also the conventional method has the problem that water-soluble low molecular weight components can be extracted only insufficiently. The present invention provides a method of the preparation of an isolated sugar-like flavorous component which is added to beverages or flavorous compositions to impart a mellow feeling and natural flavor to the compound products and produces a sensible flavor even if it is diluted thousands times. 
     The inventors of the present invention have made earnest studies to solve the aforementioned problems and, as a result, not only a recovery flavor is simply recovered but also a flavorous component which solves the above problem can be obtained by making good use of the aforementioned SCC. Specifically, 1.5 to 3 parts by weight of ion exchange water and 0.02 to 0.05 parts by weight of ethanol are added to 1 part by weight of molasses, which is dissolved under heat to regulate the viscosity, in a feed tank and these components are thoroughly mixed and dissolved with stirring. The resulting solution is introduced into the spinning cone column (SCC) and treated for 1 to 3 minutes in the following condition: the temperature in a column: 40 to 60° C., strip rate: 0.5 to 7% and the degree of pressure reduction: 70 to 100 kPa, whereby the objective sugar-like flavorous component can be prepared. 
     According to a first aspect of the present invention, there is provided: 
     (1) a method of the preparation of a sugar-like flavorous component, the method comprising steps of; 
     adding 1.5 to 3 parts by weight of ion exchange water and 0.02 to 0.05 parts by weight of ethanol to 1 part by weight of molasses in a feed tank; 
     mixing and dissolving these components thoroughly with stirring; and 
     introducing the resulting solution into a spinning cone column (SCC) to treat the solution in the following condition: the temperature in a column: 40 to 60° C., strip rate: 0.5 to 7% and the degree of pressure reduction: 70 to 100 kPa. 
     (2) In a method of the preparation of a sugar-like flavorous component according to the invention (1), preferably the strip rate is 0.5 to 3% and the sugar-like flavor is highly refined sugar-like flavor. 
     (3) In a method of the preparation of a sugar-like flavorous component according to the invention (1), preferably the strip rate is 3 to 7% and the sugar-like flavor is unrefined sugar-like flavor. 
     According to a second aspect of the present invention, there is provided: 
     (4) a method of the preparation of a flavorous composition, the method comprising adding the sugar-like flavor component obtained by the method as claimed in any one of the above (1) to (3) to a perfumery in an amount of 5 to 30% by weight. 
     According to a third aspect of the present invention, there is provided: 
     (5) a method of the preparation of a beverage, the method comprising adding the sugar-like flavor component obtained by the method as claimed in any one of the above (1) to (3) to a beverage in an amount of 0.01 to 5% by weight. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a schematic view of an spinning cone column (SCC); 
     FIG. 2 is an explanatory view showing a flow of the start of an operation until the start of recovery by an spinning cone column (SCC); and 
     FIG. 3 is a schematic view showing a KD (Kuderna Danish) concentrator. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The present invention will be hereinafter explained in more detail. 
     The raw material, namely, molasses is a by-product in the production of sugar, the production center of imported raw sugar is diversified and the manufacturing place comprises various places. However, as the molasses, those which are used as the usual foods and have a Brix (the content of soluble solids) of about 75 may be all utilized. The viscosity of molasses in the preparation in relation to its concentration is 20 to 60 mPa·s, preferably 40 to 55 mPa·s and more preferably 54 mPa·s in view of its operability. A viscosity exceeding 60 mPa·s results in difficult feed because of a systemic limitation. So the feed solution is adjusted to a viscosity lower than 60 mPa·s. 
     The amount of ion exchange water to be added is 1.5 to 3 parts by weight and preferably 1 to 2 parts by weight based on 1 part by weight of molasses. As the ion exchange water, for example, water which is obtained by treating city water by using an ion exchange resin (e.g., porous resins such as a negative ion exchange resin: RGA416 (manufactured by Mitsubishi Chemical) and a positive ion exchange resin: SK1B (manufactured by Mitsubishi Chemical)) and which has an electroconductivity of 2 μS/cm or less as one of the water qualities thereof. The amount of ethanol is 0.02 to 0.05 parts by weight and preferably 0.02 to 0.04 parts by weight based on 1 part by weight of molasses. 
     As to the strip rate, the maximum strip rate is 10% and the minimum strip rate can be 0.001% if restripping is carried out in a usual operation based on the design of the equipment. In the case of the present invention, the strip rate is 0.5 to 7% and preferably 2 to 6% to obtain a desired flavor of molasses. The resultant flavorous component has a highly refined sugar-like flavor when the strip rate is 0.5 to 3% and a highly refined sugar-like flavor when the strip rate is 3 to 7%. 
     It is necessary that the temperature in the column when the resulting solution is introduced into the SCC column is 40 to 60° C. A temperature exceeding 60° C. causes an offensive smell. The degree of pressure reduction must be 70 to 100 kPa and preferably 80 to 95 kPa. The degree of pressure reduction is changed according to the conditions such as the type of molasses, the amount of alcohol and strip rate. The process time, namely, the time during which the feed solution flows from the heater to the lower portion of the column body is about 1 to 4 minutes and preferably about 2 minutes. This time relates to the amount to be fed after the condition in the column reaches steady state, to the sprit ratio and to what levels are required as the concentration and amount of the feed. 
     Preferably the flavor of the resulting extract ranges from a highly refined sugar-like flavor to a unrefined sugar-like flavor. The content of alcohol contained in the resulting extract is 15 to 65% by weight and preferably 16 to 60% by weight. The specific gravity of the extract is 0.863 to 0.975 and the refractive index of the extract is 1.341 to 1.364. 
     The proportion of the sugar-like flavorous component, obtained by the aforementioned preparation method, in a perfumery is generally in such a range as not to spoil especially the characteristic smell. The sugar-like flavorous component may be added to a perfumery in an amount of 5 to 30% by weight. An excessive amount brings about a too conspicuous sugar-like flavor whereas excessively small amount gives no effect by addition. The amount of the sugar-like flavorous component, obtained by the aforementioned preparation method, to be added in a beverage is 0.01 to 5% by weight. An amount out of the above range makes it impossible to impart a natural flavor like the above. Examples of beverages on which an effect is brought about by applying the sugar-like flavorous component thereto include beverages such as coffee beverages (non-sugar or containing sugar), tea beverages (non-sugar or containing sugar), lactic beverages, fruit juice beverages, cocoa beverages, nutrient beverages, carbonated beverages (non-sugar or containing sugar), sports drinks (non-sugar or containing sugar), cola beverages and a light flavored water (non-sugar or containing sugar), alcoholic beverages such as cocktails, frozen sweets and deserts such as puddings, jellies, yogurts, sherbets, popsicles, gums, candies and tablets and baked sweets such as cookies. 
     The present invention ensures that a unique sugar-like flavorous component which can be applied to a wide range of products can be prepared. The flavorous component obtained in the present invention can impart a natural mellow feeling and sweet to products using artificial/natural sweeteners (excluding sugar) and can give profundity with a pleasant aftertaste to compound perfumeries and beverages. Especially, the astringent taste and bitter taste of tea or coffee, the acrid taste and astringent taste of inorganic salts such as sports drinks can be softened or masked. Moreover, compositions having an effect which cannot be predicted from molasses having a characteristic flavor and color can be prepared. 
     EXAMPLE 
     The present invention will be hereinafter explained in more detail by way of examples, which are not intended to be limiting of the present invention. 
     1. A spinning cone column (SCC), measuring instruments and measurement methods used in examples are as follows. 
     1) SCC: M1000, manufactured by Flavourtech, 300 mm (the inside diameter of the column)×3,700 mm (the height of the column). 
     2) Measurement of refractive index 
     Precision Abbe&#39;s refractometer NAR-3T (ATAGO) 
     3) Measurement of the content of ethanol 
     Gas chromatography 
     Hewlett Packard HP 6890 
     Column TC-WAX (GL Science) (30 m×0.25 mmID, 0.25 μmdf) 
     Detector: TCD, temperature: from 50° C. (4 minutes) to 210° C., the rate of a rise in temperature: 10° C./minute 
     Injection amount: 0.1 μl, sprit ratio: 100:1, injection temperature: 240° C., detection temperature: 240° C. 
     4) Analysis of components 
     Gas chromatography 
     Perkin-Elmer Autosystem GC 
     Column BC-WAX (GL Science) (50 m×0.25 mmID, 0.25 μmdf) 
     Detector: FID, temperature: from 50° C. (4 minutes) to 230° C., the rate of a rise in temperature: 4° C./minute 
     Injection amount: 0.1 μl, sprit ratio: 80:1, injection temperature: 230° C., detection temperature: 230° C. 
     5) Measurement of the content of flavorous components 
     Instrument: Perkin-Elmer Autosystem GC 
     Equipment: see FIG. 3 
     Operation method: 
     300 g of a sample obtained according to the process flow of FIG. 2 was diluted and dissolved in 60 ml of pure water. Isoamyl isovalerate was added as the internal standard to the mixture in an amount of 1 ppm based on the sample. The resulting solution was poured into two columns each packed with 20 cc (5 g) of Bond Elute C-18 (manufactured by *BARIAN*) with a particle diameter of 40 μm. Thereafter, the column was washed with 80 ml of ion exchange water and a flavorous component was extracted using 80 ml of diethyl ether as a desorption solvent. The extract was dried by adding sodium sulfate anhydrous and then placed in a flask after sodium sulfate anhydride was removed. The extracted flavorous component was set on a Kuderna Danish (KD) concentrator shown in FIG.  3  and the flask ( 20 ) was heated to 40 to 45° C. in a water bath ( 21 ) in a nitrogen stream to distill the solvent (ether) which was rapidly cooled and collected in a conical flask ( 25 ) thereby obtaining a residue (including a flavorous component). This residual sample was analyzed by means of gas chromatography to calculate the content of the flavorous component from a relative value of each peak to that of the peak of the internal standard. 
     2. The method of the operation of the spinning cone column (SCC: M1000), the flow process of the start of the operation of the SCC and the regulations of column temperature and stripping ratio will be briefly explained with reference to FIG.  1  and FIG.  2 . 
     Raw materials weighing in accordance with a desired amount to be produced are placed in an SCC feed tank ( 1 ) equipped with a stirrer and stirred sufficiently such that the raw materials are uniformed as a feed material. The feed material is sampled to measure the viscosity and the like. 
     Firstly, city water is allowed to flow from a city water tank ( 1 ′) to the SCC column ( 5 ) to set up the condition required to recover a flavor. The feed amount, the outlet temperature of a heat exchanger and each temperature of the top and bottom of the column are set on an operation control panel. Next, the opening of a vacuum valve is regulated and each temperature of all portions (the top and bottom temperatures of the column) of the SCC column ( 5 ) is determined. The strip rate is determined by regulating the amount of steam supplied from a steam filter ( 4 ) to the column ( 5 ) to confirm whether or not a desired strip rate in accordance with the feed amount is obtained by measuring the amount of city water discharged from a second condenser ( 13 ) and discharged time. If the amount obtained by stripping accords with the set condition, city water is switched to the feed solution. 
     Specifically, the feed solution is allowed to flow from the SCC feed tank ( 1 ) of the SCC equipment to the SCC column ( 5 ) to set up the condition required to recover a flavor like the above case of city water. After a drainage of the feed is discharged from the outlet of the SCC column ( 5 ) and a solution containing a flavor begins to flow out via the second condenser ( 13 ) and a condensate-discharge pump  2  ( 15 ), the flow rate per hour is confirmed and the flavor of the discharged solution is confirmed (whether the strip rate is correct or not) by comparing with that of a standard sample and then the recovery of a flavor is started. At this time, the flavor of the drainage is confirmed. The feed amount, the outlet temperature of a heat exchanger, each temperature of the top and bottom of the column, the degree of vacuum and the strip rate are checked and recorded at intervals of about 30 minutes until the termination of the operation. 
     The SCC was washed immediately after the operation is terminated. The washing is performed sufficiently to the extent that no residual smell is left particularly in the system from the second condenser to the second condensate-discharge pump. 
     Examples 1-3 
     Molasses (manufactured by Sansho, Brix: 75) was used as raw materials  1  and  2  and molasses (manufactured by Sansho, differing from the raw materials  1  and  2  in lot, Brix: 75) was used as a raw material  3 . 
     According to the aforementioned process flow of FIG. 2, the SCC feed tank was charged with 800 kg of ion exchange water and in succession, 400 kg of molasses, which has been heated, was added with stirring to be dissolved. After the molasses was dissolved, 12 kg of ethanol was added and dissolved in the solution. The resulting solution was fed to the SCC at a feed rate of 500 l/h and at strip rates of about 2.5%, 5% and 2.5% for the raw materials  1 ,  2  and  3  respectively at a column temperature of 40 to 60° C. Thus a flavor component was recovered in about 2.5 hours. Each amount of the flavor components recovered from the raw materials  1 ,  2  and  3  were 27 kg, 55 kg and 27.5 kg respectively. The properties of each of the resulting components were as follows. In the table, the specific gravity is a value of d 20   20  and the refractive index is a value of n D   20 . The operations using the raw materials  1 ,  2  and  3  are shown by Examples 1, 2 and 3. 
     
       
         
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 Amount of 
                   
                   
                   
                   
               
               
                   
                 flavorous 
                 Alcohol 
                 Specific 
                 Refractive 
               
               
                   
                 components 
                 content 
                 gravity 
                 index 
                 color 
               
               
                   
                   
               
             
             
               
                   
               
             
          
           
               
                 Example 1 
                 45.5 ppm 
                 18% 
                 0.973 
                 1.3448 
                 Non-color 
               
               
                 Example 2 
                 27.8 ppm 
                 15% 
                 0.975 
                 1.3454 
                 Non-color 
               
               
                 Example 3 
                 48.3 ppm 
                 18% 
                 0.973 
                 1.3449 
                 Non-color 
               
               
                   
               
             
          
         
       
     
     Comparative 1 
     Acetone Extraction 205 g of acetone was added to 100 g of molasses (the same as in the above example) to carry out extraction. The mixture was cooled and allowed to stand all night and was then subjected to a separatory operation. The upper layer was concentrated under normal pressure at 60° C. The concentrated extract was further cooled and allowed to stand all night. Thereafter, suspended solids in the upper part were removed and the lower part was filtered using a filtering adjuvant and the filtrate was concentrated under reduced pressure to distill acetone. The concentrated filtrate was adjusted to Brix 40 by using ion exchange water to obtain 137.5 g of a blackish brown viscous liquid extract. The properties, specific gravity and refractive index of the resulting sugar-like flavorous component were as shown below. 
     Properties: the amount of a flavorous component: 659.6 ppm 
     Specific gravity: 1.137 to 1.153 
     Refractive index: 1.395 to 1.403 
     Comparative Examples 2 and 3 
     SCC Process (Non Alcohol is Added) 
     According to the same process flow as in the aforementioned Example 1, 800 kg of ion exchange water was added in a feed tank. In succession, 400 kg of molasses was raised in temperature and poured into the feed tank with stirring to be dissolved. The dissolved molasses was fed to the SCC column at a flow rate of 500 l/h at a strip rate of 2.5% (Comparative Example 2) and 5% (Comparative Example 3) and a column temperature of 40 to 60° C. to obtain flavorous concentrates in amounts of 29 kg and 58 kg respectively in about 2.5 hours. The properties of the resulting sugar-like flavorous component were as follows. 
     
       
         
               
               
               
               
               
             
               
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 Amount of 
                   
                   
                   
               
               
                   
                 flavorous 
                 Specific 
                 Refractive 
                 Alcohol 
               
               
                   
                 components 
                 gravity 
                 index 
                 content 
               
               
                   
                   
               
             
             
               
                   
               
             
          
           
               
                 Comparative 
                 106.3 ppm  
                 0.987 
                 1.3376 
                 0 
               
               
                 Example 2 
               
               
                 Comparative 
                 67.6 ppm 
                 0.989 
                 1.3369 
                 0 
               
               
                 Example 3 
               
               
                   
               
             
          
         
       
     
     Functional Test Example 1 
     The sugar-like flavorous components obtained in Examples 1 to 3 and Comparative Examples 1 to 3 were respectively applied to blotter to compare the intensity of the flavor (flavorous intensity), flavorous tone and color by 10 trained panelists (years of experience: 4 to 15 years, men and women five each). The results are shown below. 
     
       
         
               
               
               
               
             
               
               
               
               
             
           
               
                   
                   
               
               
                   
                 Flavorous 
                   
                   
               
               
                   
                 intensity 
                 Color 
                 Flavorous tone 
               
               
                   
                   
               
             
             
               
                   
               
             
          
           
               
                 Example 1 
                 2,000 times 
                 Colorless and 
                 Highly refined sugar-like 
               
               
                   
                   
                 transparent 
               
               
                 Example 2 
                 1,500 times 
                 Colorless and 
                 Unrefined sugar-like 
               
               
                   
                   
                 transparent 
               
               
                 Example 3 
                 2,000 times 
                 Colorless and 
                 Highly refined sugar-like 
               
               
                   
                   
                 transparent 
               
               
                 Comparative 
                 1,200 times 
                 Brown and 
                 Flavor heavier and deeper 
               
               
                 Example 1 
                   
                 transparent 
                 than that of the above 
               
               
                   
                   
                   
                 examples 
               
               
                 Comparative 
                 1,600 times 
                 Colorless and 
                 Weaker in top note than 
               
               
                 Example 2 
                   
                 transparent 
                 the above examples 
               
               
                 Comparative 
                 1,200 times 
                 Colorless and 
                 Weaker in top note than 
               
               
                 Example 3 
                   
                 transparent 
                 the above examples 
               
               
                   
               
             
          
         
       
     
     Test Example 2 
     A difference in the content of the component of the resulting extract was measured using gas chromatography. The analysis method is the same as the method described above. 
     The contents of flavor components classified by functional groups in the extract obtained using an internal standard are shown in the following table. 
     
       
         
               
               
               
               
               
               
             
               
               
             
               
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                   
               
               
                 Classi- 
                   
                   
                   
                   
                   
               
               
                 fication 
                   
                   
                   
                 Compara- 
                 Compara- 
               
               
                 accord- 
                   
                   
                   
                 tive 
                 tive 
               
               
                 ing to 
                 Exam- 
                 Exam- 
                 Exam- 
                 Exam- 
                 Exam- 
               
               
                 functional 
                 ple 1 
                 ple 2 
                 ple 3 
                 ple 1 
                 ple 2 
               
             
          
           
               
                   
                 Contents of flavor components 
               
             
          
           
               
                 groups 
                 45.5 ppm 
                 27.8 ppm 
                 48.3 ppm 
                 659.6 ppm 
                 106.3 ppm 
               
               
                   
               
             
          
           
               
                 Alcohol 
                 28.05 
                 15.269 
                 32.383 
                 36.843 
                 76.696 
               
               
                 Ester 
                 2.676 
                 1.981 
                 2.740 
                 — 
                 4.475 
               
               
                 Terpene 
                 1.825 
                 1.467 
                 1.341 
                 — 
                 1.588 
               
               
                 Furan 
                 1.064 
                 0.587 
                 1.024 
                 1.319 
                 0.512 
               
               
                 Lactone 
                 0.287 
                 0.371 
                 0.018 
                 4.202 
                 0.388 
               
               
                 Nitrogen 
                 0.109 
                 0.124 
                 0.077 
                 15.921 
                 0.287 
               
               
                 compound 
               
               
                 Aldehyde 
                 0.107 
                 0.070 
                 0.251 
                 15.697 
                 0.300 
               
               
                 Phenol 
                 0.026 
                 0.076 
                 0.028 
                 14.041 
                 0.101 
               
               
                 Acid 
                 0.065 
                 0.070 
                 0.078 
                 275.616 
                 0.134 
               
               
                 Others 
                 11.281 
                 7.784 
                 10.362 
                 297.281 
                 21.819 
               
               
                   
               
             
          
         
       
     
     Each content of major flavorous components confirmed from the area of the peak of a gas chromatogram in the extract is shown in the following table. 
     
       
         
               
               
               
               
               
               
             
               
               
               
               
               
               
               
             
           
               
                   
               
               
                   
                   
                   
                   
                 Comparative 
                 Comparative 
               
               
                 Compounds showing a peak 
                 Example 1 
                 Example 2 
                 Example 3 
                 Example 1 
                 Example 2 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                  1 
                 2-methyl-3-butene-2-ol 
                 — 
                 — 
                 — 
                 0.430 
                 — 
               
               
                  2 
                 Hexanol 
                 — 
                 — 
                 — 
                 0.354 
                 — 
               
               
                  3 
                 Isobutanol 
                 2.533 
                 1.004 
                 3.177 
                 — 
                 8.139 
               
               
                  4 
                 Isoamyl acetate 
                 0.158 
                 0.074 
                 0.343 
                 — 
                 0.719 
               
               
                  5 
                 4-methyl-3-pentene-2-ol 
                 — 
                 — 
                 — 
                 4.818 
                 — 
               
               
                  6 
                 Butanol 
                 0.132 
                 0.071 
                 0.176 
                 — 
                 0.072 
               
               
                  7 
                 Limonene 
                 0.038 
                 0.040 
                 0.115 
                 — 
                 0.075 
               
               
                  8 
                 Isoamyl alcohol 
                 23.934 
                 13.405 
                 27.639 
                 0.243 
                 64.226 
               
               
                  9 
                 Ethyl caproate 
                 0.114 
                 0.059 
                 0.193 
                 — 
                 0.330 
               
               
                 10 
                 Amyl alcohol 
                 0.098 
                 0.050 
                 0.111 
                 — 
                 0.090 
               
               
                 11 
                 2,3,5,6-tetramethyl-1,4-dioxane-2,5-diol 
                 — 
                 — 
                 — 
                 1.654 
                 — 
               
               
                 12 
                 Octanal 
                 0.107 
                 0.070 
                 0.251 
                 — 
                 0.300 
               
               
                 13 
                 Acetol 
                 — 
                 — 
                 — 
                 0.588 
                 — 
               
               
                 14 
                 Isoamyl isovalerianate 
                 1.000 
                 1.000 
                 1.000 
                 1.000 
                 1.000 
               
               
                 15 
                 Isohexanol 
                 0.174 
                 0.107 
                 0.172 
                 — 
                 0.401 
               
               
                 16 
                 2-heptanol 
                 0.201 
                 0.124 
                 0.195 
                 — 
                 0.510 
               
               
                 17 
                 3-methylpentanol 
                 0.207 
                 0.124 
                 0.251 
                 — 
                 0.323 
               
               
                 18 
                 Hexanol 
                 0.299 
                 0.169 
                 0.303 
                 — 
                 0.475 
               
               
                 19 
                 2-methyl-4-oxopentane-2-ol 
                 — 
                 — 
                 — 
                 9.731 
                 — 
               
               
                 20 
                 2-octanol 
                 0.081 
                 0.049 
                 0.075 
                 — 
                 0.188 
               
               
                 21 
                 Ethyl caprylate 
                 0.255 
                 0.151 
                 0.388 
                 — 
                 0.481 
               
               
                 22 
                 Acetic acid 
                 — 
                 — 
                 — 
                 157.935 
                 — 
               
               
                 23 
                 Furfural 
                 — 
                 — 
                 — 
                 3.316 
                 — 
               
               
                 24 
                 Heptanol 
                 0.121 
                 0.079 
                 0.121 
                 — 
                 0.248 
               
               
                 25 
                 2-ethylhexanol 
                 0.176 
                 0.029 
                 0.057 
                 — 
                 0.192 
               
               
                 26 
                 2-acetylfuran 
                 — 
                 — 
                 — 
                 1.319 
                 — 
               
               
                 27 
                 Propionic acid 
                 — 
                 — 
                 — 
                 9.457 
                 — 
               
               
                 28 
                 Ethyl nonanoate 
                 0.096 
                 0.062 
                 0.141 
                 — 
                 0.134 
               
               
                 29 
                 Octanol 
                 0.101 
                 0.057 
                 0.104 
                 — 
                 0.247 
               
               
                 30 
                 5-methylfurfural 
                 — 
                 — 
                 — 
                 1.729 
                 — 
               
               
                 31 
                 Butyric acid 
                 — 
                 — 
                 — 
                 8.486 
                 — 
               
               
                 32 
                 Ethyl caprate 
                 0.137 
                 0.135 
                 0.257 
                 — 
                 0.329 
               
               
                 33 
                 Furfuryl alcohol 
                 — 
                 — 
                 — 
                 7.846 
                 — 
               
               
                 34 
                 Ethyl benzoate 
                 0.360 
                 0.169 
                 0.305 
                 — 
                 0.572 
               
               
                 35 
                 Isovaleric acid 
                 — 
                 — 
                 — 
                 3.790 
                 — 
               
               
                 36 
                 δ-hexalactone 
                 — 
                 — 
                 — 
                 0.138 
                 — 
               
               
                 37 
                 5-methylfurfuryl alcohol 
                 0.646 
                 0.398 
                 0.693 
                 — 
                 0.539 
               
               
                 38 
                 Decanol 
                 — 
                 — 
                 — 
                 1.342 
                 — 
               
               
                 39 
                 Phenylethyl acetate 
                 1.335 
                 1.089 
                 0.867 
                 — 
                 0.957 
               
               
                 40 
                 cyclotene 
                 — 
                 — 
                 — 
                 3.083 
                 — 
               
               
                 41 
                 β-damascenone 
                 1.030 
                 0.590 
                 0.545 
                 — 
                 0.796 
               
               
                 42 
                 Ethyl laurate 
                 0.192 
                 0.166 
                 0.205 
                 — 
                 0.772 
               
               
                 43 
                 Phenylethyl alcohol 
                 0.341 
                 0.419 
                 0.329 
                 10.192 
                 1.046 
               
               
                 44 
                 2-acetylpyrrole 
                 0.109 
                 0.124 
                 0.077 
                 15.921 
                 0.287 
               
               
                 45 
                 Pantolactone 
                 — 
                 — 
                 — 
                 3.727 
                 — 
               
               
                 46 
                 Caprylic acid 
                 0.065 
                 0.070 
                 0.078 
                 0.720 
                 0.183 
               
               
                 47 
                 γ-nonalactone 
                 — 
                 — 
                 — 
                 0.337 
                 — 
               
               
                 48 
                 Megastigmatrienone-1 
                 0.069 
                 0.061 
                 0.050 
                 — 
                 0.102 
               
               
                 49 
                 4-ethylphenol 
                 0.026 
                 0.076 
                 0.028 
                 — 
                 0.101 
               
               
                 50 
                 Decane-1,5-olide 
                 0.287 
                 0.371 
                 0.018 
                 — 
                 0.388 
               
               
                 51 
                 Megastigmatrienone-2 
                 0.208 
                 0.216 
                 0.018 
                 — 
                 0.380 
               
               
                 52 
                 2,6-dimethoxyphenol 
                 — 
                 — 
                 — 
                 5.745 
                 — 
               
               
                 53 
                 Ethyl palmitate 
                 0.029 
                 0.076 
                 0.041 
                 — 
                 0.181 
               
               
                 54 
                 Megastigmatrienone-3 
                 0.140 
                 0.141 
                 0.122 
                 — 
                 0.235 
               
               
                 55 
                 Benzoic acid 
                 — 
                 — 
                 — 
                 78.127 
                 — 
               
               
                 56 
                 5-hydroxymethyl-2-furfural 
                 — 
                 — 
                 — 
                 10.299 
                 — 
               
               
                 57 
                 Phenylacetic acid 
                 — 
                 — 
                 — 
                 17.102 
                 — 
               
               
                 58 
                 Acetovanillone 
                 — 
                 — 
                 — 
                 8.296 
                 — 
               
               
                   
               
             
          
         
       
     
     The data of Comparative Example 3 is omitted since it is the same as that of Comparative 2 (SCC treatment, non-alcohol, SR: 2.5%). 
     Comparing Example 3 (alcohol is added) with Comparative Example 2 (no alcohol is added) in the ratio of components, the total amount of flavors is larger in Comparative Example 2 (no alcohol is added). It seems that there is no large difference when these flavors are classified by functional groups. However, comparing each component in the flavor balance, the proportion of the amount of components including β-damascenone, octanal, phenylethyl acetate, amyl alcohol, ethyl caprylate, ethyl nonanate and ethyl caprate to the total amount of flavors is larger in Example 3. Each threshold value of, particularly, β-damascenone, octanal and phenylethyl acetate is low, which is supposed to contribute to the sugar-like flavor. 
     Example 4 
     Using the molasses flavor (sugar-like flavor component) obtained in Example 1, a rum flavor was prepared according to the following formulation. 
     
       
         
               
               
               
             
               
               
               
             
           
               
                   
                   
               
               
                   
                 Formulation of a rum flavor 
                 % by weight 
               
               
                   
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Rum ether 
                 20.0 
               
               
                   
                 Vanillin 
                 3.0 
               
               
                   
                 Molasses flavor 
                 20.0 
               
               
                   
                 Rum extract 
                 30.0 
               
               
                   
                 Ethyl propionate 
                 1.0 
               
               
                   
                 Ethyl acetate 
                 2.0 
               
               
                   
                 Ethanol 
                 20.0 
               
               
                   
                 Fusel oil 
                 4.0 
               
               
                   
                 Total 
                 100.0 
               
               
                   
                   
               
             
          
         
       
     
     Example 5 
     Using the molasses flavor (sugar-like flavor component) obtained in Example 2, a tea beverage (non-sugar) was prepared according to the following formulation. Formulation of a tea beverage (non-sugar) % by weight 
     
       
         
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 Tea extract (Brix: 0.25) 
                 99.9 
               
               
                   
                 Molasses flavor 
                 0.1 
               
               
                   
                 Total 
                 100.0 
               
               
                   
                   
               
             
          
         
       
     
     Functional Test Example 2 
     Examples 4 and 5 and examples (controls 1 and 2) using ion exchange water in place of the molasses flavor in these Examples 4 and 5 were compared by the same specialty panelists as above. 
     Flavor tone, Comparison and characteristics 
     Example 4 This has the individual sweetness of rum and produces a better mild rum flavor. 
     Controls This seems to have a fermented odor accompanied by an ester odor, specifically, a chemical odor without the individual sweetness of rum. 
     Example 5 The tea has a faintly sweet flavor and a taste relieved of a unique astringent taste. A sugar-like flavor is left after retort disinfection. 
     Controls This has a more astringent taste than Example 5 and seems to have a strong disinfect odor. 
     From the foregoing results, it is understood that the composition of the present invention can impart a natural flavor and mellowness to compound products and beverages and is largely different from conventional flavorous compositions.