Abstract:
An apparatus for delamination drying a substrate is provided. A chamber for receiving a substrate is provided. A chuck supports and clamps the substrate within the chamber. A temperature controller controls the temperature of the substrate and is able to cool the substrate. A vacuum pump is in fluid connection with the chamber. A tilting mechanism is able to tilt the chuck at least 90 degrees.

Description:
BACKGROUND OF THE INVENTION 
     The present invention relates to the formation of semiconductor devices. More specifically, the invention relates to an apparatus or method for removing liquids from a substrate during the formation of semiconductor devices. 
     During semiconductor wafer processing, wet processing requires the subsequent removal of liquid from semiconductor devices. 
     As semiconductor devices continue to scale down to smaller sizes, higher aspect ratio structures are required to achieve the desired device performance. The fabrication of microelectronic/semiconductor devices requires a repetitive flow of multiple processing steps such as, material deposition, planarization, feature patterning, feature etching, and feature cleaning. The drive towards higher aspect ratio structures creates processing challenges for many of these traditional fabrication steps. Wet processes such as etch and clean, which typically make up greater than ˜25% of the process flow, are particularly challenging on high aspect ratio features due to the capillary forces that are generated during drying. The strength of these capillary forces are dependent on the surface tension and contact angle of the etch, clean, or rinse fluids that are being dried, as well as the feature spacing and aspect ratio. If the forces generated during drying are too high, then the high aspect ratio features will collapse onto each other and stiction may occur. Feature collapse and stiction will severely degrade the device yield. 
     In addition, the formation of capacitors may also provide structures that are subject to collapse during drying. 
     SUMMARY OF THE INVENTION 
     To achieve the foregoing and in accordance with the purpose of the present invention, an apparatus for delamination drying a substrate is provided. A chamber for receiving a substrate is provided. A chuck supports and clamps the substrate within the chamber. A temperature controller controls the temperature of the substrate and is able to cool the substrate. A vacuum pump is in fluid connection with the chamber. A tilting mechanism is able to tilt the chuck at least 90 degrees. 
     In another manifestation of the invention, a method is provided. A substrate, which is wet with a drying chemistry, is placed on a chuck in a drying chamber. The drying chemistry is frozen to a solid drying chemistry on the substrate. The solid drying chemistry is delaminated from the substrate. The delaminated solid drying chemistry is removed from the substrate. 
     These and other features of the present invention will be described in more detail below in the detailed description of the invention and in conjunction with the following figures. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       The present invention is illustrated by way of example, and not by way of limitation, in the figures of the accompanying drawings and in which like reference numerals refer to similar elements and in which: 
         FIG. 1  is a high level flow chart of an embodiment of the invention. 
         FIGS. 2A-C  are schematic illustrations of a delamination drying system in an embodiment of the invention. 
         FIG. 3  illustrates a computer system, which is suitable for implementing a controller used in embodiments of the present invention. 
     
    
    
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     The present invention will now be described in detail with reference to a few preferred embodiments thereof as illustrated in the accompanying drawings. In the following description, numerous specific details are set forth in order to provide a thorough understanding of the present invention. It will be apparent, however, to one skilled in the art, that the present invention may be practiced without some or all of these specific details. In other instances, well known process steps and/or structures have not been described in detail in order to not unnecessarily obscure the present invention. 
     In the current and prior art, alternative rinsing liquids with lower surface tension than deionized water have been implemented to prevent feature collapse. While this method has been successful for lower aspect ratio structures, it suffers the same collapse and stiction issues as deionized water at higher aspect ratios and smaller feature spacing. This failing is due to the fact that these lower surface tension fluids still possess a finite surface tension that generates forces during drying that are too strong for the fragile features. An alternative method to dry high aspect ratio structures is to dissolve and flush the rinsing fluid with a supercritical fluid. Supercritical fluids should generally be free of surface tension and thus eliminate the capillary forces that result in feature collapse. Despite the advantages of supercritical fluids, there are several technical and manufacturing challenges in implementing these fluids. These challenges include high equipment and safety costs, long process times, variable solvent quality during the process, extreme process sensitivity due to the diffuse and tunable nature of the fluid, and wafer defectivity/contamination issues arising from the interaction of the fluid with the chamber parts. Another strategy for preventing collapse of high aspect ratio structures is to add a mechanical bracing structure that supports the features. There are several tradeoffs with this approach including higher cost and process complexity that negatively impact throughput and yield. Furthermore, bracing is not a robust solution since it is limited to certain types of structures. Thus, alternative methods and systems for damage-free removal of liquids from semiconductor/microelectronic devices are desirable. 
       FIG. 1  is a high level flow chart of an embodiment of the invention. In this embodiment, features are formed on a substrate (step  104 ). The features may be formed by wet or dry etching the features, or by a deposition process for depositing features. The features may have such a high aspect ratio that a subsequent drying process would cause feature collapse. A wet process is used on the substrate (step  108 ). The wet process may be used to form the features or may be a subsequent process, such as a cleaning after the features are formed. Liquid from the wet process is displaced with a drying chemistry (step  112 ). In some embodiments, the liquid for the wet process is the same as the drying chemistry; in such a case this step is not needed. The wet substrate is placed in a delamination drying chamber (step  116 ). The atmosphere of the delamination drying chamber is controlled (step  120 ). If the drying chemistry is tert-butanol (TBA), then the controlled atmosphere would be moisture free or have reduced water content. The liquid drying chemistry is frozen (step  124 ). The frozen solid drying chemistry is delaminated from the substrate (step  128 ). The solid drying chemistry is removed from the substrate (step  132 ). The substrate is removed from the chamber (step  136 ). 
     EXAMPLE 
     In a specific example of an embodiment of an invention, a patterned substrate is provided with an etch layer. The etch layer is etched forming memory lines with a CD of less than 40 nm and a pitch of less than 80 nm and a height to width aspect ratio of greater than 10:1 (step  104 ). The substrate is subjected to a wet process, such as the etching or a cleaning process (step  108 ). In this example, the substrate is cleaned with dilute hydrofluoric acid. The substrate is then rinsed with deionized water. The deionized water is then displaced with a liquid drying chemistry (step  112 ), which in this example is pure tert-butanol (TBA). The wet substrate is placed in a delamination drying chamber (step  116 ). 
       FIG. 2A  is a schematic view of an example of a delamination drying system  200  that may be used in this embodiment of the invention. An atmosphere control  204  is in fluid connection with a delamination drying chamber  202 . The atmosphere control  204  controls the pressure and type of gas in the delamination drying chamber  202 . An electrostatic chuck (ESC)  208  is placed in the chamber to support a substrate  206 , such as a wafer. The delamination drying system  200  further comprises a wet transfer station  232 , which provides a method for transferring the wet substrate  206  into the delamination drying chamber  202  and provides a vacuum seal through which the atmosphere can be controlled and the delamination drying process pressure can be achieved. The delamination drying system further comprises a vacuum pump  216 . 
     In this embodiment the ESC  208  comprises a contact layer  212 , a layer of thermoelectric devices  217 , and a body  220 . A thermoelectric power supply  284  is electrically connected to the layer of thermoelectric devices  217 . The thermoelectric power supply  284  provides a voltage to the thermoelectric devices  217 . The thermoelectric power supply  284  uses the magnitude and direction of the voltage to determine whether the thermoelectric devices  217  provide a heat differential or cooling differential and the magnitude of such a differential between the ESC body  220  and the contact layer  212 . A chuck power supply  257  provides a clamping voltage to electrostatically clamp the substrate  206  onto the ESC  208 . A backside cooling and heating system  230  is connect to the ESC  208  and provides a fluid, such as helium, through the ESC  208  to the backside of the substrate  206  to increase heat transfer between the ESC  208  and the substrate  206 . The backside cooling/heating system  230  is also connected to the vacuum pump  216  which allows for the substrate to be vacuum clamped to the ESC  208 . An example of a backside cooling system is described in U.S. Pat. No. 5,835,334 entitled, “Variable High Temperature Chuck for High Density Plasma Chemical Vapor Deposition,” by McMillin et al., which is incorporated by reference for all purposes. A manometer  219  is connected to the delamination drying chamber  202 . Grooves  224  are placed on a surface of the ESC  208 , between the ESC  208  and the substrate  206 . An axel  228  is connected between the ESC  208  and a motor  218 . 
     A controller  270  is controllably connected to the thermoelectric power supply  284 , the chuck power supply  257 , the atmosphere control  204 , the backside cooling and heating system  230 , the vacuum pump  216 , the motor  218 , and the manometer  219 . A solid drying chemistry removal system  244  is placed below the ESC  208 . 
       FIG. 3  is a high level block diagram showing a computer system  300 , which is suitable for implementing a controller  270  used in embodiments of the present invention. The computer system may have many physical forms ranging from an integrated circuit, a printed circuit board, and a small handheld device up to a huge super computer. The computer system  300  includes one or more processors  302 , and further can include an electronic display device  304  (for displaying graphics, text, and other data), a main memory  306  (e.g., random access memory (RAM)), storage device  308  (e.g., hard disk drive), removable storage device  310  (e.g., optical disk drive), user interface devices  312  (e.g., keyboards, touch screens, keypads, mice or other pointing devices, etc.), and a communication interface  314  (e.g., wireless network interface). The communication interface  314  allows software and data to be transferred between the computer system  300  and external devices via a link. The system may also include a communications infrastructure  316  (e.g., a communications bus, cross-over bar, or network) to which the aforementioned devices/modules are connected. 
     Information transferred via communications interface  314  may be in the form of signals such as electronic, electromagnetic, optical, or other signals capable of being received by communications interface  314 , via a communication link that carries signals and may be implemented using wire or cable, fiber optics, a phone line, a cellular phone link, a radio frequency link, and/or other communication channels. With such a communications interface, it is contemplated that the one or more processors  302  might receive information from a network, or might output information to the network in the course of performing the above-described method steps. Furthermore, method embodiments of the present invention may execute solely upon the processors or may execute over a network such as the Internet in conjunction with remote processors that shares a portion of the processing. 
     The term “non-transient computer readable medium” is used generally to refer to media such as main memory, secondary memory, removable storage, and storage devices, such as hard disks, flash memory, disk drive memory, CD-ROM and other forms of persistent memory and shall not be construed to cover transitory subject matter, such as carrier waves or signals. Examples of computer code include machine code, such as produced by a compiler, and files containing higher level code that are executed by a computer using an interpreter. Computer readable media may also be computer code transmitted by a computer data signal embodied in a carrier wave and representing a sequence of instructions that are executable by a processor. 
     The atmosphere is controlled (step  120 ). In this example, since the drying chemistry is TBA, the controlled atmosphere is moisture free. In this example, this may be accomplished by flowing a nitrogen gas that is moisture free. It is believed that the moisture free atmosphere improves the delamination drying, since moisture adsorption would depress the freezing point of the drying solution, and evaporating unfrozen liquid would provide capillary forces, which would cause damage. Such a moisture free atmosphere may not be needed if the drying chemistry is not as hygroscopic as TBA. 
     The wet substrate  206  is transferred through the wet transfer station  232  into the delamination drying chamber  202  at atmospheric pressure (760 Torr) and room temperature, and mounted onto the chuck  208 . The wet transfer station  232  would be connected between a wet processing station and the delamination drying chamber  202 , and may have a robotic mechanism for transferring a substrate from the wet processing station to the delamination drying chamber  202 . After drying, the robotic mechanism in the wet transfer station may be used to remove the substrate from the delamination drying chamber  202  to another chamber. The wet transfer station would be able to handle wet substrates by providing a controlled atmosphere to prevent drying or to prevent other chemical changes to the wet substrate. Some of the liquid drying chemistry may drip from the substrate before or after placing the substrate on the chuck. Grooves  224  in the surface of the chuck allow the wet drying chemistry to flow away from contact surfaces between the chuck and the substrate and prevent pressure build up upon sublimation at reduced chamber pressures. 
     The drying chemistry is frozen (step  124 ). In this example, this is accomplished by cooling the chuck to 0° C. using both the thermoelectric devices  217  and the backside cooling and heating system  230 . The pressure is maintained at about 1 atmosphere, until the drying chemistry is frozen to form a solid drying chemistry  210 . In this example, the freezing was found to take place in 10 seconds. In this example, the frozen drying chemistry is maintained for about 10 seconds. 
     After the drying chemistry is frozen, the solid drying chemistry is delaminated from the substrate (step  128 ). In this example, the chuck is rotated 180°, so that the substrate  206  goes from being above the chuck  208  to below the chuck  208 , as shown in  FIG. 2B . In this example, this is accomplished when the controller  270  provides a signal to the motor  218  to rotate the axel  228 , which rotates the chuck  208 . The pressure is reduced. In this example, a fast pump down is used to pump down the chamber  202  to a pressure between 3 Torr and 0.1 Torr within 25 seconds. The reduction in pressure and the other factors cause the solid drying chemistry  210  to delaminate and fall off of the substrate  206 , as shown in  FIG. 2C . The solid drying chemistry  210  falls into the solid drying chemistry removal system  244 , so that the solid drying chemistry  210  may be removed from the delamination drying chamber  202 . 
     In this example, the chuck  208  is rotated back to the original position, as shown in  FIG. 2A , to place the substrate  206  on top. The pressure is increased back to atmospheric pressure with a moisture-free gas, such as dry nitrogen. The chuck temperature is elevated to room temperature. The electrostatic force is removed from the substrate  206  by removing the chucking voltage. The substrate  206  is removed from the delamination drying chamber  202  (step  136 ). 
     Alternative Embodiments 
     Various alternative embodiments of the invention may be provided. In other embodiments of the invention other drying chemistries may be used. Some of the alternative chemistries may be but are not limited to Dimethyl sulfoxide, cyclohexane, acetic acid, carbon tetrachloride, isopropanol, dimethyl carbonate, water and mixtures thereof. In an embodiment using cyclohexane, where the drying chemistry does not comprise water, the controlled atmosphere may have a low humidity. Such drying chemistries may be a pure liquid or a mixture of two or more liquids. In another embodiment, the wet processing liquid may be used as the drying chemistry, so that the wet processing liquid does not need to be displaced by the drying chemistry. 
     In another embodiment, the displacement of the liquid with the drying chemistry may be performed in the delamination drying chamber. Such processes may spin or may not spin the substrate during the displacement of the liquid with the drying chemistry. 
     In another embodiment the controlled atmosphere may be any inert gas that contains a low percentage or is free of moisture. Certain inert gases, such as Ar, may have advantages for electrostatically chucking/dechucking the wafers from the ESC. 
     In another embodiment, the chuck is precooled, before the substrate is placed on the chuck. In another embodiment, a vacuum or mechanical chuck is used instead of an electrostatic chuck. These embodiments may have a slower cooling time and therefore increase processing time, but may provide other advantages. In another embodiment, liquid nitrogen or cold gases may contact the substrate to provide the cool down. 
     Various different devices may be used to achieve chamber vacuum, such as, a mechanical pump, a cryogenic pump, and/or a turbo molecular pump. An inert gas, such as Ar, He, or N 2 , may be supplied to the chamber at a controlled flow rate to maintain the desired chamber pressure. In an alternative embodiment, no gas is supplied to maintain desired chamber pressure. Preferably, the chamber pressure is maintained at &lt;5 mTorr. For backside cooling or heating, an inert gas, such as but not limited to He or Ar, is supplied to the backside of the electrostatically chucked wafer at a pressure preferably in the range of 1 Torr-40 Torr in order to provide uniform and efficient heat transfer to the wafer. 
     In alternative embodiments, the cooling and/or heating of the substrate may be accomplished by a chiller system with one or more chillers or thermoelectric units. Lifting pins may be used to raise the substrate off of the chuck. 
     In one embodiment after the delamination of the solid drying chemistry is complete, the wafer/ESC may be heated to a temperature near or above the melting temperature of the drying chemistry for a secondary drying. 
     In various embodiments, during the removal of the substrate, the chamber pressure is increased to 760 Torr by the introduction of an inert gas, such as but not limited to N 2 , Ar, or He. The wafer is discharged from the ESC and any wafer backside gas flow is shut off. The wafer is then removed from the chamber. 
     In another embodiment of the invention, a plurality of ESCs with each ESC holding a substrate so that a plurality of substrates is processed at the same time in a single drying chamber. The ESCs may be in a single plane or may be stacked. 
     It was unexpectedly found that delamination may be used to remove drying chemistry, while reducing collapse of small high aspect ratio structures. Embodiments using delamination allow for solid drying chemistry to be removed, which is faster than sublimation or evaporation. Embodiments that remove solid drying chemistry from the chamber require less energy for sublimation and vapor removal. 
     Other embodiments may use other methods or apparatuses for removing delaminated solid drying chemistry. A mechanical arm or a shutter or a vacuum system may be used to mechanically remove the delaminated solid drying chemistry. In various experiments, the delamination causes solid drying chemistry to be ejected off of the substrate a distance of inches even when the substrate is above the chuck and the solid drying chemistry is on top of the substrate. 
     In another embodiment of the invention, high aspect ratio vias are formed in an etch layer. Metal structures are formed in the vias. A wet etch is used to remove the remaining etch layer, leaving the metal structures, which may be used as capacitors. Embodiments of the invention may be used to dry the metal structures to prevent the structures from collapsing. 
     Other embodiments of the invention may be used to prevent photoresist collapse. Other embodiments of the invention would provide a cleaning process on a wafer that does not have high aspect ratio features. 
     Various experiments have found embodiments using delamination with less than 1% collapse damage. Various experiments have found that embodiments using delamination have less residues than processes that use evaporation or sublimation. It is believed that the residues are removed in the solid drying chemistry. Various experiments found that embodiments eliminated collapse for structures located at the edge of large feature arrays, a problem that has been observed for sublimation drying. Various experiments have found that the speed of pumping down the chamber to cause delamination does not increase or decrease damage. This allows for fast pump down speeds to provide faster throughput. Various experiments also found that the freeze hold time of the solid drying chemistry does not influence delamination damage, allowing for short hold times and faster throughput. Various experiments did find that increasing drying chemistry volumes require decreasing pressures to allow delamination. These experiments were performed when the solid drying chemistry was on top of the substrate. Therefore, lower volumes of drying chemistries allow for faster delamination, when the solid drying chemistry is on top of the substrate. It is believed that the higher volume of solid drying chemistry creates more weight which may require more pump down to provide a greater force to delaminate a solid drying chemistry of greater weight. If this is correct, then when the substrate is inverted, so that the drying chemistry is below the substrate, then less pump down may be needed to provide delamination of higher volume drying chemistry. Various experiments found that too low of a volume of the drying chemistry may increase collapse. Therefore, some embodiments would use an optimized volume of drying chemistry. 
     From various experiments, it has been found that for some drying chemistries, the freezing temperature used in delamination would be significantly greater than the freezing temperature used in freeze drying. For example, for delamination drying using tert-butanol as the drying chemistry, the drying chemistry is cooled to about 0° C., whereas for freeze drying, the drying chemistry would be cooled to less than −20° C. Therefore, delamination drying does not require as much of a temperature change, allowing for a faster process and reduced system requirements. 
     Various embodiments eliminate the need for special bracing of high aspect ratio features, which reduces overall process complexities and costs. These embodiments can be applied to all types of microelectronic topography, whereas bracing is limited to very specific applications. 
     It is believed that embodiments of the invention provide a thin layer of sublimation between the solid drying chemistry and the substrate. If such sublimation is not uniform, then the delamination may work with features with retrograde surfaces. 
     While this invention has been described in terms of several preferred embodiments, there are alterations, permutations, and various substitute equivalents, which fall within the scope of this invention. It should also be noted that there are many alternative ways of implementing the methods and apparatuses of the present invention. It is therefore intended that the following appended claims be interpreted as including all such alterations, permutations, and various substitute equivalents as fall within the true spirit and scope of the present invention.