Abstract:
A method for fabricating an interconnect system is provided. A low dielectric constant layer (LDCL) is formed onto a substrate. A hard mask is formed onto the LDCL. A patterning material is formed onto the hard mask. The patterning material is via patterned. A via pattern of the patterning material is transferred to the hard mask. The patterning material is stripped at a substantially low temperature. Vias are formed through the LDC using a via pattern formed in the hard mask.

Description:
BACKGROUND OF THE INVENTION  
         [0001]    (1) Field of the Invention  
           [0002]    The present invention generally relates to fabrication of interconnect systems. More specifically, the present invention relates to fabrication of via plugs in interconnect systems that include low dielectric constant materials.  
           [0003]    (2) Description of the Related Art  
           [0004]    Modern integrated circuits are generally made up of a silicon substrate containing millions of active and passive devices including transistors, capacitors, and resistors. Such devices are initially isolated from one another, but are later interconnected together to form functional circuits. The quality of the interconnection of these devices drastically affects the performance and reliability of the fabricated integrated circuit. An interconnect system typically includes metal lines, spaced apart from each other, with dielectric layers therebetween that isolate the metal lines from one another. The metal lines typically interconnect the various active and passive devices residing in a silicon wafer to which the interconnect system is coupled.  
           [0005]    Inherent in the structure of the interconnect system is a capacitance associated with the metal lines and the distance therebetween, i.e., inter-metal-line capacitance (hereinafter “capacitance”). Decreasing this capacitance is desirable as several advantages can be achieved therefrom, such as reduced RC delay, reduced power dissipation, and reduced cross-talk between the metal lines. As the capacitance is inversely proportional to the distance between the metal lines, one way to reduce the capacitance formed between the lines of an interconnect system would be to increase the space between these lines. However, this option is not desirable because of limitations imposed by packing density.  
           [0006]    However, as the capacitance of an interconnect system is also directly proportional with the dielectric constant of a dielectric disposed between these lines, a better way to reduce the capacitance of the interconnect system is to utilize a dielectric material with a low dielectric constant. Typically, interconnect systems use a dielectric material such as silicon dioxide (SiO 2 ). The dielectric constant of SiO 2  is approximately 4. Other dielectric materials that are used in interconnect systems include silicon oxyfluoride (SiOF), with a dielectric constant of 3.5 and below.  
           [0007]    Incorporating dielectric materials with low dielectric constants in interconnect systems, however, is problematic. Low dielectric materials, such as organic polymers, may not adequately mechanically support the structure of the interconnect system as these materials are mechanically weak. Moreover, low dielectric constant materials such as organic polymers are vulnerable to certain processes involved in the fabrication of the interconnect system. For example, polymers have to withstand high temperatures and mechanical stresses at which the interconnect system is subjected. Also, polymers used in an interconnect system interact with photoresist solvents and developers used in the process of fabrication of the interconnect system. Moreover, polymers are vulnerable to exposure to photoresist solvents and developers as the polymers may dissolve in the solvents or developers and swell. Furthermore, polymers are vulnerable to oxygen plasma used .in ashing.  
           [0008]    An interconnect system typically utilizes via plugs made of tungsten (W), by way of non-limiting example, that interconnect the various layers of metal lines within the interconnect system. The vias plugs connect various layers of metal lines therebetween within the interconnect system. The process of connecting devices by interconnects is known as metallization. Current semiconductor fabrication processes typically utilize aluminum as metal for interconnects. Aluminum is superior to the other metals, such as copper, gold, and silver, for example, in terms of relative ease of deposition and patterning onto the semiconductor substrate.  
           [0009]    Once the via plugs are formed in an interconnect system, the via plugs are subjected to a process of chemical mechanical polishing (CMP), wherein a CMP slurry solution is used to polish and thereby planarize the outer parts of the via plugs. The CMP slurry solution, however, may cause deterioration or contamination of the polymer within which the via plugs are formed, if the interconnect system utilizes a polymer.  
           [0010]    Low dielectric polymers suffer of other deficiencies that may discourage their incorporation in interconnects and formations of vias therein. The low dielectric polymer material may interact with via barrier and plug formation. Low dielectric constant polymer materials may interact in tungsten CMP processes. Also, low dielectric polymer materials have lower thermal stability (relative to silicon oxides).  
           [0011]    With continued device scaling technology, it becomes more important to both reduce and control the interconnect thermal budget in processing. High temperature processing, after device formation, may have an adverse effect in transistor performance. Once the devices have been created, it is desirable to create the interconnects as low as possible processing temperature history. Typically, the photoresist is stripped at a temperature that may exceed 200 to 420 degrees Celsius when oxygen plasma or a microwave discharge is used.  
           [0012]    It is desirable to provide an interconnect system that may accommodate the above-mentioned shortcomings of polymers or materials similar thereto.  
         BRIEF SUMMARY OF THE INVENTION  
         [0013]    The present invention provides a method for fabricating an interconnect system. A low dielectric constant layer (LDCL) is formed onto a substrate. A hard mask is formed onto the LDCL. A patterning material is formed onto the hard mask. The patterning material is via patterned. A via pattern of the patterning material is transferred to the hard mask. The patterning material is stripped at a substantially low temperature. Vias are formed through the LCDL using a via pattern formed in the hard mask.  
       
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS  
       [0014]    The features, aspects, and advantages of the present invention will become more fully apparent from the following Detailed Description, appended claims, and accompanying drawings in which:  
         [0015]    [0015]FIG. 1 illustrates a cross-section of a first layer of dielectric deposited on a substrate of an interconnect system according to one embodiment of the present invention;  
         [0016]    [0016]FIG. 2 shows a cross-section of the interconnect system of FIG. 1, with a patterning layer of photoresist formed upon the hard mask according to one embodiment of the present invention;  
         [0017]    [0017]FIG. 3 shows a first hard mask layer etched, according to the pattern defined by the photoresist mask, according to one embodiment of the present invention;  
         [0018]    [0018]FIG. 4 shows a cross-section of the interconnect system, with the patterning layer stripped, according to one embodiment of the present invention;  
         [0019]    [0019]FIG. 5 illustrates a cross-section of the interconnect system, with a second layer of the hard mask etched through in accordance with the via pattern formed in the first hard mask layer, according to one embodiment of the present invention;  
         [0020]    [0020]FIG. 6 illustrates a cross-section of the interconnect system, with vias patterned into a low-dielectric-constant (low-k) polymer layer, according to one embodiment of the present invention;  
         [0021]    [0021]FIG. 7 shows an interconnect system with a layer of electrically conductive material, formed upon the hard mask and in the vias, according to one embodiment of the present invention;  
         [0022]    [0022]FIG. 8 illustrates a cross-section through the interconnect system, with via plugs formed into the low-k polymer layer, according to one embodiment of the present invention; and  
         [0023]    [0023]FIG. 9 illustrates the interconnect system, with a layer of metal deposited over the hard mask and in electrical contact with the via plug, according to one embodiment of the present invention;  
     
    
     DETAILED DESCRIPTION OF THE INVENTION  
       [0024]    In the following description, numerous specific details are set forth to provide a thorough understanding of the present invention. However, one having an ordinary skill in the art will recognize that the invention can be practiced without these specific details. In some instances, well-known circuits, structures and techniques have not been shown in detail to avoid unnecessarily obscuring the present invention.  
         [0025]    [0025]FIG. 1 illustrates a cross-section of an interconnect system  100  according to one embodiment of the present invention. The interconnect system  100  includes a silicon substrate  102 . Silicon substrate  102  may be, by way of non-limiting example, a semiconductor wafer including device regions such as diffused junctions, other structures such as gates, local interconnects, metal layers, or other active or passive device structures or layers. In many cases, depending upon the device being fabricated (interconnect-system for example), device layers or structures, or processing steps used to fabricate the device according to the present invention, may have been omitted to avoid unnecessarily obscuring the present invention.  
         [0026]    The interconnect system  100  also includes a first dielectric layer  104  formed upon substrate  102 . The first dielectric layer  104  serves the purpose of insulating between any conductive structures which may be found in the silicon substrate  102  and other conductive layers or lines which are further formed in the interconnect system  100 . First, dielectric layer  104  typically has a dielectric constant which is substantially equal to  4 . The first dielectric layer  104  typically has a thickness in the range of approximately a few thousand Angstroms. For example, the thickness of layer  104  may be approximately 6,000 Å. The first dielectric layer  104  may be made of materials such as, but not limited to: silicon dioxide (SiO 2 ), undoped or doped using dopants such as Phosphorus (PSG, Silicate Glass) or Boron and Phosphorus (BPSG, Doped Silicate Glass); silicon nitride (Si 3 N 4 ); or silicon oxi-nitride (SiOxNy).  
         [0027]    A first level of at least two electrically conductive interconnect lines  117 , which are typically made of aluminum, are formed upon the first dielectric layer  104 . The interconnect lines  117  may be formed by depositing a layer of a first electrically conductive material such as aluminum or an alloy thereof upon the first dielectric layer  104 . Following the deposition of this first electrically conductive layer, a patterning layer such as photoresist layer (not shown) is formed. The photoresist layer is patterned by well known techniques, which include masking the layer of photoresist, exposing the masked layer of photoresist to light, and then developing the portions not exposed to light. The layer of electrically conductive material is then etched in alignment with the pattern formed in the photoresist layer thereby producing the pattern of interconnect lines  117  shown in FIG. 2. In one embodiment of the present invention, the electrically conductive lines  117  have a thickness in the range of 4000-10,000 Angstroms, but the present invention is not limited to such thickness range.  
         [0028]    Once the electrically conductive interconnect lines  117  are etched as explained above, a material with a low dielectric constant (LDC) is deposited upon and therebetween interconnect lines  117  thereby forming region  106 . The low dielectric constant of the LDC preferably has a value in the range of 1.5-3.5, although this value may be higher. In the embodiment shown in FIG. 2, the region  106  of material with a low dielectric constant may include a polymer or amorphous-fluorocarbon (a-F:C) by way of non-limiting example with a thickness in the range of a few thousand Angstroms. Acceptable polymers are ones that are stable at high temperatures, since most polymers tend to decompose at high temperatures The temperatures at which the polymers may be stable are generally temperatures within the range of 380-450° C., which are compatible with integrated circuit process temperatures. Organic materials, such as polyarylether, polynaphthalene, parylene, or amorphous fluorocarbons, (a-F:C) which are stable at high temperatures may be used for layer  106 . The polymer region  106  confers the interconnect system  100  a low inter-metal capacitance as the inter-metal capacitance, generally, is proportional with the dielectric constant of the material interposed between metal lines.  
         [0029]    Following formation of polymer region  106 , hard mask  110 , which improves the mechanical strength of the interconnect system, is deposited upon polymer region  106 . Hard mask  110  is typically made of SiO 2  or may be a dual layer hard mask including a first hard mask layer  112  of Si 3 N 4  and a second hard mask layer  114  of SiO 2 . Materials of which hard masks may be made include SiC, a-C, BN, SiO 2  or Si 3 N 4  but are not limited to this group of materials. Hard mask  110  has a higher dielectric constant than the dielectric constant of polymer of region  106 . For example, the dielectric constant of the hard mask  110  is approximately  4  while the polymers used for region  106  have an average dielectric constant of approximately 2.2-3.0. The hard mask  110  typically has a thickness sufficient to withstand process steps such as chemicol mechnaical polishing (CMP), metal etch, etc., involved in the fabrication of the interconnect system according to the present invention. Each of these processes may erode part of the hard mask and therefore the thickness of the hard mask is designed to insure that the various processes the interconnect system undergoes do not fully erode hard mask  110 . The layer of hard mask  112  may have a thickness in the range of 200-2000 Å, and the layer of hard mask  114  may have a thickness in the range of 200-2000 Å, for example. By way of example, an average thickness of the polymer region measured from a top surface of the metal lines  117  to a bottom surface of hard mask  110  may be in the range of approximately 6000-7000 Å.  
         [0030]    [0030]FIG. 2 shows a cross-section of the interconnect structure illustrated in FIG. 1 with a patterning layer  116  (photoresist layer) formed upon hard mask  110 . and the structures such as electrically conductive interconnect lines  117 , polymer region  106  and hard mask  110 . A photoresist layer  116  is formed on top of hard mask layer  114 . The photoresist layer  116  can have a thickness of approximately a few thousand Angstroms to a micron. Photoresist layer  116  is made of a suitable photosensitive material and is processed using standard techniques. An oxide etch then follows through photoresist  116 , forming openings  115 , positioned at places where the hard mask  110  will subsequently be etched.  
         [0031]    [0031]FIG. 3 shows second hard mask layer  114  etched, according to the pattern defined by the photoresist mask  116 , with an etchant having a high selectivity to the second hard mask layer  114  (SiO 2 ) relative to the first hard mask layer  112  (Si 3 N 4 ) beneath the hard mask  114 . Once the second hard mask  114  is etched, the via pattern of the photoresist  116  is transferred to second hard mask  114  that displays a pattern with openings  118  therethrough as shown in FIG. 3. The hard mask  114  with the pattern of openings  118  therethrough is thereafter used as a mask in the subsequent process of etching hard mask  112 .  
         [0032]    The photoresist  116  is then removed (FIG. 4) at a low temperature process relative to temperatures used in conventional techniques. Almost room-temperature stripping is performed on photoresist  116 . The photoresist is essentially dissolved in a solution that includes inter olia, ethylene glycol monethyl ether acetate (EGMEA), propylene glycol monoethyl ether acetate (PGMEA), ethyl lactate (EL), ethyl pyruvate (EP), methyl-3-methoxy propionate (MMP). By effective use of a dual hardmask (viz. patterning of the second hard mask layer  114  (SiO 2 ) and not of the first hard mask layer  112  (Si 3 N 4 )), the photoresist may be selectively removed without attack of the low-k dielectric  106  by a low temperature scheme. Conventional plasma or microwave ashing of photoresist is eliminated. The dual layer of hard mask  110  provides a differential etch stop. The top part of the hard mask (hard mask layer  114 ) may be used to transfer the pattern directly to the subsequent remainder layer  112  of the hard mask. This provides more precision to the etching of vias subsequently done through the polymer layer  106 .  
         [0033]    Etching is then continued at FIG. 5, where portions of the first hard mask layer  112  corresponding to the pattern of openings  118  are removed by using an etchant such as CF 4 , C 2 F 6 , SF 6 , etc. that is more selective to the portion  112  of the hard mask than to the polymer  116 .  
         [0034]    In FIG. 6, the interconnect system  100  is shown with the vias  120  patterned into the low dielectric polymer layer  116  by a conventional process of etching. By utilizing the embodiment of the process of the present invention described herein over-etching and long-term exposure of the bottom of the via to oxygen is reduced or eliminated since the photoresist is removed before the via is produced through the polymer. The process is usable in both landed or unlanded via schemes. FIGS.  1 - 9  represent the process for the landed scheme.  
         [0035]    [0035]FIG. 7 shows a cross-section through interconnect system  100  with a layer  122  of electrically conductive material such as tungsten (W) formed upon hard mask  110  and into vias  120 . The electrically conductive material is blanket deposited upon hard mask  110  and into vias  120  by a process of chemical vapor deposition (CVD), which is well known in the art.  
         [0036]    Following the tungsten blanket deposition, a process of chemical mechanical polishing (CMP) is applied to the layer of (ingsten  122  thereby providing the interconnect system shown in FIG. 8. The CMP process ensures that the top surface of each via plug  120  is planarized and the rest of the Tungsten, deposited on top of hard mask  110  is removed. Via plugs  120  serve the purpose of electrically interconnecting electrically conductive interconnect lines  117  with other interconnect lines (not shown) which are further deposited upon hard mask  110 . A CMP slurry, used in the CMP process, is selected to have a higher selectivity to tungsten than to hard mask  110 . The slurries can be, by way of non-limiting example be silica or alumina with an Oxidizer. The CMP slurry may contaminate the polymer region  106 . The hard mask  110  prevents the contamination of polymer region  106  by the CMP slurry. The hard mask  110  also works as a CMP stop layer.  
         [0037]    [0037]FIG. 9 illustrates the interconnect system with a layer of metal  129  deposited over the hard mask  110  and in electrical contact with via plugs  120 . This layer of metal may be used to form a new level of interconnect lines that are electrically connected to interconnect lines  117  through vias  120 .  
         [0038]    The hard mask  110  thus serves multiple purposes. First, it serves the purpose of a patterning mask for defining via holes, at lower temperatures, into the polymer. The hard mask  110  also serves as a barrier protection against the photoresist strip etchant process, which is performed to strip the photoresist material left at via patterning. Additionally, the hard mask serves as a barrier protection when the upper level of conductive lines is patterned. Moreover, the hard mask serves as a Tungsten CMP stop during the process of CMP of the tungsten. Furthermore, hard mask  110  serves the purpose of metal patterning etch stop which prevents a polymer from being attacked as a result of a metal patterning process performed on the metal disposed on top of the hard mask.  
         [0039]    In the foregoing specification, the invention has been described with reference to specific embodiments thereof. It will however be evident that various modifications and changes can be made thereto without departing from the broader spirit and scope of the invention as set forth in the appended claims. The specification and drawings are, accordingly, to be regarded in an illustrative rather than a restrictive sense. Therefore, the scope of the invention should be limited only by the appended claims.