Abstract:
A hot water heater or similar heating device includes equipment for pre-cooling hot flue gas while preheating water for the water heater. It further includes a heat and mass exchanger for transferring heat and water from the pre-cooled flue gas to combustion air for the hot water heater. The pre-cooler may comprise a separate device or may be incorporated as part of a condensing water heater. The heat and mass exchanger may use membranes having condensing sides and evaporating sides, which allow water to pass from the condensing sides to the evaporating sides. It may further comprise troughs for wetting the membranes.

Description:
BACKGROUND OF THE INVENTION 
       [0001]    1. Field of the Invention 
         [0002]    The present invention relates to methods and apparatus for improving the efficiency of systems such as gas hot water heaters by a process of humid flue gas heat recovery. 
         [0003]    2. Discussion of Related Art 
         [0004]    Most industrial processes use large quantities of fuel and electricity that ultimately produce heat, much of which is wasted either to the atmosphere or to water. A variety of methods and equipment have been developed to reuse some of this waste heat. This may save up to approximately 20 percent of a facility&#39;s annual fuel bill and, in some instances, reduce pollution emissions and plant maintenance. However, in other applications it may increase pollutants (e.g., preheating combustion air increases combustion temperatures which can increase NOx) and maintenance. 
         [0005]    Waste heat&#39;s usefulness is determined by its temperature; the higher the temperature the higher the quality or value. Most waste-heat-recovery devices transfer heat from a high-temperature effluent stream to a lower-temperature input stream. This can either increase the temperature of the input stream, or change the input stream from a liquid to a vapor, as in a water heater or boiler. All these devices can be broadly categorized as heat exchangers. 
         [0006]    Heat recovery equipment must take into account temperature, pressure ranges, corrosiveness of the effluent and input streams, presence of materials that could foul the heat exchange surfaces, and thermal cycling. Extreme values of any of these may dictate the use of special materials and design, resulting in high implementation costs. In addition, the waste-heat source and the site for use of the recovered heat should be reasonably close. 
         [0007]    In a process that requires heat as input, using waste heat can displace fuel or electricity that would otherwise have to be purchased. Of course, the waste heat recovered has to account for enough fuel savings to make up for capital and operational costs of the heat-recovery equipment. 
         [0008]    In actual industrial facilities several processes may exist that could use the waste heat. The higher the temperatures of the waste heat the more potential gain that would be available. 
         [0009]    This list identifies process input and output characteristics that can help give a relative sense of possible energy savings from waste-heat recovery.
       The greater the temperature, flow rate and moisture content, the greater the quantity of heat in the stream.   The proximity of waste-heat to possible processes that could uses this heat influences total energy savings, due to heat loss in fluid transit from the source, and the energy required to move the fluid.   Latent heat from the condensation of moisture in exhaust gas can be significant; however condensation is often undesirable due to low condensing temperatures and the potential for corrosion down-stream of the heat-recovery device.       
 
         [0013]    Waste-heat recovery can save up to 20% of the energy costs in industrial facilities, as noted earlier. Most of the energy savings will affect fuel consumption, however, electrical heating of ancillary equipment may also be affected. 
         [0014]    Most gas or oil water heaters on the market today are simply a hot water storage tank, cold water in, hot water out, insulated tank, combustor, a gas or oil regulator valve and a center flue gas to hot water heat exchanger tube using natural buoyancy of hot flue gas. See, for example,  FIG. 3A  (prior art). Because the exhaust gases can still be hot when leaving the system there are known several patents that add ambient air to the flue gas to cool down the flue gas requiring a blower and additional ducting: see U.S. Pat. Nos. 5,697,330 and 7,159,540. 
         [0015]    To increase efficiency, a blower can also be added to overcome any pressure drop created by an internal baffle in the heat exchanger tube, see U.S. Pat. No. 7,032,543. 
         [0016]    There is at least one known flue gas treatment that removes carbon monoxide with the use of a catalyst converter, see U.S. Pat. No. 7,055,465. 
         [0017]    U.S. Pat. No. 4,175,518 describes a water heating system with a preheater which utilizes hot flue gases to preheat not only incoming cold water, but also for recirculating and preheating water from the storage tank of the system. Preheaters for hot water heating systems are not per se new. It has been suggested many times in the past that hot flue gases may be used in order to preheat incoming water for a hot water tank. 
         [0018]    Today a popular water heater on the market is the Condensing Water Heater, (CWH). See, for example,  FIG. 3B  (prior art). The drawback to the CWH is that often hot water use is sporadic so that small amounts of cold water are brought in and the burners are on for a much longer time than the water coming in. This means there is often little to no incoming water to preheat the hot exhaust gas and thus little efficiency gain. These condensing water heaters apparatus and methods are well known for adding additional heat exchange with cold water entering or in the tank cooling the flue gases to below their dew point temperature causing water to condense out (see U.S. Pat. Nos. 4,541,410 and 4,651,714). However, in such a water heater the hot exhaust gas is cooled with cold or cool water that is not always available and may discharge hot flue gas from the heat exchanger with insufficient cooling for condensing preventing high efficiency. 
         [0019]    The water heaters of the conventional type described above often have less than ideal levels of combustion efficiency and undesirably high levels of emitted pollutants such as Nitrogen Oxide and Carbon Monoxide. 
       SUMMARY OF THE INVENTION 
       [0020]    The present invention improves the thermal efficiency of a water heater (or similar heating equipment) whenever the equipment is in operation, and not just when cold water is available to cool flue gases. Providing high efficiency is accomplished by reducing the flue gas temperature below its dew point temperature or lowering its enthalpy to near the outdoor air temperature enthalpy whenever in operation. This is accomplished by a second stage Heat and Mass Exchanger (HMX) that heats and humidifies input combustion air while cooling and condensing flue gas. A first stage heat exchanger or condensing hot water heater initiates the flue gas cooling and/or condensing process. The condensing starts at a much higher temperature than previous water heaters due to the added humidity in the combustion air and thus a higher dew point temperature of the flue gas. 
         [0021]    The present invention lowers the Nitrogen Oxide and Carbon Monoxide of the combustion process by increasing the absolute humidity of the combustion air. Reducing Nitrogen Oxide and Carbon Monoxide becomes a side benefit of the high humidity created to lower flue gas enthalpy. 
         [0022]    The present invention further transports water from the HMX condensing channels through membranes to the evaporative channels directly. This provides an efficient means to transfer heat and transfer water from the condensing side to the evaporation side with little or no water makeup needed. 
         [0023]    The invention delivers the desired amount of water at any time through the unique design of a trough. 
         [0024]    The present invention provides an improved heat recovery process and apparatus for transferring “waste” heat from the exhaust gases for a water heater, boiler, furnace, or other heating equipment, where the waste heat is used to heat or preheat water, air or some other substance that is needed (such as water in a water heater) and to heat and humidify the air supplied to a combustion chamber, through the use of flue gas latent heat. 
         [0025]    The heat recovery method of the invention makes use of pre-cooling and a heat and mass exchanger that create the following advantages:
       1. High Efficiency all the time, rather than just when a large amount of hot water is being used;   2. Raised condensing temperature, which results in higher temperature condensing waste heat to heat with;   3. Less pollution due to moisture in combustion;   4. Higher efficiency heat and mass transfer in the HMX;   5. Trough reservoir that delivers correct amount of water all the time;   6. Better burning;   7. Can be located outside water heater, which allows retrofitting.       
 
         [0033]    The present invention provides heat recovery apparatus comprising a counter flow heat and mass exchanger (HMX) for a water heater, boiler, furnace, and other heating equipment. 
         [0034]    The HMX apparatus was specifically designed to be an efficient cooler for the flue gas, and simultaneously to saturate the input combustion air before this air enters the combustion apparatus. In addition and because of the higher efficiency through the HMX, pollution is dramatically reduced due to the high levels of water vapor creating a more even burning process during combustion. Additional water will not be needed, because the proposed heat recovery process and apparatus constantly reclaims water condensed in the flue gas. 
         [0035]    Drain water can come from two sources: water condensed from the flue gas in the water heater or heat exchanger by heating or preheating water; and water condensed from the flue gas in the HMX (minus what is evaporated by the combustion air in the heat and mass exchanger). At higher outdoor air temperatures the HMX may produce more evaporation than condensing, creating a need for water to be added. 
         [0036]    The HMX has counter flowing evaporation and condensing channels on opposite sides of a heat exchange membrane, which: 
         [0000]    1) allows heat transfer through the voids in the membrane filled with water, due to the thin polymer wick construction (or other suitable materials), but minimizes heat transfer laterally along the plate;
 
2) allows mass (water) transfer from condensing channels to evaporative channels through the membrane, due to the membranes structure or ability to hold water by capillarity of membrane construction.
 
         [0037]    The membrane also has perforations between the condensing side of the membrane and the evaporative side or the membrane in defined areas, providing water flow from the condensing channels to the evaporative channels in which indirect evaporative cooling takes place. This direct transfer of water from the condensation side to the evaporation side reduces the heat and mass transfer resistance. Along the plate the hot flue gas temperature is transferring both sensible and latent heat and condensing in direct contact with water evaporating and heating combustion air. This makes for very efficient heat and mass transfer as condensing on one side of the membrane and evaporation directly on the opposite on the other side of the membrane results in more direct transfer of sensible and latent heat. 
         [0038]    This system works by continuous cycling of water, by evaporating it into the combustion air stream while condensing it from the flue gas. This cycling of water is kind of like a heat pipe that evaporates and condenses a refrigerant. In both cases energy is transferred from one source to another through evaporation and condensing. 
         [0039]    The HMX provides an indirect evaporative cooler having efficient wicking action via a trough, allowing easy wetting of the surface area of the wet channels without excess water (which would cool the water rather than the air). 
         [0040]    There are a couple ways to increase the efficiency of a gas hot water heater. High efficient hot water heaters on the market today gain their efficiency by preheating the cold water going into the water heater with the exhaust gas leaving the water heater. When exhaust or now flue gas is cooled to a low enough temperature water vapor from burning the fuel, (oxidizing or combining the H with O 2  to get H 2 O), partially condenses adding a significant amount of heat to the cold water coming in. Therefore even the latent heat (condensing water vapor), is used to heat the water. Condensing water vapor adds a significant amount of heat to the system considering that it takes 1 Btu to cool one pound of water 1° F. and 1040 Btu to condense that same one pound of water vapor. Adding the latent heat has a significant effect on the thermal efficiency. This is all built into the internal design of water heaters according to the present invention. 
         [0041]    The present invention significantly raises the dew point temperature of the flue gas making it possible to at a minimum preheat the hot water and in many cases heat the hot water to its high temperature. The proposed high efficiency heat recovery method starts the moment the hot exhaust gases pass through the counter flow heat and mass exchanger (HMX). It is not dependent on cold water that may be short-lived or not present, such as when bringing the water heater up to temperature without any cold water being added. 
         [0042]    Within the HMX low temperature flue gas has its energy transferred to the combustion air through temperature and humidity exchange. The flue gas temperature is cooled to below its dew point temperature or more importantly lowering its enthalpy to near the input combustion air temperature enthalpy whenever it is in operation. 
         [0043]    Raising the combustion air temperature requires less heating of the air fuel mixture, and is therefore more efficient. What is more surprising is that adding humidity to the combustion air will also reduce the fuel needed. The added humidity increases the mass flow of the input combustion air at a higher temperature requiring less fuel to heat the hot water. 
         [0044]    Water vapor has other positive effects. For example, it comprises polyatomic molecules (three atoms H 2 O as opposed to two atoms like O 2  or N 2 ), that can radiate and be radiated to. This ability to radiate reduces hot spots in the burning process giving more complete burning with about half the amount of NOx, an endothermic or energy draining reaction. This is similar to but better than an automobile engine that uses a small amount of Exhaust Gas Recirculation or CO 2  plus H 2 O recirculation to lower its NOx. The higher efficient burning at lower temperatures also decreases the carbon monoxide in the same way as reducing NOx. 
         [0045]    The present heat recovery method and apparatus can also include implementing the Maisotsenko Cycle or M-Cycle (see paper: L. Gillan, “Maisotsenko cycle for cooling process”, Clean Air, 9 (2008) 1-18), which is also suited for the HMX, especially in the winter time, when the dew point temperature is low. This more thermally efficient process cools the input combustion air to near its dew point in the working air dry channels, and humidifies working air in its wet channels. This is in preparation for cooling and condensing water from the combustion exhaust gas and further heating and humidifying the input air that is now combustion air. 
         [0046]    The air psychrometric saturation line slopes such that cool air has a greater change in energy for a given humidity ratio change than at higher temperatures. This means that in a Humid Air Recovery (HAR) HMX there will be more condensation than evaporation, producing distilled water. The design of this HAR HMX takes into account the higher rate of condensation from the combustion exhaust gas than the water evaporated by allowing condensate to pass directly through the plate. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0047]      FIG. 1  is a block diagram illustrating a preferred embodiment of an HMX Humid Air Recovery (HAR) system for a gas hot water heater according to the present invention. 
           [0048]      FIG. 2A  is a schematic diagram of a preferred embodiment of a HAR system, using a membrane. 
           [0049]      FIG. 2B  is a schematic diagram of the embodiment of  FIG. 2A , showing water held by the membrane. 
           [0050]      FIG. 3A  (prior art) is a schematic diagram showing a conventional non-condensing water heater 
           [0051]      FIG. 3B  (prior art) is a schematic diagram showing a conventional Condensing Water Heater (CWH) 
           [0052]      FIG. 3C  is a schematic diagram showing a hot water heater similar to that of  FIG. 3B , but with an HMX HAR system according to the present invention. 
           [0053]      FIG. 4  is an isometric diagram showing a preferred embodiment of an HAR system utilizing a counterflow HMX and troughs to provide water. 
           [0054]      FIG. 5  is an isometric drawing showing the bottom of a trough of  FIG. 4  coated with an impervious coating. 
           [0055]      FIG. 6  is an isometric drawing showing a stack of the troughs of  FIGS. 4 and 5  with overflow perforations 
           [0056]      FIG. 7  is an isometric diagram of an HAR system utilizing a counterflow HMX and troughs, utilizing an end cap for the trough stack. 
           [0057]      FIG. 8  is a schematic diagram showing a counterflow HMX according to the present invention. 
           [0058]      FIG. 9  is a schematic diagram showing an HMX according to the present invention, wherein input combustion air first travels along dry sides of membranes. 
           [0059]      FIG. 10  is a schematic diagram of an HMX similar to  FIG. 9 , with the input combustion air eventually split into two streams and turned to travel counterflow. 
           [0060]      FIG. 11  is a schematic block diagram of a system for providing a combustor with saturated combustion air according to the present invention. 
       
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Reference Number List 
       [0000]    
       
           1 ,  301  Input Combustion Air 
           2 ,  302  Saturated Combustion Air 
           3 ,  303  Combustor 
           4 ,  304  Hot Flue Gas 
           5 ,  305  Precooled (Warm) Flue Gas 
           6 ,  306  Flue Gas Out (Cool) 
           7 ,  307  Heat and Mass Exchanger HMX 
           8 ,  308  Pre-cooler 
           9  Water Heater 
           10  Pump 
           11  Cold Water In 
           12  Cooling Water 
           13  Heated Water 
           14  Hot Water Out 
           15  Cool Water to Tank 
           16  Liquid (Condensate) 
           17  Drain Water 
           18  Trough 
           19  Membrane,s (Plates) 
           20  Fan 
           22  Heat 
           23  Evaporated Water 
           24  Membrane Water 
           25  Trough End Cap 
           26  Dry (condensing) Side of Membrane 
           27  Trough Overflow Perforations 
           28  Channel Guide 
           29  Impervious Coating 
           30  Wet (evaporating) Side of Membrane 
           32  Condensing Water Heater 
           34  HMX Humid Air Recovery System 
           35  Flue Gas Coil 
           36  Tank Water 
           37  Flue Gas Channels 
           38  Combustion Air Channels 
           39  Tank of Hot Water Heater  9   
           40  Non-condensing Water Heater 
           41  End Element 
           42  Fuel 
           300  Combustor System 
       
     
         [0101]      FIG. 1  is a block diagram illustrating a preferred embodiment 34A of a Humid Air Recovery (HAR) water heater system, including a Heat and Mass Exchanger (HMX)  7  and a Pre-cooler  8  (in this case a pre-condenser) for a gas Hot Water Heater  9  according to the present invention.  FIGS. 2A and 2B  illustrate the process. 
         [0102]    In a preferred embodiment of HAR HMX system  34 , Input Combustion Air  1  is forced into Heat and Mass Exchanger (HMX)  7  by Fan  20 , where it is heated and saturated with Water  24  becoming Saturated Combustion Air  2 . Water  24  is heated by Precooled Flue Gas  5 . The water may comprise Condensate  16  and/or an independent source of water such as shown in  FIGS. 4-7 . 
         [0103]    Saturated Combustion Air  2  then enters Combustor  3  where it is combusted with Fuel  42  and used to heat Cool Water  15  within Tank  39  of Water Heater  9 . The somewhat cooler Hot Flue Gas  4  then enters Pre-cooler  8  where it is cooled to below its condensing temperature by Cooling Water  12  (generally comprising Cold Water  11  and/or Cool Water  15 ), and becomes Precooled Flue Gas  5  (aka warm flue gas). Thus, Hot Flue Gas  4  preheats Cold Water  11  or heats Cool Water  15 , and is itself cooled to become Precooled Flue Gas  5 . Water condenses from Hot Flue Gas  4  and becomes Condensate  16 . Precooled Flue Gas  5  and Condensate  16 , (if the flue gas is cooled below its dew point temperature), are provided to HMX  7 . Because Cold Water  11  may not be flowing at all times when Water Heater  9  is calling for heat, Pump  10  may be provided to pull Cold Water  11  or Cool Water  15  into Pre-cooler  8  (as Cooling Water  12 ). Cooling Water  12  is warmed within Pre-cooler  8  and returns to Tank  39  as Heated Water  13 . 
         [0104]    Precooled Flue Gas  5  is further cooled in HMX  7  causing additional condensation (not shown). Condensate  16  may drain to Trough  18  (See  FIGS. 4-7 ) in HMX  7  ensuring an adequate water supply when outdoor weather conditions are hot and dry. Excess water from Trough  18  becomes Drain Water  17  that is drained from the system. 
         [0105]    In a typical non-condensing water heater,  FIG. 3A  (prior art), Cold Water  11  into Water Heater  9  is delivered through a Tube  31  where it starts to mix in Water Heater  9  Tank  39  becoming Cool Water  15 . Input Combustion Air  1  enters the bottom of the Water Heater  9  where it enters Combustor  3 . The exhaust Flue Gas  4  passes through Water Heater  9 , heating the water and leaving. Hot Water  14  leaves the tank for use. 
         [0106]    In a typical Condensing Water Heater  32 ,  FIG. 3B , (there are many varieties), Input Combustion Air  1  is directed into Combustor  3  through an induced draft Fan  20  that pulls Hot Flue Gas  4  to the top of Flue Gas Coils  35 . Water  36  is heated, cooling the flue gas below its dew point temperature creating Condensate  17  that is collected and drained from the system. 
         [0107]    A Condensing Water Heater  32  can replace Pre-cooler  8  in  FIG. 2 , such that the systems needs only HMX  7  as shown in HMX Humid Air Recovery  34 B in  FIG. 3C . This eliminates the need for Pump  10 . 
         [0108]      FIG. 2A  is a schematic diagram of a preferred embodiment of Humid Air Recovery, using a Membrane  19 . Hot Flue Gas  5  provides Heat  22  in the form of higher temperature and condensate to Membrane  19  becoming Flue Gas Out  6 . Evaporated Water  23  is taken up by Input Combustion Air  1  becoming Saturated Combustion Air  2 .  FIG. 2B  is a schematic diagram of the embodiment of  FIG. 2A , showing Water  24  held by Membrane  19  which is evaporated by Heat  22  to become Evaporated Water  23  into Input Combustion Air  1  becoming Saturated Combustion Air  2 . Water  24  may also be wicked onto the surface of Membrane  19  facing Input Combustion Air  1  (the wet side of membrane  19 ). 
         [0109]      FIG. 3A  (prior art) is a schematic diagram showing a conventional Non-condensing Water Heater  40 .  FIG. 3B  (prior art) is a schematic diagram showing a conventional Condensing Water Heater (CWH)  32 . Fuel in  42  is not shown. 
         [0110]    In a typical Non-condensing Water Heater  40  or CWH  32 , the condensing temperature of Hot Flue Gas  4  would be about 131° F. This is based on the amount of water created by the oxidation of the hydrogen. This temperature is so low that it can only be used to somewhat preheat Cold Water  11  entering Water Heater  9  but typically not sufficiently heat Cool Water  15  within Tank  39 . Non-condensing Water Heater  40  uses about 70% of the heat from Hot Flue Gas  4 , as it passes straight up the center of Tank  39 . 
         [0111]    CWH  32  does well when Cold Water  11  is entering Tank  39 , as Hot Flue Gas  4  takes a circuitous path  35  within Tank  39 . The efficiency of CWH  32  quickly drops off to about 80% efficiency or less when Cold Water  11  is not entering Tank  39 . 
         [0112]      FIG. 3C  is a schematic diagram showing a Hot Water Heater  9  similar to that of  FIG. 3B , but with an HMX HAR system according to the present invention.  FIG. 3C  shows the advantages of the present invention. When humidity is added to Input Combustion Air  1  in HMX  7 , Saturated Combustion Air  2  is formed. The Hot Flue Gas  4  dew point temperature rises to about 160° F. This temperature is typically hot enough to either heat or preheat Cool Water  15 . Hot Water Out  14  of Water Heater  9  is often only set at about 130° F. so that it will not be too hot and cause burns at the water faucets. This allows the 160° F. condensing flue gas to sufficiently heat the water. In addition, because the water is causing Hot Flue Gas  4  to condense, the latent heat of vaporization can heat a significant amount of water to a much higher temperature. 
         [0113]    In order to better understand this Humid Air Recovery method, Table 1 has four mathematical simulations: run 1  a typical Water Heater  9 ; run 2  using only the HMX  7 ; run 3  using a Pre-Cooler, (no condensing) with an HMX  7 ; and run 4  using a Pre-cooler  8  with an HMX  7 . 
         [0000]    
       
         
               
             
               
               
             
               
               
               
             
               
               
               
               
               
             
               
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
               
             
               
             
               
               
             
               
               
               
             
               
               
               
               
               
             
               
               
               
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
             
               
             
               
               
             
               
               
               
             
               
               
               
               
             
               
               
               
               
               
               
               
               
               
               
             
           
               
                 TABLE 1 
               
               
                   
               
             
             
               
                 Part 1 
               
             
          
           
               
                   
                 Combustion Air 
               
             
          
           
               
                   
                 Outdoor Air In 
                   
               
             
          
           
               
                   
                   
                   
                 Dry 
                   
               
               
                   
                 Gas Burned 
                   
                 Air 
               
             
          
           
               
                   
                 Mass 
                   
                 1, 
                   
                   
                 Mass 
                 Out of HMX 
               
             
          
           
               
                   
                   
                 Flow 
                 Firing 
                 Temp 
                   
                   
                 Flow, 
                 2, 
                 Humidity 
                   
               
               
                   
                   
                 Rate, 
                 Rate, 
                 Dry 
                 Humidity 
                 Enthalpy, 
                 lb/ 
                 Dry 
                 Ratio, 
                 Enthalpy, 
               
               
                 Description 
                 Run 
                 lb/min 
                 btu/hr 
                 Bulb, F. 
                 Ratio 
                 btu/lb 
                 min 
                 Bulb, F. 
                 lb/lb 
                 btu/lb 
               
               
                   
               
               
                 Water Heater 
                 1 
                 0.0869 
                 110, 523 
                 68 
                 0.0080 
                 25.05 
                 1.63 
                 68 
                 0.0080 
                 25.05 
               
               
                 Only 
               
               
                 HMX Only 
                 2 
                 0.0869 
                 110, 523 
                 68 
                 0.0080 
                 25.05 
                 1.63 
                 150 
                 0.2110 
                 273.92 
               
               
                 PreCool/HMX 
                 3 
                 0.0869 
                 110, 523 
                 68 
                 0.0080 
                 25.05 
                 1.63 
                 150 
                 0.2110 
                 273.92 
               
               
                 PreCond/HMX 
                 4 
                 0.0869 
                 110, 523 
                 68 
                 0.0080 
                 25.05 
                 1.63 
                 150 
                 0.2110 
                 273.92 
               
               
                   
               
             
          
           
               
                 Part 2 
               
             
          
           
               
                   
                 Flue Gas Pre-Condenser 
               
             
          
           
               
                   
                 Flue Gas Into Pre-condenser 
                   
               
             
          
           
               
                   
                 Water 
                   
                 Flue Gas Out of 
                 Water Preheated In 
               
               
                   
                 to Dry 
                   
                 Pre-condenser 
                 Pre-condenser 
               
             
          
           
               
                   
                 Flue 
                   
                 and Into HMX 
                 12, 
                 13, 
                 Water 
               
             
          
           
               
                   
                   
                   
                 Gas 
                   
                 5, 
                   
                 Temp 
                 Temp 
                 Flow 
               
               
                   
                 Cond 
                 4, 
                 Ratio, 
                 Enthalpy, 
                 Temp 
                 Enthalpy, 
                 Water 
                 Water 
                 Rate, 
               
               
                 Run 
                 Temp, F. 
                 Temp, F. 
                 lb/lb: 
                 btu/lb 
                 Out, F. 
                 btu/lb 
                 In, F. 
                 Out, F. 
                 lb/min 
               
               
                   
               
               
                 1 
                 131.7 
                 400 
                 0.1170 
                 240.91 
                 400 
                 240.91 
                 135 
                 135 
                 0.0 
               
               
                 2 
                 163.2 
                 400 
                 0.3315 
                 506.59 
                 400 
                 506.59 
                 135 
                 135 
                 0.0 
               
               
                 3 
                 163.2 
                 400 
                 0.3315 
                 506.59 
                 164 
                 415.21 
                 135 
                 145 
                 14.1 
               
               
                 4 
                 163.2 
                 400 
                 0.3315 
                 506.59 
                 158 
                 350.89 
                 135 
                 145 
                 24.079 
               
               
                   
               
             
          
           
               
                 Part 3 
               
             
          
           
               
                   
                 Flue Gas HMX 
               
             
          
           
               
                   
                 Water Drained 
                   
               
             
          
           
               
                   
                 Flue Gas Out of HMX 
                 Water 
                   
               
             
          
           
               
                   
                   
                   
                   
                 Mass 
                   
                   
                 Vapor 
                   
                   
               
               
                   
                   
                   
                   
                 Flow 
                   
                   
                 above 
               
               
                   
                   
                   
                   
                 of Dry 
                 Oxidized 
                 Total 
                 Outdoor 
               
               
                   
                   
                 Humidity 
                   
                 Flue 
                 Comb 
                 Water 
                 Air 
                 17, 
               
               
                   
                 6, 
                 Ratio, 
                 Enthalpy, 
                 Gas, 
                 H2O, 
                 Cond, 
                 Exhaust, 
                 Drained, 
               
               
                 Run 
                 Temp, F. 
                 lb/lb 
                 btu/lb 
                 lb/min 
                 lbw/min 
                 lbw/min 
                 lbw/min 
                 lbw/min 
                 Efficiency 
               
               
                   
               
               
                 1 
                 400.0 
                 0.1170 
                 240.91 
                 1.55 
                 0.168 
                 0.00 
                 0.17 
                 0.000 
                 82.0% 
               
               
                 2 
                 146.1 
                 0.1856 
                 244.03 
                 1.55 
                 0.168 
                 0.23 
                 0.27 
                 −0.106 
                 81.7% 
               
               
                 3 
                 129.2 
                 0.1082 
                 152.06 
                 1.55 
                 0.1679 
                 0.35 
                 0.16 
                 0.014 
                 89.5% 
               
               
                 4 
                 107.4 
                 0.0545 
                 86.17 
                 1.55 
                 0.168 
                 0.43 
                 0.07 
                 0.097 
                 95.0% 
               
               
                   
               
             
          
         
       
     
         [0114]    In Water Heater only, run 1 , the flue gas is cooled only in Water Heater  9  and exits the system at about 400° F. See  FIG. 3A  for a typical configuration. The condensing temperature of the flue gas is about 131° F. This results in an efficiency of about 82%, high for a Non-condensing Water Heater  40 , and typically would require Cold Water  11  entering the Tank  39 . 
         [0115]    In run 2  with the HMX only, (not shown but for the case where an HMX is connected to a Non-condensing Water Heater  40 ) more water is evaporated than condensed because of the cooling of the Hot Flue Gas  4  down from 400° F. and condensing starts at about 160° F. As with all heat exchangers the energy removed on one side must equal the energy gain on the other. On the cooling side the Input Combustion air  1  will be heated but most of the heat gain will be through evaporation of water while becoming Saturated Combustion Air  2 . In this run more water is evaporated into the combustion air stream than can be condensed from the flue gas due to desuperheat of the Flue Gas  5 . Nothing is gained as far as efficiency is concerned as the flue gas enthalpy leaving the system is about the same as run 1 , lower temperature but saturated. Over all the efficiency is about the same as run 1  or maybe a little less, 82%. What is needed in this embodiment is cooling of Hot Flue Gas  4  before the HMX  7 , or putting flue gas heat to use such as for heating the water in the Water Heater  9  or Cold Water In  11 . 
         [0116]    Run  3  demonstrates that when Pre-cooler  8  cools Flue Gas  5  to just above its condensing temperature the maximum efficiency is limited to about 90%. 
         [0117]    In run  4  the Hot Flue Gas  4  is pre-condensed in Pre-cooler  8  to about 158° F. This results in an efficiency of about 95%. As mentioned earlier the water can now be heated at much higher temperature with the flue gas at 158° F. rather than 131° F. This is the configuration of  FIG. 1  or  FIG. 3C . 
         [0118]    As can be imagined, this heat recovery method can be used on other devices such as furnaces, boilers, and other applications that have either an internal need for a heat above 140° F., to heat water in the hot water heater case shown, or to heat another fluid.  FIG. 11  illustrates a more general system. 
         [0119]    HMX  7  can be as simple as a heat and mass exchanger that is able to have condensing on one side of the plate and evaporation on the other. Of course on the evaporation side there must be a means to distribute water from the condensing side or from another source across the plate (e.g., wicking, spraying, gravity delivery, etc.) On the condensing side there must be a means to collect the water and either deliver it to the evaporation side or drain it away. 
         [0120]    One preferred HMX method was shown in  FIG. 2A  where Membrane  19  separates Pre-cooler Flue Gas  5  from Combustion Air  1 . Water, e.g. Condensate  16 , passes through Membrane  19  to the Combustion Air side  30  and Evaporated Water  23  is added to Combustion Air  1 . Membrane  19  is made of a wick material that will hold Water  24 , see  FIG. 2B , with capillary action (like water absorbed in a towel). The water in the wick membrane separates the flue gas from the combustion air. In a preferred embodiment a stiff wicking material is used such as a polyester spunbond material that is flat bonded. This has several advantages, e.g. there is little heat resistance through Membrane  19 , no pump is needed to move water from one side to the other, and the water condensing on the flue gas side becomes the water on the evaporating side. In this way no heat or mass transfer is lost in gathering water, pumping water to the other side and evaporating it. 
         [0121]      FIG. 4  is an isometric diagram showing a preferred embodiment of a HAR system utilizing a counterflow HMX  7  with Troughs  18  to provide additional water as needed. In this embodiment, Membranes  19  are separated and supported by Channel Guides  28 , which form channels  37 ,  38 . Flue Gas Channels  37  direct Pre-condensed Flue Gas  5  on Condensing side  26 . Combustion Air Channels  38  direct Input Combustion Air  1  on Evaporation Side  30  of each Membrane  19  in counterflow. Warm Pre-condensed Flue Gas  5  becomes cool Flue Gas Out  6 . Input combustion Air  1  becomes Saturated Combustion Air  2 . 
         [0122]    Membranes  19  are attached to Troughs  18  having Trough Overflow Perforations  27  to drain excess water from one Membrane to the next Membrane down. Troughs  18  insure that Membranes  19  are always wetted during startup and when it is hot and dry out, for example with added Condensate  16  from Pre-cooler  8 . Trough  18  also can collect excess condensing Water  24  from Flue Gas  5  that is not evaporated into Input Combustion Air  1  as it is condensed on Membrane  19 . 
         [0123]      FIG. 5  is an isometric drawing showing the bottom of Trough  18  coated with an Impervious Coating  29  to prevent water from dripping through except via Trough Overflow Perforations  27 . 
         [0124]      FIG. 6  is an isometric drawing showing Trough Over Flow Perforations  27  in a stack of Troughs  18 . As each Trough  18  fills with water, the Trough Over Flow Perforations  27  allow water to drain to the next Trough below. The bottom Trough will allow the water to drain from the system as Drain Water  17 . 
         [0125]      FIG. 7  is an isometric drawing showing an HMX system  7  configured with Trough End Caps  25  that prevent the water in Troughs  18  from flowing out the ends. 
         [0126]    There are many heat and mass exchanger configurations that can be used.  FIG. 8  is a schematic of a counter flow HMX. Input Combustion Air  1  passes along saturated Membranes  19  in Combustion Air Channels  38  becoming Saturated Combustion Air  2 . It is heated by Pre-condensed Flue Gas  5  in Flue Gas Channels  37 , and causing water to condense out as it passes along the opposite side of Membrane  19 . Flue Gas  5  becomes Flue Gas out  6 . 
         [0127]    Membrane  19  could be an impervious plate with other means to distribute the condensate water from one side of the plate to the other for evaporation. 
         [0128]    To create lower temperatures it maybe desirable to use the M-Cycle wherein Input Combustion Air  1  first travels along Dry Sides  26  of Membranes  19  where it is cooled towards its dew point temperature, as shown in  FIG. 9 . It is then turned to travel counterflow across the Wet Sides  30  of Membranes  19  and becomes Saturated Combustion Air  2  as it picks up heat from both the Input Combustion Air  1  and the Pre-condensed Flue Gas  5  through Membrane  19 . 
         [0129]    Another schematic of an M-Cycle type of HMX which is useful in embodiments of the present invention is shown in  FIG. 10 . Input Combustion Air  1  first travels along Dry Sides  26  of Membranes  19  where it is cooled towards its dew point temperature as in the embodiment of  FIG. 9 . It is then split into 2 streams and turned to travel counterflow across the Wet Sides of Membranes  30  and becomes Saturated Combustion Air  2  as it picks up heat from both the Input Combustion Air  1  and the Pre-condensed Flue Gas  5 . 
         [0130]      FIG. 11  is a schematic block diagram of a system  300  for providing a Combustor  303  with Saturated Combustion air  2  according to the present invention. Combustor  303  generates Hot Flue Gas  4 , which is cooled by Pre-cooler  8 , generating Warm Flue Gas  5 . Pre-cooler  8  utilizes a fluid  312  to accomplishes precooling. 
         [0131]    HMX  307  warms and humidifies atmospheric air  1  (with Warm Flue Gas  5  and Liquid  24 ) to produce saturated combustion air  2  for combustor  303 . Cool Flue Gas  6  is generally vented into the atmosphere.