Abstract:
A generally cylindrical, elongated thermal isolator for in-line placement proximate to a vaporizer of a sample take-off conditioning system for minimizing upstream heat migration from a sample vaporizer to prevent liquid sample pre-vaporization.

Description:
FIELD OF THE INVENTION 
       [0001]    This invention relates to a fabricable, in-line, thermal isolator/break that can be used in the gas sample conditioning field. The invention also contemplates control of the volume of fluid flow and provides flow restriction to the entry of an associated sample vaporizer such as the Applicant&#39;s Mustang Model 2 sample condition system and like that described and disclosed in U.S. Pat. No. 7,484,404 and its progeny, the content of which is incorporated herein by reference. 
       BACKGROUND 
       [0002]    In the gas sample conditioning field, particularly when dealing with cryogenic liquids such as LNG, heat generated within a vaporizer can migrate up-stream of the vaporizer entry port and along the sample conduit tubing employed to communicate a cryogenic liquid sample from its source. (i.e., a pipeline) into the sample conditioning cabinet. Such heat energy migration has the undesirable effect of causing sample pre-vaporization before introduction of the extracted liquid sample into the vaporizer. Pre-vaporization of an incoming sample adversely impacts the accuracy of a sample analysis thereof by, for example, creating phase and fluid component partitioning within the sample, interfering with uniform sample flow into the vaporizer, and/or generating sufficient back-pressure to create a deadheading effect within the system. In the event any of the foregoing occur, the accuracy of any analysis, i.e., quantifying the energy content of a particular LNG sample, becomes suspect. 
       SUMMARY OF THE INVENTION 
       [0003]    It is an object of the present invention to provide an adjunct to minimize heat migration from a sample vaporizer to a liquid sample conduit. 
         [0004]    It is another object of the present invention to also enhance sample fluid flow control by reducing a sample volume passing through the adjunct. 
         [0005]    These and other objects are satisfied by an embodiment of the invention characterized by an in-line thermal isolator disposed proximate to the entry port of a sample vaporizer to minimize heat migration from a sample vaporizer to the upstream sample conduit, the isolator featuring an elongated, generally cylindrical body incorporating an axial bore for accommodating fluid flow from a sample source, and a fitting member adapted for in-line sealable connection with a mating member formed in the sample conduit. 
         [0006]    The invention provides a second embodiment to the first embodiment further characterized by the in-line thermal isolator formed from a polymeric material selected from the group consisting of PETE and PEEK. 
         [0007]    The invention provides a third embodiment to the previous embodiments further characterized by the axial bore where the in-line thermal isolator restricts fluid flow. 
         [0008]    The invention provides a further embodiment to the previous embodiment further characterized by the in-line thermal isolator with compression fittings on each end. 
         [0009]    The invention provides a further embodiment to the first embodiment further characterized by the in-line thermal isolator formed from a thermally insulative material being selected from the group consisting of synthetic polymers and ceramics. 
         [0010]    A further embodiment of the invention is characterized by a method of preventing thermally-induced sample pre-vaporization in a sample conduit comprising the step of inserting an isolator according to any of the previous embodiments upstream from a sample vaporizer in the sample conduit line to prevent heat migration. 
         [0011]    An essential function of the invention is to provide a thermal break/discontinuity in sample tubing conveying, for example, cryogenic Liquid Natural Gas or non-cryogenic Natural Gas Liquids to a sample vaporizer. When connected to a LNG or NGL Vaporizer, in-line placement of the inventive thermal break prevents heat from migrating from the sample vaporizer along the tubing to thereby pre-warm an incoming liquid sample. This pre-warming prior to vaporization can cause component/phase separation of the liquid sample leading to erroneous analyzer results. In the simplest of terms, use of the invention thermally isolates two co-linear segments of metal tubing in a process sample line. 
         [0012]    The thermal break of the invention can assume different configurations and be formed of any number of thermally-insulating, engineered materials. Functionally, a thermal break in accordance with the invention must possess a functionality of sealingly securing a liquid communication conduit while providing thermal isolation by interrupting heat transfer along tubing/conduit. Preferably, the in-line thermal isolator/break is positioned close to the sample entry port to a sample vaporizer, particularly in the case of a cryogenic liquid sample to avoid issues resulting from pre-vaporization and deadheading. 
         [0013]    In this detailed description, references to “one embodiment”, “an embodiment”, or “in embodiments” mean that the feature being referred to is included in at least one embodiment of the invention. Moreover, separate references to “one embodiment”, “an embodiment”, or “embodiments” neither necessarily refer to the same embodiment nor does this mean such embodiments are mutually exclusive, unless so stated, and except as will be readily apparent to those skilled in the art. Thus, the invention can include any variety of combinations and/or integrations of the embodiments described herein. 
         [0014]    The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of the invention. As used herein, the singular forms, “a”, “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the root terms “include” and/or “have”, when used in this specification, specify the presence of stated features, steps, operations, elements, and/or components, but do not preclude the presence or addition of at least one other feature, step, operation, element, component, and/or groups thereof. 
         [0015]    As used herein, “analyte sample” contemplates a constituent from a source such as natural gas, a liquid natural gas, natural gas liquid, or a cryogenic liquid capable of vaporization and sample content characterization by conventional analysis equipment such as a gas chromatograph, mass spectrograph, Raman spectrophotometer, tunable diode laser spectrograph, etc. 
         [0016]    As used herein, the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having” or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a process, method, article, or apparatus that comprises a list of features is not necessarily limited only to those features but may include other features not expressly listed or inherent to such process, method, article, or apparatus. 
         [0017]    For definitional purposes and as used herein “connected” includes physical, whether direct or indirect, affixed or adjustably mounted. Thus, unless specified, “connected” is intended to embrace any operationally functional connection. 
         [0018]    As used herein, and unless expressly stated to the contrary, “or” refers to an inclusive-or and not to an exclusive-or. For example, a condition A or B is satisfied by any one of the following: A is true (or present) and B is false (or not present), A is false (or not present) and B is true (or present), and both A and B are true (or present). 
         [0019]    As used herein “substantially,” “generally,” and other words of degree are relative modifiers intended to indicate permissible variation from the characteristic so modified. It is not intended to be limited to the absolute value or characteristic which it modifies but rather possessing more of the physical or functional characteristic than its opposite, and preferably, approaching or approximating such a physical or functional characteristic. 
         [0020]    In the following description, reference is made to the accompanying drawings which are provided for illustration purposes as representative of a specific exemplary embodiment in which the invention may be practiced. The following illustrated embodiment is described in sufficient detail to enable those skilled in the art to practice the invention. It is to be understood that other embodiments may be utilized and that structural changes based on presently known structural and/or functional equivalents may be made without departing from the scope of the invention. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWING 
         [0021]      FIG. 1  is a side perspective end view of a first embodiment of the invention. 
           [0022]      FIG. 2  is a side view of the embodiment of  FIG. 1 . 
           [0023]      FIG. 3  is a perspective end view of the embodiment of  FIG. 1 . 
           [0024]      FIG. 4  is a further side view of the embodiment of  FIG. 1 . 
           [0025]      FIG. 5  is an exploded view of the embodiment of  FIG. 1  with threaded metal end caps for connecting to the sample line (not illustrated). 
           [0026]      FIG. 6  is a perspective side assembly view of the components depicted in  FIG. 5 . 
           [0027]      FIG. 7  is a view of an elongated alternative embodiment in accordance with the invention. 
           [0028]      FIG. 8  is a perspective side assembly view of the embodiment of  FIG. 7  with in-line, nut style compression fitting connectors. 
           [0029]      FIG. 9  is a perspective view of a further alternative embodiment of the invention providing a smooth, outer cylindrical surface in accordance with the invention. 
           [0030]      FIG. 10  is a cutaway side view of the embodiment of  FIG. 9  illustrating the unitary elongated body with in-line threading for sealingly receiving a correspondingly-sized, threaded, tubing connector. 
           [0031]      FIG. 11  is a simplified schematic representation of a thermal isolator in relation to a sample vaporizer system according to the invention. 
       
    
    
     DETAILED DESCRIPTION 
       [0032]      FIGS. 1-6  depict a Process Thermal Isolator structure  10  contemplated by the invention. The isolator  10  refines a relatively cylindrical body defined by a central annular section  12  and threaded connectors  14 . The threaded connectors  14  project oppositely of the annular section  12  and feature an axially-oriented, fluid passage, bore  16 . 
         [0033]    The material selected for fabrication of the isolator  10  must demonstrate sufficient resistance to burst at very high pressures and to thermal stresses even at cryogenic temperatures. Preferably, the composition of the thermal isolator/break is a highly-engineered, burst-resistant, thermally-stable composition, preferably formed from a polymeric material such as PETE (polyethylene terephthalate) or PEEK particularly suited for disposition between a sample takeoff manifold and vacuum jacketed tubing to prevent migration of frost to the vaporizer and heat to the upstream tubing of the vaporizer. Alternative materials can be employed, e.g., other synthetic polymers, ceramics, etc., so long as they possess the necessary degree of thermal stability and burst resistance while providing the ability for precision molding/machining into the desired engineered configuration. 
         [0034]    Referring to  FIGS. 5 and 6 , each respectively illustrates in assembly and assembled view, thermal isolator  10  and female threaded compression end caps  18 ,  20  for securing the thermal isolator  10  in a liquid sample line. 
         [0035]    Illustrated in  FIGS. 7-8  is an elongated version of a thermal isolator  20 , where the annular segment  22  is of greater length than its shorter counterpart  12  illustrated in  FIGS. 1-6 . The remaining structures, threaded connectors  24 , and the central bore  26  are substantially structurally identical to their respective counterparts  14 ,  16  illustrated in  FIGS. 1-6 . The end fittings of  FIG. 8  are unthreaded compression fittings  28 ,  29  that sealingly secure the isolator  20  in-line with an associated liquid sample pipeline (not illustrated). 
         [0036]    The variation of the invention illustrated in  FIGS. 9 and 10  provides an isolator  30  with a smooth continuous cylindrical outer surface that includes female-threaded, axial openings  32  for securing corresponding threaded male members formed on the associated liquid sample line. The isolator  30  includes an axial bore  34  of reduced diameter for flow control. It is a matter of design choice whether the isolator is a screw on or screw in version. 
         [0037]      FIG. 11  illustrates exemplary in-line placement of a thermal isolator  42  according to the invention. The illustrated generic arrangement includes a heated enclosure  40  of the type described in any one of Applicant&#39;s earlier issued patents, U.S. Pat. No. 7,162,933, U.S. Pat. No. 7,484,404, or U.S. Pat. No. 9,057,668, all being incorporated herein by reference. The enclosure  40  is positioned near a pipeline P and includes a takeoff probe  41  and an analyte sample takeoff line  42  with a thermal isolator  43  disposed in-line proximate to an analyte sample vaporizer unit  44 . The vaporizer unit  44  is associated with flow control valves as well as heat and pressure regulators (not illustrated) and vaporized gas input to a mixing accumulator  46  for throughput without dew point drop out caused by Joules-Thompson condensation or the like, to a thermally insulated analyzer output line  50  exiting the heated enclosure  40 . 
         [0038]    It should be understood that the invention is not limited to the specific embodiments disclosed herein, and that many modifications and other embodiments of the invention are intended to be included within the scope of the invention. Moreover, although specific terms are employed herein, they are used only in a generic and descriptive sense, and not for the purposes of limiting the description invention.