Abstract:
A high-k dielectric films is provided, which is doped with divalent or trivalent metals to vary the electron affinity, and consequently the electron and hole barrier height. The high-k dielectric film is a metal oxide of either zirconium (Zr) or hafnium (Hf), doped with a divalent metal, such as calcium (Ca) or strontium (Sr), or a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y). By selecting either a divalent or trivalent doping metal, the electron affinity of the dielectric material can be controlled, while also providing a higher dielectric constant material then silicon dioxide. Preferably, the dielectric material will also be amorphous to reduce leakage caused by grain boundaries. Also provided are sputtering, CVD, Atomic Layer CVD, and evaporation deposition methods for the above-mentioned, doped high dielectric films.

Description:
This application is a continuation-in-part of U. S. patent application Ser. No. 09/515,743, filed Feb. 29, 2000, which is a divisional of U.S. patent application Ser. No. 09/356,470, filed Jul. 19, 1999, U.S. Pat. No. 6,060,755. 
    
    
     BACKGROUND OF THE INVENTION 
     The present invention relates generally to integrated circuit (IC) fabrication processes and, more particularly, to a high dielectric constant gate insulation film, and a deposition method for such film. 
     Current Si VLSI technology uses SiO 2 , or nitrogen containing SiO 2 , as the gate dielectric in MOS devices. As device dimensions continue to scale down, the thickness of the SiO 2  layer must also decrease to maintain the same capacitance between the gate and channel regions. Thicknesses of less than 2 nanometers (nm) are expected in the future. However, the occurrence of high tunneling current through such thin layers of SiO 2  requires that alternate materials be considered. Materials with high dielectric constants would permit gate dielectric layers to be made thicker, and so alleviate the tunneling current problem. These so-called high-k dielectric films are defined herein as having a high dielectric constant relative to silicon dioxide. Typically, silicon dioxide has a dielectric constant of approximately 4, while high-k films have a dielectric constant of greater than approximately 10. Current high-k candidate materials include titanium oxide (TiO 2 ), zirconium oxide (ZrO 2 ), tantalum oxide (Ta 2 O 5 ), and barium and strontium titanium oxide (Ba,Sr)TiO 3 . One common problem associated with the above-mentioned high-k dielectrics is that they develop a crystalline structure under 
     normal preparation conditions. As a result, the surface of the film is very rough. Surface roughness causes non-uniform electrical fields in the channel region adjacent the dielectric film. Such films are not suitable for the gate dielectrics of MOSFET devices. 
     Because of high direct tunneling currents, SiO 2  films thinner than 1.5 nm cannot be used as the gate dielectric in CMOS devices. There are currently intense efforts in the search for the replacement of SiO 2 , with TiO 2  and Ta 2 O 5  attracting the greatest attention. However, high temperature post deposition annealing, and the formation of an interfacial SiO 2  layer, make achieving equivalent SiO 2  thicknesses (EOT) of less than 1.5 nm very difficult. 
     It would be advantageous if a high-k dielectric film could be used as an insulating barrier between a gate electrode and the underlying channel region in a MOS transistor. 
     It would be advantageous if improved high-k dielectric materials could be formed by simply doping, or otherwise adding additional elements to currently existing high-k dielectric materials. 
     It would be advantageous if the electrical properties, including electron affinity, of the high-k dielectric materials could be modified by simply doping, or otherwise adding additional elements to currently existing high-k dielectric materials. 
     SUMMARY OF THE INVENTION 
     Accordingly, a thin film having a high dielectric constant (10 to 25) is provided. The film including a doping metal, a metal selected from the group consisting of zirconium (Zr) and hafnium (Hf), and oxygen. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). 
     By selecting the doping metal, it is possible to vary the electron affinity of the dielectric material deposited. By varying the electron affinity it is possible to vary the electron barrier height and the hole barrier height. Accordingly, the present invention allows one to modify the electron affinity of the dielectric film while producing a film with a higher dielectric constant than silicon dioxide. In addition, the presence of the doping metal tends to produce amorphous dielectric materials since the presence of the doping metals reduces, or eliminates, the formation of crystalline structures. 
     The present invention provides, in part, zirconia (ZrO 2 ) stabilized by Y 2 O 3 , CaO 2 , Al 2 O 3 , La 2 O 3 , La and Sr. In another embodiment SrZO 3  is provided as a dielectric material. 
     Typically, the percentage of doping metal in the film does not exceed approximately 50%. In some applications the percentage of doping metal will be less than approximately 10%, in which case the film produced may not be amorphous. 
     Also provided is a MOSFET transistor. The transistor comprising a gate electrode, a channel region having a top surface underlying said gate electrode, and a gate dielectric film interposed between the gate electrode and the channel region top surface. The content of the dielectric film is as described above. Typically, the gate dielectric film has a thickness in the range of approximately 20 and 200 Å. 
     Some aspects of the invention further comprise the transistor having an interface barrier, with a thickness in the range of approximately 2 to 5 Å, interposed between the channel region and the gate dielectric film. The interface materials are selected from the group consisting of silicon nitride and silicon oxynitride, whereby the channel region top surface is made smoother to prevent the degradation of electron mobility of the MOSFET. 
     In the fabrication of an integrated circuit (IC) having a surface, a sputtering method is also provided to form a doped metal oxide film on the IC surface. The method comprises the steps of: 
     a) establishing an atmosphere including oxygen; 
     b) sputtering at least one target metal including a metal selected from the group consisting of Zr and Hf, and a doping metal, such as Ca, Sr, Al, Sc, La, or Y, on the IC silicon surface; 
     c) in response to Steps a) and b), forming the doped metal oxide film; and 
     d) annealing at a temperature in the range of approximately 400 and 900 degrees C., whereby a thin film having a high dielectric constant and good insulating properties is formed. 
     In some aspects of the invention Step a) includes co-sputtering with separate targets including a first target of a metal selected from the group consisting of Zr and Hf, and a second target of the doping metal in an oxidizing atmosphere. 
     Alternately, a chemical vapor deposition (CVD) method of depositing the doped metal oxide film is provided comprising the steps of: 
     a) preparing at least one precursor, including a metal selected from the group consisting of Zr and Hf, and a doping metal; 
     b) vaporizing the precursor; 
     c) establishing an atmosphere including oxygen; 
     d) decomposing the precursor on the IC surface to deposit, by chemical vapor deposition (CVD), an alloy film including the metal selected from the group consisting of Zr and Hf, the doping metal, and oxygen; and 
     e) annealing at a temperature in the range of approximately 400 to 900 degrees C., whereby a thin film having a high dielectric constant and good barrier properties is formed. 
     In another alternative embodiment, atomic layer chemical vapor deposition (ALCVD), which is also known as atomic layer deposition (ALD), is employed as a method of depositing the doped metal oxide film. The ALCVD method comprises the steps of: 
     a) preparing a first precursor including a metal selected from the group consisting of Zr and Hf; 
     b) vaporizing the first precursor and exposing the IC surface to the precursor, whereby a layer, preferably a monolayer, of the metal is chemically adsorbed to the surface to deposit, by ALCVD, the layer of metal; 
     c) preparing an oxygen precursor; 
     d) vaporizing the oxygen precursor and exposing the IC surface to the oxygen precursor, whereby a layer, preferably a monolayer, of oxygen is chemically adsorbed to the surface to deposit, by ALCVD, the layer of oxygen; 
     e) preparing a doping metal precursor, which includes a doping metal; 
     f) vaporizing the doping metal precursor and exposing the IC surface to the doping metal precursor, whereby a layer of the doping metal is chemically adsorbed to the surface to deposit, by ALCVD, the layer of doping metal; and 
     g) annealing at a temperature in the range of approximately 300 to 900 degrees C. to condition the deposited layers, whereby a thin film having a high dielectric constant and good barrier properties is formed. 
     By repeating the steps as necessary, multiple layers of each material in the dielectric may be deposited, followed by one, or more layers of other constituent elements. So for example, several layers zirconium could be deposited followed by oxygen and then a doping metal. The process could then be repeated until a total thickness of dielectric material is deposited having the desired amount of doping metal in a zirconium oxide dielectric material. 
     In yet another alternative embodiment, an evaporation deposition method of depositing the doped metal oxide film is provided comprising the steps of: 
     a) establishing a high vacuum (gas-free) atmosphere, in the range of between approximately 1×10 −6  and 1×10 −8  Torr; 
     b) preparing at least one crucible including a metal selected from the group consisting of Zr and Hf, and a doping metal; 
     c) heating the at least one crucible at a temperature in the range of approximately 1000 and 2000 degrees C., to evaporate the metals prepared in Step b); 
     d) in response to Steps a) through c), depositing an alloy film including the metal selected from the group consisting of Zr and Hf, and the doping metal; and 
     e) annealing in an atmosphere including oxygen at a temperature in the range of approximately 400 to 900 degrees C., to form an alloy film with oxygen, whereby a thin film having a high dielectric constant and good barrier properties is formed. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     FIG. 1 is a flowchart illustrating a sputter deposition method for the doped metal oxide film of the present invention. 
     FIG. 2 illustrates a step in completing a transistor made using the present invention. 
     FIG. 3 illustrates a step in completing a transistor made using the present invention. 
     FIG. 4 is a flowchart illustrating steps in a CVD method of forming a doped metal oxide film of the present invention. 
     FIG. 5 is a flowchart illustrating steps in a ALCVD method of forming a doped metal oxide film of the present invention. 
     FIG. 6 is a flowchart illustrating steps in an evaporation method of forming a doped metal oxide film. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     The present invention investigates doped zirconium oxide. Submicron PMOSFETs have been fabricated with the Zr—O gate dielectrics with excellent characteristics. In short, it was discovered that doping a ZrO 2  film, with a divalent, or trivalent, doping metal, results in the ability to control the electrical properties of the film, especially the electron affinity. 
     The present invention is a thin film having a high dielectric constant, with respect to silicon dioxide, which comprises a divalent, or trivalent, doping metal, a metal selected from the group consisting of zirconium (Zr) and hafnium (Hf), and oxygen. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). 
     In several useful applications, the thin film typically has a thickness in the range of approximately 20 and 200 Å, a dielectric constant in the range of approximately 10 to 25. 
     The percentage of doping metal in the film, typically does not exceed approximately 50%. 
     FIG. 1 is a flowchart illustrating a sputter deposition method for the doped metal oxide film of the present invention. Step  10  provides an integrated circuit (IC) having a surface. Step  12  establishes an atmosphere including oxygen. Typically, Step  12  includes the atmosphere also comprising argon (Ar), with the ratio of O 2  to Ar being in the range of approximately 5 to 25%. The pressure is in the range of approximately 1 to 10 millitorr (mT). Step  14  sputters at least one target metal including a metal selected from the group consisting of Zr and Hf on the IC surface. Step  14  also sputters the doping metal on the IC surface. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). In some aspects of the invention, Step  14  includes co-sputtering with separate targets including a first target of a metal selected from the group consisting of Zr and Hf, and a second target including the doping metal. 
     Step  16 , in response to Steps  12  and  14 , forms the doped metal oxide film. Step  18  anneals at a temperature in the range of approximately 400 and 900 degrees C. The annealing time varies in the range of approximately 10 seconds to 30 minutes, depending on the annealing temperature. Step  18  includes establishing an atmosphere including elements selected from the group consisting of Ar, N 2 , N 2 :H 2  forming gas, O 2 , H 2 O, N 2 O, NO, no gas (gas-free environment), and oxygen plasma. Step  20  is a product, where a thin film having a high dielectric constant and good insulation properties is formed. 
     In some aspects of the invention, wherein Step  10  provides a silicon IC surface, a further step precedes Step  16 . Step  14   a  (not shown) establishes an IC silicon surface temperature in the range of approximately room temperature and 400 degrees C. 
     Zr—Al—O and Hf—Al—O films were prepared by co-sputtering as described above. The sputtering power ratio was adjusted to vary the amount of Al concentration in zirconium oxide. 
     The dielectric film of the present invention is applicable to gate dielectrics, storage capacitors, and other applications such as one transistor ( 1 T) ferroelectric memory. The dielectric film produced according to the method of the present invention may have wide applicability wherever high-k dielectric materials will be used. 
     FIGS. 2 and 3 illustrate steps in a completed MOSFET transistor made using the doped metal oxide film of the present invention. FIG. 2 illustrates transistor  50  having a channel region  52  with a top surface  54 . Overlying channel region  52  is a gate dielectric film  56 . 
     In some aspects of the invention, transistor  50  further comprises an interface barrier  62  having a thickness  64  in the range of approximately 2 to 5 Å, interposed between channel region  52  and gate dielectric film  56 . Interface barrier  62  is comprised of materials selected from the group consisting of silicon nitride and silicon oxynitride, whereby channel region top surface  54  is made smoother to increase the electron mobility of MOSFET  50 . 
     FIG. 3 illustrates gate dielectric film  56  interposed between gate electrode  58  and channel region top surface  54 . Gate dielectric film  56  has a high dielectric constant relative to silicon dioxide, and includes a metal selected from the group consisting of zirconium (Zr) and hafnium (Hf), and oxygen. Gate dielectric film  56  includes a doping metal. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). The percentage of doping metal, in film  56  is in the range of approximately 0 to 50%. Preferably, the percentage of Al in film  56  is approximately 25%. Gate dielectric film  56  has a thickness  60  (FIG. 3) in the range of approximately 20 and 200 Å. Gate dielectric film  56  has a dielectric constant in the range of approximately 10 to 25. 
     In the case of gate dielectrics in bulk CMOS device applications, the wafers are processed using any state of the art conventional method, such as isolation, followed by P-well and N-well formation to expose the channel region. An ultra-thin layer of oxidation barrier may still be needed. In this case, possible barriers include silicon nitride and silicon oxynitride. Next, the high-k dielectric is deposited. There are several ways of preparing the film: 
     A. Co-sputtering of Zr and the doping metal in inert or oxidizing ambient; 
     B. Co-sputtering compound targets, such as Zr—Al, in inert or oxidizing ambient; 
     C. Chemical vapor deposition of Zr—Al—O and Hf—Al—O; or 
     D. Evaporation. 
     Following deposition, the film is annealed in inert (e.g., Ar, N 2 , N 2 :H 2  forming gas) and/or oxidizing (O 2 , H 2 O, N 2 O, NO, and no gases (gas-free) ambient atmosphere at an elevated temperature (400-900° C.) to condition the high k-film and the high-k/Si interface. However, if the film is deposited by evaporation, the annealing process typically includes oxygen, to include oxygen in the alloy film. 
     Following annealing, a gate is deposited and patterned into a gate stack. The gate material could be metal or polysilicon. Then, using any state of the art device fabrication process, the device is completed by the conventional method, or a gate replacement method using nitride, polysilicon, or poly SiGe dummy gate. 
     FIG. 4 is a flowchart illustrating steps in a CVD method of forming a doped metal oxide film of the present invention. Step  100  provides an integrated circuit (IC) having a surface. Step  102  prepares at least one precursor including a metal selected from the group consisting of Zr and Hf, and the doping metal. Step  102  includes the doping metal. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). In some aspects of the invention, step  102  comprises a first precursor including a metal selected from the group consisting of Zr and Hf, and a second precursor including the doping metal metal. Step  104  vaporizes at least one precursor. Step  106  establishes an atmosphere including oxygen. Typically, step  106  includes the atmosphere comprising argon (Ar), with the ratio of O 2  to Ar being in the range of approximately 5 to 25%, and the pressure being in the range of approximately 1 to 10 T. Step  108  decomposes the precursor on the IC surface to deposit, by chemical vapor deposition (CVD), an alloy film including the metal selected from the group consisting of Zr and Hf, the doping metal, and oxygen. 
     Step  110  anneals at a temperature in the range of approximately 400 to 800 degrees C. Step  110  includes establishing an atmosphere including elements selected from the group consisting of Ar, N 2 , N 2 :H 2  forming gas, O 2 , H 2 O, N 2 O, NO, no gas, and oxygen plasma. Step  112  is a product, where a thin film having a high dielectric constant and good barrier properties is formed. 
     In some aspects of the invention, Step  100  provides a silicon IC surface, and a further step precedes Step  108 . Step  106   a  establishes an IC silicon surface temperature in the range of approximately 300 and 500 degrees C. 
     In another embodiment of the present invention, atomic layer chemical vapor deposition (ALCVD) is used to form the doped metal oxide dielectric layer. ALCVD employs a chemical phenomenon known as chemisorption. In chemisorption, a material in a gas phase will adsorb to a surface saturating it, forming a monolayer. Most conventional deposition techniques employ physisorption processes, which produce multilayer deposition regions with a surface coverage that is purely statistical. By taking advantage of chemisorption, films can be grown that are extremely uniform in thickness and composition. For instance, zirconium oxide films have reportedly been grown this way on silicon by using zirconium chloride (ZrCl 4 ) to form the first monolayer, purging the system of ZrCl 4 , and then exposing the surface to water vapor (H 2 O). Other precursors for producing zirconium oxide layers include zirconium propoxide (Zr(iOPr) 4 ) and zirconium tetramethyl heptanedionato (Zr(tmhd) 4 ). Chemisorption occurs over a very limited range of temperature and pressures for a given gas-solid combination. Typically the temperature will be between 100 and 700 degrees C. at a pressure of between 1 and 1000 mTorr. For example, zirconium oxide has reportedly been deposited on silicon substrates at a temperature of 300 degrees Celsius using ZrCl 4  and H 2 O. As the process produces a monolayer, thicker layers of zirconium oxide would be produced by adding additional monolayers. A doping precusor may be used to deposit a layer of doping metal. ALCVD is also commonly referred to as pulsed CVD. This is because the methodology typically relies on a pulse of precursor material to control the amount of material to be deposited. Typically the pulse will contain enough material to coat an IC surface. In another embodiment of the present method, the pulse of doping precursor is introduced that is less than that required to form a monolayer over the entire IC surface. The general processes will need to be optimized, without undue experimentation, to utilize chemisorption in connection with selected precursors. The critical aspects of this deposition scheme are sufficient purging from one component prior to introduction of the next component, and the ability to control the temperature and pressure. Atomic layer deposition makes it possible to produce layers of less than 10 angstroms thick, and preferably layers between approximately 2 and 5 angstroms thick. An efficient tool for preparing such ultrathin, atomic layers depositions on semiconductor substrates does not currently exist, although experimental depositions have demonstrated that atomic layer deposition is workable. 
     FIG. 5 is a flowchart illustrating the steps in an ALCVD method of forming a doped metal oxide film. 
     Step  150  provides an integrated circuit (IC) having a surface. In a preferred embodiment, the surface native oxide on the surface is desorbed to provide a bare silicon surface. 
     Step  152  prepares at least one precursor including a metal selected from the group consisting of Zr and Hf, vaporizes the at least one precursor, and exposes the IC surface to the at least one precursor. The precursor should be suitable for depositing a monolayer of material on an IC surface in an ALCVD chamber. For example, in a preferred embodiment zirconium chloride (ZrCl 4 ), zirconium propoxide (Zr(iOPr) 4 ) and zirconium tetramethyl heptanedionato (Zr(tmhd) 4 )is the precursor for depositing Zr, whereby Zr adsorbs to the IC surface forming a monolayer. 
     Step  154  prepares an oxygen precursor and exposing the IC surface to the oxygen precursor. Preferably the oxygen precursor will be a vapor. For example, in a preferred embodiment, H 2 O is used as the oxygen precursor. 
     Step  156  prepares a doping precursor including a doping metal. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). In a preferred embodiment, the doping precursor is selected from the group consisting of AlCl 3 , Al(CH 3 ) 3 , and Al(acac) 3 , for aluminum doping. The IC surface is exposed to the doping precursor, whereby a layer, or partial layer, of doping metal is adsorbed onto the IC surface. 
     Step  158  refers to the result of successive steps and repetitions of steps  152 ,  154  and  156  as necessary to produce the desired dielectric material. As can is denoted by the arrows to the left, steps  152 ,  154  and  156  may need to be repeated individually or in varying sequences to produce the desired dielectric material. The requirement for repetition is in large part due to the monolayer deposition associated with ALCVD. As is well known in the art of ALCVD, each precursor is preferably exhausted between successive layers, even if the same precursor is used for the subsequent layer. The precursors should be preferably be pulsed with sufficient material to produce a monolayer of material over the IC surface. 
     Step  160  following deposition the dielectric material is annealed to finally condition the dielectric material and the interface with the underlying material. 
     Step  162  refers to the final high dielectric constant film. 
     Although step  152  and  156  are shown as distinct steps, in another embodiment of the present invention, the two precursors could be introduced simultaneously. 
     FIG. 6 is a flowchart illustrating steps in an evaporation method of forming a doped metal oxide film. Step  200  provides an integrated circuit (IC) having a silicon surface. Step  202  prepares at least one crucible including the metal selected from the group consisting of Zr and Hf, and the doping metal. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). Step  204  establishes a vacuum (gas-free) atmosphere. Step  206  heats the at least one crucible to a crucible temperature in the range of approximately 1000 and 2000 degrees C., to evaporate the metals prepared in Step  202 . Step  208 , in response to steps  202  through  206 , deposits an alloy film including the metal selected from the group consisting of Zr and Hf, and the doping metal. Step  210  anneals in an atmosphere including oxygen at a temperature in the range of approximately 400 to 800 degrees C. to form an alloy film including the metal selected from the group consisting of Zr and Hf, the doping metal, and oxygen. Step  210  includes establishing an atmosphere including elements selected from the group consisting of Ar, N 2 , N 2 :H 2  forming gas, O 2 , H 2 O, N 2 O, NO, no gas, and oxygen plasma. Step  212  is a product, where a thin film having a high dielectric constant and good barrier properties is formed. 
     In some aspects of the invention, step  202  includes a first crucible for the metal selected from the group of Zr and Hf, and a second crucible for the doping metal. Then, Step  206  includes heating the first crucible to a temperature in the range of approximately 1000 and 2000 degrees C., and heating the second crucible to a temperature in the range of approximately 1000 and 2000 degrees C. The Zr/Hf crucible need not be the same temperature as the doping metal crucible. 
     In some aspects of the invention, Step  210  includes sub-steps (not shown). Step  210   a  anneals in an atmosphere including oxygen at a temperature in the range of approximately 400 and 900 degrees C. Step  210   b  anneals in an atmosphere including elements selected from the group consisting of Ar, N 2 , N 2 :H 2  forming gas, O 2 , H 2 O, N 2 O, NO, no gas, and oxygen plasma, at a temperature in the range of approximately 400 and 900 degrees C. A high-k dielectric film has been disclosed along with several methods of making same. The electron affinity, electron barrier height, 
     and hole barrier height, of the dielectric film can be modified by including a doping metal. The doping metal is preferably a trivalent metal, such as aluminum (Al), scandium (Sc), lanthanum (La), or yttrium (Y), or a divalent metal, such as calcium (Ca) or strontium (Sr). 
     In a preferred embodiment, the high-k dielectric film remains amorphous at relatively high annealing temperatures. Because the film does not form a crystalline structure, interfaces to adjacent films have fewer irregularities. When used as a gate dielectric, the film can be made thick enough to provide the capacitance required to couple the gate electric field into the channel regions, while the surface of the channel region can be made smooth to support high electron mobility. The film is formed through CVD, ALCVD, sputtering, or evaporation deposition methods. Other variations and embodiments of the present invention will likely occur to others skilled in the art. 
     Although certain embodiments have been described above, the scope of the invention is by no means limited to the disclosed embodiments. Reasonable changes and new improvements to the invention may be made in the future, and yet still within the scope of this invention. This invention is defined by the claims.