Abstract:
Polyalkylated benzenes containing chlorosilyl groups represented by formula III ##STR1## wherein R 1  represents hydrogen or alkyl; R 2  represents hydrogen or alkyl; R&#39; represents methyl or chloro; and n=3-6.

Description:
BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to polyalkylated benzenes containing chlorosilyl groups and to a process for the preparation of the compounds by reacting a benzene compound with a vinylchlorosilane. 
     2. Description of the Background 
     In 1877, Friedel and Crafts first reported that when benzene is reacted with alkyl chloride in the presence of aluminum chloride catalyst, benzene is substituted with the alkyl group of the alkyl chloride. Under the same reaction conditions, acyl chloride is also known to react with benzene to give acylbenzene. The Friedel-Crafts alkylation and acylation reactions have been widely used as synthetic procedures for alkyl or acyl group substituted aromatic compounds in the laboratory and on the commercial scale as well. (Friedel, C.; Crafts, J. M., Bull. Soc. Chim. France, 27(2), 530, 1877. 
     In 1879, Balson reported that aromatic compounds react with olefins in the presence of Lewis acids such as aluminum chloride, the reaction being an addition reaction of olefin to the aromatic compounds. (Balson, M., Bull. Soc. Chim. France. 1879, 2, 31, 539) This Friedel/Crafts type alkylation has been widely used for the preparation of ethylbenzene and isopropylbenzene in the petrochemical industry. (Yoneda, N., Sekiyu Gakkai Shi. 1972, 15(11), 894). 
     Friedel-Crafts also reported obtaining a mixture of toluene, xylenes, durene, and penta- and hexamethylbenzene from a reaction of benzene with methyl chloride in the presence of aluminum chloride. (Friedel, C.; Crafts, J. M., Compt., rend. 1877, 84, 1392). Anschutz and Immendorff reported that methylated benzenes from mono- to hexamethylated benzene were obtained from the reaction of methyl chloride with benzene and the distribution of each component varied depending upon the reaction conditions such as mixing ratios of the reactants and reaction time. They also obtained similar results from the reaction of ethyl chloride with benzene. (Anschutz, R., Immendorff, H. Ber. 1885, 18, 657). 
     In 1957, Chernyshev and Dolgaya reported first that aromatic compounds can be alkylated with chloroethyl group containing chlorosilanes. They obtained trichlorosilylethyl substituted aromatic compounds from the Friedel-Crafts alkylation with chloroethyl trichlorosilane in good yields from 30 to 83%. (Chernyshev, E. A.; Dolgaya, M. E., Zhur. Obshchei Khim. 1957, 27, 48-51) In 1953, Wagner et al. reported that vinylchlorosilanes can be added to aromatic compounds in the presence of aluminum chloride catalyst. They obtained β-phenylethyltrichlorosilane as the major product and bis(trichlorosilylethyl)benzene as a minor product from the reaction of vinyltrichlorosilane with benzene. (Wagner, G. H.; Bailey, D. L.; Pines, A. N.; Dunhum, M. L. and McIntire, D. B., Industrial and Engineering Chemistry 1953, 45, 367). In 1961, Andrianov et al. reported that bis(chlorosilylethyl)benzene can be prepared in yields from 30 to 50% by reacting benzene with sufficient vinylchlorosilane. (Andrianov, K. B.; Zhdanov, A. A. and Odinets, V. A., Zh. Obshch. Khim., 1961, 31, 4033-8; Andrianov, K. B.; Zhdanov, A. A. and Odinets, V. A., Zh. Obshch. Khim., 1962, 38(3), 627-31). ##STR2## 
     In 1966, Nametkin et al. reported that substituted benzenes can be alkylated with allylchlorosilanes such as allyldichlorosilane and allyltrichlorosilane to give (2-arylpropyl)chlorosilanes. The yields ranged from 34% to 66%, depending upon the benzene ring substituents, but information concerning product isomer distribution was not reported. (Nametkin, N. S.; Vdovin, V. M.; Finkelshtein, E. S.; Oppengeium, V. D. and Chekalina, N. A., Izv. Akad. Nauk SSSR, Ser. Khim., 1966, (11) 1998-2004). 
     The present inventors reported the preparation of (2-arylpropyl)dichlorosilanes by the Friedel-Crafts alkylation of various substituted aromatic compounds with allyldichlorosilane in the presence of Lewis acid catalysts in good yields ranging from 60% to 80%. (Lee, B. W.; Yoo, B. R.; Kim, S. I.; Jung, I. N., Organometallics 1994, 13, 1312). In this reaction, bis-alkylated aromatic compounds were obtained by controlling the reaction conditions such as the mole ratio of the reactants. However, the yield of polyalkylated compounds was very low probably because of the steric hindrance of silyl group containing isopropyl groups. 
     SUMMARY OF THE INVENTION 
     Accordingly, one object of the present invention is to provide a method of preparing polyalkylated benzene compounds containing chlorosilyl groups. 
     Briefly, this object and other objects of the present invention as hereinafter will become more readily apparent can be attained by polyalkylated benzenes containing chlorosilyl groups of formula III: ##STR3## wherein R 1  is hydrogen or alkyl, R 2  is hydrogen or alkyl, R&#39; is methyl or chloro and n is an integer of 3 to 6. 
     The polyalkylated benzene containing chlorosilyl groups is prepared by reacting a vinylchlorosilane of formula II with a benzene compound of formula I in the presence of a Lewis acid catalyst. ##STR4## wherein R 1 , R 2  and R&#39; are as defined above. 
     DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     The alkylation reactions of the present invention can be conducted in standard laboratory glassware or commercial equipment, under inert atmosphere, with units for external cooling and heating, stirring, and for incremental addition of the starting aromatic compounds or vinylchlorosilanes. The reaction can be carried out in most of the nonaromatic hydrocarbon solvents, but it also proceeds under neat conditions. Any hydrocarbon solvent which is inert to the Freidel-Crafts reaction conditions may be used in the present invention. Suitable solvents include carbon disulfide, petroleum ether, ethylene chloride, methylene chloride, and carbon tetrachloride. Alternatively, the reaction may be run with an excess of the benzene compound as solvent. 
     Suitable Lewis acid catalysts include any Lewis acid catalyst which will function as a Freidel-Crafts catalyst. Freidel-Crafts catalysts are electron acceptors and are well known in the art. Suitable catalysts are described, for example, in Encyclopedia of Chemical Technology, 1980, vol. 11, pp. 292-297. Suitable catalysts include, but are not limited to AlC 3 , AlBr 3 , AlI 3 , GaCl 3 , GaCl 2 , GaBr 3 , GaI 3 , ZrCl 4 , HfCl 4 , HfBr 4 , HfI 4 , SbF 5 , NbF 5 , NbCl 5 , TaF 5 , TaCl 5 , TaBr 5 , MoF 6  and MoCl 5 . A preferred catalyst is aluminum chloride (AlCl 3 ). The catalyst is used in an amount sufficient to catalyze the reaction; generally, in an amount of about 0.001-0.1 moles of catalyst per mole of the vinylchlorosilane. 
     As used herein, the term &#34;alkyl&#34; means an alkyl group which enables the vinylchlorosilane and the benzene compound to undergo the desired Freidel-Crafts reaction. One having ordinary skill in this art can easily determine the degree of branching and number of carbon atoms in suitable alkyl groups with a few preliminary experiments in which the product mixture is analyzed to determine the presence of the polyalkylated benzene. The product mixture may be analyzed using any suitable well-known method, for example, high pressure liquid chromatography, thin layer chromatography, etc. Preferably, R 1  is hydrogen or a linear or branched alkyl group having 1-10 carbon atoms, more preferably 1-4 carbon atoms. R 2  is preferably hydrogen or a linear or branched alkyl group having 1-4 carbon atoms, preferably 1-2 carbon atoms, more preferably methyl. 
     In a typical preparation, benzene compounds represented by formula I and catalyst are placed in the reactor under inert atmosphere. A vinyl-chlorosilane represented by formula II is then slowly added to the solution with stirring. The reaction may be exothermic, but it is desirable to maintain the reaction temperature below 80° C. by controlling the rate of addition of reactant or by continuously carrying out external cooling. Depending upon the targeted alkylation compound, vinylchlorosilanes represented by formula II may be used in a 0.01 to 20 fold amount, preferably a 4 to 10 fold amount, relative to the benzene derivative represented by formula I in terms of molar quantities. After completion of addition, heating and stirring may be carried out for certain period of time, generally about 10 minutes to about 10 hours, to complete the alkylation and then the solid products may be filtered and the liquid products fractionally distilled at atmosphere or under vacuum. 
     The polyalkylated aromatic compounds containing silicon-chlorine bonds of the invention can be functionalized by reaction with organolithium compounds and can be polymerized by hydrolysis to produce silicon polymers in a process which is analogous to the well-known chlorosilane hydrolysis of chlorosilane monomers to produce silicone polymers. See, for example, the discussion of silicone polymers and methods of making these polymers described in Encyclopedia of Chemical Technology, 1982, vol. 20, pps. 922-962 and the references cited therein. The silicone polymers prepared from the monomers of the present invention are suitable for use as emulsions, greases, adhesives, sealants, coatings, etc. in the automotive and engineering fields. 
    
    
     EXAMPLES 
     Having generally described this invention, a further understanding can be obtained by reference to certain specific examples which are provided herein for purposes of illustration only and are not intended to be limiting unless otherwise specified. 
     Example 1 
     Reaction of Benzene With Vinyldichloromethylsilane 
     To a 100 ml, three necked, round bottomed flask equipped with a mechanical stirrer, a dropping funnel, and a reflux condenser, 0.10 g (0.75 mmol) of aluminum chloride and 0.87 g (11.00 mmol) of benzene were placed under a dry nitrogen atmosphere. To the solution, 10.87 g (77.0 mmol) of vinyldichloromethylsilane was added dropwise while the flask was immersed in a water bath. The temperature of the water bath was increased from 25° C. to 50° C. because of the exothermic nature of the alkylation reaction. After completion of addition, the solution was stirred vigorously for another two hours. The water temperature dropped down to room temperature again and some solid precipitated out of solution. 20 ml of dried hexane and 10.3 g (0.0051 mol) of NaCl were added to the solution and the solution was stirred at 80° C. for 2 hours to deactivate aluminum chloride catalyst. The solid mixture was filtered and THF was added to dissolve the organic product. After filtering off NaCl, a recrystallization from THF gave 4.41 g (yield; 39.3%, mp; 165°-75° C.) of hexakis(methyldichlorosilylethyl)benzene. 
     On the other hand, vacuum distillation of the filtrate gave 1.16 g (yield; 10.3%), 1.52 g (yield; 13.5%), 1.17 g (yield; 10.4%, bp; 165°-70° C./0.6 mm), 0.58 g (yield; 5.17%, bp; 200°-4° C./0.6 mm), 0.96 g (8.53%, bp; 255°-9° C./0.6 mm) of mono-, bis-, tris-, tetrakis-, pentakis(methyldichlorosilylethyl)benzenes respectively. NMR data of the polyalkylated products prepared as above are listed in Table 1. 
     
                       TABLE 1______________________________________.sup.1 H NMR data of poly(methyldichlorosilylethyl)benzenesNo.of subst.  NMR data (ppm)(n)    Si--CH.sub.3           Si--CH.sub.2                      Aryl-CH.sub.2                               Aryl-H______________________________________3      0.82 (s) 1.42-1.52 (m)                      2.80-2.90 (m)                               7.08-7.22 (m)4      0.83 (s) 1.42-1.52 (m)                      2.80-2.90 (m)                               7.03 (s)5      0.84 (s) 1.42-1.52 (m)                      2.80-2.90 (m)                               6.97 (s)6      0.87 (s) 1.29-1.36 (m)                      2.71-2.77 (m)                               *______________________________________ 
    
     Example 2 
     Reaction of Toluene With Vinyldichloromethylsilane 
     In the same apparatus and by the same procedure of EXAMPLE 1, 0.88 g (9.35 mmol) of toluene, 9.78 g (69.35 mmol) of vinyldichloromethylsilane and 0.12 g (0.90 mmol) of aluminum chloride were reacted for 1 hour under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 4.55 g (yield; 61.16%, mp; 254°-6° C.) of white crystalline pentakis(methyldichlorosilylethyl)toluene. Distillation of the filtrate gave 0.11 g (yield; 1.48%), 0.14 g (yield; 1.88%), 0.48 g (yield; 6.18%, bp; 179°-82° C./0.6 mm), 0.86 g (yield; 11.56%, bp; 214°-8° C./0.6 mm) of mono-, bis-, tris-, and tetrakis(methyldichlorosilylethyl)toluenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 2. 
     Table 2.  1  H NMR data of poly(methyldichlorosilylethyl)toluenes 
     
         __________________________________________________________________________No. ofSubst    NMR data (ppm)(n) Si--CH.sub.3      Si--CH.sub.2             Aryl--CH.sub.3                    Aryl--CH.sub.2                           Aryl--H__________________________________________________________________________3   0.82-0.99(m)      1.22-1.45(m)             2.30-2.38(m)                    2.65-2.91(m)                           6.93-7.14(m)4   0.91(s)      1.22-1.35(m)             2.32(s)                    2.85-2.91(m)                           6.93(m)5   0.86(s)      1.27-1.34(m)             2.27(s)                    2.73-2.83(m)                           *__________________________________________________________________________ 
    
     Example 3 
     Reaction of Ethylbenzene With Vinyldichloromethylsilane 
     In the same apparatus and by the same procedure described in EXAMPLE 1, 0.87 g (8.20 mmol) of ethylbenzene, 5.76 g (41.00 mmol) of vinyldichloromethylsilane and 0.01 g (0.082 mmol) of aluminum chloride were reacted for 3 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 1.66 g (yield; 25.0%, mp; 185°-8° C.) of white crystalline pentakis(methyldichlorosilylethyl)ethylbenzene. Distillation of the filtrate gave 0.069 g (yield; 1.04%), 0.29 g (yield; 4.38%, bp; 165°-9° C./0.6 mm), 0.586 g (yield; 8.73%, bp; 211°-6° C./0.6 mm), 0.12 g (yield; 1.81%), 0.71 g (yield; 10.7%), 0.75 g (yield; 11.3%), 0.32 g (yield; 4.83%), 0.43 g (yield; 6.55%) and 0.52 g (yield; 7.86%) of bis-, tris-, tetrakis(methyldichlorosilylethyl)ethylbenzenes, bis-, tris-, tetrakis(methyldichlorosilylethyl)diethylbenzenes, tris-, tetrakis- and pentakis(methyldichlorosilylethyl)benzenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 3. 
     
         __________________________________________________________________________No. ofSubst.    NMR data (ppm)(n) Si--CH.sub.2      Et(CH.sub.3)             Si--CH.sub.2                    Et(CH.sub.2)                           Aryl--CH.sub.2                                  Aryl--H__________________________________________________________________________3   0.59-0.75(m)      1.19-1.21(m)             1.42-1.49(m)                    2.58-2.60(m)                           2.71-2.77(m)                                  7.01-7.09(m)4   0.81-0.83(m)      1.19-1.21(m)             1.42-1.49(m)                    2.58-2.60(m)                           2.71-2.77(m)                                  6.95(s)5   0.87(m)      1.20(t)             1.29-1.36(m)                    2.59(q)                           2.71-2.77(m)                                  --__________________________________________________________________________ 
    
     Example 4 
     Reaction of n-propylbenzene With Vinyldichloromethylsilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, n-propylbenzene 0.86 g (7.17 mmol), vinyldichloromethylsilane 5.06 g (35.90 mmol) and aluminum chloride 0.047 g (0.35 mmol) were reacted for 1 hour under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 1.59 g (yield; 26.8%, mp; 201°-6° C.) of white crystalline pentakis(methyldichlorosilylethyl)-n-propylbenzene. Distillation of the filtrate gave 0.40 g (yield; 6.57%), 0.60 g (yield; 10.1%), 0.66 g (yield; 11.1%; bp: 182°-8° C./0.6 mm), 0.78 g (yield: 13.1%, bp; 210°-5° C./0.6 mm), 0.48 g (yield: 8.15%), 0.062 g (yield: 1.05%), and 0.094 g (yield: 1.59%) of mono-, bis-, tris-, tetrakis(methyldichlorosilylethyl)-n-propylbenzenes, tetrakis(methyldichlorosilylethyl)dipropylbenzenes, mono- and bis(methyldichlorosilylethyl)benzenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 4. 
     Table 4.  1  H NMR data of poly(methyldichlorosilylethyl)-n-propylbenzenes 
     
         __________________________________________________________________________No. ofSubst.    NMR data (ppm)(n) Si--CH.sub.3      Pr(CH.sub.3)             Si--CH.sub.2                    Pr(CH.sub.2)                           Pr(CH.sub.2)                                  Aryl--CH.sub.2                                         Aryl--H__________________________________________________________________________3   0.59-0.76(m)      1.00-1.02(m)             1.43-1.50(m)                    1.49-1.54(m)                           2.50-2.52(m)                                  2.71-2.79(m)                                         7.01-7.09(m)4   0.83, 0.84(s)      1.00-1.02(m)             1.43-1.50(m)                    1.49-1.54(m)                           2.50-2.52(m)                                  2.71-2.79(m)                                         6.95(s)5   0.87(s)      1.01(t)             1.30-1.37(m)                    1.49-1.54(m)                           2.51(t)                                  2.71-2.79(m)                                         *__________________________________________________________________________ 
    
     Example 5 
     Reaction of n-butylbenzene With Vinyldichloromethylsilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, n-butylbenzene 0.86 g (6.40 mmol), vinyldichloromethylsilane 4.52 g (32.00 mmol) and aluminum chloride 0.047 g (0.35 mmol) were reacted for 1 hour under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 1.35 g (yield: 26.8%, mp; 218°-25° C.) of white crystalline pentakis(methyldichlorosilylethyl)-n-butylbenzene. Distillation of the filtrate gave 0.34 g (yield: 6.75%), 0.51 g (yield: 10.1%), 0.56 g (yield: 11.1%, bp: 182°-8° C./0.6 mm), 0.66 g (yield: 13.1%, bp: 210°-5° C./0.6 mm), 0.41 g (yield: 8.15%), 0.053 g (yield: 1.05%) and 0.08 g (yield: 1.59%) of mono-, bis-, tris-, tetrakis(methyldichlorosilylethyl)-n-butylbenzenes, tetrakis(methyldichlorosilylethyl)dibutylbenzene, mono- and bis(methyldichlorosilylethyl)benzenes respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 5. 
     
                                           TABLE 5__________________________________________________________________________.sup.1 H NMR data of poly(methyldichlorosilylethyl)-η-butylbenzenesNo. ofSubst.    NMR data (ppm)(n) Si--CH.sub.3      Bu(CH.sub.3)             Si--CH.sub.2                    Bu(CH.sub.2 CH.sub.2)                           Bu(CH.sub.2)                                  Aryl--CH.sub.2                                         Aryl--H__________________________________________________________________________3   0.59-0.78(m)      1.00-1.02(m)             1.45-1.51(m)                    1.49-1.54(m)                           2.51-2.53(m)                                  2.71-2.79(m)                                         7.01-7.09(m)4   0.83-0.84(s)      1.00-1.02(m)             1.45-1.51(m)                    1.49-1.54(m)                           2.51-2.53(m)                                  2.71-2.79(m)                                         6.95(s)5   0.87(s)      1.01(t)             1.32-1.38(m)                    1.49-1.54(m)                           2.52(t)                                  2.71-2.79(m)                                         *__________________________________________________________________________ 
    
     Example 6 
     Reaction of o-xylene With Vinyldichloromethylsilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, o-xylene 0.87 g (8.21 mmol), vinyldichloromethylsilane 6.95 g (49.34 mmol) and aluminum chloride 0.096 g (0.72 mmol) were reacted for 2 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 1.50 g (yield: 29.07%) of white crystalline tetrakis(methyldichlorosilylethyl)-p-xylene. Distillation of the filtrate gave 0.08 g (yield: 1.16%), 0.24 g (yield: 4.65%), 0.48 g (yield; 9.30%, bp: 183°-8° C./0.6 mm), 2.37 g (yield: 45.93%, bp: 230°-2° C./0.6 mm) and 0.05 g (yield: 0.97%) of mono-, bis-, tris-, tetrakis(methyldichlorosilylethyl)-o-xylenes and tetrakis(methyldichlorosilylethyl)toluene, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 6. 
     
                                           TABLE 6__________________________________________________________________________.sup.1 H NMR data of poly(methyldichlorosilylethyl)-o-xylenesNo. ofSubst.    NMR data (ppm)(n) Si--CH.sub.3      Si--CH.sub.2             Aryl--CH.sub.3                    Aryl--CH.sub.2                           Aryl--H__________________________________________________________________________3   0.82-1.00(m)      1.12-1.45(m)             2.19-2.33(m)                    2.85-2.97(m)                           6.92-7.12(m)4   0.91(s)      1.12-1.45(m)             2.28(s)                    2.65-2.97(m)                           *__________________________________________________________________________ 
    
     Example 7 
     Reaction of m-xylene With Vinyldichloromethylsilane 
     In the same apparatus and by the same procedure as EXAMPLE 1, m-xylene 0.87 g (8.20 mmol), vinyldichloromethylsilane 4.60 g (22.00 mmol) and aluminum chloride 0.14 g (0.82 mmol) were reacted for 2 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 1.34 g (yield: 24.5%) of white crystalline tetrakis(methyldichlorosilylethyl)-P-xylene. Distillation of the filtrate gave 0.82 g (yield: 15.0%), 0.25 g (yield: 4.58%), 2.14 g (yield: 39.1%, bp; 182°-8° C./0.6 mm) and 0.25 g (yield: 4.56%, bp: 230°-5° C./0.6 mm) of mono-, bis-, tris- and tetrakis(methyldichlorosilylethyl)-m-xylenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 7. 
     
                                           TABLE 7__________________________________________________________________________1H NMR data of poly(methyldichlorosilyl-ethyl)-m-xylenesNo. ofSubst.    NMR data (ppm)(n) Si--CH.sub.3      Si--CH.sub.2              Aryl--CH.sub.3                      Aryl--CH.sub.2                              Aryl--H__________________________________________________________________________3   0.80, 0.84(s)      1.36-1.49(m)              2.23-2.28(m)                      2.80-2.85(m)                              6.90(s)4   0.88(s)      1.28-1.34(m)              2.29(s) 2.80-2.85(m)                              *__________________________________________________________________________ 
    
     Example 8 
     Reaction of p-xylene With Vinyldichloromethylsilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, p-xylene 0.87 g (8.20 mmol), vinyldichloromethylsilane 4.60 g (22.00 mol) and aluminum chloride 0.22 g (1.65 mmol) were reacted for 1 hour under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 3.48 g (yield: 63.6%, mp: 193°-8° C.) of white crystalline tetrakis(methyldichlorosilylethyl)-p-xylene. Distillation of the filtrate gave 0.82 g (yield: 15.0%), 0.25 g (yield: 4.58%) and 0.71 g (yield: 12.98, bp: 182°-8° C./0.6 mm) of mono-, bis- and tris(methyldichlorosilylethyl)-p-xylenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 8. 
     
                                           TABLE 8__________________________________________________________________________.sup.1 H NMR data of poly(methyldichlorosilylethyl)-p-xylenesNo. ofsubst.    NMR data (ppm)(n) Si--CH.sub.3      Si--CH.sub.2              Aryl--CH.sub.3                      Aryl--CH.sub.2                              Aryl--H__________________________________________________________________________3   0.79(s)      1.34-1.46(m)              2.31(s) 2.80-2.85(m)                              7.02(s)4   0.88(s)      1.28-1.34(m)              2.29(s) 2.80-2.85(m)                              *__________________________________________________________________________ 
    
     Example 9 
     Reaction of Benzene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, benzene 0.87 g (11.00 mmol), vinyltrichlorosilane 11.18 g (69.00 mmol) and aluminum chloride 0.3 g (2.25 mmol) were reacted at 80° C. for 1 hour under the dry nitrogen atmosphere. Recrystallization of solid product from THF gave 5.15 g (yield: 42.7%, bp: 135°-8° C.) of 1,2,4,5-tetrakis(trichlorosilylethyl)benzene. Distillation of the filtrate gave 0.73 g (yield: 6.04%, bp: 176°-9° C./0.6 mm), 7.41 g (yield: 61.5%, bp: 204°-10° C./0.6 mm) and 1.31 g (yield: 10.8%, bp: 261°-6° C./0.6 mm) of tris-, tetrakis- and pentakis(trichlorosilylethyl)benzenes, respectively isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 9. 
     
                       TABLE 9______________________________________.sup.1 H NMR data of poly(trichlorosilylethyl)benzenesNo. ofSubst.  NMR data (ppm)(n)     Si--CH.sub.2 Aryl-CH.sub.2                           Aryl-H______________________________________3       1.51-1.59 (m)                2.81-2.98 (m)                           7.10-7.22 (m)4       1.61-1.69 (m)                2.18-2.98 (m)                           7.02-7.14 (m)5       1.71-1.79 (m)                2.81-2.98 (m)                           7.01 (s)______________________________________ 
    
     Example 10 Reaction of Toluene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, toluene 0.88 g (9.35 mmol), vinyltrichlorosilane 7.55 g (46.80 mmol) and aluminum chloride 0.12 g (0.90 mmol) were reacted at 80° C. for 6 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 0.51 g (yield: 6.12%, bp: 264°-6° C.) of pentakis(trichlorosilylethyl)toluene. Distillation of the filtrate gave 3.37 g (yield: 40.1%, bp: 189°-92° C./0.6 mm) and 3.62 g (yield: 43.00%, bp: 224°-8° C./0.6 mm) of tris- and tetrakis(trichlorosilylethyl)toluenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 10. 
     Table 10.  1  H NMR data of poly(trichlorosilylethyl) toluenes 
     
         ______________________________________No.ofsubst.NMR data (ppm)(n)  Si--CH.sub.2           Aryl-CH.sub.3                      Aryl-CH.sub.2                               Aryl-H______________________________________3    1.62-1.72 (m)           2.23-2.28 (m)                      2.78-2.88 (m)                               6.93-7.14 (m)4    1.62-1.72 (m)           2.23-2.28 (m)                      2.78-2.88 (m)                               6.93 (s)5    1.52-1.59 (m)           2.28 (s)   2.78-2.88 (m)                               *______________________________________ 
    
     Example 11 
     Reaction of Ethylbenzene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure described in EXAMPLE 1, ethylbenzene 0.87 g (8.20 mmol), vinyltrichlorosilane 6.59 g (40.80 mmol) and aluminum chloride 0.47 g (3.52 mmol) were reacted at 80° C. for 6 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 0.18 g (yield: 2.47%, mp: 195°-8° C.) of pentakis(trichlorosilylethyl)ethylbenzene. Distillation of the filtrate gave 1.56 g (yield: 18.6%, bp: 175°-9° C./0.6 mm), 1.20 g (yield: 14.3% bp: 221°-6° C./0.6 mm), 0.15 g (yield: 1.81%), 0.84 g (yield: 10.7%), 0.95 g (yield: 11.3%), 0.41 g (yield: 4.83%), 0.55 g (yield: 6.55%) and 0.66 g (yield: 7.86%) of tris-, tetrakis(trichlorosilylethyl)ethylbenzenes, bis-, tris-, tetrakis(trichlorosilylethyl)diethylbenzenes, tris-, tetrakis- and pentakis(trichlorosilylethyl)benzene respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 11. 
     
                                           TABLE 11__________________________________________________________________________.sup.1 H NMR data ofpoly(trichlorosilylethyl)ethylbenzenesNo. ofsubst.    NMR data (ppm)(n) Et(CH.sub.3)      Si--CH.sub.2             Et(CH.sub.2)                    Aryl--CH.sub.2                           Aryl--H__________________________________________________________________________3   1.21-1.08(m)      1.70-1.74(m)             2.61-2.65(m)                    2.78-2.83(m)                           6.94-7.19(m)4   1.21-1.08(m)      1.70-1.74(m)             2.61-2.65(m)                    2.78-2.83(m)                           6.94-7.19(m)5   1.23(t)      1.60-1.67(m)             2.62(q)                    2.78-2.83(m)                           *__________________________________________________________________________ 
    
     Example 12 
     Reaction of n-propylbenzene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, n-propylbenzene 0.86 g (7.17 mmol), vinyltrichlorosilane 5.9 g (35.90 mmol) and aluminum chloride 0.047 g (0.35 mmol) were reacted at 80° C. for 6 hours under dry nitrogen atmosphere. Recrystallization of solid product from THF gave 0.18 g (yield: 2.86%, mp; 211°-6° C.) of pentakis(trichlorosilylethyl)-n-propylbenzene. Distillation of the filtrate gave 2.43 g (yield: 36.51%, bp: 192°-8° C./0.6 mm), 2.00 g (yield: 30.0%, bp: 220°-5° C./0.6 mm), 0.61 g (yield: 9.15%), 0.14 g (yield: 2.05%) and 0.24 g (yield: 3.59%) of tris-, tetrakis(trichlorosilylethyl)-n-propylbenzenes, tetrakis(trichlorosilylethyl)dipropylbenzene, mono- and bis(trichlorosilylethyl)benzenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 12. 
     
                                           TABLE 12__________________________________________________________________________.sup.1 H NMR data of poly(trichlorosilylethyl)-n-propylbenzenesNo. of Subst NMR data (ppm)(n)   Pr(CH.sub.3)        SI--CH.sub.2               Pr(CH.sub.2)                      Pr(CH.sub.2)                             Aryl--CH.sub.2                                    Aryl--H__________________________________________________________________________3     1.02-1.08(m)        1.70-1.74(m)               1.74-1.79(m)                      2.53-2.55(m)                             2.78-2.83(m)                                    6.94-7.19(m)4     1.02-1.08(m)        1.70-1.74(m)               1.74-1.79(m)                      2.53-2.55(m)                             2.78-2.83(m)                                    6.94-7.19(m)5     1.04(t)        1.60-1.67(m)               1.74-1.79(m)                      2.54(t)                             2.78-2.83(m)__________________________________________________________________________ 
    
     Example 13 
     Reaction of n-butylbenzene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure described in EXAMPLE 1, n-butylbenzene 0.86 g (6.40 mmol), vinyltrichlorosilane 5.17 g (32.00 mmol) and aluminum chloride 0.047 g (0.35 mmol) were reacted at 80° C. for 6 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 6.16 g (yield: 2.68%, mp: 228°-35° C.) of pentakis(trichlorosilylethyl)-n-butylbenzene. Distillation of the filtrate gave 2.20 g (yield: 36.59%, bp: 192°-8° C./0.6 mm), 1.81 g (yield: 30.0%, bp: 220°-5° C./0-6 mm), 0.63 g (yield: 10.15%), 0.12 g (yield: 2.05%) and 0.22 g (yield: 3.59%) of tris-, tetrakis(trichlorosilylethyl)-n-butylbenzenes, tetrakis(trichlorosilylethyl)dibutylbenzene, mono- and bis(trichlorosilylethyl)benzenes, respectively. isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 13. 
     
                                           TABLE 13__________________________________________________________________________1H NMR data of poly(trichlorosilylethyl)-n-butylbenzenesNo. of Subst  NMR data (ppm)(n)    Bu(CH.sub.3)         Si--CH.sub.2                Bu(CH.sub.2 CH.sub.2)                       Bu(CH.sub.2)                              Aryl--CH.sub.2                                     Aryl--H__________________________________________________________________________3      1.02-1.08(m)         1.72-1.76(m)                1.74-1.79(m)                       2.54-2.56(m)                              2.78-2.83(m)                                     6.94-7.19(m)4      1.02-1.08(m)         1.72-1.76(m)                1.74-1.79(m)                       2.53-2.56(m)                              2.78-2.83(m)                                     6.94-7.19(m)5      1.04(t)         1.62-1.69(m)                1.74-1.79(m)                       2.55(t)                              2.78-2.83(m)                                     *__________________________________________________________________________ 
    
     Example 14 
     Reaction of o-xylene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, o-xylene 0.87 g (8.21 mmol), vinyltrichlorosilane 5.27 g (32.80 mmol) and aluminum chloride 0.096 g (0.72 mmol) were reacted at 80° C. for 2 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 0.83 g (yield: 15.1%) of tetrakis(trichlorosilylethyl)-p-xylene. Distillation of the filtrate gave 1.99 g (yield: 32.9%, bp: 193°-8° C./0.6 mm) and 1.91 g (yield: 30.3%, bp: 240°-2° C./0.6 mm) of tris- and tetrakis(trichlorosilylethyl)-o-xylenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 14. 
     
                       TABLE 14______________________________________.sup.1 H NMR data of poly(trichlorosilylethyl)-o-xylenesNo.ofsubst.NMR data (ppm)(n)  Si--CH.sub.2           Aryl-CH.sub.3                      Aryl-CH.sub.2                               Aryl-H______________________________________3    1.63-1.72 (m)           2.24-2.28 (m)                      2.84-2.90 (m)                               6.89-6.93(m)4    1.52-1.59 (m)           2.30 (s)   2.84-2.90 (m)                               *______________________________________ 
    
     Example 15 
     Reaction of m-xylene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, m-xylene 0.87 g (8.20 mmol), vinyltrichlorosilane 5.27 g (32.80 mol) and aluminum chloride 0.14 g (0.82 mmol) were reacted at 80° C. for 2 hour under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 2.46 g (yield: 40.0%) of tetrakis(trichlorosilylethyl)-p-xylene. Distillation of the filtrate gave 2.28 g (yield: 37.1%, bp: 192°-8° C./0.6 mm) and 0.49 g (yield: 8.05%, bp: 241°-5° C./0.6 mm) of tris- and tetrakis(trichlorosilylethyl)-m-xylenes, respectively. Isomeric mixtures were also obtained. NMR data of the polyalkylated products prepared as above as listed in Table 15. 
     
                       TABLE 15______________________________________.sup.1 H NMR data of poly(trichlorosilylethyl)-m-xylenesNo.ofsubst.NMR data (ppm)(n)  Si--CH.sub.2           Aryl-CH.sub.3                      Aryl-CH.sub.2                               Aryl-H______________________________________3    1.63-1.72 (m)           2.24-2.28 (m)                      2.84-2.90 (m)                               6.89-6.93 (m)4    1.52-1.59 (m)           2.30 (s)   2.84-2.90 (m)                               *______________________________________ 
    
     Example 16 
     Reaction of p-xylene With Vinyltrichlorosilane 
     In the same apparatus and by the same procedure as described in EXAMPLE 1, p-xylene 0.87 g (8.19 mmol), vinyltrichlorosilane 5.27 g (32.8 mmol) and aluminum chloride 0.11 g (0.82 mmol) were reacted at 80° C. for 2 hours under a dry nitrogen atmosphere. Recrystallization of solid product from THF gave 2.74 g (yield: 45.4%, mp; 220°-4° C.) of tetrakis(trichlorosilylethyl)-p-xylene. Distillation of the filtrate gave 1.99 g (yield: 32.9%, bp; 192°-8° C./0.6 mm) of tris (trichlorosilyethyl)-p-xylene. An isomeric mixture was also obtained. NMR data of the polyalkylated products prepared as above are listed in Table 16. 
     
                       TABLE 16______________________________________.sup.1 H NMR data of poly(trichlorosilylethyl)-p-xylenesNo.ofsubst.NMR data (ppm)(n)  Si--CH.sub.2           Aryl-CH.sub.3                      Aryl-CH.sub.2                               Aryl-H______________________________________3    1.63-1.72 (m)           2.24-2.28 (m)                      2.84-2.90 (m)                               6.89-6.93(m)4    1.52-1.59 (m)           2.30 (s)   2.84-2.90 (m)                               *______________________________________ 
    
     Having now fully described the invention, it will be apparent to one of ordinary skill in the art that many changes and modifications can be made thereto without departing from the spirit or scope of the invention as set forth herein.