Abstract:
Methods and materials for forming in-situ features in a ceramic matrix composite component are described. The method of forming a ceramic matrix composite component with cooling features, comprises forming a preform tape, laying up said preform tape to a desired shape, placing a high-temperature resistant fugitive material insert of preselected geometry in the preform tape of the desired shape, compacting the preform tape of the desired shape, burning out the preform tape of the desired shape, melt infiltrating the desired shape, removing the high-temperature resistant insert to form the cooling features during one of the burning out or the melt infiltrating or following the burning out or the melt infiltrating.

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
       [0001]    This application is a national stage application under 35 U.S.C. §371(c) of prior filed, co-pending PCT application serial number PCT/US14/35088, filed on Apr. 23, 2014 which claims priority to U.S. Patent Application Ser. No. 61/828,273, titled “METHODS AND MATERIALS FOR FORMING IN-SITU CAVITIES FOR SILICON-BASED CERAMIC MATRIX COMPOSITE COMPONENTS” filed May 29, 2013, all of which is incorporated by reference herein. 
     
    
     BACKGROUND 
       [0002]    The disclosed embodiments generally pertain to ceramic matrix composite components for gas turbine engines. More particularly, the present embodiments relate to methods and materials for forming in-situ cavities in ceramic matrix composite components. 
         [0003]    In a gas turbine engine, air is pressurized in a compressor and mixed with fuel in a combustor for generating hot combustion gases which flow downstream through turbine stages. A typical gas turbine engine generally possesses a forward end and an aft end with its several core or propulsion components positioned axially therebetween. An air inlet or intake is located at a forward end of the engine. Moving toward the aft end, in order, the intake is followed by a fan, a compressor, a combustion chamber, and a turbine. It will be readily apparent from those skilled in the art that additional components may also be included in the engine, such as, for example, low-pressure and high-pressure compressors, and low-pressure and high-pressure turbines. This, however, is not an exhaustive list. 
         [0004]    The compressor and turbine generally include rows of airfoils that are stacked axially in stages. Each stage includes a row of circumferentially spaced stator vanes and a rotor assembly which rotates about a center shaft or axis of the turbine engine. A multi-stage low pressure turbine follows the multi-stage high pressure turbine and is typically joined by a second shaft to a fan disposed upstream from the compressor in a typical turbo fan aircraft engine configuration for powering an aircraft in flight. These turbine stages extract energy from the combustion gases. 
         [0005]    The stator is formed by a plurality of nozzle segments which are abutted at circumferential ends to form a complete ring about the axis of the gas turbine engine. Each nozzle segment may comprise one or more vanes which extend between an inner band and an outer band. The stator nozzles direct the hot combustion gas in a manner to maximize extraction at the adjacent downstream turbine blades. 
         [0006]    Turbine rotor assemblies typically include at least one row of circumferentially-spaced rotor blades. Each rotor blade includes an airfoil that having a pressure side and a suction side connected together at leading and trailing edges. Each airfoil extends radially outward from a rotor blade platform. Each rotor blade may also include a dovetail that extends radially inward from a shank extending between the platform and the dovetail. The dovetail is used to mount the rotor blade within the rotor assembly to a rotor disc or spool. Known blades are hollow such that an internal cooling cavity is defined at least partially by the airfoil, platform, shank, and dovetail. 
         [0007]    Ceramic matrix composite (“CMC”) materials are of particular interest for use in gas turbine engines as higher operating temperatures are sought to increase efficiencies. CMC materials may be used for various components, for example airfoils in the turbine, compressor and fan regions of the engine. CMC materials typically comprise a ceramic fiber reinforcement material embedded in a ceramic matrix material. The reinforcement material aids to provide load-bearing function for the CMC and the ceramic matrix protects the reinforcement material, maintains fiber orientation and dissipates loads to the reinforcement material. Various methods are taught in U.S. Publication No. 2013/0285296 dated 31 Oct. 2013 and U.S. Publication 2014/0072736 dated 13 Mar. 2014, both of which are incorporated by reference herein. 
         [0008]    With currently utilized ceramic matrix composite components, features are formed in the parts after molding by subsequent machining. The machining results in removal of material to form the desired feature, for example, cooling apertures. The machined features are limited in design due to the manufacturing process of the machining to remove the material. For example, in a drilling process, the feature is generally limited to straight-line features. 
         [0009]    It would be desirable to overcome these and other features and form a molded component with improved geometric features that currently may not be formed utilizing known machining techniques. It is further desirable to decrease or eliminate material removal or clearing steps currently required in prior art molding techniques. 
       SUMMARY OF THE INVENTION 
       [0010]    According to present embodiments, a method of forming a molded ceramic matrix composite component is provided wherein an insert is provided in a preform layup of desired shape during the manufacturing process. The insert is formed of a material which can withstand temperatures associated with pyrolysis and melt infiltration steps of the manufacturing process. The insert may be formed of more complex shapes than otherwise available through known post molding processes to provide a molded feature which is otherwise not easily formable with current state of the art processes. 
         [0011]    A method of forming a ceramic matrix composite component with cooling features, comprises forming a preform tape, laying up the preform tape to a desired shape, placing a high-temperature resistant fugitive material insert of preselected geometry in the preform tape of the desired shape, compacting the preform tape of the desired shape, burning out the preform tape of the desired shape, melt infiltrating the desired shape, removing the high-temperature resistant insert to form the cooling features during one of the burning out or the melt infiltrating or following the burning out or the melt infiltrating. The method wherein the removing is one of mechanical or chemical removal. The method further comprises mechanically clearing the cooling features formed by the insert. The method further comprising forming the high-temperature fugitive material resistant insert of one of boron nitride, silica, silicon oxide, boron nitride coated DAP polymer, Y 2 Si 2 O 7  rare earth oxides, boron nitride coated silicon oxide, carbon coated boron nitride, molybdenum wire, high refractories and diamond powder. The method wherein the placing is by tape-cast placement, pre-formed tube placement, spraying, screen printing, rapid prototype polymer coated with boron nitride placement, and injection molding. The method wherein the removing is a chemical dissolution. The method wherein the removing occurring during the burning out or the melt infiltrating when the insert is formed of silicon oxide. The method wherein the melt infiltrating comprises inserting molten silicon at least 2600 degrees on the burned-out preform tape of preselected shape. The method further comprising forming complex non-line of sight cooling features. 
         [0012]    This Summary is provided to introduce a selection of concepts in a simplified form that are further described below in the Detailed Description. This Summary is not intended to identify key features or essential features of the claimed subject matter, nor is it intended to be used to limit the scope of the claimed subject matter. A more extensive presentation of features, details, utilities, and advantages of the present invention is provided in the following written description of various embodiments of the invention, illustrated in the accompanying drawings, and defined in the appended claims. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0013]    The above-mentioned and other features and advantages of these embodiments, and the manner of attaining them, will become more apparent and the methods and material for forming in-situ cavities will be better understood by reference to the following description of embodiments taken in conjunction with the accompanying drawings, wherein: 
           [0014]      FIG. 1  is a side section view of an exemplary gas turbine engine; 
           [0015]      FIG. 2  is a schematic view of a method of forming in-situ cavities; 
           [0016]      FIG. 3  is a top view of an exemplary coupon including a plurality of inserts for forming the cavities; 
           [0017]      FIG. 4  is a side section view of a portion of a preform layup including cavities formed by the coupon of  FIG. 3 ; and, 
           [0018]      FIG. 5  is a partial section view of a CMC component formed by the process with a molded feature therein. 
       
    
    
     DETAILED DESCRIPTION 
       [0019]    Reference now will be made in detail to embodiments provided, one or more examples of which are illustrated in the drawings. Each example is provided by way of explanation, not limitation of the disclosed embodiments. In fact, it will be apparent to those skilled in the art that various modifications and variations can be made in the present embodiments without departing from the scope or spirit of the disclosure. For instance, features illustrated or described as part of one embodiment can be used with another embodiment to still yield further embodiments. Thus it is intended that the present invention covers such modifications and variations as come within the scope of the appended claims and their equivalents. 
         [0020]    Referring to  FIGS. 1-5 , various embodiments of the methods and materials for forming in-situ cavities are depicted. The methods and materials are utilized to manufacture cavity features in a ceramic matrix composite (CMC) component, for example to create cooling channels, slots, holes, and or achieve weight reduction and/or other purposes or functions. The method involves a fugitive material which is inserted into a preform and is removed either during or after a melt infiltration process. The process allows creation of ceramic matrix composite components with more complex features, such as in-situ cavities, molded into the components which are not otherwise formable by known post-molding machining techniques. For example, the features may include complex, non-line of sight cooling features within a CMC component. Further, features may be more readily located near surfaces where heat reduction is desired for improved cooling for example. These examples however are not limiting and other embodiments may be utilized. 
         [0021]    As used herein, the terms “axial” or “axially” refer to a dimension along a longitudinal axis of an engine. The term “forward” used in conjunction with “axial” or “axially” refers to moving in a direction toward the engine inlet, or a component being relatively closer to the engine inlet as compared to another component. The term “aft” used in conjunction with “axial” or “axially” refers to moving in a direction toward the engine nozzle, or a component being relatively closer to the engine nozzle as compared to another component. 
         [0022]    As used herein, the terms “radial” or “radially” refer to a dimension extending between a center longitudinal axis of the engine and an outer engine circumference. The use of the terms “proximal” or “proximally,” either by themselves or in conjunction with the terms “radial” or “radially,” refers to moving in a direction toward the center longitudinal axis, or a component being relatively closer to the center longitudinal axis as compared to another component. The use of the terms “distal” or “distally,” either by themselves or in conjunction with the terms “radial” or “radially,” refers to moving in a direction toward the outer engine circumference, or a component being relatively closer to the outer engine circumference as compared to another component. 
         [0023]    As used herein, the terms “lateral” or “laterally” refer to a dimension that is perpendicular to both the axial and radial dimensions. 
         [0024]    All directional references (e.g., radial, axial, proximal, distal, upper, lower, upward, downward, left, right, lateral, front, back, top, bottom, above, below, vertical, horizontal, clockwise, counterclockwise) are only used for identification purposes to aid the reader&#39;s understanding of the present invention, and do not create limitations, particularly as to the position, orientation, or use of embodiments of the invention. Connection references (e.g., attached, coupled, connected, and joined) are to be construed broadly and may include intermediate members between a collection of elements and relative movement between elements unless otherwise indicated. As such, connection references do not necessarily infer that two elements are directly connected and in fixed relation to each other. The exemplary drawings are for purposes of illustration only and the dimensions, positions, order and relative sizes reflected in the drawings attached hereto may vary. 
         [0025]    Referring initially to  FIG. 1 , a schematic side section view of a gas turbine engine  10  is shown having an engine inlet end  12  wherein air enters a propulsor  13 , which is defined generally by a multi-stage compressor, including for example a low pressure compressor  15  and a high pressure compressor  14 , a combustor  16  and a multi-stage turbine, including for example a high pressure turbine  20  and a low pressure turbine  21 . Collectively, the propulsor  13  provides power during operation. The gas turbine  10  may be used for aviation, power generation, industrial, marine service or the like. The gas turbine  10  is axis-symmetrical about engine axis  26  so that various engine components rotate thereabout. In operation air enters through the air inlet end  12  of the engine  10  and moves through at least one stage of compression where the air pressure is increased and directed to the combustor  16 . The compressed air is mixed with fuel and burned providing the hot combustion gas which exits the combustor  16  toward the high pressure turbine  20 . At the high pressure turbine  20 , energy is extracted from the hot combustion gas causing rotation of turbine blades which in turn cause rotation of the shaft  24 . The shaft  24  passes toward the front of the engine to continue rotation of one or more high pressure compressor stages  14 . 
         [0026]    The engine  10  includes two shafts  24 ,  28 . The axis-symmetrical shaft  24  extends through the turbine engine  10 , from the forward end to an aft end. The shaft  24  is supported by bearings along its length. The shaft  24  may be hollow to allow rotation of the second shaft  28 , a low pressure turbine shaft therein. The shaft  28  extends between the low pressure turbine  21  and a low pressure compressor  15 . Both shafts  24 ,  28  may rotate about the centerline axis  26  of the engine. During operation the shafts  24 ,  28  rotate along with other structures connected to the shafts such as the rotor assemblies of the turbine  20 ,  21 , compressor  14 ,  15  and fan  18  in order to create power or thrust depending on the area of use, for example power, industrial or aviation. 
         [0027]    Referring still to  FIG. 1 , the inlet  12  includes a turbofan  18  which includes a circumferential array of exemplary blades  19  extending radially outward from the root. The turbofan  18  is operably connected by the shaft  28  to the low pressure turbine  21  and creates thrust for the turbine engine  10 . 
         [0028]    Within the turbine areas  20 ,  21  are airfoils which are exposed to extremely high temperature operating conditions. It is desirable to increase temperatures in these areas of the gas turbine engine as it is believed such increase results in higher operating efficiency. However, this desire to operate at high temperatures is bounded by material limitations in this area of the engine. Ceramic matrix composite (“CMC”) components have become a desired material for use due to their ability to better withstand higher temperature operating conditions than known metal alloys. 
         [0029]    Referring now to  FIG. 2 , a schematic flow chart is depicted of a method  100  for forming cooling features in a CMC component  200  ( FIG. 4 ). First, a fiber  112  is coated with a chemical vapor deposition (“CVD”) fiber coating at step  110 . According to some embodiments, the fiber  112  may be formed of silicon carbide. 
         [0030]    Next, the coated fiber  112  is moved through a prepreg slurry  114  at step  116 . The prepreg slurry  114  provides an additional protective coating for the fiber. Such prepreg  114  is desirable in the bonding of the fibers as well as protection of the fiber during the manufacturing process. 
         [0031]    After the prepregging slurry step  116 , the fiber  112  is wet wound at step  118 , for example, on a drum. The winding process allows for formation of pre-preg tapes  120  ( FIG. 4 ) which are subsequently cut to desired shapes and laid-up at step  122 . During the lay-up preforming at step  122 , a desired component  200  shape may be formed. For example, as shown in  FIG. 4 , the component  200  is depicted as an airfoil and more specifically may include but is not limited to, a turbine blade, a compressor blade, a turbine vane, a compressor vane, a fan blade or any of various features which may be exposed to high temperatures and may require various types of molded in features, including but not limited to cooling features. The lay-up performing step  122  comprises layering of multiple pre-preg tape structures  120  to form a desired shape of the component  200 . The layers  120  ( FIG. 4 ) are stacked to form the “lay-up” which is a precursor to the formed ceramic component  200 . 
         [0032]    Additionally during such lay-up performing step  122 , a fugitive material or insert  30  and coupon  32  ( FIG. 3 ) is positioned within the lay-up  200  ( FIG. 4 ) of preselected shape at step  124 . The insert  30  may be in the form of the desired feature only, for example a cooling hole, or may alternatively be in the form of a coupon  32  as depicted having one or more fugitive material inserts  30  disposed thereon. The coupon  32  and inserts  30  ( FIG. 3 ) are shown as layer  232  in the prepreg layers  120  of lay up  200  ( FIG. 4 ). It should be understood that while one row of inserts  230  is shown in  FIG. 4 , this is merely one area of cross section and additional coupons  32  may be utilized. It should also be understood that the inserts  30  of  FIG. 3  become the cavities or features  230  in  FIG. 4 . It is desirable that various CMC components have inner cavities  230  ( FIG. 4 ) for various functions including, but not limited to, cooling slots, holes or weight saving features. According to some embodiments for example, a coupon  32  ( FIG. 3 ) may be formed of SiC fibers in a silica carbide matrix and the insert or fugitive material  30  may formed of the same material or different material. The inserts  30  are capable of formation in various manners, such as tape cast, preformed silicon oxide tubes, spray, screen print, rapid prototype polymer coating with boron nitride or injection molding. For example, the fugitive material insert  30  may be formed of a tape of fugitive material particulate bound by polymer in a flexible tape. The particulate may be a refractory material which is bound by polymer binders that define the flexible tape. The flexible tape may be formed by a tape casting process where a ceramic slurry is pulled under a doctor blade according to procedures known to one skilled in the art. The ceramic slurry is comprised of fugitive particulate material, polymer binders, solvents, dispersants, plasticizers and any other processing aid well known in the art for tape casting. It may be desirable that the fugitive material  30  be a low melting metal or alloy which may melt during a burnout pyrolysis operation  138  ( FIG. 2 ) or melt infiltration step  140  of the CMC lay-up preform  200 , to leave a hollow cavity or feature  230  in the preform  200 . According to alternative embodiments, the fugitive material  30  may be formed of a high temperature material, which will not melt during the burnout pyrolysis operation. For example, such fugitive materials  30  include, but are not limited to, boron nitride (BN), silicon oxide (including crystalline and amorphous forms; silicon dioxide and silicon monoxide), silicon oxide coated with boron nitride, rare earth elements (where the rare earth is selected from scandium, yttrium, lanthanum, cerium, praseodymium, neodymium, promethium, samarium, europium, gadolinium, terbium, holmium, erbium, thulium, ytterbium, and lutetium), rare earth elements coated with boron nitride, rare earth oxides, rare earth oxides coated with boron nitride, rare earth silicate (monosilicates and disilicates), rare earth silicate coated with boron nitride, elemental molybdenum, elemental molybdenum coated with boron nitride, molybdenum silicides (all forms such as MoSi2, Mo5Si3, Mo3Si, etc.), molybdenum silicides coated with boron nitride, gallium oxide, gallium nitride, indium oxide, indium nitride, tin oxide, tin nitride, indium tin oxide (ITO), alkaline earth silicates where the alkaline earth is magnesium, calcium, strontium, barium, and combinations thereof, alkaline earth aluminates, diamond powder, diamond powder coated with boron nitride, or boron nitride coated with carbon and mixtures and combinations thereof. All of these high temperature materials may be placed into the CMC during layup as a flexible tape filled with powders of the high temperature materials. Alternately, all of these high temperature materials may also be placed into the CMC during layup as a dense, flexible wire or an inflexible rod or tube. Such high temperature materials, after the CMC component is melt infiltrated, may require a subsequent air heat treatment to oxidize the high temperature material, vacuum heat treatment, inert gas heat treatment, acid treatment, base treatment, combinations thereof, or alternating combinations thereof, in order to remove the fugitive material—which may occur by melting, dissolution, sublimation, evaporation, etc. 
         [0033]    Additionally, the shape of the fugitive material  30  may vary. One benefit of the instant process is that the molding process allows for more complex shapes  230 , as shown in  FIG. 4 . For example, rather than drilling a cavity, such as a cooling feature, which must be linear in nature, the insert  30  ( FIG. 3 ) may be curved and formed of differing cross-sections or shapes. Additionally, or in combination, the various shapes may change direction, as shown with the cooling aperture  230  disposed between the pressure and suction sides  212 ,  210  ( FIG. 5 ) and extending to the trailing edge  214 . In the embodiment, the complex shape represents a cooling aperture  230  which changes in direction and is disposed closely to the pressure (concave) side of the airfoil depicted. Additionally other geometric variations may be formed in the component  200  by varying the one or more of the shape(s) or dimension(s) of the fugitive material insert  30 . Additionally, the placement of the fugitive material insert  30  allows for precise locating of the insert  30 , which results in precise locating of the cavity  230  ( FIG. 5 ) in the component  200  and further which may be closer or further from desired surfaces for temperature control. 
         [0034]    Next, referring again to  FIG. 2 , the lay-up form of the component  200  goes through a compaction or debulking process at step  134 , for example, an autoclave compaction process. In the compaction or debulking step  134 , the preformed lay-up  200  of preselected shape is exposed to elevated temperature and pressure for purpose of beginning curing. 
         [0035]    The melt-filtration process entails heating the laminate preform in a vacuum or an inert atmosphere to decompose the binders and produce a porous preform  200  then infiltrating the component with molten silicon. First, the component  200  first goes through a burnout step  138  wherein the lay-up  200  is placed in a furnace to convert the matrix to carbon. This process is generally referred to as pyrolysis and may also be performed at both elevated temperature and pressure. 
         [0036]    Following this burnout at step  138 , the carbon component  200  goes through a melt infiltration step  140 . The preform  200  is melt infiltrated with molten silicon supplied to the preform  200 . In the melt infiltration step  140 , molten silicon may be utilized as an infiltrant for CMC articles formed of silicon compounds, for example, SiC. The molten silicon, for example, infiltrates into the porous burned-out preform  200  ( FIG. 4 ) and in an embodiment, reacts with constituents within the matrix of the burned out lay-up component  200  to form a silicon-based ceramic (for example silicon carbide) that fills the porosity to yield the desired CMC component  200 . 
         [0037]    Again after the CMC component is melt infiltrated, the component  200  may require a subsequent air heat treatment to oxidize the high temperature material, vacuum heat treatment, inert gas heat treatment, acid treatment, base treatment, combinations thereof, or alternating combinations thereof, in order to remove the fugitive material—which may occur by melting, dissolution, sublimation, evaporation, etc. 
         [0038]    In such cases, an internal cavity may be formed within a CMC preform  200  and ingress of the molten silicon infiltrant into the internal cavity during melt infiltration may be prevented or at least inhibited by use of specific inserts  30  ( FIG. 3 ) formed of fugitive materials. The inserts  30  may include, for example, a coupon  32  of a preselected size having the desired cooling feature shapes formed of various of the fugitive materials  30 . As previously indicated, the fugitive material  30  may burn off or be reduced during the pyrolysis or melt infiltration. Alternatively, other materials may not burn off during either or both of the burnout or the melt infiltration steps  138 ,  140 . 
         [0039]    Various materials are suitable for use as the insert  30 . Materials which may be removed from the preform component  200  include non-wetting of the CMC preform, low or no reactivity with the constituents of the CMC preform  200 , and/or completely fusible and drainable at a temperature of a thermal treatment performed on the CMC preform. In some embodiments, the fugitive material inserts  30  include, but are not limited to, boron nitride (BN), silicon oxide, silicon oxide coated with boron nitride (BN), silica tape, diamond powder, or boron nitride coated with carbon. Such materials may be cast into the desired shape of the inner cavity  230  ( FIG. 5 ) and incorporated into the CMC preform. According to some embodiments, the inserts  30  were formed of fused silicon oxide (SiO 2 ). The tubes have, for non-limiting example, an inner diameter of 20 mil. and an outer diameter of 40 mil. Following the melt infiltration process, the fused silicon oxide was reduced to SiO. The insert  30  ( FIG. 3 ) does not wet or react with the constituents of the preform  200  ( FIG. 4 ). Additionally, the insert  30  may melt and be allowed to drain from the preform  200  during the burnout at step  138  leaving the CMC preform  200  with the hollow cavities. 
         [0040]    Additionally, or alternatively, after the burnout  138  and melt infiltration process  140 , the preform  200  may be manipulated mechanically or chemically to remove the fugitive material  30  inserted into the preformed shape at step  142  ( FIG. 2 ). In some cases, the heat treatment may be used to oxidize the insert  30  to an oxide that may be melted or dissolved in an acid or base. In other embodiments, the insert  30  may be directly dissolved in acid or base. In further embodiments, the insert  30  may be sublimed or evaporated in a vacuum heat treatment. In still other embodiments, the insert may be oxidized and subsequently sublimed or evaporated in a vacuum heat treatment. Mechanical methods may be used to mechanically remove the insert and may or may not be used with any of the previously described methods. Various methods may be utilized including chemical dissolution of the fugitive material insert  30 . Additionally, it is noted that certain material such as silicon oxide may not require a removal, as such may be reduced during the burnout process  138  or melt infiltration process  140 . After the mechanical or chemical of the fugitive material at step  142 , the preformed of preselected shape is machined at step  144 . This may include clearing the formed features  230  ( FIG. 5 ) with wire to, for example, ensure proper flow through the slots. Subsequently, the part may be dimensionally inspected  146  by non-destructive examination at step  148  and further have environmental coating applied at step  150 . A further step of non-destructive examination may be performed at step  152  after the environmental barrier coating is applied. 
         [0041]    Referring now to  FIG. 5 , a partial side section view of a CMC component  200 , such as an airfoil, is depicted. The exemplary airfoil  200  is formed of a composite including matrix and reinforcement. The CMC component  200  comprises a pressure side  212  and a suction side  210 . These sides  210 ,  212  extend between a leading edge (not shown) and a trailing edge  214  in the chordwise direction, a direction defined along a straight axial line between the leading edge and trailing edge  214 . The curvature of the pressure and suction sides  212 ,  210  may be dependent on the desired turning of the air flow from the fan  18 . The suction side  210  of the component  200  may be convex while the pressure side  212  may be concave. 
         [0042]    The exemplary molded in feature  230  includes various turns. Such non-line-of-sight features are not possible with drilled features. Also, by controlling the shape and placement of the insert  30 , the subsequent cavity  230  may be placed closer or further from a surface of the airfoil  200 . Such molded in features allows optimization of cooling for example. The optimization may come through the shape and locating of the molded in feature  230 , by way of the fugitive material insert  30 . 
         [0043]    The foregoing description of structures and methods has been presented for purposes of illustration. It is not intended to be exhaustive or to limit the invention to the precise steps and/or forms disclosed, and obviously many modifications and variations are possible in light of the above teaching. Features described herein may be combined in any combination. Steps of a method described herein may be performed in any sequence that is physically possible. It is understood that while certain embodiments of methods and materials have been illustrated and described, it is not limited thereto and instead will only be limited by the claims, appended hereto.