Abstract:
The present invention relates to a non-magnetic monocomponent color toner and a preparing method thereof. In the non-magnetic monocomponent color toner including a toner mother particle, silica and titanium dioxide, the toner mother particle comprises a specific shaped particle size distribution of the charge control agents, and thus, providing non-magnetic monocomponent color toner with a narrow charge distribution and good chargeability. Accordingly, the color toner does not cause contamination in the non-imaging region. Also, because it has superior image density and printing efficiency and significantly improved charge maintenance, it has good long-term stability.

Description:
CROSS REFERENCE TO RELATED APPLICATION  
       [0001]     This application claims priority to Korean patent applications Nos. 10-2004-0002281 filed in the Korean Intellectual Property Office on Jan. 13, 2004 and 10-2004-0106176 filed in the Korean Intellectual Property Office on Dec. 15, 2004, the entire disclosure of which is incorporated herein by reference.  
       BACKGROUND OF THE INVENTION  
       [0002]     (a) Field of the Invention  
         [0003]     The present invention relates to a non-magnetic monocomponent color toner offering superior image density and printing efficiency because of a narrow charge distribution and good chargeability, and having superior long-term stability because of significantly improved charge maintenance, and a preparation method thereof.  
         [0004]     (b) Description of the Related Art  
         [0005]     Recently, demand for color toner is increasing in the field of electrophotography. Color toner is prepared by kneading and crushing, suspension polymerization, emulsion polymerization, etc. Among them, the kneading and crushing method is mainly used in terms of stability, productivity, and so forth.  
         [0006]     In the kneading and crushing method, a binder resin, a colorant, a charge controller, a releasing agent, etc., are melted and kneaded to obtain a mixture. The mixture is cooled and crushed to a desired particle size and classified to obtain a toner. The toner is developed by frictional charging to a positive or negative charge depending on the polarity of the developed electrostatic latent image. Recently, printers adopting electrophotography, in which a laser beam is used as light source, have been leading the market. The demand for compactness, lightness, reliability, and full color is increasing rapidly. Thus, electrophotographic devices having a simple structure and offering high good quality and durability are required. Also, a toner having good printing efficiency and stable developing properties in the long term is required.  
         [0007]     In order to satisfy the recent need for higher resolution and better image quality, the particle size of toner is becoming smaller. As the particle size of the toner decreases, the surface area per unit weight of the toner particle increases. As a result, the surface characteristics affect charging and particle characteristics of the toner. As the particle size becomes smaller, the charging characteristic is more affected by the charge control agent. In general, a metal complex, a chromium-containing metal dye, or a quaternary ammonium salt is used for negative charging, and nigrosine or a quaternary ammonium salt is used for positive charging, as the charge control agent. The charge control agent is melted and kneaded along with a binder resin, a wax, a colorant, etc., and crushing and classifying are performed to obtain a toner.  
         [0008]     The raw material of the charge control agent may have quite a broad particle size distribution. Although the charge control agent particles may be broken down during melting or kneading, the original particle size determines the characteristics of the charge control agent. If the charge control agent has too large a particle size, the binding ability with the binder resin decreases, so it tends to be separated from the toner during crushing. As a result, many toner particles do not contain the charge control agent and the charge distribution becomes broader, so background contamination or fogging tends to occur. Otherwise, if the charge control agent has too small a particle size, most of the charge control agent particles exist inside the toner, so they do not contribute to improvement in charging characteristics.  
         [0009]     Accordingly, it is required to improve binding ability with the binder resin, charge distribution, and charge maintenance by specifying the particle size and distribution of the charge control agent.  
       SUMMARY OF THE INVENTION  
       [0010]     The present inventors worked for a color toner having a narrow charge distribution and good chargeability, and that is capable of improving charge maintenance. Noticing that the binding ability with the binder resin, charge distribution, charge maintenance, etc., are affected by particle size and distribution of the charge control agent, they completed the present invention by identifying that a toner comprising 10-35 wt % of a charge control agent having a particle size of 50-500 nm and 65-90 wt % of a charge control agent having a particle size of 1-4 μm has superior long-term stability because of uniform charge distribution and good chargeability.  
         [0011]     Thus, it is an aspect of the present invention to provide a non-magnetic monocomponent color toner comprising both a toner mother particle comprising a charge control agent having a large particle size and a charge control agent having a small particle size; silica; and titanium dioxide, and a preparing method thereof. 
     
    
     DETAILED DESCRIPTION OF THE INVENTION  
       [0012]     In the following detailed description, the embodiments of the invention have been shown and described, simply by way of illustrating the best mode contemplated by the inventors of carrying out the invention. As will be realized, the present invention can be modified in various respects, all without departing from the invention. Accordingly, the description is to be regarded as illustrative in nature, and not restrictive.  
         [0013]     The present invention provides a non-magnetic monocomponent color toner comprising a toner mother particle comprising 10-35 wt % of a charge control agent having a particle size of 50-500 nm, and 65-90 wt % of a charge control agent having a particle size of 1-4 μm; silica; and titanium dioxide.  
         [0014]     The present invention also provides a method of preparing a non-magnetic monocomponent color toner comprising the steps of preparing a toner mother particle comprising 10-35 wt % of a charge control agent having a particle size of 50-500 nm and 65-90 wt % of a charge control agent having a particle size of 1-4 μm (step 1); and coating the toner mother particle with silica and titanium dioxide (step 2).  
         [0015]     The charge control agent used in the present invention comprises a) 10-35 wt % of a charge control agent having a particle size of 50-500 nm and b) 65-90 wt % of a charge control agent having a particle size of 14 μm. More preferably, it comprises 15-25 wt % of a charge control agent having a particle size of 150-450 nm and b) 75-85 wt % of a charge control agent having a particle size of 14 μm. The charge control agent is preferably comprised at 0.5-5 wt %, more preferably at 1-3 wt %. The silica has an average particle size of 5-50 nm, preferably 10-40 nm. It is preferably comprised at 1.0-3.0 wt %, more preferably at 1.5-2.8 wt %. The titanium dioxide has an average particle size of 0.05-2 μm, preferably 0.1-1.5 μm. It is preferably comprised at 0.2-2.5 wt %, more preferably at 0.5-2 wt %.  
         [0016]     Unless specified otherwise, average particle size mentioned in the description of the present invention is number-average particle size.  
         [0017]     If the content of the charge control agent having a smaller average particle size is below 10 wt %, a sufficiently uniform charge distribution is not obtained. Otherwise, if it exceeds 35 wt %, the particles having a smaller particle size, which have a much larger specific surface area, penetrate the toner particles, thereby failing to fully function as a charge control agent on the surface of the toner particle. In this case, long-term printing efficiency may deteriorate.  
         [0018]     If the content of the charge control agent having a larger average particle size is below 65 wt %, the charge control agents having a larger average particle size tend to concentrate on the surface of the toner particle, thereby failing to offer good chargeability. Otherwise, if it exceeds 90 wt %, it is difficult to obtain uniform charge distribution, and if a lot of the charge control agent particles come into the surface, many of them are separated because they have weaker binding ability with the binder resin than the particles having a smaller particle size. As a result, it is difficult to obtain uniform charge distribution, and background contamination or fogging may occur.  
         [0019]     For the charge control agent having a specifically shaped particle size distribution, a metal complex, a nigrosine dye, a triphenylmethane dye, a quaternary ammonium salt, or an organotartar compound such as dibutyl tin oxide, etc. may be used. The metal of the metal complex may be Al, Zr, Zn, Ba, etc. Although such intrinsic property of the charge control agent as positive chargeability or negative chargeability does not change, a narrower charge distribution and a better chargeability can be obtained with a specific particle size distribution.  
         [0020]     The toner mother particle also comprises a binder resin, a colorant, and a wax as essential components.  
         [0021]     The binder resin may be a styrene such as styrene, chlorostyrene and vinylstyrene; an olefin such as ethylene, propylene, butylene and isoprene; a vinyl ester such as vinyl acetate, vinyl propionate, vinyl benzoate and vinyl lactate; an acrylate or a methacrylate such as methyl acrylate, ethyl acrylate, butyl acrylate, dodecyl acrylate, octyl acrylate, phenyl acrylate, methyl methacrylate, ethyl methacrylate, butyl methacrylate, and dodecyl methacrylate; a vinyl ether such as vinyl methyl ether, vinyl ethyl ether, and vinyl butyl ether; a vinyl ketone such as vinyl methyl ketone, vinyl hexyl ketone, and vinyl isopropenyl ketone; and a mixture thereof.  
         [0022]     Preferably, polystyrene, a styrene-alkyl acrylate copolymer, a styrene-alkyl methacrylate copolymer, a styrene-acrylonitrile copolymer, a styrene-butadiene copolymer, a styrene-maleic anhydride copolymer, polyethylene, polypropylene, etc. is used. More preferably, polyester, polyurethane, an epoxy resin, a silicone resin, polyamide, a modified resin, paraffin, etc. is used.  
         [0023]     For the colorant, carbon black, a magnetic paint, a dye, or a pigment may be used. For example, a nigrosine dye, aniline blue, charcoal blue, chromium yellow, navy blue, DuPont oil red, methylene blue chloride, phthalocyanine blue, lamp black, rose bengal, C.I. pigment red 48:1, C.I. pigment red 48:4, C.I. pigment red 122, C.I. pigment red 57:1, C.I. pigment red 257, C.I. pigment red 269, C.I. pigment yellow 97, C.I. pigment yellow 12, C.I. pigment yellow 17, C.I. pigment yellow 14, C.I. pigment yellow 13, C.I. pigment yellow 16, C.I. pigment yellow 81, C.I. pigment yellow 126, C.I. pigment yellow 127, C.I. pigment blue 9, C.I. pigment blue 15, C.I. pigment blue 15:1, C.I. pigment blue 15:3, etc. may be used.  
         [0024]     An inorganic oxide fine particle such as SiO 2 , TiO 2 , MgO, A 1   2 O 3 , MnO, ZnO, Fe 2 O 3 , CaO, BaSO 4 , CeO 2 , K 2 O, Na 2 O, ZrO 2 , CaO·SiO, K 2 O·(TiO 2 )n and Al 2 O 3 ·2SiO 2  hydrophobic-treated with hexamethyldisilazane, dimethyldichlorosilane, octyltrimethoxysilane, etc. may be added to the toner mother particle as a fluidity accelerator. The toner mother particle may further comprise a releasing agent.  
         [0025]     The toner mother particle preferably has an average particle size of 10 μm, more preferably 4-10 μm, and most preferably 5-9 μm.  
         [0026]     After a toner mother particle is prepared by mixing and kneading the charge control agent, which has a specific shaped particle size distribution, along with a binder resin, a colorant and a wax (releasing agent), silica and titanium oxide particles are added to prepare the non-magnetic monocomponent color toner of the present invention.  
         [0027]     The silica preferably has an average particle size of 5-50 nm, preferably 10-40 nm. It is preferably comprised at 1.0-3.0 wt %, more preferably at 1.5-2.8 wt %. The titanium dioxide preferably has an average particle size of 0.05-2 μm, more preferably 0.1-1.5 μm. It is preferably comprised at 0.2-2.5 wt %, more preferably at 0.5-2wt %.  
         [0028]     Although the silica and the titanium dioxide may be attached to the surface of the toner mother particle electrostatically, a mechanical mixing treatment using a Henschel mixer, a hybridizer, etc. is preferable. Preferably, the toner mother particle, silica, and titanium dioxide are coated after being mixed at a stirring rate of at least 10 m/s.  
         [0029]     The resultant non-magnetic monocomponent color toner preferably has an average particle size of at most 20 μm, more preferably 3-15 μm.  
         [0030]     The non-magnetic monocomponent color toner of the present invention offers better long-term image stability than the conventional counterpart. It is also advantageous in offering higher resolution, better printing efficiency, and clearer color. The better effect is attained as the toner particle has the smaller size.  
         [0031]     Accordingly, a non-magnetic monocomponent color toner having good chargeability, charge maintenance, and clear color can be prepared according to the present invention. The toner is more environmentally friendly and can offer a more stable image while satisfying the need of higher resolution.  
         [0032]     Hereinafter, the present invention is described in more detail through examples. However, the following examples are only for the understanding of the present invention and they do not limit the present invention.  
       EXAMPLE 1  
       [0033]     1) Preparation of Toner Mother Particle  
         [0034]     94 parts by weight of polyester resin (molecular weight=2.5×10 5 ), 4 parts by weight of phthalocyanine P.BI.15:3, 1 part by weight of a metal-containing azo salt (charge control agent C) comprising 30 wt % of a particle having a particle size of 50-500 nm and 70 wt % of a particle having a particle size of 1-4 μm, and 4 parts by weight of polypropylene having a small molecular weight were mixed using a Henschel mixer. The mixture was melted and kneaded at 165 ° C. using a twin melt kneader, crushed using a jet mil crusher, and classified using an air classifier to obtain a toner mother particle having a volume-average particle size of 7.5 μm.  
         [0035]     2) Preparation of Non-Magnetic Monocomponent Color Toner  
         [0036]     2.0 wt % of silica having an average particle size of 17 nm and 1.0 wt % of titanium dioxide particle having an average particle size of 0.1 μm were mixed with 100 parts by weight of the prepared toner mother particle while stirring for 3 minutes at a tip speed of at least 10 m/s using a Henschel mixer to obtain a non-magnetic monocomponent color toner.  
       EXAMPLES 2-182  
       [0037]     Non-magnetic monocomponent color-toners were prepared in the same manner of Example 1, except that charge control agents presented in Table 1 below, silica presented in Table 2 below, and titanium dioxide presented in Table 3 below were used according to the composition given in Table 4 below.  
                                             TABLE 1                                       Average particle size           Compounds   distribution                                    Charge control   Metal-containing azo salt   50-500   nm       agent A       Charge control   Metal-containing azo salt   1-4   μm       agent B       Charge control   Metal-containing azo salt   50-500   nm, 30 wt %;       agent C       1-4   μm, 70 wt %       Charge control   Quaternary ammonium salt   50-500   nm       agent D       Charge control   Quaternary ammonium salt   1-4   μm       agent E       Charge control   Quaternary ammonium salt   50-500   nm, 30 wt %;       agent F       1-4   μm, 70 wt %       Charge control   Zinc salicylate   50-500   nm       agent G       Charge control   Zinc salicylate   1-4   μm       agent H       Charge control   Zinc salicylate   50-500   nm, 30 wt %;       agent I       1-4   μm, 70 wt %       Charge control   Boron complex   50-500   nm       agent J       Charge control   Boron complex   1-4   μm       agent K       Charge control   Boron complex   50-500   nm, 30 wt %;       agent L       1-4   μm, 70 wt %       Charge control   Metal-containing azo salt   50-500   nm, 15 wt %;       agent M       1-4   μm, 85 wt %       Charge control   Quaternary ammonium salt   50-500   nm, 20 wt %;       agent N       1-4   μm, 80 wt %       Charge control   Boron complex   50-500   nm, 10 wt %;       agent O       1-4   μm, 90 wt %       Charge control   Zinc salicylate   30-300   nm, 85 wt %;       agent P       1-4   μm, 15 wt %       Charge control   Metal-containing azo salt   30-300   nm, 90 wt %;       agent Q       1-4   μm, 10 wt %       Charge control   Quaternary ammonium salt   30-300   nm, 85 wt %;       agent R       1-4   μm, 15 wt %       Charge control   Boron complex   30-300   nm, 85 wt %;       agent S       1-4   μm, 15 wt %                  
 
         [0038]    
       
         
               
               
               
             
               
               
               
             
           
               
                   
                 TABLE 2 
               
               
                   
                   
               
               
                   
                   
               
               
                   
                   
                 Hydrophobic surface 
               
               
                   
                 Specific surface area (m 2 /g)* 1   
                 treatment 
               
               
                   
                   
               
             
             
               
                   
               
             
          
           
               
                 Silica A 
                 7 
                 Dimethyl silicone oil 
               
               
                 Silica B 
                 17 
                 Dimethyl silicone oil 
               
               
                 Silica C 
                 50 
                 HMDS* 2   
               
               
                   
               
               
                   * 1 BET measurement values    
               
               
                   * 2 HMDS = hexamethyldisilazane    
               
             
          
         
       
     
         [0039]    
       
         
               
               
             
               
               
               
             
           
               
                   
                 TABLE 3 
               
               
                   
                   
               
               
                   
                   
               
               
                   
                 Average particle size (μm) 
               
               
                   
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Titanium dioxide A 
                 0.1 
               
               
                   
                 Titanium dioxide B 
                 1.1 
               
               
                   
                 Titanium dioxide C 
                 1.6 
               
               
                   
                   
               
             
          
         
       
     
         [0040]    
       
         
               
               
               
               
             
               
               
               
               
               
               
               
             
           
               
                 TABLE 4 
               
               
                   
               
               
                   
               
               
                 Example 
                 Charge control agent(wt %) 
                 Silica (wt %) 
                 Titanium oxide(wt %) 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 2 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 3 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 4 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 5 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 6 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 7 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 2.5 
               
               
                 8 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 9 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 2.0 
                 Titanium oxide C 
                 1.0 
               
               
                 10 
                 Charge control agent C 
                 1.0 
                 Silica A 
                 3.0 
                 Titanium oxide C 
                 2.0 
               
               
                 11 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 12 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 13 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 2.5 
               
               
                 14 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 15 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 16 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 17 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 18 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 1.0 
               
               
                 19 
                 Charge control agent C 
                 1.0 
                 Silica B 
                 3.0 
                 Titanium oxide C 
                 2.0 
               
               
                 20 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 21 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 22 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 23 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 24 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 25 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 26 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 27 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 1.0 
               
               
                 28 
                 Charge control agent C 
                 3.0 
                 Silica C 
                 3.0 
                 Titanium oxide C 
                 2.0 
               
               
                 29 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 30 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 31 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 32 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 33 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 34 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 35 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 36 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 1.0 
               
               
                 37 
                 Charge control agent F 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 2.0 
               
               
                 38 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 39 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 40 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 41 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 42 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 43 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 44 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 45 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 1.0 
               
               
                 46 
                 Charge control agent F 
                 3.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 2.0 
               
               
                 47 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide A 
                 0.5 
               
               
                 48 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide A 
                 1.0 
               
               
                 49 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide A 
                 2.0 
               
               
                 50 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide B 
                 0.5 
               
               
                 51 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide B 
                 1.0 
               
               
                 52 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide B 
                 2.0 
               
               
                 53 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 54 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 3.0 
                 Titanium oxide C 
                 1.0 
               
               
                 55 
                 Charge control agent F 
                 3.0 
                 Silica C 
                 3.0 
                 Titanium oxide C 
                 2.0 
               
               
                 56 
                 Charge control agent I 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 2.0 
               
               
                 57 
                 Charge control agent I 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 58 
                 Charge control agent I 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 1.0 
               
               
                 59 
                 Charge control agent I 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 2.0 
               
               
                 60 
                 Charge control agent I 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 61 
                 Charge control agent I 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 62 
                 Charge control agent I 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 2.5 
               
               
                 63 
                 Charge control agent I 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 64 
                 Charge control agent I 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 65 
                 Charge control agent I 
                 3.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 66 
                 Charge control agent I 
                 3.0 
                 Silica B 
                 2.0 
                 Titanium oxide A 
                 1.5 
               
               
                 67 
                 Charge control agent I 
                 3.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 68 
                 Charge control agent I 
                 3.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 2.0 
               
               
                 69 
                 Charge control agent I 
                 3.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 70 
                 Charge control agent I 
                 3.0 
                 Silica B 
                 2.0 
                 Titanium oxide B 
                 1.5 
               
               
                 71 
                 Charge control agent I 
                 3.0 
                 Silica B 
                 3.0 
                 Titanium oxide C 
                 1.0 
               
               
                 72 
                 Charge control agent I 
                 3.0 
                 Silica B 
                 2.0 
                 Titanium oxide A 
                 2.0 
               
               
                 73 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 74 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 1.5 
               
               
                 75 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 76 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 1.5 
               
               
                 77 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 78 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 2.5 
               
               
                 79 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 3.0 
                 Titanium oxide A 
                 0.5 
               
               
                 80 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 3.0 
                 Titanium oxide B 
                 0.5 
               
               
                 81 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 3.0 
                 Titanium oxide C 
                 0.5 
               
               
                 82 
                 Charge control agent L 
                 1.0 
                 Silica A 
                 3.0 
                 Titanium oxide A 
                 1.5 
               
               
                 83 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide A 
                 0.5 
               
               
                 84 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide A 
                 1.0 
               
               
                 85 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide A 
                 2.5 
               
               
                 86 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide B 
                 0.5 
               
               
                 87 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide B 
                 1.0 
               
               
                 88 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide B 
                 2.5 
               
               
                 89 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 90 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 1.0 
               
               
                 91 
                 Charge control agent L 
                 1.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 2.0 
               
               
                 92 
                 Charge control agent L 
                 2.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 2.0 
               
               
                 93 
                 Charge control agent L 
                 1.0 
                 Silica C 
                 2.0 
                 Titanium oxide A 
                 0.5 
               
               
                 94 
                 Charge control agent L 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide A 
                 1.5 
               
               
                 95 
                 Charge control agent L 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide A 
                 2.5 
               
               
                 96 
                 Charge control agent L 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide B 
                 0.5 
               
               
                 97 
                 Charge control agent L 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide B 
                 1.0 
               
               
                 98 
                 Charge control agent L 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide B 
                 2.0 
               
               
                 99 
                 Charge control agent L 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 100 
                 Charge control agent L 
                 2.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 1.0 
               
               
                 101 
                 Charge control agent L 
                 2.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 2.0 
               
               
                 102 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 0.5 
                 Titanium oxide A 
                 0.5 
               
               
                 103 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 104 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 105 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 106 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 107 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 108 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 109 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 2.0 
                 Titanium oxide C 
                 1.0 
               
               
                 110 
                 Charge control agent M 
                 1.0 
                 Silica A 
                 3.0 
                 Titanium oxide C 
                 2.5 
               
               
                 111 
                 Charge control agent M 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 112 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 113 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 114 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 115 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 116 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 117 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 118 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 2.0 
                 Titanium oxide C 
                 1.0 
               
               
                 119 
                 Charge control agent M 
                 2.0 
                 Silica B 
                 3.0 
                 Titanium oxide C 
                 2.0 
               
               
                 120 
                 Charge control agent M 
                 2.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 121 
                 Charge control agent M 
                 2.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 122 
                 Charge control agent M 
                 2.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 123 
                 Charge control agent M 
                 2.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 124 
                 Charge control agent M 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 125 
                 Charge control agent M 
                 3.0 
                 Silica C 
                 3.0 
                 Titanium oxide B 
                 2.0 
               
               
                 126 
                 Charge control agent M 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 127 
                 Charge control agent M 
                 3.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 1.0 
               
               
                 128 
                 Charge control agent M 
                 3.0 
                 Silica C 
                 3.0 
                 Titanium oxide C 
                 2.5 
               
               
                 129 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 130 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 131 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 132 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 133 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 134 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 135 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 2.0 
                 Titanium oxide C 
                 0.5 
               
               
                 136 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 3.0 
                 Titanium oxide C 
                 1.0 
               
               
                 137 
                 Charge control agent N 
                 1.0 
                 Silica A 
                 2.0 
                 Titanium oxide C 
                 2.0 
               
               
                 138 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 139 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 140 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 2.5 
               
               
                 141 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 142 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 143 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 144 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 145 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 3.0 
                 Titanium oxide C 
                 1.0 
               
               
                 146 
                 Charge control agent N 
                 2.0 
                 Silica B 
                 3.0 
                 Titanium oxide C 
                 2.0 
               
               
                 147 
                 Charge control agent N 
                 2.0 
                 Silica C 
                 2.0 
                 Titanium oxide A 
                 0.5 
               
               
                 148 
                 Charge control agent N 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 149 
                 Charge control agent N 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 150 
                 Charge control agent N 
                 4.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 151 
                 Charge control agent N 
                 4.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 152 
                 Charge control agent N 
                 4.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 153 
                 Charge control agent N 
                 5.0 
                 Silica C 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 154 
                 Charge control agent N 
                 5.0 
                 Silica C 
                 3.0 
                 Titanium oxide C 
                 1.0 
               
               
                 155 
                 Charge control agent N 
                 5.0 
                 Silica C 
                 2.0 
                 Titanium oxide C 
                 2.0 
               
               
                 156 
                 Charge control agent O 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 157 
                 Charge control agent O 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 158 
                 Charge control agent O 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 159 
                 Charge control agent O 
                 1.0 
                 Silica A 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 160 
                 Charge control agent O 
                 1.0 
                 Silica A 
                 2.0 
                 Titanium oxide B 
                 1.0 
               
               
                 161 
                 Charge control agent O 
                 1.0 
                 Silica A 
                 2.0 
                 Titanium oxide B 
                 2.0 
               
               
                 162 
                 Charge control agent O 
                 2.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 163 
                 Charge control agent O 
                 2.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 1.0 
               
               
                 164 
                 Charge control agent O 
                 2.0 
                 Silica A 
                 1.0 
                 Titanium oxide C 
                 2.0 
               
               
                 165 
                 Charge control agent O 
                 1.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 166 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 167 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 168 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 169 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 170 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 171 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 172 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 1.0 
               
               
                 173 
                 Charge control agent O 
                 2.0 
                 Silica B 
                 1.0 
                 Titanium oxide C 
                 2.5 
               
               
                 174 
                 Charge control agent O 
                 2.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 0.5 
               
               
                 175 
                 Charge control agent O 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 1.0 
               
               
                 176 
                 Charge control agent O 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide A 
                 2.0 
               
               
                 177 
                 Charge control agent O 
                 3.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 0.5 
               
               
                 178 
                 Charge control agent O 
                 4.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 1.0 
               
               
                 179 
                 Charge control agent O 
                 4.0 
                 Silica C 
                 1.0 
                 Titanium oxide B 
                 2.0 
               
               
                 180 
                 Charge control agent O 
                 4.0 
                 Silica C 
                 1.0 
                 Titanium oxide C 
                 0.5 
               
               
                 181 
                 Charge control agent O 
                 5.0 
                 Silica C 
                 1.0 
                 Titanium oxide C 
                 1.0 
               
               
                 182 
                 Charge control agent O 
                 5.0 
                 Silica C 
                 1.0 
                 Titanium oxide C 
                 2.0 
               
               
                   
               
             
          
         
       
     
       COMPARATIVE EXAMPLES 1-270  
       [0041]     Non-magnetic monocomponent color toners were prepared in the same manner of Example 1, except that charge control agents presented in Table 1 above, silica presented in Table 2 above, and titanium dioxide presented in Table 3 above were used according to the composition given in Table 5 below. That is to say, charge control agents not having a specific shaped particle size were used in the Comparative Examples.  
                                                         TABLE 5                       Comparative                   Example   Charge control agent(wt %)   Silica(wt %)   Titanium oxide (wt %)                                1   Charge control agent A   1.0   Silica A   1.0   Titanium oxide A   0.5       2   Charge control agent A   2.0   Silica A   1.0   Titanium oxide A   0.5       3   Charge control agent A   1.0   Silica A   1.0   Titanium oxide A   1.0       4   Charge control agent A   1.0   Silica A   1.0   Titanium oxide A   2.0       5   Charge control agent A   1.0   Silica A   1.0   Titanium oxide B   0.5       6   Charge control agent A   1.0   Silica A   1.0   Titanium oxide B   1.0       7   Charge control agent A   1.0   Silica A   1.0   Titanium oxide B   2.0       8   Charge control agent A   1.0   Silica A   1.0   Titanium oxide C   0.5       9   Charge control agent A   1.0   Silica A   1.0   Titanium oxide C   1.0       10   Charge control agent A   1.0   Silica A   1.0   Titanium oxide C   2.0       11   Charge control agent A   1.0   Silica B   1.0   Titanium oxide A   0.5       12   Charge control agent A   1.0   Silica B   1.0   Titanium oxide A   1.0       13   Charge control agent A   1.0   Silica B   1.0   Titanium oxide A   2.0       14   Charge control agent A   1.0   Silica B   1.0   Titanium oxide B   0.5       15   Charge control agent A   1.0   Silica B   1.0   Titanium oxide B   1.0       16   Charge control agent A   1.0   Silica B   1.0   Titanium oxide B   2.0       17   Charge control agent A   1.0   Silica B   1.0   Titanium oxide C   0.5       18   Charge control agent A   1.0   Silica B   1.0   Titanium oxide C   1.0       19   Charge control agent A   1.0   Silica B   1.0   Titanium oxide C   2.0       20   Charge control agent A   3.0   Silica C   1.0   Titanium oxide A   0.5       21   Charge control agent A   3.0   Silica C   1.0   Titanium oxide A   1.0       22   Charge control agent A   3.0   Silica C   1.0   Titanium oxide A   2.0       23   Charge control agent A   3.0   Silica C   1.0   Titanium oxide B   0.5       24   Charge control agent A   3.0   Silica C   1.0   Titanium oxide B   1.0       25   Charge control agent A   3.0   Silica C   1.0   Titanium oxide B   2.0       26   Charge control agent A   3.0   Silica C   1.0   Titanium oxide C   0.5       27   Charge control agent A   3.0   Silica C   1.0   Titanium oxide C   1.0       28   Charge control agent A   3.0   Silica C   1.0   Titanium oxide C   2.0       29   Charge control agent B   3.0   Silica A   1.0   Titanium oxide A   0.5       30   Charge control agent B   3.0   Silica A   1.0   Titanium oxide A   1.0       31   Charge control agent B   3.0   Silica A   1.0   Titanium oxide A   2.0       32   Charge control agent B   3.0   Silica A   1.0   Titanium oxide B   0.5       33   Charge control agent B   3.0   Silica A   1.0   Titanium oxide B   1.0       34   Charge control agent B   3.0   Silica A   1.0   Titanium oxide B   2.0       35   Charge control agent B   3.0   Silica A   1.0   Titanium oxide C   0.5       36   Charge control agent B   3.0   Silica A   1.0   Titanium oxide C   1.0       37   Charge control agent B   3.0   Silica A   1.0   Titanium oxide C   2.0       38   Charge control agent B   3.0   Silica B   1.0   Titanium oxide A   0.5       39   Charge control agent B   3.0   Silica B   1.0   Titanium oxide A   1.0       40   Charge control agent B   3.0   Silica B   1.0   Titanium oxide A   2.0       41   Charge control agent B   3.0   Silica B   1.0   Titanium oxide B   0.5       42   Charge control agent B   3.0   Silica B   1.0   Titanium oxide B   1.0       43   Charge control agent B   3.0   Silica B   1.0   Titanium oxide B   2.0       44   Charge control agent B   3.0   Silica B   1.0   Titanium oxide C   0.5       45   Charge control agent B   3.0   Silica B   1.0   Titanium oxide C   1.0       46   Charge control agent B   3.0   Silica B   1.0   Titanium oxide C   2.0       47   Charge control agent B   3.0   Silica C   2.0   Titanium oxide A   0.5       48   Charge control agent B   3.0   Silica C   2.0   Titanium oxide A   1.0       49   Charge control agent B   3.0   Silica C   2.0   Titanium oxide A   2.0       50   Charge control agent B   3.0   Silica C   2.0   Titanium oxide B   0.5       51   Charge control agent B   3.0   Silica C   2.0   Titanium oxide B   1.0       52   Charge control agent B   3.0   Silica C   2.0   Titanium oxide B   2.0       53   Charge control agent B   3.0   Silica C   2.0   Titanium oxide C   0.5       54   Charge control agent B   3.0   Silica C   2.0   Titanium oxide C   1.0       55   Charge control agent B   3.0   Silica C   2.0   Titanium oxide C   2.0       56   Charge control agent D   1.0   Silica A   1.0   Titanium oxide C   3.0       57   Charge control agent D   1.0   Silica A   1.0   Titanium oxide C   0.5       58   Charge control agent D   1.0   Silica A   1.0   Titanium oxide C   1.0       59   Charge control agent D   1.0   Silica A   1.0   Titanium oxide C   2.0       60   Charge control agent D   1.0   Silica A   1.0   Titanium oxide A   0.5       61   Charge control agent D   1.0   Silica A   1.0   Titanium oxide A   1.0       62   Charge control agent D   1.0   Silica A   1.0   Titanium oxide A   2.0       63   Charge control agent D   3.0   Silica A   1.0   Titanium oxide A   0.5       64   Charge control agent D   3.0   Silica A   1.0   Titanium oxide A   2.0       65   Charge control agent D   3.0   Silica A   1.0   Titanium oxide B   0.5       66   Charge control agent D   3.0   Silica B   2.0   Titanium oxide A   1.5       67   Charge control agent D   3.0   Silica B   2.0   Titanium oxide C   0.5       68   Charge control agent D   3.0   Silica B   2.0   Titanium oxide C   2.0       69   Charge control agent D   3.0   Silica B   2.0   Titanium oxide C   0.5       70   Charge control agent D   3.0   Silica B   2.0   Titanium oxide B   1.5       71   Charge control agent D   3.0   Silica B   2.0   Titanium oxide C   1.0       72   Charge control agent D   3.0   Silica B   2.0   Titanium oxide A   2.0       73   Charge control agent E   1.0   Silica A   1.0   Titanium oxide A   0.5       74   Charge control agent E   1.0   Silica A   1.0   Titanium oxide A   1.5       75   Charge control agent E   1.0   Silica A   1.0   Titanium oxide B   0.5       76   Charge control agent E   1.0   Silica A   1.0   Titanium oxide B   1.5       77   Charge control agent E   1.0   Silica A   1.0   Titanium oxide C   0.5       78   Charge control agent E   1.0   Silica A   1.0   Titanium oxide C   2.0       79   Charge control agent E   1.0   Silica A   3.0   Titanium oxide A   0.5       80   Charge control agent E   1.0   Silica A   3.0   Titanium oxide B   0.5       81   Charge control agent E   1.0   Silica A   3.0   Titanium oxide C   0.5       82   Charge control agent E   1.0   Silica A   3.0   Titanium oxide A   1.5       83   Charge control agent E   1.0   Silica B   2.0   Titanium oxide A   0.5       84   Charge control agent E   1.0   Silica B   2.0   Titanium oxide A   1.0       85   Charge control agent E   1.0   Silica B   2.0   Titanium oxide A   2.0       86   Charge control agent E   1.0   Silica B   2.0   Titanium oxide B   0.5       87   Charge control agent E   1.0   Silica B   2.0   Titanium oxide B   1.0       88   Charge control agent E   1.0   Silica B   2.0   Titanium oxide B   2.0       89   Charge control agent E   1.0   Silica B   2.0   Titanium oxide C   0.5       90   Charge control agent E   1.0   Silica B   2.0   Titanium oxide C   1.0       91   Charge control agent E   1.0   Silica B   2.0   Titanium oxide C   2.0       92   Charge control agent E   2.0   Silica B   2.0   Titanium oxide C   2.0       93   Charge control agent E   1.0   Silica C   2.0   Titanium oxide A   0.5       94   Charge control agent E   3.0   Silica C   2.0   Titanium oxide A   1.5       95   Charge control agent E   3.0   Silica C   2.0   Titanium oxide A   2.0       96   Charge control agent E   3.0   Silica C   2.0   Titanium oxide B   0.5       97   Charge control agent E   3.0   Silica C   2.0   Titanium oxide B   1.0       98   Charge control agent E   3.0   Silica C   2.0   Titanium oxide B   2.0       99   Charge control agent E   3.0   Silica C   2.0   Titanium oxide C   0.5       100   Charge control agent E   2.0   Silica C   2.0   Titanium oxide C   1.0       101   Charge control agent E   2.0   Silica C   2.0   Titanium oxide C   2.0       102   Charge control agent G   2.0   Silica A   1.0   Titanium oxide A   0.5       103   Charge control agent G   2.0   Silica A   1.0   Titanium oxide A   1.0       104   Charge control agent G   2.0   Silica A   1.0   Titanium oxide A   2.0       105   Charge control agent G   2.0   Silica A   2.0   Titanium oxide B   0.5       106   Charge control agent G   2.0   Silica A   2.0   Titanium oxide B   1.0       107   Charge control agent G   2.0   Silica A   2.0   Titanium oxide B   2.0       108   Charge control agent G   2.0   Silica A   3.0   Titanium oxide C   0.5       109   Charge control agent G   2.0   Silica A   3.0   Titanium oxide C   1.0       110   Charge control agent G   2.0   Silica A   3.0   Titanium oxide C   2.0       111   Charge control agent G   2.0   Silica B   1.0   Titanium oxide A   0.5       112   Charge control agent G   2.0   Silica B   1.0   Titanium oxide A   1.0       113   Charge control agent G   2.0   Silica B   1.0   Titanium oxide A   2.0       114   Charge control agent G   2.0   Silica B   2.0   Titanium oxide B   0.5       115   Charge control agent G   2.0   Silica B   2.0   Titanium oxide B   1.0       116   Charge control agent G   2.0   Silica B   2.0   Titanium oxide B   2.0       117   Charge control agent G   2.0   Silica C   1.0   Titanium oxide A   0.5       118   Charge control agent G   2.0   Silica C   1.0   Titanium oxide A   1.0       119   Charge control agent G   2.0   Silica C   1.0   Titanium oxide B   1.5       120   Charge control agent G   2.0   Silica C   2.0   Titanium oxide B   0.5       121   Charge control agent G   2.0   Silica C   2.0   Titanium oxide C   2.0       122   Charge control agent H   2.0   Silica A   1.0   Titanium oxide A   0.5       123   Charge control agent H   2.0   Silica A   2.0   Titanium oxide A   1.0       124   Charge control agent H   2.0   Silica A   3.0   Titanium oxide A   2.0       25   Charge control agent H   2.0   Silica A   1.0   Titanium oxide B   0.5       126   Charge control agent H   2.0   Silica A   2.0   Titanium oxide B   1.0       127   Charge control agent H   2.0   Silica A   3.0   Titanium oxide B   2.0       128   Charge control agent H   2.0   Silica A   1.0   Titanium oxide C   0.5       129   Charge control agent H   2.0   Silica A   2.0   Titanium oxide C   1.0       130   Charge control agent H   2.0   Silica A   3.0   Titanium oxide C   2.0       131   Charge control agent H   2.0   Silica B   1.0   Titanium oxide A   0.5       132   Charge control agent H   2.0   Silica B   1.0   Titanium oxide A   1.0       133   Charge control agent H   2.0   Silica B   1.0   Titanium oxide A   2.0       134   Charge control agent H   2.0   Silica B   1.0   Titanium oxide B   0.5       135   Charge control agent H   2.0   Silica B   1.0   Titanium oxide B   1.0       136   Charge control agent H   2.0   Silica B   1.0   Titanium oxide B   2.0       137   Charge control agent H   2.0   Silica B   1.0   Titanium oxide C   0.5       138   Charge control agent H   2.0   Silica B   1.0   Titanium oxide C   1.0       139   Charge control agent H   2.0   Silica B   1.0   Titanium oxide C   2.5       140   Charge control agent H   2.0   Silica B   2.0   Titanium oxide B   1.0       141   Charge control agent H   2.0   Silica B   3.0   Titanium oxide A   3.0       142   Charge control agent H   2.0   Silica C   1.0   Titanium oxide A   0.5       143   Charge control agent H   2.0   Silica C   1.0   Titanium oxide A   1.0       144   Charge control agent H   2.0   Silica C   1.0   Titanium oxide A   2.0       145   Charge control agent H   2.0   Silica C   1.0   Titanium oxide B   0.5       146   Charge control agent H   2.0   Silica C   1.0   Titanium oxide B   2.0       147   Charge control agent H   2.0   Silica C   1.0   Titanium oxide C   2.0       148   Charge control agent H   2.0   Silica C   1.0   Titanium oxide C   3.0       149   Charge control agent K   2.0   Silica A   1.0   Titanium oxide A   0.5       150   Charge control agent K   2.0   Silica A   1.0   Titanium oxide A   1.0       151   Charge control agent K   2.0   Silica A   1.0   Titanium oxide A   2.0       152   Charge control agent K   2.0   Silica A   1.0   Titanium oxide B   0.5       153   Charge control agent K   2.0   Silica A   1.0   Titanium oxide B   1.0       154   Charge control agent K   2.0   Silica A   1.0   Titanium oxide B   3.0       155   Charge control agent K   2.0   Silica A   1.0   Titanium oxide C   0.5       156   Charge control agent K   2.0   Silica A   5.0   Titanium oxide C   1.0       157   Charge control agent K   2.0   Silica A   1.0   Titanium oxide C   3.0       158   Charge control agent K   1.0   Silica A   3.0   Titanium oxide C   3.0       159   Charge control agent K   1.0   Silica B   1.0   Titanium oxide A   0.5       160   Charge control agent K   1.0   Silica B   1.0   Titanium oxide A   1.0       161   Charge control agent K   1.0   Silica B   1.0   Titanium oxide A   2.5       162   Charge control agent K   1.0   Silica B   1.0   Titanium oxide B   1.0       163   Charge control agent K   1.0   Silica B   1.0   Titanium oxide B   2.0       164   Charge control agent K   1.0   Silica B   1.0   Titanium oxide B   3.0       165   Charge control agent K   1.0   Silica B   1.0   Titanium oxide C   1.0       166   Charge control agent K   1.0   Silica C   1.0   Titanium oxide C   2.0       167   Charge control agent K   1.0   Silica C   1.0   Titanium oxide C   1.0       168   Charge control agent K   1.0   Silica C   1.0   Titanium oxide C   3.0       169   Charge control agent J   2.0   Silica A   1.0   Titanium oxide A   1.0       170   Charge control agent J   2.0   Silica A   1.0   Titanium oxide A   2.0       171   Charge control agent J   2.0   Silica A   1.0   Titanium oxide A   1.0       172   Charge control agent J   2.0   Silica A   1.0   Titanium oxide B   1.0       173   Charge control agent P   1.0   Silica A   1.0   Titanium oxide A   1.0       174   Charge control agent P   1.0   Silica A   1.0   Titanium oxide A   2.0       175   Charge control agent P   1.0   Silica A   1.0   Titanium oxide A   1.0       176   Charge control agent P   1.0   Silica A   1.0   Titanium oxide B   1.0       177   Charge control agent P   1.0   Silica A   1.0   Titanium oxide B   2.0       178   Charge control agent P   1.0   Silica A   1.0   Titanium oxide B   3.0       179   Charge control agent P   1.0   Silica A     1.0 w   Titanium oxide C   1.0       180   Charge control agent P   1.0   Silica A   1.0   Titanium oxide C   2.0       181   Charge control agent P   1.0   Silica A   1.0   Titanium oxide C   3.0       182   Charge control agent P   1.0   Silica A   2.0   Titanium oxide A   1.0       183   Charge control agent P   1.0   Silica B   5.0   Titanium oxide B   1.0       184   Charge control agent P   2.0   Silica B   1.0   Titanium oxide A   1.0       185   Charge control agent P   2.0   Silica C   1.0   Titanium oxide A   2.0       186   Charge control agent P   2.0   Silica B   1.0   Titanium oxide A   3.0       187   Charge control agent P   2.0   Silica B   1.0   Titanium oxide B   1.0       188   Charge control agent P   2.0   Silica B   1.0   Titanium oxide B   2.0       189   Charge control agent P   2.0   Silica B   1.0   Titanium oxide B   3.0       190   Charge control agent P   2.0   Silica C   1.0   Titanium oxide C   1.0       191   Charge control agent P   3.0   Silica B   1.0   Titanium oxide C   2.0       192   Charge control agent P   4.0   Silica B   1.0   Titanium oxide C   3.0       193   Charge control agent P   8.0   Silica C   2.0   Titanium oxide A   1.0       194   Charge control agent Q   1.0   Silica A   1.0   Titanium oxide A   1.0       195   Charge control agent Q   1.0   Silica A   1.0   Titanium oxide A   2.0       196   Charge control agent Q   1.0   Silica A   1.0   Titanium oxide A   1.0       197   Charge control agent Q   1.0   Silica A   1.0   Titanium oxide B   1.0       198   Charge control agent Q   1.0   Silica A   1.0   Titanium oxide B   2.0       199   Charge control agent Q   1.0   Silica A   1.0   Titanium oxide B   3.0       200   Charge control agent Q   1.0   Silica C   1.0   Titanium oxide C   1.0       201   Charge control agent Q   1.0   Silica C   1.0   Titanium oxide C   2.0       202   Charge control agent Q   1.0   Silica A   1.0   Titanium oxide C   3.0       203   Charge control agent Q   1.0   Silica A   2.0   Titanium oxide A   1.0       204   Charge control agent Q   2.0   Silica A   5.0   Titanium oxide B   1.0       205   Charge control agent Q   2.0   Silica B   1.0   Titanium oxide A   1.0       206   Charge control agent Q   2.0   Silica B   1.0   Titanium oxide A   2.0       207   Charge control agent Q   2.0   Silica B   1.0   Titanium oxide A   3.0       208   Charge control agent Q   2.0   Silica B   5.0   Titanium oxide B   1.0       209   Charge control agent Q   2.0   Silica B   5.0   Titanium oxide B   2.0       210   Charge control agent Q   2.0   Silica B   1.0   Titanium oxide B   3.0       211   Charge control agent Q   2.0   Silica B   1.0   Titanium oxide C   1.0       212   Charge control agent Q   3.0   Silica B   1.0   Titanium oxide C   2.0       213   Charge control agent Q   5.0   Silica B   1.0   Titanium oxide C   3.0       214   Charge control agent Q   6.0   Silica B   2.0   Titanium oxide A   1.0       215   Charge control agent Q   3.0   Silica C   1.0   Titanium oxide A   1.0       216   Charge control agent R   1.0   Silica A   1.0   Titanium oxide A   0.5       217   Charge control agent R   1.0   Silica A   1.0   Titanium oxide A   1.0       218   Charge control agent R   1.0   Silica A   1.0   Titanium oxide A   2.0       219   Charge control agent R   1.0   Silica A   1.0   Titanium oxide B   0.5       220   Charge control agent R   1.0   Silica A   1.0   Titanium oxide B   1.0       221   Charge control agent R   1.0   Silica A   1.0   Titanium oxide B   2.0       222   Charge control agent R   1.0   Silica A   1.0   Titanium oxide C   0.5       223   Charge control agent R   1.0   Silica A   5.0   Titanium oxide C   1.0       224   Charge control agent R   1.0   Silica A   6.0   Titanium oxide C   3.0       225   Charge control agent R   1.0   Silica B   6.0   Titanium oxide A   0.5       226   Charge control agent R   1.0   Silica B   1.0   Titanium oxide A   1.0       227   Charge control agent R   2.0   Silica B   1.0   Titanium oxide A   2.0       228   Charge control agent R   2.0   Silica B   1.0   Titanium oxide B   0.5       229   Charge control agent R   2.0   Silica B   1.0   Titanium oxide B   1.0       230   Charge control agent R   2.0   Silica B   1.0   Titanium oxide B   5.0       231   Charge control agent R   6.0   Silica B   1.0   Titanium oxide C   0.5       232   Charge control agent R   5.0   Silica B   1.0   Titanium oxide C   1.0       233   Charge control agent S   1.0   Silica B   1.0   Titanium oxide C   2.0       234   Charge control agent S   1.0   Silica C   2.0   Titanium oxide A   0.5       235   Charge control agent S   1.0   Silica C   2.0   Titanium oxide A   1.0       236   Charge control agent S   1.0   Silica C   2.0   Titanium oxide A   2.0       237   Charge control agent S   1.0   Silica C   2.0   Titanium oxide B   0.5       238   Charge control agent S   1.0   Silica C   2.0   Titanium oxide B   1.0       239   Charge control agent S   1.0   Silica C   2.0   Titanium oxide B   2.0       240   Charge control agent S   1.0   Silica C   2.0   Titanium oxide C   0.5       241   Charge control agent S   1.0   Silica C   2.0   Titanium oxide C   1.0       242   Charge control agent S   1.0   Silica C   2.0   Titanium oxide C   2.0       243   Charge control agent S   1.0   Silica A   1.0   Titanium oxide A   0.5       244   Charge control agent S   2.0   Silica A   1.0   Titanium oxide A   1.0       245   Charge control agent S   2.0   Silica A   1.0   Titanium oxide A   2.0       246   Charge control agent S   2.0   Silica A   1.0   Titanium oxide B   0.5       247   Charge control agent S   2.0   Silica A   1.0   Titanium oxide B   1.0       248   Charge control agent S   2.0   Silica A   1.0   Titanium oxide B   2.0       249   Charge control agent S   2.0   Silica A   1.0   Titanium oxide C   0.5       250   Charge control agent S   2.0   Silica A   1.0   Titanium oxide C   1.0       251   Charge control agent S   2.0   Silica A   1.0   Titanium oxide C   2.0       252   Charge control agent S   2.0   Silica B   1.0   Titanium oxide B   2.0       253   Charge control agent S   3.0   Silica B   1.0   Titanium oxide C     0.5 w       254   Charge control agent S   3.0   Silica B   1.0   Titanium oxide C   1.0       255   Charge control agent S   3.0   Silica B   1.0   Titanium oxide C   2.0       256   Charge control agent S   2.0   Silica A   1.0   Titanium oxide B   0.5       257   Charge control agent S   2.0   Silica A   1.0   Titanium oxide B   1.0       258   Charge control agent S   2.0   Silica A   1.0   Titanium oxide B   2.0       259   Charge control agent S   2.0   Silica A   1.0   Titanium oxide C   0.5       260   Charge control agent S   2.0   Silica A   1.0   Titanium oxide C   1.0       261   Charge control agent S   2.0   Silica A   1.0   Titanium oxide C   2.0       262   Charge control agent S   2.0   Silica B   1.0   Titanium oxide B   2.0       263   Charge control agent S   5.0   Silica B   1.0   Titanium oxide C   0.5       264   Charge control agent S   6.0   Silica B   1.0   Titanium oxide C   1.0       265   Charge control agent S   10.0   Silica B   1.0   Titanium oxide C   2.0       266   Charge control agent R   1.0   Silica A   1.0   Titanium oxide C   0.5       267   Charge control agent R   5.0   Silica A   5.0   Titanium oxide C   3.0       268   Charge control agent R   1.0   Silica A   5.0   Titanium oxide C   3.0       269   Charge control agent R   1.0   Silica B   0.5   Titanium oxide A   0.5       270   Charge control agent R   5.0   Silica B   1.0   Titanium oxide A   1.0                  
 
       TESTING EXAMPLE 1  
       [0042]     5,000 sheets of paper was printed with each of the non-magnetic monocomponent color toner prepared in Examples 1-182 and Comparative Examples 1-270 using a contact type of non-magnetic monocomponent development printer (HP 4600, Hewlett-Packard) at normal temperature and humidity (20° C., 55% RH). Image density, printing efficiency, and long-term stability were tested. The results are given in Table 6 below.  
         [0043]     1) Image Density (I.D.)  
         [0044]     Solid area was measured using a Macbeth reflectance densitometer RD918.  
         [0045]     ∘: Image density was 1.4 or above.  
         [0046]     Δ: Image density was 1.2-1.4.  
         [0047]     ×: Image density was 1.0-1.2.  
         [0048]     2) Printing efficiency  
         [0049]     Of the 5,000 sheets of paper, printing efficiency was calculated by counting the number of wasted sheets per each 500 sheets.  
         [0050]     {circle over (∘)}: Printing efficiency was 80% or over.  
         [0051]     ∘: Printing efficiency was 70-80%.  
         [0052]     Δ: Printing efficiency was 60-70%.  
         [0053]     ×: Printing efficiency was 50-60%.  
         [0054]     3) Long-term stability  
         [0055]     It was confirmed if I.D. and printing efficiency were maintained after printing 5,000 sheets.  
         [0056]     A: I.D. was 1.4 or over and printing efficiency was 80% or over.  
         [0057]     B: I.D. was 1.3-1.4 and printing efficiency was 70-80%.  
         [0058]     C: I.D. was 1.2-1.3 and printing efficiency was 60-70%.  
         [0059]     D: I.D. was 1.0-1.2 and printing efficiency was 50-60%.  
                                             TABLE 6                           Image   Printing   Long-term       Example   density   efficiency   stability                                1   ∘   ⊚   A       2   ∘   ⊚   A       3   ∘   ⊚   A       4   ∘   ⊚   A       5   ∘   ⊚   A       6   ∘   ⊚   A       7   ∘   ∘   A       8   ∘   ⊚   A       9   ∘   ⊚   A       10   ∘   ⊚   A       11   ∘   ⊚   A       12   ∘   ⊚   A       13   ∘   ⊚   B       14   ∘   ⊚   A       15   ∘   ⊚   A       16   ∘   ⊚   A       17   ∘   ⊚   A       18   ∘   ⊚   A       19   ∘   ⊚   A       20   ∘   ⊚   A       21   ∘   ⊚   A       22   ∘   ⊚   A       23   ∘   ⊚   A       24   ∘   ⊚   A       25   ∘   ⊚   A       26   ∘   ⊚   A       27   ∘   ⊚   A       28   ∘   ∘   A       29   ∘   ⊚   A       30   ∘   ⊚   A       31   ∘   ⊚   A       32   ∘   ⊚   A       33   ∘   ⊚   A       34   ∘   ⊚   A       35   ∘   ⊚   A       36   ∘   ⊚   A       37   ∘   ⊚   A       38   ∘   ⊚   A       39   ∘   ⊚   A       40   ∘   ⊚   A       41   ∘   ⊚   A       42   ∘   ⊚   A       43   ∘   ∘   B       44   ∘   ⊚   A       45   ∘   ⊚   A       46   ∘   ∘   B       47   ∘   ⊚   A       48   ∘   ⊚   A       49   ∘   ∘   B       50   ∘   ⊚   A       51   ∘   ⊚   A       52   ∘   ⊚   B       53   ∘   ⊚   A       54   ∘   ⊚   A       55   ∘   ∘   A       56   ∘   ∘   A       57   ∘   ⊚   A       58   ∘   ⊚   A       59   ∘   ⊚   A       60   ∘   ⊚   A       61   ∘   ⊚   A       62   ∘   ∘   A       63   ∘   ⊚   A       64   ∘   ∘   B       65   ∘   ⊚   A       66   ∘   ⊚   A       67   ∘   ⊚   A       68   ∘   ∘   B       69   ∘   ⊚   A       70   ∘   ⊚   A       71   ∘   ⊚   A       72   ∘   ⊚   A       73   ∘   ⊚   A       74   ∘   ⊚   A       75   ∘   ⊚   A       76   ∘   ⊚   A       77   ∘   ⊚   A       78   ∘   ⊚   A       79   Δ   ⊚   B       80   ∘   ⊚   A       81   ∘   ⊚   A       82   ∘   ⊚   A       83   ∘   ⊚   A       84   ∘   ⊚   A       85   ∘   ⊚   A       86   ∘   ⊚   A       87   ∘   ⊚   A       88   ∘   ∘   A       89   ∘   ⊚   A       90   ∘   ⊚   A       91   ∘   ⊚   A       92   ∘   ⊚   A       93   ∘   ⊚   A       94   ∘   ⊚   A       95   Δ   ⊚   A       96   ∘   ⊚   A       97   ∘   ⊚   A       98   ∘   ⊚   A       99   ∘   ⊚   A       100   ∘   ⊚   A       101   ∘   ∘   B       101   ∘   ⊚   A       102   ∘   ⊚   A       103   ∘   ⊚   A       104   ∘   ⊚   A       105   ∘   ⊚   A       106   ∘   ⊚   A       107   ∘   ⊚   A       108   ∘   ⊚   A       109   ∘   ⊚   A       110   ∘   ⊚   A       111   ∘   ⊚   A       112   ∘   ⊚   A       113   ∘   ⊚   A       114   ∘   ⊚   A       115   ∘   ⊚   A       116   ∘   ⊚   A       117   ∘   ⊚   A       118   ∘   ⊚   A       119   ∘   ⊚   A       120   ∘   ⊚   A       121   ∘   ⊚   A       122   ∘   ⊚   A       123   ∘   ⊚   A       124   ∘   ⊚   A       125   ∘   ⊚   B       126   ∘   ⊚   A       127   ∘   ⊚   A       128   ∘   ∘   A       129   ∘   ⊚   A       130   ∘   ⊚   A       131   ∘   ⊚   A       132   ∘   ⊚   A       133   ∘   ⊚   A       134   ∘   ⊚   A       135   ∘   ⊚   A       136   ∘   ⊚   A       137   ∘   ⊚   A       138   ∘   ⊚   A       139   ∘   ⊚   A       140   ∘   ⊚   A       141   ∘   ⊚   A       142   ∘   ⊚   A       143   ∘   ∘   B       144   ∘   ⊚   A       145   ∘   ⊚   A       146   ∘   ∘   B       47   ∘   ⊚   A       148   ∘   ⊚   A       149   ∘   ∘   B       150   ∘   ⊚   A       151   ∘   ⊚   A       152   ∘   ∘   B       153   ∘   ⊚   A       154   ∘   ∘   A       155   ∘   ⊚   A       156   ∘   ∘   A       157   ∘   ⊚   A       158   ∘   ⊚   A       159   ∘   ⊚   A       160   ∘   ⊚   A       161   ∘   ⊚   A       162   ∘   ⊚   A       163   ∘   ⊚   A       164   ∘   ⊚   A       165   ∘   ⊚   A       166   ∘   ⊚   A       167   ∘   ⊚   A       168   ∘   ⊚   A       169   ∘   ⊚   A       170   ∘   ⊚   A       171   ∘   ⊚   A       172   ∘   ⊚   A       173   ∘   ⊚   B       174   ∘   ⊚   A       175   ∘   ⊚   A       176   ∘   ⊚   A       177   ∘   ⊚   A       178   ∘   ∘   A       179   ∘   ∘   A       180   ∘   ∘   A       181   ∘   ∘   A       182   ∘   ⊚   A                  
 
         [0060]    
       
         
               
               
               
               
             
               
               
               
               
             
           
               
                 TABLE 7 
               
               
                   
               
               
                   
               
               
                 Comparative 
                 Image 
                 Printing 
                 Long-term 
               
               
                 Example 
                 density 
                 efficiency 
                 stability 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 1 
                 x 
                 x 
                 D 
               
               
                 2 
                 x 
                 Δ 
                 C 
               
               
                 3 
                 Δ 
                 x 
                 D 
               
               
                 4 
                 x 
                 x 
                 D 
               
               
                 5 
                 x 
                 x 
                 D 
               
               
                 6 
                 Δ 
                 x 
                 D 
               
               
                 7 
                 x 
                 x 
                 D 
               
               
                 8 
                 x 
                 x 
                 C 
               
               
                 9 
                 Δ 
                 x 
                 D 
               
               
                 10 
                 x 
                 x 
                 D 
               
               
                 11 
                 x 
                 x 
                 C 
               
               
                 12 
                 Δ 
                 x 
                 D 
               
               
                 13 
                 x 
                 x 
                 D 
               
               
                 14 
                 x 
                 x 
                 C 
               
               
                 15 
                 x 
                 x 
                 D 
               
               
                 16 
                 x 
                 x 
                 D 
               
               
                 17 
                 x 
                 x 
                 C 
               
               
                 18 
                 Δ 
                 x 
                 D 
               
               
                 19 
                 x 
                 x 
                 D 
               
               
                 20 
                 x 
                 x 
                 D 
               
               
                 21 
                 x 
                 x 
                 D 
               
               
                 22 
                 x 
                 Δ 
                 D 
               
               
                 23 
                 x 
                 x 
                 D 
               
               
                 24 
                 x 
                 x 
                 D 
               
               
                 25 
                 x 
                 x 
                 D 
               
               
                 26 
                 x 
                 x 
                 C 
               
               
                 27 
                 x 
                 x 
                 D 
               
               
                 28 
                 x 
                 Δ 
                 D 
               
               
                 29 
                 x 
                 x 
                 D 
               
               
                 30 
                 x 
                 x 
                 D 
               
               
                 31 
                 x 
                 Δ 
                 D 
               
               
                 32 
                 x 
                 x 
                 D 
               
               
                 33 
                 x 
                 x 
                 D 
               
               
                 34 
                 x 
                 Δ 
                 D 
               
               
                 35 
                 x 
                 x 
                 D 
               
               
                 36 
                 x 
                 x 
                 D 
               
               
                 37 
                 x 
                 Δ 
                 D 
               
               
                 38 
                 x 
                 x 
                 D 
               
               
                 39 
                 x 
                 x 
                 D 
               
               
                   
               
             
          
         
       
     
         [0061]     As seen in Table 6 and Table 7, when a charge control agent having a specific shaped particle size distribution was used, as in the present invention, image density, printing efficiency, and long-term stability were superior. This is because the charge control agent particle having a larger particle size tends to be present on the surface, while the charge control agent particle having a smaller particle size does not because of a stronger binding ability with the binder resin.  
         [0062]     As apparent from the above description, the non-magnetic monocomponent color toner of the present invention, which comprises a charge control agent having a specific shaped particle size distribution, enables excellent functioning as a charge control agent because the charge control agent particle having a smaller particle size has good binding ability with the binder resin and the charge control agent having a larger particle size tends to be present on the surface. The toner comprising such a charge control agent offers higher resolution because of good chargeability and ensures long-term stability because of uniform charge distribution.  
         [0063]     While the present invention has been described in detail with reference to exemplary embodiments, those skilled in the art will appreciate that various modifications and substitutions can be made thereto without departing from the spirit and scope of the present invention as set forth in the appended claims.