Abstract:
Disclosed is an organic compound represented by the following Chemical Formula 1 that easily dissolves in an organic solvent, and that is applicable as a host material of an emission layer of an organic photoelectric device since it emits fluorescence and phosphorescence at a red wavelength through a blue wavelength.

Description:
CROSS-REFERENCE TO RELATED APPLICATION 
     This application claims priority to and the benefit of Korean Patent Application No. 10-2007-0093879 filed in the Korean Intellectual Property Office on Sep. 14, 2007, the entire contents of which are incorporated herein by reference. 
    
    
     BACKGROUND OF THE INVENTION 
     (a) Field of the Invention 
     The present invention relates to an organic compound and an organic photoelectric device including the same. More particularly, the present invention relates to an organic compound that easily dissolves in an organic solvent, and is applicable as a host material of an emission layer of an organic photoelectric device since it emits fluorescence and phosphorescence at a red wavelength through a blue wavelength, and an organic photoelectric device including the same. 
     (b) Description of the Related Art 
     An organic photoelectric device includes an organic light emitting material between a rear plate including ITO transparent electrode patterns as an anode on a transparent glass substrate and an upper plate including a metal electrode as a cathode on a substrate. When a predetermined voltage is applied between the transparent electrode and metal electrode, current flows through the organic light emitting material to emit light. 
     Such an organic light emitting material for an organic photoelectric device was firstly developed by Eastman Kodak, Inc., in 1987. The material is a low molecular aromatic diamine and aluminum complex as an emission-layer-forming material (Applied Physics Letters. 51, 913, 1987). C. W Tang et al. firstly disclosed a practicable device as an organic photoelectric device in 1987 (Applied Physics Letters, 51 12, 913-915, 1987). 
     According to the reference, the organic layer has a structure in which a thin film (hole transport layer (HTL)) of a diamine derivative and a thin film of tris(8-hydroxy-quinolate)aluminum (Alq 3 ) are laminated. The Alq 3  thin film functions as an emission layer for transporting electrons. The Alq 3  thin film functions as an emission layer for transporting electrons. 
     Generally, the organic photoelectric device is composed of an anode of a transparent electrode, an organic thin layer of a light emitting region, and a metal electrode (cathode) formed on a glass substrate, in that order. The organic thin layer may includes an emission layer, a hole injection layer (HIL), a hole transport layer (HTL), an electron transport layer (ETL), or an electron injection layer (EIL). It may further include an electron blocking layer or a hole blocking layer due to the emission characteristics of the emission layer. 
     When the organic photoelectric device is applied with an electric field, holes and electrons are injected from the anode and the cathode, respectively. The injected holes and electrons are recombined on the emission layer though the hole transport layer (HTL) and the electron transport layer (ETL) to provide light emitting excitons. 
     The provided light emitting excitons emit light by transiting to the ground state. 
     The light emitting may be classified as a fluorescent material including singlet excitons and a phosphorescent material including triplet excitons. 
     Recently, it has become known that the phosphorescent light emitting material can be used for a light emitting material in addition to the fluorescent light emitting material (D. F. O&#39;Brien et al., Applied Physics Letters, 74 3, 442-444, 1999; M. A. Baldo et al., Applied Physics letters, 75 1, 4-6, 1999). Such phosphorescent emission occurs by transiting electrons from the ground state to the exited state, non-radiative transiting of a singlet exciton to a triplet exciton through intersystem crossing, and transiting the triplet exciton to the ground state to emit light. 
     When the triplet exciton is transited, it cannot directly transit to the ground state. Therefore, the electron spin is flipped, and then it is transited to the ground state so that it provides a characteristic of extending the lifetime (emission duration) to more than that of fluorescent. 
     In other words, the duration of fluorescent emission is extremely short at several nanoseconds, but the duration of phosphorescent emission is relatively long such as at several microseconds, so that it provides a characteristic of extending the lifetime (emission duration) to more than that of the fluorescent emission. 
     In addition, evaluating quantum mechanically, when holes injected from the anode are recombined with electrons injected from the cathode to provide light emitting excitons, the singlet and the triplet are produced in a ratio of 1:3, in which the triplet light emitting excitons are produced at three times the amount of the singlet light emitting excitons in the organic photoelectric device. 
     Accordingly, the percentage of the singlet exited state is 25% (the triplet is 75%) in the case of a fluorescent material, so it has limits in luminous efficiency. On the other hand, in the case of a phosphorescent material, it can utilize 75% of the triplet exited state and 25% of the singlet exited state, so theoretically the internal quantum efficiency can reach up to 100%. When a phosphorescent light emitting material is used, it has advantages in an increase in luminous efficiency of around four times that of the fluorescent light emitting material. 
     In the above-mentioned organic light emitting diode, a light emitting colorant (dopant) may be added in an emission layer (host) in order to increase the efficiency and stability in the emission state. 
     In this structure, the efficiency and properties of the light emission diodes are dependent on the host material in the emission layer. According to studies regarding the emission layer (host), the organic host material can be exemplified by a material including naphthalene, anthracene, phenanthrene, tetracene, pyrene, benzopyrene, chrysene, pycene, carbazole, fluorene, biphenyl, terphenyl, triphenylene oxide, dihalobiphenyl, trans-stilbene, and 1,4-diphenylbutadiene. 
     Generally, the host material includes 4,4-N,N-dicarbazolebiphenyl (CBP) having a glass transition temperature of 110° C. or less and a thermal decomposition temperature of 400° C. or less, in which the thermal stability is low and the symmetry is excessively high. Thereby, it tends to crystallize and cause problems such as a short and a pixel defect according to results of thermal resistance tests of the devices. 
     In addition, most host materials including CBP are materials in which the hole transporting property is greater than the electron transporting property. In other words, as the injected hole transportation is faster than the injected electron transportation, the excitons are ineffectively formed in the emission layer. Therefore, the resultant device has deteriorated luminous efficiency. 
     Accordingly, in order to realize a highly efficient and long lifetime organic light emitting device, it is required to develop a phosphorescent host material having high electrical and thermal stability and that is capable of transporting both holes and electrons. 
     SUMMARY OF THE INVENTION 
     One aspect of the present invention provides an organic compound that easily dissolves in an organic solvent, and is applicable as a host material of an emission layer of an organic photoelectric device since it emits fluorescence and phosphorescence at a red wavelength through a blue wavelength. 
     Another aspect of the present invention provides an organic photoelectric device including the organic compound. 
     The aspects of the present invention are not limited to the above technical purposes, and a person of ordinary skill in the art can understand other technical purposes. 
     According to one aspect of the present invention, provided is an organic compound represented by the following Chemical Formula 1: 
     
       
                 
         
             
             
         
      
     
     In the above Chemical Formula 1, 
     X 1  to X 16  are the same or different and independently selected from CR′ or N, 
     Ar 1  to Ar 3  are the same or different and independently selected from a single bond, a substituted or unsubstituted C6 to C30 arylene group, or a substituted or unsubstituted C2 to C30 heteroarylene group, and 
     Ar′ and Ar″ are the same or different and independently are selected from a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C2 to C30 heteroaryl group, 
     wherein R′ is independently selected from hydrogen, a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, substituted or unsubstituted C2 to C20 acyloxy group, a substituted or unsubstituted C2 to C20 acylamino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group. 
     Ar 1  to Ar 3  are the same or different, and may be independently selected from a substituted or unsubstituted carbazole, a substituted or unsubstituted arylamine, a substituted or unsubstituted phenyl, a substituted or unsubstituted tolyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted stilbene, a substituted or unsubstituted fluorenyl, a substituted or unsubstituted anthracenyl, a substituted or unsubstituted terphenyl, a substituted or unsubstituted pyrenyl, a substituted or unsubstituted diphenyl anthracenyl, a substituted or unsubstituted dinaphthylanthracenyl, a substituted or unsubstituted pentacenyl, a substituted or unsubstituted bromophenyl, a substituted or unsubstituted hydroxyphenyl, a substituted or unsubstituted thienyl, a substituted or unsubstituted pyridyl, a substituted or unsubstituted azobenzenyl, or a substituted or unsubstituted ferrocenyl. Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted carbazole, a substituted or unsubstituted arylamine, a substituted or unsubstituted phenyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted anthracenyl, a substituted or unsubstituted fluorene, a substituted or unsubstituted thiophene, a substituted or unsubstituted pyrrole, a substituted or unsubstituted pyridine, a substituted or unsubstituted aryloxadiazole, a substituted or unsubstituted triazole, or a substituted or unsubstituted arylsilane. 
     Ar′ and Ar″ are the same or different, and are independently selected from substituents represented by the following Chemical Formulae 2 to 31. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
     In the above Chemical Formulae 2 to 31, 
     R 1  to R 76  are the same or different, and are independently selected from hydrogen, a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to C20 acyloxy group, a substituted or unsubstituted C2 to C20 acylamino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl, 
     n 1 , n 2 , n 4 , n 6 , n 10 , n 21 , n 26 , n 27 , n 35 , n 39 , n 46 , n 47 , n 49 , n 53 , n 59 , n 61 , and n 62  are the same or different, and are independently integers ranging from 0 to 5, 
     n 3 , n 5 , n 7 , n 8 , n 11 , n 12 , n 16 , n 22 , n 23 , n 29 , n 30 , n 31 , n 33 , n 36 , n 37 , n 40 , n 41  to n 44 , n 48 , n 50  to n 52 , n 54 , n 55 , n 57 , n 56 , n 60 , n 63 , n 65 , n 67 , n 68 , n 69 , n 70 , and n 71  are the same or different, and are independently integers ranging from 0 to 4, 
     n 9 , n 13 , n 14 , n 18 , n 19 , n 20 , n 25 , n 28 , n 32 , n 34 , n 38 , n 45 , n 58 , and n 66  are the same or different, and are independently integers ranging from 0 to 3, and 
     n 15  and n 24  are the same or different, and are independently integers ranging from 0 to 2. 
     According to another aspect of the present invention, an organic compound represented by the following Chemical Formula 32 is provided. 
     
       
                 
         
             
             
         
      
     
     In the above Chemical Formula 32, X 1  to X 16  are the same or different, and are independently selected from CR′ and N, 
     Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted C6 to C30 aryl group or a substituted or unsubstituted C2 to C30 heteroaryl group, and 
     R5 and R′ are the same or different, and are independently selected from hydrogen, a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to C20 acyloxy group, a substituted or unsubstituted C2 to C20 acylamino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group, 
     Ar′ and Ar″ are the same or different, and are independently selected from substituents represented by the following Chemical Formulae B-1 to B-9. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
     
     Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted carbazolyl, a substituted or unsubstituted arylamine, a substituted or unsubstituted phenyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted anthracenyl, a substituted or unsubstituted fluorenyl, a substituted or unsubstituted thiophene, a substituted or unsubstituted pyrrole, a substituted or unsubstituted pyridine, a substituted or unsubstituted aryloxadiazole, a substituted or unsubstituted triazole, or a substituted or unsubstituted arylsilane. 
     Ar′ and Ar″ are the same or different, and are independently selected from substituents represented by the following Chemical Formulae 2 to 31. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
     In the above Chemical Formulae 2 to 31, 
     R 1  to R 76  are the same or different, and are independently a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to 20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to 20 acyloxy group, a substituted or unsubstituted C2 to 20 acylamino group, a substituted or unsubstituted C2 to 20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to 20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group, 
     n 1 , n 2 , n 4 , n 6 , n 10 , n 21 , n 26 , n 27 , n 35 , n 39 , n 46 , n 47 , n 49 , n 53 , n 59 , n 61 , and n 62  are the same or different, and are independently integers ranging from 0 to 5, 
     n 3 , n 5 , n 7 , n 8 , n 11 , n 12 , n 16 , n 22 , n 23 , n 29 , n 30 , n 31 , n 33 , n 36 , n 37 , n 40 , n 41  to n 44 , n 48 , n 50  to n 52 , n 54 , n 55 , n 57 , n 56 , n 60 , n 63 , n 65 , n 67 , n 68 , n 69 , n 70 , and n 71  are the same or different, and are independently integers ranging from 0 to 4, 
     n 9 , n 13 , n 14 , n 18 , n 19 , n 20 , n 25 , n 28 , n 32 , n 34 , n 38 , n 45 , n 58 , and n 66  are the same or different, and are independently integers ranging from 0 to 3, and 
     n 15  and n 24  are the same or different, and are independently integers ranging from 0 to 2. 
     According to another aspect of the present invention, provided is an organic compound represented by one of the Chemical Formulae selected from the following Chemical Formulae 33 to 37. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
     
     In the above Chemical Formulae 33 to 37, 
     X 1  to X 16  are the same or different, and are independently selected from CR′ or N, 
     Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted C6 to C30 aryl group or a substituted or unsubstituted C2 to C30 heteroaryl group, 
     R 5  to R 7  and R′ are the same or different, and are independently hydrogen, a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to C20 acyloxy group, a substituted or unsubstituted C2 to C20 acylamino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group, and 
     n 5  to n 7  are the same or different, and are independently integers ranging from 0 to 5. 
     Ar′ and Ar″ are the same or different, and are independently selected from substituents represented by the following Chemical Formulae B-1 to B-9. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
     
     Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted carbazole, a substituted or unsubstituted arylamine, a substituted or unsubstituted phenyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted anthracenyl, a substituted or unsubstituted fluorene, a substituted or unsubstituted thiophene, a substituted or unsubstituted pyrrole, a substituted or unsubstituted pyridine, a substituted or unsubstituted aryloxadiazole, a substituted or unsubstituted triazole, or a substituted or unsubstituted arylsilane. 
     Ar′ and Ar″ are the same or different, and are independently selected from substituents represented by the following Chemical Formulae 2 to 31. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
     In the above Chemical Formulae 2 to 31, 
     R 1  to R 76  are the same or different, and are independently selected from a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to C20 acyloxy group, a substituted or unsubstituted C2 to C20 acylamino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group, 
     n 1 , n 2 , n 4 , n 6 , n 10 , n 21 , n 26 , n 27 , n 35 , n 39 , n 46 , n 47 , n 49 , n 53 , n 59 , n 61 , and n 62  are the same or different, and are independently integers ranging from 0 to 5, 
     n 3 , n 5 , n 7 , n 8 , n 11 , n 12 , n 16 , n 22 , n 23 , n 29 , n 30 , n 31 , n 33 , n 36 , n 37 , n 40 , n 41  to n 44 , 
     n 48 , n 50  to n 52 , n 54 , n 55 , n 57 , n 56 , n 60 , n 63 , n 65 , n 67 , n 68 , n 69 , n 70 , and n 71  are the same or different, and are independently integers ranging from 0 to 4, 
     n 9 , n 13 , n 14 , n 18 , n 19 , n 20 , n 25 , n 28 , n 32 , n 34 , n 38 , n 45 , n 58 , and n 66  are the same or different, and are independently integers ranging from 0 to 3, and 
     n 15  and n 24  are the same or different, and are independently integers ranging from 0 to 2. 
     According to still another aspect of the present invention, provided is an organic photoelectric device that includes an organic thin layer disposed between a pair of electrodes. The organic thin layer includes the above organic compound. 
     The organic layer may be an emission layer. 
     The organic layer may be selected from a hole injection layer (HIL), a hole transport layer (HTL), a hole blocking film, and a combination thereof. 
     The organic layer may be selected from an electron injection layer (EIL), an electron transport layer (ETL), an electron blocking film, and a combination thereof. 
     Hereinafter, further embodiments of the present invention will be described in detail. 
     The organic compound easily dissolves in an organic solvent, and is applicable as a host material of an emission layer of an organic photoelectric device since it emits fluorescence and phosphorescence at a red wavelength through a blue wavelength. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a cross-sectional view showing an organic photoelectric device according to one embodiment of the present invention. 
         FIG. 2  shows a  1 H-NMR spectrum of the organic compound according to Example 7. 
         FIG. 3  is a graph showing PL (photoluminescence) wavelength of the organic compound according to Example 7. 
         FIG. 4  is a graph showing output efficiency of the organic photoelectric device including the organic compound according to Example 7. 
         FIG. 5  is a graph showing voltage-luminance of the organic photoelectric device including the organic compound according to Example 7. 
         FIG. 6A  shows a differential scanning calorimetry (DSC) result of Example 7. 
         FIG. 6B  shows a thermogravimetric analysis (TGA) result of Example 7. 
         FIG. 7A  shows a DSC result of Example 10. 
         FIG. 7B  shows a TGA result of Example 10. 
         FIG. 8A  shows luminous efficiency data of Examples 14 and 15 and Comparative Example 2. 
         FIG. 8B  shows electrical power efficiency data of Examples 14 and 15 and Comparative Example 2. 
         FIG. 9A  shows a topography image after forming an emission layer according to Comparative Example 1. 
         FIG. 9B  shows a topography image after forming an emission layer according to Example 7. 
         FIG. 9C  shows a topography image after forming an emission layer according to Example 9. 
         FIG. 10A  is a photograph showing light emission of a device of Comparative Example 2. 
         FIG. 10B  is a photograph showing light emission of a device of Example 14. 
     
    
    
     DESCRIPTION OF REFERENCE NUMERALS INDICATING PRIMARY ELEMENTS IN THE DRAWINGS 
     
         
         
           
               11 : substrate  12 : anode 
               13 : hole transport layer (HTL)  14 : organic emission layer 
               15 : electron transport layer (ETL)  16 : cathode 
           
         
       
    
     DETAILED DESCRIPTION OF THE EMBODIMENTS 
     Exemplary embodiments of the present invention will hereinafter be described in detail. However, these embodiments are only exemplary, and the present invention is not limited thereto but rather is defined by scope of the appended claims. 
     According to one embodiment of the present invention, provided is the organic compound represented by the following Chemical Formula 1: 
     
       
                 
         
             
             
         
      
     
     In the above Chemical Formula 1, 
     X 1  to X 16  are the same or different, and are independently selected from CR′ or N, 
     Ar 1  to Ar 3  are the same or different, and are independently selected from a single bond, a substituted or unsubstituted C6 to C30 arylene group, or a substituted or unsubstituted C2 to C30 heteroarylene group, 
     Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C2 to C30 heteroaryl group, 
     R′ is independently selected from hydrogen, a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to C20 acyloxy group, a substituted or unsubstituted C2 to C20 acylamino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group. 
     In one embodiment, Ar 1  to Ar 3  are the same or different, and are independently selected from a substituted or unsubstituted carbazole, a substituted or unsubstituted arylamine, a substituted or unsubstituted phenyl, a substituted or unsubstituted tolyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted stilbene, a substituted or unsubstituted fluorenyl, a substituted or unsubstituted anthracenyl, a substituted or unsubstituted terphenyl, a substituted or unsubstituted pyrenyl, a substituted or unsubstituted diphenyl anthracenyl, a substituted or unsubstituted dinaphthylanthracenyl, a substituted or unsubstituted pentacenyl, a substituted or unsubstituted bromophenyl, a substituted or unsubstituted hydroxyphenyl, a substituted or unsubstituted thienyl, a substituted or unsubstituted pyridyl, a substituted or unsubstituted azobenzenyl, or a substituted or unsubstituted ferrocenyl. 
     In one embodiment, Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted carbazolyl, a substituted or unsubstituted arylamine, a substituted or unsubstituted phenyl, a substituted or unsubstituted naphthyl, a substituted or unsubstituted anthracenyl, a substituted or unsubstituted fluorene, a substituted or unsubstituted thiophene, a substituted or unsubstituted pyrrole, a substituted or unsubstituted pyridine, a substituted or unsubstituted aryloxadiazole, a substituted or unsubstituted triazole, or a substituted or unsubstituted arylsilane. 
     As used herein, the substituted arylene and substituted heteroarylene respectively refer to an arylene and a heteroarylene substituted with a C1 to C30 alkyl, a halogen, a C1 to C30 haloalkyl, a C6 to C30 aryl, or C2 to C30 heteroaryl. 
     As used herein, the substituted alkyl, substituted alkenyl, substituted aryl, substituted heteroaryl, substituted alkoxy, substituted aryl oxy, substituted hetero oxy, substituted silyl oxy, substituted acyl, substituted alkoxy carbonyl, substituted acyl oxy, substituted acyl amino, substituted alkoxy carbonyl amino, substituted aryloxycarbonylamino, substituted sulfamoyl amino, substituted sulfonyl, substituted alkylthiol, substituted aryl thiol, substituted hetero cycloalkyl thiol, substituted ureide, substituted phosphoric acid amide, and substituted silyl respectively refer to an alkyl, alkenyl, an aryl, a heteroaryl, an alkoxy, an aryl oxy, a heterooxy, a silyl oxy, an acyl, an alkoxy carbonyl, an acyl oxy, an acyl amino, an alkoxy carbonyl amino, an aryloxycarbonylamino, a sulfamoyl amino, a sulfonyl, an alkylthiol, an aryl thiol, a hetero cycloalkyl thiol, a ureide, a phosphoric acid amide, and silyl substituted with C1 to C30 alkyl, a halogen, a C1 to C30 haloalkyl, a C6 to C30 aryl, or a C2 to C30 heteroaryl. 
     As used herein, the substituted carbazole, substituted arylamine, substituted phenyl, substituted tolyl, substituted naphthyl, substituted stilbene, substituted fluorenyl, substituted anthracenyl, substituted terphenyl, substituted pyrenyl, substituted diphenylanthracenyl, substituted dinaphthylanthracenyl, substituted pentacenyl, substituted bromophenyl, substituted hydroxyphenyl, substituted thienyl, substituted pyridyl, substituted azobenzenyl, and substituted ferrocenyl refers to a carbazole, an arylamine, a phenyl, a tolyl, a naphthyl, a stilbene, a fluorenyl, an anthracenyl, a terphenyl, a pyrenyl, a diphenylanthracenyl, a dinaphthylanthracenyl, a pentacenyl, a bromophenyl, a hydroxyphenyl, a thienyl, a pyridyl, an azobenzenyl, and a ferrocenyl substituted with a C1 to C30 alkyl, a halogen, a C1 to C30 haloalkyl, a C6 to C30 aryl, or C2 to C30 heteroaryl. 
     As used herein, the substituted thiophene, substituted pyrrole, substituted pyridine, substituted aryloxadiazole, substituted triazole, and substituted arylsilane refer to a thiophene, a pyrrole, a pyridine, an aryloxadiazole, a triazole and an arylsilane substituted with a C1 to C30 alkyl, a halogen, a C1 to C30 haloalkyl, a C6 to C30 aryl, or C2 to C30 heteroaryl. 
     In the present specification, the term “hetero” refers to one including 1 to 3 heteroatoms selected from nitrogen (N), oxygen (O), sulfur (S), or phosphorus (P), and the remainder being carbon. 
     Ar′ and Ar″ are the same or different, and are independently selected from the substituents of the following Chemical Formulae 2 to 31: 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
     In the above Chemical Formulae 2 to 31, 
     R 1  to R 76  are the same or different, and are independently selected from a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to C40 silyl oxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to C20 acyl oxy group, a substituted or unsubstituted C2 to C20 acyl amino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 aryloxycarbonylamino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 aryl thiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group, 
     n 1 , n 2 , n 4 , n 6 , n 10 , n 21 , n 26 , n 27 , n 35 , n 39 , n 46 , n 47 , n 49 , n 53 , n 59 , n 61 , and n 62  are the same or different, and are independently integers ranging from 0 to 5, 
     n 3 , n 5 , n 7 , n 8 , n 11 , n 12 , n 16 , n 22 , n 23 , n 29 , n 30 , n 31 , n 33 , n 36 , n 37 , n 40 , n 41  to n 44 , n 48 , n 50  to n 52 , n 54 , n 55 , n 57 , n 56 , n 60 , n 63 , n 65 , n 67 , n 68 , n 69 , n 70 , and n 71  are the same or different, and are independently integers ranging from 0 to 4, 
     n 9 , n 13 , n 14 , n 18 , n 19 , n 20 , n 25 , n 28 , n 32 , n 34 , n 38 , n 45 , n 58 , and n 66  are the same or different, and are independently integers ranging from 0 to 3, and 
     n 15  and n 24  are the same or different, and are independently integers ranging from 0 to 2. 
     Ar′ and Ar″ are the same or different and independently a substituent selected from the following Chemical Formulae B-1 to B-9. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
     
     The compound represented by the above Chemical Formula 1 may be one of the compounds represented by the following Chemical Formulae 32 to 37. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
     
     In the above Chemical Formulae 32 to 37, 
     X 1  to X 16  are the same or different, and are independently selected from 
     CR′ or N, 
     Ar′ and Ar″ are the same or different, and are independently selected from a substituted or unsubstituted C6 to C30 aryl group, or a substituted or unsubstituted C2 to C30 heteroaryl group, 
     R 5  to R 7  and R′ are the same or different, and are independently selected from hydrogen, a halogen, a cyano group, a hydroxyl group, an amino group, a nitro group, a carboxyl group, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C2 to C20 alkenyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heteroaryl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C6 to C20 aryloxy group, a substituted or unsubstituted C2 to C20 heterooxy group, a substituted or unsubstituted C3 to 
     C40 silyloxy group, a substituted or unsubstituted C1 to C20 acyl group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl group, a substituted or unsubstituted C2 to C20 acyloxy group, a substituted or unsubstituted C2 to C20 acylamino group, a substituted or unsubstituted C2 to C20 alkoxy carbonyl amino group, a substituted or unsubstituted C7 to C20 acyloxy carbonyl amino group, a substituted or unsubstituted C1 to C20 sulfamoyl amino group, a substituted or unsubstituted C1 to C20 sulfonyl group, a substituted or unsubstituted C1 to C20 alkylthiol group, a substituted or unsubstituted C6 to C20 arylthiol group, a substituted or unsubstituted C1 to C20 hetero cycloalkyl thiol group, a substituted or unsubstituted C1 to C20 ureide group, a substituted or unsubstituted C1 to C20 phosphoric acid amide group, or a substituted or unsubstituted C3 to C40 silyl group, and 
     n 5  to n 7  are independently integers ranging from 0 to 5. 
     The compound represented by the above Chemical Formulae 31 to 36 may be the compound represented by the following Chemical Formulae 38 to 126. 
     
       
                 
         
             
             
         
      
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
       
                 
         
             
             
         
       
     
     The above Chemical Formulae 38 to 126 are examples of Chemical Formula 1. The compounds where X 1  to X 16  are N in the above Chemical Formula 1 are not exemplified. 
     The organic compounds may be prepared using a generally-used preparation method of organic compounds without limitation. In one embodiment, the preparation method may be Yamamoto reactions, Suzuki reactions, Stille reactions, Ullman reactions, or so on. 
     Reaction temperatures, reaction solvents, and reaction times of the preparation method can be adjusted to provide the above organic compounds. 
     Another embodiment of the present invention provides an organic photoelectric device that includes an organic layer including the above-described organic compounds between a pair of electrodes. In one embodiment, the organic photoelectric device may be an organic light emitting diode. 
     The organic layer may be an emission layer, a hole injection layer (HIL), a hole transport layer (HTL), an electron transport layer (ETL), an electron injection layer (EIL), an interlayer, and a hole blocking layer. In another embodiment, the emission layer is appropriate for the organic layer. 
     The organic photoelectric device may further selectively include an interlayer, a hole transport layer (HTL), and an electron transport layer (ETL) as well as a basic device structure of anode/emission layer/cathode. 
       FIG. 1  is a cross-sectional schematic view of the organic photoelectric device  1  according to one embodiment.  FIG. 1  shows an organic photoelectric device including a substrate  11 , an anode  12 , a hole transport layer (HTL)  13 , an emission layer  14 , an electron transport layer (ETL)  15 , and a cathode  16 . 
     Referring to  FIG. 1 , the organic photoelectric device may be fabricated using the organic compounds as follows. 
     First, an anode  12  material is coated on an upper side of the substrate  11 . 
     The substrate  11  is a glass substrate or a transparent plastic substrate having excellent general transparence, face smoothness, handling ease, and water repellency. 
     The anode  12  material may include transparent and highly conductive indium tin oxide (ITO), tin oxide (SnO 2 ), zinc oxide (ZnO), or so on. 
     Then, a hole transport layer (HTL)  13  is disposed on the anode  12  using vacuum deposition, sputtering, or spin coating, and an emission layer  14  is disposed on the hole transport layer (HTL)  13  using vacuum deposition, or a solution coating method such as spin coating, Inkjet printing, and so on. 
     An electron transport layer (ETL)  15  is disposed between the emission layer  14  and a cathode  16 . 
     The emission layer  14  has a thickness ranging from 5 nm to 1 μm, and preferably 10 to 500 nm, and the hole transport layer (HTL)  13  and electron transport layer (ETL)  15  respectively have a thickness ranging from 10 to 10,000 Å. 
     The electron transport layer (ETL)  15  is formed using vacuum deposition, sputtering, or spin coating of generally-used electron transport layer (ETL)  15  materials. 
     The hole transport layer (HTL)  13  and electron transport layer (ETL)  15  play roles of efficiently transporting a carrier to the emission layer  14  to heighten light emitting recombination in the emission layer  14 . 
     The hole transport layer (HTL)  13  material includes, but is not limited to, poly(3,4-ethylenedioxy-thiophene) (PEDOT) doped with poly(styrenesulfonic acid) (PSS), and N,N′-bis(3-methylphenyl)-N,N-diphenyl-[1,1 1 -biphenyl]-4,4′-diamine (TPD). 
     The electron transport layer (ETL)  15  material includes, but is not limited to, aluminum trihydroxyquinoline (Alq 3 ), a 1,3,4-oxadiazole derivative such as 2-(4-biphenylyl-5-phenyl-1,3,4-oxadiazole (PBD), a quinoxaline derivative such as 1,3,4-tris[(3-phenyl-6-trifluoromethyl)quinoxalin-2-yl]benzene (TPQ), and a triazole derivative. 
     The organic compound may be mixed with a phosphorescent light emitting organic compound. The phosphorescent organic compound may be a phosphorescent light emitting organic metal complex from its triplet state, and is preferably a metal complex of at least one group VIII metal ion according to the periodic table of Gregor Johann Mendel. The group VIII metal ion includes a metal ion selected from Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, and Pt, and is preferably Ir or Pt. 
     Examples of the metal complex may be represented by the following 
     Chemical Formulae 127 to 129, but are not limited thereto. 
     
       
                 
         
             
             
         
      
     
     When the organic layer including the organic compound is formed using a solution coating, another low molecular host material can be included along with the organic compound. Examples of the low molecular host material include the compound of the following Chemical Formulae 130 to 133, but are not limited thereto. 
     
       
                 
         
             
             
         
      
     
     The organic compound may be used by mixing with polymers having conjugated double bonds such as fluorene-based polymers, polyphenylenevinylene-based polymers, and polyparaphenylene-based polymers, and also by mixing with binder resins. 
     The binder resins may include polyvinylcarbazole (PVK), polycarbonate, polyester, polyarylate, polystyrene, acryl polymers, methacryl polymers, polybutyral, polyvinylacetal, diallylphthalate polymers, phenol resins, epoxy resins, silicone resins, polysulfone resins, or urea resins, and these resins can be used singularly and in combinations. 
     Selectively, a hole blocking layer may be disposed using vacuum deposition to limit a transport speed of holes into the emission layer  14  and thus to increase recombination opportunity of electrons and holes. 
     A cathode  16  material is coated on the electron transport layer (ETL)  15 . 
     The cathode material may be lithium (Li), magnesium (Mg), calcium (Ca), aluminum (Al), Al:Li, Ba:Li, or Ca:Li having a small work function. 
     Hereinafter, the embodiments are illustrated in more detail with reference to examples. However, the following are exemplary embodiments and are not limiting. 
     A person having ordinary skills in this art can sufficiently understand parts of the present invention that are not specifically described. 
     EXAMPLE 1 
     Synthesis of M-1 
     
       
                 
         
             
             
         
      
     
     6.0 g (17.79 mmol) of 9-(3-bromophenyl)-9-H-fluorene-9-ol (A) and 2.13 g (7.11 mmol) of 9-(4-tert-butylphenyl)9-H-carbazole (B) were dissolved in 40 mL of dichloromethane under a nitrogen atmosphere, and 3 mL of a boron trifluoride diethylether complex (BF 3 .OEt 2 ) was slowly added thereto in a dropwise fashion. The mixture was agitated at room temperature for 12 hours, and 50 mL of water was added thereto, completing the reaction. The reactant was extracted with dichloromethane and washed four times. The extraction solution was dried with anhydrous magnesium sulfate. Then, the solvent in the dried solution was removed under reduced pressure. The resulting product was purified through silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 1:3, obtaining 5 g (56.2%) of white M-1. 
     EXAMPLE 2 
     Synthesis of M-2 
     
       
                 
         
             
             
         
      
     
     6.0 g (17.79 mmol) of 9-(4-bromophenyl)-9-H-fluorene-9-ol (C) and 2.13 g (7.11 mmol) of (9-(4-tert-butylphenyl)-9-H-carbazole) (B) were dissolved in 40 mL of dichloromethane under a nitrogen atmosphere, and 3 mL of a boron trifluoride diethylether complex (BF 3 .OEt 2 ) was slowly added thereto in a dropwise fashion. The mixture was agitated at room temperature for 12 hours, and 50 mL of water was added thereto, completing the reaction. The reactant was extracted with dichloromethane and washed four times. The extraction solution was dried with anhydrous magnesium sulfate. Then, the solvent was removed from the dried solution under reduced pressure. The resulting product was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 2:3, obtaining 5.0 g (75%) of white M-2. 
     EXAMPLE 3 
     Synthesis of M-3 
     
       
                 
         
             
             
         
      
     
     3.0 g (8.89 mmol) of 9-(3-bromophenyl)-9-H-fluorene-9-ol (A) and 1.77 g (4.04 mmol) of a material D were dissolved in 50 mL of dichloromethane under a nitrogen atmosphere, and 1.5 mL of a boron trifluoride diethylether complex (BF 3 .OEt 2 ) was slowly added thereto in a dropwise fashion. The mixture was agitated at room temperature for 12 hours, and 50 mL of water was added thereto, completing the reaction. The reactant was extracted and washed four times with dichloromethane. The extraction solution was dried with anhydrous magnesium sulfate. Then, the solvent was removed from the dried solution under reduced pressure. The resulting product was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 1:2, obtaining 3.3 g (75.8%) of white M-3. 
     EXAMPLE 4 
     Synthesis of M-4 
     
       
                 
         
             
             
         
      
     
     3.0 g (8.89 mmol) of 9-(4-bromophenyl)-9-H-fluorene-9-ol and 1.77 g (4.04 mmol) of a material D were dissolved in 50 mL of dichloromethane under a nitrogen atmosphere, and 1.5 mL of a boron trifluoride diethylether complex (BF 3 .OEt 2 ) was slowly added thereto in a dropwise fashion. The mixture was agitated at room temperature for 12 hours, and 50 mL of water was added thereto, completing the reaction. The reactant was extracted with dichloromethane and washed four times with water. The extraction solution was dried with anhydrous magnesium sulfate. The solution was removed from the resulting solution under reduced pressure. The resulting product was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 1:2, obtaining 3.0 g (69%) of white M-4. 
     EXAMPLE 5 
     Synthesis of M-5 
     
       
                 
         
             
             
         
      
     
     4.11 g (7.37 mmol) of a material E and 2.0 g (3.35 mmol) of a material F were dissolved in 40 mL of dichloromethane under a nitrogen atmosphere, and 1.5 mL of a trifluoride diethylether complex (BF 3 .OEt 2 ) was slowly added thereto in a dropwise fashion. The mixture was agitated at room temperature for 12 hours, and 50 mL of water was added thereto, completing the reaction. The reactant was extracted with dichloromethane and washed four times with water. The extraction solution was dried with anhydrous magnesium sulfate. Then, the solvent was removed from the dried solution under reduced pressure. The resulting product was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 1:2, obtaining 4.1 g (73%) of white M-5. 
     EXAMPLE 6 
     Synthesis of CISH-1 
     
       
                 
         
             
             
         
      
     
     1.2 g (1.27 mmol) of M-1, 1.71 g (3.19 mmol) of a material G (3-(9H-carbazol-9-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole), and 0.06 g (0.05 mmol) of tetrakistriphenylphosphine palladium were dissolved in 30 mL of THF (tetrahydrofuran) in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator, and 15 mL of 20% tetratriethylammonium hydroxide was added thereto. The resulting mixture was refluxed for reaction at 75° C. for 48 hours. 
     When the reaction was complete, the reactant was cooled to room temperature and then extracted several times with methylenechloride and washed several times with water. 
     Then, the reactant was treated with anhydrous magnesium sulfate to remove moisture. After the resulting product was filtered, the solvent was removed. 
     The reactant without the solvent was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 2:3 and recrystallized in a mixed solvent of methylenechloride/hexane, obtaining 1.49 g (73.3%) of white CISH-1. This material had a maximum light emitting wavelength of 365 nm in a chloroform solution. 
     EXAMPLE 7 
     Synthesis of CISH-2 
     
       
                 
         
             
             
         
      
     
     1.2 g (1.27 mmol) of M-2, 1.71 g (3.19 mmol) of a material G (3-(9H-carbazol-9-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole, and 0.06 g (0.05 mmol) of tetrakistriphenylphosphinepalladium were dissolved in 30 mL of THF (tetrahydrofuran) in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator under an argon atmosphere, and 15 mL of 20% tetratriethylammonium hydroxide was added thereto. The resulting mixture was refluxed for reaction at 75° C. for 48 hours. 
     When the reaction was complete, the reactant was cooled to room temperature and extracted several times with methylenechloride, and was also washed several times with water. 
     Then, the washed reactant was treated with anhydrous magnesium sulfate to remove moisture. After the resulting product was filtered, the solvent was removed therefrom. 
     The reactant with no solvent was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 2:3 and recrystallized in a mixed solvent of methylenechloride/hexane, obtaining 1.6 g (78.8%) of white CISH-2. This material had a maximum light emitting wavelength of 363 nm in a chloroform solution. 
     EXAMPLE 8 
     Synthesis of CISH-3 
     
       
                 
         
             
             
         
      
     
     1.2 g (1.27 mmol) of M-2, 2.71 g (3.83 mmol) of a material H, 0.37 g (3.81 mmol) of sodium tert-butoxide, 23 mg (0.025 mmol) of Pd(dba) 2 , and 7.7 mg (0.038 mmol) of P(t-Bu) 3  were dissolved in 60 mL of anhydrous toluene in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator under an argon atmosphere. The mixture was refluxed for reaction at 75° C. for 48 hours. 
     When the reaction was complete, the reactant was cooled to room temperature and extracted several times extracted with toluene, and was also washed several times with water. 
     Then, the reactant was treated with anhydrous magnesium sulfate to remove moisture. After the reactant was filtered, the solvent was removed therefrom. 
     The resulting reactant with no solvent was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 1:2 and recrystallized in a mixed solvent of methylenechloride/acetone, obtaining 1.3 g (47.1%) of white CISH-3. This material had a maximum light emitting wavelength of 443 nm in a chloroform solution. 
     EXAMPLE 9 
     Synthesis of CISH-4 
     
       
                 
         
             
             
         
      
     
     1.2 g (1.11 mmol) of M-3, 1.78 g (3.34 mmol) of a material G (3-(9H-carbazol-9-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole, and 0.06 g (0.05 mmol) of tetraistriphenylphosphinepalladium were dissolved in 30 mL of THF (tetrahydrofuran) in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator under an argon atmosphere, and 15 mL of 20% tetratriethylammonium hydroxide was added thereto. The resulting mixture was refluxed for reaction at 75° C. for 48 hours. 
     When the reaction was complete, the reactant was cooled to room temperature. The reactant was extracted several times with methylenechloride, and was also washed several times with water. 
     Then, the reactant was treated with anhydrous magnesium sulfate to remove moisture. After it was filtered, the solvent was removed therefrom. 
     The reactant with no solvent was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 1:2 and recrystallized a mixed solvent of acetone/hexane, obtaining 1.3 g (68%) of white CISH-4. This material had a maximum light emitting wavelength of 388 nm in a chloroform solution. 
     EXAMPLE 10 
     Synthesis of CISH-5 
     
       
                 
         
             
             
         
      
     
     1.2 g (1.11 mmol) of M-4, 1.78 g (3.34 mmol) of a material G (3-(9H-carbazol-9-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole, and 0.06 g (0.05 mmol) of tetrakistriphenylphosphinepalladium were dissolved in 30 mL of THF (tetrahydrofuran) in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator under an argon atmosphere, and 15 mL of 20% tetratriethylammonium hydroxide was added thereto. The resulting mixture was refluxed for reaction at 75° C. for 48 hours. 
     When the reaction was complete, the reactant was cooled to room temperature and then extracted several times with methylenechloride, and was also washed several times with water. 
     Then, the reactant was treated with anhydrous magnesium sulfate to remove moisture. After it was filtered, the solvent was removed therefrom. 
     The reactant with no solvent was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 1:2 and recrystallized in a mixed solvent of acetone/hexane, obtaining 1.35 g (70%) of white CISH-5. This material had a maximum light emitting wavelength of 386 nm in a chloroform solution. 
     EXAMPLE 11 
     Synthesis of CISH-6 
     
       
                 
         
             
             
         
      
     
     1.2 g (0.71 mmol) of M-5, 0.6 g (2.14 mmol) of a material I, and 0.05 g (0.043 mmol) of tetrakistriphenylphosphinepalladium were dissolved in 30 mL of THF (tetrahydrofuran) in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator under an argon atmosphere, and 15 mL of 20% tetratriethylammonium hydroxide was added thereto. The resulting mixture was refluxed for reaction at 75° C. for 48. 
     When the reaction was complete, the reactant was cooled to room temperature and then extracted several times with methylenechloride, and was also washed several times with water. 
     Then, the reactant was treated with anhydrous magnesium sulfate to remove moisture. After it was filtered, the solvent was removed therefrom. 
     The reactant with no solvent was purified through a silica gel column using a solvent of methylenechloride/ethyl acetate mixed in a ratio of 9.8:0.2, obtaining 0.8 g (61.5%) of white CISH-6. This material had a maximum light emitting wavelength of 386 nm in a chloroform solution. 
     EXAMPLE 12 
     Synthesis of CISH-7 
     
       
                 
         
             
             
         
      
     
     1.2 g (0.71 mmol) of M-5, 0.768 g (2.14 mmol) of a material J, and 0.05 g (0.043 mmol) of tetrakistriphenylphosphinepalladium were dissolved in 30 mL of THF (tetrahydrofuran) in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator under an argon atmosphere, and 15 mL of 20% tetratriethylammonium hydroxide was added thereto. The resulting mixture was refluxed for reaction at 75° C. for 48 hours. 
     When the reaction was complete, the reactant was cooled to room temperature and then extracted several times with methylenechloride, and was also washed several times with water. 
     Then, the reactant was treated with anhydrous magnesium sulfate to remove moisture therefrom. After it was filtered, the solvent was removed therefrom. 
     The reactant with no solvent was purified through a silica gel column using a solvent of THF/ethylacetate mixed in a ratio ranging from 1:9 to 3:7, obtaining 0.5 g (35.4%) of white CISH-7. This material had a maximum light emitting wavelength of 387 nm in a chloroform solution. 
     EXAMPLE 13 
     Synthesis of CISH-8 
     
       
                 
         
             
             
         
      
     
     1.2 g (0.71 mmol) of M-5, 0.95 g (1.78 mmol) of a material G (3-(9H-carbazol-9-yl)-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)-9H-carbazole, and 0.05 g (0.043 mmol) of tetrakistriphenylphosphinepalladium were dissolved in 30 mL of THF (tetrahydrofuran) in a 250 ml round flask with a thermometer, a reflux condenser, and an agitator, and 15 mL of 20% tetratriethylammonium hydroxide was added thereto. The resulting mixture was refluxed for reaction at 75° C. for 48 hours. 
     When the reaction was complete, the reactant was cooled to room temperature and then extracted several times with methylenechloride, and was also washed several times with water. 
     Then, the reactant was treated with anhydrous magnesium sulfate to remove moisture. After it was filtered, the solvent was removed therefrom. 
     The reactant with no solvent was purified through a silica gel column using a solvent of methylenechloride/hexane mixed in a ratio of 2:3 and recrystallized with a mixed solvent of acetone/hexane, obtaining 0.9 g (54%) of white CISH-8. This material had a maximum light emitting wavelength of 386 nm in a chloroform solution. 
     COMPARATIVE EXAMPLE 1 
     Synthesis of a Compound Represented by the Following Chemical Formula 127 
     
       
                 
         
             
             
         
      
     
     The compound of the above Chemical Formula 127 was synthesized according to the method described with reference to Organic Letters, 2006, 8, 2779. 
     Performance Evaluation of the Prepared Organic Compounds 
     The CISH-2 of Example 7 was measured regarding  1 H-NMR using Bruker 300 MHz®. The result is shown in  FIG. 2 . Referring to  FIG. 2 , the organic compound of Example 7 was identified as CISH-2. 
     In addition, the CISH-2 was used to form a thin film on a glass substrate and measured regarding photoluminescence (PL) wavelength using a HITACHI F-4500®. The result is shown in  FIG. 3 . Referring to  FIG. 3 , the CISH-2 was found to have a maximum light emitting wavelength of 368 nm, when it was made into a thin film. 
     Fabrication of an Organic Photoelectric Device 
     EXAMPLE 14 
     Fabrication of a Device Using Example 7 (CISH-2) 
     An ITO substrate was used as an anode, and poly(3,4-ethylenedioxy-thiophene) (PEDOT) was spin-coated thereon. 
     Next, an emission layer was formed on the PEDOT by doping Ir(mppy) 3  in an amount of 6 to 7% as a dopant into CISH-2. 
     Then, a 50 Å-thick hole-blocking layer was formed by vacuum-depositing BAlq on the emission layer. 
     Then, a 200 Å-thick electron transport layer (ETL) was formed on the emission layer by vacuum-depositing Alq 3 . 
     Subsequently, LiF 10 Å and Al 1000 Å were sequentially vacuum-deposited on the electron transport layer (ETL) to form a cathode, completing an organic photoelectric device. 
     As for a comparison reference device structure, PVK was used as a polymer host. 
     Herein, an evaluation device structure included Al 1000 Å/LiF 10 Å/Alq 3  200 Å/BAlq 50 Å/EML (CISH-2+Ir(mppy) 3 )/PEDOT/ITO 1500 Å. A comparison reference device structure included Al 1000 Å/LiF 10 Å/Alq 3  200 Å/BAlq 50 Å/EML (PVK+Ir(mppy) 3 )/PEDOT/ITO 1500 Å. 
     EXAMPLE 15 
     Fabrication of a Device Using Example 9 (CISH-4) 
     An organic photoelectric device was fabricated using the same method as Example 14, except that CISH-4 was used instead of CISH-2 as a compound of an emission layer. 
     COMPARATIVE EXAMPLE 2 
     Fabrication of a Device Using Comparative Example 1 
     An organic photoelectric device was fabricated using the same method as Example 14, except that a compound of Comparative Example 1 was used instead of CISH-2 as a compound of an emission layer. 
     COMPARATIVE EXAMPLE 3 
     Fabrication of a Device Using poly(9-vinylcarbazole) 
     An organic photoelectric device was fabricated using the same method as Example 14, except that poly(9-vinylcarbazole) was used instead of CISH-2 as a compound of an emission layer. 
     Performance Evaluation of the Organic Photoelectric Device 
     The organic photoelectric device of Example 14 was measured regarding output efficiency and luminance changes depending on voltage change. The results are respectively shown in  FIGS. 4 and 5 . 
     In addition, its threshold voltage, driving voltage, current efficiency, and electrical power efficiency at 1000 nit were measured. The results are shown in the following Table 1. 
     
       
         
               
               
             
               
               
               
               
               
             
               
               
               
               
               
               
             
           
               
                   
                 TABLE 1 
               
             
             
               
                   
                   
               
               
                   
                 At 1000 nit 
               
             
          
           
               
                   
                   
                   
                   
                 Electrical 
               
               
                   
                 Threshold 
                 Driving 
                 Current 
                 power 
               
               
                   
                 voltage 
                 voltage 
                 efficiency 
                 efficiency 
               
               
                 Device 
                 (V) 
                 (V) 
                 (cd/A) 
                 (lm/W) 
               
               
                   
               
             
          
           
               
                 Green 
                 Comparative 
                 2.8 
                 7.2 
                 4.75 
                 2.07 
               
               
                   
                 Example 3 
               
               
                   
                 Example 14 
                 2.8 
                 7.4 
                 6.58 
                 2.79 
               
               
                   
               
             
          
         
       
     
     Referring to  FIGS. 4 and 5  and Table 1, an organic compound of the present invention can be used as a host material for an organic photoelectric device. 
     (Measurement of Characteristics of Compound) 
     DSC, TGA of the compounds of Examples 7 and 9, and Comparative Example 1 were measured, and the glass transition temperature, the decomposition temperature, the melting point, and the triplet exciton energy level were compared. 
       FIG. 6A  shows the result of differential scanning calorimetry (DSC) of Example 7, and  FIG. 6B  shows the result of a thermogravimetric analysis (TGA) of Example 7. 
       FIG. 7A  shows the result of DSC of Example 10, and  FIG. 7B  shows the result of a TGA of Example 10. 
     The results of  FIGS. 6A ,  6 B,  7 A, and  7 B are as shown in the following Table 2. 
     
       
         
               
               
               
               
               
             
           
               
                   
                 TABLE 2 
               
               
                   
                   
               
               
                   
                 Material 
                 Tg 
                 Tm 
                 Td 
               
               
                   
                   
               
             
             
               
                   
                 Comparative Example 1 
                 171 
                 328 
                 429 
               
               
                   
                 Example 7 
                 278 
                 N.D 
                 561 
               
               
                   
                 Example 9 
                 236 
                 N.D 
                 560 
               
               
                   
                   
               
               
                   
                 Tg: glass transition temperature 
               
               
                   
                 Tm: melting point 
               
               
                   
                 Td: decomposition temperature 
               
               
                   
                 N.D: Not determined 
               
             
          
         
       
     
     The thermal property data of the compound of Comparative Example 1 is referred to with reference to Chinese Patent Laid-Open Publication No. CN1769269 A. 
     As shown in Table 2, Examples 7 and 9 have remarkably improved thermal properties compared with Comparative Example 1. 
     The thermal stability of a compound as a material remarkably affects the life-span of a device, and as a person of ordinary skill in the art can understand this, a device prepared according to Examples 7 and 9 is expected to have an excellent life-span compared to a device prepared according to Comparative Example 1. 
     (Evaluation of Efficiency of Organic Photoelectric Device) 
     Efficiency of the organic photoelectric devices according to Examples 14 and 15 and Comparative Example 2 were evaluated. The results are shown in  FIGS. 8A and 8B . 
       FIG. 8A  shows luminous efficiency data of Examples 14 and 15 and Comparative Example 2, and  FIG. 8B  shows electrical power efficiency data of Examples 14 and 15 and Comparative Example 2. 
     As for Comparative Example 2, the material used did not have a bulky structure without a substituent, and since the device was prepared with the material through a solution process, the thin film characteristics were poor, and the device characteristics were remarkably deteriorated due to low thermal stability. 
     However, the device prepared according to Examples 14 and 15 had remarkably increased thermal stability and thin film characteristics because the material used had a bulky structure including a hetero aryl at the terminal end, and had increased molecular weight, and therefore it had excellent device characteristics. 
     (Evaluation of Thin Film Characteristics) 
     The compounds of Comparative Example 1 and Examples 7 and 9 were used to form an emission layer of an organic photoelectric device through a solution process, and the surfaces of the prepared layers were compared with an atomic force microscope (AFM). 
       FIG. 9A  shows a topography image of an emission layer according to Comparative Example 1,  FIG. 9B  shows a topography image of an emission layer according to Example 7, and  FIG. 9C  shows a topography image of an emission layer according to Example 9. 
     Rq was surface roughness measured with the AFM. 
     
       
         
               
               
               
             
           
               
                   
                 TABLE 3 
               
               
                   
                   
               
               
                   
                 Compound 
                 Rq (nm) 
               
               
                   
                   
               
             
             
               
                   
                 Comparative Example 1 
                 0.876 
               
               
                   
                 Example 7 
                 0.520 
               
               
                   
                 Example 9 
                 0.645 
               
               
                   
                   
               
             
          
         
       
     
     The compounds of Examples 7 and 9 are suitable materials for an organic photoelectric device for a solution process, and as shown in Table 3, when an emission layer is formed through a solution process using the compounds, it has low Rq which is surface roughness. 
     A low Rq refers to low surface roughness indicating that the surface may be formed very uniformly. 
     As a result of crystallinity of a resulting material, Comparative Example 1 having a light molecular weight has bad surface roughness of an emission layer due to crystallization of a compound through a solution process. 
     As shown in Table 3, Examples 7 and 9 have superb molecular weight compared with Comparative Example 1 because they have a structure including a heteroaryl substituent at the terminal end thereof, and the substituent prevents crystallization of a compound and recrystallization after a solution process does not occur. The benefit not only accrues because of the molecular weight of Examples 7 and 9, but also because of low tacticity of the compound. 
     Therefore, as shown in Table 3, the surface roughness of Examples 7 and 9 is low. 
     When the surface roughness is increased the device characteristics are remarkably decreased, as is well known to a person of ordinary skill in the art. 
     It is therefore absolutely expected that the organic photoelectric device prepared according to Examples 7 and 9 may have excellent device characteristics compared to the organic photoelectric device prepared according to Comparative Example 1. 
     (Evaluation of Optical Characteristics of Organic Photoelectric Device) 
     Optical characteristics of the organic photoelectric devices according to Example 14 and Comparative Example 2 were evaluated. 
       FIG. 10A  shows a light emission photograph of the device of Comparative Example 2, and  FIG. 10B  shows a light emission photograph of the device of Example 14. 
     As shown in the photographs of  FIGS. 10A and 10C , when the compound of Comparative Example 1 that is a compound of the emission layer of Comparative Example 2 is formed as a thin film with a dopant during a solution process, it has a light molecular weight as well as a firm structure, and therefore it is easily recrystallized during thin film conditions. 
     The recrystallization of a host used for an emission layer causes non-uniform light emission and shortens the life-span of a device. 
     The device of Example 14 using the compound of Example 7 shows very uniform light emission. Therefore, recrystallization is remarkably decreased. 
     The present invention is not limited to the embodiments illustrated with the drawings and table, but can be fabricated into various modifications and equivalent arrangements included within the spirit and scope of the appended claims by a person who is ordinarily skilled in this field. Therefore, the aforementioned embodiments should be understood to be exemplary but not limiting the present invention in any way.