Abstract:
A novel application of a transition metal oxo complex, a cationic oxorhenium(V) oxazoline, in the production of molecular hydrogen (H 2 ) from the catalytic hydrolytic oxidation of organosilanes. The reaction is characterized by quantitative hydrogen yields, low catalyst loading, ambient conditions, high selectivity for silanols, water as the only co-reagent, and no solvent requirement. The amount of hydrogen produced is proportional to the water stoichiometry. For example, reaction mixtures of polysilyl organics such as HC(SiH 3 ) 3  and water contain potentially greater than 6 weight percent hydrogen. Kinetic and isotope labeling experiments reveal a new mechanistic paradigm for the activation of Si—H bonds by oxometalates.

Description:
RELATED APPLICATIONS 
       [0001]    This application claims priority to U.S. Provisional Application Ser. No. 60/710,666 filed Aug. 23, 2005. 
     
    
     BACKGROUND 
       [0002]    The present invention generally relates to processes for producing hydrogen and more particularly to producing catalytic and recyclable hydrogen (H 2 ) by oxidizing organic silanes. 
         [0003]    Renewable energy sources have been sought for decades to replace fossil fuels. The interest in hydrogen utilization as a fuel has intensified recently because its use in fuel cells produces water and heat as the only byproducts. Currently, the most efficient method for obtaining hydrogen involves the combustion of methane and other hydrocarbons; however, these energy sources are nonrenewable in nature. While finding an inexpensive and renewable source of hydrogen poses a significant scientific challenge, moving toward a hydrogen-based economy requires that the problems associated with hydrogen storage, transport, and delivery be addressed. If hydrogen fuel cells are to become commonplace, it would be desirable to develop a practical process for handling the on-board storage and delivery of hydrogen to fuel cells. None of the currently available hydrogen storage options, viz., liquefied or high-pressure H 2  gas, metal hydrides, etc., satisfies criteria of size, cost, kinetics, and safety for use in transportation. 
       SUMMARY OF THE INVENTION 
       [0004]    The present invention provides a method for the production of hydrogen on demand and under kinetic control from organic liquid, using only water as co-reagent. The inventive method represents a new paradigm for the use of high-valent oxometalate catalysts in dehydrogenative oxidations with water. In exemplary embodiments, hydrogen gas is produced under ambient conditions from catalytic hydrolytic oxidation of organosilanes using an oxorhenium(V) oxazoline coordination complex. It has been found that the yield of hydrogen is proportional to the water stoichiometry. Advantageously, the costs of the organosilanes used in the method can be offset by efficiently recycling the valuable organic silicon byproducts produced in the inventive method. 
     
    
     
       BRIEF DESCRIPTION OF DRAWINGS 
         [0005]    The above-mentioned aspects of the present invention and the manner of obtaining them will become more apparent and the invention itself will be better understood by reference to the following description of the embodiments of the invention taken in conjunction with the accompanying drawings, wherein: 
           [0006]      FIG. 1  is a chromatogram of an aliquot sample analyzed under GC/MS procedures in accordance with the present invention; 
           [0007]      FIG. 2  is a mass spectrum of triethylsilanol obtained under GC/MS procedures in accordance with the present invention; 
           [0008]      FIG. 2   a  is the mass spectrum of  FIG. 2  reproduced in smaller scale for comparison to the library mass spectrum of triethylsilanol shown in  FIG. 2   b , in accordance with the present invention; 
           [0009]      FIG. 2   b  is a library mass spectrum of triethylsilanol for comparison with the mass spectrum of  FIG. 2 ; 
           [0010]      FIG. 3  is a mass spectrum of hexaethyldisiloxane obtained under GC/MS procedures in accordance with the present invention; 
           [0011]      FIG. 3   a  is the mass spectrum of  FIG. 3  reproduced in smaller scale for comparison to the library mass spectrum of hexaethyldisiloxane shown in  FIG. 3   b;    
           [0012]      FIG. 3   b  is a library mass spectrum of hexaethyldisiloxane for comparison with the mass spectrum of  FIG. 3   a  in accordance with the present invention; 
           [0013]      FIG. 4  depicts  1 H NMR spectrum of triethylsilane in accordance with the present invention; 
           [0014]      FIG. 5  depicts  1 H NMR spectrum of the products of a catalytic reaction of triethylsilane with water, namely, triethylsilanol and hexaethyldisiloxane in accordance with the present invention; 
           [0015]      FIG. 6  depicts  1 H NMR spectrum of the products triethylsilanol and hexaethylsiloxane in accordance with the present invention; 
           [0016]      FIG. 7  depicts  1 H NMR spectrum of the reaction solution at the conclusion of H 2  evolution from the hydrolytic oxidation of methyldiphenylsilane with 1.0 mol % Re catalyst in accordance with the present invention; 
           [0017]      FIG. 8  depicts  1 H NMR spectrum of the reaction solution at the conclusion of H 2  evolution from the alchololysis of triethylsilane with 1 mol % Re catalyst and EtOH in accordance with the present invention; 
           [0018]      FIG. 9  depicts a time profile showing hydrogen evolution using electron impact mass spectrometry for the reaction of Me 2 EtSiH and water catalyzed by oxorhenium; 
           [0019]      FIG. 10  depicts a typical kinetic profile obtained by  1 H NMR spectrum for oxorhenium catalyzed hydrolytic oxidation of organosilanes; 
           [0020]      FIG. 11   a  depicts an MS-ESI +  spectrum of [Re(O)(hoz) 2 ] + ; 
           [0021]      FIG. 11   b  depicts an MS-ESI +  spectrum of [R e 18O(hoz) 2 ] +  (84%  18 O-enriched); 
           [0022]      FIG. 12  depicts an MS-ESI +  spectrum of an isotope labeling experiment with  18 OH 2 , showing both [Re(O)(hoz) 2 ] +  and reduced [Re(hoz) 2 ] + ; and 
           [0023]      FIG. 13  depicts  29 Si NMR spectrum (in CDCl 3 ) for the reaction products of diphenylsilane (Ph 2 SiH 2 ) and shows the diol Ph 2 Si(OH) 2  (δ −31.3) and silanol Ph 2 SiH(OH) (δ −38.4). TMS was used as an internal reference (δ 0.00). 
       
    
    
     DETAILED DESCRIPTION 
       [0024]    The embodiments of the present invention described below are not intended to be exhaustive or to limit the invention to the precise forms disclosed in the following detailed description. Rather, the embodiments are chosen and described so that others skilled in the art may appreciate and understand the principles and practices of the present invention. 
         [0025]    The present disclosure relates to processes for producing (on demand) catalytic and recyclable hydrogen (H 2 ) from the hydrolytic oxidation of organic silanes. In one exemplary embodiment, a cationic oxorhenium(V) oxazoline complex catalyzes the production of hydrogen from a reaction of organosilanes and water. (See formula 1 listed below). According to this embodiment, the reaction utilizes about 0.1 to about 5 mol % of catalyst and is conducted in an organic solvent, such as, but not limited to acetonitrile, benzene and dichloromethane and is not sensitive to moisture or air. While a solvent is used according to this exemplary embodiment, those skilled in the art will appreciate that the reactions can also be run neat, in the absence of solvent. 
         [0026]    The organic byproduct produced according to formula 1, below, is silanol, and the reaction is slightly exothermic and capable of being completed in a matter of minutes under ambient conditions. 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    The Rhenium Catalyst can be prepared from the chloride precursor, Re(O)(hoz) 2 Cl via halide abstraction by the silylium cation Et 3 Si +  (Et is used to signify an ethyl group) produced from the reaction of silane (Et 3 SiH) and [Ph 3 C][B(C 6 F 5 ) 4 ] (Ph is used to signify a phenyl group). This synthetic strategy is convenient because it allows in situ generation of the active catalyst from the precursor. The precursor is stable for years under ambient conditions. Alternatively, the Rhenium Catalyst may be prepared in advance, ex situ. The structure of the Rhenium Catalyst is shown below: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    Although reference is made to “the Rhenium Catalyst” listed above, one of skill in the art would appreciate that variations of the Rhenium catalyst are possible. For example, the phenoxide and/or oxazoline ligand may include alkyl, aryl or halide, etc. substituents. Further, instead of the phenoxide and oxazoline components in the Rhenium catalyst of the above formula, the ligand can be in the form of bisoxazoline and diamidato ligands. Schiff base ligands (salen-type ligands), bidentate as well as tetradentate, are also possible and examples of these are as follows: 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    See Ison, J. E. Cessarich, G. Du, P. E. Fanwick, and M. M. Abu-Omar Inorg. Chem. 2006, 45, 2385-2387). Further, the phenoxide ring of the above Schiff base ligands may include alkyl, aryl or halide, etc. substituents, the bridge may include substituents, and the bridge itself may be varied (e.g., ethyl, propyl, butyl, cyclolhexyl, etc.). Also, one of skill in the art would readily appreciate many variations that may be made to the anion or solvent coordinated molecule. Finally, it has recently been found that catalyst loading can be as little as 0.01 mol %. 
         [0027]    Without wishing to be tied to any specific theory, the described catalytic reaction (see equation 1, above) could be regarded as a “splitting” of water in the stoichiometric sense with organosilane providing the needed energy by forming a Si—O bond: H 2 O→[O]+H 2 . The oxygen atom in brackets, [O], denotes its transfer to silicon, which circumvents the uphill oxygen evolution problem. 
         [0028]    In another exemplary embodiment, the water component described herein can be replaced with an alcohol component such as ethanol, methanol, or phenol. According to this embodiment, the product from the reaction would produce a stable silylether liquid. See formula 1a listed below. According to this embodiment, the reaction utilizes about 0.1 to about 1 mol % of catalyst and is conducted in an organic solvent, such as, but not limited to acetonitrile and is not sensitive to air. While a solvent is used according to this exemplary embodiment, those skilled in the relevant art will appreciate that the reactions described can also be run neat, in the absence of solvent. 
         [0000]    
       
                 
         
             
             
         
       
     
         [0029]    In yet another exemplary embodiment, secondary (R 2 SiH 2 ) and primary (RSiH 3 ) silanes are utlized to produce silanediol (R 2 Si(OH) 2 ) and silanetriol (RSi(OH) 3 ), respectively, and increase the yield of hydrogen per silane equivalent relevant to tertiary silanes. As is appreciated by those of ordinary skill within the relevant art, both silanediols (R 2 Si(OH) 2 ) and silanetriols (RSi(OH) 3 ) are valuable by-products that may be used for making silicone polymers, among other things. 
         [0030]    One relevant difference between tertiary (R 3 SiH), secondary (R 2 SiH 2 ), and primary (RSiH 3 ) silanes is the number of hydrogen atoms in the molecule. Each hydrogen atom provides a potential location for hydrolytic oxidation, and each hydrolytic oxidation reaction produces one molecule of H 2  gas. Therefore secondary silanes, which have 2 hydrogen atoms, and primary silanes, which have 3 hydrogen atoms, have the capacity to generate more hydrogen gas per silane molecule than tertiary silanes, which have only 1 hydrogen atom. The total volume of reactants required is important to the portability of the fuel, and therefore to the utility of the system in mobile applications, such as hydrogen fuel cells for automobiles. The different amounts of silane required to produce 3.0 kg H 2  using tertiary, secondary, primary and polysilyl silanes illustrated below for four reactions, equations 2-5. Three (3.0) kg of H 2  represents a benchmark quantity for storage in automotive applications. See T-Raissi, A.; Block, D. L. “Hydrogen: Automotive Fuel of the Future,” IEEE Power &amp; Energy, November-December 2004. pg. 40-45. 
         [0000]      Et 3 SiH+H 2 O→Et 3 Si(OH)+H 2   (2) 
         [0031]    To produce 3.0 kg H 2  (1488 moles), 173 kg (238 L or 63 gal) of Et 3 SiH and 27 kg (27 L or 7 gal) of water are needed. 
         [0000]      Et 2 SiH 2 +2H 2 O→Et 2 Si(OH) 2 +2H 2   (3) 
         [0032]    By utilizing a secondary silane and producing silanediol, 2 equivalents of H 2  per equivalent silane are produced, wherein the water molar ratio to hydrogen is constant. The molar mass of Et 2 SiH 2  is 88.22 g mol −1  and its density is 0.6837 g mL −1 . Therefore, to produce 3.0 kg H 2 , 66 kg (96 L or 25 gal) of Et 2 SiH 2  and 7 gal of water are needed. According to this embodiment, the total liquid is only 32 gal. 
         [0000]      PhSiH 3 +3H 2 O→PhSi(OH) 3 +3H 2   (4) 
         [0033]    With phenyl silane or other primary silanes, 3 equivalents of H 2  are produced per equivalent silane. Thus, to get 3.0 kg H 2 , only 54 kg (62 L or 16 gal) of PhSiH 3  and 7 gal of water are needed. A total of only 23 gal of liquid (PhSiH 3  plus water) is needed to yield 3.0 kg of H 2 . 
         [0000]      HC(SiH 3 ) 3 +9H 2 O→HC(Si(OH) 3 ) 3 +9H 2   (5) 
         [0034]    With polysilyl silanes, 9 equivalents of H 2  are produced per equivalent silane. Thus, to get 3.0 kg H 2 , only 18 kg (21 L) of HC(SiH 3 ) 3  and 27 L of water are needed. 
         [0035]    Some silyl ether is produced as a side product with triethylsilane. The source of the silyl ether is the silanol, which is known to condense to the ether, as shown in equation 6, below. This latter reaction is catalyzed by the rhenium catalyst. If the catalytic reaction is allowed to stand, the bulk of the silanol converts to the ether. The net stoichiometric reaction is thus described by equation 7, below. 
         [0000]      2Et 3 Si(OH)→Et 3 SiOSiEt 3 +H 2 O  (6) 
         [0000]      2Et 3 SiH+H 2 O→Et 3 SiOSiEt 3 +2H 2   (7) 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
               
               
             
           
               
                 TABLE 1 
               
             
             
               
                   
               
               
                 Rhenium-Catalyzed Production of Hydrogen from Organosilane 
               
             
          
           
               
                   
                 % yield b   
               
             
          
           
               
                 entry 
                 substrate 
                 method a   
                 H 2   
                 —SiOH 
                 —SiOSi— 
               
               
                   
               
               
                 1 
                 Ph 2 MeSiH 
                 A 
                 94 
                 100 
                 0 
               
               
                   
                   
                 B 
                 98 
                 100 
                 0 
               
               
                 2 
                 PhMe 2 SiH 
                      B c   
                 78 
                  (88) d   
                 — 
               
               
                   
                   
                 C 
                 95 
                 — 
                 (70)  
               
               
                 3 
                 Et 3 SiH 
                 A 
                 97 
                  92 
                 8 
               
               
                 4 
                 Et 2 SiH 2   
                 A 
                 72 
                 n.d. e   
                 n.d. 
               
               
                 5 
                 Ph 2 SiH 2   
                 A 
                 82 
                 100 f   
                 0 
               
               
                   
                   
                 B 
                 88 
                 100 f   
                 0 
               
               
                 6 
                 PhSiH 3   
                 A 
                 66 
                 g 
                 g 
               
               
                   
               
               
                   a Method A: 1 mol % 2/[Ph 3 C][B(C 6 F 5 ) 4 ], 1.0 M silane substrate, 2.0-10.0 equiv of H 2 O in CH 3 CN at 20° C. Method B: 1 mol % 1 (isolated catalyst), 1.0 M silane substrate. 2.0-10.0 equiv of H 2 O in CH 3 CN at 20° C. Method C: Neat as a biphasic reaction without solvent; same conditions as method B. 
               
               
                   b Isolated yields for silicon products are reported in parentheses; otherwise, silanol and silyl ether product yields were determined by  29 Si NMR. 
               
               
                   c 0.1 mol % catalyst 1. 
               
               
                   d 95:5 PhMe 2 Si(OH)/(PhMe 2 Si) 2 O. 
               
               
                   e n.d. = not determined. 
               
               
                   f 26% Ph 2 SiH(OH) and 74% Ph 2 Si(OH) 2 . 
               
               
                   g Multiple silicon containing products result. 
               
             
          
         
       
     
         [0036]    Table 1, above, summarizes the representative yields of hydrogen for different organosilanes. The catalytic reactions were carried out at ambient temperature with 1 mol % catalyst loading or less. Reactions reach completion (100% conversion) in less than one hour and give silanol selectively. Even though acetonitrile is used as solvent to maintain homogenous conditions, the reaction proceeds smoothly in the absence of a solvent (see entry 2 in Table 1). Once hydrogen evolution ceases, the initial silicon product is silanol (see  FIG. 10 ), which condenses over time to the silyl ether. However, when the reaction is run neat, the silicon product is silyl ether (see entry 2 in Table 1). Since water inhibits silanol condensation to silyl ether, biphasic conditions reduce the effective concentration of water in the organic phase, resulting in silyl ether. In the case of primary silanes, the initially formed silanol condenses to oligomeric/polymeric siloxanes. See Baney, R. H.; Itoh, M.; Sakakibara, A.; Suzuki, T.  Chem. Rev.  1995, vol. 95, page 1409; and Loy, D. A.; Shea, K. J.,  Chem. Rev.  1995, vol. 95, page 1431. It is worth noting that while secondary silanes afford nearly 2 equivalents of H 2  per silane, primary silanes do not afford the expected 3 equivalents of H 2  (compare entries 5 and 6 in Table 1). Once silanediol is generated, the reactivity of the remaining Si—H bond is reduced. 
         [0037]    Under steady-state conditions, the major catalyst species is the Rhenium Catalyst depicted above (per UV-vis and ESI-MS). When this catalyst is reacted with organosilane in the absence of water, the solution turns red with production of stoichiometric (relative to Re) amounts of hydrogen and silyl ether. See Equation 8, below. 
         [0000]    
       
                 
         
             
             
         
       
     
         [0000]    The reduced red rhenium(III) complex is not believed catalytically relevant. Addition of water and/or air in the presence of excess organosilane does not ensure catalysis. Furthermore, the rate of reduction of catalyst is slower than the rate of the catalytic reaction. Surprisingly, it has been found that other simple oxorhenium complexes such as Re(O)Cl 3 (PPh 3 ) 2 , CH 3 ReO 3  (MTO), [NH 4 ]ReO 4 , and Re(O) 2 I(PPh 3 ) 2  do not catalyze the hydrolytic oxidation of organosilanes. The latter complex is of particular interest because it has been shown to effect hydrosilation of organic carbonyl compounds. See Kennedy-Smith, J. J.; Nolin, K. A.; Gunterman, H. P.; Toste, F. D.  J. Am. Chem. Soc.  2003, 125, 4056. 
         [0038]    One of the advantages for hydrogen storage according to the present invention is the feasibility of recycling the ether product with dihydrogen utilizing catalytic chemistry. For example, the silylether product from the reaction of a primary silane and alcohol, RSi(OR′) 3 , can be recycled to the alcohol and the silylchloride, RSiCl 3 , with hydrochloric acid (HCl). The silylchloride affords the starting silane, RSiH 3 , upon reaction with lithium aluminum hydride (LiAlH 4 ). Alternatively, the silylchloride can be hydrogenated to the silane with dihydrogen and a transition metal catalyst. In the latter scenario HCl is the byproduct, making all reagents recoverable and H 2  and water the only consumable. 
         [0039]    Other advantages of on-board hydrogen storage in the form of organic silanes include: (1) silanes such as thriethylsilane or phenylsilane are liquids, which translates to facile transportation; (2) catalytic H 2  production allows kinetic control; (3) mild conditions and absence of waste (solvent is not needed and water or alcohol is the only co-reagent); and (4) the catalyst is based on rhenium, an inexpensive metal in comparison to noble metals (Ru, Rh, and Pt) since it is a byproduct of copper and molybdenum mining, both of which being very abundant in the earth&#39;s crust. 
       EXAMPLES 
       [0040]    The examples are illustrative only and are not intended to limit or preclude other embodiments of the invention. Reactions were performed in a nitrogen-filled glove-box or open to the ambient atmosphere as stated. Solvents were degassed, and distilled over CaH 2  prior to use. Trityl tetra(pentafluorophenyl) borate was purchased from Strem Chemicals and used as received. Organosilanes were purchased from Gelest and used as received. The oxorhenium chloride complex, Re(O)(hoz) 2 Cl, was prepared according to published procedures. See Mcpherson, L. D.; Drees, M.; Khan, S. I.; Strassner, T.; Abu-Omar, M. M.  Inorg. Chem.  2004, 43, 4036.  1 NMR spectra were recorded on Varian Inova300 instruments. Mass spectrometry was performed by the Purdue University Campus Wide Mass Spectrometry Center on a FinniganMAT LCQ mass spectrometer system (ESI) or a Hewlett Packard Engine mass spectrometer (GC/MS). A commercial gas evolution apparatus (ChemGlass CG-1818) was used to determine the yields of hydrogen gas evolved. Alternatively, a customized schlenk flask featuring a side-arm vacuum Teflon valve and a threaded joint fitted with a silicone septum was used to determine H 2  yields. Hydrogen gas analyses were performed on a Hiden Analytical HPR20 mass-spectrometer at 70 eV ionization energy, utilizing a Faraday detector. H 2 /HD/D 2  ratios were obtained via an empirical deconvolution table based on authentic H 2 , HD, and D 2  samples (Aldrich, 98+%). 
       Example 1 
     Preparation of Rhenium Cataylst (Isolated) 
       [0041]    Trityl tetra(pentafluorophenyl) borate, (2.05 g, 2.22 mmol) was dissolved in 25 mL of CH 3 CN in a nitrogen-filled glove-box and treated with PhMe 2 SiH (0.35 mL, 2.22 mmol) to form the silylium cation [Et 3 Si(CD 3 CN)][B(C 6 F 5 ) 4 ] as a brown solution. (The “D” in CD 3 CN represents deuterium, a heavy or “labeled” form of hydrogen which can be used to track the movement of hydrogen between molecules during a chemical reaction.) Treatment of this solution with Re(O)(hoz) 2 Cl, (1.25 g, 2.22 mmol) yields a green solution that contains the Rhenium Catalyst, triphenyl methane, and PhMe 2 SiCl. The solvent was removed in vacuo and the resulting green oil was washed repeatedly with pentane, to yield the Rhenium Catalyst as a green powder in 90% yield (2.5 g).  1 H NMR (300 MHz, CD 3 CN), 7.93 (d, 1H, 6.8 Hz), 7.59 (t, 1H, 7.1 Hz), 7.10 (t, 1H, 7.1 Hz), 7.03 (d, 1H, 6.8 Hz). MS (ESI + ) m/z Calc. For C 18 H 16 N 2 O 5 Re: 525.06/527.06. Found 524.90/526.88. MS (ESI − ) m/z Calc. For C 24 BF 20 : 678.98. Found 679.14. 
       Example 2 
     Preparation of Rhenium Cataylst (In Situ) 
       [0042]    Trityl tetra(pentafluorophenyl) borate, (0.050 g, 0.053 mmol) was dissolved in 1 mL of CD 3 CN in a nitrogen-filled glove-box and treated with Et 3 SiH (8.7 μl, 0.053 mmol) to form the silylium cation [Et 3 Si(CD 3 CN)][B(C 6 F 5 ) 4 ] as a brown solution. Treatment of this solution with Re(O)(hoz) 2 Cl, (0.030 g, 0.053 mmol) yields a green solution that contains the Rhenium Catalyst, triphenyl methane, and Et 3 SiCl. 
       Example 3 
     Catalytic Oxidation of Et 3 SiH and H 2  Production (Typical Procedure with Catalyst Generated In Situ, as Described Above) 
       [0043]    Et 3 SiH (0.87 μL, 0.053 mmol) was added to a CD 3 CN solution of trityl tetra(pentafluorophenyl)borate (0.050 g, 0.053 mmol) in a resealable NMR tube. Re(O)Cl(hoz) 2  (0.030 g, 0.053 mmol) was then added and the NMR tube was sealed and removed from the glove box. The NMR tube was then opened to the atmosphere and Et 3 SiH (0.180 mL, 1.12 mmol) was added. Vigorous hydrogen evolution occurred upon the addition of the silane and the green catalyst solution quickly turned red. After the hydrogen evolution seized (15 minutes) an aliquot of this reaction was submitted for GC/MS ( FIG. 1 ). Three peaks were found in the GC analysis; peak 1 had the highest abundance. The identity of the three peaks was determined by Mass Spectrometry and was found to be triethylsilanol (peak 1), hexaethyldisiloxane (peak 2) and triphenylmethane (peak 3, internal standard). The ratios of the peaks 1:2:3 by GC was 87:9:4. The mass spectra for peaks 1 and 2 are illustrated in  FIGS. 2 and 3 , respectively. NMR spectra of the starting triethylsilane and the catalytic reaction are depicted in  FIGS. 4 and 5  respectively. The expanded alkyl region of  FIG. 5 , shown in  FIG. 6 , shows two sets of quartets and triplets in agreement with formation of triethylsilanol and hexaethylsiloxane. See  FIGS. 2 ,  2   a ,  2   b ,  3 ,  3   a , and  3   b  for reference spectra for triethylsilanol and hexaethylsiloxane. The silylether forms from the silanol and after a period of two hours the bulk of the silanol is converted to the ether. 
       Example 4 
     Catalytic Hydrolytic Oxidation of Et 3 SiH and H 2  Production 
       [0044]    Et 3 SiH (0.87 μL, 0.053 mmol) was added to a CD 3 CN solution of trityl tetra(pentafluorophenyl)borate (0.050 g, 0.053 mmol) in a resealable NMR tube. Re(O)Cl(hoz) 2  (0.030 g, 0.053 mmol) was then added and the NMR tube was sealed and removed from the glove box. The NMR tube was then opened to the atmosphere and Et 3 SiH (0.200 mL, 1.25 mmol) and water (28.6 μL, 1.59 mmol) was added. Vigorous hydrogen evolution occurred upon the addition of the silane and the green catalyst solution remained green throughout the reaction. After the hydrogen evolution seized (15 minutes) an aliquot of this reaction was submitted for GC/MS. One peak was found in the GC analysis. The identity of the peak was determined by Mass Spectrometry and was found to be hexaethyldisiloxane. This is in agreement with formation of the silylether from the initial silanol product. 
       Example 5 
     Catalytic Hydrolytic Oxidation of PhMe 2 SiH and H 2  Production (Typical Procedure with Isolated Catalyst) 
       [0045]    An acetonitrile solution of [Re(O)(hoz) 2 ][B(C 6 F 5 )] (0.050 g, 0.040 mmol) was treated with water (3 mL, 166 mmol) in a Schlenk tube. Phenyldimethyl silane (1 mL, 6.53 mmol) was then added and the evolution of hydrogen was monitored using a glass evolution apparatus. Upon cessation of hydrogen evolution the reaction mixture was poured onto ice and treated with pentane to precipitate the catalyst. The mixture was filtered and the organic layer was extracted with diethyl ether and pentane. The solution was dried with anhydrous MgSO 4  and filtered. Pentane and ether were removed in vacuo to afford 88% isolated yield of PhMe 2 Si(OH) (95%) and (PhMe 2 Si) 2 O (5%). 
       Example 6 
     Hydrogen Yield of the Reaction of MePh 2 SiH and H 2 O 
       [0046]    To a solution of 0.0080 g (0.0088 mmol) of trityl tetra(pentafluorophenyl)borate in CD 3 CN (1 mL), 1.4 μL (0.0088 mmol) of triethylsilane was added. To this brown solution 0.0050 g (0.0088 mmol) of Re(O)Cl(hoz) 2  was dissolved producing a green solution. The reaction vessel was then charged with this solution and 0.079 mL (4.41 mmol) nanopure H 2 O was injected through the silicone septum. To initiate the reaction, 0.175 mL (0.881 mmol) of methyldiphenylsilane (MePh 2 SiH) was added and rapid H 2  evolution ensued. A total volume of 19±1 mL of evolved H 2  gas was measured (95% yield). The NMR spectrum of the final organic reaction product, siloxane, is depicted in  FIG. 7 .  FIG. 13  shows the NMR spectrum of the final organic reaction product for a related reaction, using diphenylsilane (Ph 2 SiH 2 ). 
       Example 7 
     Hydrogen Yield from the Reaction of Et 3 SiH and Ethanol 
       [0047]    To a solution of 0.016 g (0.018 mmol) of trityl tetra(pentafluorophenyl)borate in CD 3 CN (1 mL), 2.8 μL (0.018 mmol) of triethylsilane was added. To this brown solution 0.010 g (0.018 mmol) of Re(O)Cl(hoz) 2  was dissolved producing a green solution. The reaction vessel was then charged with this solution and 0.126 mL (2.16 mmol) ethanol (200 proof) was injected through the septum resulting in an intensely green solution. To initiate the reaction, 0.250 mL (1.57 mmol) of triethylsilane was added and rapid H 2  evolution ensued. A total volume of 34±1 mL of evolved H 2  gas was measured (96% yield). The NMR spectrum of the final organic reaction product, Et 3 SiOEt, is given in  FIG. 8 . 
       Example 9 
     The Source of Oxygen in Silicon Product 
       [0048]    To ascertain the source of oxygen in the silicon product, a catalytic reaction in open air with  18 OH 2  in accordance with Equation 9, below, was conducted. 
         [0000]    
       
                 
         
             
             
         
       
     
         [0049]    In a nitrogen-filled glove box trityl tetra(pentafluorophenyl) borate, (0.050 g, 0.053 mmol) was dissolved in 1 mL of CD 3 CN and treated with Et 3 SiH (8.7 μL, 0.053 mmol) to form the silylium cation. The brown solution was then treated with Re(O)(hoz) 2 Cl (0.030 g, 0.053 mmol) and the green solution removed from the glove box.  18 OH 2  (95%  18 O, 30.0 μL, 1.66 mmol) was added to this solution and the solution stirred for 1 hour. Analysis by mass spectrometry (ESI) revealed [Re(O)(hoz) 2 ][B(C 6 F 5 )], as 84%  18 O enriched.  FIGS. 11   a  and  11   b  show the MS-ESI spectra for [Re(O)(hoz) 2 ][B(C 6 F 5 )] and  18 O enriched [Re(O)(hoz) 2 ][B(C 6 F 5 )]. Preparation of the labeled water and catalyst were necessary to evaluate the mechanism of the hydrolytic oxidation. Quantitative  18 O-enrichment was observed in the product, confirming water as the oxidant. 
       Example 10 
     Whether Silane Adds Across R═O Double Bond 
       [0050]    To investigate whether silane adds across a Re═O multiple bond, two experiments were conducted. 
       Experiment 1 
       [0051]    The first experiment was an isotope labeling experiment under stoichiometric conditions (Re/Ph 2 MeSiH/H 2   18 O=1:1:1) using a different order of substrate addition, as shown in Table 2, below. 
         [0000]    
       
         
               
             
               
               
             
               
               
               
               
             
           
               
                 TABLE 2 
               
             
             
               
                   
               
               
                 Results from Isotope Labeling Experiments with  18 OH 2   a   
               
               
                 
                   
                             
                     
                         
                         
                     
                   
                 
               
               
                   
               
             
          
           
               
                   
                 %  18 O b   
               
             
          
           
               
                 entry 
                 substrate added last 
                 (Ph 2 MeSi) 2 O 
                 1 
               
               
                   
               
               
                 1 
                 Re cat. 1 
                 86 
                 ~2 
               
               
                 2 
                 Ph 2 MeSiH 
                 80 
                   4 
               
               
                 3 
                 H 2   18 O 
                 69 
                     5 c   
               
               
                   
               
               
                   a Conditions: [Ph 2 MeSiH] = [1] = [H 2   18 O] (~95%  18 O) = 0.053 M in CH 3 CN at ambient temperature. Two substrates were incubated for 30 min prior to addition of the third. 
               
               
                   b   1S O-Incorporation into (Ph 2 MeSi) 2 O was determined by GC-MS and into complex 1 by ESI-MS. 
               
               
                   c [Re(hoz) 2 ] +  (m/z = 509.511) was detected in addition to 1. 
               
             
          
         
       
     
         [0052]    Order 1—Rhenium Catalyst Added Last. 
         [0053]    In a nitrogen-filled glove box trityl tetra(pentafluorophenyl) borate (0.050 g, 0.053 mmol) was dissolved in 1 mL of CD 3 CN and treated with Ph 2 MeSiH (10.6 μL, 0.053 mmol) to form the silylium cation. The brown solution was then treated with Re(O)(hoz) 2 Cl (0.030 g, 0.053 mmol) and the green solution removed from the glove box. Diphenylmethyl silane (10.6 μL, 0.053 mmol) was combined with  18 OH 2  (1.1 μL, 0.053 mmol), and added to the catalyst solution. The resulting homogenous reaction mixture was allowed to stand for 30 minutes, passed through a plug of silica (benzene/hexanes), and collected fractions analyzed by GC/MS and ESI/MS. 
         [0054]    Order 2—Ph 2 MeSiH Added Last. 
         [0055]    In a nitrogen-filled glove box trityl tetra(pentafluorophenyl) borate (0.050 g, 0.053 mmol) was dissolved in 1 mL of CD 3 CN and treated with Ph 2 MeSiH (10.6 μL, 0.053 mmol) to form the silylium cation. The brown solution was treated with Re(O)(hoz) 2 Cl (0.030 g, 0.053 mmol) and the green solution removed from the glove box and treated with  18 OH 2  (1.1 μL, 0.053 mmol) and allowed to stand for 30 minutes. Diphenylmethyl silane (10.6 μL, 0.053 mmol) was added to this solution. The resulting reaction mixture was allowed to stand for 15 minutes, passed through a plug of silica (benzene/hexanes), and collected fractions analyzed by GC/MS and ESI/MS. 
         [0056]    Order 3- 18 OH 2  Added Last. 
         [0057]    In a nitrogen-filled glove box, trityl tetra(pentafluorophenyl) borate (0.050 g, 0.053 mmol) was dissolved in 1 mL of CD 3 CN and treated with Ph 2 MeSiH (10.6 μL, 0.053 mmol) to form the silylium cation. The brown solution was then treated with Re(O)(hoz) 2 Cl (0.030 g, 0.053 mmol), the resulting green solution was treated with diphenylmethyl silane (10.6 μL, 0.053 mmol), and allowed to stand for 30 minutes during which the solution became red in color. The solution was removed from the glove box and treated with  18 OH 2  (1.1 μL, 0.053 mmol), allowed to stand for 15 minutes, passed through a silica plug (benzene/hexanes), and recovered fractions analyzed by GC/MS and ESI/MS. This procedure afforded the least  18 O enrichment, probably due to reduction of the rhenium catalyst by the Ph 2 MeSiH prior to the addition of  18 OH 2 .  FIG. 12  depicts an MS-ESI spectrum indicating the presence of reduced [Re(hoz) 2 ] + . 
         [0058]    The slightly reduced  18 O-enrichment in the silyl ether product is due to oxo exchange between H 2   18 O and the Rhenium Catalyst (see  FIGS. 11   a  and  11   b ) and the minor side reduction of the Rhenium Catalyst by Ph 2 MeSiH. It is notable that adding the silane last after incubation of the Rhenium Catalyst and H 2   18 O afforded less enrichment (compare entry 1 and entry 2 in Table 2). Addition of water last (entry 3 in Table 2) gave the least enrichment because incubation of the Rhenium Catalyst and Ph 2 MeSiH prior to water addition resulted in reduction of some of the rhenium catalyst ( FIG. 12 ). 
       Experiment 2 
       [0059]    The second experiment tested base catalysis by employing a hindered noncoordinating base, 2,6-lutidene, which shifts the acid/base equilibria in favor of dioxorhenium (eq. 10). Thus, if 4 is the active form, 2,6-lutidene would promote catalysis. On the contrary, it was found that addition of base shuts down the catalytic reaction completely. Therefore, it was concluded that 4 is not the active catalyst, and a second multiply bonded ligand is not needed, contrary to a previous report. 
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         [0060]    The source of each hydrogen atom in the dihydrogen product was discerned by employing Et 3 Si-D with H 2 O, and Et 3 Si—H with D 2 O (eqs 11 and 12). The produced hydrogen gas was analyzed by mass spectrometry and found to be exclusively HD. 
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         [0061]    The progress of reaction was investigated by  1 H NMR for Ph 2 MeSiH ( FIG. 10 ). The rate of formation of silanol is first-order in [Ph 2 MeSiH], [Re] T , and [H 2 O]. The rate of silyl ether formation is first-order in [Ph 2 MeSiOH] and [Re], but inhibited by water. Again without wishing to be tied to any specific theory, a mechanism that is consistent with the observed isotope labeling and kinetic experiments is given in Scheme 1. 
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         [0062]    Surprisingly, the results of these experiments indicated that, contrary to previous reports on the mechanism of oxosilation using alternate Rhenium Catalysts (such as [Re(O) 2 ][(PPh 3 ) 2 ]) and early transition metals, two multiply bonded ligands are not required for the rhenium catalyst to promote the hydrolytic oxidation of organosilanes. See Kennedy-Smith, J. J.; Nolin, K. A.; Guneterman, H. P.; Toste, F. D.,  J. Am. Chem. Soc.  2003, vol. 125, p. 4056; Sweeney, Z. K.; Polse, J. L.; Andersen, R. A.; Bergman, R. G.; Kubinec, M. G.,  J. Am. Chem. Soc.  1997, vol. 119, p. 4543; and, Gountchev, T. I.; Tilley, T. D.,  J. Am. Chem. Soc.  1997, vol. 119, p. 12831. The rhenium catalyst disclosed herein does not necessarily require two oxygen atoms doubly bonded to the Rhenium atom of the catalyst molecule, which were previously believed necessary for this sort of reaction. 
         [0063]    While exemplary embodiments incorporating the principles of the present invention has been disclosed hereinabove, the present invention is not limited to the disclosed embodiments. Instead, this application is intended to cover any variations, uses, or adaptations of the invention using its general principles. Further, this application is intended to cover such departures from the present disclosure as come within known or customary practice in the art to which this invention pertains and which fall within the limits of the appended claims.