Abstract:
A high temperature heat pump comprising a low temperature heat exchanger to produce vapor of a first fluid from heat transferred from a second fluid to a mixture of liquid and vapor of the first fluid; a compressor to increase the pressure and temperature of the produced vapor; a high temperature heat exchanger to heat the second fluid to useful, high temperatures from the condensation of the first fluid; and an expander to lower the pressure and temperature of the first fluid producing a mixture of vapor and liquid.

Description:
BACKGROUND OF THE INVENTION 
   This invention relates generally to utilization of waste heat in industrial applications, and in buildings, and more particularly to use of heat pumps to enable such waste heat utilization. 
   The amount of low level (&lt;200 F) waste heat in commercial buildings and industry is enormous. Many studies have been performed on application of heat pumps to convert this lower level heat to a higher temperature at which it is useful. However, the economics of such systems and their relatively lower temperature capabilities have limited their application. 
   SUMMARY OF THE INVENTION 
   It is a major object of the invention to provide method and means to enable waste heat utilization in an efficient and cost effective manner. 
   A further object is to use a high temperature refrigerant in a heat pump cycle to raise the temperature of waste heat to a high temperature at which the heat is useful. 
   Yet another object is to provide an unusually effective way to use the output of a heat pump to produce steam. 
   An added object is to utilize a two-phase turbine to reduce the throttling losses in the heat pump cycle, thereby increasing efficiency. 
   Another object is to utilize a high temperature heat pump to reduce steam production in the winter time while increasing the electricity sold. 
   Basically, the invention is embodied in heat pump apparatus comprising
         a) a low temperature heat exchanger to produce vapor of a first fluid from heat transferred from a second fluid to a mixture of liquid and vapor of the first fluid,   b) a compressor to increase the pressure and temperature of the produced vapor,   c) a high temperature heat exchanger to heat the second fluid to useful, high temperatures from the condensation of the first fluid,   d) an expander to lower the pressure and temperature of the first fluid producing a mixture of vapor and liquid.       

   As will be seen, the expander may for example comprise a two-phase turbine, and the compressor may derive a fraction of its required power from the turbine. The expander may alternatively comprise a liquid expansion valve. 
   A further object is to vaporize the second fluid by heat transfer in a high temperature heat exchanger, and additional load means may be provided to receive the second fluid vapor for use, as in:
         i) a heating system   ii) a building heating system   iii) a building heating system also served by a district heating system   iv) a building heating system also served by a boiler   v) an industrial process employing heat input.       

   These and other objects and advantages of the invention, as well as the details of an illustrative embodiment, will be more fully understood from the following specification and drawings, in which: 

   
     DRAWING DESCRIPTION 
       FIG. 1  is a diagrammatic view of a system embodying the invention, and employing a high temperature heat pump, with a two-phase turbine; 
       FIG. 2  is a diagrammatic view of a system embodying the invention, and employing a high temperature heat pump, with an expansion valve; 
       FIG. 3  is a temperature entropy diagram, for the high temperature heat pump, shown in  FIGS. 1 and 2 . 
   

   DETAILED DESCRIPTION 
     FIG. 1  shows a heat pump with a two-phase turbine to recover throttling losses in the cycle. A fluid stream (the “waste flow”)  1 , having a lower temperature than would normally be useful, flows though a pipe or other duct. It can be mixed with another fluid stream,  12 , also having a lower temperature than would normally be useful. Part of the waste flow, regulated by a valve  2 , flows through a lower temperature heat exchanger  3 , where heat is transferred to vaporize a working fluid  18 , at a yet lower temperature. Another part of the waste flow is regulated by a valve  5 , pressurized by a pump  6 , to the desired high temperature vapor pressure and flows to the high temperature heat exchanger  8 . 
   The temperature of the waste flow  4  leaving the low temperature heat exchanger is lower than the temperature when it entered. The waste flow is discharged for waste disposal or another use. 
   The working fluid stream  18  is completely vaporized in the low temperature heat exchanger and leaves as a vapor. 
   The vapor of the working fluid  13  is compressed to a high pressure and temperature by the compressor  14 , which is driven by a motor  19  via shaft  16 ″. The resulting high temperature working fluid vapor at  15  enters the high temperature heat exchanger  8 , in which it transfers heat to another part  7 , of the waste flow  1 . The working fluid vapor is condensed in the high temperature heat exchanger, resulting in a liquid stream  16 , which is at a higher pressure and temperature than the working fluid vapor entering the compressor at  13 . 
   The working fluid is expanded in a two-phase turbine  17 , to low pressure  18 , flashing and cooling the working fluid. The temperature at  18  is very nearly the same as at the compressor inlet  14   a . The power generated by the two-phase turbine can be via shaft  16 ′ used to reduce the net power consumed by the compressor  14 . A typical two-phase turbine is of the type described in U.S. Pat. No. 5,385,446, or in references listed therein. 
   The portion of the waste flow  7 , entering the high temperature heat exchanger is vaporized at a high temperature and pressure  9 , forming a useful fluid stream which can be used, for example, in a heat exchanger load  10 . The cooled useful fluid stream  11 , leaving the heat exchanger load can be re-mixed with the waste flow stream, for example at  12 , to recycle the fluid and recover additional heat. 
   Another variation of the high temperature heat pump, which uses a valve for expansion instead of the two-phase turbine, is shown in  FIG. 2 . A fluid stream (the “waste flow”)  1   a , having a lower temperature than would normally be useful, flows through a pipe or other duct. It can be mixed with another fluid stream  12   a , also having a lower temperature than would normally be useful. Part of the waste flow, regulated by a valve  2   b , flows through a low temperature heat exchanger  3   a , where heat is transferred to vaporize the working fluid  18   a , at a yet lower temperature. Another part of the waste flow is regulated by a valve  5   a , then pressurized by a pump  6   a , to the desired high temperature vapor pressure, and flows to the high temperature heat exchanger  8   a.    
   The temperature of the waste flow  4   a , leaving the low temperature heat exchanger is lower than the temperature when it entered. The waste flow is discharged for waste disposal or another use. 
   The working fluid stream  18   a  is completely vaporized in the low temperature heat exchanger and leaves as a vapor. 
   The vapor of the working fluid at  13   a  is compressed by the compressor  14   b , to a high pressure and temperature. The high temperature working fluid vapor enters the high temperature heat exchanger  8   a , in which it transfers heat to another part  7   a  of the waste flow  1   a . The working fluid vapor is condensed in the high temperature heat exchanger, resulting in a liquid stream  16   a , which is at a higher pressure and temperature than the working fluid vapor entering the compressor at  13   a.    
   The working fluid is expanded in a valve  17   a  to the low pressure of flow at  18   a , flashing and cooling the working fluid. The temperature of fluid at  18   a  is very nearly the same as the temperature of fluid  13   a  supplied to the compressor inlet. 
   The portion of the waste flow  7   a , entering the high temperature heat exchanger  8   a  is vaporized at a high temperature and pressure, at  9   a  forming a useful fluid stream which can be used, for example, in a heat exchanger load  10   a . The cooled useful fluid stream  11   a  leaving the heat exchanger load can be re-mixed with the waste flow, for example at  12   a , to reuse the fluid and recover additional heat. 
     FIG. 3  illustrates the two high temperature heat pumps on a temperature-entropy diagram for the working fluid. The working fluid vapor enters the compressor  14  at  13 . The compressor  14  increases the temperature and pressure to level  15 . The working fluid flows through the high temperature heat exchanger  8  leaving as saturated liquid at  16 . The working fluid is expanded in the turbine  17  to a lower temperature and pressure, at  18 . The power generated is proportional to the enthalpy difference h 1 −h 2 . 
   The liquid fraction of the working fluid x/y, is vaporized in the low temperature heat exchanger by the heat from the first fluid stream to provide the vapor working fluid stream  13  to the compressor. If an expansion valve  17   a  is used instead of the two-phase turbine, no power is generated. In addition a lower liquid fraction x′/y is generated. 
   An analysis was performed using the heat pump to convert heat from a stream of low temperature water to produce high temperature steam. 
   For purposes of the discussion, consider the conditions analyzed as an example. Heat exchanger pressure drop is neglected for the example. 
   Refrigerant vapor is generated in the low temperature heat exchanger by heat from a low temperature water stream or other fluid stream. For the case analyzed the waste flow stream is at 160° F. The refrigerant vapor at  13  is saturated. For the case analyzed the refrigerant is R 123. It is assumed to be vaporized at 150°, at which temperature the saturation pressure is 48.6 psia. 
   The saturated vapor enters a compressor where, as in a conventional refrigeration cycle, the vapor is compressed to a higher pressure and temperature. For a compressor efficiency of 80% the vapor at  15  leaves the compressor at 260° F. and 199 psia. 
   The vapor is condensed in the high temperature heat exchanger, transferring heat to a part of the low temperature water stream  7 , which has been pressurized to 15 psig by the pump  6  shown. The water is vaporized by the condensing refrigerant, leaving the heat exchanger as steam at 15 psig and 250° F. The steam flow rate is a fraction of the flow rate of the low temperature stream. 
   The condensed refrigerant leaves the heat exchanger at  16 . For the example, the temperature is 250° F. and the fluid is saturated liquid at 199 psia. 
   The temperature of the condensed refrigerant can be lowered by flashing it to 48.6 psia, either through a valve or through a two-phase turbine. A mixture of vapor and liquid is formed as a result of the expansion. For the conditions chosen, the vapor fraction is 43% with a turbine expansion as in  FIG. 1  and 45% with a valve expansion as in  FIG. 2 . 
   For the turbine expansion, the power generated is used to decrease the power input required to operate the compressor. 
   The two-phase refrigerant enters the low temperature heat exchanger wherein the liquid fraction is evaporated, closing the cycle. 
   Analysis 
   The property tables for R 123 were used to determine enthalpy and entropy at the cycle state points. Compressor isentropic efficiency and two-phase turbine efficiency were inputs. 
   For a selected evaporator pressure p 13 , and condenser pressure p 15 , the enthalpy at the compressor discharge is:
 
 h   15 =( h   i15   −h   13 )/ηc +h   13  
         where:
           h=enthalpy at the subscripted cycle point   i=isentropic compression   value (subscript)   η c =compressor isentropic efficiency.   
               

   The heat transfer in the high temperature heat exchanger is:
 
 Q   h   =h   15   −h   115  
         where:
           h 115 =enthalpy of saturated liquid at at P 15 , and point  16     p 15 =pressure at compressor exit.   
               

   The enthalpy leaving the two-phase turbine is:
 
 h   18 =( h   115   −h   i18 )(1−η t )+ h   il8  
         where:
           h i18 =enthalpy for isentropic   expansion from point  16  to point  18     η t =two-phase turbine isentropic efficiency.   
               

   For expansion through the valve:
 
h 18 =h 115  
 
   The heat transferred to the working fluid to evaporate the liquid fraction is:
 
 Q   1   =h   13   −h   18 .
 
   The compressor power is:
 
 P   c   =h   15   −h   13 .
 
   The turbine power is:
 
 P   t   =h   115   −h   18 .
 
   The net compressor power with a two-phase turbine is:
 
 P   n   =P   c   −P   t .
 
   EXAMPLE 
   The power and heating performance were determined for a waste flow stream temperature of 160° F.; a steam generation temperature of 250° F. at 15 psig; an evaporator temperature of 150° F.; and a compressor outlet pressure of 199 psia (which gives a temperature of 260° F.). The compressor pressure ratio 4.09 is within the range of commercial centrifugal chillers. The compressor efficiency was assumed to be 80% and the two-phase turbine efficiency to be 70%. 
   With these assumptions the coefficient of performance for the valve expansion was calculated to be:
 
 COP   v   =Q   h   /P   c =13, 406 Btu/kWh.
 
   The coefficient of performance for the turbine expansion was calculated to be:
 
 COP   t   =Q   h   /P   n =15,977 Btu/kWh.
 
   For these conditions the heat pump using the turbine for power recovery generates 19% more high temperature heat (steam) than the heat pump using an expansion valve. 
   Economics 
   The economics were examined for winter conditions in New York. The average steam price is about $20/1000 lb. and the power price is about $0.15/kWh. A 100 kW power input produces 1522 lb/h of 15 psig steam for the heat pump with a two-phase turbine and 1277 lb/h for the heat pump with an expansion valve. 
   Operation for 4 months at 24/7 duty produces a savings (steam cost minus electricity cost) of $45,000 with the turbine and $31,000 with the expansion valve. For reference the selling price for a commercial 200 ton centrifugal chiller with turbine is believed to be approximately $60,000. If the selling price is doubled for installation costs a simple payback of 2.7 years results for the heat pump with two-phase turbine versus 3.9 years for the unit with an expansion valve.