Abstract:
A method to integrate low dielectric constant dielectric materials with copper metallization is described. A metal line is provided overlying a semiconductor substrate and having a nitride capping layer thereover. A polysilicon layer is deposited over the nitride layer and patterned to form dummy vias. A dielectric liner layer is conformally deposited overlying the nitride layer and dummy vias. A dielectric layer having a low dielectric constant is spun-on overlying the liner layer and covering the dummy vias. The dielectric layer is polished down whereby the dummy vias are exposed. Thereafter, the dielectric layer is cured whereby a cross-linked surface layer is formed. The dummy vias are removed thereby exposing a portion of the nitride layer within the via openings. The exposed nitride layer is removed. The via openings are filled with a copper layer which is planarized to complete copper metallization in the fabrication of an integrated circuit device.

Description:
BACKGROUND OF THE INVENTION 
     (1) Field of the Invention 
     The invention relates to a method of metallization in the fabrication of integrated circuits, and more particularly, to a method of integrating low dielectric constant materials with copper metallization in the manufacture of integrated circuits. 
     (2) Description of the Prior Art 
     Copper metallization has become a future trend in integrated circuit manufacturing. However, copper contamination of the intermetal dielectric layer is a problem, especially for the desirable low dielectric constant (low-k) materials. Copper mobile ion contamination is fatal and detrimental to low-k dielectric materials. In addition, low-k dielectrics are also fairly susceptible to the harsh effects of plasma ashing as well as plasma etching. It is desired to provide a smooth integration of low-k dielectric materials with copper metallization in order to attain a device of high performance quality. 
     Co-pending U.S. patent application Ser. No. 09/398,294 (CS-99-024) to L. J. Xun et al, filed on Sept. 20, 1999, teaches using a dielectric layer to protect an underlying low-k dielectric during plasma ashing. U.S. Pat. No. 6,001,730 to Farkas et al and U.S. Pat. No. 5,723,387 to Chen disclose copper dual damascene processes. U.S. Pat. No. 6,033,963 to Huang et al teaches forming a metal gate using a replacement gate process. 
     SUMMARY OF THE INVENTION 
     A principal object of the present invention is to provide an effective and very manufacturable method of copper metallization in the fabrication of integrated circuit devices. 
     Another object of the present invention is to provide an effective and very manufacturable method of integrating low dielectric constant materials with copper metallization in the fabrication of integrated circuit devices. 
     Another object of the invention is to prevent copper contamination of the low-k dielectric layer. 
     Yet another object of the invention is to protect the low-k dielectric layer from damage caused by plasma etching and/or plasma ashing. 
     A further object of the invention is to effectively integrate low-k dielectrics with copper metallization using a replacement line and replacement via technique. 
     A still further object of the invention is to prevent copper mobile ion contamination of the low-k dielectric layer with a sidewall liner layer. 
     Another further object of the invention is to protect the low-k dielectric layer from plasma etch and ashing damage by electron-beam, ion-beam, or X-ray curing. 
     Yet another object of the invention is to effectively integrate low-k dielectric with copper metallization using replacement line and replacement via techniques which are applicable to single, double, and triple damascene processes. 
     In accordance with the objects of this invention a new method to integrate low dielectric constant dielectric materials with copper metallization is achieved. A metal line is provided overlying a semiconductor substrate and having a nitride capping layer thereover. A polysilicon layer is deposited over the nitride layer and patterned to form dummy vias. A dielectric liner layer is conformally deposited overlying the nitride layer and dummy vias. A dielectric layer having a low dielectric constant is spun-on overlying the liner layer and covering the dummy vias. The dielectric layer is polished down whereby the dummy vias are exposed. Thereafter, the dielectric layer is cured whereby a cross-linked surface layer is formed. The dummy vias are removed thereby exposing a portion of the nitride layer within the via openings. The exposed nitride layer is removed. The via openings are filled with a copper layer which is planarized to complete copper metallization in the fabrication of an integrated circuit device. 
    
    
     BRIEF DESCRIPTION OF THE DRAWINGS 
     In the accompanying drawings forming a material part of this description, there is shown: 
     FIGS. 1 through 12 schematically illustrate in cross-sectional representation a preferred embodiment of the present invention. 
     FIGS. 3A and 3B and  9 A and  9 B illustrate two alternatives for forming the liner layer in the present invention. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     The present invention provides a method for effectively integrating low dielectric constant dielectrics with copper metallization. The low-k materials are protected from copper mobile ions by a sidewall liner layer and are protected from harmful effects of plasma etching and ashing by electron-beam, ion-beam, or X-ray curing. Integration is accomplished using a replacement line and replacement via technique that is applicable to single, double, and triple damascene processes. 
     Referring now more particularly to FIG. 1, there is illustrated a portion of a partially completed integrated circuit device. There is shown a semiconductor substrate  10 , preferably composed of monocrystalline silicon. An intermetal dielectric (IMD) or interlevel dielectric (ILD) layer  14  is deposited on the substrate wafer. Semiconductor devices structures, such as gate electrodes and source and drain regions, not shown, may be formed in and on the semiconductor substrate and covered by the IMD or ILD layer  14 . A copper line  16  is formed over the ILD layer  14  and connects to one or some of the underlying semiconductor device structures, not shown. A thin nitride capping layer  18  is deposited over the copper line to a thickness of between about 300 and 500 Angstroms. 
     Referring now to FIG. 2, a thick polysilicon layer is deposited over the nitride capping layer. The thickness of the polysilicon layer should be equal to the height of the metal via connection to be formed. The polysilicon layer is etched to form via studs, or dummy vias,  20  where the vias are to be formed. 
     Now, a conformal dielectric liner layer  22  is deposited over the nitride layer and the dummy vias  20 , as shown in FIG.  3 A. The liner layer  22  will provide a sidewall liner for the vias to be formed and will prevent copper mobile ion penetration of the to-be-deposited low-k dielectric layer. The liner layer  22  preferably comprises silicon nitride and is deposited by plasma-enhanced chemical vapor deposition (PE-CVD) to a thickness of between about 300 and 800 Angstroms, depending on future barrier metal thickness. 
     FIG. 3B illustrates an optional step in which a reactive ion etch (RIE) is performed to etch away the liner layer  22  on the horizontal surfaces and leave the liner layer only on the sidewalls of the dummy vias. This will provide some improvement in resistance. It will be understood that processing continues for this option in the same way as shown in the succeeding figures. 
     The liner layer  22  provides a second protection layer, after the barrier metal layer to be deposited later, to prevent mobile copper ions. Future technologies will see vias becoming ever smaller. It will not be beneficial to deposit a thick barrier metal layer, such as tantalum nitride, into the via hole because that will allow room for little copper fill into the vias, thus causing high via resistance. Therefore, a thin barrier metal layer is attractive, but it will not provide enough protection. Thus, to strengthen the protection of the barrier layer, the non-conducting silicon nitride liner is deposited to increase the “barrier” thickness. The protective property of the barrier metal layer is strengthened by the silicon nitride liner thickness externally. The silicon nitride liner layer provides little contamination to the subsequently deposited low-k dielectric and affords better adhesion. 
     Now, a low-k dielectric layer  26  is spun-on over the liner layer  22  and covering the dummy vias  20 . The low-k material may comprise hydrogen silsesquioxane (HSQ), methylsilsesquioxane (MSQ), fluorinated silicate glass (FSG), SILK, FLARE, and so on. The low-k dielectric is polished back using chemical mechanical polishing (CMP) or fixed abrasive pad (FAP) polishing, for example, until the polysilicon of the dummy vias is exposed, as shown in FIG.  4 . 
     Referring now to FIG. 5, the low-k dielectric surface is exposed to electron-beam, ion-beam, O 2  plasma, or X-ray curing  30 . The curing alters the low-k dielectric surface properties. That is, the top surface  32  of the dielectric layer is vulcanized or cross-linked to make it mechanically robust and chemically resistant. The strengthening phenomenon is similar to sulfur or rubber vulcanization. However, we can only allow cross-linking or vulcanization at the low-k dielectric surface and not throughout the entire low-k layer so as to preserve the low-k dielectric properties. 
     Electron-beam curing is preferred. The beam is either rastered across the die as a beam or electron flooding of about a 20×20 field size is performed. The beam intensity may be between about 0.1 to 1 mc/cm 2 . The following table shows examples of electron-beam curing conditions. 
     
       
         
               
             
               
               
               
               
               
             
           
               
                   
               
               
                 Electron-beam Curing 
               
             
          
           
               
                   
                 Dose (cm −2 ) 
                 Voltage (V) 
                 Current 
                 Temperature (° C.) 
               
               
                   
                   
               
               
                   
                 1,000 
                 3 
                 10 
                 250 
               
               
                   
                 3,000 
                 3 
                 10 
                 250 
               
               
                   
                 5,000 
                 3 
                 10 
                 250 
               
               
                   
                 5,000 
                 3 
                 20 
                 400 
               
               
                   
                 5,000 
                 5 
                 20 
                 400 
               
               
                   
                   
               
             
          
         
       
     
     Now, the exposed polysilicon dummy vias are removed by a wet etch, such as hot concentrated potassium hydroxide (KOH). However, since the low-k dielectric is already protected with a cross-linked surface layer, a remote isotropic plasma dry etch that is selective to remove only polysilicon can also be used. This kind of dry etch technique does not adversely effect the low-k properties. 
     A short self-aligned nitride etch is performed to remove the nitride layer  18  within the via openings  34 , as shown in FIG.  6 . Alternatively, this step can be incorporated with the Argon pre-sputter cleaning of the via openings. In this alternative, resistance will be reduced and operating frequency will be increased. 
     Referring now to FIG. 7, a barrier metal layer  36  is deposited over the cross-linked low-k layer  32  and within the via openings  34 . For example, the barrier metal layer may comprise titanium or a titanium compound, tantalum or a tantalum compound, or tungsten or a tungsten compound and may have a thickness of between about 100 and 200 Angstroms for common physical vapor deposition (PVD) techniques such as ionized metal plasma (IMP). For future technologies, we may use atomic layer CVD barrier metal. This barrier metal layer will be thin, but unless proven, will not offer enough protection against copper diffusion. So, the invention&#39;s external liner layer of silicon nitride  22  outside the via offers a second protection. 
     A copper layer  40  is formed over the barrier metal layer  36 , by any of the conventional means, including physical or chemical vapor deposition, electrochemical plating (ECP), or electroless plating, and so on. Preferably, a copper seed layer is deposited and copper formed by electroless plating. The copper and barrier metal layers are planarized by CMP or FAP, as shown in FIG.  7 . The treated surface  32  of the low-k dielectric and the encapsulating liner layer  22  protect the low-k dielectric layer from copper contamination and deterioration of integrity during the polishing step. 
     This completes a single damascene structure. If further metallization is to be provided, processing continues. As shown in FIG. 8, another thin nitride layer  48  is deposited over the planarized substrate surface. This layer  40  serves as a capping layer over the copper vias. A second thick polysilicon layer  50  is deposited over the nitride layer to the thickness desired for the metal lines to be formed. The polysilicon layer is patterned to form dummy lines  50 . 
     Processing continues similarly to that described previously for forming the metal vias. Referring to FIG. 9A, a conformal dielectric liner layer  52  is deposited over the nitride layer and the dummy lines  50 . The liner layer  52  will provide a sidewall liner for the lines to be formed and will prevent copper mobile ion penetration of the to-be-deposited low-k dielectric layer. The liner layer  52  preferably comprises silicon nitride and is deposited by PECVD to a thickness of between about 300 and 800 Angstroms. 
     FIG. 9B illustrates the option where the silicon nitride liner layers  22  and  52  have been anisotropically etched by RIE to form spacers on the sidewalls of the vias and lines, respectively. The liner layer provides protection against copper diffusion and so is needed only on the sidewalls of the copper vias and lines. Removing the unnecessary silicon nitride improves RC delay. Processing continues as described for both options. 
     As described for the first liner layer  22 , the second liner layer  52  provides double protection to increase the protective properties of the to-be-deposited barrier metal layer. 
     Now, a low-k dielectric layer  56  is spun-on over the liner layer  52  and covering the dummy lines  50 . The low-k material may comprise hydrogen silsesquioxane (HSQ), methylsilsesquioxane (MSQ), fluorinated silicate glass (FSG), SILK, FLARE, and so on. The low-k dielectric is polished back using CMP or FAP until the polysilicon of the dummy lines is exposed, as shown in FIG.  10 . 
     The low-k dielectric surface is exposed to electron-beam curing, as described above. The electron-beam curing alters the low-k dielectric surface properties. That is, the top surface  62  of the dielectric layer is vulcanized or cross-linked to make it mechanically robust and chemically resistant. Other forms of curing may be applicable, as noted above. Ion-beam, O 2  plasma, or X-ray curing may be used. However, these processes need to be more closely controlled to guard against unintentional damage (physical and radiation). 
     Now, the exposed polysilicon dummy lines are removed by a wet etch, such as concentrated KOH. A short self-aligned nitride etch is performed to remove the nitride layer  48  within the trench openings  64 , as illustrated in FIG.  11 . Alternatively, this step can be incorporated with the Argon pre-sputter cleaning of the trench openings. In this alternative, resistance will be reduced and operating frequency will be increased. 
     Now, referring to FIG. 12, a barrier metal layer  66  is deposited over the cross-linked low-k layer  62  and within the via openings  64 . For example, the barrier metal layer may comprise titanium or a titanium compound, tantalum or a tantalum compound, or tungsten or a tungsten compound and may have a thickness of between about 100 and 200 Angstroms. 
     A copper layer  70  is formed over the barrier metal layer  66 , by any of the conventional means, including physical or chemical vapor deposition, electrochemical plating (ECP), or electroless plating, and so on. Preferably, a copper seed layer us deposited and copper formed by electroless plating. The copper and barrier metal layer are planarized by CMP or FAP, as shown in FIG.  12 . The treated surface  62  of the low-k dielectric and the encapsulating liner layer  52  protect the low-k dielectric layer from copper contamination and deterioration of integrity during polishing. 
     This completes a double damascene structure. If further metallization is to be provided, processing continues, again using the process of the present invention. 
     The process of the present invention provides a method for effectively integrating low dielectric constant dielectrics with copper metallization. The low-k materials are protected from copper mobile ions by a sidewall dielectric liner layer and are protected from harmful effects of plasma etching and ashing by electron-beam curing, or other forms of curing such as ion-beam or X-ray curing. Integration is accomplished using a replacement line and replacement via technique that is applicable to single, double, and triple damascene processes. 
     While the invention has been particularly shown and described with reference to the preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made without departing from the spirit and scope of the invention.