Abstract:
A preferably clear or transparent agent in gel form for carrying out oxidative treatments in various application fields, for example cosmetics, dental technology, pharmacy and cleaning agents. The agent is particularly well suited for use in cosmetic hair treatments such as, for example, blonding, oxidative hair coloring, and permanent hair deformation. The agent contains a mixture of an oxidant, at least one peroxide stabilizer, at least one specific polymer thickener and water or an aqueous solvent.

Description:
CROSS-REFEERENCE TO REALTED APPLICATIONS 
     This application claims priority under 35 U.S.C 119(a)-(d) to German patent application number 10 2004 002 349.2, filed 01/16/2004. 
     BACKGROUND OF THE INVENTION 
     1. Field of the Invention 
     The present invention relates to a, preferably clear or transparent, agent in gel form for carrying out oxidative treatments in various application fields, such as, for example, cosmetics, dental technology, pharmacy and cleaning agents. is particularly well suited for use in cosmetic hair treatments, for example blonding, oxidative hair dyeing and the fixation of permanently deformed hair. The agent of the invention contains a mixture of an oxidant, at least one stabilizer, at least one specific polymer thickener and water or an aqueous solvent. 
     The need for such an agent will be illustrated in the following using the hair cosmetics field as an example. In the hair cosmetics field, oxidant-containing hair-treatment agents are used for various applications, hydrogen peroxide being the most commonly used oxidant contained in said agents. These oxidative hair-treatment agents play an important role in a number of cosmetic hair treatments. In blonding, for example, the hair pigments are oxidatively broken down by the action of oxidant-containing formulations which results in a brightening of the hair. 
     2. Description of Related Art 
     As a rule, blonding agents consist of two components, a hydrogen peroxide-containing formulation and a basic component. peroxodisulfates can be used to achieve a more pronounced effect. Because aqueous hydrogen peroxide solutions are very difficult to apply to the hair in a controlled manner, more or less thickened oxidizing emulsions are used. The consistency-imparting agent for such emulsions is in most cases a long-chain fatty alcohol, the emulsifiers most frequently being fatty alcohol ethoxylates, alkylsulfates, alkyl ether sulfates etc. Although these white formulations can be well localized on the hair, the ability of the hairdresser to see the condition of the hair through the formulation after said formulation has been applied to the hair is very limited. To have control of the brightening efficacy while the brightening formulation is acting on the hair, namely to be able to observe the degree of hair brightening through the applied formulation at any time, it would be desirable for the formulation to be transparent. At the same time, depending on the nature of the product, the formulation should be more or less thickened thus allowing controlled application to the hair, it should not run off the hair and thus it should come in contact with the skin only to a minor extent, which would enhance the product&#39;s acceptance and reduce the risk of skin irritations. 
     These properties (transparency and thickened consistency) would also be desirable for other hair treatments, for example for permanent hair deformation brought about by reducing agent-containing formulations. For lasting hair deformation, the hair is usually first treated with a deformation agent based on a keratin-reducing mercapto compound which opens the disulfide bridges of hair keratin, after which the hair is brought into the desired shape. As a rule, the deformation agent is a keratin-reducing mercapto compound, for example a salt or ester of a mercaptocarboxylic acid. The hair is then rinsed with water and oxidatively post-treated with a fixing agent. As a result, the previously opened disulfide bridges are reconnected in a new way. 
     In certain embodiments of the permanent hair deformation, the hair is first treated with a reducing cream, usually a thioglycolate-containing cream, and then brought into the desired shape by means of suitable auxiliary agents such as clips or a certain kind of rollers. After an exposure time which depends on the condition of the hair, the thioglycolate-based hair-deformation agent is rinsed out after which an oxidant-containing formulation is applied to the hair for fixing purposes. As a rule, the oxidant is hydrogen peroxide. The agents imparting consistency to these emulsions are in most cases long-chain fatty alcohols and the emulsifiers used cases most frequently are fatty alcohol ethoxylates, alkylsulfates and alkyl ether sulfates. 
     Here, too, the drawback of the emulsions is that they are not clear and transparent but white and turbid. After the formulation has been applied, therefore, the hairdresser can observe changes in the shape of the hair only to a very limited extent. To have optimum control over the hair shaping during the action of the fixing formulation on the hair, namely to be able to observe the shape of the hair through the applied formulation at any time, it would be desirable for the formulation to be transparent. At the same time, depending on the nature of the product, the formulation should here, too, be more or less thickened and be salt-resistant so that said formulation could be applied to the hair in controlled manner without it running off. It is particularly advantageous if the agent for oxidative treatment of the hair does not run off the roller at all so that the fixation can be carried out with the hair-dresser&#39;s customer sitting in the upright position and without the customary use of a washing pan during the treatment period. 
     Long-term thickening of oxidant-containing formulations with polymeric thickeners that form transparent gels has a destabilizing effect on the oxidant used. From a technical point of view, this necessarily leads either to poor results because of the reduced oxidant content or to dangerous deformations including destruction of the container holding these agents (known as swelling). When the most frequently employed oxidant, namely hydrogen peroxide, is used, it has thus far been necessary to adjust the pH to 2 to 3 to stabilize the hydrogen peroxide. This leads to another problem: At such a low pH, no suitable thickening polymers are thus far known that would impart to the agent sufficient viscosity and at the same time give a transparent formulation which over a period of 6 months at 40° C. would show a stable viscosity, be peroxide-resistant and have a stable pH. 
     BRIEF SUMMARY OF THE INVENTION 
     The goal was therefore to provide an agent for carrying out oxidative treatment, particularly of hair, that would not show the afore-indicated drawbacks, namely that would have a gel-like consistency, would be transparent at the same time, would not drip off the hair and over a period of 6 months at 40° C. would show a constant viscosity, a constant pH and a constant peroxide content. 
     This goal cannot be reached by selecting a method known to those skilled in the art and consisting of simply thickening an aqueous hydrogen peroxide solution with a thickener that appears to be suitable. Such mixtures do not show the required long-term stability over 6 months at 40° C. 
     Surprisingly, we have now found that this goal can be reached in outstanding manner if the transparent, agent in gel form for the oxidative treatment contains at least one oxidant, at least one specific peroxide stabilizer, at least one specific polymer thickener and water or an aqueous solvent. 
    
    
     DETAILED DESCRIPTION OF THE INVENTION 
     Preferably, the agent is in the form of a gel and most preferably it is in the form of a gel and is transparent. 
     It is possible to use as the oxidant any oxidizing compound that has thus far been used for oxidative treatment of, for example, hair. Examples of such oxidizing compounds are hydrogen peroxide, alkali metal bromates, such as, for example, ammonium bromate, alkaline earth metal bromates, alkali metal persulfates, alkaline earth metal persulfates, ammonium persulfate, alkali metal perborates, alkaline earth metal perborates, ammonium perborate, alkali metal percarbonates, alkaline earth metal percarbonates, ammonium perborate [sic], calcium peroxide and sodium iodate. Preferably, different grades of hydrogen peroxide are used (for example the standard cosmetic grade and particularly a highly stabilized grade). The amount of oxidant present in the fixing agent varies depending on the duration of application and the use temperature. Usually, the oxidant is present in amount from 0.1 to 25 wt. %, preferably in an amount from 2 to 14 wt. % and most preferably in an amount from 4 to 12 wt. %. 
     The pH of the formulation, particularly when a peroxide is used, ranges from 2 to 6 and preferably from 3 to 5. When a bromate is used, the pH preferably ranges from 6 to 9 and most preferably from 7 to 8.5. 
     The agent of the invention also contains one or more stabilizers preferably selected from among the dialkali metal hydrogen phosphates, p-acetamidophenol, hydroxyquinoline salts, salicylic acid and the salts thereof, 1-hydroxyethane-1,1-diphosphonic acid, tetrasodium 1-hydroxyethane-1,1-diphosphonate (CAS 3794-83-0; CTFA: TETRASODIUM ETIDRONATE), tetrasodium iminodisuccinate (CAS 144538-83-0; CTFA: TETRASODIUM IMINODISUCCINATE), ethylenediaminetetraacetic acid tetrasodium salt (INCI: EDTA) and N-(4-ethoxyphenyl)acetamide (CTFA: PHENACETIN). 
     Particularly suitable peroxide stabilizers are those listed in the following table. 
     
       
         
               
               
               
             
           
               
                   
               
               
                 No. 
                 CTFA/INCI Name 
                 Chemical Designation 
               
               
                   
               
             
             
               
                 (1) 
                 DISODIUM PHOSPHATE 
                 disodium hydrogen phosphate 
               
               
                 (2) 
                 ACETAMINOPHEN 
                 p-acetamidophenol 
               
               
                 (3) 
                 HYDROXYQUINOLINE 
                 8-hydroxyquinoline sulfate 
               
               
                   
                 SULFATE 
               
               
                 (4) 
                 SALICYLIC ACID 
                 salicylic acid and the salts 
               
               
                   
                   
                 thereof 
               
               
                 (5) 
                 EDITRONIC ACID 
                 1-hydroxyethane-1,1- 
               
               
                   
                   
                 diphosphonic acid and the 
               
               
                   
                   
                 tetrasodium salt thereof 
               
               
                 (6) 
                 TETRASODIUM 
                 tetrasodium iminodisuccinate 
               
               
                   
                 IMINODISUCCINATE 
               
               
                 (7) 
                 PHENACETIN 
                 N-(4-ethoxyphenyl)acetamide 
               
               
                   
               
             
          
         
       
     
     The peroxide stabilizers, alone or in admixture with one another, are preferably contained in the agent of the invention at a concentration from 0.01 to 2 wt. % and most preferably in an amount from 0.05 to 0.3 wt. %. 
     Preferred are the following peroxide stabilizer combinations:
     EDITRONIC ACID and SALICYLIC ACID   EDITRONIC ACID and DISODIUM PHOSPHATE   TETRASODIUM EDITRONATE and SALICYLIC ACID   TETRASODIUM EDITRONATE and SALICYLIC ACID   TETRASODIUM EDITRONATE and DISODIUM PHOSPHATE   

     The agent of the invention most preferably contains the peroxide stabilizer combination in the following amounts:
     0.1 wt. % of EDITRONIC ACID and 0.1 wt. % of SALICYLIC ACID   0.05 wt. % of EDITRONIC ACID and 0.15 wt. % of DISODIUM PHOSPHATE   0.05 wt. % of TETRASODIUM EDITRONATE and 0.15 wt. % of SALICYLIC ACID   0.15 wt. % of TETRASODIM EDITRONATE and 0.05 wt. % of SALICYLIC ACID   0.1 wt. % of TETRASODIUM EDITRONATE and 0.1 wt. % of DISODIUM PHOSPHATE   

     When only one peroxide stabilizer is used, it is preferably selected from among TETRASODIUM EDITRONATE, salicylic acid and EDITRONIC ACID, the preferred use concentration in each case being 0.2 wt. %. 
     The preferred polymer thickeners are the following: 
     
       
         
               
               
               
             
           
               
                   
               
               
                 No. 
                 INCI/CTFA NAME 
                 Chemical Designation 
               
               
                   
               
             
             
               
                 (8) 
                 ACRYLATES COPOLYMER 
                 Copolymer of acrylic 
               
               
                   
                   
                 acid and methacrylic 
               
               
                   
                   
                 acid or of simple esters 
               
               
                   
                   
                 thereof 
               
               
                 (9) 
                 ACRYLATES/C10–30 
                 Copolymer of C 10-30  alkyl 
               
               
                   
                 ALKYL ACRYLATE 
                 acrylate and acrylic acid, 
               
               
                   
                 CROSSPOLYMER 
                 methacrylic acid or simple 
               
               
                   
                   
                 esters thereof, crosslinked 
               
               
                   
                   
                 with an allyl ether of 
               
               
                   
                   
                 sucrose or an allyl ether 
               
               
                   
                   
                 of pentaerythritol 
               
               
                 (10) 
                 ACRYLATES/ACRYLAMIDE 
                 Copolymer of acrylamide 
               
               
                   
                 COPOLYMER 
                 and acrylic acid, 
               
               
                   
                   
                 methacrylic acid or a 
               
               
                   
                   
                 simple ester thereof 
               
               
                   
                   
                 (CAS No. 9003-06-9) 
               
               
                 (11) 
                 AMMONIUM ACRYLOYLDI- 
                 Copolymer of ammonium 
               
               
                   
                 METHYLTAURATE/ 
                 acryloyldimethyltaurate 
               
               
                   
                 BEHENETH-25 
                 and Beheneth-25 
               
               
                   
                 METHACRYLATE COPOLYMER 
                 methacrylate 
               
               
                 (12) 
                 AMMONIUM ACRYLOYLDI- 
                 Copolymer of ammonium 
               
               
                   
                 METHYLTAURATE/VP 
                 acryloyldimethyltaurate 
               
               
                   
                 COPOLYMER 
                 and vinylpyrrolidone 
               
               
                 (13) 
                 CARBOMER 
                 Homopolymer of acrylic 
               
               
                   
                   
                 acid, methacrylic acid, 
               
               
                   
                   
                 crosslinked with an allyl 
               
               
                   
                   
                 ether of sucrose, of 
               
               
                   
                   
                 pentaerythritol or of 
               
               
                   
                   
                 propylene 
               
               
                 (14) 
                 HYDROXYPROPYL STARCH 
                 Hydroxypropyl ether of 
               
               
                   
                 PHOSPHATE 
                 distarch phosphate 
               
               
                 (15) 
                 POLYQUATERNIUM-44 
                 Copolymer of 3-methyl-1- 
               
               
                   
                   
                 vinyl-1H-imidazolium 
               
               
                   
                   
                 methylsulfate and 1-vinyl- 
               
               
                   
                   
                 2-pyrrolidone 
               
               
                 (16) 
                 POLYQUATERNIUM-37 
                 N,N,N-Trimethyl-2- 
               
               
                   
                   
                 [(methyl-1-keto-2- 
               
               
                   
                   
                 propenyl)oxy] 
               
               
                   
                   
                 chloride homopolymer 
               
               
                 (17) 
                 POLYQUATERNIUM-37, 
                 Mixture of N,N,N- 
               
               
                   
                 MINERAL OIL, SORBITAN 
                 trimethyl-2-[(methyl- 
               
               
                   
                 OLEATE, PEG-1/PPG-6 
                 1-keto-2-propenyl)oxy] 
               
               
                   
                 TRIDECCETH 6, C10–12 
                 chloride, homopolymer, 
               
               
                   
                 ALKANE/CYCLOALKANE 
                 sorbitan monooleate, 
               
               
                   
                   
                 polyethylene glycol/ 
               
               
                   
                   
                 polypropylene glycol 
               
               
                   
                   
                 tridecyl ether, C 10-12 - 
               
               
                   
                   
                 alkanes and cycloalkanes 
               
               
                   
                   
                 (CAS 64742-48-9) 
               
               
                 (18) 
                 POLYQUATERNIUM-37, 
                 Mixture of N,N,N- 
               
               
                   
                 SORBITANE OLEATE, 
                 trimethyl-2-[(methyl-1- 
               
               
                   
                 PROPYLENE GLYCOL 
                 keto-2-propenyl)oxy] 
               
               
                   
                 DICAPRYLATE/DICAPRATE, 
                 chloride, homopolymer, 
               
               
                   
                 PPG-1 TRIDECETH-6, 
                 sorbitan monooleate, 
               
               
                   
                 C10-12 ALKANE/ 
                 propylene glycol 
               
               
                   
                 CYCLOALKANE 
                 dicaprylate 
               
               
                   
                   
                 (EINECS 271-516-3), 
               
               
                   
                   
                 polypropylene glycol 
               
               
                   
                   
                 tridecyl ether, C 10-12   
               
               
                   
                   
                 alkanes and cycloalkanes 
               
               
                   
                   
                 (CAS 64742-48-9) 
               
               
                 (19) 
                 SODIUM MAGNESIUM 
                 Sodium magnesium silicate 
               
               
                   
                 SILICATE 
               
               
                   
               
             
          
         
       
     
     The agent of the invention contains the polymer thickeners, alone or in admixture with one another, preferably in an amount from 0.1 to 5.0 weight percent, most preferably in an amount from 0.5 to 3.0 weight percent and optimally in an amount from 1.5 to 2.5 weight percent. 
     The agent of the invention also contains water or an aqueous solution. The water is preferably present in an amount from 50 to 98 wt. %, more preferably in an amount from 65 to 85 wt. % and most preferably in an amount from 65 to 80 wt. %. 
     The agent of the invention, for example one for oxidative treatment of hair, can contain cationic polymers, preferably in an amount from 0.1 to 2 weight percent, the following cationic polymers or mixtures of said cationic polymers being suitable: cationic cellulose derivatives, for example cationic cellulose ethers (for example CTFA: POLYQUATERNIUM-10), polydimethylaminoethyl methacrylate (75% quaternized with dimethyl sulfate or 100% with methyl chloride or methyl bromide), beta-methacryloxyethyltrimethylammonium methosulfate homopolymers (CTFA: POLYQUATERNIUM-14), beta-methacryloxy-ethyltrime-thylammonium methosulfate/acrylamide copolymers (CTFA: POLYQUATERNIUM-5), beta-methacryloxyethyltrimethylammonium methosulfate/vinylpyrrolidone copolymers (CTFA: POLYQUATERNIUM-11), N-vinylpyrrolidone/methacrylamidopropyltrimethylamammonium chloride copolymers and cationic chitosan derivatives. 
     Particularly preferred among these cationic polymers are the following: polydimethylaminoethyl methacrylate (75% quaternized with dimethyl sulfate), N-vinylpyrrolidone/methacrylamidopropyltrimethylammonium chloride copolymers, beta-methacryloxyethyltrimethylammonium methosulfate/vinylpyrrolidone copolymers and beta-methacryloxyethyl-trimethylammonium methosulfate homopolymers. 
     Moreover, the agent of the invention, particularly one for oxidative treatment of hair, can additionally contain nonionic surface-active compounds, for example fatty alcohol polyglycol ethers with a low degree of ethoxylation, for example ethoxylated alkylphenols with 1 to 5 ethylene oxide units in the molecule, or ethoxylated sorbitan fatty esters. The non-ionic surface-active compounds are contained in the agent of the invention preferably in a total amount from 0.1 to 6 weight percent. 
     The agent of the invention can also contain amphoteric surface-active compounds, for example at a concentration of 0.1 to 3 weight percent, suitable being, for example, the following amphoteric surface-active compounds or mixtures of these amphoteric surface-active compounds: carboxyl derivatives of imidazole, for example CTFA: COCOAMPHODIPROPIONATE, CTFA: SODIUM COCOAMPHOACETATE or CTFA: COCOBETAINAMIDO AMPHOPROPIONATE (CAS 100085-64-1); N-alkylbetains and N-alkylamidobetains, N-alkylsulfobetains, N-alkylaminopropionates, alkyldimethylcarboxymethylammonium salts with 12 to 18 carbon atoms and fatty acid alkylamidobetains, for example fatty acid amidopropyldimethylaminoacetic acid betain. 
     The agent of the invention can of course also contain additives commonly used for such agents, for example dyes or alcohols, for example ethanol, propanol, isopropanol, ethylene glycol, 1,2-propylene glycol and 1,2,3-propanetriol (glycerol); dissolution promoters, buffering substances, perfume oils, defoamers and hair-conditioning or hair-care constituents, for example lanolin derivatives, cholesterol or betain. Moreover, the agent of the invention can contain additional additives, for example swelling and penetration agents, for example urea, 2-pyrrolidone, 1-methyl-2-pyrrolidone and dipropylene glycol monomethyl ether. The agent of the invention contains the additives in an amount from 0.1 to 50 wt. % and preferably from 1 to 20 wt. %. The amount of alcohols used is preferably from 5 to 15 wt. %. 
     The agent of the invention preferably has a viscosity from 100 to 30,000 mPa s, more preferably from 300 to 18,000 mPa s and most preferably from 300 to 5,000 mPa s measured at 25° C. The viscosity data were obtained with a Haake VT 550 Rotational Viscosimeter at a shearing rate of 12.9 per second. An NV- or MV-type double-slit cylindrical measuring device was used. 
     The agent of the invention for carrying out an oxidative treatment can be in the form of a uniform two-component preparation and in that case is prepared only just before use by mixing the pure polymer thickener or a composition containing the polymer thickener (Component 1) with an aqueous solution of the oxidant, preferably with an aqueous hydrogen peroxide solution (Component 2). 
     For decolorizing or blonding hair, too, oxidizing preparations are commonly used which are obtained by dissolving a blonding agent mixture (powdered mixture of alkali metal salts and inorganic persalts, for example sodium persulfate or ammonium persulfate) in an aqueous hydrogen peroxide solution. 
     Our goal was to provide a storage-stable agent for decolorizing or blonding human hair which would be prepared before use by simple shaking or stirring with a thickened, hydrogen peroxide-containing agent and which besides its absolutely dust-free appearance and application form would ensure maximum blonding efficacy and at the same time outstanding storage stability. 
     Before use, a blonding mixture that in and of itself is known is mixed with an aqueous hydrogen peroxide gel to form an applicable blonding agent, the mixing being carried out in a bowl or by shaking in an application bottle. The mixing ratio of blonding agent to oxidant when a 6-12% hydrogen peroxide gel of the invention is used amounts to 1:1 to 1:3. 
     The ready-to-use agent for decolorizing or blonding hair thus obtained is uniformly applied to the hair and after an exposure period of 15 to 60 min at room temperature (20-25° C.) or of 10 to 50 min with heating (30-50° C.) is rinsed out with water. 
     In a particular embodiment of the present invention, the agent of the invention for oxidative treatment can also be formulated as the oxidizing component of an oxidation hair colorant. 
     The ready-to-use oxidation colorant is prepared just before use by mixing a dye carrier composition with the agent of the invention for oxidative treatment. 
     In this case, too, suitable oxidants are mainly hydrogen peroxide or the products of addition thereof to urea, melamine or sodium bromate in a 1-12% and preferably 6% solution, hydrogen peroxide being particularly preferred. 
     To this end, the dye carrier composition and the agent of the invention for oxidative treatment are mixed with one another in a weight ratio of 5:1 to 1:3, a weight ratio of 1:1 to 1:2 being particularly preferred. 
     To adjust the pH of the dye carrier and of the agent of the invention for oxidative treatment, depending on the desired pH, a dilute organic or inorganic acid, for example phosphoric acid, ascorbic acid or lactic acid, or an alkaline substance, for example monoethanolamine, triethanolamine, 2-amino-2-methyl-lpropanol, ammonia, sodium hydroxide, potassium hydroxide or tris(hydroxymethyl)aminomethane, can be used. 
     After the dye carrier composition has been mixed with the agent for oxidative treatment, an amount of the resulting ready-to-use oxidation hair colorant sufficient for the hair treatment is applied to the hair. This amount depends on the hair fullness and generally ranges from about 60 to 200 g. 
     Preferably, the agent for oxidative treatment can be an agent for fixing the hair after a reductive permanent deformation treatment (permanent waving or hair smoothing). 
     The fixing agent is applied after the reductive deformation agent (for example a 10% ammonium thioglycolate solution with a pH of 8.5) has acted for a length of time sufficient to bring about a permanent hair deformation. Depending on the condition of the hair, on the pH, on the deformation efficacy of the agent and on the use temperature, the time of action of the reductive deformation agent is about 5 to 45 minutes (5 to 20 minutes with heating; 20 to 45 minutes without heating). The hair is then rinsed with water after which it is subjected to oxidative post-treatment with about 20 to 300 g and preferably with 60 to 150 g of the fixing agent of the invention (preferably as in Examples 15 to 27). After the fixing agent has acted for about 1 to 20 min and preferably for 6 to 10 min, the rollers are removed and the rolled hair, if necessary, is subjected to another oxidative post-treatment with the fixing agent for 1 to 5 minutes. The hair is then rinsed with water, arranged into a hairdo and dried. 
     The hair thus treated exhibits a uniform and durable deformation and is conditioned in an outstanding manner. 
     The advantages of the agent of the invention lie in an increase in viscosity, in an unproblematic application and particularly in the fact that the formulation exhibits clarity which allows visual control of the action on the hair, and in long-term storage stability of the formulations without undesirable peroxide degradation, undesirable viscosity fluctuations and undesirable changes in pH during storage. 
     The following examples will explain the subject matter of the invention in greater detail. 
     EXAMPLES 
     Example 1 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/VP 
                 2.00 
                 g 
               
               
                 COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 10.00 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 2.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.04 
                 g 
               
               
                 1,2,3-Propanetriol 
                 12.00 
                 g 
               
               
                 Phosphoric acid 
                 0.14 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 9,500 mPa s at 25° C. and a pH of 3.5 
     Example 2 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 2.00 
                 g 
               
               
                 BEHENETH-25 
               
               
                 METHACRYLATE COPOLYMER (No. 11) 
                 [sic] 
               
               
                 Hydrogen peroxide 
                 12.00 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.15 
                 g 
               
               
                 Phosphoric acid 
                 0.13 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 15,000 mPa s at 25° C. and a pH of 4.0. 
     Example 3 
     
       
         
               
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 ACRYLATES/C 10-30  ALKYL ACRYLATE 
                 2.10 
                 g 
               
               
                   
                 CROSSPOLYMER (No. 12) 
               
               
                   
                 Hydrogen peroxide 
                 11.00 
                 g 
               
               
                   
                 EDITRONIC ACID (No. 5) 
                 0.15 
                 g 
               
               
                   
                 Disodium hydrogen phosphate 
                 0.05 
                 g 
               
               
                   
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                   
                 Sodium hydroxide 
                 0.09 
                 g 
               
               
                   
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     The gel had a viscosity of 9,500 mPa s at 25° C. and a pH of 3.5. 
     Example 4 
     
       
         
               
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 POLYQUATERNIUM-37 (No. 16) 
                 2.50 
                 g 
               
               
                   
                 Hydrogen peroxide 
                 12.00 
                 g 
               
               
                   
                 Salicylic acid 
                 0.10 
                 g 
               
               
                   
                 ACETAMINOPHEN (No. 2) 
                 0.10 
                 g 
               
               
                   
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                   
                 Phosphoric acid 
                 0.12 
                 g 
               
               
                   
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     The gel had a viscosity of 7,500 mPa s at 25° C. and a pH of 3.5. 
     Example 5 
     
       
         
               
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 POLYQUATERNIUM 37, MINERAL OIL, 
                 2.50 
                 g 
               
               
                   
                 SORBITAN OLEATE, PPG-1/PPG-6 
               
               
                   
                 TRIDECCETH 6, C 10-12  ALKANE/ 
               
               
                   
                 CYCLOALKANE (No. 17) [sic] 
               
               
                   
                 Hydrogen peroxide 
                 12.00 
                 g 
               
               
                   
                 Salicylic acid 
                 0.15 
                 g 
               
               
                   
                 HYDROXYQUINOLINE SULFATE (No. 3) 
                 0.05 
                 g 
               
               
                   
                 1,2,3-Propanetriol 
                 15.00 
                 g 
               
               
                   
                 Phosphoric acid 
                 0.09 
                 g 
               
               
                   
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     The gel had a viscosity of 6,800 mPa s at 25° C. and a pH of 3.5. 
     Example 6 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 2.00 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 Hydrogen peroxide 
                 9.00 
                 g 
               
               
                 Salicylic acid 
                 0.10 
                 g 
               
               
                 ACETAMINOPHEN (No. 2) 
                 0.10 
                 g 
               
               
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                 Phosphoric acid 
                 0.17 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 23,500 mPa s at 25° C. and a pH of 4.0. 
     Example 7 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 1.00 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/VP 
                 1.00 
                 g 
               
               
                 COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 10.00 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.15 
                 g 
               
               
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                 Phosphoric acid 
                 0.11 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 16,000 mPa s at 25° C. and a pH of 3.5. 
     Example 8 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 ACRYLATES/C10-30 ALKYL ACRYLATE 
                 1.00 
                 g 
               
               
                 CROSSPOLYMER (No. 9) 
               
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 1.00 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 Hydrogen peroxide 
                 10.00 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.15 
                 g 
               
               
                 Castor oil ethoxylated with 35 ethylene oxide groups 
                 0.50 
                 g 
               
               
                 Hydrogenated castor oil ethoxylated with 40 ethylene 
                 1.00 
                 g 
               
               
                 oxide groups 
               
               
                 Perfume oil 
                 0.15 
                 g 
               
               
                 1,2-Propylene glycol 
                 2.00 
                 g 
               
               
                 Ethanol 
                 2.00 
                 g 
               
               
                 Phosphoric acid 
                 0.11 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 19,500 mPa s at 25° C. and a pH of 3.5. 
     Example 9 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 ACRYLATES/C10-30 ALKYL ACRYLATE 
                 2.00 
                 g 
               
               
                 CROSSPOLYMER (No. 9) 
               
               
                 Hydrogen peroxide 
                 10.00 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.15 
                 g 
               
               
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                 Castor oil ethoxylated with 35 ethylene oxide groups 
                 0.50 
                 g 
               
               
                 Hydrogenated castor oil ethoxylated with 40 ethylene 
                 1.90 
                 g 
               
               
                 oxide groups 
               
               
                 Perfume oil 
                 0.15 
                 g 
               
               
                 1,2-Propylene glycol 
                 2.00 
                 g 
               
               
                 Urea 
                 2.00 
                 g 
               
               
                 Isopropanol 
                 2.00 
                 g 
               
               
                 Phosphoric acid 
                 0.15 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 13,000 mPa s at 25° C. and a pH of 4.0. 
     Example 10 
     Component 1 
     AMMONIUM ACRYLOYLDIMETHYLTAURATE/BEHENETH-25 METHA—2.00 g CRYLATE COPOLYMER (No. 11) 
     
       
         
               
             
               
               
               
               
             
           
               
                   
               
               
                 Component 2 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Hydrogen peroxide 
                 9.00 
                 g 
               
               
                   
                 Salicylic acid 
                 0.10 
                 g 
               
               
                   
                 ACETAMINOPHEN (No. 2) 
                 0.10 
                 g 
               
               
                   
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                   
                 Phosphoric acid 
                 0.17 
                 g 
               
               
                   
                 Water, demineralized 
                 to 98.00 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     Components 1 and 2 were mixed with one another just before use. The gel had a viscosity of 22,000 mPa s at 25° C. and a pH of 3.5. 
     Example 11 
     
       
         
               
             
               
               
               
             
           
               
                   
               
               
                 Component 1 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 2.00 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 1,3-Bis(hydroxymethyl)-5,5-dimethylimidazolidin- 
                 0.30 
                 g 
               
               
                 2,4-dione (+) [sic] (CTFA: DMDM 
               
               
                 HYDANTOIN) 
               
               
                 Phosphoric acid 
                 0.20 
                 g 
               
               
                 Water, demineralized 
                 47.50 
                 g 
               
               
                   
               
             
          
         
       
     
     
       
         
               
             
               
               
               
               
             
           
               
                   
               
               
                 Component 2 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Hydrogen peroxide 
                 9.00 
                 g 
               
               
                   
                 Salicylic acid 
                 0.10 
                 g 
               
               
                   
                 ACETAMINOPHEN (No. 2) 
                 0.10 
                 g 
               
               
                   
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                   
                 Phosphoric acid 
                 0.17 
                 g 
               
               
                   
                 Water, demineralized 
                 to 50.00 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     Components 1 and 2 were mixed with one another just before use. The gel had a viscosity of 23,000 mPa s at 25° C. and a pH of 3.0. 
     Example 12 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 2.00 
                 g 
               
               
                 VP COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 6.00 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 2.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.04 
                 g 
               
               
                 1,2,3-Propanetriol 
                 12.00 
                 g 
               
               
                 Phosphoric acid 
                 0.14 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 9,300 mPa s at 25° C. and a pH of 3.5. 
     Example 13 
     Blonding Agent 
     
       
         
               
             
               
               
               
               
             
           
               
                   
               
               
                 Component 1 Blonding agent mixture 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                   
                 Potassium persulfate 
                 25.00 
                 g 
               
               
                   
                 Ammonium persulfate 
                 18.00 
                 g 
               
               
                   
                 Sodium metasilicate 
                 23.00 
                 g 
               
               
                   
                 Sodium alginate 
                 2.00 
                 g 
               
               
                   
                 Xanthan gum 
                 2.00 
                 g 
               
               
                   
                 Acrylic acid polymer (CTFA: Carbomer) 
                 0.50 
                 g 
               
               
                   
                 Isopropyl palmitate 
                 26.50 
                 g 
               
               
                   
                 Beeswax 
                 2.50 
                 g 
               
               
                   
                 Ethylenediaminetetraacetic acid 
                 0.50 
                 g 
               
               
                   
                   
                 100.00 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     In a bowl and by use of a brush, 25 g of the blonding agent mixture (Component 1) was mixed uniformly with 25 g of a hydrogen peroxide-containing gel (Component 2) having the following composition: 
     
       
         
               
             
               
               
               
             
           
               
                   
               
               
                 Component 2 Hydrogen Peroxide Gel 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 2.00 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 Hydrogen peroxide 
                 9.00 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.15 
                 g 
               
               
                 1,2,3-Propanetriol 
                 10.00 
                 g 
               
               
                 Phosphoric acid 
                 0.13 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 23,000 mPa s at 25° C. and a pH of 3.5. 
     The resulting blonding agent was applied uniformly to medium-brown hair and after an exposure time of 30 minutes at room temperature was rinsed out with warm water after which the hair was dried. The hair treated in this manner was brightened to a bright-blond shade. 
     Example 14 
     Oxidation Hair Colorant 
     
       
         
               
             
               
               
               
             
           
               
                   
               
               
                 Component 1 Dye Carrier Composition 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 Ethanol 
                 8.00 
                 g 
               
               
                 Sodium lauryl ether sulfate, 28% aqueous solution 
                 10.00 
                 g 
               
               
                 Ammonia, 25% aqueous solution 
                 9.00 
                 g 
               
               
                 Ascorbic acid 
                 0.30 
                 g 
               
               
                 Sodium sulfite 
                 0.40 
                 g 
               
               
                 Oxidation dye mixture consisting of at least one 
                 5 
                 mmol 
               
               
                 coupler and at least one developer 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     Just before use, 20 g of the dye carrier composition (Component 1) and 20 g of the 6% hydrogen peroxide gel indicated hereinbelow (Component 2) were mixed with one another to obtain the ready-to-use oxidation hair colorant. 
     
       
         
               
             
               
               
               
             
           
               
                   
               
               
                 Component 2 Hydrogen Peroxide Gel 
               
               
                   
               
             
             
               
                   
               
             
          
           
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 2.00 
                 g 
               
               
                 VP COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 6.00 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 2.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.04 
                 g 
               
               
                 1,2,3-Propanetriol 
                 12.00 
                 g 
               
               
                 Phosphoric acid 
                 0.14 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The gel had a viscosity of 10,300 mPa s at 25° C. and a pH of 3.5. 
     The ready-to-use oxidation hair colorant thus obtained was then applied to human hair. After an exposure time of 30 min at 40° C., the hair was washed with a shampoo, rinsed with water and dried. 
     Example 15 
     Fixing Agent 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.60 
                 g 
               
               
                 VP COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide, 50% aqueous solution 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.30 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.80 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.05 
                 g 
               
               
                 Salicylic acid 
                 0.15 
                 g 
               
               
                 1,2,3-Propanetriol 
                 1.00 
                 g 
               
               
                 Sodium hydroxide 
                 0.06 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a pH of 3.5. The viscosity of the agent amounted to 450 mPa s at 25° C. 
     After reductive hair deformation, the hair was fixed as described on page 11, lines 21-30. 
     The hair treated in this manner showed a lasting and uniform deformation and was conditoned in outstanding manner. 
     Example 16 
     Fixing Agent 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.80 
                 g 
               
               
                 VP COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.30 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.10 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.05 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 1,2,3-Propanetriol 
                 1.00 
                 g 
               
               
                 Sodium hydroxide 
                 0.14 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 700 mPa s at 25° C. and a pH of 4.0. 
     Example 17 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.70 
                 g 
               
               
                 VP COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.30 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.05 
                 g 
               
               
                 Salicylic acid 
                 0.15 
                 g 
               
               
                 Panthenol 
                 0.25 
                 g 
               
               
                 Sodium hydroxide 
                 0.10 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 720 mPa s at 25° C. and a pH of 3.0. 
     Example 18 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.70 
                 g 
               
               
                 VP COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.30 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.15 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 PEG/PPG-25/25 DIMETHICONE 
                 1.00 
                 g 
               
               
                 Sodium hydroxide 
                 0.10 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 680 mPa s at 25° C. and a pH of 3.5. 
     Example 19 
     
       
         
               
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 POLYQUATERNIUM 37 (No. 16) 
                 0.80 
                 g 
               
               
                   
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                   
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                   
                 (CTFA: POLYSORBATE 40) 
               
               
                   
                 Perfume 
                 0.30 
                 g 
               
               
                   
                 EDITRONIC ACID (No. 5) 
                 0.15 
                 g 
               
               
                   
                 Salicylic acid 
                 0.05 
                 g 
               
               
                   
                 1,2,3-Propanetriol 
                 3.00 
                 g 
               
               
                   
                 Sodium hydroxide 
                 0.14 
                 g 
               
               
                   
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                   
                 Water 
                 to 100.00 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 700 mPa s at 25° C. and a pH of 3.5. 
     Example 20 
     
       
         
               
               
               
               
             
           
               
                   
                   
               
             
             
               
                   
                 POLYQUATERNIUM 37 (No. 16) 
                 0.80 
                 g 
               
               
                   
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                   
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                   
                 (CTFA: POLYSORBATE 40) 
               
               
                   
                 Perfume 
                 0.30 
                 g 
               
               
                   
                 EDITRONIC ACID (No. 5) 
                 0.15 
                 g 
               
               
                   
                 Salicylic acid 
                 0.05 
                 g 
               
               
                   
                 Cetyltrimethylammonium chloride 
                 0.15 
                 g 
               
               
                   
                 Sodium hydroxide 
                 0.14 
                 g 
               
               
                   
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                   
                 Water 
                 to 100 
                 g 
               
               
                   
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 730 mPa s at 25° C. and a pH of 3.5. 
     Example 21 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.60 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.30 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.70 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.05 
                 g 
               
               
                 Salicylic acid 
                 0.15 
                 g 
               
               
                 1,2,3-Propanetriol 
                 1.00 
                 g 
               
               
                 Sodium hydroxide 
                 0.06 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 500 mPa s at 25° C. and a pH of 3.0. 
     Example 22 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.70 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.30 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.20 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.05 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 1,2,3-Propanetriol 
                 1.00 
                 g 
               
               
                 Sodium hydroxide 
                 0.14 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 750 mPa s at 25° C. 
     Example 23 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.80 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.30 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.05 
                 g 
               
               
                 Salicylic acid 
                 0.15 
                 g 
               
               
                 Panthenol 
                 0.25 
                 g 
               
               
                 Sodium hydroxide 
                 0.10 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 800 mPa s at 25° C. and a pH of 3.5. 
     Example 24 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 ACRYLATES/C 10-30 ALKYL ACRYLATE 
                 0.65 
                 g 
               
               
                 CROSSPOLYMER (No. 9) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.15 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume oil 
                 0.15 
                 g 
               
               
                 1,2,3-Propanetriol 
                 1.00 
                 g 
               
               
                 Ethoxylated castor oil with 35 ethylene oxide groups 
                 0.50 
                 g 
               
               
                 Ethoxylated hydrogenated castor oil with 40 ethylene 
                 1.00 
                 g 
               
               
                 oxide groups 
               
               
                 Panthenol 
                 0.21 
                 g 
               
               
                 Ethanol 
                 2.00 
                 g 
               
               
                 Sodium hydroxide 
                 0.12 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 450 mPa s at 25° C. and a pH of 3.5. 
     Example 25 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 ACRYLATES/C10-30 ALKYL ACRYLATE 
                 0.75 
                 g 
               
               
                 CROSSPOLYMER (No. 9) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 Polyoxyethylene(20) sorbitan monopalmitate 
                 1.00 
                 g 
               
               
                 (CTFA: POLYSORBATE 40) 
               
               
                 Perfume 
                 0.03 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.85 
                 g 
               
               
                 Disodium hydrogen phosphate 
                 0.50 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Ethoxylated hydrogenated castor oil with 60 ethylene 
                 1.00 
                 g 
               
               
                 oxide groups (CTFA: PEG-60 HYDROGENATED 
               
               
                 CASTOR OIL) 
               
               
                 Perfume oil 
                 0.30 
                 g 
               
               
                 1,2-Propylene glycol 
                 2.00 
                 g 
               
               
                 Sodium hydroxide 
                 0.06 
                 g 
               
               
                 Phosphoric acid 
                 0.04 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 600 mPa s at 25° C. and a pH of 3.5. 
     Example 26 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.30 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.32 
                 g 
               
               
                 VP COPOLYMER (No. 12) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.85 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Ethoxylated hydrogenated castor oil with 60 ethylene 
                 1.00 
                 g 
               
               
                 oxide groups (CTFA: PEG-60 HYDROGENATED 
               
               
                 CASTOR OIL) 
               
               
                 Perfume oil 
                 0.30 
                 g 
               
               
                 Sodium hydroxide 
                 0.06 
                 g 
               
               
                 Phosphoric acid 
                 0.07 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 600 mPa s at 25° C. and a pH of 3.5. 
     Example 27 
     
       
         
               
               
               
             
           
               
                   
               
             
             
               
                 AMMONIUM ACRYLOYLDIMETHYLTAURATE/ 
                 0.32 
                 g 
               
               
                 BEHENETH-25 METHACRYLATE COPOLYMER 
               
               
                 (No. 11) 
               
               
                 ACRYLATES/C10-30 ALKYL ACRYLATE 
                 0.32 
                 g 
               
               
                 CROSSPOLYMER (No. 9) 
               
               
                 Hydrogen peroxide 
                 5.00 
                 g 
               
               
                 EDITRONIC ACID (No. 5) 
                 0.85 
                 g 
               
               
                 Salicylic acid 
                 0.05 
                 g 
               
               
                 Ethoxylated hydrogenated castor oil with 60 ethylene 
                 1.00 
                 g 
               
               
                 oxide groups (CTFA: PEG-60 HYDROGENATED 
               
               
                 CASTOR OIL) 
               
               
                 Perfume oil 
                 0.30 
                 g 
               
               
                 Sodium hydroxide 
                 0.06 
                 g 
               
               
                 Phosphoric acid 
                 0.06 
                 g 
               
               
                 Water, demineralized 
                 to 100.00 
                 g 
               
               
                   
               
             
          
         
       
     
     The fixing agent had a viscosity of 750 mPa s at 25° C. and a pH of 4.0.