Abstract:
The invention relates to novel halogenated alkylaryl ethers having at least one fluoroalkyl grouping, which have very good thermal stability and chemical resistance, and to a process for producing the ethers.

Description:
BACKGROUND OF THE INVENTION 
     This invention relates to novel halogenated alkylaryl thermostable ethers and a process for the preparation thereof. 
     BRIEF DESCRIPTION OF THE INVENTION 
     The novel ethers of this invention have the general formula: ##SPC1## 
     Wherein R is an aliphatic saturated radical having the formula CH 2  --OC n  X 2n   +1  and is linear or branched with one tertiary carbon atom located α- to the oxygen atom and substituted by 2 methyl groups, n is equal or greater than 3 when R is linear, or equal or greater than 4 when R is branched, X is F or H, the substituents X being only H on the carbon atom located α to the oxygen atom but at least one of the other substituents X being F, and wherein a is 1 or 2; R&#39; is F, Cl or Z, Z being CH 3 , CF 3  or CF 2  Cl, the substituents R&#39; being identical or different, but only one substituent R&#39; being Z, and b is 0 or an integer from 0 to 6-a. 
     In the formula as defined above, when a is equal to 2, the two radicals R can be respectively in ortho, meta or para positon on the phenyl radical, the optional substituents R&#39; being in any other position. According as a is equal to 1 or 2, monoethers or diethers are prepared. 
     When the products of the present invention are subjected to high temperatures, they have a very good thermal stability and chemical resistance. Due to their physico-chemical properties, i.e., low melting point, high boiling points, and high viscosities, the compounds can be used in lubrication, heat transmission, electrical insulation, hydraulic fluids, or special solvents according to their particular physical form, i.e., solid or liquid at atmospheric pressure and room temperatures. 
     DETAILED DESCRIPTION OF THE INVENTION 
     The novel ethers of the invention can also be defined by the following general formula: ##SPC2## 
     Wherein R&#34; is --CH 2  -- or ##EQU1## and C m  X 2m   +1  is linear fluoroalkyl group in which X is F or H, at least one X being F; m is at least 2 when R&#34; is --CH 2  and at least 1 when R&#34; is ##EQU2## a is 1 or 2; R&#39;&#34; is F, Cl or only one of the groups consisting of CH 3 , CF 3 , and CF 2  Cl; and b is 0-(6-a). The substituents R&#39;&#34; can be the same or different, however, only one of the groups CH 3 , CF 3  and CF 2  Cl can be a substituent alone or with F and/or Cl. Preferably, m is 2-6 when R&#34; is --CH 2  --, and m is 1-6 when R&#34; is ##EQU3## 
     In the above defined general formula, when a is equal to 2, the substituents --CH 2  --O--R&#34;--C m  X 2m   +1 , can be in the ortho, meta or para positions with respect to each other on the phenyl group, and the substituents R&#39;&#34; can be in any of the remaining positions. Thus, when a is 1 or 2, monoethers or diethers are prepared. 
     The compounds according to the present invention are obtained by reaction of a benzyl halide(chloride, fluoride or bromide), its methyl or methyl halogenated derivatives, or one of the halogenated derivatives thereof with a halogenated aliphatic alcohol. The starting halides have the formula: ##SPC3## 
     wherein Y is F, Cl or Br, and R&#39;&#34;, a and b have the same significance as defined above in Formula II. 
     Suitable halides particularly suitable as represented by Formula III are: benzyl chloride, bromide or fluoride; benzyl chlorides, fluorides, bromides mono-substituted in ortho, meta or para position by chlorine or fluorine; di-, tri-, tetra- or penta- substituted benzyl chlorides, fluorides or bromides substituted by chlorine and/or fluorine; tri-fluoromethyl benzyl chlorides, fluorides, bromides; methyl benzyl chlorides, fluorides or bromides; monochloro-difluoro methyl benzyl chlorides, fluorides or bromides; and xylene dichlorides, dibromides, difluorides optionally mono, di-, tri-, or tetra- substituted by chlorine and/or fluorine. 
     Generally the reaction can be achieved by using a chloride, a bromide or a fluoride, but for economical reasons, the chloride is preferably used as a starting material. Moreover, in the most cases, fluorides give yields lower than the chlorides. 
     The halogenated saturated aliphatic alcohols suitable for the present invention are either linear primary alcohols having the formula: 
     
         C.sub.n.sub.-1 X.sub.2(n.sub.-1).sub.+1 CH.sub.2 OH        IV 
    
     wherein X is F or H and at least one X being F, n is an integer equal or greater than 3, or the corresponding tertiary alcohols of the formula: ##EQU4## wherein X is defined above and n is equal or greater than 4 and wherein C n   -  3 X 2n   -  5 is linear. 
     In the practice of the invention, the alcohols preferably used are the alcohols either partly or entirely substituted by fluorine on the carbon atoms which do not carry the alcohol function. Among these alcohols can be cited fluorinated primary alcohols of Formula IV such as 1-propanol, 1-butanol, 1-pentanol, 1-hexanol, 1-heptanol and fluorinated tertiary alcohols of Formula V such as tert-butyl alcohol, tert-amyl alcohol, and the like. 
     For the practice of the invention an alkaline alcoholate is prepared according to any of the known techniques, generally sodium or potassium alcoholate of the used halogenated alcohol. For example, the halogenated alcohol can be reacted with an alkaline metal such as sodium metal in anhydrous medium or with an alkaline hydroxide such as potassium hydroxide. Then the alkaline alcoholate is reacted with the starting halide. 
     The reaction is achieved in the presence of a solvent inert towards the reactants such as for example, dimethyl sulfoxide, tetrahydrofuran, N, N dimethylformamide, diglyme (diethylene glycol dimethyl ether), N-methylpyrrolidine, methyl cyanide. Generally the reaction is achieved at atmospheric pressure and by heating and refluxing the reaction mixture. 
     The ethers, according to the present invention, can be prepared by using stoichiometric quantities of the halide and of the halogenated alcohol but preferably by using an excess of the alcohol. For example, when the reaction is carried out in the presence of metallic sodium with tetrahydrofuran an solvent, an amount of halogenated alcohol comprises within the range from 100 to 150 percent by weight, and preferably from 110 to 130 percent by weight of the molar theoretical quantity, is used. Under these conditions the reaction is relatively slow and its duration is from 2 to 20 hours to obtain a yield at least equal to 90 percent based on the used benzyl halide. When the reaction is achieved by using anhydrous alkaline hydroxide and an aprotic dipolar solvent such as dimethyl sulfoxide (DMSO), a larger excess of alcohol is generally used, this excess amounting up to 200 percent by weight of the molar theoretical quantity and being preferably comprised between 150 and 160 percent by weight. In this case, the reaction is faster and yields equal or superior to 90 percent by weight based on the used benzyl halide can be obtained in 30 to  90 minutes. 
     According to a preferred embodiment of the process of the invention, the reaction is achieved in a single step by introducing into the solvent the halogenated alcohol, the metal or the metallic hydroxide and the starting halide optionally dissolved in a fraction of the solvent and by heating the reaction mixture as said hereinbefore. When the reaction is completed, the reaction mixture is then treated with water to obtain on the one hand an organic phase containing the ether and the unreacted products and on the other hand an aqueous phase containing the alkaline halide formed during the reaction. These two phases are separated according to known techniques and the orginic phase is distilled off under vacuum in order to obtain the aralkyl ether. According to the used method and solvents and the nature of starting reactants, aralkyl ether yields can vary from 60 to 90 percent by weight or more based on the used benzyl halide. 
    
    
     Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The following preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever. 
     EXAMPLE 1 
     In a reaction vessel provided with a magnetic stirrer, a condenser and a dropping funnel, 1.08 mole of metallic sodium (25 g) and 1 mole of pentafluoropropanol-1 (150 g) were introduced and dissolved in 200 ml of tetrahydrofuran previously dried with sodium, thereafter 0.8 mole (100 g) of benzyl chloride in solution in tetrahydrofuran was added, and the reaction mixture was refluxed for 20 hours. 
     Water was then added to the reaction mixture, the sodium chloride in suspension in the aqueous phase was filtered and the organic phase was separated from the aqueous phase by extraction with ethyl ether. After decantation and washing with water, the organic phase was dried with calcium chloride and the ethyl ether was evaporated. The obtained product was distilled under vacuum. 
     175 g of 1,2-pentafluoropropylbenzylether were obtained, which corresponds to a yield equal to 93 percent by weight based on the amount of benzyl halide used. This ether was a liquid having the formula: 
     
         C.sub.6 H.sub.5 CH.sub.2 OCH.sub.2 CF.sub.2 CF.sub.3 
    
     and having the following properties: 
     Boiling point (B.P.): 180° C 
     Melting point (M.P.): -50° C 
     n D   20  : 1,4205 
     In a similar experiment different ethers were obtained by using pentafluoropropanol-1 and various aralkyl halides. Table 1 gives the results obtained. 
     EXAMPLE 2 
     The Example 1 was repeated by using tetrafluoropropanol-1 of formula CHF 2  CF 2  CH 2  OH, and two different halides. The products obtained are shown in table 2. 
     EXAMPLE 3 
     In a reactor vessel equipped as described in Example 1, 1.08 mole of metallic sodium (26 g) and 0.94 mole of pentafluoropropanol-1 (140 g) were dissolved into 200 ml of tetrahydrofuran previously dried with sodium, and 100 g (0.319 mole) of α, α&#39; 2,4,5,6-hexachloro-m-xylene in solution in tetrahydrofuran were introduced. The reaction mixture was refluxed for 20 hours. 
     After reaction, water was added and sodium chloride in suspension in the aqueous phase was separated from the organic phase by extraction with ethyl ether. After decantation and washing with water, the product was dried with calcium chloride and the ethyl ether was evaporated. 
     After distillation under vacuum, there were obtained 165 g of an oily product having the following characteristics: 
     
         B.P. (760 mm Hg)     : 316° C           Viscosity at 20°C                       : 673 cpsM.P.      : -40° C           Viscosity at 37.8°C                       : 143.4 cpsn.sub.D.sup.20     : 1.445           Viscosity at 71°C                       : 22.37 cpsd.sup.20  : 1.6460           Viscosity at 99°C                       : 8.41 cps 
    
     
                                           TABLE 1__________________________________________________________________________Starting halide        Obtained ether Physical constants of                                     N.M.R. spectrum of the                       the obtained ether                                     obtained ether__________________________________________________________________________p-ClC.sub.6 H.sub. 4 CH.sub.2 Cl        p-ClC.sub.6 H.sub.4 CH.sub.2 OCH.sub.2 CF.sub.2 CF.sub.3                       B.P.: 207°C M.P.: -58°C                                     δ CH.sub.2 --O--CH.sub.2                                     = 4.3 singletp-chlorobenzyl chloride        1&#39;2&#39;-pentafluoropropyl-                       n.sub.D.sup.20 : 1.4371                                     δ CH.sub.2 --CF.sub.2                                     --CF.sub.3 = 3.5 triplet        p-chlorobenzyl ether                       d.sup.20 : 1.3489        oil            Viscosity at 20°C:                       3.24. centipoises (cps)3,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 Cl        3,4-Cl.sub.2 C.sub.6 H.sub. 3 CH.sub.2 OCH.sub.2 CF.sub.2        CF.sub.3       B.P.: 245°C M.P.: -101°C                                     δ CH.sub.2 --OCH.sub.2 =                                     4.2 singlet3,4-dichlorobenzyl        1&#39;,2&#39;-pentafluoropropyl-                       n.sub.D.sup.20 : 1.4591                                     δ CH.sub.2 --CF.sub.2                                     --CF.sub.3 = 3.5 tripletchloride     3,4-dichlorobenzyl ether                       d.sup.20 : 1.4634        oil            Viscosity at 20°C:                       6.14 cps2,6-Cl.sub. 2 C.sub.6 H.sub.3 CH.sub.2 Cl        2,6-Cl.sub.2 C.sub.6 H.sub. 3 CH.sub. 2 OCH.sub. 2 CF.sub.2        CF.sub.3       B.P.: 232°C M.P.: -30°C                                     δ CH.sub.2 --O-- CH.sub.                                     2 = 4.5 singlet2,6-dichlorobenzyl        1&#39;,2&#39;-pentafluoropropyl-                       n.sub.D.sup.20 : 1.4617                                     δ CH.sub.2 --CF.sub.2                                     --CF.sub.3 = 3.6 tripletchloride     2,6-dichlorobenzyl ether                       d.sup.20 : 1.461        oil            Viscosity at 20°C:                       7.746 cps2,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 Cl        2,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 OCH.sub.2 CF.sub.2        CF.sub.3       B.P.: 232°C                                     CH.sub.2 --O--CH.sub.2 = 4.4                                     singlet2,4 dichlorobenzyl        1&#39;,2&#39;-pentafluoropropyl-                       M.P.: -93°Cchloride     2,4-dichlorobenzyl ether                       n.sub.D.sup.20 : 1.4608                                     CH.sub.2 --CF.sub.2 --CF.sub.3                                     = 3.7 triplet        liquid2,4,6-Cl.sub.3 C.sub.6 H.sub. 2 CH.sub. 2 Cl        2,4 6-Cl.sub.3 C.sub.6 H.sub. 2 OCH.sub.2 CF.sub.2 CF.sub.3                       B.P.: 248°C                                     CH.sub.2 --O--CH.sub. 2 = 4.9                                     singlet2,4,6-trichlorobenzyl        1&#39; ,2&#39;-pentafluoropropyl-                       M.P.: -70°Cchloride     2,4,6-trichlorobenzyl                       n.sub.D.sup.20 : 1.4880                                     CH.sub.2 --CF.sub.2 --CF.sub.3                                     = 3.8 triplet        ether          d.sup.20 : 1.5265        oil            Viscosity at 20°C                       9.34 cpsC.sub.6 F.sub.5 CH.sub.2 Br        C.sub.6 F.sub.5 CH.sub.2 OCH.sub.2 CF.sub.2 CF.sub.3                       B.P.: 229°CPentafluorobenzyl        1&#39;,2&#39;-pentafluoropropyl-                       M.P.: -40°Cbromide      pentafluorobenzyl ether                       n.sub.D.sup.20 : 1.375__________________________________________________________________________ 
    
     
                                           TABLE 2__________________________________________________________________________Starting halide       Obtained ether                    Physical constants                    of the obtained ether__________________________________________________________________________P-ClC.sub.6 H.sub.4 CH.sub.2 Cl     p-ClC.sub.6 H.sub.4 CH.sub. 2 OCH.sub.2 CF.sub.2 CF.sub.2                    B.P.: 234°Cp-chlorobenzyl     1&#39;,2&#39;-tetrafluoropropyl-                    M.P.: -27°Cchloride  p-chloro benzyl ether                    n.sub.D.sup.20 : 1.46052,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 Cl     2,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 OCH.sub.2 CF.sub.2     CF.sub.2 H     B.P.: 254°C2,4-dichloro-     1&#39;,2&#39;-tetrafluoropropyl-                    M.P.: -70°Cbenzyl chloride     2,4-dichlorobenzyl ether                    n.sub.D.sup.20 : 1.4775                    d.sup.20 : 1.4359                    Viscosity = 9.13 cps                    at 20°C__________________________________________________________________________ 
    
     Table 3 gives the results of the analysis of this product. These results show that this product is a mixture of several compounds. An analytical study by using vapor phase chromatography revealed the presence of two compounds. The main compound was identified by N.M.R. spectrum, as 1&#39;,2&#39;-dipentafluoropropyl-2,4,5,6-chloro-m-xylene diether having the formula: ##SPC4## 
     In a similar manner, a diether was obtained by starting with m-xylylene chloride and pentafluoropropanol-1. The diether was α,α-dipenta-1&#39;,2&#39;-fluoropropyl-m-exlene diether, which was a liquid and had the following properties: 
     B.p.: 240° c 
     m.p.: -85° c 
     n D   20  : 1.4072 
     d 20  : 1.3953 
     Viscosity at 20° C : 8.25 cps. 
     By using tetrafluoropropanol as the alcohol, the para- and meta-xylene dichloride, other diethers were obtained. Their properties are given in table 4. 
     Table 5 gives the results of the analysis of α, α-ditetrafluoro-1&#39;,2&#39;-propyl-p-xylene diether. It was determined that this diether was 95 % pure by using vapor phase chromatography. 
     
                       TABLE 3______________________________________        Calculated    FoundMolecular weight        540           667% C          31.14         29.42% H          1.49          1.41% F          35.18         37.5% Cl         26.26         22.4% halogen    61.14         59.5(Cl + F)______________________________________ 
    
     
                                           TABLE 4__________________________________________________________________________Starting halide        Obtained ether                    Physical constants                               N.M.R. spectrum__________________________________________________________________________p-ClCH.sub.2 C.sub.6 H.sub.4 CH.sub.2 Cl      p-C.sub.6 H.sub.4 (CH.sub.2 OCH.sub.2 CF.sub.2 CF.sub.2      H).sub.2      B.P.: 285°C                               δ CF.sub.2 H: 5.9 triplet                                 of tripletsp-zylene dichloride      α,α &#39;-ditetrafluoro-                    M.P.: -25°C      1&#39;,2&#39;-propyl-p-xylene                    n.sub.D.sup.20 : 1.423                               δ OCH.sub.2 CF.sub.2 : 3.6                               triplet      diether       d.sup.20 : 1.3712                               δ CH.sub.2 --O : 4.4 singlet      oil           Viscosity at 20°C:                    22.75 cpsm-ClCH.sub.2 C.sub.6 H.sub.4 CH.sub.2 Cl      m-C.sub.6 H.sub.4 (CH.sub. 2 OCH.sub.2 CF.sub.2 CF.sub.2      H).sub.2      B.P.: 278°C                               δ CF.sub.2 H: 5.9 triplet                                 of tripletsm-xylene dichloride      α,α&#39;-ditetrafluoro-                    M.P.: -70°C      1&#39;,2&#39;-propyl-m-xylene                    n.sub.D.sup.20 : 1.4237                               δ OCH.sub.2 CF.sub.2 : 3.6                               triplet      diether       d.sup.20 : 1.3715                               δ CH.sub.2 --O:  4.4 singlet      oil           Viscosity at 20°C:                    18.64 cps__________________________________________________________________________ 
    
     EXAMPLE 4 
     In a reactor vessel equipped as described in Example 1, 16.1 g (0.1 mole) of p-chlorobenxyl chloride, 2.76 g (0.12 mole of sodium, and 24 g (0.12 mole) of heptafluorobutanol-1 having the formula CF 3  (CF 2 ) 2  CH 2  OH were dissolved in 60 ml of tetrahydrofuran. The reaction mixture was refluxed for 5 hours. 22.7 g of 1&#39;,2&#39;,3&#39;-heptafluoropropyl-p-chlorobenzyl ether were obtained which corresponds to a yield equal to 70 percent based on the starting halide. The ether had the following formula and properties: 
     
         p-ClC.sub.6 H.sub.4 CH.sub.2 OCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.3 
    
     
         B.P.   : 220°CM.P.   : -27°C            δ--O--CH.sub.2 --CF.sub.2                         = 3.6 tripletn.sub.D.sup.20  : 1.4225  δ--CH.sub.2 --OCH.sub.2                         = 4.2 singlet 
    
     Table 6 gives the analysis results of the prepared ether. 
     By using potassium hydroxide instead of metallic sodium and by performing the reaction with dimethylsulfoxide as the solvent, the reaction yield was equal to 45 percent based on the starting halide. 
     Table 7 gives the properties of different ethers prepared by using heptafluorobutanol-1 and different aralkyl halides, the reaction being effected under the same conditions as hereabove. 
     The vapor phase chromatography analysis was carried out on the product obtained from m-xylene dichloride. This product contained 80 percent by weight of 1&#39;,2&#39;,3&#39;-butyl-m-xylene diether. 
     Table 8 gives the results of the chemical analysis of this product. 
     
                       TABLE 5______________________________________        Calculated    FoundMolecular weight        366.25        366% C          45.91         45.81% H          3.85          4.28% F          41.5          40.53______________________________________ 
    
     
                       TABLE 6______________________________________        Calculated    FoundMolecular weight        324.63        324% C          40.70         37.69% H          2.48          2.79% F          40.97         39.87% Cl         10.92         11.47% total halogen        51.89         51.34(Cl + F)______________________________________ 
    
     
                       TABLE 8______________________________________        Calculated    FoundMolecular weight        502.25        502% C          38.26         39.71% H          2.41          2.68% F          52.96         47.05______________________________________ 
    
     
                                           TABLE 7__________________________________________________________________________Starting halide         Obtained ether                      Physical constants of                                      N.M.R. spectrum                      the obtained ether__________________________________________________________________________2,4-Cl.sub.2 C.sub.6 H.sub. 3 CH.sub.2 Cl      2,4-Cl.sub.2 C.sub.6 H.sub. 3 CH.sub.2 OCH.sub.2 CF.sub.2      CF.sub.2 CF.sub.3                      B.P. : 231°C                                      δ--O--CH.sub.2 --CF.sub.2                                       =3.7                                         triplet2,4-dichlorobenzyl      1&#39;,2&#39;,3&#39;,-heptafluorobutyl-                      M.P. : -42°Cchloride   2-4,-dichlorobenzyl ether                      n.sub.D.sup.20 : 1.4355                                      δ--CH.sub.2 --O--CH.sub.2                                       =4.4                                         singlet                      d.sup.20 : 1.5021                      Viscosity at 20°C:7.15 cpsp-ClCH.sub.2 C.sub.6 H.sub.4 CH.sub.2 Cl      p-CF.sub.3 CF.sub.2 CF.sub.2 CH.sub. 2 OCH.sub.2 C.sub.6      H.sub.4 CH.sub.2 --                      B.P. : 258°C                                      δ--O--CH.sub.2 --CF.sub.2                                       =3.6                                         tripletp-xylene dichloride      OCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.3                      M.P. : -13°C      α,α&#39;1&#39;,2&#39;,3&#39; diheptafluo-                      n.sub.D.sup.20 : 1.3903                                      δ--CH.sub.2 --O--CH.sub.2                                       =4.3      robutyl-m-xylyle diether           singletm-ClCH.sub.2 C.sub.6 H.sub.4 CH.sub.2 Cl      m-CF.sub.3 CF.sub.2 CF.sub.2 CH.sub.2 OCH.sub.2 C.sub.6      H.sub.4 CH.sub.2 --                      B.P. : 252°C                                      δ--O--CH.sub.2 --CF.sub.2                                       =3.7                                         tripletm-xylene dichloride      OCH.sub.2 CF.sub.2 CF.sub.2 CF.sub.3                      M.P. : -78°C      α,α&#39;-1&#39;,2&#39;,3&#39;-diheptafluo-                      n.sub.D.sup.20 : 1.3992                                      δ CH.sub.2 --O--CH.sub.2                                      =4.4      robutyl-m-xylyle diether           singlet                      d.sup.20 : 1.4565                      Viscosity at 20°C:14.62 cpsm-ClCH.sub.2 C.sub.6 Cl.sub.4 CH.sub.2 Cl      m-C.sub.6 Cl.sub.4 (CH.sub.2 OCH.sub.2 CF.sub.2 CF.sub.2      CF.sub.3).sub.2 B.P. : 323°Cα,α&#39;-2,4,5,6-hexa-      α,α&#39;-1&#39;,2&#39;,3&#39;-diheptafluoro-                      M.P. : -35°Cchloro-m-xylene      butyl-tetrachlorobenzyl-m-      xylene dieter   n.sub.D.sup.20 : 1.419                      Viscosity at 20°C:700__________________________________________________________________________                      cps 
    
     EXAMPLE 8 
     In a reactor vessel equipped as described in Example 1, 0.06 mole (13 g) of m-trifluoromethylbenzyl chloride, 0.1 mole (20 g) of heptafluorobutanol-1, and 0.12 mole (6.72 g) of anhydrous potassium hydroxide were dissolved in 45 g of dimethylsulfoxide. 
     The reaction mixture was refluxed for 90 minutes, then water was added and the mixture was heated. The organic phase was washed with water, extracted with ethyl ether and purified with active carbon. 
     The ethyl ether was removed and the obtained product was submitted to a fractional distillation. There were obtained 17 g of 1&#39;,2&#39;,3&#39;-heptafluorobutyl-m-trifluoromethylbenzyl ether having the formula m--CF 3  C 6  H 4  CH 2  OCH 2  (CF 2 ) 2  CF 3 . The reaction yield was equal to 70 percent based on the starting halide. The ether had the following properties. 
     B.p.: 205° c 
     m.p.: -108° c 
     n D   20  : 1.3835 
     EXAMPLE 6 
     Bu using the mode of operation of Example 1 and octafluoropentanol-1 having the formula H(CF 2 ) 4  CH 2  OH, other ethers were obtained. Table 10 gives the starting halide and properties of the ethers obtained. 
     N.M.R. spectrum achieved on the 1&#39;,2&#39;,3&#39;,4-octafluoropentyl-2,4,6-trichlororbenzyl ether confirms its structure. ##SPC5## 
     δ(CF 2 ) 4  --H: 6 triplet of triplets 
     δO -- CH 2  --(CF 2 ) 4  : 4 triplet 
     δCH 2  --O--CH 2  : 4.8 singlet 
     Table 9 gives the chemical analysis of this ether. 
     
                       TABLE 9______________________________________        Calculated    FoundMolecular weight        422           425% C          31.9          33.8% H          1.78          1.65% Cl         25.96         25% F          34.6          35.72% total halogen        60.56         60.72(Cl and F)______________________________________ 
    
     EXAMPLE 7 
     1&#39;H,1&#39;H,7&#39;H-dodecafluoroheptyl-2,4-dichlorobenzyl ether was obtained by starting from 1H,1H,7H-dodecafluoro-1-heptanol and 2,4-dichlorobenzyl dichloride. 
     
         2,4Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 --OCH.sub.2 (CF.sub.2).sub.5 CHF.sub.2 
    
     b.p.: 276° c 
     m.p.: 45° c 
     example 8 
     in a reactor vessel as described in Example 1, 24 g (0.15 mole of 2-methyl-3,3,4,4-tetrafluoro-2-butanol, 15.7 g (0.12 mole) of benzyl chloride and 9.7 g (0.17 mole) of anhydrous potassium hydroxide were 
     
                                           TABLE 10__________________________________________________________________________Starting halide       Obtained ether     Physical constants__________________________________________________________________________o-ClC.sub.6 H.sub.4 CH.sub.2 Cl       o-ClC.sub.6 H.sub.4 CH.sub.2 OCH.sub.2 (CF.sub.2).sub.4                          B.P. : 243°Corthothlorobenzyl       1&#39;,2&#39;,3&#39;,-octafluoro-                          M.P. : -75°Cchloride    penthyl-ortho-chlorobenzyl ether                          n.sub.D.sup.20 : 1.43002,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 Cl       2,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 OCH.sub.2 (CH.sub.2).sub       .4 H               B.P. : 264°C2,4-dichlorobenzyl       1&#39;,2&#39;,3&#39;,4;-octafluoro-pentyl                          M.P. : -75°Cchloride    2,4 dichlorobenzyl ether                          n.sub.D.sup.20 : 1.4505       oil                d.sup.20 : 1.5378                          Viscosity at 20°C 10.51                          cps2,4,6-Cl.sub.3 C.sub.6 H.sub.2 CH.sub.2 Cl       2,4,6Cl.sub.3 C.sub.6 H.sub.2 CH.sub.2 OCH.sub.2 (CF.sub.2).su       b.4 H              B.P. : 284°C2,4,6-trichlorobenzyl       1&#39;,2&#39;,3&#39;,4&#39;-octafluoro-penthyl                          M.P. : &lt;-75°Cchloride    2,4,6,-trichlorobenzyl ether                          n.sub.D.sup.20 : 1.4597       oil                d.sup.20 : 1.6059                          Viscosity at 20°C                          33.52 cpsm-ClCH.sub.2 C.sub.6 H.sub.4 CH.sub.2 Cl       m C.sub.6 H.sub.4 (CH.sub.2 OCH.sub.2 CF.sub.2 CF.sub.2       --CF.sub.2 CF.sub.2 H).sub.2                          B.P. : 295°Cm-xylene dichloride       α,α&#39;-1&#39;,2&#39;,3&#39;,4&#39;,-dioctafluoro-                          M.P. : &lt;-75°C       penthyl-m-xylene diether                          n.sub.D.sup.20 : 1.397                          d.sup.20 : 1.5315                          Viscosity at 20°C                          36.55 cps__________________________________________________________________________ 
    
     dissolved in 150 ml of dimethylsulfoxide. The reaction mixture was refluxed for 90 minutes. After cooling, the reaction mixture was washed with water and the organic phase was treated with ethyl ether and dried. The resulting organic phase was distilled under vacuum (5mm Hg) to yield 15 g of 1,1-dimethyl-2,2,3,3-tetrafluoropropylbenzyl ether having the formula: ##EQU5## This compound was an oily liquid which had the following properties: B.P.: 210° C 
     M.p.: -78° c 
     n D   20  : 1.4479 
     d 20  : 1.1961 
     Viscosity at 20° C: 6.84 cps 
     The yield was 54 percent by weight based on the amount of benzyl chloride used. The nuclear magnetic resonance analysis showed: 
     δ -- CH 2  -- O: 4.5 p.p.m. 
     δ -- (CH 3 ) 3  --: 1.42 p.p.m. 
     δ -- CF 2  H: 6.04 p.p.m. 
     δ -- φ: 7.33 p.p.m. 
     These data are consistent with and support the ether structure. 
     In a similar manner other ethers were obtained by starting with 2-methyl-3,3,4,4-tetrafluoro-2-butanol and different halides. Table 11 gives the starting halides used and the obtained results. 
     
                                           TABLE 11__________________________________________________________________________Starting halide   Obtained ether                           Physical constants of                                       N.M.R. spectrum of                           the obtained ether                                       the obtained__________________________________________________________________________                                       ether           CH.sub.3           |p-ClC.sub.6 H.sub.4 CH.sub.2 Cl           p-ClC.sub. 6 H.sub.4 CH.sub.2 OC--CF.sub.2 CF.sub.2                           B.P.:230°C M.P.:-8°C                                       δ--CH.sub.2 --O                                              =4.48 p.p.m.           |           CH.sub.3p-chlorobenzyl chloride           1,1-dimethyl-2,2,3,3-tetra-                           n.sub.D.sup.20 : 1.4649                                       δ--(CH.sub.3).sub.2                                              = 2.4  p.p.m.           fluoropropyl-p-chlorobenzyl                           d.sup.20 : 1.2828                                       δ--CH.sub.2 H--                                              = 6  p.p.m.           ether           γ.sup.20 : 10.88 cps                                       δ--φ--                                              =7.25 p.p.m.2,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 Cl           CH.sub.3        B.P.:270°C M.P.:-10°C                                       δ--CH.sub.2 --O                                              =4.6  p.p.m.           |2,4-dichlorobenzyl chloride           2,4-Cl.sub. 2 C.sub.6 H.sub.3 CH.sub.2 OCCF.sub.2           CF.sub.2 H      n.sub.D.sup.20 : 1.4776                                       δ--(CH.sub.3).sub.2                                              =1.5  p.p.m.           |           CH.sub.3        d.sup. 20 : 1.3683                                       δ--CF.sub.2 H                                              =6  p.p.m.           1&#39;,1&#39;-dimethyl-2&#39;,2&#39;,3&#39;,3&#39;-                           δ.sup.20 : 15.97 cps                                       δ--φ&lt;                                              = 7.29 p.p.m.           tetrafluoropropyl-2,4-di-           chlorobenzyl ether3,4-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 Cl           CH.sub.3        B.P.:280°C M.P.:10°C                                       δ--CH.sub.2 --O                                              = 5.25 p.p.m.           |3,4-dichlorobenzyl chloride           3,4Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 OCCF.sub.2 CF.sub.2           H               n.sub.D.sup.20 : 1.4851                                       δ--(CH.sub.3).sub.2                                              = 1.65 p.p.m.           |           CH.sub.3        d.sup.20 : 1.3743                                       δ--(CF.sub.2 H)                                              =7.05 p.p.m.           1&#39;,1&#39;-dimethyl-2&#39;,2&#39;,3&#39;,3&#39;-                           δ.sup.20 : 15.99 cps                                       δ--φ&lt;                                              = 8.6  p.p.m.           tetrafluoropropyl-3,4-di-           chlorobenzyl ether2,6-Cl.sub.2 C.sub.6 H.sub.3 CH.sub.2 Cl           CH.sub.3        B.P.:273°C M.P.:17°C                                       δ--CH.sub.2 --O                                              = 5.25 p.p.m.           |2,6-dichlorobenzyl chloride           2,6-Cl.sub. 2 C.sub.6 H.sub.3 CH.sub.2 OCCF.sub.2           CF.sub.2 H      n.sub.D.sup.20 : 1.4798                                       δ--(CH.sub.3).sub.2                                              = 1.5  p.p.m.           |           CH.sub.3        d.sup.20 : 1.3730                                       δ--CF.sub.2                                              = 6.75 p.p.m.           1&#39;,1&#39;-dimethyl-2&#39;,2&#39;,3&#39;,3&#39;-                           δ.sup.20 : 26.39 cps                                       δ--φ--                                              =8.2 p.p.m.           tetrafluoropropyl-2,6-           dichlorobenzyl ether2,4,6-Cl.sub.2 C.sub.6 H.sub.2 CH.sub.2 Cl-           CH.sub.3        B.P.:280°C M.P.:45°C|2,4,6-trichlorobenzyl           2,4,6Cl.sub.2 C.sub.6 H.sub.2 CH.sub.2 OCCF.sub.2           CF.sub.2 H      n.sub.D.sup.20 : 1.5529           |chloride        CH.sub.3        solid           1&#39;,1&#39;-dimethyl-2&#39;,2&#39;,3&#39;,3&#39;-           tetrafluoropropyl-2,4,6-           trichlorobenzyl ether__________________________________________________________________________ 
    
     EXAMPLE 9 
     In a reactor vessel as described in Example 1 and the procedure therein, 40 g (0.249 mole) of 2-methyl 3,3,4,4-tetrafluoro-2-butanol, 18 g (0.104 mole) of 1, 3bis (chloromethyl) benzene, 16.4 (0.29 mole) of anhydrous potassium hydroxide were dissolved in 150 ml of dimethylsulfoxide. 
     After reaction, 13 g of an oily product were obtained, which corresponds to a yield equal to 33 percent by weight based on the amount of halide used. The ether had the following properties: 
     B.p.: 305° c 
     m.p.: -45° c 
     n D   20  : 1.4392 
     D 20  : 1.2856 
     γ20: 55.52 cps 
     N.m.r. analysis showed: 
     δ CH 2  --O: 4.5 p.p.m. 
     δ (CH 3 ) 2  : 1.4 p.p.m. 
     δ CF 2  H: 5.46 p.p.m. 
     δ -- φ--: 7.3 p.p.m. 
     The data supports the following ether structure: ##EQU6## α,α&#39;,-di(1&#39;,1&#39;-dimethyl-2&#39;,2&#39;,3&#39;,3&#39;-tetrafluoropropyl)-m- xylene diether. 
     In a similar manner, the α,α&#39;-di(1&#39;,1&#39;-dimethyl-2&#39;,2&#39;,3&#39;,3&#39;,-tetrafluoropropyl)-p-xylene diether was obtained by using the 1,4-bis-(chloromethyl) benzene. The obtained product was a solid having the following properties: 
     B.p.: 300° c 
     m.p.: 30°-34° c 
     n D   20  : 1.4384 
     N.m.r. spectrum 
     δ CH 2  -- O: 4.5 p.p.m. 
     δ (CH 3 ) 2  : 1.4 p.p.m. 
     δ CF 2  H: 6 p.p.m. 
     δ -- φ: 7.25 p.p.m. 
     The N.M.R. spectrum of the ethers obtained according to the present invention were achieved by using a 60 M.C. apparatus and the molecular weights were determined by mass spectrography. 
     The chemical settings (δ) of the N.M.R. spectrum are given in parts per million (p.p.m.).