Abstract:
A process and a device implementing the process, for separating fluids in emulsion and/or in solution, and/or for low pressure distillation, in particular of water and/or gaseous hydrocarbons dissolved in crude petroleum, and/or for separation of crude petroleum droplets emulsified in water, to obtain water with necessary characteristics for its injection without pollution of underground aquifers, and/or when the mixture is dominant in crude petroleum, acceleration of settling of the water in the lower part of the mixture, and/or for low pressure distillation of crude petroleum. The method creates a localized zone of reduced pressure on part of the free surface of a liquid to be processed, within a closed processing tank, without the overall pressure inside the closed processing tank being affected.

Description:
BACKGROUND OF THE INVENTION 
       [0001]    1. Field of the Invention 
         [0002]    The present invention refers to a process for separation of fluids in emulsion and/or in solution, and/or for low pressure distillation of fractions of same, and to the device for implementing the process. The separation of the fluids will be done by locally reducing the relative pressure on a particular part of the free surface of the liquids, the process making possible the degasification and separation of the liquids contained in a closed processing tank, without affecting the service pressure prevailing inside the processing tank. 
         [0003]    2. Discussion of the Background 
         [0004]    The separation as stated above, in accordance with the background art, is done by applying a partial vacuum to the processing equipment in its entirety and not just to a part of its interior. 
         [0005]    Also according to the background art, in the case of large processing tanks, the costs of construction and installation of the same so as to withstand negative pressures are elevated, and what is more there is always the risk of vacuum-induced collapse and explosion due to fuel getting in. 
         [0006]    Moreover according to the background art, the hydrocarbon processing industry is quite familiar with two or three phase separators, which operate on the basis of the Stokes law, these being used for the separation of liquids in emulsion and gases in solution, such separation being relatively slow. 
       SUMMARY OF THE INVENTION 
       [0007]    One object of the present invention is to do away with the above drawbacks, by providing a process based on the Bernoulli laws, according to which a fluid in moving over a surface brings about a pressure reduction at the surface, one conspicuous example of its application being the creation of lift on the wings of aircraft, in that the pressure reduction at the upper surface or extrados of the wing is greater than the pressure reduction on the lower surface or intrados of the wing, owing to the more convex profile (the extrados) of the former, which forces the air to move more quickly on this one than on the intrados, thereby producing, thanks to the pressure difference at the two surfaces, a force directed upward, providing the lift characteristic of the wing. 
         [0008]    Consequently, the present invention applies the principle of pressure reduction with increase in velocity of a gas moving over a surface and tangentially to the same, so that, in the processing device where this localized pressure reduction is generated, there is encouraged a separation of fluids in emulsion and/or in solution, and/or a low pressure distillation of the components of the fluid, the evaporated components afterwards being processed and recovered. 
         [0009]    A current of gas projected onto and tangentially to a free surface of a liquid will bring about a pressure reduction at the area of contact between the gas and the liquid, as described above, creating the conditions for the components with less vapor pressure to gradually separate from the liquid, as well as a faster migration to the surface of the dissolved gases and of the liquid in emulsion with less specific gravity. 
         [0010]    According to the invention, the localized pressure reduction at the particular part of free surface of the liquid is achieved by projecting a current of gas against the particular part of the free surface and tangentially to same, and the current of processing gas before making contact with the free surface makes an angle which can vary between zero and thirty degrees. Preferably, the angle is five degrees. The processing gas which is projected onto the surface is a gas compatible with the liquid contained in the processing tank or an inert gas, so as to eliminate any risks inherent to the nature of the liquid, such as fire, pollution, explosion, etc. 
         [0011]    The gas current can be applied in a particular part of the free surface of a liquid contained in a closed processing tank or it can be applied on a specific surface over which the liquid will flow so as to increase the area/volume ratio and thus the separation yield and the volume of liquid being processed. In this case, the surface can be planar or assume any other adequate shape for the intended purpose, preferably the shape of the extrados of an aircraft wing. 
         [0012]    Therefore, one way of improving the process of the present invention is to use a platform on whose surface the liquid to be processed flows, so as to increase the area/volume ratio of liquid on the free surface of the platform, and to project a current of gas onto the surface tangentially, the current of processing gas making a certain angle before it comes into contact with the free surface, which can vary between zero and thirty degrees, the angle being preferably five degrees. In accordance with what has just been noted, such a platform preferably will have the shape of the extrados of an aircraft wing. 
         [0013]    The generating of a localized pressure reduction inside a closed processing tank on the particular part of free surface of the liquid by projecting a the current of processing gas against and tangentially to the same, the current of processing gas making a particular angle before coming into contact with the surface, in accordance with the present invention, is novel with regard to the background art. The present invention can be applied especially to petroleum products, without restricting its application to other fluids and, in particular, to the separation of water in emulsion and gases in solution in crude petroleum or in its subproducts, and/or to distillation of fractions of crude petroleum or its subproducts, by a pressure reduction on a particular part of the surface of the crude petroleum, or its subproduct, without generating a partial vacuum or excess pressure in the internal environment of the processing tank or receptacle, being therefore more efficient in terms of process speed, energy consumption, cheapness and safety, than background processes for the same purpose. 
         [0014]    One case illustrating the present invention is a closed processing tank, inside which the pressure is reduced in only one particular part of the free surface of the liquid, by the projecting of a current of processing gas against the part of free surface of the liquid, thereby generating a pressure reduction in the zone of contact between the part of free surface of the liquid and the current of processing gas, such that the range of influence of the reduced pressure does not affect the general pressure inside the tank, which does not undergo any reduction, and therefore no outside gases are admitted into the tank, with the accompanying risk of formation of flammable mixtures, an explosion. 
         [0015]    One application of the process of the present invention involves the separation of crude petroleum, coming from the production wells, from the water which it contains in emulsion and from part of the gas in solution in same. The crude petroleum, stored within a processing tank, will be made to flow over a platform, arranged for this purpose inside the tank at a certain distance above the free surface of the crude petroleum, which may or may not be heated, against which there is made to impinge a current of gas onto the free surface of the crude petroleum in movement on the platform and tangentially to the surface, the current of gas making an angle before impinging on the surface, which may vary between zero and thirty degrees, the angle preferably being five degrees, bringing about a pressure reduction on the free surface, and the crude petroleum being continually recirculated, until one has achieved a substantial migration of the water to the bottom of the receptacle, from which it is drained, and the liberation of the gases in solution in the crude petroleum, and the desired final product is obtained, namely, crude petroleum with lesser percentage of water and stabilized at the required temperature by degasification. It is within the scope of the invention to arrange several other platforms placed in series within the processing tank. 
         [0016]    Another application of the process of the present invention includes the separation of the water coming from the above-mentioned processing from the residual hydrocarbons so that it can be injected, upon reaching a concentration of hydrocarbons on the order of 15 parts per million or less, into the subsoil without polluting the existing paretic zones with such hydrocarbons, the water being subjected to a processing equal to that of the preceding paragraph. Thanks to the pressure reduction on the platform, the droplets of crude petroleum and the gases lighter than water tend to evaporate and will either be entrained by the current of gas or will emerge onto the surface for subsequent decanting. 
         [0017]    It is within the scope of the invention that the projecting of a current of processing gas is done either in opposite current or concurrent manner. 
         [0018]    It is also within the scope of the invention that the process of the present invention can be done inside a hydrocyclone. As is known, hydrocyclones make possible, for a particular volume of equipment, a greater area of contact with a current of processing gas. The processing gas is projected against the crude petroleum, containing water and gas, which upon being centrifuged against the walls of the hydrocyclone during the centrifugation process inside the hydrocyclone, creates an interior free surface of truncated conical shape, with the hydrocarbons being closer to the axis and the water to the walls. The current of processing gas is then projected onto and tangentially to this surface with an annular shape, the current of processing gas making an angle before coming into contact with the surface, which can vary between zero and thirty degrees. Preferably, the angle is five degrees. In this way, one obtains a cylindrical contact surface between the gas and the liquid, which allows one to apply the process of localized pressure reduction on a greater surface for a particular equipment volume. The hydrocyclone can be installed independently or it can be an integral part of the processing equipment. 
         [0019]    It is also within the scope of the invention to carry out the process within an independent apparatus or one inserted within processing equipment such as, without being restricted hereto, storage tanks, dehydration and degasification tanks, and phase separators. 
         [0020]    It is also within the scope of the invention to use Venturis in order to create the localized partial vacuum on a surface. As is known, Venturis are static machines used for the movement of fluids, which exploit the partial vacuum created by the application of a driving fluid. 
         [0021]    The aspiration brought about by the Venturi will create a movement of gas present in the process apparatus, which in moving over the free surface of the liquid will bring about a localized pressure reduction in this area. 
         [0022]    The processing gas, after passing over the free surface of the liquid, is saturated with the components removed from same and it will be processed thereafter, in order to separate these components via an exchanger, which cools down the gas and condenses the separated gases, which will be taken outside of the apparatus for subsequent processing. The depleted gas will return to the processing apparatus and be used again as the processing gas, perhaps with addition, when necessary, of another processing gas. Any overall pressure rise due to operating abnormality is controlled by a properly calibrated and fast-opening safety valve. The process of the invention is energy-efficient when compared to the existing alternatives, since it only moves the quantity of gas necessary to obtain a localized partial vacuum, and the processing apparatus does not need to be designed for negative pressures. 
         [0023]    The present invention also refers to the devices used to implement the process. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         [0024]    The characteristics and additional aspects of the invention will be better understood by reading the description of preferred embodiments of the invention, furnished as illustrative but not limiting examples and shown on the attached drawings, in which: 
           [0025]      FIG. 1  shows a simplified schematic view in cross section of a processing tank in which the theoretical process of the invention is carried out; 
           [0026]      FIG. 2  shows another simplified schematic view in cross section of a processing tank in which the theoretical process of the invention is carried out; 
           [0027]      FIG. 3  shows a schematic view in partial cross section of an installation to carry out the process according to the present invention; 
           [0028]      FIG. 4  shows a schematic and partial cross sectional view of an installation which includes a hydrocyclone to carry out the process according to the present invention; 
           [0029]      FIG. 5  shows a schematic and partial cross sectional view of a hydrocyclone in which the process according to the present invention is carried out; 
           [0030]      FIG. 6  shows a schematic and partial cross sectional view of another installation to carry out the process according to the present invention; and 
           [0031]      FIG. 7  shows a schematic and partial cross sectional view of yet another installation to carry out the process according to the present invention. 
       
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
       [0032]      FIG. 1  shows one theoretical way of implementing the process according to the invention, in which the crude petroleum with water in emulsion and dissolved gas, that is, the crude petroleum to be processed  2 , is introduced into the closed processing tank  1  where the crude petroleum will be stored, via the inlet pipe  2   a , until the time when it leaves, after processing, via the outlet pipe  8 , in static or dynamic manner (that is, the crude petroleum  2  enters the tank simultaneously with the leaving of the already processed crude petroleum). The processing gas  3  is compressed by a compressor  4 , a current of processing gas  3  being projected, via an injector  4   a , onto and tangentially to the free surface of the crude petroleum, the current of processing gas  3  making a particular angle with the free surface of the crude petroleum before reaching the surface, which can vary between zero and thirty degrees, the angle preferably being between 0 and 8 degrees, but preferably five degrees. In the zone of influence of the current of processing gas  3  there is created a localized zone of reduced pressure  5  on the surface of the crude petroleum. The compressor  4  is fed by the actual gas present in the tank or by a compatible gas arriving from the outside by the pipe  21 , or by a mixture of same. 
         [0033]    In the localized zone of reduced pressure  5 , the gas and water in emulsion will separate from the crude petroleum  2  with a speed that depends on the velocity of the processing gas  3 , which creates the localized zone of reduced pressure  5  on the interface with the crude petroleum being stored, and a gaseous mixture  6  is formed, which leaves the tank by the pressure regulating valve  7 , being able to go directly on to further processing or return in whole or in part via a three-way control valve  9 . 
         [0034]    The gas above the free surface of the crude petroleum will be maintained at the service pressure prevailing inside the closed processing tank  1 , by the action of the pressure regulating valve  7  and the overpressure rapid relief valve  10 , which is the current practice in the oil industry. 
         [0035]    The water separated will drop slowly by gravity to the bottom of the tank and will be drained in usual manner into the storage tanks of the oil industry by the bottom pipe  11 . 
         [0036]    The degasified and dehydrated oil will leave the closed processing tank  1  by the outlet pipe  8  for further processing or exporting. 
         [0037]      FIG. 2  shows another theoretical way of implementing the process, in which the crude petroleum with water in emulsion and dissolved gas, that is, crude petroleum to be processed  2 , is introduced into a closed processing tank  1  by the inlet pipe  2   a , being sprinkled over a plate  2   b . The crude petroleum is stored until the time it leaves through the outlet pipe  8 , in static or dynamic manner. The processing gas  3  is compressed by a compressor  4 , a current of the processing gas  3  being projected via the injector  4   a  onto and tangentially to the free surface of the crude petroleum, the current of the processing gas  3  making a particular angle with the free surface of the crude petroleum on the plate  2   b , before reaching the surface, which angle may vary between zero and thirty degrees, the angle being preferably between 0 and 8 degrees, but preferably five degrees. The compressor  4  is fed by the actual gas present in the tank or by compatible gas coming from the outside, or by a mixture of same. 
         [0038]    In the localized zone of reduced pressure  5 , the gas and water in emulsion will separate from the crude petroleum  2  with a speed that depends on the velocity of the processing gas  3 , which creates the partial vacuum on the interface with the crude petroleum being stored, and a gaseous mixture  6  will be formed, which will leave the tank  1  by the pressure regulating valve  7 , being able to go directly on to further processing or return in whole or in part via a three-way control valve  9 . 
         [0039]    The gas above the free surface of the crude petroleum will be maintained at the service pressure prevailing inside the closed processing tank  1 , by the action of the pressure regulating valve  7  and the overpressure rapid relief valve  10 , which is the current practice in the oil industry. 
         [0040]    The water separated will drop slowly by gravity to the bottom of the tank and will be drained in usual manner into the storage tanks of the oil industry by the bottom pipe  11 . 
         [0041]    The degasified and dehydrated oil will leave the closed processing tank  1  by the outlet pipe  8  for further processing or exporting. 
         [0042]      FIG. 3  shows in schematic fashion a processing installation for dehydration and degasification of crude petroleum with water in emulsion and dissolved gas, that is, crude petroleum to be processed  2 , which is introduced into the closed processing tank  1  by the inlet pipe  2   a . The crude petroleum  2  is compressed by a pump  2   c , goes through a flexible articulated tube  2   d  and is sprinkled over a plate  2   b , both the plate and the flexible articulated tube  2   d  being supported in a float  16 , which makes it possible to follow the changes in level in the closed processing tank  1 . The crude petroleum, once processed, is stored until the time of its leaving via the outlet pipe  8 , in static or dynamic manner. 
         [0043]    The processing gas  3  is compressed by a compressor  4 , a current of the processing gas  3  being projected via the injector  4   a  onto and tangentially to the free surface of the crude petroleum, the current of the processing gas  3  making a particular angle with the free surface of the crude petroleum above the plate  2   b , before reaching the surface, which angle can vary between zero and thirty degrees, the angle being preferably between 0 and eight degrees, but preferably five degrees. The injector  4   a  is also joined and connected to the plate  2   b , so that it can follow the level of the crude petroleum in the tank  1 . 
         [0044]    The compressor  4  is fed by the gas present in the tank after it circulates through the exchanger  14 , with addition, adding if necessary, of compatible gas  21  coming from the outside. The exchanger  14  receives the gaseous mixture  6  through the pipe  14   a , which is cooled by an outside refrigerant  15 . The condensates of the exchanger  14  are sent on through the pipe  19  for subsequent processing, while the gas coming from the exchanger  14  is aspirated by the compressor  4  and supplied to the tank, its being possible to add, as already mentioned, when necessary, a compatible gas  21  coming from the outside, or if the gas liberated in  5  is excessive, this excess can be exported for subsequent processing. 
         [0045]    One can also provide for a heating of the plate  2   b , by a heat exchanger  17 , which will accelerate the processing and, thus, the separation of the water in emulsion and dissolved gases. The heat exchanger  17  is supplied with an outside heating fluid  18 . 
         [0046]    The gas above the free surface of the crude petroleum will be maintained at the service pressure prevailing inside the closed processing tank  1 , by the action of the pressure regulating valve  7  and the overpressure rapid relief valve  10 , which is the current practice in the oil industry. 
         [0047]    The water separated will drop slowly by gravity to the bottom of the tank and will be drained in usual manner into the storage tanks of the oil industry by the bottom pipe  11 . 
         [0048]    The degasified and dehydrated oil will leave the closed processing tank  1  by the outlet pipe  8  for further processing or exporting. 
         [0049]      FIG. 4  shows in schematic fashion a processing installation for dehydration and degasification of crude petroleum with water in emulsion and dissolved gas, that is, crude petroleum to be processed  2 , which is introduced into the closed processing tank  1  by the inlet pipe  2   a , the crude petroleum  2  being compressed by the pump  2   c , via the pipe  2   d  going to a hydrocyclone  1 A. 
         [0050]    The outer wall of the hydrocyclone  1 A can be heated by any adequate device. The centrifugal force inside the hydrocyclone  1 A will cause the crude petroleum to be dispersed in a truncated conical surface  3   b . The processing gas  3  is compressed by a compressor  4 , having an injector  4   a , with an annular outlet surface, which latter projects a current of the processing gas  3  onto and tangentially to the free surface of the crude petroleum  2 , which makes a particular angle with it, before reaching the surface, which angle can vary between zero and thirty degrees, the angle preferably being between 0 and 8 degrees, but preferably five degrees. A localized zone of reduced pressure  5  is than created, where the subsequent separation of the water in emulsion and the gas dissolved in the petroleum will take place. 
         [0051]    The processing gas  3 , which creates the localized zone of reduced pressure  5 , together with separated hydrocarbons and/or evaporated water, forms the gaseous mixture  6 . 
         [0052]    The exchanger  14  receives the gaseous mixture  6  directly from the hydrocyclone  1 A, which is cooled by an outside refrigerant  15 . The condensates of the exchanger  14  are taken by the pipe  19  for subsequent processing. The gas coming from the exchanger  14  is taken by the pipe  20  to the tank  1 , its being possible to add, if necessary, compatible gas  21  coming from the outside, or it can be exported for subsequent processing (three-way valve  9 ). This gas repeatedly will continue its compression process through the compressor  4  and it will return to the hydrocyclone  1 A. 
         [0053]    The degasified and dehydrated oil will leave the hydrocyclone  1 A through the outlet pipe  12  and return  12   a  to the closed processing tank  1 , from which it will leave by the outlet pipe  8  for further processing or exporting or it will go on directly for subsequent processing or export  12   b.    
         [0054]    The gas above the free surface of the crude petroleum will be maintained at the service pressure prevailing inside the closed processing tank  1 , by the action of the pressure regulating valve  7  and the overpressure rapid relief valve  10 , which is the current practice in the oil industry. 
         [0055]    If there is any water separated by gravity within the tank, it will fall slowly by gravity to the bottom of the tank and it will be drained in customary fashion into the storage tanks of the oil industry, by the bottom pipeline  11 . 
         [0056]      FIG. 5  shows in schematic fashion a processing installation for dehydration and degasification of crude petroleum with water in emulsion and dissolved gas, that is, crude petroleum to be processed  2 , which is introduced into a hydrocyclone  1 A, such as that shown in  FIG. 4 , but the hydrocyclone  1 A being an independent piece of equipment, that is, in this embodiment the closed processing tank  1  was eliminated, everything else being as described for the embodiment of  FIG. 4  as regards the functioning of the hydrocyclone  1 A. 
         [0057]    The dehydrated and degasified oil will leave the hydrocyclone  1 A via the outlet pipe  12  for further processing. 
         [0058]      FIG. 6  shows schematically a processing installation including a three-phase separator, for dehydration and degasification of crude petroleum with water in emulsion and dissolved gas, that is, the crude petroleum to be processed  2 , in which, according to the background art, the crude petroleum  2  is introduced into the closed processing tank  1  by the inlet pipe  2   a , the crude petroleum moving through the zone  2   e  as far as the retention plate  2   f , where the crude petroleum thanks to its lesser density will go on to the part  2   g  of the separator, leaving by the outlet pipe  8 . The water, thanks to its greater density, will go to the bottom of zone  2   e , from which it will exit by the bottom pipe  11 . The dissolved gas will be separated slowly and will exit by the bottom pipe  11 . In order to adapt this installation for implementation of the process per the present invention and to make more efficient and rapid the separation of the liquids in emulsion and dissolved gases, there were added to this installation a compressor  4 , an injector  4   a , a three-way control valve  9 . 
         [0059]    The current of the processing gas  3 , compressed by the compressor  4 , is projected by the injector  4   a  onto and tangentially to the free surface of the crude petroleum, the current of the processing gas  3  making a particular angle with the free surface of the crude petroleum before reaching the surface, which angle can vary between zero and thirty degrees, the angle being preferably between 0 and 8 degrees, but preferably five degrees. The compressor  4  is fed by the actual gas present in the tank  1  or by compatible gas coming from outside  21 . The selection occurs by the three-way control valve  9 . In the zone of influence of the current of the processing gas  3  there is generated a localized zone of reduced pressure  5  above the surface of the crude petroleum. 
         [0060]    In the localized zone of reduced pressure  5 , the gas and water in emulsion will separate from the crude petroleum  2  with a speed that depends on the velocity of the processing gas  3 , which creates the partial vacuum on the interface with the crude petroleum being stored, and a gaseous mixture  6  will be formed, which will leave the tank by the pipeline  20  for further processing. The petroleum will also be separated more rapidly from the water, due to the creation of the localized partial vacuum. The gas above the free surface of the crude petroleum will be maintained at the service pressure prevailing inside the closed processing tank  1 , by the action of the pressure regulating valve  7  and by the overpressure rapid relief valve  10 , which is current practice in the oil industry. 
         [0061]      FIG. 7  shows in schematic fashion a processing installation for dehydration and degasification of crude petroleum with water in emulsion and dissolved gas, that is, crude petroleum to be processed  2 , which is introduced into the closed processing tank  1  by the inlet pipe  2   a , being then dispersed on a plate  2   b , as it enters the tank. The crude petroleum is stored until the time it leaves through the outlet pipe  8 , in static or dynamic manner. 
         [0062]    There is then created by the intake nozzle  13   a  of a venturi  13  a localized zone of reduced pressure  5  on the free surface of the crude petroleum  2 , dispersed on the plate  2   b , the outside gas  21  being used as driving fluid in the venturi to bring about the aspiration responsible for the localized zone of reduced pressure  5 . The outside gas can be supplied from some of the process gas present in the tank  1  after its recycling through the exchanger  14  via the pipe  20  and the three-way valve  9 . 
         [0063]    The processing gas, after going through the aspiration zone of the venturi  13   a , entrains the gaseous mixture  6  formed by the liberation of the gas dissolved in the crude petroleum and the gas present in the closed processing tank  1 . The gaseous mixture  6  goes on to the exchanger  14 . The exchanger  14  receives a gaseous mixture  6  via the pipeline  13   b , which is cooled by an outside refrigerant  15 . The condensates of the exchanger  14  are sent on through the pipe  19  for subsequent processing, while the gas  3  coming from the exchanger  14  is supplied to the tank  1 . If necessary, depending on the volume of gas liberated in  5 , part of the gas returned to the tank will be recirculated entirely or partially by the compressor  4  via the pipeline  20  and the three-way valve  9   a  or it can be exported in whole or in part for subsequent processing  20   a.    
         [0064]    The gas above the free surface of the crude petroleum will be maintained at the service pressure prevailing inside the closed processing tank  1 , by the action of the pressure regulating valve  7  and the overpressure rapid relief valve  10 , which is the current practice in the oil industry. 
         [0065]    The water separated will drop slowly by gravity to the bottom of the tank and will be drained in usual manner into the storage tanks of the oil industry by the bottom pipe  11 . 
         [0066]    The degasified and dehydrated oil will leave the closed processing tank  1  by the outlet pipe  8  for further processing or exporting. 
         [0067]    There are described above embodiments which are considered most illustrative of the invention, although modifications are clearly possible, it being possible, for example, in the embodiment of  FIG. 3 , for the crude petroleum  2  to be dispersed directly onto the plate  2   b , or in the embodiment of  FIG. 7  the plate  2   b  can be mounted in a float, the aspiration nozzle  13   a  can be connected to its respective pipe and to the plate  2   b , so as to follow the change in level of the petroleum within the tank  1 , and the inlet pipe  2   a  for the crude petroleum  2  can be flexible and be connected to the plate  2   b  so that it can also follow the change in level of the petroleum within the tank  1 . 
         [0068]    Without departing from the scope of the invention, it is possible for a materials expert to realize all the modifications and improvements suggested by normal experience and the natural progress of engineering, in the process and device for implementing of the process of the present invention.