Abstract:
A pair of organic Rankine cycle systems ( 20, 25 ) are combined and their respective organic working fluids are chosen such that the organic working fluid of the first organic Rankine cycle is condensed at a condensation temperature that is well above the boiling point of the organic working fluid of the second organic Rankine style system, and a single common heat exchanger ( 23 ) is used for both the condenser of the first organic Rankine cycle system and the evaporator of the second organic Rankine cycle system. A preferred organic working fluid of the first system is toluene and that of the second organic working fluid is R245fa.

Description:
STATEMENT OF GOVERNMENT INTEREST 
       [0001]    The United States Government has certain rights in this invention pursuant to Contract No. DE-FC02-00CH11060 between the Department of Energy and United Technologies Corporation. 
     
    
     BACKGROUND OF THE INVENTION 
       [0002]    Power generation systems that provide low cost energy with minimum environmental impact, and that can be readily integrated into the existing power grids or rapidly sited as stand-alone units, can help solve critical power needs in many areas. Combustion engines such as microturbines or reciprocating engines can generate electricity at low cost with efficiencies of 25% to 40% using commonly available fuels such as gasoline, natural gas and diesel fuel. However, atmospheric emissions such as nitrogen oxides (NOx) and particulates can be a problem with reciprocating engines. 
         [0003]    One method to generate electricity from the waste heat of a combustion engine without increasing the output of emissions is to apply a bottoming cycle. Bottoming cycles use waste heat from such an engine and convert that thermal energy into electricity. Rankine cycles are often applied as the bottoming cycle for combustion engines. A fundamental organic Rankine cycle consists of a turbogenerator, a preheater/boiler, a condenser, and a liquid pump. Such a cycle can accept waste heat at temperatures somewhat above the boiling point of the organic working fluid chosen, and typically rejects heat to the ambient air or water at a temperature somewhat below the boiling point of the organic working fluid chosen. The choice of working fluid determines the temperature range/thermal efficiency characteristics of the cycle. 
         [0004]    Simple ORC Systems using one fluid are efficient and cost effective when transferring low temperature waste heat sources into electrical power, using hardware and working fluids similar to those used in the air conditioning/refrigeration industry. Examples are ORC systems using radial turbines derived from existing centrifugal compressors and working fluids such as refrigerant R245fa. 
         [0005]    For higher temperature waste heat streams, the most cost-effective ORC systems still operate at relatively low working fluid temperatures, allowing the continued use of HVAC derived equipment and common refrigerant. However these systems, although very cost-effective, do not take full advantage of the thermodynamic potential of the waste heat stream. 
       SUMMARY OF THE INVENTION 
       [0006]    Briefly, in accordance with one aspect of the invention, a pair of organic Rankine cycle (ORC) systems are combined, and a single common heat exchanger is used as both the condenser for the first ORC system and as the evaporator for the second ORC system. 
         [0007]    By another aspect of the invention, the refrigerants of the two systems are chosen such that the condensation temperature of the first, higher temperature, system is a useable temperature for boiling the refrigerant of the second, lower temperature, system. In this way, greater efficiencies may be obtained and the waste heat loss to the atmosphere is substantially reduced. 
         [0008]    In accordance with another aspect of the invention, the single common heat exchanger is used to both desuperheat and condense the working fluid of the first ORC system. 
         [0009]    By another aspect of the invention, if a second heat exchanger is provided in the first ORC system, with the common heat exchanger acting to desuperheat the working fluid of the first ORC system, and the second condenser acting to condense the working fluid in the first ORC system. 
         [0010]    By yet another aspect of the invention, a preheater, using waste heat, is provided to preheat the working fluid in the second ORC system prior to its entry into the common heat exchanger. 
         [0011]    In the drawings as hereinafter described, preferred and modified embodiments are depicted; however various other modifications and alternate constructions can be made thereto without departing from the true spirit and scope of the invention. 
     
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS  
         [0012]      FIG. 1  is a schematic illustration of an organic Rankine cycle system in accordance with the prior art. 
           [0013]      FIG. 2  is a TS diagram thereof. 
           [0014]      FIG. 3  is a schematic illustration of a pair of organic Rankine cycle systems as combined in accordance with the present invention. 
           [0015]      FIG. 4  is a TS diagram thereof. 
           [0016]      FIG. 5  is an alternate embodiment of the present invention. 
           [0017]      FIG. 6  is a TS diagram thereof. 
           [0018]      FIG. 7  is another alternate embodiment of the present invention. 
           [0019]      FIG. 8  is a TS diagram thereof. 
       
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENT 
       [0020]    Referring now to  FIG. 1 , a conventional type of organic Rankine cycle system is shown to include an evaporator/boiler  11  which receives waste heat from a source as described hereinabove. The heated working fluid passes to the turbine  12 , where it is converted to motive power to drive a generator  13 . The resulting lower temperature and pressure working fluid then passes to a condenser  14  where it is converted to a liquid, which is then pumped by the pump  16  back to the evaporator/boiler  11 . 
         [0021]    In such a typical system, a common working fluid is toluene. In the vapor generator  11  the working fluid has its temperature raised to around 525° F. after which it is passed to the turbine  12 . After passing through the turbine  12 , the temperature of the vapor drops down to about 300° F. before it is condensed and then pumped back to the evaporator/boiler  11 . 
         [0022]    Shown in  FIG. 2  is a TS diagram of the organic rankine cycle system illustrated in  FIG. 1 , using toluene as the working fluid. As will be seen, because of the relatively high critical temperature, the toluene is thermodynamically more efficient than systems with working fluids having lower critical temperatures. However, it is less cost effective and still leaves much to be desired in terms of efficiency. The reason for the higher cost of these higher temperature ORC systems is twofold: First, working fluids such as toluene, with high critical temperatures, allow operation at a higher evaporation temperature, which is relatively good for efficiency, but exhibit a very low density at ambient conditions, thus requiring large and expensive condensation equipment. Secondly, the nature of such high critical temperature organic fluids is that the higher the turbine pressure ratio (typically larger than 25:1 in such a system), the more superheated the vapor that leaves the turbine. The thermal energy represented by the superheat of the vapor leaving the turbine is therefore not used for power generation and requires additional condenser surface for rejection to ambient. Accordingly, there is a substantial amount of lower temperature waste heat (i.e. the heat of the superheated low pressure vapor leaving the turbine) which is not converted into power, thereby limiting the turbine efficiency. 
         [0023]    Referring now to  FIG. 3 , a modified arrangement is shown to include a pair of organic Rankine cycle systems  20  and  25  that are combined in a manner which will now be described. An evaporator boiler or vapor generator  17  receives heat from a heat source  18  to produce relatively high pressure high temperature vapor which is passed to a turbine  19  to drive a generator  21 . After passing through the turbine  19 , the lower pressure, lower temperature vapor passes to the condenser/evaporator  23  where it is condensed into a liquid which is then pumped by the pump  24  to the vapor generator  17  to again be vaporized. 
         [0024]    Typically an unrecuperated microturbine has an exit temperature of its exhaust gases of about 1200° F. This hot gas can be used to boil a high temperature organic fluid such as pentane, toluene or acetone in an ORC. If toluene is the working fluid, the leaving temperature from the vapor generator  17  would be about 500° F., and the temperature of the vapor leaving the turbine  19  and entering the condenser  23  would be about 300° F. After being condensed, the liquid toluene is at a temperature of about 275° F. as it leaves the condenser  23  and passes to the vapor generator  17  by way of the pump  24 . These temperatures and related entropies are shown in the TS diagram of  FIG. 4 . 
         [0025]    In this cascaded ORC arrangement, the first ORC system (i.e. the toluene loop), is a high temperature system that extracts all the heat, either sensible such as from a hot gas or hot liquid, or latent such as from a condensing fluid such as steam in a refrigerant boiler/evaporator, creating high pressure and high temperature vapor. This high pressure vapor expands through the turbine  19  to a lower pressure with a saturation temperature corresponding to a level where a low cost/low temperature ORC system can be used to efficiently and cost effectively convert the lower temperature waste heat to power. By doing this, the high temperature refrigerant still has positive pressure and a corresponding larger density in the condenser  23 . This results in a condenser with less pressure drop, better heat transfer and smaller size, all of which result in a more cost effective ORC system. The high pressure and larger density of the vapor exiting the turbine  19  also allows a smaller turbine design. A substantial reduction in cost can be obtained by these modifications. Further, the lower pressure ratio (i.e. 5:1) at the turbine  19  allows for higher turbine efficiencies. 
         [0026]    Considering now that the temperature of the toluene vapor entering the condenser/evaporator  23  is relatively high, its energy can now be used as a heat source for a vapor generator of a second ORC system  25 , with the condenser/evaporator  23  acting both as the condenser for the first ORC system  20  and as the evaporator or boiler of the second ORC  25  system. The second ORC system therefore has a turbine  26 , a generator  27 , a condenser  28  and a pump  29 . The organic working fluid for the second ORC must have relatively low boiling and condensation temperatures. Examples of organic working fluids that would be suitable for such a cycle are R245fa or isobutane. 
         [0027]    In the second ORC system  25 , with R245fa as the organic working fluid, the temperature of the working fluid passing to the turbine  26  would be around 250° F., and that of the vapor passing to the condenser would be about 90° F. After condensation of the vapor, the refrigerant would be pumped to the condenser/evaporator  23  by the pump  29 . 
         [0028]    Referring to  FIG. 5 , an alternate, nested arrangement is shown wherein, within the toluene circuit, the working fluid again passes from the boiler or vapor generator  17  to the turbine and then to a common heat exchanger  31 . Again, the heat exchanger  31  acts as an evaporator or boiler for the R245fa circuit, with the R245fa refrigerant passing from the boiler  31  to the turbine  26  to a condenser  28 , the pump  29 , and back to the boiler  31 . However, unlike the condenser/evaporator  23  of the  FIG. 3  embodiment, the heat exchanger  31  acts as a desuperheater only within the toluene circuit, with a condenser  32  then being applied to complete the condensation process before the working fluid is passed by way of the pump  24  back to the boiler  17 . The TS diagram for such a nested ORC cycle system is shown in  FIG. 6 . 
         [0029]    In this nested arrangement a cost reduction is obtained by adding the low temperature, R245fa, ORC system in such a way that the overall system efficiency is increased. The major irreversibility (thermodynamic loss) of the simple cycle high temperature ORC system is the so-called desuperheat loss in the condenser. Organic fluids leave the turbine more superheated than they enter it. The larger the pressure ratio at the turbine, the stronger this effect. High temperature simple cycle ORC systems, although thermodynamically more efficient than the simple cycle low temperature ORC systems, reject a lot of moderate temperature waste heat that has to be rejected in the desuperheater/condenser. As a result, a relatively large condenser is required. In the nested ORC system, desuperheating is done in the low temperature ORC evaporator  31 . This increases the overall power output since this heat was previously rejected to ambient and is now used in a low temperature ORC system to generate power. A further advantage is that the size of the high temperature ORC condenser  32  may be reduced. 
         [0030]    Thus, the overall result of the nested ORC system is a more cost effective overall ORC system for high temperature waste heat sources. The increased cost effectiveness is obtained by increased power output and by reducing the size of the original desuperheater/condenser unit. 
         [0031]    Although the  FIG. 5  embodiment has been described in terms of use with two different refrigerants, it should be understood that the same refrigerant could be used in the two circuits. 
         [0032]    A further embodiment of the present invention is shown in  FIG. 7  wherein the  FIG. 5  embodiment is modified by the addition of a preheater  33  in the R245fa cycle as shown. Here, the working fluid, after passing through the condenser  28  and the pump  29 , passes through the liquid preheater  33  using the waste heat source at lower temperatures (from 400° F. to 200° F.). The corresponding TS diagram is shown in  FIG. 8 . 
         [0033]    While the present invention has been particularly shown and described with reference to preferred and alternate embodiments as illustrated in the drawings, it will be understood by one skilled in the art that various changes in detail may be effected therein without departing from the true spirit and scope of the invention as defined by the claims.