Abstract:
A method of manufacturing a sensor is provided. The method includes disposing a sacrificial layer on a substrate, disposing a low-thermal-conductivity layer on the sacrificial layer, and disposing a first set of conductive arms and a second set of conductive arms on the low-thermal-conductivity layer to form a plurality of thermal junctions. The plurality of thermal junctions is adapted to form a plurality of hot junctions and a plurality of cold junctions when subjected to a difference in temperature. The method also includes removing the sacrificial layer and a portion of the low-thermal-conductivity layer to form a cavity therein. The cavity is configured to provide insulation for the plurality of hot junctions. A thermopile sensor is also provided, and a calorimetric gas sensor implementing the thermopile sensor is provided.

Description:
BACKGROUND 
     The invention relates generally to the field of miniaturized sensors and, more specifically, to highly sensitive thermopile-based gas sensors. 
     A thermopile sensor is a set of thermocouples connected in series for obtaining a larger signal output. Thermocouples measure the temperature difference between the hot and cold junctions by generating an electromotive force (emf) caused by a phenomenon known as the Seebeck effect, as appreciated by those of ordinary skill in the art. Thus, a thermopile adds up the emf of all the thermocouples to provide a higher voltage output. Thermal isolation in thermopiles is achieved by providing a thin diaphragm region and a relatively large heat sink. 
     Silicon is used as a substrate material for thermopiles. However, there is typically a high amount of heat loss in such thermopiles because silicon is thermally conductive. Attempts have been made to prevent such heat losses because heat loss tends to result in decreased thermopile efficiency. Thermal isolation between the hot and the cold junctions may be provided by etching a section of the silicon substrate under the hot junction while providing thermal insulation through a multiple stacked structure. However, even after etching the silicon substrate, conductive heat losses occur through the thermal insulating layers. 
     Attempts have been made to stack numerous thermopiles together to increase thermopile output resolution. Such devices involve creating separate thermopiles and then bonding them together. However, such attempts have proven to be costly, time-consuming and difficult to implement because of the need for separate etching for each thermopile that is bonded together. 
     An improved thermopile sensor that has higher sensitivity and reduced cost is therefore desirable. 
     SUMMARY 
     A method of manufacturing a sensor is provided. The method includes disposing a sacrificial layer on a substrate, disposing a low-thermal-conductivity layer on the sacrificial layer, disposing a first set of conductive arms and a second set of conductive arms on the low-thermal-conductivity layer to form a plurality of thermal junctions. The plurality of thermal junctions is adapted to form a plurality of hot junctions and a plurality of cold junctions when subjected to a difference in temperature. The method also includes removing the sacrificial layer and a portion of the low-thermal-conductivity layer to form a cavity therein. The cavity is configured to provide insulation for the plurality of hot junctions. A thermopile sensor is also provided, and a calorimetric gas sensor implementing the thermopile sensor is provided. 
     These and other advantages and features will be more readily understood from the following detailed description of preferred embodiments of the invention that is provided in connection with the accompanying drawings. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a diagrammatical view of a system including an exemplary thermopile sensor in accordance with an embodiment of the invention. 
         FIG. 2  is a flow chart illustrating a fabrication process of an exemplary thermopile sensor in accordance with one aspect of the present technique. 
         FIGS. 3-7  are cross-sectional views of a thermopile sensor at various points in a fabrication process in accordance with an embodiment of the invention. 
         FIG. 8  illustrates a cross-sectional view and a top-view of a first layer of the thermopile sensor of  FIG. 7 . 
         FIG. 9  is a cross-sectional view of the thermopile sensor of  FIG. 8 . 
         FIG. 10  is a cross-sectional view of the thermopile sensor of  FIG. 8 . 
         FIG. 11  illustrates a cross-sectional view and a top-view of the thermopile sensor of  FIG. 10 . 
         FIG. 12  is a cross-sectional view of an exemplary calorimetric gas sensor including a thermopile sensor, in accordance with one aspect of the present technique. 
     
    
    
     DETAILED DESCRIPTION OF EXEMPLARY EMBODIMENTS 
       FIG. 1  is a diagrammatical view of a system  10  including an exemplary thermopile sensor  12  in accordance with one aspect of the present technique. The system  10  may be a closed or an open vessel in which temperature is measured. In one embodiment, the thermopile sensor  12  may be coupled with the system  10  to measure the temperature of the gas within the system  10 . However, in various other embodiments, one or more thermopile sensors  12  may be utilized. 
     Referring generally to  FIG. 2 , a flow chart illustrating a fabrication process  14  of a thermopile sensor  12  in accordance with certain embodiments of the present technique is shown. In the illustrated embodiment, the fabrication process  14  begins at Step  16  by deposition of a sacrificial layer over a substrate wafer. The sacrificial layer may serve as a supporting layer on which other conductive or insulation layers may be built. The sacrificial layer may then be etched out to form a cavity. 
     A low-thermal-conductivity layer is deposited over the sacrificial layer at Step  18 . The low-thermal-conductivity layer may serve as a thermal insulation layer for preventing heat leakages. A set of conductive arms, such as metal strips or conductive semiconductor strips, may be deposited at Step  20  to form the arms of individual thermocouples that together form the thermopile sensor. The ends of the conductive arms may be electrically coupled to form thermal junctions at Step  22 . These thermal junctions form the “hot” and “cold” junctions of the thermopile. The sacrificial layer may then be etched out along with a portion of the low-thermal-conductivity layer to form a cavity at Step  24 . This air-filled cavity enhances the thermal insulation so that heat leakages from the hot junction to the cold junction or from the hot junction through the base substrate are minimized. The details of the fabrication process  14  will become better understood in the description that follows. 
     Referring generally to  FIGS. 3 through 9 , cross-sectional views of an exemplary micro-fabricated thermopile sensor at various points in a fabrication process, in accordance with aspects of the present technique are shown. In  FIG. 3 , a sacrificial layer  28  is deposited on a semiconductor wafer  26  (Step  16 ,  FIG. 2 ). The semiconductor wafer  26 , which may comprise a p-type silicon wafer having resistivity of about 50 ohm-cm, forms a substrate for deposition of other layers. The sacrificial layer  28  may include a phospho-silicate-glass material having a thickness of about 0.2 micrometer. 
     As shown in  FIG. 4 , a low-thermal-conductivity layer  30  may be deposited on the sacrificial layer  28  (Step  18 ,  FIG. 2 ). The low-thermal-conductivity layer  30  may include a nitride layer, such as a layer of silicon nitride (Si x N y ) for example Si 3 N 4 , and may be deposited with a thickness of about 0.3 micrometer. The nitride layer  30  forms an insulation layer that reduces heat leakage, as will be described in detail below. 
     As shown in  FIG. 5 , a polysilicon layer  32  may be deposited on the low-thermal-conductivity layer  30  for constructing a plurality of conductive arms. The polysilicon layer  32  may be made of a semiconductor material such as silicon (Si z ). 
     Turning now to  FIG. 6 , there is shown etching of the polysilicon layer  32  to form electrode lines. The polysilicon layer  32  may be patterned and etched to form a plurality of electrode lines or two sets of strips. 
       FIG. 7  shows masking and doping of one set of electrode lines shown in  FIG. 6 . In particular, a first set of strips  34  are masked by deposition of a masking layer. A second set of strips  36  is then doped to form p +  doped silicon conductive arms  36  via an ion implantation process. 
       FIG. 8  illustrates a cross-sectional view and a top-view of a first layer of the thermopile sensor, highlighting the masking and doping of another set of electrode lines shown in  FIG. 6 . As shown, the second set of strips  36  are masked by deposition of a masking layer and the first set of strips  34  are doped to form n −  doped silicon conductive arms  34 . As will be appreciated by one of ordinary skill in the art, the operations described with reference to  FIGS. 7 and 8  may be performed in either order. For example, the operations shown in  FIG. 7  may follow the operations shown in  FIG. 8 . In such a case, the second set of strips  36  may be masked initially to dope the first set of strips  34  and form n −  doped silicon conductive arms  34 . Then, the first set of strips  34  may be masked for doping the second set of strips  36  to form p +  doped silicon conductive arms  36 . Similarly, n −  doped silicon conductive arms  34  and p +  doped silicon conductive arms  36  may be formed in either of the operations shown in  FIG. 7  or  8 . When these sets of conductive arms  34  and  36  are formed, these conductive arms  34  and  36  may be electrically coupled to form a plurality of thermal junctions  38  (Step  22 ,  FIG. 2 ). The thermal junctions may include “hot” junctions  40  and “cold” junctions  42 . 
     Turning now to  FIG. 9 , the sacrificial layer  28  and a portion of the low-thermal-conductivity layer  30  may be removed by etching to form a cavity  44 . The cavity  44  provides insulation between the hot junctions  40  and the cold junctions  42 . Also, the cavity  44  helps to reduce heat-sinking from the hot junctions  40  to the substrate layer  28 . The operations discussed above with respect to  FIGS. 3-9  illustrate cross-sectional views at various points during the fabrication process of a single layer of n − /p +  junction pair thermopile sensor. Thermal insulation of the hot junction  40  is achieved through the release of the sacrificial layer  28  and a portion of the low-thermal-conductivity layer  30  to form the air-gap or cavity  44 . 
     In another embodiment, the operations referred to with respect to  FIGS. 3 and 4  may be performed prior to the deposition of a first set of metallic conductive arms and a second set of metallic conductive arms. The first and the second set of metallic conductive arms may be made of different metals, for example aluminum, bismuth, antimony, copper, and the like or alloys such as Constantan. The specific combination of metals or metal-alloy combination is matters of design choice. For example, the set of metallic conductive arms may be chosen such that one set possesses a positive Seebeck coefficient, while the other set possesses a negative Seebeck coefficient. By releasing the sacrificial layer  28  and a portion of the low-thermal-conductivity layer  30 , the air-gap or cavity  44  may then be formed, as illustrated in  FIG. 9 . 
     In still another embodiment, the operations described with respect to  FIGS. 3-6  may be performed to form the first set of strips. Then the first set of strips may be doped to form either n −  doped silicon conductive arms  34  or p +  doped silicon conductive arms  36 . These operations may be performed as illustrated in  FIG. 7  or  FIG. 8 , respectively. If n −  doped silicon conductive arms  34  are formed, then a set of metallic conductive arms with a positive Seebeck coefficient may be deposited to form the second set of conductive arms. Alternatively, if p +  doped silicon conductive arms  36  are formed, then a set of metallic conductive arms with a negative Seebeck coefficient may be deposited to form the second set of conductive arms. By releasing the sacrificial layer  28  and a portion of the low-thermal-conductivity layer  30 , as shown in  FIG. 9 , the air-gap or cavity  44  may then be formed. 
     Referring now to  FIGS. 10 and 11 , an embodiment of a multi-layered thermopile structure having various layers of n − /p +  junction pair thermopile sensors is shown.  FIG. 10  illustrates a multi-layered thermopile structure. During the fabrication of the multi-layered thermopile structure, the operations described with respect to  FIGS. 3-8  may be performed to form n −  doped silicon conductive arms  34  and p +  doped silicon conductive arms  36 . These operations form the first layer  38  of n − /p +  junction pair thermopile sensor. However, as described previously, the conductive arms in the first layer  38  of the thermopile sensor may be a combination of metallic conductive arms and doped semiconductor arms, such as p +  doped silicon arms or n −  doped silicon arms. Alternatively, the first layer  38  of the thermopile sensor may include only metallic conductive arms. These conductive arms may then be electrically coupled to form thermal junctions, for example hot and cold junctions. When the first layer  38  of the thermopile sensor is fabricated, a second layer  46  of thermopile sensor may be fabricated over the first layer  38 , by following the operations described with reference to  FIGS. 4-8 . Similarly, a plurality of thermopile layers may be fabricated by repeating the operations described with reference to  FIGS. 4-8 . Again, the plurality of layers may comprise a combination of p +  doped silicon arms and n −  doped silicon arms, or a combination of metallic conductive arms and doped semiconductor conductive arms, or only sets of metallic conductive arms, as had been described previously in the various embodiments. Although only two thermopile layers  38  and  46  have been shown, additional layers may be fabricated. 
       FIG. 11  shows electrical coupling of various layers of the multi-layered thermopile structure. When a desirable number of layers are achieved, the multilayered structure shown in  FIG. 10 , may be defined with a photoresist for etching holes  48 . The holes  48  thus formed may be deposited with metallic contacts  50  to electrically couple the thermopile sensor layers  38  and  46 . It may be noted that each of the thermopile layers may be fabricated slightly offset with respect to the previous layer for ease of achieving electrical coupling, such as Schottky metal contacts. For example, the second layer  46  may be fabricated slightly offset with respect to the first layer  38 , as shown in block  50 , which is a top view of the multilayered structure showing metallic contacts  50  that couple the conductive arms of the two thermopile sensor layers  38  and  46 . 
     Applications for embodiments of the invention may be found in differentially measuring or tracking the temperature of a location with respect to a reference location maintained at a reference temperature. Similarly, other parameters such as concentration or presence of a gas within an enclosure may be detected. For example, a highly sensitive thermopile sensor constructed in accordance with the present technique may be utilized in a calorimetric gas sensor for detecting the presence of a gas or the concentration of the gas. 
       FIG. 12  shows a cross-sectional view of an exemplary calorimetric gas sensor  54  including a thermopile sensor, in accordance with aspects of the present technique. The calorimetric gas sensor  54  may comprise a reference cell  56  and a sensor cell  58 . The calorimetric gas sensor  54  may be fed with the gas whose concentration is to be determined. A thermopile sensor may be coupled to the micro-fabricated calorimetric gas sensor  54  so that hot junctions  60  and cold junctions  62  of the thermopile sensor are thermally coupled to the reference cell  56  and the sensor cell  58 . The thermopile sensor may be micro-fabricated with the calorimetric gas sensor  54  and may be enclosed in a closed enclosure  64  having an inert gas, for example Nitrogen (N 2 ), Argon (Ar), Helium (He), and the like. A reference cell heater  66  and a sensor cell heater  68  may be coupled with the reference cell  56  and sensor cell  58 . The sensor cell  58  comprises an adsorbent material  70 . This adsorbent layer  70  is adapted to absorb a defined amount of gas. Furthermore, the adsorbent layer  70  is adapted to desorb a portion of the adsorbed gas when heated. 
     The temperature of the reference cell  56  and the sensor cell  58  may be scanned within a temperature domain of interest. For example, the temperature scanning may be performed between room temperature of about 25 degrees Celsius to about 500 degrees Celsius. The temperature profile may be chosen such that total gas desorption occurs within the scanned interval. Because of the difference in heat capacities of the two cells  56  and  58  and because of the endothermal desorption of the gas from the adsorbent layer  70 , the sensor cell  58  thermally lags behind the reference cell  56 . For measuring the heat of desorption of the gas, this thermal lag may be compensated by heating the sensor cell  58  by providing more power into the sensor cell heater  68 . The amount of power fed into the sensor cell heater  68  for achieving thermal equilibrium between the two cells  56  and  58  may be calibrated to read the concentration of the gas within the sensor cell  58 . This is because the adsorbent layer  70  absorbs an amount of gas proportional to the concentration of the gas within the sensor cell  58 . When the cells  56  and  58  are heated by the respective heaters  66  and  68 , gas from the adsorbent layer  70  desorbs, thereby cooling the sensor cell  58 . The temperature of the sensor cell  58  would thus fall proportional to the amount of gas absorbed by the adsorbent layer  70 . Therefore, a proportional amount of power may be required to heat the sensor cell  58  to compensate for the thermal lag from the reference cell  56 . 
     It will be appreciated by those of ordinary skill in the art that a closed loop for measuring the differential temperatures between the two cells  56  and  58  and utilizing that signal to adjust the power flow to the sensor cell  58  for matching its temperature to that of the reference cell  56 , may be implemented. High sensitivity thermopiles, in accordance with aspects of the present techniques, may be fabricated such that the cold junctions  62  are located on the silicon frame (maintained at room temperature). In such a case, the hot junctions  60  may be located on the two cells  56  and  58  and would serve to directly measure the heat flux between the two cells  56  and  58 . A voltage signal that is proportional to the differential temperature between the cells  56  and  58 , may then be generated. This voltage signal may be used to adjust the power flow to the sensor cell  58 . The differential power consumed in the two cells  56  and  58  correspond directly to the heat of desorption. 
     Moreover, the calorimetric gas sensor  54  may be operated in adsorption mode. For example, the heat generated in the sensor cell  58  because of adsorption of the gas by the adsorbent layer  70  may be measured. The amount of heat generated in the sensor cell  58  may be calibrated to read the concentration of the gas within the sensor cell  58 . 
     The fabrication of thermopile sensor, as described hereinabove, produces an air-gap or air-cavity as illustrated, which can be distinguished by other fabrication methods known in the art, which remove the substrate to yield a free-standing membrane. Similarly, the calorimetric gas sensor  54  described hereinabove includes a thermopile sensor having a cavity fabricated by the abovementioned operations, as compared to other calorimetric gas sensors, such as catalytic calorimetric gas sensor, catalytic differential calorimetric gas sensor or calorimetric gas sensors utilizing resistance temperature detectors. 
     While the invention has been described in detail in connection with only a limited number of embodiments, it should be readily understood that the invention is not limited to such disclosed embodiments. Rather, the invention can be modified to incorporate any number of variations, alterations, substitutions or equivalent arrangements not heretofore described, but which are commensurate with the spirit and scope of the invention. Additionally, while various embodiments of the invention have been described, it is to be understood that aspects of the invention may include only some of the described embodiments. Accordingly, the invention is not to be seen as limited by the foregoing description, but is only limited by the scope of the appended claims.