Abstract:
An apparatus to detect and measure suspended particles in a molten metal where the suspended particles have an associated noise frequency range has in addition to the electrically non-conductive barrier for immersion in the molten-metal, a device to move the molten metal through an orifice in the barrier and electrodes, a time varying excitation source that generates an AC current at a predetermined range of excitation frequency that is out of the predominant noise frequency range to generate an AC signal that is representative of the measure of the suspended particles. A detector detects and quantifies from the measurement AC signal the suspended particles. The detector can be a synchronous detector.

Description:
FIELD OF THE INVENTION 
       [0001]    This invention relates to analyzers that detect suspended particulates in molten metals such as aluminum, gallium, lead, zinc, steel, iron etc. These particulates, also called inclusions are solid, liquid or gaseous particles that have a low electrical conductivity compare to the molten metals. 
       DESCRIPTION OF THE PRIOR ART 
       [0002]    Molten metals, particularly molten aluminum and steel, are frequently contaminated to some extent by entrained inclusions that give rise to a variety of shortcomings or defects in the resulting finished products. Such inclusions can arise from a number of sources, for example, in aluminum through the entrainment of surface oxide films, from the formation of insoluble impurities such as coarse or clustered boride particles, or fine or coarse carbides and nitrides, from the oxidation of alloying elements such as magnesium, and from the erosion of the refractory linings of vessels used to hold or transport the liquid metal. 
         [0003]    Problems that are caused by the presence of inclusions include the tearing of the metal during mechanical working operations, the presence of pin-holes and streaks in foils, surface defects and blisters in sheet, and increased rates of breakage during production of wire. These problems are becoming more acute as customers demand thinner, lighter products and better surface appearance, and as the proportion of recycled metal that is used in the production of some sheet metal products rises, with attendant increases in inclusion formation during remelting. 
         [0004]    There are liquid metal cleanliness analyzers (“LiMCAs”) such as ABB&#39;s LiMCA II and LiMCA CM that provide a relatively rapid detection and measurement of the concentration and size distribution of suspended particulates in molten metal. These analyzers both use the same measurement principle, however the LiMCA II uses batteries to accumulate the energy for the direct current used in the measurement and the LiMCA CM uses ultra-capacitors to accumulate the energy for that current. The analyzers can be employed during a processing operation on the molten metal. U.S. Pat. No. 4,600,880 (“the &#39;880 Patent”) describes one embodiment for a LiMCA. 
       SUMMARY OF THE INVENTION 
       [0005]    Apparatus for separately detecting and measuring suspended particles in a molten metal where the measuring of the suspended particles has an associated predominant noise frequency range, the apparatus having: 
         [0006]    an electrically non-conductive barrier having opposed sides and having an orifice of predetermined hydrodynamic diameter, the barrier being suitable for immersion in a molten metal with the orifice below a surface of the metal; 
         [0007]    a device for moving molten metal through the orifice in a direction from one side of the barrier to the other; 
         [0008]    electrodes, suitable for immersion in the molten metal, positioned on opposite sides of the barrier for establishing a current path in the molten metal passing through the orifice; and 
         [0009]    a time varying excitation source for generating an AC current at a predetermined range of excitation frequency which is out of predominant noise&#39;s frequency range, the time varying excitation source connectable to the electrodes when the barrier and the electrodes are immersed in the molten metal to use the AC current to measure the suspended particles and generate an AC signal representative of the measurement of the suspended particles. 
         [0010]    Apparatus for separately detecting and measuring suspended particles in a molten metal where the measuring of the suspended particles has a predominant noise frequency range and the apparatus has: 
         [0011]    an electrically non-conductive barrier having opposed sides and having an orifice of predetermined hydrodynamic diameter with the barrier being suitable for immersion in a molten metal with the orifice below a surface of the metal; 
         [0012]    a device for moving molten metal through the orifice in a direction from one side of the barrier to the other; 
         [0013]    electrodes, suitable for immersion in the molten metal, positioned on opposite sides of the barrier for establishing a current path in the molten metal passing through the orifice; 
         [0014]    a time varying excitation source for generating an AC current at a predetermined range of excitation frequency which is higher than the predominant noise frequency range, the time varying excitation source connectable to the electrodes when the barrier and the electrodes are immersed in the molten metal to use the AC current to measure the suspended particles, wherein the measurement is an AC signal having the excitation source predetermined frequency range; and 
         [0015]    a detector to detect and quantify from the measurement AC signal the suspended particles in the molten metal. 
         [0016]    A system for use in an apparatus that is for separately detecting and measuring suspended particles in a molten metal. The measuring of the suspended particles having a predominant noise frequency range. The apparatus has an electrically non-conductive barrier having an orifice. The barrier is suitable for immersion in a molten metal with the orifice below a surface of the metal. The apparatus also has electrodes that are suitable for immersion in the molten metal. The electrodes are positioned on both sides of the barrier for establishing a current path in the molten metal passing through the orifice. 
         [0017]    The system has a time varying excitation source for generating an AC current at a predetermined range of excitation frequency which is out of predominant noise frequency range. The time varying excitation source is for connection to the electrodes so that when the barrier and the electrodes are immersed in the molten metal the AC current can be used to measure the suspended particles. The measurement is an AC signal that has the excitation source predetermined frequency range. The system has a detector that is connected to the source and is for connection to the apparatus to detect and quantify from the measurement AC signal the suspended particles in the molten metal. 
     
    
     
       DESCRIPTION OF THE DRAWING 
         [0018]      FIG. 1  shows a schematic representation of a prior art liquid metal cleanliness analyzer. 
           [0019]      FIG. 2-4  show cross-sections through a sample-receiving vessel of the analyzer of  FIG. 1  and show preferred forms of the flow aperture. 
           [0020]      FIG. 5  shows the changes in resistivity when aluminum includes inclusions. 
           [0021]      FIG. 6  shows examples of excitation sources for use in the LiMCA described herein. 
           [0022]      FIG. 7  shows the excitation frequency, the inclusion and noise spectral density. 
           [0023]      FIG. 8   a  shows an embodiment for the resonant tank circuit used in the apparatus described herein. 
           [0024]      FIG. 8   b  shows a low pass impedance match circuit as one of the excitation source. 
           [0025]      FIG. 8   c  shows a high pass impedance match circuit as one of the excitation source. 
           [0026]      FIGS. 9   a  and  9   b  show examples of embodiment of the detector that are used in the LiMCA measurement. 
           [0027]      FIG. 10  shows a block diagram of an experimental setup for the apparatus described herein. 
           [0028]      FIG. 11  shows one embodiment for the AC current source generator described herein. 
           [0029]      FIG. 12  shows one embodiment for the added amplification in the ADC evaluation board shown in  FIG. 10 . 
           [0030]      FIG. 13  shows the results of inclusions measurement in the apparatus described herein for an AC source connected to a 12 V battery. 
           [0031]      FIG. 14  shows the results of inclusions measurement in the apparatus described herein for an AC source and analog to digital converter connected to a 12 V battery. 
           [0032]      FIG. 15  shows the result of measuring the four simulated inclusions when the resonant circuit is fed from a 120 V AC source. 
           [0033]      FIG. 16  shows a schematic representation for the LiMCA described herein. 
       
    
    
     DETAILED DESCRIPTION 
       [0034]      FIGS. 1-4  herein are identical to  FIGS. 1-4  of the &#39;880 Patent. As is described in the &#39;880 Patent, a sample-receiving container or vessel  14  (see  FIG. 1 ) is dipped into the flowing stream  12  of molted metal that is to be analyzed. Container  14  has as is shown in  FIGS. 1-4 , an orifice  26  in the order of  300  um to obtain in vessel  14  a sample of the molted metal when a vacuum is created inside vessel  14 . The technique for creating the vacuum is described in the &#39;880 Patent. 
         [0035]    The vessel  14  is removably mounted by any suitable means in an end cap  16 . The end cap  16  is mounted by a standard  18  for vertical up and down movement, so that the vessel  14  can be dipped at will into the flowing stream  12  and withdrawn therefrom. The end cap  16  has four electrodes  20 ,  28 ,  50  and  54  protruding downwardly therefrom. Electrodes  20 ,  50  and  54  are inside the container  14  and electrode  28  is outside of the container. 
         [0036]    The LiMCA inclusions measurement is based on Ohms law, namely that current I through a conductor between two points is directly proportional to the potential difference V across the two points and inversely proportional to the resistance R between them. 
         [0037]    The first of three electrodes inside container  14  is a current-carrying electrode  20  consisting of a metal rod the upper part of which is encased in an insulating material  22 , so that only the exposed lower tip  24  immediately adjacent to a passage  26  in the container wall is in electrical contact with molten metal that enters the container. A similar current-carrying electrode  28  is mounted by the end cap so as to extend outside the container parallel to the first electrode  20  with its bare lower tip also immediately adjacent to the passage  26 . 
         [0038]    In the LiMCA of  FIG. 1 , the resultant current path between the electrodes  20  and  28  and through the passage  26  is supplied with a current normally about  60  A from a battery  30  via a ballast resistor  32  that can be shunted when required by a switch  33 , with one of the leads in the path including a switch  31  and an ammeter  34 . The short circuiting of resistor  32  allows a current in the range of 120 to 600 A to be applied to a newly formed passage  26  for a specific minimum period of time, at least 1 to 5 seconds, to precondition the passage. 
         [0039]    The nominal resistance of a LiMCA, that is, the resistance with no inclusions, is about 2 mΩ.  FIG. 5  shows the resistivity changes when aluminum includes inclusions. The changes are in the order of ˜10 −4  to 10 −7 Ω corresponding to inclusion sizes from about 20 to 300 μm. Applying Ohms law to a LiMCA with a normal current of about 60 A, the measured voltage variation is then between ˜10 −3  to 10 −6  V. 
         [0040]    While  FIG. 1  shows a battery  30  as the source of the non-periodic or direct current, as described in patent &#39;880, it is well known to use ultra-capacitance for that source. Either of such sources isolates the generated DC source signal from the noise generated in the plant environment in which the LiMCA is used for the inclusions measurement but they are massive weighing from about 60 kg to 100 kg which substantially reduces the portability of the prior art LiMCA and increases its complexity and maintenance requirements as the batteries will have to be replaced. Noise influencing the LimCA measurement include but are not limited to: pink noise and coupled industrial environment noise. As is well known, pink noise or 1/f noise (sometimes also called flicker noise) is a signal or process with a frequency spectrum such that the power spectral density (energy or power per Hz) is inversely proportional to the frequency. Noise from the industrial environment can be coupled in several ways and can come from many sources, such as: power line, motors, electromagnetic fields.  FIG. 7  shows typical noise influencing the LiMCA measurement. 
         [0041]    The prior art LiMCA also uses an AC coupling to read the resistivity variations due to the inclusions compared to the nominal probe aperture resistivity. 
         [0042]    As is described in more detail below, the apparatus described herein combines a periodic excitation source with detection methods to perform the quantification of the inclusions in various liquid metals. This combination of a periodic excitation source and detection method is used in the detection of the entrained inclusions in molten metals such as aluminum, gallium, zinc, lead, steel, iron etc. The excitation sources include all periodic based generators such as: high current amplifiers for direct electric sensing zone drive, indirect drive via transformers, indirect drive via tuned impedance transformation networks and circuits such as “L, T, n, SP”, tank circuits (LC parallel) resonators. 
         [0043]    The detection methods include analog demodulation techniques such as: envelop detector, product detector (synchronous detection, analog or digital lock-in) and digital demodulation techniques such as: digital down converter 
         [0044]    Examples of the excitation sources for use in the apparatus described herein are shown in the chart attached as  FIG. 6 . The two major categories of excitation sources are: 
         [0045]    Low to medium power (&lt;50 W) AC amplifier driver: indirect excitation electrical sensing zone; and 
         [0046]    High power 50 W) AC amplifier driver: direct excitation electrical sensing zone. 
         [0047]    As is shown in  FIG. 6 , these categories each have either direct impedance matching through a broadband transformer or a tuned circuit that has impedance matching through an impedance transformation network that can be one of either the “L, T, n, SP” impedance matching network or a resonant circuit. 
         [0048]    The use of demodulation techniques to measure very small variations of resistivity helps to immunize the apparatus against those industrial environments that are electromagnetically noisy, for example, those environments that have noise from electromagnetic casting. The use of periodic excitation combined with demodulation techniques greatly reduces the effect of pink noise or 1/f noise at a frequency below 1 kHz, since the signal is than out of the predominant noise&#39;s spectral region. Noise as used herein includes pink noise, electromagnetic casting noise and electromagnetic noise arising from other sources in the environment in which the LiMCA described herein is used to detect and measure suspended particles in a molten metal. 
         [0049]    Eliminating the batteries and power supply needed to operate the prior art DC excitation version of the LiMCA substantially reduces the overall size and weight of the analyzer and the use of the impedance adaptation and tuned resonating circuits described below allows the efficient generation of high currents in the order of 60 A while greatly reducing the average power dissipated by the circuit. 
         [0050]    The apparatus described herein uses a resonant tank circuit to generate the current in the order of 60 A with a frequency of between about 10 kHz to 100 kHz.  FIG. 8   a  shows an embodiment for such a circuit. As is shown in  FIG. 8   a,  the circuit has the series combination of a capacitor C and resistor Ra in parallel with the series combination of an inductor L and a resistor Rb. 
         [0051]    As is shown in the chart of  FIG. 6 , the excitation source may also either be a low pass impedance match circuit one example of which is shown in  FIG. 8   b  or a high pass impedance match circuit one example of which is shown in  FIG. 8   c.  Both circuits have an AC source that provides a voltage Vi. In both circuits, a resistor Rs is connected between the source and a first junction that has a voltage Va. In the low pass circuit of  FIG. 8   b,  an inductor L connects the first junction to a circuit junction at which appears the output voltage Vo. In the high pass circuit of  FIG. 8   c,  a capacitor C connects the first junction to a circuit junction at which appears the output voltage Vo. In the low pass circuit a capacitor C connects the first junction to ground whereas in the high pass circuit an inductor L connects that junction to ground. In both circuits, the second junction is connected to ground through resistor R 1 . 
         [0052]      FIG. 9   a  and  FIG. 9   b  show embodiments of a detector  900  that can be used in the apparatus measurement. The apparatus uses a time varying current source such as any periodic wave as the excitation source  902 . The measurement between the electrodes gives a change of resistivity when an inclusion  904  passes through the probe orifice. The change of resistivity translates to a change in voltage  906 . In  FIG. 9   a,  the voltage is digitalized using an analog to digital converter (ADC)  908 . The digitalized signal is then demodulated by demodulator  910  to retrieve low frequency signal generate by inclusions. In  FIG. 9   b,  the demodulation is performed first by demodulator  910  and then the voltage is digitalized using an analog to digital converter (ADC)  908 . Appropriate analog or digital filtering is performed before and after digitalization or demodulation. 
         [0053]    The number of inclusions as a function of time is then quantified by counter  912  and shown on a histogram  916 . In quantifying the inclusions, counter  912  uses the known non-linear relationship between the height of the signal for each detected inclusion and the size of the inclusion, that is, the suspend particle. The particles that have a size that falls within a predetermined range of inclusion size are grouped together. The histogram  914  shows the number of particles in each group. 
         [0054]    Referring now to  FIG. 10 , there is shown a block diagram of an experimental setup  1000  for the apparatus described herein. Setup  1000  has an AC current source generator  1002 , one embodiment for which is shown in the block diagram of  FIG. 11 . 
         [0055]    Referring now to  FIG. 11 , the AC current source generator  1002  has a square wave generator  1102  the output of which is connected to optocoupler  1104 . Generator  1002  also has an AC excitation source  1106  having inputs from optocoupler  1104  and DC to DC converter  1108 . A Micrel MIC4102 half bridge MOSFET driver can be used to embody source  1106 . The output of source  1106  is connected to calibrator  1110 . 
         [0056]    The experimental setup  1000  of  FIG. 10  has a calibrator  1004 . Calibrator  1110  of  FIG. 11  is identical to calibrator  1004  to simulate various sizes of the inclusions so that setup  1000  does not have to be used on a live process. 
         [0057]    Experimental setup  1000  also has an ADC evaluation board  1006 . The output of the calibrator  1110  of  FIG. 11  is connected to the input of ADC  908  in  FIGS. 9   a  and  9   b.  Thus the calibrator replaces the functions of the inclusion flow  904  and probe orifice voltage  906  in  FIGS. 9   a  and  9   b.    
         [0058]    The input to board  1006  has an added ultra-low noise amplification front end. One embodiment for the added amplification is shown in  FIG. 12  as amplifier  1200 . The amplifier is the combination of a pre-amplifier  1202  having an input from calibrator  1004  and a differential amplifier  1204  that can be embodied using a Texas Instruments THS4503 wideband low distortion fully differential amplifier. The output of differential amplifier  1204  is the input to the analog to digital converter. The differential amplifier  1204  allows the use of most of the ADC&#39;s dynamic range. 
         [0059]    Referring now to  FIGS. 13 and 14 , there is shown the results acquired using setup  1000 . The smallest inclusions of the calibrator  1004 , which are 20 microns, can be measured with a signal to noise ratio (SNR) of up to 25:1. The other inclusions of the calibrator  1004  which are larger in size can be measured with a SNR better than 25:1.  FIG. 13  shows the results for an AC source connected to a 12 V battery and  FIG. 14  shows the results for the AC source and ADC connected to a 12 V battery. Therefore the results in  FIGS. 13 and 14  show that the apparatus described herein will give good results as compared to the prior art LiMCA&#39;s even when a 12 V battery is used as the source of power for the AC current generator. 
         [0060]    Referring now to  FIG. 15 , there is shown the result of measuring the four simulated inclusions when the resonant circuit is fed from a 120 V AC source. As  FIG. 15  shows when compared to  FIGS. 13 and 14 , the results when the resonant circuit is fed from the 120 V AC source are similar to the results of using an AC source connected to a 12 V battery or an AC source and ADC connected to a 12 V battery. 
         [0061]    Referring now to  FIG. 16 , there is shown diagram of the LiMCA described herein in use to measure inclusions. A closed sample receiving container or vessel  1614  having an outer wall  1614   a  is dipped in the flowing stream  1611  of molten metal. The arrow  1612  shows the direction of flow of stream  1611  in delivery trough  1610 . Container  1614  has an orifice  1617  that has a passage  1621  to obtain a sample of the molten metal when a vacuum is created inside vessel  1614 . 
         [0062]    The vessel  1614  is suitably mounted in a retaining head  1613 . The mechanism that provides up and down movement of the vessel  1614  is not shown in  FIG. 16 . The retaining head  1613  has four electrodes  1623 ,  1624 ,  1637  and  1638  protruding downwardly from the head. Electrodes  1623 ,  1637  and  1638  are inside vessel  1614  and electrode  1624  is outside of the vessel. Electrodes  1623  and  1624  are the current carrying electrodes and their lower tips are adjacent orifice  1617  when a measurement is made. 
         [0063]    The current is supplied by AC current source  1626  which can be embodied by any one of the excitation sources described herein. The two electrodes  1623  and  1624  are connected to a differential amplifier  1631  embodied as described herein. The output of the amplifier  1631  is connected to peak detector  1634  embodied as described herein and then to an analyzer/recorder  1635  and a metal level detector  1636  to head  1613 . 
         [0064]    The head  1613  also provides a fluid connection from the interior of the container  1614  to a three-way valve  1616 , which permits the interior to be connected alternatively to a source of reduced pressure, or to a source of a suitable shielding inert gas, such as argon, or to the atmosphere. The reduced pressure source consists of a vacuum source  1615  which is exhausted as required in between measures through valve by a pump. The pump is shut off while the measures are underway, so that any electrical noise produced by its electric motor does not hinder electrical signal processing, and so that any pulsations in flow of the evacuating gas are not transmitted to the entering molten metal. 
         [0065]    The interior of the container  1614  is flushed before use with argon gas supplied by gas line  1640  to avoid as much as possible contamination of the metal by air. The container  1614  is then lowered into the stream, and the valve  1616  is operated to connect the container interior to the reduced pressure reservoir, whereupon the molten metal is drawn smoothly and rapidly through the passage orifice  1617 . As soon as enough metal has entered the container to touch the tip of the electrode  1623  a current path is established between the two electrodes  1623  and  1624  and through the orifice. 
         [0066]    It should be appreciated that the time varying excitation source and detector described herein can be used in an apparatus that has the barrier and electrodes that are described herein for detecting and measuring suspended particles in a molten metal as a replacement for the current source and associated detection circuitry now used in that apparatus. 
         [0067]    It is to be understood that the description of the foregoing exemplary embodiment(s) is (are) intended to be only illustrative, rather than exhaustive, of the present invention. Those of ordinary skill will be able to make certain additions, deletions, and/or modifications to the embodiment(s) of the disclosed subject matter without departing from the spirit of the invention or its scope, as defined by the appended claims.