Abstract:
A friction brake material contains fibers, graphite and a binder. All or part of the graphite is physically combined with one or more metals or alloys which are softer than steel to form a first combination or mixture. A separate combination or mixture is formed to include friction increasing fibers in a binder. Both mixtures are then combined to form the friction brake material which has an ability to cause substantially less creaking noise upon brake application as compared to differently prepared friction brake material.

Description:
FIELD OF THE INVENTION 
     This invention relates to a friction material used for making brake linings for applying braking forces to automobile wheels and the like. More particularly an improved friction material is disclosed for preventing creaking noises which are otherwise produced during the braking action of a disk brake. 
     DESCRIPTION OF THE PRIOR ART 
     When a brake rotor is braked at low temperatures below 100° C., creaking noises with a low frequency of about 50-500 HZ are often produced immediately before the wheels come to a stop or when a car with an automatic transmission is started or when the brake is released. These creaking noises are produced in organic type friction materials and are noticeable particularly in semimetallic friction materials using steel fiber material. 
     It has been found that the reason for these creaking noises produced by friction materials including steel, is that the steel and graphite ingredients in a steel type friction material cause so-called &#34;stick slip&#34; at very low speeds. It has also been found that such creaking noises tend to be produced even in organic type friction material which do not use steel fibers, but have a high graphite content. 
     To reduce said creaking noises, therefore, it would appear to be effective to reduce the steel fiber content or the graphite content. However, the smaller amount of steel, the lower the friction coefficient. If the steel content is less than 5% by volume, it is no longer possible to maintain the practical function of friction materials. Further, the smaller the amount of graphite, the lower the wear resistance. If the graphite content is less than 5% by volume, the amount of wear of the friction materials increases substantially. In friction material not using steel fibers, the addition of graphite is an effective means for increasing wear resistance. Therefore, it is not preferable to reduce the amount of graphite or do away with it. 
     Japanese Patent Publication No. 22984/1984 discloses that the aforesaid creaking noises may be prevented if the steel fibers are combined with nickel, zinc, tin, lead or an alloy thereof by melting. This method, however, is expensive. 
     SUMMARY OF THE INVENTION 
     Accordingly, an object of the invention is to provide a friction material which reduces creaking noises, contains an amount of graphite required to prevent a degradation of the wear resistance and is also cost-effective. 
     This invention provides a friction material which is a mixture containing fibers, graphite and one or more metals or alloys which are softer than steel embedded in a binder or matrix material, wherein all or part of said graphite is first mixed with said metal or alloy before further mixing with the fibers and binder. 
     These object and other objects, features, aspects and advantages of the present invention will become more apparent from the following detailed description of the present invention when taken in conjunction with the accompanying drawings. 
     BRIEF DESCRIPTION OF THE DRAWING 
     FIG. 1 is a schematic sectional view of an example of a friction material according to this invention; and 
     FIG. 2 is a schematic sectional view of an example of a conventional friction material. 
    
    
     DESCRIPTION OF THE PREFERRED EMBODIMENTS 
     We have found that the above mentioned creaking noises of brake linings can be effectively prevented by first physically mixing all or part of the graphite with one or more metals or alloys, which are softer than steel to prepare a first metal graphite mixture, which is then further mixed with the fibers and a binder to form a friction material. FIG. 1 shows an example of a friction material according to this invention comprising a mixture 4 graphite and metal or alloy, and steel fibers 1 in a matrix material. On the other hand, a conventional friction material shown in FIG. 2 contains graphite 2 separate from the steel fibers 1. That is, this invention is characterized in that all or part of the graphite has been first physically mixed with one or more metals or alloys. 
     As for metals or alloys which are softer than steel, lead, tin, zinc and copper are effective and brass and bronze, which are alloys thereof, are effective. 
     There are various methods of physically combining e.g., by mixing graphite with metal or alloy to form a first mixture which is then further combined with fibers in a matrix to form a second mixture. For example, graphite and metal or alloy may be physically mixed and held together by a first binder which initimately bonds the graphite and the metal or metal alloy to each other. Among binders to be used are rubber, epoxy resin, phenol resin and other organic matter, water glass and other inorganic matter. Further, graphite and metal or alloy may be physically combined by together by mixing, pressing and sintering. It is also possible to physically combine graphite and metal or alloy together by plating the graphite with the metal or alloy. Further, graphite and metal or alloy may be physically combined together by melting. 
     The components which are effective as a frictant or friction causing agent in the friction material of this invention are inorganic fibers of asbestos, glass, rock wool, glass wool and the like, metal fibers such as steel fibers, and organic fibers such as carbon fibers, acrylic fibers treated for flame resistance, and aramid fibers. Further, to ensure a satisfactory friction coefficient and wear resistance, preferably, the friction material contains, on a volume basis, 5-35% of steel fibers or steel powder as a frictant, 10-35% binder, and 0.5-15% metal other than steel, the balance being graphite, and organic and/or inorganic filler. 
     Functional tests were conducted using friction materials A-E formulated according to Table 1 shown below. In the table 1, samples A-D are examples of the invention and sample E is a control sample. 
     
                       TABLE 1______________________________________     Formulation (volume percent)     Example of Invention                      ControlSample      A       B      C     D     E______________________________________Steel fiber 30      30     32    32    30Phenol resin       25      25     27    27    25Barium sulfate       12      12     13    13    12Silica       3       3      3     3     3Combination 30circle.aCombination  ○b               30Combination  ○c     12Combination  ○d           25Graphite                   13          21Epoxy resin                             6Zinc powder                             3______________________________________ 
    
     SAMPLE A (EXAMPLE OF THE INVENTION) 
     On a volume basis, 5% zinc powder with a grain size of less than 200 mesh, 25% epoxy resin as a first binder, and 70% graphite with a grain size of less than 200 mesh were mixed, and the mixture was maintained in a hot air furnace in a 200° C. atmosphere for 4 hours and cured. Thereafter, it was crushed to provide a first mixture or combination  ○a . This first combination or mixture  ○a , was further combined with a second mixture of steel fiber, phenol resin, as a second binder or matrix material barium sulfate and silica prepared according to Table 1.The result of combining the first and second mixtures was press-molded and after-cured to thereby prepare a friction material having a porosity of about 5%. 
     SAMPLE B (EXAMPLE OF THE INVENTION) 
     On a volume basis, 5% lead-tin alloy powder with a grain size of less than 200 mesh, 25% epoxy resin as a first binder, and 70% graphite with a grain size of less than 200 mesh were mixed, and the mixture was maintained in a hot air furnace in a 200° C. atmosphere for 4 hours and cured. It was crushed to provide a first combination of mixture  ○b , which is then further combined with a second mixture including steel fiber, phenol resin as a second binder or matrix material, barium sulfate and silica prepared according to the Table 1. The result of combining the first and second mixtures was press-molded and after-cured to thereby prepare a friction material having a porosity of about 5%. 
     SAMPLE C (EXAMPLE OF THE INVENTION) 
     On a volume basis, 70% graphite and 30% zinc powder were mixed together with a caking agent. The mixture was pressed and sintered and then crushed to provide a first combination or mixture  ○c  which is then further combined with a second mixture of steel fiber, phenol resin as a matrix material, barium sulfate, silica and graphite prepared according to Table 1. The result of combining the first and second mixtures was press-molded and after-cured to thereby prepare a friction material having a porosity of about 5%. The term &#34;caking agent&#34; means a molding auxiliary, such as an organic substance e.g., paraffin or camphor. 
     SAMPLE D (EXAMPLE OF THE INVENTION) 
     Porous graphite was impregnated with molten zinc and then crushed, to form a first combination or mixture  ○d  of70% graphite and 30% zinc, on a volume basis. This first combination or mixture  ○d , was then further combined with a second mixture of steel fiber, phenol resin as a matrix material, barium sulfate and silica prepared according to Table 1. The result of combining the first and second mixtures was press-molded and after-cured to thereby prepare a friction material having a porosity of about 5%. 
     SAMPLE E (CONTROL) 
     Steel fibers, phenol resin, barium sulfate, silica, graphite, epoxy resin and zinc powder were mixed according to the formulation shown in Table 1. Under the following condition, it was press-molded and after-cured to thereby prepare a friction material having a porosity of about 5%. 
     Press condition: Putting the mixture in a mold heated to 150° C. and pressing it therein for 10 minutes. 
     In addition, the mold was a force-cut type mold designed for a constant volume, and the mixture was charged into the mold with sufficient accuracy to ensure that the porosity of the friction material was 5%. The mixture was maintained in a hot air furnace in a 250° C. atmosphere for 10 hours and then after-cured. 
     RESULTS OF FUNCTIONAL TESTS 
     Functional tests in creaking noises were conducted using said friction material A-E in ordinary automobiles. The magnitude of the creaking noises produced was evaluated as shown in Table 2 below. 
     
                       TABLE 2______________________________________Friction RotorMaterial Tempera-  Deceleration (g)Class    ture (°C.)              0.05   0.10 0.15 0.20 0.25 0.30______________________________________Example  A     30        2    2    0    1    1    0of the       50        2    1    1    0    0    0Invention    70        1    0    0    0    0    0        100       0    0    0    0    0    0  B     30        2    2    2    1    1    0        50        2    1    2    1    1    0        70        0    0    1    0    0    1        100       0    0    1    0    0    0  C     30        2    1    1    1    1    0        50        1    1    1    1    0    0        70        1    1    1    0    0    0        100       0    1    0    0    0    0  D     30        1    1    1    1    0    0        50        1    1    1    0    0    0        70        1    1    1    0    0    0        100       0    0    0    0    0    0Control  E     30        3    2    2    2    1    0        50        3    3    3    3    2    1        70        2    2    2    0    2    2        100       2    2    1    0    0    0______________________________________ 
    
     The initial velocity of the automobile was 20 Km/hr., and the rotor temperature Ti (°C.) was changed in 4 steps as shown in Table 2. Further, the deceleration β(g) was changed in 6 steps for each temperature step, as shown in Table 2. Thus, brake tests were conducted once for each combination of values, and the magnitude of the creaking sound was evaluated. Creaking noises were evaluated by conducting a functional test in which the driver evaluated it with his ears, rating the noises at 3, 2 or 1 in the decreasing order of magnitude, using 0 to indicate the absence of any creaking noises. 
     It can be seen from Table 2 that the friction materials according to the invention are effective in preventing creaking noises. Further, fade tests were conducted for the friction materials using a dynamometer. 
     When the initial velocity of the automobile was 100 Km/hr and the deceleration was 0.45 g, the brake was applied 10 times at intervals of 35 seconds to determine the friction coefficient (μ). Each friction material showed its minimum value at the 6th braking, the respective values being as follows. 
     Sample A (example of the invention): 0.23 
     Sample B (example of the invention): 0.24 
     Sample C (example of the invention): 0.26 
     Sample D (example of the invention): 0.28 
     Sample E (control): 0.19 
     The above results prove that the fade resistance and creaking noise reduction of the examples of the invention are superior to the fade resistance and creaking noise reduction of the control example. In addition, concerning the samples C and D it is to be noted that the improvement the fade resistance is particularly remarkable since substantially no organic matter was used in producing the friction brake material. 
     As described above, friction materials according to the invention are effective in preventing creaking noises and are superior in fade resistance. 
     Although the present invention has been described and illustrated in detail, it is clearly understood that the same is by way of illustration and example only and is not to be taken by way of limitation, the spirit and scope of the present invention being limited only by the terms of the appended claims.