| [ | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1002/ente.201300102\nUltrathin Surface Modification by Atomic Layer Deposition on High Voltage Cathode LiNi 0.5 Mn 1.5 O 4 for Lithium Ion Batteries\n\n\nLiNi0.5Mn1.5O4 particles were synthesized through solid-state reactions. Nickel acetate [Ni(Ac)2[?]4 H2O] and manganese acetate [Mn(Ac)2[?]4 H2O] were mixed at a molar ratio of Ni/Mn=1:3 and milled in a mortar. After heating at 500 degC for 5 h, lithium acetate (LiAc[?]2 H2O) was added to the mixture at a molar ratio of Li/Ni/Mn=2.1:1:3 (5 % excess Li source was added to balance for the volatilized Li during calcination), and the mixture was heated to 500 degC for 5 h once more. Then the mixture was milled and sintered at 950 degC for 10 h followed by annealing at 700 degC for 10 h.\n\n\n\n", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "1:3", | |
| "unit": null, | |
| "measured_entity": "Ni/Mn", | |
| "measured_property": "molar ratio" | |
| }, | |
| { | |
| "quantity": "500 degC", | |
| "unit": "degC", | |
| "measured_entity": "mixture", | |
| "measured_property": "heating" | |
| }, | |
| { | |
| "quantity": "5 h", | |
| "unit": "h", | |
| "measured_entity": "mixture", | |
| "measured_property": "heating" | |
| }, | |
| { | |
| "quantity": "5 %", | |
| "unit": "%", | |
| "measured_entity": "Li source", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "500 degC", | |
| "unit": "degC", | |
| "measured_entity": "mixture", | |
| "measured_property": "heated" | |
| }, | |
| { | |
| "quantity": "5 h", | |
| "unit": "h", | |
| "measured_entity": "mixture", | |
| "measured_property": "heated" | |
| }, | |
| { | |
| "quantity": "2.1:1:3", | |
| "unit": null, | |
| "measured_entity": "Li/Ni/Mn", | |
| "measured_property": "molar ratio" | |
| }, | |
| { | |
| "quantity": "950 degC", | |
| "unit": "degC", | |
| "measured_entity": "mixture", | |
| "measured_property": "sintered" | |
| }, | |
| { | |
| "quantity": "10 h", | |
| "unit": "h", | |
| "measured_entity": "mixture", | |
| "measured_property": "milled and sintered" | |
| }, | |
| { | |
| "quantity": "700 degC", | |
| "unit": "degC", | |
| "measured_entity": "mixture", | |
| "measured_property": "annealing" | |
| }, | |
| { | |
| "quantity": "10 h", | |
| "unit": "h", | |
| "measured_entity": "mixture", | |
| "measured_property": "annealing" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101002ente201300102", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "LiMnPO4 plates were synthesized by a hydrothermal method. In a typical synthesis procedure, 14 mmol Na2S*9H2O, 40 mmol Li2SO4*H2O, 20 mmol MnSO4*H2O and 20 mmol NH4H2PO4 were added in sequence in a 40 mL Teflon liner with 30 mL distilled water under vigorous stirring for 30 min, and the Teflon liner was then placed in a stainless steel autoclave. The sealed tank was put into an oven and maintained at 200 degC for 10 h. After the hydrothermal reaction, the autoclave was cooled to room temperature and the resulted precipitate was filtered, washed and finally dried in air at 60 degC overnight.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "14 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "Na2S*9H2O", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "40 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "Li2SO4*H2O", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "20 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "MnSO4*H2O", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "20 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "NH4H2PO4", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "40 mL", | |
| "unit": "mL", | |
| "measured_entity": "Teflon liner", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "30 mL", | |
| "unit": "mL", | |
| "measured_entity": "distilled water", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "30 min", | |
| "unit": "min", | |
| "measured_entity": "14 mmol Na2S*9H2O, 40 mmol Li2SO4*H2O, 20 mmol MnSO4*H2O and 20 mmol NH4H2PO4 were added in sequence in a 40 mL Teflon liner with 30 mL distilled water", | |
| "measured_property": "stirring" | |
| }, | |
| { | |
| "quantity": "200 degC", | |
| "unit": "degC", | |
| "measured_entity": "sealed tank", | |
| "measured_property": "maintained" | |
| }, | |
| { | |
| "quantity": "10 h", | |
| "unit": "h", | |
| "measured_entity": "sealed tank", | |
| "measured_property": "maintained" | |
| }, | |
| { | |
| "quantity": "60 degC", | |
| "unit": "degC", | |
| "measured_entity": "precipitate", | |
| "measured_property": "dried" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jelectacta201209106", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1016/j.electacta.2014.04.056\nEffects of highly crumpled graphene nanosheets on the electrochemical performances of pseudocapacitor electrode materials\n\n All chemicals were of analytical grade and used without further purification. In a typical synthesis process, 5 mg GS and 0.3 g NiCl2*6H2O were dispersed in 20 ml distilled water and subjected to ultrasonic vibration to form a homogeneous suspension, respectively. The two former suspensions were homogeneously mixed with each other and subjected to ultrasonic vibration for a while, and then freeze drying (named as M1). The 1.03 g NaH2PO2*H2O was grinded in a mortar and mixed with M1. Then, the mixture was calcined at 500 degC for 1 h with 2 degC/min heating rate and cooled to room temperature under a flow of Ar (99.999%). The solid obtained was washed thoroughly with distilled water and absolute ethyl alcohol to remove the by-products. After that, the wet products were dried at 80 degC for 12 h in a vacuum oven.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "5 mg", | |
| "unit": "mg", | |
| "measured_entity": "GS", | |
| "measured_property": "dispersed" | |
| }, | |
| { | |
| "quantity": "0.3 g", | |
| "unit": "g", | |
| "measured_entity": "dispersed", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "20 ml", | |
| "unit": "ml", | |
| "measured_entity": "distilled water", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "1.03 g", | |
| "unit": "g", | |
| "measured_entity": "NaH2PO2*H2O", | |
| "measured_property": "grinded" | |
| }, | |
| { | |
| "quantity": "500 degC", | |
| "unit": "degC", | |
| "measured_entity": "mixture", | |
| "measured_property": "calcined" | |
| }, | |
| { | |
| "quantity": "1 h", | |
| "unit": "h", | |
| "measured_entity": "mixture", | |
| "measured_property": "calcined" | |
| }, | |
| { | |
| "quantity": "2 degC/min", | |
| "unit": "degC/min", | |
| "measured_entity": "mixture", | |
| "measured_property": "heating rate" | |
| }, | |
| { | |
| "quantity": "99.999%", | |
| "unit": "%", | |
| "measured_entity": "Ar", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "80 degC", | |
| "unit": "degC", | |
| "measured_entity": "wet products", | |
| "measured_property": "dried" | |
| }, | |
| { | |
| "quantity": "12 h", | |
| "unit": "h", | |
| "measured_entity": "wet products", | |
| "measured_property": "dried" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jelectacta201404056", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1016/j.electacta.2014.08.103\nFacile synthesis of heterogeneous Ni-Si@C nanocomposites as high-performance anodes for Li-ion batteries\n\nBefore the electrical pulse process with Ni wire, Si nanoparticles (0.2, 0.6, and 0.8 g) were first dispersed in 700 mL of OA, and the Si nanoparticles-dispersed suspension was sonicated for 1 h. Then, the electrical wire explosion (NTi-mini P, Nano Tech, Korea) was conducted at a feeding distance of 40 mm and a charge voltage of 320 V in the Si nanoparticles-dispersed suspension. After completing the electrical pulse treatment with Ni wire, the obtained brownish Ni-Si nanocolloidal suspension was sonicated and filtered through a nylon membrane (Durapore, 0.22 mm, Millipore) several times and subsequently dried at 120 degC for 10 h. Finally, the carbon-coated Ni-Si nanocomposites were obtained via carbonization process (heat-treatment) carried out at 500 degC for 5 h in an Ar atmosphere.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "0.2, 0.6, and 0.8 g", | |
| "unit": "g", | |
| "measured_entity": "Si nanoparticles", | |
| "measured_property": "dispersed" | |
| }, | |
| { | |
| "quantity": "700 mL", | |
| "unit": "mL", | |
| "measured_entity": "OA", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "1 h", | |
| "unit": "h", | |
| "measured_entity": "Si nanoparticles-dispersed suspension", | |
| "measured_property": "sonicated" | |
| }, | |
| { | |
| "quantity": "40 mm", | |
| "unit": "mm", | |
| "measured_entity": "electrical wire explosion", | |
| "measured_property": "feeding distance" | |
| }, | |
| { | |
| "quantity": "320 V", | |
| "unit": "V", | |
| "measured_entity": "electrical wire explosion", | |
| "measured_property": "charge voltage" | |
| }, | |
| { | |
| "quantity": "120 degC", | |
| "unit": "degC", | |
| "measured_entity": "brownish Ni-Si nanocolloidal suspension", | |
| "measured_property": "dried" | |
| }, | |
| { | |
| "quantity": "10 h", | |
| "unit": "h", | |
| "measured_entity": "brownish Ni-Si nanocolloidal suspension", | |
| "measured_property": "dried" | |
| }, | |
| { | |
| "quantity": "0.22 mm", | |
| "unit": "mm", | |
| "measured_entity": "nylon membrane (Durapore", | |
| "measured_property": "Millipore" | |
| }, | |
| { | |
| "quantity": "500 degC", | |
| "unit": "degC", | |
| "measured_entity": "carbon-coated Ni-Si nanocomposites", | |
| "measured_property": "carbonization process (heat-treatment)" | |
| }, | |
| { | |
| "quantity": "5 h", | |
| "unit": "h", | |
| "measured_entity": "carbon-coated Ni-Si nanocomposites", | |
| "measured_property": "carbonization process (heat-treatment)" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jelectacta201408103", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1016/j.electacta.2014.12.157\nSynthesis and electrochemical performance of ZnCo2O4 for lithium-ion battery application\n\n\nAll of the chemicals in our synthesis were analytical grade and were used without further purification. In a typical procedure, zinc acetate dihydrate and cobalt (II) acetate tetrahydrate with a Zn/Co molar ratio of 1:2 were added to a ball mill. Citric acid with a 120% mole fraction relative to the Zn and Co was then added into the ball mill. After adding a suitable volume of water, the ball mill was run for 4 h at 500 rpm to obtain the precursor. Then, the resultant mixture was dried at 80 degC in air, and the wine red precursor powder was collected and heat-treated in a muffle furnace at 400 degC and 500 degC, with the products designated as 400-ZCO and 500-ZCO, respectively.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "1:2", | |
| "unit": null, | |
| "measured_entity": "zinc acetate dihydrate and cobalt (II) acetate tetrahydrate", | |
| "measured_property": "molar ratio" | |
| }, | |
| { | |
| "quantity": "120%", | |
| "unit": "%", | |
| "measured_entity": "Citric acid", | |
| "measured_property": "mole fraction relative to the Zn and Co" | |
| }, | |
| { | |
| "quantity": "4 h", | |
| "unit": "h", | |
| "measured_entity": "ball mill", | |
| "measured_property": "run" | |
| }, | |
| { | |
| "quantity": "500 rpm", | |
| "unit": "rpm", | |
| "measured_entity": "ball mill", | |
| "measured_property": "run" | |
| }, | |
| { | |
| "quantity": "400 degC and 500 degC", | |
| "unit": "degC", | |
| "measured_entity": "wine red precursor powder", | |
| "measured_property": "heat-treated" | |
| }, | |
| { | |
| "quantity": "80 degC", | |
| "unit": "degC", | |
| "measured_entity": "mixture", | |
| "measured_property": "dried" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jelectacta201412157", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1016/j.energy.2014.08.058\nHierarchical 3D micro-/nano-V2O5 (vanadium pentoxide) spheres as cathode materials for high-energy and high-power lithium ion-batteries\n\nHierarchical 3D micro-/nano-V2O5 spheres were prepared via a facile low temperature hydrothermal method. Typically, NH4VO3 (ammonium metavanadate) solution, HCl, and poly (sodium 4-styrenesulfonate) (PSS, 2 mL) were well mixed in DI (deionized) water. The pH of the mixed solution was adjusted to be less than 2.7 so as to assist the growth of V2O5[58]. The resultant solution was transferred into a 100 mL Teflon-lined autoclave and heated to 180 degC for 24 h in an electrical oven. After cooling down naturally to room temperature, the precipitates were washed with DI water and ethanol alternatively for several times to remove residual starting materials before further characterization and electrochemical testing.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "2 mL", | |
| "unit": "mL", | |
| "measured_entity": "poly (sodium 4-styrenesulfonate)", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "less than 2.7", | |
| "unit": null, | |
| "measured_entity": "mixed solution", | |
| "measured_property": "adjusted" | |
| }, | |
| { | |
| "quantity": "100 mL", | |
| "unit": "mL", | |
| "measured_entity": "Teflon-lined autoclave", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "180 degC", | |
| "unit": "degC", | |
| "measured_entity": "resultant solution", | |
| "measured_property": "heated" | |
| }, | |
| { | |
| "quantity": "24 h", | |
| "unit": "h", | |
| "measured_entity": "resultant solution", | |
| "measured_property": "heated" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jenergy201408058", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "Tailoring of phase composition and morphology of TiO2-based electrode materials for lithium-ion batteries\n\nThe mixed titania phases were synthesized via hydrothermal treatment in alkaline environment based on procedure by Yoshida et al. As starting material TiO2 from Umicore was used which was mixed with NaOH in distilled water. Throughout stirring a homogeneous solution was obtained which was transferred into a Teflon lined autoclave and kept at 150 degC for 72 h. After cooling naturally to ambient temperature the white, sorbet-like product was washed in distilled water to eliminate remaining NaOH before washing in 0.1 M HCl at pH <= 2. In a final washing step the solution was brought to neutrality. Subsequently the product was dried at [?]100 degC, ground and sieved to a 50 \u03bcm mesh. In a final preparation step the white powder samples were heat treated in air at 450 degC for 4 h in air.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "150 degC", | |
| "unit": "degC", | |
| "measured_entity": "homogeneous solution", | |
| "measured_property": "kept" | |
| }, | |
| { | |
| "quantity": "72 h", | |
| "unit": "h", | |
| "measured_entity": "homogeneous solution", | |
| "measured_property": "kept" | |
| }, | |
| { | |
| "quantity": "0.1 M", | |
| "unit": "M", | |
| "measured_entity": "HCl", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "<= 2", | |
| "unit": null, | |
| "measured_entity": "0.1 M HCl", | |
| "measured_property": "pH" | |
| }, | |
| { | |
| "quantity": "100 degC", | |
| "unit": "degC", | |
| "measured_entity": "product", | |
| "measured_property": "dried" | |
| }, | |
| { | |
| "quantity": "50 \u03bcm", | |
| "unit": "\u03bcm", | |
| "measured_entity": "mesh", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "450 degC", | |
| "unit": "degC", | |
| "measured_entity": "white powder samples", | |
| "measured_property": "heat treated" | |
| }, | |
| { | |
| "quantity": "4 h", | |
| "unit": "h", | |
| "measured_entity": "white powder samples", | |
| "measured_property": "heat treated" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jjpowsour201212058", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "j.jpowsour.2013.10.120\nFabrication and performance of BaCe0.8Y0.2O3-\u03b4-BaZr0.8Y0.2O3-\u03b4 bilayer electrolyte for anode-supported solid oxide fuel cells\n\nBCY and BZCY powders were fabricated using a citric acid-nitrate gel combustion process [15]. First, BaCO3, Ce(NO3)4*4H2O, Zr(NO3)4 *5H2O and Y(NO3)3*6H2O was added to a solution of HNO3. After the solution became clear, citric acid was added in a 1:1.5 metal ions:citric acid molar ratio. The solution was continuously stirred and heated at 70 degC until a gel formed. The gel was then heated on a hot plate and combusted to form powder precursors, which were then calcined at 1000 degC for 3 h to obtain a pure, crystalline BCY and BZCY phase. NiO (basic nickel carbonate decomposed at 600 degC) and BZCY were mixed by ball milling in ethanol for 24 h in a weight ratio of 60/40 with 10 wt.% of starch as pore formers. The mixture was dried in an oven at 60 degC and prepared as anode supporting substrates.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "1:1.5", | |
| "unit": null, | |
| "measured_entity": "metal ions:citric acid", | |
| "measured_property": "molar ratio" | |
| }, | |
| { | |
| "quantity": "70 degC", | |
| "unit": "degC", | |
| "measured_entity": "solution", | |
| "measured_property": "heated" | |
| }, | |
| { | |
| "quantity": "1000 degC", | |
| "unit": "degC", | |
| "measured_entity": "powder precursors", | |
| "measured_property": "calcined" | |
| }, | |
| { | |
| "quantity": "3 h", | |
| "unit": "h", | |
| "measured_entity": "powder precursors", | |
| "measured_property": "calcined" | |
| }, | |
| { | |
| "quantity": "24 h", | |
| "unit": "h", | |
| "measured_entity": "NiO (basic nickel carbonate decomposed at 600 degC) and BZCY", | |
| "measured_property": "mixed by ball milling in ethanol" | |
| }, | |
| { | |
| "quantity": "60/40", | |
| "unit": null, | |
| "measured_entity": "NiO (basic nickel carbonate decomposed at 600 degC) and BZCY", | |
| "measured_property": "weight ratio" | |
| }, | |
| { | |
| "quantity": "10 wt.%", | |
| "unit": "wt.%", | |
| "measured_entity": "starch", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "600 degC", | |
| "unit": "degC", | |
| "measured_entity": "basic nickel carbonate", | |
| "measured_property": "decomposed" | |
| }, | |
| { | |
| "quantity": "60 degC", | |
| "unit": "degC", | |
| "measured_entity": "mixture", | |
| "measured_property": "dried" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jjpowsour201310120", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "(001) Si wafers were etched by mixed solution of 0.4 M AgNO3 and HF for 30 min. After the etching process, the by-products (Ag nanostructures) were removed by nitric acid, leaving the nanowire bundles (Fig. 1(a)). The samples were cleaned by deionized water and dilute HF is used to remove the surface oxide. Then different amount of hydrazine monohydrate (98%) was controlled and infiltrated through the as-formed nanowires (Fig. 1(b)). A solution of mixing BiCl3 (0.2 M) in nitric acid and H6TeO6 (0.15 M) in deionized water was prepared, followed by the addition of thioglycolic acid for the formation of the mixed complex at room temperature. Then the solution temperature was raised to 90 degC and Bi2Te3 nanoparticles were synthesized when dipping the hydrazine-coated samples in the as-prepared solution for the reduction of the Bi2Te3 (Fig. 1(c)). The as-synthesized samples were then washed with excess acetone and dried by N2 blow.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "0.4 M", | |
| "unit": "M", | |
| "measured_entity": "mixed solution", | |
| "measured_property": "AgNO3 and HF" | |
| }, | |
| { | |
| "quantity": "30 min", | |
| "unit": "min", | |
| "measured_entity": "Si wafers", | |
| "measured_property": "etched" | |
| }, | |
| { | |
| "quantity": "98%", | |
| "unit": "%", | |
| "measured_entity": "hydrazine monohydrate", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "0.2 M", | |
| "unit": "M", | |
| "measured_entity": "BiCl3", | |
| "measured_property": "mixing" | |
| }, | |
| { | |
| "quantity": "0.15 M", | |
| "unit": "M", | |
| "measured_entity": "H6TeO6", | |
| "measured_property": "mixing" | |
| }, | |
| { | |
| "quantity": "90 degC", | |
| "unit": "degC", | |
| "measured_entity": "solution", | |
| "measured_property": "temperature" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jnanoen201411053", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1016/j.nanoen.2016.05.050\nNaV3(PO4)3/C nanocomposite as novel anode material for Na-ion batteries with high stability\n\nNaV3(PO4)3/C was synthesized by a sol-gel process and followed by carbon thermal reduction synthesis. Typically, 6 mmol NH4VO3 were added to 70 mL deionized water maintaining at 80 degC with continuous stirring to obtain a clear yellow solution, and then 6 mmol NH4H2PO4, 2 mmol Na2CO3 and 4 mmol citric acid were added. The gel was dried in an oven at 150 degC for 4 h, and heat-treated at 400 degC for 5 h under nitrogen atmosphere to remove CO2, H2O, and NH3. Afterward, the powder was grounded and annealed at 900 degC under H2/Ar flow (10% H2) for 12 h to produce the final compound.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "6 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "NH4VO3", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "70 mL", | |
| "unit": "mL", | |
| "measured_entity": "deionized water", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "80 degC", | |
| "unit": "degC", | |
| "measured_entity": "6 mmol NH4VO3 were added to 70 mL deionized water", | |
| "measured_property": "maintaining" | |
| }, | |
| { | |
| "quantity": "6 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "NH4H2PO4", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "2 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "Na2CO3", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "4 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "citric acid", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "150 degC", | |
| "unit": "degC", | |
| "measured_entity": "dried", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "4 h", | |
| "unit": "h", | |
| "measured_entity": "gel", | |
| "measured_property": "dried" | |
| }, | |
| { | |
| "quantity": "400 degC", | |
| "unit": "degC", | |
| "measured_entity": "gel", | |
| "measured_property": "heat-treated" | |
| }, | |
| { | |
| "quantity": "5 h", | |
| "unit": "h", | |
| "measured_entity": "gel", | |
| "measured_property": "heat-treated" | |
| }, | |
| { | |
| "quantity": "900 degC", | |
| "unit": "degC", | |
| "measured_entity": "powder", | |
| "measured_property": "annealed" | |
| }, | |
| { | |
| "quantity": "10%", | |
| "unit": "%", | |
| "measured_entity": "H2", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "12 h", | |
| "unit": "h", | |
| "measured_entity": "H2/Ar", | |
| "measured_property": "annealed" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jnanoen201605050", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1016/j.poly.2011.06.009\nPhotoinduced electron transfer in pentacoordinated complex of zinc tetraphenylporphyrin and isoquinoline N-oxide. Crystal structure, spectroscopy and DFT studies\nTetraphenylporphine (TPP) was prepared from pyrrole and benzaldehyde in boiling propionic acid [22]. Pyrrole was obtained by the known method [23] using the thermal decomposition of diammonium salt of mucic acid which was prepared from mucic acid and NH4OH. Mucic acid was synthesized by galactose oxidation with HNO3 upon heating [24]. \nZn-tetraphenylporphine (Zn-TPP) was synthesized according to known procedure [25] with some changes. Tetraphenylporphine (TPP) in CHCl3 was kept over PbO2 during 2 days to remove admixture of tetraphenylchlorine (2-10% of which can be formed at TPP synthesis) and a radical of unknown structure [26]. A mixture of 0.5 g (0.813 mmol) TPP, 0.25 g (1.14 mmol, 1.4-fold excess) of (CH3COO)2Zn*2H2O, 50 mL of chloroform and 250 mL of glacial acetic acid was boiled for 1 h (using of 7-fold excess of (CH3COO)2Zn leads to the final substance almost without the initial TPP). The resultant dark blue crystals of Zn-TPP were washed with acetic acid. Then the substance was chromatographed on an alumina column with chloroform. TLC was used (Silufol, chloroform-hexane 2:1) for Zn-TPP purity determination. To 34 mg (0.05 mM) of Zn-TPP dissolved in 15 mL of acetone, 1 mL of an acetone solution of isoquinoline N-oxide (7.3 mg, 0.05 mM) was added. The red-violet crystals appeared in 30 min, which were washed with acetone (1 mL, 2 times) and air dried.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "2 days", | |
| "unit": "days", | |
| "measured_entity": "Tetraphenylporphine (TPP) in CHCl3", | |
| "measured_property": "kept over PbO2" | |
| }, | |
| { | |
| "quantity": "2-10%", | |
| "unit": "%", | |
| "measured_entity": "admixture", | |
| "measured_property": "tetraphenylchlorine" | |
| }, | |
| { | |
| "quantity": "0.5 g", | |
| "unit": "g", | |
| "measured_entity": "TPP", | |
| "measured_property": "boiled" | |
| }, | |
| { | |
| "quantity": "0.813 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "TPP", | |
| "measured_property": "boiled" | |
| }, | |
| { | |
| "quantity": "0.25 g", | |
| "unit": "g", | |
| "measured_entity": "(CH3COO)2Zn*2H2O", | |
| "measured_property": "boiled" | |
| }, | |
| { | |
| "quantity": "1.14 mmol", | |
| "unit": "mmol", | |
| "measured_entity": "(CH3COO)2Zn*2H2O", | |
| "measured_property": "boiled" | |
| }, | |
| { | |
| "quantity": "50 mL", | |
| "unit": "mL", | |
| "measured_entity": "chloroform", | |
| "measured_property": "boiled" | |
| }, | |
| { | |
| "quantity": "250 mL", | |
| "unit": "mL", | |
| "measured_entity": "glacial acetic acid", | |
| "measured_property": "boiled" | |
| }, | |
| { | |
| "quantity": "1 h", | |
| "unit": "h", | |
| "measured_entity": "mixture", | |
| "measured_property": "boiled" | |
| }, | |
| { | |
| "quantity": "2:1", | |
| "unit": null, | |
| "measured_entity": "TLC", | |
| "measured_property": "Silufol, chloroform-hexane" | |
| }, | |
| { | |
| "quantity": "34 mg", | |
| "unit": "mg", | |
| "measured_entity": "Zn-TPP", | |
| "measured_property": "dissolved" | |
| }, | |
| { | |
| "quantity": "0.05 mM", | |
| "unit": "mM", | |
| "measured_entity": "Zn-TPP", | |
| "measured_property": "dissolved" | |
| }, | |
| { | |
| "quantity": "15 mL", | |
| "unit": "mL", | |
| "measured_entity": "acetone", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "1 mL", | |
| "unit": "mL", | |
| "measured_entity": "acetone solution", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "7.3 mg", | |
| "unit": "mg", | |
| "measured_entity": "isoquinoline N-oxide", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "0.05 mM", | |
| "unit": "mM", | |
| "measured_entity": "isoquinoline N-oxide", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "30 min", | |
| "unit": "min", | |
| "measured_entity": "red-violet crystals", | |
| "measured_property": "appeared" | |
| }, | |
| { | |
| "quantity": "1 mL", | |
| "unit": "mL", | |
| "measured_entity": "acetone", | |
| "measured_property": "washed" | |
| }, | |
| { | |
| "quantity": "2 times", | |
| "unit": "times", | |
| "measured_entity": "acetone", | |
| "measured_property": "washed" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101016jpoly201106009", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1038/srep43506\nMultifunctional Nanographene Oxide for Targeted Gene-Mediated Thermochemotherapy of Drug-resistant Tumour\nGraphite powder was purchased from Acros. KMnO4 (AR), NaNO3 (AR), linear chain PEG amine (5000), branched polyethylenimine 10000 (BPEI 10000), folic acid, EDC and NHS, were purchased from Sigma-Aldrich. Doxorubicin was purchased from Sangon Biotech (Shanghai, China). Modified RPMI-1640 Medium was purchased from HyClone. Fetal bovine serum (FBS), penicillin-streptomycin, and trypsin were obtained from Gibco. Propidium iodide, LysoTracker, MitoTracker and Hoechst were purchased from Molecular Probes (USA). The Cell Counting Kit-8 (CCK-8) and Calcein AM were purchased from Dojindo (Japan). The \u03b2-actin antibody was purchased from GeneTex (USA). The dialysis bags and ultrafiltration tubes (molecular weight cutoff: 10-kDa and 30-kDa) were purchased from Millipore. The P-gp siRNA, the scrambled siRNA and FAM-labelled siRNA were supplied by GenePharma (Shanghai, China). \nPPG was prepared based on our previously reported methods27,28. Briefly, to strongly bind negatively charged siRNA via electrostatic interactions, we used the high molecular weight branched polyethylenimine (10000) instead of low molecular weight branched polyethylenimine (1800) to modify PG via using cross-linking reagents EDC and NHS. Firstly, 40 mg EDC and 40 mg NHS were mixed in 4 mL FA (0.5 mg/mL, DMSO) solution and magnetically stirred at room temperature for 15 min, after activation, 4 ml PPG (1.0 mg/mL) solution was added in the solution to react at room temperature for 24 h. Finally, excess FA was removed by dialyzing against double distilled water (DD) for 24 h (molecular weight cutoff: 10-kDa). PPG-FA was obtained in an amount equal to NGO-PEG (0.5 mg/mL). \nPreparation of PPG-FA/Dox. Dox was loaded onto PPG-FA via the following method. Briefly, 500 \u03bcL PPG-FA (0.5 mg/mL) and 500 \u03bcL Dox (1 mg/mL) were mixed in a 5 mL PBS solution and magnetically stirred at room temperature for 12 h. Then, excess Dox was removed by dialyzing the entire system against DD water until the filtrate was free of red colour. \nPreparation of PPG-FA/siRNA: The P-gp siRNA, scrambled siRNA and FAM-labelled siRNA were respectively dissolved in DEPC-treated water to achieve 0.1 mg/mL solution. The PPG-FA was blend with different siRNA solution at a weight ratio of 4:1 (NGO: siRNA), and incubated at room temperature for 30 min. It allows the electrostatic adsorption between negatively charged siRNA and positively charged PPG-FA. For preparation of PPG-FA/Dox/siRNA, the procedures were the same as that for PPG-FA/siRNA except using PPG-FA/Dox dispersed in DEPC-treated water.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "5000", | |
| "unit": null, | |
| "measured_entity": "linear chain PEG amine", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "10000", | |
| "unit": null, | |
| "measured_entity": "branched polyethylenimine", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "10000", | |
| "unit": null, | |
| "measured_entity": "BPEI", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "10-kDa", | |
| "unit": "kDa", | |
| "measured_entity": "dialysis bags", | |
| "measured_property": "molecular weight cutoff" | |
| }, | |
| { | |
| "quantity": "30-kDa", | |
| "unit": "kDa", | |
| "measured_entity": "ultrafiltration tubes", | |
| "measured_property": "molecular weight cutoff" | |
| }, | |
| { | |
| "quantity": "10000", | |
| "unit": null, | |
| "measured_entity": "branched polyethylenimine", | |
| "measured_property": "high molecular weight" | |
| }, | |
| { | |
| "quantity": "1800", | |
| "unit": null, | |
| "measured_entity": "branched polyethylenimine", | |
| "measured_property": "low molecular weight" | |
| }, | |
| { | |
| "quantity": "40 mg", | |
| "unit": "mg", | |
| "measured_entity": "EDC", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "40 mg", | |
| "unit": "mg", | |
| "measured_entity": "NHS", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "4 mL", | |
| "unit": "mL", | |
| "measured_entity": "FA (0.5 mg/mL, DMSO) solution", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "0.5 mg/mL", | |
| "unit": "mg/mL", | |
| "measured_entity": "solution", | |
| "measured_property": "FA" | |
| }, | |
| { | |
| "quantity": "15 min", | |
| "unit": "min", | |
| "measured_entity": "40 mg EDC and 40 mg NHS were mixed in 4 mL FA (0.5 mg/mL, DMSO) solution", | |
| "measured_property": "stirred" | |
| }, | |
| { | |
| "quantity": "4 ml", | |
| "unit": "ml", | |
| "measured_entity": "PPG (1.0 mg/mL) solution", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "1.0 mg/mL", | |
| "unit": "mg/mL", | |
| "measured_entity": "solution", | |
| "measured_property": "PPG" | |
| }, | |
| { | |
| "quantity": "24 h", | |
| "unit": "h", | |
| "measured_entity": "solution", | |
| "measured_property": "react" | |
| }, | |
| { | |
| "quantity": "24 h", | |
| "unit": "h", | |
| "measured_entity": "excess FA", | |
| "measured_property": "removed by dialyzing against double distilled water (DD)" | |
| }, | |
| { | |
| "quantity": "10-kDa", | |
| "unit": "kDa", | |
| "measured_entity": "dialyzing", | |
| "measured_property": "molecular weight cutoff" | |
| }, | |
| { | |
| "quantity": "0.5 mg/mL", | |
| "unit": "mg/mL", | |
| "measured_entity": "NGO-PEG", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "500 \u03bcL", | |
| "unit": "\u03bcL", | |
| "measured_entity": "PPG-FA", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "0.5 mg/mL", | |
| "unit": "mg/mL", | |
| "measured_entity": "PPG-FA", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "500 \u03bcL", | |
| "unit": "\u03bcL", | |
| "measured_entity": "Dox", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "5 mL", | |
| "unit": "mL", | |
| "measured_entity": "PBS solution", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "12 h", | |
| "unit": "h", | |
| "measured_entity": "500 \u03bcL PPG-FA (0.5 mg/mL) and 500 \u03bcL Dox (1 mg/mL) were mixed in a 5 mL PBS solution", | |
| "measured_property": "magnetically stirred" | |
| }, | |
| { | |
| "quantity": "1 mg/mL", | |
| "unit": "mg/mL", | |
| "measured_entity": "Dox", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "0.1 mg/mL", | |
| "unit": "mg/mL", | |
| "measured_entity": "solution", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "4:1", | |
| "unit": null, | |
| "measured_entity": "NGO: siRNA", | |
| "measured_property": "weight ratio" | |
| }, | |
| { | |
| "quantity": "30 min", | |
| "unit": "min", | |
| "measured_entity": "PPG-FA was blend with different siRNA solution at a weight ratio of 4:1 (NGO: siRNA)", | |
| "measured_property": "incubated" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101038srep43506", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1039/c3gc41362d\nInsights into the stability of gold nanoparticles supported on metal oxides for the base-free oxidation of glucose to gluconic acid\nAu was deposited on the metal oxides by the deposition-precipitation method.30 A solution of HAuCl4*3H2O (175 mg) in deionized water (80 mL) was brought to pH 10 by adding a NaOH solution (0.2 M). This solution was mixed with a suspension containing the metal oxide (2 g) in deionized water (25 mL). After stirring for 18 h, the suspension was filtered and washed with an excess amount of deionized water until no more chlorine could be detected by the AgCl test. The supported Au catalyst was dried overnight at 80 degC and then reduced for 4 h at 225 degC in 5% H2 in N2 (100 mL min-1). \nThe Au/AC catalyst was prepared according to the procedure reported by Biella et al.12 A solution of HAuCl4*3H2O (1 L, 100 \u03bcg mL-1) was mixed with 2.5 g of a 2 wt% solution of poly(vinyl alcohol) (PVA, MW ~ 10000). To this solution, 0.1 M NaBH4 solution (20 mL) was added dropwise, leading to the formation of metallic Au NPs. The PVA stabilized Au NPs were then immobilized on activated carbon (Darco(r), 100 mesh) by adding 2 g of the support. The as-synthesized Au/AC catalyst was filtered after 2 h and washed with deionized water. Nanosized ceria and zirconia, hereafter referred to as nCeO2 and nZrO2, were synthesized according to a previously reported method.30 Briefly, an aqueous solution of Ce(NO3)3*6H2O or ZrO(NO3)2*xH2O (0.8 M, 375 mL) was added to a solution of NH4OH in deionized water (0.8 M, 1.1 L). After stirring for 30 min, the solution was aged at 100 degC for 24 h in a polyethylene vessel. The mixture was cooled down, filtered and washed with an excess amount of deionized water. The resulting particles were dried under vacuum and calcined under an air flow of 100 mL min-1 at 400 degC for 4 h. The other support materials were purchased from Sigma Aldrich and used as received (see ESI+).", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "175 mg", | |
| "unit": "mg", | |
| "measured_entity": "solution", | |
| "measured_property": "HAuCl4*3H2O" | |
| }, | |
| { | |
| "quantity": "80 mL", | |
| "unit": "mL", | |
| "measured_entity": "solution", | |
| "measured_property": "deionized water" | |
| }, | |
| { | |
| "quantity": "10", | |
| "unit": null, | |
| "measured_entity": "solution", | |
| "measured_property": "pH" | |
| }, | |
| { | |
| "quantity": "0.2 M", | |
| "unit": "M", | |
| "measured_entity": "NaOH solution", | |
| "measured_property": "adding" | |
| }, | |
| { | |
| "quantity": "2 g", | |
| "unit": "g", | |
| "measured_entity": "metal oxide", | |
| "measured_property": "suspension" | |
| }, | |
| { | |
| "quantity": "25 mL", | |
| "unit": "mL", | |
| "measured_entity": "water", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "18 h", | |
| "unit": "h", | |
| "measured_entity": "stirring", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "80 degC", | |
| "unit": "degC", | |
| "measured_entity": "Au catalyst", | |
| "measured_property": "dried" | |
| }, | |
| { | |
| "quantity": "4 h", | |
| "unit": "h", | |
| "measured_entity": "Au catalyst", | |
| "measured_property": "reduced" | |
| }, | |
| { | |
| "quantity": "225 degC", | |
| "unit": "degC", | |
| "measured_entity": "Au catalyst", | |
| "measured_property": "reduced" | |
| }, | |
| { | |
| "quantity": "5%", | |
| "unit": "%", | |
| "measured_entity": "N2", | |
| "measured_property": "H2" | |
| }, | |
| { | |
| "quantity": "100 mL min-1", | |
| "unit": "mL min-1", | |
| "measured_entity": "5% H2 in N2", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "1 L", | |
| "unit": "L", | |
| "measured_entity": "solution", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "100 \u03bcg mL-1", | |
| "unit": "\u03bcg mL-1", | |
| "measured_entity": "solution", | |
| "measured_property": "HAuCl4*3H2O" | |
| }, | |
| { | |
| "quantity": "2.5 g", | |
| "unit": "g", | |
| "measured_entity": "2 wt% solution of poly(vinyl alcohol) (PVA", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "2 wt%", | |
| "unit": "wt%", | |
| "measured_entity": "solution", | |
| "measured_property": "poly(vinyl alcohol) (PVA" | |
| }, | |
| { | |
| "quantity": "MW ~ 10000", | |
| "unit": "MW", | |
| "measured_entity": "poly(vinyl alcohol) (PVA", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "0.1 M", | |
| "unit": "M", | |
| "measured_entity": "NaBH4", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "20 mL", | |
| "unit": "mL", | |
| "measured_entity": "NaBH4", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "100 mesh", | |
| "unit": "mesh", | |
| "measured_entity": "activated carbon (Darco(r)", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "2 g", | |
| "unit": "g", | |
| "measured_entity": "support", | |
| "measured_property": "adding" | |
| }, | |
| { | |
| "quantity": "2 h", | |
| "unit": "h", | |
| "measured_entity": "Au/AC catalyst", | |
| "measured_property": "filtered" | |
| }, | |
| { | |
| "quantity": "0.8 M", | |
| "unit": "M", | |
| "measured_entity": "aqueous solution of Ce(NO3)3*6H2O or ZrO(NO3)2*xH2O", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "375 mL", | |
| "unit": "mL", | |
| "measured_entity": "aqueous solution of Ce(NO3)3*6H2O or ZrO(NO3)2*xH2O", | |
| "measured_property": "added" | |
| }, | |
| { | |
| "quantity": "0.8 M", | |
| "unit": "M", | |
| "measured_entity": "solution of NH4OH in deionized water", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "1.1 L", | |
| "unit": "L", | |
| "measured_entity": "solution of NH4OH in deionized water", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "30 min", | |
| "unit": "min", | |
| "measured_entity": "solution", | |
| "measured_property": "stirring" | |
| }, | |
| { | |
| "quantity": "100 degC", | |
| "unit": "degC", | |
| "measured_entity": "solution", | |
| "measured_property": "aged" | |
| }, | |
| { | |
| "quantity": "24 h", | |
| "unit": "h", | |
| "measured_entity": "solution", | |
| "measured_property": "aged" | |
| }, | |
| { | |
| "quantity": "100 mL min-1", | |
| "unit": "mL min-1", | |
| "measured_entity": "calcined", | |
| "measured_property": "air flow" | |
| }, | |
| { | |
| "quantity": "400 degC", | |
| "unit": "degC", | |
| "measured_entity": "air flow", | |
| "measured_property": "calcined" | |
| }, | |
| { | |
| "quantity": "4 h", | |
| "unit": "h", | |
| "measured_entity": "resulting particles", | |
| "measured_property": "calcined" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101039c3gc41362d", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "10.1039/c5ta01668a\nHysteresis-free and highly stable perovskite solar cells produced via a chlorine-mediated interdiffusion method\nAll chemicals were purchased from commercial suppliers and used as received unless stated otherwise. PbI2 (Sigma Aldrich, 99%) and methyl ammonium iodide (MAI) (Wako Chem., 98%) were dissolved in anhydrous N,N-dimethylformamide (Wako chem., 99.5%) (50 mg ml-1), respectively. For chlorine doping, 5-20 wt% MACl (Wako chem.) was mixed with the MAI solution. PC61BM (Solenne or Lumitec, 99%) solution (2 wt%) dissolved in anhydrous chlorobenzene (Wako chem., 99%) was used for coating of the electron selective layer. All the solutions were filtered using 0.45 \u03bcm syringe filters to avoid the risk of particle formation. UV-curable resins (NagaseChemtex XNR5516Z) were used to seal devices with cavity glasses. The X-ray diffraction patterns of MAPbI3 and MAPbI3-xClx were collected using Bruker D8 advanced X-ray diffractometer (CuK\u03b1 radiation, \u03bb = 1.54050 \u00c5). The top surface and cross-sectional images were taken by a high resolution scanning electron microscope at 5 kV accelerating voltage (Hitachi-4800). Additionally, elemental mapping was done using energy dispersive X-ray measurement mode at accelerating voltage of 10 kV. S9+) and incident monochromatic photon to current conversion efficiency (IPCE) spectra or External quantum efficiency (EQE) were measured with a CEP-200BX spectrometer (Bunkokeiki, Tokyo, Japan) at room temperature. Histogram of over 240 devices were generated from the devices using 0.18 cm2 aperture mask.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "99%", | |
| "unit": "%", | |
| "measured_entity": "PbI2", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "98%", | |
| "unit": "%", | |
| "measured_entity": "methyl ammonium iodide (MAI)", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "99.5%", | |
| "unit": "%", | |
| "measured_entity": "anhydrous N,N-dimethylformamide", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "50 mg ml-1", | |
| "unit": "mg ml-1", | |
| "measured_entity": null, | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "5-20 wt%", | |
| "unit": "wt%", | |
| "measured_entity": "MACl", | |
| "measured_property": "mixed" | |
| }, | |
| { | |
| "quantity": "99%", | |
| "unit": "%", | |
| "measured_entity": "PC61BM", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "2 wt%", | |
| "unit": "wt%", | |
| "measured_entity": "solution", | |
| "measured_property": "PC61BM" | |
| }, | |
| { | |
| "quantity": "99%", | |
| "unit": "%", | |
| "measured_entity": "anhydrous chlorobenzene", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "0.45 \u03bcm", | |
| "unit": "\u03bcm", | |
| "measured_entity": "syringe filters", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "1.54050 \u00c5", | |
| "unit": "\u00c5", | |
| "measured_entity": "Bruker D8 advanced X-ray diffractometer (CuK\u03b1 radiation", | |
| "measured_property": "\u03bb" | |
| }, | |
| { | |
| "quantity": "5 kV", | |
| "unit": "kV", | |
| "measured_entity": "high resolution scanning electron microscope", | |
| "measured_property": "accelerating voltage" | |
| }, | |
| { | |
| "quantity": "10 kV", | |
| "unit": "kV", | |
| "measured_entity": "X-ray measurement", | |
| "measured_property": "accelerating voltage" | |
| }, | |
| { | |
| "quantity": "0.18 cm2", | |
| "unit": "cm2", | |
| "measured_entity": "aperture mask", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "over 240", | |
| "unit": null, | |
| "measured_entity": "Histogram", | |
| "measured_property": "devices" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101039c5ta01668a", | |
| "dataset": "msp" | |
| }, | |
| { | |
| "instruction": "\n You are an expert at extracting quantity, units and their related context from text. \n Given a paragraph below identify each quantity and its related unit and related context, i.e. the measured entity and measured property if they exist.\n ", | |
| "paragraph": "The elements, Ba (rod, 99+%), Se (shots, 99.999%) and Cr (powder -325 Mesh, 99%) all from Alfa Aesar, were used as received. The synthesis of the solid-solution samples was performed following ref. 20. BaSe was prepared by mechanical alloying using appropriate amounts of the elements (10 g total) loaded in 20 ml tungsten carbide jars and using 7 balls of the same material. The mechanical alloying synthesis was achieved using a Fritsch Pulverisette 7 PL, with a program of 15 cycles of 2 minutes at a speed of 700 rpm. BaxCr5Se8 was then prepared from an appropriate amount of BaSe and elemental Cr and Se. In order to obtain 5 g of the title phase, precursors were ground, mixed and placed in an alumina boat in a sealed silica tube, and heated to 873 K in 10 hours, the temperature at which it remained for two days. The mixture was then slowly cooled to room temperature within 10 hours and a homogeneous dark grey powder was obtained. The powder was compacted using spark plasma sintering (FCT HP D 25/1) in order to produce dense samples for physical property measurements. About 5 g of the sample were inserted into high density graphite dies (Carbonloraine) with an inner diameter of 15 mm. The temperature was raised in 45 minutes to 973 K, this temperature plateau lasted 40 minutes before a 45 minutes ramp down to room temperature. The pressure was raised from 28 MPa to 50 MPa during the heating step, kept constant over the temperature plateau and released during the cooling step.", | |
| "measurement_extractions": [ | |
| { | |
| "quantity": "99+%", | |
| "unit": "%", | |
| "measured_entity": "Ba", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "99.999%", | |
| "unit": "%", | |
| "measured_entity": "Se", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "99%", | |
| "unit": "%", | |
| "measured_entity": "Cr", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "-325 Mesh", | |
| "unit": "Mesh", | |
| "measured_entity": null, | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "10 g", | |
| "unit": "g", | |
| "measured_entity": "elements", | |
| "measured_property": "loaded" | |
| }, | |
| { | |
| "quantity": "20 ml", | |
| "unit": "ml", | |
| "measured_entity": "tungsten carbide jars", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "7 balls", | |
| "unit": "balls", | |
| "measured_entity": "same material", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "15 cycles", | |
| "unit": "cycles", | |
| "measured_entity": "mechanical alloying synthesis", | |
| "measured_property": "program" | |
| }, | |
| { | |
| "quantity": "2 minutes", | |
| "unit": "minutes", | |
| "measured_entity": "mechanical alloying synthesis", | |
| "measured_property": "program" | |
| }, | |
| { | |
| "quantity": "700 rpm", | |
| "unit": "rpm", | |
| "measured_entity": "mechanical alloying synthesis", | |
| "measured_property": "speed" | |
| }, | |
| { | |
| "quantity": "5 g", | |
| "unit": "g", | |
| "measured_entity": "title phase", | |
| "measured_property": null | |
| }, | |
| { | |
| "quantity": "873 K", | |
| "unit": "K", | |
| "measured_entity": "precursors", | |
| "measured_property": "heated" | |
| }, | |
| { | |
| "quantity": "10 hours", | |
| "unit": "hours", | |
| "measured_entity": "precursors", | |
| "measured_property": "heated" | |
| }, | |
| { | |
| "quantity": "10 hours", | |
| "unit": "hours", | |
| "measured_entity": "mixture", | |
| "measured_property": "slowly cooled" | |
| }, | |
| { | |
| "quantity": "5 g", | |
| "unit": "g", | |
| "measured_entity": "sample", | |
| "measured_property": "inserted" | |
| }, | |
| { | |
| "quantity": "15 mm", | |
| "unit": "mm", | |
| "measured_entity": "high density graphite dies", | |
| "measured_property": "inner diameter" | |
| }, | |
| { | |
| "quantity": "45 minutes", | |
| "unit": "minutes", | |
| "measured_entity": "temperature", | |
| "measured_property": "raised" | |
| }, | |
| { | |
| "quantity": "973 K", | |
| "unit": "K", | |
| "measured_entity": "temperature", | |
| "measured_property": "raised" | |
| }, | |
| { | |
| "quantity": "40 minutes", | |
| "unit": "minutes", | |
| "measured_entity": "temperature", | |
| "measured_property": "plateau" | |
| }, | |
| { | |
| "quantity": "45 minutes", | |
| "unit": "minutes", | |
| "measured_entity": "temperature", | |
| "measured_property": "ramp down" | |
| }, | |
| { | |
| "quantity": "from 28 MPa to 50 MPa", | |
| "unit": "MPa", | |
| "measured_entity": "pressure", | |
| "measured_property": "raised" | |
| } | |
| ], | |
| "split": "test", | |
| "docId": "101039c6dt02166b", | |
| "dataset": "msp" | |
| } | |
| ] |