The Landau–Zener formula is an analytic solution to the equations of motion governing the transition dynamics of a two-state quantum system, with a time-dependent Hamiltonian varying such that the energy separation of the two states is a linear function of time. The formula, giving the probability of a diabatic (not adiabatic) transition between the two energy states, was published separately by Lev Landau, Clarence Zener, Ernst Stueckelberg, and Ettore Majorana, in 1932.
 If the system starts, in the infinite past, in the lower energy eigenstate, we wish to calculate the probability of finding the system in the upper energy eigenstate in the infinite future (a so-called Landau–Zener transition). For infinitely slow variation of the energy difference (that is, a Landau–Zener velocity of zero), the adiabatic theorem tells us that no such transition will take place, as the system will always be in an instantaneous eigenstate of the Hamiltonian at that moment in time. At non-zero velocities, transitions occur with probability as described by the Landau–Zener formula.
 Such transitions occur between states of the entire system, hence any description of the system must include all external influences, including collisions and external electric and magnetic fields. In order that the equations of motion for the system might be solved analytically, a set of simplifications are made, known collectively as the Landau–Zener approximation. The simplifications are as follows:
 The first simplification makes this a semi-classical treatment. In the case of an atom in a magnetic field, the field strength becomes a classical variable which can be precisely measured during the transition. This requirement is quite restrictive as a linear change will not, in general, be the optimal profile to achieve the desired transition probability.
 The second simplification allows us to make the substitution
 where 
  
    
      
        
          E
          
            1
          
        
        (
        t
        )
      
    
    {\displaystyle E_{1}(t)}
  
 and 
  
    
      
        
          E
          
            2
          
        
        (
        t
        )
      
    
    {\displaystyle E_{2}(t)}
  
 are the energies of the two states at time t, given by the diagonal elements of the Hamiltonian matrix, and 
  
    
      
        α
      
    
    {\displaystyle \alpha }
  
 is a constant. For the case of an atom in a magnetic field this corresponds to a linear change in magnetic field. For a linear Zeeman shift this follows directly from point 1.
 The final simplification requires that the time–dependent perturbation does not couple the diabatic states; rather, the coupling must be due to a static deviation from a 
  
    
      
        1
        
          /
        
        r
      
    
    {\displaystyle 1/r}
  
 Coulomb potential, commonly described by a quantum defect.
 The details of Zener's solution are somewhat opaque, relying on a set of substitutions to put the equation of motion into the form of the Weber equation and using the known solution. A more transparent solution is provided by Curt Wittig using contour integration.
 The key figure of merit in this approach is the Landau–Zener velocity:
 where q is the perturbation variable (electric or magnetic field, molecular bond-length, or any other perturbation to the system), and 
  
    
      
        
          E
          
            1
          
        
      
    
    {\displaystyle E_{1}}
  
 and 
  
    
      
        
          E
          
            2
          
        
      
    
    {\displaystyle E_{2}}
  
 are the energies of the two diabatic (crossing) states. A large 
  
    
      
        
          v
          
            
              L
              Z
            
          
        
      
    
    {\displaystyle v_{\rm {LZ}}}
  
 results in a large diabatic transition probability and vice versa.
 Using the Landau–Zener formula the probability, 
  
    
      
        
          P
          
            
              D
            
          
        
      
    
    {\displaystyle P_{\rm {D}}}
  
, of a diabatic transition is given by
 The quantity 
  
    
      
        a
      
    
    {\displaystyle a}
  
 is the off-diagonal element of the two-level system's Hamiltonian coupling the bases, and as such it is half the distance between the two unperturbed eigenenergies at the avoided crossing, when 
  
    
      
        
          E
          
            1
          
        
        =
        
          E
          
            2
          
        
      
    
    {\displaystyle E_{1}=E_{2}}
  
.
 The simplest generalization of the two-state Landau–Zener model is a multistate system with a Hamiltonian of the form
 where A and B are Hermitian NxN matrices with time-independent elements. The goal of the multistate Landau–Zener theory is to determine elements of the scattering matrix and the transition probabilities between states of this model after evolution with such a Hamiltonian from negative infinite to positive infinite time. The transition probabilities are the absolute value squared of scattering matrix elements.
 There are exact formulas, called hierarchy constraints, that provide analytical expressions for special elements of the scattering matrix in any multi-state Landau–Zener model. Special cases of these relations are known as the Brundobler–Elser (BE) formula ,, ), and the no-go theorem,. Discrete symmetries often lead to constraints that reduce the number of independent elements of the scattering matrix.
 There are also integrability conditions that, when they are satisfied, lead to exact expressions for the entire scattering matrices in multistate Landau–Zener models. Numerous such completely solvable models have been identified, including:
 Applications of the Landau–Zener solution to the problems of quantum state preparation and manipulation with discrete degrees of freedom stimulated the study of noise and decoherence effects on the transition probability in a driven two-state system. Several compact analytical results have been derived to describe these effects, including the Kayanuma formula
 
for a strong diagonal noise, and Pokrovsky–Sinitsyn formula
 
for the coupling to a fast colored noise with off-diagonal components.
 Using the Schwinger–Keldysh Green's function, a rather complete and comprehensive study on the effect of quantum noise in all parameter regimes were performed by Ao and Rammer in late 1980s, from weak to strong coupling, low to high temperature, slow to fast passage, etc. Concise analytical expressions were obtained in various limits, showing the rich behaviors of such problem. 
 
The effects of nuclear spin bath and heat bath coupling on the Landau–Zener process were explored by Sinitsyn and Prokof'ev and Pokrovsky and Sun, respectively.
 Exact results in multistate Landau–Zener theory (no-go theorem and BE-formula) can be applied to Landau–Zener systems which are coupled to baths composed of infinite many oscillators and/or spin baths (dissipative Landau–Zener transitions). They provide exact expressions for transition probabilities averaged over final bath states if the evolution begins from the ground state at zero temperature, see in Ref. for oscillator baths and for universal results including spin baths in Ref.