Complex sentence: The morning news broadcasts are branded as "My 24 News at 5AM" and "My 24 News at 7AM", while the 10 PM newscast is branded as "My 24 News at 10PM".
Split into simpler sentences: The morning news will be branded as "My 24 News at 5AM" and "My 24 News at 7AM". The 10 PM newscast will be branded as "My 24 News at 10PM".