Complex sentence: Williams is perhaps best-known for this talking blues style; his biggest hit, the novelty song "Smoke, Smoke, Smoke (That Cigarette)", is heard during the opening scenes of the hit movie "Thank You For Smoking".
Split into simpler sentences: Williams is perhaps best-known for this talking blues style; his biggest hit, the novelty song Smoke! Smoke! (That Cigarette) is heard during the opening scenes of the hit movie "Thank You For Smoking".