Complex sentence: He used to present the 10pm-2am Friday and Saturday evening show, and Sunday Night 6-10pm, but took over Virgin's early breakfast show Monday-Friday 4-6am, from Monday 7th January.
Split into simpler sentences: He used to present the 10pm-2am Friday and Saturday evening show, and Sunday Night 6-10pm. He took over Virgin's early breakfast show Monday-Friday 4-6am, from Monday 7th January.