Complex sentence: This was not the only occasion where a cover of the song appeared on a film's soundtrack as in 2002, a recording by Bono and composed by Elliot Goldenthal appeared on the soundtrack to "The Good Thief".
Split into simpler sentences: This was not the only occasion when a cover of the song appeared on a film's soundtrack. In 2002, a recording by Bono and composed by Elliot Goldenthal appeared on the soundtrack for "The Good Thief".