Complex sentence: Upon its first week in release, Dalma's 2013 album, "Cadore 33", topped the chart in Spain, thus becoming Dalma's fifth consecutive album to reach No.1 on the national chart, excluding compilations.
Split into simpler sentences: Upon its first week in release, Dalma's 2013 album, "Cadore 33", topped the chart in Spain. It thus became Dalma's fifth consecutive album to reach No.1 on the national chart, excluding compilations.