{{위키데이터 속성 추적}}
{{chembox
| Watchedfields = changed
| verifiedrevid = 443382196
| Name = 불화 알루미늄
| ImageFile = Aluminium-trifluoride-3D-polyhedra.png
| ImageFile2 =
| ImageCaption = Anhydrous AlF<sub>3</sub>
| OtherNames = Aluminium(III) fluoride<br />Aluminum trifluoride
|Section1={{Chembox Identifiers
| InChI = 1/Al.3FH/h;3*1H/q+3;;;/p-3
| ChEBI_Ref = {{ebicite|correct|EBI}}
| ChEBI = 49464
| StdInChI_Ref = {{stdinchicite|correct|chemspider}}
| StdInChI = 1S/Al.3FH/h;3*1H/q+3;;;/p-3
| StdInChIKey_Ref = {{stdinchicite|correct|chemspider}}
| StdInChIKey = KLZUFWVZNOTSEM-UHFFFAOYSA-K
| SMILES = F[Al](F)F
| SMILES_Comment = [[monomer]]
| SMILES1 = F[Al](F[Al]0(F)(F)(F)F)(F[Al]1(F)(F)(F)F)(F[Al]2(F)(F)(F)F)(F[Al]3(F)(F)(F)F)F[Al](F[Al](F[Al]4(F)(F)(F)F)(F[Al]5(F)(F)(F)F)(F[Al]6(F)(F)(F)F)(F0)F)(F[Al](F[Al]7(F)(F)(F)F)(F[Al]8(F)(F)(F)F)(F1)(F4)F)(F[Al](F[Al]9(F)(F)(F)F)(F[Al]0(F)(F)(F)F)(F5)(F7)F)(F[Al](F[Al]1(F)(F)(F)F)(F2)(F8)(F9)F)F[Al](F3)(F6)(F0)(F1)F
| SMILES1_Comment = crystal form
| InChIKey = KLZUFWVZNOTSEM-DFZHHIFOAC
| CASNo = 7784-18-1
| CASNo_Ref = {{cascite|correct|CAS}}
| CASNo1_Ref = {{cascite|correct|??}}
| CASNo1 = 32287-65-3
| CASNo1_Comment = (monohydrate)
| CASNo2_Ref = {{cascite|correct|??}}
| CASNo2 = 15098-87-0
| CASNo2_Comment = (trihydrate)
| UNII_Ref = {{fdacite|correct|FDA}}
| UNII = Z77H3IKW94
| PubChem = 2124
| ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}}
| ChemSpiderID =2039
| RTECS = BD0725000
  }}
|Section2={{Chembox Properties
| Formula = AlF<sub>3</sub>
| MolarMass = 83.977 g/mol (anhydrous) <br/> 101.992 g/mol (monohydrate) <br/> 138.023 (trihydrate)<ref name=b92>{{RubberBible92nd|page=4.45}}</ref>
| Appearance = white, crystalline solid<br />odorless
| Density = 3.10 g/cm<sup>3</sup> (anhydrous) <br/> 2.17 g/cm<sup>3</sup> (monohydrate) <br/> 1.914 g/cm<sup>3</sup> (trihydrate)<ref name=b92/>
| Solubility = 5.6 g/L (0&nbsp;°C) <br/> 6.7 g/L (20&nbsp;°C) <br/> 17.2 g/L (100&nbsp;°C)
| MeltingPtC = 1290
| MeltingPt_notes = (anhydrous) (sublimes)
| MeltingPt_ref =<ref name="g233">{{Greenwood&Earnshaw2nd|page=233}}</ref>
| RefractIndex = 1.3767 (visible range)<ref>{{서적 인용|url=https://books.google.com/books?id=kTnxSi2B2FcC|title=CRC Handbook of Chemistry and Physics|edition=84th|last=Lide|first=David R.|date=2003-06-19|publisher=CRC Press|isbn=9780849304842|series=[[CRC Handbook]]
}}</ref>
| MagSus = {{val|-13.4e-6|u=cm<sup>3</sup>/mol}}<ref>{{RubberBible92nd|page=4.131}}</ref>
  }}
|Section3={{Chembox Structure
| CrystalStruct = [[Rhombohedral lattice system|Rhombohedral]], [[Pearson symbol|hR24]]
| SpaceGroup = R{{overline|3}}c, No. 167<ref>{{저널 인용|doi=10.1016/S0022-1139(00)81321-4|title=Zur kenntnis von AlF<sub>3</sub> und InF<sub>3</sub> [1]|journal=Journal of Fluorine Chemistry|volume=24|issue=3|pages=327|year=1984|last1=Hoppe|first1=R.|last2=Kissel|first2=D.}}</ref>
| LattConst_a =  0.49254 nm
| LattConst_c =  1.24477 nm
| UnitCellFormulas = 6
| UnitCellVolume =0.261519
 }}
|Section5={{Chembox Thermochemistry
| DeltaHf = −1510.4 kJ/mol<ref name=b92t>{{RubberBible92nd|page=5.5}}</ref>
| Entropy = 66.5 J/mol·K<ref name=b92t/>
| DeltaGf = −1431.1 kJ/mol<ref name=b92t/>
| HeatCapacity = 75.1 J/mol·K<ref name=b92t/>
}}
|Section7={{Chembox Hazards
| Hazards_ref =<ref>{{서적 인용|url=https://books.google.com/books?id=3Tbl2W8j-3oC&q=nfpa+704+aluminum+fluoride|title=HazMat Data: For First Response, Transportation, Storage, and Security|last=Pohanish|first=Richard P.|date=2005-03-04|publisher=John Wiley & Sons|isbn=9780471726104|language=en}}</ref><ref>{{웹 인용|url=https://pubchem.ncbi.nlm.nih.gov/compound/aluminum_fluoride|title=Aluminum Fluoride|website=PubChem|publisher=National Institute of Health|access-date=October 12, 2017}}</ref><ref name=PGCH>{{PGCH|0024}}</ref>
| NFPA-H = 3
| NFPA-F = 0
| NFPA-R = 0
| ExternalSDS = [http://www.inchem.org/documents/icsc/icsc/eics1324.htm InChem MSDS]
| GHSPictograms = {{GHS05|Corrosive}} {{GHS06|Acute toxicity}} {{GHS07|Irritant}} {{GHS08|Reproductive toxicity, target organ toxicity, aspiration hazard}}
| GHSSignalWord = DANGER
| HPhrases = {{H-phrases|301|302|314|315|319|335|361|372}}
| PPhrases = {{P-phrases|260|261|264|270|271|280|301+310|301+312|301+330+331|302+352|303+361+353|304+340|305+351+338|310|312|321|330|332+313|337+313|362|363|403+233|405|501}}
| IDLH = N.D.
| PEL = none
| REL = 2 mg/m<sup>3</sup>
  }}
}}
'''불화 알루미늄'''(Aluminium fluoride)은 [[화학식]] AlF<sub>3</sub>을 갖는 [[무기 화합물]]들이다. 이것들은 모두 무색의 고체이다. 무수화물 AlF<sub>3</sub>는 알루미늄 금속 생산에 사용된다. 여러 가지가 무기물로서 발생한다.

== 생성 ==
:H<sub>2</sub>SiF<sub>6</sub> + Al<sub>2</sub>O<sub>3</sub> + 3 H<sub>2</sub>O → 2 AlF<sub>3</sub> + SiO<sub>2</sub> + 4 H<sub>2</sub>O

== 안전 ==
장기간 흡입, 노출하면 [[천식]]을 유발할 수 있으며 뼈와 신경계에 영향을 주어 뼈의 변화를 주고 신경계의 손상을 줄 수 있다.<ref name=":0">{{웹 인용|url=https://www.cdc.gov/niosh/ipcsneng/neng1324.html|title=ALUMINIUM FLUORIDE (ANHYDROUS) International Chemical Safety Cards (ICSC)|date=July 22, 2015|website=CDC.gov National Institute for Occupational Safety and Health (NIOSH)|access-date=July 17, 2017}}</ref>

== 각주 ==
{{각주}}

== 외부 링크 ==
* [https://web.archive.org/web/20110722155414/http://www.solvaychemicals.us/static/wma/pdf/5/1/1/9/ALF.pdf MSDS]
* [https://toxnet.nlm.nih.gov/cgi-bin/sis/search/a?dbs+hsdb:@term+@DOCNO+600 ToxNet Profile]
* [https://pubchem.ncbi.nlm.nih.gov/compound/aluminum_fluoride PubChem]
{{전거 통제}}

[[분류:알루미늄 화합물]]
[[분류:플루오린화물]]
[[분류:금속 할로젠화물]]