Patent GB-907971-A (GB)
Title: Improvements in or relating to the manufacture of foamed polyurethane materials
Inventor: WILD JAMES HARRY
IPC: C08J9/00
Filed: 1960-05-20
Abstract: Foamed polyurethanes are prepared by the reaction of hydroxyl group-containing polyethers containing at least two hydroxyl groups per molecule with organic polyisocyanates in the presence of a polydialkylsiloxane having a viscosity of 2-9 centistokes at 25 DEG C.  Suitable polydialkylsiloxanes are those in which the alkyl group is methyl, ethyl, propyl or butyl.  Numerous polyisocyanates and reactants for preparing the polyethers are specified.  Foam formation may be carried out using water or the gas-forming agent may be a volatile liquid such as monofluoro-trichloromethane, dibromodifluoromethane and 1:1:2-trichloro-1:2:2-trifluoroethane.  A polyether-polyisocyanate prepolymer may first be formed or the polyether, polyisocyanate and gas forming material interacted simultaneously.  Additional reaction mixture ingredients specified include catalysts tertiary amines, e.g. N,N-dimethylbenzylamine, or a non-basic heavy metal compound such as manganese acetylacetonate for the pre-polymer formation and a tertiary amine, e.g. dimethylcyclohexylamine, 4-dimethylaminopyridine and N,N-dimethylbenzylamine, an alkali metal hydroxide, a carbonate or acetate or a non-basic heavy metal compound such as dibutyl tin dilaurate, manganese acetylacetonate or stannous octoate for the foaming reaction surfactants oxyethylated phenols such as an octylphenol/ethylene oxide reaction product, oxyethylated fatty alcohols such as oleyl alcohol, fatty acid salts such as diethylamine oleate, sulphuric acid derivatives of long chain compounds such as sulphated methyl oleate and polyalkylene oxide and polysiloxane-polyalkylene oxide block copolymers flame retardants such as b -trichloroethyl phosphate and antimony oxide plasticizers such as tricresyl phosphate and dioctyl phthalate antioxidants such as alkyl phenols colouring matter and fillers, e.g. carbon black, mica and silica auxiliary gas-forming agents, e.g. lithium aluminium hydride crosslinking agents such as trihydric alcohols.  In the examples, polyurethane foams are prepared from (1) a polypropylene glycol and a mixture of 2,4- and 2,6-tolylene diisocyanates (2) the same diisocyanate mixture, a polypropylene glycol and a polypropylene triol obtained by oxypropylating hexanetriol and (3) the same diisocyanate mixture and a condensation product of glycerol and propylene oxide.ALSO:Foamed polyurethanes are prepared by the reaction of hydroxyl group containing polyethers containing at least two hydroxyl groups per molecule with organic polyisocyanates in the presence of a polydialkylsiloxane having a viscosity of 2-9 centistokes at 25 DEG C.  Suitable polydialkylsiloxanes are those in which the alkyl group is methyl, ethyl, propyl or butyl.  Numerous polyisocyanates and reactants for preparing the polyethers are specified.  Foam formation may be carried out in the presence of water or the gas forming agent may be a volatile liquid such as monofluoro-trichloromethane, di bromo di fluoromethane and 1 : 1 : 2- trichloro- 1 : 2 : 2- trifluoroethane.  A polyether-polyisocyanate prepolymer may first be formed on the polyether, polyisocyanate and gas-forming material interacted simultaneously.  Additional reaction mixture ingredients specified include catalysts tertiary amines, e.g. N, N -dimethylbenzylamine, or a non-basic heavy metal compound, such as manganese acetylacetonate, for the pre-polymer formation and a tertiary amine, e.g. dimethylcyclohexylamine, 4-dimethylaminopyridine and N, N -dimethylbenzylamine, an alkali metal hydroxide, a carbonate or acetate or a non-basic heavy metal compound such as dibutyl tin dilaurate, manganese acetylacetonate or stannous octoate for the foaming reaction surfactants oxyethylated phenols such as an octylphenol/ethylene oxide reaction product, oxyethylated fatty alcohols such as oleyl alcohol, fatty acid salts such as diethylamine oleate, sulphuric acid derivatives of long chain compounds such as sulphated methyl oleate and polyalkylene oxide and polysiloxane-polyalkylene oxide block copolymers flame retardants such as b -trichlorethyl phosphate and antimony oxide plasticizers such as tricresyl phosphate and dioctyl phthalate antioxidants such as alkylphenols colouring matter and fillers such as carbon black, mica and silica auxiliary gas forming agents such as lithium aluminium hydride cross-linking agents such as trihydric alcohols. In the examples, polyurethane foams are prepared from (1) a polypropylene glycol and a mixture of 2 : 4-and 2 : 6- tolylene diisocyanates (2) the same diisocyanate mixture, a polypropylene glycol and a polypropylene triol obtained by oxypropylating hexanetriol and (3) the same diisocyanate mixture and a condensation product of glycerol and propylene oxide.