Patent GB-808129-A (GB)
Title: Purification of precipitated silica
IPC: B01J47/10
Filed: 1955-12-09
Abstract: Ions are removed from finely divided hydrated silica in the form of filterable flocs by mixing the silica with an ion exchange resin of larger particle size than the silica in aqueous suspension, passing the mixture on to the centre portion of a sieve of such a mesh size that the silica particles pass through while the resin particles are retained thereon, and continuously moving the resin particles towards the edge of the sieve so as to prevent build-up of resin at the centre portion of the sieve and consequent retention of the silica by the resin.  A batch or continuous <PICT:0808129/III/1> process may be employed.  It is desirable that build-up should not exceed 2 inches, and is preferably less than 0.5 inch in depth. For best results it should not be more than 2 resin particles in depth.  The silica flocs may be less than, and the resin particles greater than, 10 microns in size.  An 80-mesh sieve may be employed.  Movement of the resin particles may be effected by a sieve-shaker which imparts a combined high-speed gyratory and oscillatory motion to each point on the sieve, the oscillatory component of the motion increasing from zero at the centre of the sieve to a maximum at the outer edge of the sieve.  Means are desirably provided for periodically bumping the sieve.  As shown the shaking motion is effected by the rotation about its longitudinal axis of a shaft 20 provided with eccentrically-mounted weights 21 and 22, and is transmitted from a resiliently mounted table 4, which supports the motor operating the shaft 20 by rigid members 23.  The aqueous suspension to be treated is passed through opening 2 on to the central portion of sieve 8.  An aqueous suspension of silica free from resin passes via pan 10 to outlet 15 while the resin passes to conduit 18, and thence via pan 11 and opening 1 to a further sieve 9 where residual silica is removed from the resin.  The resin finally passes to outlet 16 while the residual silica passes via pan 12 to outlet 17.  An amount of water, e.g. 1 litre of water per litre of resin, may be mixed with the resin descending through conduit 18. In a simplified form (not shown) applicable to batch operation a single sieve is employed and the sieve container is adapted to rock about an axis through the centre of the table so as to effect occasional bumping of the bottom of the container.  The silica may be precipitated from an aqueous solution of alkali metal or alkaline earth metal silicate with acid, e.g. carbon dioxide, sulphur dioxide, or hydrogen sulphide.  Enough acid should be added to an alkali metal silicate to reduce the content of alkali metal oxide combined as silicate below 3 per cent.  The precipitated silica may be stabilized by a heat treatment as disclosed in Specification 745,890.  Cation exchange resins specified are sulphonated polystyrene, styrene-vinyl benzene copolymer, vinyl-formaldehyde, lignin and peat.  Anion exchange resins specified are amino resins derived from styrene and its copolymers.  The silica is preferably washed with water before treatment with the resin.  In the removal of cations the pH of the silica suspension should be reduced to below 5, preferably 2-4, by the addition of the ion exchange resin, optionally with the supplementary addition of a water-soluble acid.  The resin may be added to a filter cake of the silica so as to thin it out into a flowable slurry as disclosed in Specification 774,586.  The silica suspension produced by the invention may be filtered and dried or spray dried.