Patent GB-948743-A (GB)
Title: Methods for treating corn flour
IPC: A21D2/20
Filed: 1960-06-23
Abstract: In treating yellow corn (maize) flour, e.g. ungelatinized or heat-modified, to increase its capacity for imbibing water and, if desired, to effect bleaching, the flour is heated at a temperature below its caramelization point, e.g. at temperatures between 70 and 125 DEG C. and at atmospheric or higher pressures, in the presence of an oxidatively active reaction product of acetone and aqueous hydrogen peroxide having a substantial titratable peroxide content, e.g. equivalent to at least 0.01% of hydrogen peroxide based on the weight of the flour, and comprising at least one acyclic dihydroperoxide of acetone. The reaction product may contain the dimer bis-(1-11-hydroperoxy 1, 11-methyl) diethyl peroxide and the corresponding trimer (formulae given). The reaction product may be produced by reacting acetone with aqueous, 35%, hydrogen peroxide, in the presence of an acid or acidic catalyst, and, if desired, a water-binding substance such as calcium sulphate hemi-hydrate or dry gluten, at temperatures between 4 DEG C. and the boiling point of the mixture of reactants. The weight ratio of acetone to hydrogen peroxide in this mixture may range between 100:1 and 1:20, but a 1:1 molar ratio is preferred. The reaction product may be carried on an edible solid carrier such as starch, e.g. heat-modified or oxidized, dextrin, wheat flour, e.g. heat-treated or defatted, wheat gluten, soyabean protein and calcium sulphate hemi-hydrate.  Alternatively, liquid or gaseous acetone may be reacted with aqueous hydrogen peroxide mixed with the yellow corn flour. The flour may be treated with the vapour given off from a mixture of the reaction product with a substantially inert, non-volatile organic liquid, such as paraffin oil. Specification 948,741 is referred to.ALSO:In treating yellow corn (maize) flour, e.g. ungelatinized or heat-modified, to increase its capacity for imbibing water and, if desired, to effect bleaching, the flour is heated at a temperature below its caramelization point, e.g. at temperatures between 70 and 125 DEG C. and at atmospheric or higher pressures, in the presence of an oxidatively active reaction product of acetone and aqueous hydrogen peroxide having a substantial titratable peroxide content, e.g. equivalent to at least 0.01% of hydrogen peroxide based on the weight of the flour, and comprising at least one acyclic dihydroperoxide of acetone.  The reaction product may contain the dimer bis-(1-11hydroperoxy 1, 11-methyl) diethyl peroxide and the corresponding trimer (formul  given). The reaction product may be produced by reacting acetone with aqueous, 35%, hydrogen peroxide, in the presence of an acid or acidic catalyst and, if desired, a water-binding substance such as calcium sulphate hemi-hydrate or dry gluten, at temperatures between 4 DEG C. and the boiling point of the mixture of reactants. The weight ratio of acetone to hydrogen peroxide in this mixture may range between 100:1 and 1:20, but a 1:1 molar ratio is preferred.  The reaction product may be carried on an edible solid carrier such as starch, e.g. heat-modified or oxidized, dextrin, wheat flour, e.g. heat-treated or defatted wheat gluten, soyabean protein and calcium sulphate hemi-hydrate.  Alternatively, liquid or gaseous acetone may be reacted with aqueous hydrogen peroxide mixed with the yellow corn flour.  The flour may be treated with the vapour given off from a mixture of the reaction product with a substantially inert, non-volatile organic liquid, such as paraffin oil.  Specification 948,741 is referred to.