Patent GB-991627-A (GB)
Title: Improvements in or relating to water-dispersible drying oil compositions
IPC: C09D191/00
Filed: 1962-01-09
Abstract: The invention comprises paint vehicles which are liquid condensates of (a) 75.90% of a drying oil ester of an unsaturated fatty acid having 14 to 20 carbon atoms and a polyhydric alkanol of 3-6 carbon atoms and having 3 to 6 hydroxyl groups, and (b) 10-25% of a polyoxyethylene polyol, having a molecular weight of 500-2000, of the general formula R[O(C2H4O)nH]m where R is a m-valent hydrocarbon radical of 3 to 6 carbon atoms, n is 4 to 12, and m is 3 to 6. Specified (b) compounds are polyoxyethylene derivatives of glycerol, trimethylol propane, hexanetriol, pentaerythritol, and sorbitol. The condensation is carried out at 150-250 DEG  C. in presence or absence of a catalyst, specified catalysts being alkali and alkaline earth metals, heavy metal oxides, and heavy metal salts, those preferred being litharge and stannic chloride. The drying oil components are synthetic polyhydric alcohol esters of non-conjugated and conjugated fatty acids, those specified being oleic, ricinoleic, linoleic and linolenic acids, as well as non-conjugated and conjugated natural drying oils, those specified being soybean oil, linseed oil, safflower oil, tung oil, perilla oil, china-wood oil, oiticica oil, walnut oil, and poppyseed oil. The drying oils may be modified with a polycarboxylic acid, a polyhydric alcohol, or polyolefinic materials, those specified being maleic, fumaric, aconitic, succinic, glutaric, sebacic, azelaic, tartaric, and phthalic acids, as well as their anhydrides, esters and partial esters, glycerol, mannitol, sorbitol, pentaerythritol, trimethylolpropane, trimethylol ethane and 1,3,6 - hexane triol in amount in admixture with ethylene glycol, diethylene glycol and dipentaerythritol, cyclopentadiene, cyclohexadiene, 1,4-butadiene, and nioprene.  The compositions are used as bases for paints and insecticides. Many examples are given using polyoxyethylene glycerol of molecular weights 750-1250.ALSO:The invention comprises paint vehicles which are liquid condensates of (a) 75-90% of a drying oil ester of an unsaturated fatty acid having 14 to 20 carbon atoms and a polyhydric alkanol of 3 to 6 carbon atoms and having 3 to 6 hydroxyl groups, and (b) 10 to 25% of a polyoxyethylene polyol, having a molecular weight of 500-2000, of the general formula <FORM:0991627/C3/1> where R is an m-valent hydrocarbon radical of 3 to 6 carbon atoms, n is 4 to 12, and m is 3 to 6. Specified (b) compounds are polyoxyethylene derivatives of glycerol, trimethylol propane, hexanetriol, pentaerythritol, and sorbitol. The condensation is carried out at 150-250 DEG  C. in presence or absence of a catalyst, specified catalysts being alkali and alkaline earth metals, heavy metal oxides, and heavy metal salts, those preferred being litharge and stannic chloride.  A coupling solvent is preferably included in the composition, up to 30% by weight, in order to increase the solution range of the reaction product in water, which can be ethers, alcohols, or esters, those preferred being ethylene glycol ethers.  The drying oil components are synthetic polyhydric alcohol esters of non-conjugated and conjugated fatty acids, those specified being oleic, ricinoleic, linoleic and linolinic acids, as well as non-conjugated and conjugated natural drying oils, those specified being soybean, linseed oil, safflower oil, tung oil, perilla oil, chinawood oil, oiticica oil, walnut oil, and poppyseed oil.  The drying oils may be modified with a polycarboxylic acid, a polyhydric alcohol, or polyolefinic materials, those specified being maleic, fumaric, aconitic, succinic, glutaric, sebacic, azelaic, tartaric, and phthalic acids, as well as their anhydrides, esters and partial esters, glycerol, mannitol, sorbitol, pentaerythritol, trimethylol propane, trimethylolethane and 1,3,6-hexanetriol in or not in admixture with ethylene glycol, diethylene glycol and pentaerythritol, cyclopentadiene, cyclohexadiene, 1,4-butadiene, and isoprene. The compositions may contain pigments and other additives, those specified being titanium dioxide, zinc dioxide, phthalo cyanine blue, lead chromate yellow, molybdate orange, iron oxide red, talc, clay, and mica, and are compatible with solvent-thinned paints and enamels based on linseed oil and alkyd resins, and with synthetic lattices based on styrene/butadiene copolymer, polyvinyl acetate and acrylic polymer. Many examples are given using polyoxyethylene glycerol of molecular weights 750-1250.  Uses.-Bases for paints and insecticides.ALSO:An aqueous paint vehicle comprises a liquid condensate of (a) 75-90% of a drying oil ester of an unsaturated fatty acid having 14 to 20 carbon atoms and a polyhydric alkanol of 3 to 6 carbon atoms and having 3 to 6 hydroxyl groups; and (b) 10-25% of a polyoxyethylene polyol of molecular weight 500 to 2,000 of formula R-[O(C2H4O)nH]m, where R is an m-valent hydrocarbon radical of 3 to 6 carbon atoms, n is 4-12, m is 3-6. The specified drying oils are esters of oleic, ricinoleic, linoleic, and linolinic acids, and soyabean, linseed, sunflower, tung, perilla, china wood, siticia, walnut, and poppy seed oils; these may be modified by polycarboxylic acids, polyhydric alcohols or polyolefinic materials. The paint may also contain solvents e.g. ethylene glycol ethers; driers e.g. naphthenates, and pigments e.g. titania, zinc oxide, phthalocyanine blue, lead chromate, molybdate orange, iron oxide, talc, clay and mica. The paints are compatible with solvent-thinned paints and enamels based on linseed oil and alkyd resins, and with synthetic lattices based on styrene/butadiene copolymer, polyvinyl acetate and acrylic polymer. In an Example (16) a white exterior house paint comprises the condensation product of a maleic modified linseed oil and polyoxyethylene glycerol, water, ethylene glycol monobutyl ether, TiO2, zinc oxide, talc, phenylmercuric acetate, and cobalt, lead, and manganese naphthenates.ALSO:Glass plates are coated with compositions containing an aqueous paint vehicle comprising a liquid condensate of (a) 75-90% of a drying oil ester of an unsaturated fatty acid having 14-20 carbon atoms and a polyhydric alkanol of 3-6 carbon atoms and having 3-6 hydroxyl groups, and (b) 10-25% of a polyoxyethylene polyol of molecular weight of 500-2000 of formula R-[O(C2H4O)nH]m where R is an m-valent hydrocarbon radical of 3-6 carbon atoms, n is 4 to 12, m is 3 to 6.  The specified drying oils are esters of oleic, ricinoleic, linoleic and linolinic acids, and soyabean, linseed, sunflower, tung, perilla, china wood, siticia, walnut and poppy seed oils; these may be modified by polycarboxylic acids, polyhydric alcohols or polyolefinic compounds.  The coatings are hardened by exposure or by baking.  The composition may also contain solvents, e.g. ethylene glycol ethers; driers, e.g. naphthenates; and pigments, e.g. titania, zinc oxide, phthalocyanine blue, lead chromate, molybdate orange, iron oxide; talc, clay and mica.  In a typical example, (12) a glass plate was coated with a composition comprising the condensation product of dehydrated castor oil and polyoxyethylene glycerol, ethylene glycol monobutyl ether and water.