Patent SG-11201809573S-A (SG)
Title: Conversion of biomass into a liquid hydrocarbon material
Inventor: URADE VIKRANT
IPC: C10G3/00
Filed: 2017-05-23
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 411413111111011114110HOEHEIREMIERMEMIE Organization International Bureau (10) International Publication Number (43) International Publication Date .....0\"\"\" WO 2017/202837 Al 30 November 2017 (30.11.2017) WIPO I PCT (51) International Patent Classification: B.V. [NL/NL]; Carel van Bylandtlaan 30, 2596 HR THE ClOG 3/00 (2006.01) BO1J 31/04 (2006.01) HAGUE (NL). ClOG 1/00 (2006.01) ClOG 1/06 (2006.01) (71) Applicant (for US only): SHELL OIL COMPA- B01J 31/02 G006.01) ClOG 1/10 G006.01) NY [US/US]; SHELL PLAZA 1, HOUSTON, Texas (21) International Application Number: 77252-2463 (US). PCT/EP2017/062395 (72) Inventors: URADE, Vikrant, Nanasaheb; Plot No (22) International Filing Date: 7, Bengaluru Hardware Park, Devanahalli Industrial 23 May 2017 (23.05.2017) Park. Mahadeva Kodigahalli, Bangalore North 562149 (IN). DEL PAGGIO, Alan, Anthony; 18710 Scoresby (25) Filing Language: English Manor Drive, Spring, Texas 77379 (US). CHILKOOR (26) Publication Language: English SOUNDARARAJAN, Laxmi, Narasimhan; Plot No 7, Bengaluru Hardware Park, Devanahalli Industrial Park. Ma- (30) Priority Data: hadeva Kodigahalli, Bangalore North, 562149 Karnataka 201641017931 25 May 2016 (25.05.2016) IN (IN). PANCHAGNULA, Madhusudhan, Rao; Plot No 7, (71) Applicant (for all designated States except US): SHELL Bengaluru Hardware Park, Devanahalli Industrial Park Ma- INTERNATIONALE RESEARCH MAATSCHAPPIJ (54) Title: CONVERSION OF BIOMASS INTO A LIQUID HYDROCARBON MATERIAL = = Figure 1 = 11 _> 12 15 --> 16 _______>. 17 = = 10 13 s l , , 1 4 1.3 = = = = = 21 =24 24 = 22 = 25 = = = _ (57) : The present invention provides a process for producing liquid hydrocarbon products from a biomass, biomass-containing and/or biomass-derived feedstock, said process comprising the steps of: a) contacting the feedstock with one or more hydropyrolysis It catalyst compositions and molecular hydrogen in a hydropyrolysis reactor vessel at a temperature in the range of from 350 to 600°C and a pressure in the range of from 0.50 to 7.50MPa, to produce a product stream comprising hydropyrolysis product that is at least IN partially deoxygenated, H2O, H2, CO2, CO, C1 - C3 gases, char and catalyst fines; b) removing all or a portion of said char and catalyst f.r1 cc fines from said product stream; c) hydroconverting said hydropyrolysis product in a hydroconversion reactor vessel in the presence of ei one or more hydroconversion catalyst compositions and of at least a portion of the H2O, CO2, CO, H2, and C1 - C3 gases generated in step a), to produce a vapour phase product comprising substantially fully deoxygenated hydrocarbon product, H2O, CO, CO2, and C1 ei --- - C3 gases, wherein one or both of the hydropyrolysis catalyst composition and the hydroconversion catalyst composition is produced IN ,-1 in a process comprising the © ei O [Continued on next page] WO 2017/202837 Al MIDEDIMOMOIDEIRMEMODIMIlliMEMOVOIMIE hadeva Kodigahalli, Bangalore North, 562149 Karnataka (IN). (74) Agent: MATTHEZING, Robert, Maarten et al.; PO Box 384, 2501 CJ THE HAGUE (NL). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Declarations under Rule 4.17: — as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(0) Published: — with international search report (Art. 21(3)) steps of incorporating one or more metals selected from those of groups 6, 9, and 10 of the periodic table, into a shaped support; and incorporating one or more coordinating organic compounds into said shaped support, thus forming a catalyst precursor; and then either (i) treating the catalyst precursor in the presence of hydrogen and sulfiding it or (ii) calcining the catalyst precursor.