Patent GB-815875-A (GB)
Title: Improved composition for the stabilization of halogen-containing resins
IPC: C08K5/526
Filed: 1957-06-11
Abstract: Halogen-containing resins are stabilized with compositions comprising 20 to 80 per cent of a cadmium, zinc, lead, tin, barium, strontium or calcium salt of benzoic acid or a substituted benzoic acid containing as substituents fluorine, chlorine, bromine or not more than three alkyl radicals containing in the aggregate not more than 12 carbon atoms, 80 to 20 per cent of a cadmium, zinc, lead, tin, barium, strontium or calcium salt of an alkyl or chloralkyl substituted phenol containing not more than three substituent groups, and 0.5 to 50 per cent of an organic phosphite of formula <FORM:0815875/IV (a)/1> wherein X is a halogen atom, R3, R4 and R5 represent aliphatic or cycloaliphatic radicals, aryl radicals containing not more than two ring structures or aralkyl radicals containing not more than two ring structures, a, b and c have a value from 0 to 3, but do not all have the value 0 and a + b + c does not exceed 3.  Specified resins are vinyl chloride polymers and copolymers, e.g. with vinyl acetate, dienes such as chlorobutadiene, esters, nitriles and amides of unsaturated carboxylic acids such as acrylic and methacrylic acids, diethyl maleate, diethyl fumarate and maleic anhydride, after-chlorinated polymers and copolymers of vinyl chloride, polymers of vinylidene chloride and copolymers thereof with vinyl chloride and other polymerizable compounds, polymers of vinyl chloracetate, dichlorodivinyl ether and chlorinated styrenes such as dichlorostyrene, chlorinated polymers of acrylic and a -substituted acrylic acid esters, chlorinated vinyl acetate polymers, chlorinated ethylene polymers, polymers and after-chlorinated polymers of chlorobutadiene, chlorinated rubber, rubber hydrochloride and chlorinated rubber hydrochloride. Specified benzoates are cadmium benzoate and cadmium p.-tert. butylbenzoate.  Specified phenolates are those of butylphenol, monochloroctylphenol, nonylphenol, oleylphenol, laurylphenol, octadecylphenol and dibutylmethyl phenol, preferably barium phenolates containing straight chain alkyl groups of 6-13 carbon atoms such as barium octylphenolate and barium nonylphenolate. Specified phosphites are trioctyl phosphite, tri(2-chlorethyl) phosphite, tridecyl phosphite, triphenyl phosphite, tri(o-xenyl) phosphite, di(p - tert. butylphenyl) - monophenyl phosphite, diphenyl-mono orthochlorophenyl phosphite, di (nonylphenyl)-mono-2-chlorethyl phosphite, di(nonylphenyl)-mono-2-chloropropyl phosphite, diphenyl monochlorethyl phosphite, diphenyl monochloropropyl phosphite, phenyl di(chloroethyl) phosphite, phenyl-di(b -chloropropyl) phosphite, dinonyl-b -chloropropyl phosphite) diphenoxychlorophosphorus, octylphenoxy dichlorophosphorus, di (nonylphenoxy) chlorophosphorus, phenoxyoctyloxy chlorophosphorus, diphenylmonochlorononyl phosphite, diphenylmonochloroctyl phosphite, phosphite ester derivatives of glycols, polyethylene glycols and glycol ethers, and the reaction products of di (nonylphenoxy) chlorophosphorus with epoxidized soya bean triglyceride and butyl epoxy stearate.  The compositions may contain plasticizers, e.g. esters of phthalic, adipic, sebacic, azelaic, citric, aconitic, tricarballylic, maleic, fumaric, succinic, phosphoric acids and thioglycolic acids, and glycol, glycerol, pentaerythritol, sorbitol and thioglycols, amino alcohol derivatives, ester amides, sulphonamides, chlorinated plasticizers, and carbonic acid derivatives.  The stabilizer compositions may be used to stabilize plastisols and organosols.  Examples described the incorporation of the stabilizer compositions in compositions comprising (1) polyvinyl chloride, dioctyl phthalate, epoxidized soya bean oil, stearic acid and optionally zinc 2-ethylhexoate (2) chlorinated rubber, dibutyl phthalate and epoxidized soya bean oil dissolved in toluene and cast to give films (3) vinylchloride-vinyl acetate copolymer and dioctyl phthalate and (4) vinyl chloride-dibutyl maleate copolymer and dibutyl sebacate.