Patent GB-1071929-A (GB)
Title: Method of treating urea synthesis effluent
IPC: C07C273/04
Filed: 1965-06-04
Abstract: CO2 and NH3 are separated from a urea synthesis effluent by subjecting the effluent to a high pressure distillation, e.g. at 10 to 30 kg/cm.2 and 100 DEG  to 160 DEG  C., to remove the CO2 and NH3 as a gaseous mixture then condensing the mixture under high pressure, e.g. 10-30 kg/cm.2 at 20 DEG  to 80 DEG  C.  There is introduced into the effluent a liquefied gas having a vapour pressure higher than the pressure of distillation at the distillation temperature but lower than the pressure of condensation at the condensation temperature and which is inert to and of low solubility in CO2, NH3, H2O, urea and mixtures thereof under the process conditions whereby the inert liquid is distilled and condensed with the CO2 and NH3.  The inert liquid may be a C3-C4 hydrocarbon, e.g. propane, propylene, n-butane, i-butane, 2-methyl propane, but-1-ene, but-2-ene, i-butylene, CCl3F, CCl2F2, CHCl2F, CHClF2, C2Cl2F4, CH3Cl, C2H5Cl methyl-, dimethyl- or tri-methylamine or any mixture of these. The inert liquid may be recovered, e.g. by separation of the 2 layers of inert liquid and CO2 and NH3, and then returned to the distillation zone.  The inert liquid is preferably used in the amount of 0.2 to 2 mol per mol of CO2 and NH3.  The effluent may undergo an initial high pressure distillation, e.g. at 10 to 30 kg/cm.2 and 130 DEG  to 160 DEG  C., in the absence of the inert liquid to remove 70 to 90% wt. of the untreated CO2 and NH3.  An aqueous liquid which dissolves NH3 and CO2, e.g. aqueous urea or NH3, may be contacted with the gaseous mixture during the condensation. The NH3 and CO2 may be recycled to the urea synthesis.ALSO:CO2 and NH3 are separated from a urea synthesis effluent by subjecting the effluent to a high pressure distillation, e.g. at 10 to 30 kg/cm.2 and 100 DEG  to 160 DEG  C., to remove the CO2 and NH3 as a gaseous mixture then condensing the mixture under high pressure, e.g. 10 to 30 kg/cm.2 at 20 DEG  to 80 DEG  C.  There is introduced into the effluent a liquefied gas having a vapour pressure higher than the pressure of distillation at the distillation temperature but lower than the pressure of condensation at the condensation temperature and which is inert to and of low solubility in CO2, NH3, H2O1 urea and mixtures thereof under the process conditions whereby the inert liquid is distilled and condensed with the CO2 and NH3.  The inert liquid may be a C3-C4 hydrocarbon, e.g. propane, propylene, n-butane, i-butane, 2-methyl propane, but-1-ene, but-2-ene, i-butylene, CCl3F, CCl2F2, CHCl2F, CHClF2, C2Cl2F4, CH3Cl, C2H5Cl methyl-, dimethyl- or tri-methylamine or any mixture of these.  The inert liquid may be recovered, e.g. by separation of the 2 layers of inert liquid and CO2 and NH3, and then returned to the distillation zone.  The inert liquid is preferably used in the amount of 0.2 to 2 mol per mol of CO2 and NH3.  The effluent may undergo an initial high pressure distillation, e.g. at 10 to 30 kg/cm.2 and 130 DEG  to 160 DEG  C., in the absence of the inert liquid to remove 70 to 90% weight of the untreated CO2 and NH3. An aqueous liquid which dissolves NH3 and CO2, e.g. aqueous urea or NH3, may be contacted with the gaseous mixture during the condensation.  The NH3 and CO2 may be recycled to the urea synthesis.