Patent GB-923055-A (GB)
Title: Granular bleaching compositions
IPC: C11D3/395
Filed: 1959-12-07
Abstract: A dry, stable granular bleaching composition comprises dichloroisocyanuric acid, sodium tripolyphosphate, sodium dichloroisocyanurate, sodium acid tripolyphosphate and water present as water of hydration.  The composition, which preferably contains not more than 20% by weight of water of hydration, may either be prepared from water-wet dichloroisocyanuric acid or from the dried product which generally contains less than 1% by weight of water. Water-wet dichloroisocyanuric acid may be prepared by reacting chlorine and an aqueous solution of a di-alkalimetal isocyanurate at a temperature above the freezing point of the solution but not exceeding 50 DEG C. and at an acidic pH which is preferably below 4,5, separating the precipitated dichlorocyanuric acid and washing until free from alkali metal chloride.  The water-wet dichloroisocyanuric acid which normally contains 10-65 parts by weight of water per 100 parts by weight of dichloroisocyanuric acid (dry basis) may then be mixed with anhydrous granular sodium tripolyphosphate in an amount varying from 6 to 500 parts by weight of sodium tripolyphosphate per unit weight of water present in the water-wet dichloroisocyanuric acid to give a substantially dry, free-flowing powder. Alternatively, the washed precipitated water-wet dichloroisocyanuric acid may be dried and intimately mixed, in powder form, with anhydrous granular sodium tripolyphosphate and then mixed with water in the form of droplets at a temperature of 10 DEG -50 DEG C. in the proportions 5-50 parts of anhydrous dichloroisocyanuric acid, 40-85 parts of anhydrous granular sodium tripolyphosphate and 10-17 parts of water, the proportions adding up to 100, and the agglomerated mass so obtained aged for at least 6 hours at room temperature and heated at 50 DEG -90 DEG C. to reduce the water content to 1-10% by weight of the total mass.  During the mixing and any subsequent treatment of the mixture of dichloroisocyanuric acid and sodium tripolyphosphate, sodium dichloroisocyanurate and sodium acid tripolyphosphate having the formula Na5-n HnP3 O10.  XH2O in which n is an integer o 1-4 and X is an integer from 0-2, are slowly produced.ALSO:A dry, stable granular bleaching composition comprises dichloro isocyanuric acid, sodium tripolyphosphate, sodium dichloro isocyanurate, sodium acid tripolyphosphate and water present as water of hydration.  The composition, which preferably contains not more than 20% by weight of water of hydration, may either be prepared from water-wet dichloro isocyanuric acid or from the dried product which generally contains less than 1% by weight of water.  Water-wet dichloro isocyanuric acid may be prepared by reacting chlorine with an aqueous solution of a dialkali metal isocyanurate at a temperature above the freezing point of the solution but not exceeding 50 DEG C. and at an acidic pH which is preferably below 4,5, separating the precipitated dichloro isocyanuric acid and washing until free from alkali metal chloride.  The water-wet dichloro isocyanuric acid which usually contains 10-65 parts by weight of water per 100 parts by weight of dichloro isocyanuric acid may then be mixed with anhydrous granular sodium tripolyphosphate in an amount varying from 6-500 parts by weight of sodium tripolyphosphate per unit weight of water present in the water-wet dichloro isocyanuric acid to give a substantially dry, free-flowing powder.  Alternatively the washed precipitated water-wet dichloro isocyanuric acid may be dried and intimately mixed in powder form, with anhydrous granular sodium tripolyphosphate and then mixed with water in the form of droplets at a temperature of 10 DEG -50 DEG C. in the proportions 5-50 parts of anhydrous dichloro isocyanuric acid, 40-85 parts of anhydrous granular sodium tripolyphosphate and 10-17 parts of water, the proportions adding up to 100, and the agglomerated mass so obtained aged for at least 6 hours at room temperature and heated at 50 DEG -90 DEG C. to reduce the water content to 1-10% by weight of the total mass. During the mixing and any subsequent treatment of the mixture of dichloro isocyanuric acid and sodium tripolyphosphate, sodium dichloro isocyanurate and sodium acid tripolyphosphate having the formula Na5-n Hn P3O10.XH2O, in which n is an integer of 1-4 and X is an integer from 0-2, are slowly produced.ALSO:A dry, stable granular composition which when dissolved in water produces clear solutions having disinfecting and germicidal properties comprises dichloroisocyanuric acid, sodium tripolyphosphate, sodium dichloroisocyanurate, sodium acid tripolyphosphate and water present as water of hydration.  The composition, which preferably contains not more than 20% by weight of water of hydration, may either be prepared from water-wet dichloroisocyanuric acid or from the dried product which generally contains less than 1% by weight of water. Water-wet dichloroisocyanuric acid may be prepared by reacting chlorine and an aqueous solution of a di-alkalimetal isocyanurate (see Group IV (c)).  The water-wet dichloroisocyanuric acid which normally contains 10-65 parts by weight of water per 100 parts by weight of dichloroisocyanuric acid (dry basis) may then be mixed with anhydrous granular sodium tripolyphosphate in an amount varying from 6 to 500 parts by weight of sodium tripolyphosphate per unit weight of water present in the water-wet dichloroisocyanuric acid to give a substantially dry, free-flowing powder. Alternatively, the washed precipitated water-wet dichloroisocyanuric acid may be dried and intimately mixed, in powder form, with anhydrous granular sodium tripoly phosphate and then mixed with water in the form of droplets at a temperature of 10-50 DEG  C. in the proportions 5-50 parts of anhydrous dichloroisocyanuric acid, 40-85 parts of anhydrous granular sodium tripolyphosphate and 10-17 parts of water, the proportions adding up to 100, and the agglomerated mass so obtained aged for at least 6 hours at room temperature and heated at 50-90 DEG  C. to reduce the water content to 1-10% by weight of the total mass. During the mixing and any subsequent treatment of the mixture of dichloroisocyanuric acid and sodium tripolyphosphate, sodium dichloroisocyanurate and sodium acid tripolyphosphate having the formula Na5-nHnP3O10.XH2O in which n is an integer of 1-4 and X is an integer from 0-2, are slowly produced.  The composition preferably contains 2.5-40 parts by weight of dichloroisocyanuric acid (anhydrous basis), 2.7-35 parts by weight of sodium dichloroisocyanurate (anhydrous basis), 4.2-55 parts by weight of sodium acid tripolyphosphate (anhydrous basis), 28.4-56 parts by weight of sodium tripolyphosphate (anhydrous basis) and 1-10 parts by weight of water of hydration, the respective components adding up to 100 parts by weight.