Patent GB-1093794-A (GB)
Title: Bonding elastomeric copolymers on to articles
IPC: C09J151/06
Filed: 1965-04-05
Abstract: Compositions for bonding elastomeric, amorphous, saturated copolymers of ethylene with an alpha-olefin to natural or synthetic fibres or articles made therefrom comprise graft polymers of grafting maleic acid on such copolymers, emulsified with water in the presence of a non-ionic and of an anionic surface-active agent to produce a latex, which is mixed with an aqueous dispersion of a phenolformaldehyde resin and matured.  The article may be in the form of fabrics, yarns, cords or other manufactured textile articles, tyres, belt conveyers, drive belts made from, say, cotton, nylon, polyester or cellulose fibres. The copolymer may be ethylene with propylene or butene-1, or those disclosed in Specification 856,736 or 856,737. The grafting may be carried out in the presence of an organic peroxide.  The non-ionic surfactant may be a polyoxyethylated alkyl phenol, or polyoxyethylated alcohols of formula R(OCH.R1CHR1)nOH where R is an alkyl group, R1 is hydrogen or an alkyl group, and n is 4 to 10.  The anionic surfactant may be sodium lauryl sulphate, a sodium salt of a polyoxyethylated phenol, or sodium or potassium oleate, palmitate or steorate.  The latex may be obtained by emulsifying an hydrocarbon solution containing the grafted copolymer with an aqueous solution of the surfactants and removing the hydrocarbon solvent from the emulsion say by distillation.  A creaming agent such as carboxymethylcellulose may be present in the emulsion. The phenol formaldehyde resin may be a resorcinol-formaldehyde resin.  The matured mixture may be applied by immersion, spreading or friction and the treated article dried under an air current. The vulcanizing agents such as organic peroxides, e.g. alpha, alpha1-bis (tert. butyl-peroxy) diisopropylbenzene may be incorporated in the copolymer, and the applied mix of copolymer and vulcanizing agent may contain free radical acceptors such as sulphur, reinforcing fillers, and other additives such as carbon black.  In the examples a square rayon fabric is adhered to ethylene-propylene copolymer for the manufacture of tape.ALSO:An elastomeric, amorphous, saturated copolymer of ethylene with an alpha-olefin is bonded to a natural or synthetic fibre or an article made therefrom by grafting maleic acid on to the copolymer, emulsifying the resulting graft copolymer with water in the presence of a nonionic and of an anionic surface active agent to produce a latex, mixing the resulting latex with an aqueous dispersion of a phenol-formaldehyde resin, maturing the resulting mixture applying the matured mixture on to the natural or synthetic fibre or the article, applying a mixture of the copolymer with a vulcanizing agent on to the natural or synthetic fibre or the article to which the mature mixture has already been applied, and vulcanizing the natural or synthetic fibre or the article.  The article may be in the form of fabrics, yarns, cords or other manufactured textile articles, tyres, belt conveyors, drive belts made from say cotton, nylon, polyester or cellulose fibres.  The copolymer may be ethylene with propylene or butene-1, or those disclosed in Specification 856736 or 856737.  The grafting may be carried out in the presence of an organic peroxide.  The non-ionic surfactant may be a polyoxyethylated alkyl phenol, or polyoxyethylated alcohols of formula R(OCH.R\svCHR\sv)n OH where R is an alkyl group, R\sv is hydrogen or an alkyl group, and n is 4 to 10.  The anionic surfactant may be sodium lauryl sulphate, a sodium salt of a polyoxyethylated phenol, or sodium or potassium oleate, palmitate or steorate.  The latex may be obtained by emulsifying a hydrocarbon solution containing the grafted copolymer with an aqueous solution of the surfactants and removing the hydrocarbon solvent from the emulsion say by distillation.  A creaming agent such as carboxymethylcellulose may be present in the emulsion. The phenol formaldehyde resin may be a resorcinol-formaldehyde resin.  The matured mixture may be applied by immersion, spreading or friction and the treated article dried under an air current. The vulcanizing agents may be organic peroxides e.g. alpha, alpha\sv - bis (tert. butyl-peroxy) diisopropylbenzene. The applied mix of copolymer and vulcanizing agent may contain free radical acceptors such as sulphur, reinforcing fillers, and other additives such as carbon black.  In the examples a square rayon fabric is adhered to ethylene-propylene copolymer for the manufacture of tape.ALSO:An elastomeric, amorphous, saturated copolymer of ethylene with an alpha-olefin is bonded to a natural or synthetic fibre or an article made therefrom by grafting maleic acid on to the copolymer, emulsifying the resulting graft copolymer with water in the presence of a non-ionic and of an anionic surface active agent to produce a latex, mixing the resulting latex with an aqueous dispersion of a phenolformaldehyde resin, maturing the resulting mixture applying the matured mixture on to the natural or synthetic fibre or the article, applying a mixture of the copolymer with a vulcanizing agent on to the natural or synthetic fibre or the article to which the mature mixture has already been applied, and vulcanizing the natural or synthetic fibre or the article.  The article may be in the form of fabrics, yarns, cords or other manufactured textile articles, tyres, belt conveyors, drive belts made from say cotton, nylon, polyester or cellulose fibres.  The copolymer may be ethylene with propylene or butene-1, those disclosed in Specification 856736 or 856737.  The grafting may be carried out in the presence of an organic peroxide.  The non-ionic surfactant may be a polyoxyethylated alkyl phenol, or polyoxyethylated alcohols of formula R(OCH.R\svCHR\sv)nOH where R is an alkyl group, R\sv is hydrogen or an alkyl group, and n is 4 to 10.  The anionic surfactant may be sodium lauryl sulphate, a sodium salt of a polyoxyethylated phenol, or sodium or potassium oleate, palmitate or stearate.  The latex may be obtained by emulsifying a hydrocarbon solution containing the grafted copolymer with an aqueous solution of the surfactants and removing the hydrocarbon solvent from the emulsion say by distillation.  A creaming agent such as a carboxymethylcellulose may be present in the emulsion.  The phenol formaldehyde resin may be a resorcinolformaldehyde resin.  The matured mixture may be applied by immersion, spreading or friction and the treated article dried under an air current.  The vulcanizing agents may be organic peroxides, e.g. alpha, alpha\sv-bis(tert. butylperoxy)diisopropylbenzene.  The applied mix of copolymer and vulcanizing agent may contain free radical acceptors such as sulphur, reinforcing fillers, and other additives such as carbon black.  In the Examples a square rayon fabric is adhered to ethylene-propylene copolymer for the manufacture of tape.