Patent GB-992257-A (GB)
Title: Improved refractory silicon carbide articles
IPC: C04B35/573
Filed: 1962-01-31
Abstract: Bodies of density at least 3.0 gms./c.c. consisting principally of silicon carbide and having improved resistance to oxidation at 1500-1850 DEG  C. are prepared by forming a body comprising silicon carbide, carbon and as an additive for imparting oxidation resistanc at least one of the following metals: W, Cr, Fe, Hf, Ta, Ti, Zr, Mo and compounds thereof; and siliconizing said body to convert said carbon to silicon carbide, said siliconizing can be effected by heating said body to at least 2000 DEG  C. in the presence of at least a sufficient amount of silicon to form silicon carbide by reaction with the face carbon in the body, said additive being present before siliconizing in amount equivalent to from 1 wt. per cent to 30 wt. per cent of metal in said dense body and being of such a nature as to remain in said body as the temperature employed in the siliconizing.  The additive may be an oxide, carbide, silicide, hydride or nitride of the metals mentioned. Compounds specified are: tungsten oxide, Cr2O3, iron silicide, MoSi2 and TaSi2. Other ingredients from which the body is prepared are:  powdered phenolic resin or polyvinyl alcohol, pine oil, furfural and carbon.  The ingredients may be pressed into a body or pellet at 4000-5000 p.s.i., dried at 120-225 DEG  F., heated to 2300 DEG  C. in an inert atmosphere, saturated with furfural which is carbonized with acid, free carbon being subsequently siliconized by heating above 2000 DEG C. with elemental silicon.  Alternatively, the silicon carbide body may have the metal incorporated during siliconization by heating to 2100-2300 DEG  C. with a mixture of silicon and a metal, e.g. a 50 : 50 atomic percentage of Si and Zr.  Bodies prepared may be: nose cones, rocket motor parts, electrical resistance heating rods, linings for burners.ALSO:Bodies of density at least 3.0 gms./c.c. consisting principally of silicon carbide and having improved resistance to oxidation ot 1500-1850  DEG C. are prepared by forming a body comprising silicon carbide, carbon and as an additive for imparting oxidation resistance at least one of the following metals: W, Cr, Fe, Hf, Ta, Ti, Zr, Mo and compounds thereof ; and siliconizing said body to convert said carbon to silicon carbide, said siliconizing being effected by heating said body to at least 2000  DEG C. in the presence of at least a sufficient amount of silicon to form silicon carbide by reaction with the free carbon in the body, said additive being present before siliconizing in amount equivalent to from 1 weight per cent to 30 weight per cent of metal in said dense body and being of such a nature as to remain in said body as the temperature employed in the siliconizing. The additive may be an oxide, carbide, silicide, hydride or nitride of the metals mentioned. Compounds specified are: tungsten oxide, Cr2O3, iron silicide, MoSi2 and TaSi2. Other ingredients from which the body is prepared are:  powdered phenolic resin or polyvinyl alcohol, pine oil, furfural and carbon.  The ingredients may be pressed into a body or pellet at 4000-5000 p.s.i., dried at 120-225  DEG F., heated to 2300  DEG F. in an inert atmosphere, saturated with furfural which is carbonized with acid, free carbon being subsequently siliconized by heating above 2000  DEG C. with elemental silicon.  Alternatively the silicon carbide body may have the metal incorporated during siliconization by heating to 2100-2300  DEG C. with a mixture of silicon and a metal e.g. a 50:50 atomic percentage of Si and Zr. Bodies prepared may be: nose cones, rocket motor parts, electrical resistance heating rods, lining for burners.