Patent GB-494385-A (GB)
Title: Vulcanization of rubber
IPC: C08K5/00
Filed: 1938-02-04
Abstract: The vulcanization of rubber is accelerated by the addition to the mix of the reaction product of a substituted or unsubstituted dithio acid with a halo-ketone containing at least three halogen atoms substituted alpha to the carbonyl group, but with not more than two such halogen atoms on the same carbon atom.  The products possess the probable general formula <FORM:0494385/IV/1> where X represents a dithio acid radical, Y is a dithio acid radical or hydrogen and R is either an aliphatic or aromatic radical or hydrogen.  Polyhalogen ketones mentioned include a  a  a 1 trichloracetone, a  a  a 1 a 1 tetrachlor-acetone, a  a  a 1 trichlordibenzyl ketone, and a  a  a 1 a 1 tetrachlor-benzyl propyl ketone, or the corresponding bromo-compounds.  Dithio acids mentioned include dithiocarbamic acids such as N-butyl-, cyclohexyl-, diallyl-, and pentamethylene-dithiocarbamic acids, dithiofuroic acid, dithiobenzoic acid, dithioacetic acid and dithio-salicyclic acid. In an example, chlorine is passed into a mixture of acetone, calcium carbonate and a small amount of methyl alcohol.  Water and additional calcium chloride is added during the chlorination.  The product on fractional distillation is separated into a mixture of dichloracetone and a fraction having a higher chlorine content. This fraction was added to sodium dimethyl dithiocarbamate to form a dark plastic mass. Examples are given to show the efficiency of the accelerators of the present invention when incorporated in a standard rubber mix. Specifications 360,490 and 413,282 are referred to.ALSO:The vulcanization of rubber is accelerated by the addition to the mix of the reaction product of a substituted or unsubstituted dithio acid with a halogen ketone containing at least three halogen atoms substituted alpha to the carbonyl group, but not more than two such halogen atoms on the same carbon atom.  The products possess the probable general formula <FORM:0494385/V/1> where X represents a dithio acid radical, Y is a dithio acid radical or hydrogen, and R is either an aliphatic or aromatic radical or hydrogen.  Polyhalogen ketones mentioned include a  a  a 1 trichloracetone, a  a  a 1 a 1 tetrachlor-acetone, a  a  a 1 trichlor-dibenzyl ketone, and a  a  a 1 a 1 tetrachlor benzyl propyl ketone, or the corresponding bromo compounds.  Dithio acids mentioned include dithiocarbamic acids such as N-butyl-, cyclohexyl-, dialkyl-, and pentamethylene-dithiocarbamic acids, dithiofuroic acid, dithiobenzoic acid, dithioacetic acid and dithiosalicylic acid. In an example chlorine is passed into a mixture of acetone, calcium carbonate and a small amount of methyl alcohol. Water, and additional calcium chloride is added during the chlorination. The product on fractional distillation is separated into a mixture of dichloracetone and a fraction having a higher chlorine content. This fraction was added to sodium dimethyldithiocarbamate to form a dark plastic mass.  Examples are given to show the efficiency of the accelerators of the present invention when incorporated in a standard rubber mix.  Specifications 360,490 and 413,282 are referred to.