Patent GB-1093129-A (GB)
Title: A method of processing glass fibres for combination with elastomeric materials and glass fibre products produced by the method
IPC: C03C25/27
Filed: 1965-10-26
Abstract: Glass fibres to be used in a suitable form for subsequent combination with a matrix of elastomeric material to act as a reinforcing material, are coated either before or after forming them into an endless bundle with a composition containing an elastomer and overcoated with a lubricating material which will reduce the tendency of the fibres to seize during subsequent processing by winding, twisting, plying or weaving.  The elastomeric composition which may be same as the elastomeric matrix may be natural rubber or a synthetic rubber produced from neoprene, butadiene, chloroprene, isoprene or copolymers thereof with acrylonitrile or styrene and may also contain magnesium or zinc oxide, carbon black, a trialkyl thiourea accelerator for neoprene, a diphenylamine acetone reaction product, stearic acid, dicumyl peroxide, toluene, a resorcinol-formaldehyde resin, formaldehyde, ammonium hydroxide or water.  The lubricating material may be a carbohydrate e.g. corn or potato starch, dextrinized starch or a sugar, powdered polyethylene, glassfibres or synthetic resinous fibres milled to a powdered state, silica dust, graphite or carbon black.  Prior to or simultaneously with the application of the elastomeric composition the fibres may be treated with an anchoring agent such as an organo silicon compound in the form of its silane, its hydrolysis product or its polymerization product in which the silane has 1-3 hydrolyzable groups and at least one organic group directly or indirectly attached to the silicon atom containing a nitrogen group in the form of a free amine or an unsaturated group or epoxy group, e.g. gamma-aminopropyltriethoxy silane, gamma-aminopropylvinyldiethoxy silane, gamma (triethoxysilylpropylamide) propylamine, N(gamma-tri ethoxysilylpropyl) propylamine, gamma (triethoxylsilylpropyloxy) propylamine, betaaminoallyltriethoxysilane, para-amino phenyl triethoxyl silane or aniline silane derivatives, the anchoring agent composition optionally containing glycerine, partially dextrinized starch, hydrogenated vegetable oil, a cationic wetting agent, a nonionic emulsifying agent, a polyester resin, polyvinyl alcohol, polyvinyl pyrrolidone, acetic acid and water. Alternatively the anchoring agent may be a Werner complex compound in which the carboxylato group coordinated with the trivalent chromium atom contains an amino or epoxy group.  After application of the elastomeric composition and prior to the application of the lubricating material the fibres may be treated with an assimilation coating comprising an organic silicon compound or Werner complex in which the organic group attached to the silicon atom of the organo silicon compound and the carboxylate group attached to the chromium atom of the Werner complex compound contains an amino or epoxy group, an isocyanate, a phenolic end blocked isocyanate or ethylene dimethacrylate, adapted to subsequently blend the elastomeric composition with the elastomeric matrix forming material.  After application the elastomeric coating may be left uncured or may be partially or completely cured.  The lubricating material may be removed prior to incorporating the glass fibres in the elastomeric matrix by the action of a solvent or in the case of starch by means of an enzyme.  As shown in Fig. 6 polyethylene in dry powder form may be sprinkled onto bundles of glass fibres 60 to which the elastomer composition has been applied by advancing them beneath a shaker 62 containing the powdered polyethylene.