Patent SG-11201809915X-A (SG)
Title: Heat generating catalyst for hydrocarbons cracking
Inventor: ALI OLA S
IPC: C10G11/18
Filed: 2017-05-05
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 111111111111111111111111111111111111111111111111111111111111111111111111111111111 Organization International Bureau (10) International Publication Number (43) International Publication Date ......0\" WO 2017/196660 Al 16 November 2017 (16.11.2017) WIPO I PCT (51) International Patent Classification: SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, B01J 29/03 (2006.01) ClOG 11/05 (2006.01) TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. B01J 29/04 (2006.01) ClOG 11/16 (2006.01) B01J 23/72 (2006.01) ClOG 11/18 (2006.01) (84) Designated States (unless otherwise indicated, for every B01J 23/75 (2006.01) kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, (21) International Application Number: UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, PCT/US2017/031265 TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, (22) International Filing Date: EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, 05 May 2017 (05.05.2017) MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, (25) Filing Language: English KM, ML, MR, NE, SN, TD, TG). (26) Publication Language: English Published: (30) Priority Data: — with international search report (Art. 21(3)) 62/335,213 12 May 2016 (12.05.2016) US (71) Applicant: SAUDI ARABIAN OIL COMPANY [SA/SA]; Post Office Box 5000, Dhahran, 31311 (SA). (71) Applicant (for AG only): ARAMCO SERVICES COM- PANY [US/US]; 9009 West Loop South, Houston, Texas 77096 (US). Inventors: ALI, Ola S.; c/o Saudi Arabian Oil Company, Post Office Box 5000, Dhahran, 31311 (SA). AL YAMI, Hussain; c/o Saudi Arabian Oil Company, Post Office Box (72) 5000, Dhahran, 31311 (SA). KAMINSKY, Mark P.; c/o Aramco Services Company, 9009 West Loop South, Hous- ton, Texas 77096 (US). SHAIKH, Sohel K.; c/o Saudi Ara- bian Oil Company, Post Office Box 5000, Dhahran, 31311 (SA). XU, Wei; c/o Saudi Arabian Oil Company, Post Of- fice Box 5000, Dhahran, 31311 (SA). Agent: MEYER, Christopher I. et al.; Dinsmore & Shohl (74) LLP, One South Main Street Fifth Third Center, Suite 1300, Dayton, Ohio 45402 (US). Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (81) 1-1 C (54) Title: HEAT GENERATING CATALYST FOR HYDROCARBONS CRACKING (57) : A method of making a heat generating catalyst for hydrocarbon cracking. The method includes providing at least one ,C> mordenite framework-inverted (MFI) zeolite having a Si/Al molar ratio of 15 or greater and providing at least one metal oxide precursor. C:N Further, the at least one metal oxide precursor is dispersed within a microstructure of the MFI zeolite catalyst. The method additionally 1-1 ---. includes calcining the heat generating material with the at least one metal oxide precursor dispersed within the microstructure of the I N MFI zeolite catalyst to form at least one metal oxide in situ. The heat generating catalyst includes at least one MFI zeolite and and at 1-1 © least one metal oxide in a ratio between 50:50 and 95:5. Additionally, an associated method of using the heat generating catalyst in ei a hydrocarbon cracking process is provided. C