Patent SG-11201806467Y-A (SG)
Title: Nickel containing mixed metal-oxide/carbon bulk hydroprocessing catalysts and their application
Inventor: BERGWERFF JACOB ARIE
IPC: C10G45/08
Filed: 2017-02-01
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property -, Organization 111111110111101110101011111010111110111011111110110111101101111101111011111 International Bureau 0.. .... .. (10) International Publication Number ..... ..o,„,' (43) International Publication Date r:: WO 2017/134090 Al 10 August 2017(10.08.2017) WIPO I PCT (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every B01J 37/08 (2006.01) B01J 35/10 (2006.01) kind of national protection available): AE, AG, AL, AM, B01J 37/20 (2006.01) B01J 37/00 (2006.01) AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, B01J 23/888 (2006.01) ClOG 45/08 (2006.01) BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, B01J 35/00 (2006.01) B01J 31/22 (2006.01) DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, B01J 35/02 (2006.01) HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, (21) International Application Number: MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, PCT/EP2017/052122 NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, (22) International Filing Date: RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, 1 February 2017 (01.02.2017) TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (25) Filing Language: English (84) Designated States (unless otherwise indicated, for every (26) Publication Language: English kind of regional protection available): ARIPO (BW, GH, (30) Priority Data: GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, 62/289,707 1 February 2016 (01.02.2016) US TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, (71) (72) Applicant: ALBEMARLE EUROPE SPRL [BE/BE]; DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, Parc Scientifique le LLN, Rue du Bosquet 9, 1348 Louv- LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, ain-la-Neuve (BE). SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). Inventors: BERGWERFF, Jacob Arie; Overhoekspark- laan 220, 1031 KC Amsterdam (NL). VEERMAN, Wil- Declarations under Rule 4.17: helmus Clemens Jozef; Prinses Marijketstraat 2, 1131 BB — as to applicant's entitlement to apply for and be granted a Volendam (NL). HUIBERTS, Ronald Jan; A. Fre- patent (Rule 4.17(H)) derikshof 29, 1444 EP Purmerend (NL). EIJS- BOUTS-SPICKOVA, Sona; Goudenregenstraat 1, 5253 — as to the applicant's entitlement to claim the priority of the BE Nieuwkuijk (NL). earlier application (Rule 4.17(iii)) Agent: SCHWABE SANDMAIR MARX PATENTAN- Published: (74) WALTE RECHTSANWALT PARTNERSCHAFT with international search report (Art. 21(3)) MBB; Joseph-Wild-Str. 20, 81829 Munich (DE). 1-1 © C:r © 7r en (54) Title: NICKEL CONTAINING MIXED METAL-OXIDE/CARBON BULK HYDROPROCESSING CATALYSTS AND 11 THEIR APPLICATION I N (57) 1-1 : The current invention relates a bulk catalyst precursor (i.e. no support material is added as such) comprising Ni and C Mo and/or W and an organic component, wherein the molar ratio of C:(Mo+W) ranges from 1.5 to 10. The bulk catalyst precursor is N prepared from a mixture of metal-precursors with an organic agent. The organic agent is partly decomposed to form a mixed metal- en. ) oxide/C phase which is in effect the bulk catalyst precursor. This bulk catalyst precursor (i) is effectively insoluble in water (ii) does not have any appreciable pore volume or surface area and (iii) does not contain a (nano)crystalline metal-oxide phase as character - p. ized by XRD. A bulk catalyst is made from the bulk catalyst precursor.