Patent AP-969-A (AP)
Title: Benzazoles: benxoxazole, benzthiazole and benzimidazole derivatives.
Inventor: WILLIAMS CHRISTOPHER JOHN
IPC: A01N43/78
Filed: 1999-07-29
Granted: 2001-05-29
Abstract: A compound of formula fir is hydrogen, halogen, CM alkyl, CM alkoxy. CM haloalkoxy. CM alkylthio, CM haloalkylthio. Cualkylsulfuiyl, CM haloalkylsulfinyl, CM alkylsulfonyl, CM haloaikylsulfonyl, CM haloalkyl. cyano. nitro. CHO, CH=NOR5, CM alkylcarbonyl. CM alkoxycarbonyl or SFj; or together R1 and R2 form a five or six numbered saturated or unsaturaled carbocyclic ring, opdonally subsdruted by one or two CM alkyl groups; R1 is hydrogen, CM alkyl, CH2(CM haloalkyl). CM cyanoalkyl, CM alkenyl. CM alkynyl. CM alkoxy(C,. ,)alkyl, CM alkylthio(C,^)alkyl. CM alkoxy(CMWkoxy(CM)aIkyt. CM alkylcarbonyl, CM alkoxycarbonyl. formyl, CM alkylcarbonyl(CM)alkyl. CM alkoxycarbonyl(CM)alkyI, CMalkylaminocarbonyl. di(C,. t)alkylaminocarbonyl, optionally subsututed phenoxycarbonyl, opdonally subsututed phenyl(Ci^)alkyl or wherein X is O or S; n is 0 or 1; Y is O. S or NR7; R' is hydrogen, halogen, CM alkyl. CM haloalfcyl, CM S(O),R'; R* is hydrogen, halogen, cyano, CM alkyl, CM haloalkyl, CM cyanoalkyl, CM alkcnyl. Cw alkoxy. CM haloalkoxy. CM alkyllhio. CM haloalkylthio, CM cycloalkyl, CM alkoxy(CM>alkyl or SFS; R: alkynyt, CM cycloalkyl. CM halocycloalkyl. CM cyanocycloalkyl. C,.,alkyl(CM)cycloalkyl. C,.3 alfcyl(d- 7)halocycloalkyl. CM cycloalkyl(Ci-»)alkyl. CM cycloalkenyl, CM cycloalkenyl(CM)alkyl. CM haloalku^ d_icyanoalkcnyl. CM aUcoiy(C,^)alkyl. formyl, CM carboxyalkyl. CM alkylcarbonyl(CM)alkyl, CM alkoxycarbonyl(CM)alkyl, CM a!kylthio(CM)alkyl. CM alkylsulfmyl(CM)atkyl. CM alkylsulfonyKd. t)alkyl, «minocarbonyl(CM)alkyl. CMalkylaminocarbonyl(CM)alfcyl. di(CM)alkylaminocarbonyl(C,. i)alkyl, CM alkoxycarbonyl, CM alkylcarbonyl, aminocarconyl. CM alkylaminocarbonyl, di(Ci. <)alkylaminocarbonyl. opdonally subsdtuted phenyl, opdonally substituted phenyl(CM)alkyl, opdonally subsututed phenyUCwialkenyi, opdonally subsdtuted heteroaryl, opuonally subsututed heteroaryl(C|. 4)alkyl. opdonally subsdtuted hctcrocyclyl, optionally subsdtuted heterocyclyl(CM)alkyl, a group OR1, a group SH, a group S(Oyi', a group NR'V or a group C(R")=NOR'!; RJ is hydrogen. CM alkyl. opuonally subsututed phenyl or opdonally substituted phcnyKd j)alkyl; R* is CM alkyl. CM haloalkyl or opdonally subsutuled phenyl: R7 is hydrogen, cyano, CM alkyl, CM haloalkyt, CM cyanoalkyl, CM alkcnyl. CM alkynyl. CM cycloalkyl, CM haloalkenyl. CM cycloalkyl(CM)alkyl. CM alkoxy(d-i)alkyl. Ci4 alkoxycarbonyl. CM alkylcarbonyl. CMalkylaminocarbonyl, di(d.i)alkyUmtnocarbonyl, opdonally substituted phenyl or opuonally subsututed heteroaryl: R* is hydrogen, CM alkyl. CM haloalkyl, CM alkenyl. CM cyinoalkyl. CM alkoxycarbonyKC, Jalkyl. opdonally substituted phenyl. opdonally subsututed phenyl(d-<)alkyl. opdonally subsututed heteroaryl. N=C(CHj)i: R* is CM alkyl. C,_i haloalkyl. CM alkenyl, cyano, CM cyanoalkyl, CM alkoxycarbonyKd-Oalkyl, opuonally subsdtuted phenyl. opuonally subsdruted phenyl(d-<)*lkyl or opuonally subsdtuted heteroaryl: R'° and R" are. independently, hydrogen. CM alkyl, CM cycloalkyl, CM alkenyl. CM alkynyl. CM haloalkyl. CM alkoxy(CM)alkyl. CM alkoxycarbonyl, optionally subsdruted phenoxycarbonyl. formyl. CM alkylcarbonyl. CM alkylSCh. opuonally subsututed phenylSOj or optionally subsututed phenyl(CM)alkyl; R'! is C|.j alkyl; R" is CM alkyl, opuonally subsututed phenyl(C|.2)alkyl; and p and q are. independently, 0, I or 2.