Patent EA-002404-B1 (EA)
Title: Fungicidal mixture
Inventor: SCHELBERGER KLAUS
IPC: A01N43/40
Filed: 1998-06-02
Abstract: 1. A fungicidal composition comprising synergistically effective amounts of a.1) carbamates of formula I.a,   wherein X is CH or N, n is 0, 1 or 2, R is halogen, C1-C4-alkyl or C1-C4-haloalkyl, and the radicals R can be different when n is 2, or a.2) the oxime ether carboxamide of the formula I.b   and b.1) 4-[2-methyl-3-(4-tert-butylphenyl)-propyl]-2,6-dimethylmorpholine   or b.2) 4-(C10-C13alkyl)-2,6-dimethylmorpholine   and b.3) (RS)-1-[3-(4-tert-butylphenyl)-2-methylpropyl]-piperidine   and c) another active component selected from the group of strobilurine fungicide (III). 2. A fungicidal mixture defined in Claim 1, wherein strobilurine fungicide (III) is selected from the group of compounds, comprising phenylacetic acid methyl ester of formula III.1   wherein U is CHOCH3 or NOCH3, R<a> is cyano, halogen, C1-C4alkyl or C1-C4haloalkyl, x is 1, 2 or 3, and the radicals R<a> can be different when x is 2 or 3, and Y is OCH2 or O-(4,6-pyrimidinyl)-O, or benzyloxybisoxime of formula III.2   wherein the substituents have the following meanings A is OCH3 or NHCH3; B is CHOCH3 or NOCH3; R' is phenyl, which can carry from one to three substituents from the group, comprising cyano, halo, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy and C1-C4alkylthio; or C1-C6alkoxy, C1-C6alkylthio, C1-C6alkylamino, di-C1-C6alkylamino, C1-C6haloalkyloxy, C1-C6haloalkylthio, C1-C6haloalkylamino, N-C1-C6haloalkyl-N-C1-C4alkylamino, C3-C6alkenyloxy, C3-C6alkenylthio, C3-C6alkenylamino, N-C3-C6alkenyl-N-C1-C4alkylamino, C2-C6haloalkenyloxy, C2-C6haloalkenylthio, C2-C6haloalkenylamino, N-C2-C6haloalkenyl-N-C1-C4alkylamino, C3-C6alkynyloxy, C3-C6alkynylthio, C3-C6alkynylamino, N-C3-C6alkynyl-N-C1-C4alkylamino, C3-C6haloalkynyloxy, C3-C6haloalkynylthio, C3-C6haloalkynylamino, N-C3-C6haloalkynyl-N-C1-C4alkylamino, C3-C6cycloalkylmethoxy, C3-C6cycloalkylmethylthio, C3-C6cycloalkylmethylamino, N-C3-C6cycloalkylmethyl-N-C1-C4alkylamino, or benzyloxy, benzylthio, benzylamino, N-benzyl-N-C1-C4-alkylamino, wherein phenyl groups can be partly or fully halogenated and/or can carry from one to three radicals  from the group, comprising cyano, C1-C4alkyl, C1-C4haloalkyl, C1-C4alkoxy, C1-C4haloalkoxy and C1-C4alkylthio. 3. The fungicidal mixture defined in Claim 1, wherein the component I, salt or adduct thereof and the component II are present in a weight ratio of from 10:1 to 0.01:1. 4. The fungicidal mixture defined in Claim 1, wherein the component I, salt or adduct thereof and the component III are present in a weight ratio of from 10:1 to 0.01:1. 5. A method of controlling harmful fungi, which comprises treating the harmful fungi, their habitat, or plants, seeds, soils, areas, materials or spaces to be kept free from said fungi with the compound of formula I, one of salts or adducts thereof as defined in Claim 1 and the compound of formula II as defined in Claim 1 and the compound of formula III as defined in Claim 1. 6. A method of Claim 5 characterized in that the compound of formula I, one of salts or adducts thereof as defined in Claim 1 and the compound of formula II as defined in Claim 1 and the compound of formula III as defined in Claim 1 are applied simultaneously, that is either together or separately, or in succession. 7. The method of Claim 5 or 6, wherein the compound of formula I, one of salts or adducts thereof as defined in Claim 1 is applied in an amount of from 0.01 to 2.5 kg/ha. 8. The method of Claim 5 to 7, wherein the compound of formula II as defined in Claim 1 is applied in an amount of from 0.01 to 10 kg/ha. 9. The method of Claim 5 to 8, wherein the compound of formula III as defined in Claim 1 is applied in an amount of from 0.01 to 10 kg/ha. 10. The fungicidal compound, which is conditioned in two parts, a first part comprising compound of formula I in a solid or liquid carrier, and a second part comprising compound of formula II as claimed in Claim 1 in a solid or liquid carrier, and the first or the second part additionally comprising compound III of Claim 1. 11. The fungicidal compound, which is conditioned in three parts, a first part comprising compound of formula I as defined in Claim 1 in a solid or liquid carrier, a second part comprising compound of formula II as defined in Claim 1 in a solid or liquid carrier and a third part comprising compound of formula III as defined in Claim 1 in a solid or liquid carrier.