Patent EP-2065350-B1 (EP)
Inventor: HAMPEL CHRISTINA
IPC: C08F290/06
Filed: 2007-10-29
Granted: 2011-02-23
Abstract: Polymer (Q) with an ester group comprising at least an alkane structural unit (T), optionally at least a carbonyl group containing alkane structural unit (IV) and optionally at least a further structural unit (V), is new. Polymer (Q) with an ester group comprising at least an alkane structural unit (T) of formula (-(CH(R 2>)(R 3>)-CH(R 1>)(R 4>)) (I), (-(CH(R 2>)(R 6>)-CH(R 1>)(R 5>))-) (II) or (-(CH(R 2>)(R 8>)-CH(R 1>)(R 7>))-) (III), optionally at least a carbonyl group containing alkane structural unit of formula (-CH(R 2>)(R 3>)-CH(R 1>)(C(=O)-N(R 9>)(R 1> 0>)))-) (IV) and optionally at least a further structural unit (V), is new. R 1>H, CH 2COOM or 1-5C-alkyl; R 2>H, 1-5C-alkyl, COOM or CH 2COOM; either R 3>H, CH 3, COOM or CH 2COOM; and R 4>COOM; or R 3>R 4>CO-O-CO; M : H, 1-5C-alkyl, alkali metal, alkaline earth metal or other 2 or 3 valent metal atoms, ammonium and/or an organic ammonium group; R 5>-C(=O)-O-R 2> 0>; R 2> 0>[(R 1> 1>O) x-(R 1> 2>O) y-(R 1> 3>O) z]-R 1> 4>; R 1> 1>-R 1> 3>2-4C-alkylene group with an order of (R 1> 1>O)-, (R 1> 2>O)-, or (R 1> 3>O)-units in any possible sequence; R 1> 4>H, 1-12C-alkyl- or cycloalkyl, 7-20C-alkylaryl- or aralkyl, or optionally substituted aryl; either x, y, z : 0-250; or x+y+z : 3-250; R 6>H, CH 3, COOM, CH 2COOM or a substituent of R 5>or R 7>; R 7>a carbonyl residue of formula (-C(=O)-R 1> 5>-(R 1> 6>-O-C(=O)-R 1> 7>-C(=O)-O) q-R 1> 8>-O-R 1> 9>) (X1); q : 1-100; R 1> 5>O or O-(R 2> 7>) t; R 2> 7>1-12C-oxyalkylene group or one or more 2-4C-oxyalkylene groups with an order in any possible sequence; t : 1 (when R 2> 7>is 1-12C-oxyalkylene group) or 1-150 (when R 2> 7>is one or more 2-4C-oxyalkylene groups); R 1> 6>, R 1> 8>2-6C-alkylene group; R 1> 7>phenylene group or naphthylene group; R 1> 9>H, 1-12C-alkyl- or cycloalkyl, 7-20C-alkylaryl- or aralkyl, 2-12C-hydroxyalkyl, preferably CH 2CH 2-OH or -CH 2CH(OH)CH 3, optionally substituted aryl or -(R 2> 5>) s-R 2> 6>; R 2> 5>one or more 2-4C-oxyalkylene groups with an order in any possible sequence; s : 1-150; R 2> 6>H, 1-12C-alkylaryl or -aralkyl, 1-12C-alkyl- or cycloalkyl, 7-20C-alkylaryl or -aralkyl, or an optionally substituted aryl; R 8>H, CH 3, COOM, CH 2COOM or a substituent of R 5>or R 7>; either R 9>, R 1> 0>H, 1-20C-alkyl, 5-9C-cycloalkyl, 7-12C-aralkyl, OH, a group of formula (-R 2> 1>-X(R 2> 2>) r) (X2), a nitrogen containing group of formula (X3) or an oxy group of formula (-[(R11a-O) u-(R12aO) v-(R13aO) w]-R14a) (X4); or R 9>R 1> 0>a ring optionally containing O, S or N; R 2> 1>an alkylene group; R 2> 2>1-4C-alkyl; X : S, O or N; r : 1 (when X is S or O) or 2 (when X is N); R 2> 3>an alkylene group optionally with a heteroatom; R11a-R13a : 2-4C-alkylene group with an order of any sequence; R14a : 1-12C-alkyl- or cycloalkyl, 7-20C-alkylaryl, or an optionally substituted aryl; and either u, v, w : 0-100; or u+v+w : 1-100. Independent claims are included for: (1) an additive in liquid or solid form comprising (Q); (2) a binding agent comprising a mixture of at least a hydraulically binding agent and (Q) (0.01-10 wt.%); (3) the mixture comprising the binding agent, preferably cement, a latent hydraulic powder, one or more inert microscopic powders and/or gypsums; and (4) the preparation of the binding agent containing the mixture, comprising adding (Q) separately or as additive premix in solid or liquid form. [Image].