Patent EP-0234045-A2 (EP)
Inventor: HAMAGUCHI HIROSHI
IPC: C07D231/18
Filed: 1986-12-23
Abstract: A pyrazole oxime derivative represented by the general formula (I) which is useful as an insecticide, mitecide and fungicide,
     wherein R' represents C 1 -C 4  alkyl or phenyl; R 2  represents hydrogen, C 1 -C 5  alkyl, C 1 -C 3  haloalkyl or phenyl; R 3  represents hydrogen, C 1 -C 4  alkyl gr phenyl; R 4  represents hydrogen, C Z -C 4  alkylcarbonyl, benzoyl, naphthyl or a substituent of the formula.
     [in which X represents hydrogen; halogen; C 1 -C 12  alkyl; C 1 -C 6  alkyl substituted with halogen, cyano, hydroxy, C 1 -C 5  alkoxy or C 2 -C 6  alkoxycarbonyl; C 3 -C 8  cycloalkyl; cycloalkyl substituted with from one to three members selected from the group consisting of C 1 -C 4  alkyl, halogen and cyano; C 2 -C 4  alkenyl substituted with halogen, hydroxy, C 2 -C 4  alkoxycarbonyl or C 2 -C 6  alkylcarbonyl; phenyl; hydroxy; C 1 -C 6  alkoxy; C 1 -C 4  alkoxy substituted with halogen or C 2 -C 6  alkoxycarbonyl; phenoxy which may or may not be substituted with C 1 -C 3  haloalkyl benzyloxy; C 1 -C 3  alkylenedioxy formed by two adjacent Xs; pyridyloxy which may or may not be substituted with halogen or C 1 -C 3  haloalkyl; a substituent of the formula, -S(O) P R 5  (in which R 5  represents C 1 -C 6  alkyl, C 1 -C 5  haloalkyl or phenyl, and p represents an integer of 0, 1 or 2); cyano; formyl; nitro; a substituent of the formula -COOR s  (in which R 6  represents hydrogen; alkali metal; C 1 -C 10  alkyl; C 1 -C 5  alkyl substituted with halogen, C,-C 4  alkoxy, phenoxy, C 2 -C 4  alkoxycarbonyl or phenoxyphenyl; C 2 -C 7  alkenyl; C 3 -C 7  alkynyl; C 3 -C 8  cycloalkyl; C 3 -C 8  cycloalkyl substituted with C 1 -C 3  alkyl; phenyl; or a substituent of the formula,
       (in which R 7 , R 8  and R 9 , which may be the same or different, represent C 1 -C 4  alkyl or C 3 -C 8  cycloalkyl)}; C 2 -C 6  alkylcarbonyl; C 2 -C 6  alkylcarbonyl substituted with cyano or C 2 -C 6  alkoxycarbonyl; benzoyl which may or may not be substituted with halogen or C 1 -C 6  alkyl; C 2 -C 6  alkylthiocarbonyl; C 3 -C 7  alkoxycarbonylcarbonyl; a substituent of the formula,
     (in which R 10  and R", which may be the same or different, represent hydrogen, C 1 -C 6  alkyl or phenyl); piperidinocarbonyl; morpholinocarbonyl which may or may not be substituted with one or two C 1 -C 4  alkyls; a substituent of the formula,
     (in which R 12  represents hydrogen or C 1 -C 5  alkyl, and R 13  represents formyl, C 2 -C 12  alkoxycarbonyl, or C 2 -C S  alkoxycarbonyl substituted with halogen or C 1 -C 4  alkoxy); a substituent of the formula,
     (in which R 14  represents hydrogen, C 1 -C 4  alkyl or C 2 -C 6  alkoxyalkyl); a substituent of the formula,
     (in which R 15  and R 16 , which may be the same or different, represent C 1 -C 4  alkyl, or taken together, may form C 1 -C 4  alkylene, R 17  represents C 1 -C 5  alkyl, cyano or C 2 -C 6  alkoxycarbonyl, and B represents oxygen or sulfur); a substituent of the formula,
     (in which R 18  represents hydrogen or C 2 -C 4  alkylcarbonyl, and R 19  and R 20 , which may be the same or different, represent hydrogen or C 1 -C 6  alkyl); a substituent of the formula,
     (in which R 21 , R 22  and R 23 , which may be the same or different, represent C 1 -C 4  alkyl); or a substituent of the formula,
     (in which R 24 , R 25  and R 26 , which may be the same or different, represent C 1 -C 4  alkyl), and n represents an integer of from 1 to 5, and when n represents an integer of from 2 to 5, X may be the same or different ]; Y represents hydrogen, C 1 -C 6  alkyl, C 1 -C 4  haloalkyl, halogen, hydroxy, C,-C 4  alkoxy, C 1 -C 4  haloalkoxy, C 1 -C 3  alkylenedioxy, phenoxy which may or may not be substituted with trifluoromethyl, a substistuent of the formula, -S(Q) q R 27  (in which R 27  represents C 1 -C 3  alkyl and q represents an integer of 0, 1 or 2), hydroxycarbonyl, C 2 -C 5  alkoxycarbonyl or a substituent of the formula,
     (in which R28 and R 29 , which may be the same or different, represent hydrogen, C 1 -C 4  alkyl, or benzyl which may or may not be substituted with C 2 -C 6  alkoxycarbonyl); Z' represents oxygen or sulfur; Z 2  represents oxygen, sulfur or single bond; Q represents C 1 -C 8  alkylene, C 1 -C 8  alkylene substituted with halogen or phenyl, C 3 -C 12  alkenylene, C 3 -C 12  haloalkenylene or C 3 -C 6  alkynylene; and m represents an integer of from 1 to 3, and when m represents an integer of 2 or 3, Y may be the same or different; and the method of controlling said pests by using the same oxime derivative.