Patent GB-1040880-A (GB)
Title: Process and apparatus for forming chemical coatings on metal
IPC: C23C22/77
Filed: 1964-12-24
Abstract: Apparatus in which Al or Al alloy strip is chromated by treatment with an aqueous acidic solution containing CrO3, K fericyanide and fluoride ions comprises a conductivity cell which controls the flow of the chromating solution through a resin cation exchange bed to maintain the metal ion concentration low as described in Specification 846,363 and a second conductivity cell which controls the supply of replenishing liquid comprising concentrates of chromic and hydrofluoric acids and of K fericyanide.  The solution may also contain phosphate, sulphate, chloride, nitrate, arsenate, tungstate and selenate ions. Chromating of Zn and alloys of Mg, Cd, Cu, Ag, Zn and brass as described in Specification 840, 302 are referred to.  A continuous Al strip 12, Fig. 1 (not shown), passes through a tunnel 10 and is sprayed with the solution from nozzles 14 fed through pipe 20 by a pump 13 in a tank 16 to which the solution drains.  The pump also supplies a conductivity cell 28 and an associated temperature compensating device 32 which are connected to a unit 34 controlling electrically driven pumps 36, 38 in drums 40, 42 containing replenishing liquids.  Pipe 20 is also connected via a shut off valve 50 to cation exchange beds 52, 521 arranged in parallel, with remotely actuated valves 56, 561, 60, 601, at each inlet and outlet to the beds and a by-pass across each bed controlled by valves 64, 641.  Solution is passed through one bed and its by-pass, the flow through the bed being controlled by the position of the flow control valve 64 of 641.  Solution returns to tank 16, some being diverted through a second conductivity cell 72, and an associated temperature compensating device 74, both connected to unit 34 which controls the position of valve 64 or 641.  The proportion of solution passed through the bed is increased as its effeciency decreases until it becomes saturated, then the flow is stopped and directed to the other bed whilst the first bed is regenerated. Cells 28, 72 and devices 32, 74 are electrically connected by rotary switches 80, 82, Fig. 2, (not shown) to bridges 78, 84 both of which are connected to an A.C. source 98. The output of bridge 78 is fed to a primary transformer winding 101 which induces a voltage in the secondary winding 103 corresponding to the conductivity being measured. bridge 84 includes a split stator variable capacitor 88 mounted on a rotor 118 which is turned to an equilibrium position by a selsyn motor 116 in accordance with a signal from an unbalance voltage amplifier 110 passed through an unbalance detector circuit 112 and a push-pull power amplifier 114.  Rotor 118 carries arcuate contacts 122, 124 and contact bands 1201, 1202 which co-operate with brushes 126.  These are connected with a rotary selector switch 127, Fig.3 (not shown), and switches 132, 134 controlled by an eccentric 130 in a circuit which operates either of pumps 36, 38 or the motor of valve 64 via latching relays CR1, CR2.  Switch 127 and eccentric 130 are coupled to a Synchronous motor SM.  When valve 64 is completely closed and all the solution passes through the bed a cam 140 mechanically coupled to a valve 64 actuates a selector switch opening valves 56, 60 and closing valves 561 60.