Patent GB-844242-A (GB)
Title: Improvements in or relating to catalysts and catalytic conversion processes
Inventor: TURNER ROY
IPC: B01J23/85
Filed: 1956-02-03
Abstract: Unsaturated hydrocarbons are polymerized by passage in the vapour phase at elevated temperature over a catalyst (see Group III) prepared by depositing platinum, indium, palladium, rhodium, tantalum, tungsten, chromium oxide or molybdenum oxide on a high surface area amphoteric oxide which has had iron, cobalt or nickel deposited thereon and then been roasted at above 650 DEG C.  Suitable hydrocarbons are ethylene, propylene, butene-1 and-2 and higher mono-olefins, butadiene and other di-olefins, and styrene and other ethylenically unsaturated aryl alkyl hydrocarbons.  According to the Provisional Specification the catalyst component deposited in the final stage may be any catalyst of known activity for effecting the hydrogenation of unsaturated hydrocarbons and may be a Group VIII metal.ALSO:Substituted and unsubstituted hydrocarbon conversion processes are effected in the presence of a catalyst (see Group III) prepared by depositing platinum, indium palladium, rhodium, tantelum, tungsten, chromium oxide, or molybdenum oxide on a high surface area amphoteric oxide which has had iron, cobalt or nickel deposited thereon and then been roasted at above 650 DEG C.  Such processes take place in the vapour phase at elevated temperature with or without added hydrogen.  Processes mentioned are the dealkylation of alkyl aromatics, e.g. toluene, the xylenes, cumene, mesitylene, psuedo-cumene and diethyl benzene, at 250 to 500 DEG C. and up to 200 p.s.i.g.; and the hydrogenation of unsaturated compounds, e.g. ethylene, propylene, butenes, butadienes, pentenes, hexenes, di-isobutylene, propylene dimer and trimer, benzene, toluene, xylenes, ethyl benzene, cumene, pseudo-cumene, mesitylene, diphenyl, naphthalene, unsaturated fatty acids such as oleic and linoleic, unsaturated alcohols and unsaturated esters, at 150 to 400 DEG C. and up to 1000 p.s.i.g. Examples describe the demethylation of toluene. According to its Provisional Specification the catalyst component deposited in the final stage may be any catalyst of known activity for the hydrogenation of unsaturated hydrocarbons and may be a Group VIII metal.ALSO:Catalysts are prepared by (i) depositing nickel, cobalt or iron, in elemental or combined form on an amphoteric oxide in a form having a surface area greater than 10 sq. m./g. (or a form capable of conversion thereto by heat); (ii) roasting at above 650 DEG C. to form a "catalyst base"; and (iii) depositing platinum, indium, palladium, rhodium, tantalum, tungsten, chromium oxide or molybdenum oxide on the "catalyst base".  The amphoteric oxide may be alumina in the form of a wet or dry gel, in which case the roasting should not be sufficient to convert it to alpha alumina. The metal may be deposited in step (i) by impregnation with an aqueous solution of a salt, e.g. nitrate, formate or acetate, which is decomposed to the oxide by heat.  The deposition in step (iii) may be effected by any known method e.g. platinum by impregnation with a solution of tetra amine platinous chloride and chromium oxide or molybdenum oxide by impregnation with chromium nitrate or ammonium molybdate followed by heating.  After step (iii) the catalyst may be roasted at 350 to 650 DEG C. for 1 to 10 hours and reduced with hydrogen at 330 to 600 DEG C. for 2 to 48 hours.  Examples describe the preparation of platinum or molybdenum oxide on nickel/alumina catalysts.  The catalysts may be used for cracking, hydrogenating and polymerizing substituted and unsubstituted hydrocarbons (see Groups IV(a) and IV(b)).  According to the Provisional Specification the component deposited in step (iii) may be any catalyst of known activity for effecting the hydrogenation of unsaturated hydrocarbons and may be a Group VIII metal.