Patent GB-1048982-A (GB)
Title: Metal-containing additions for the improvement of polyurethane foams
IPC: C08J9/00
Filed: 1963-05-07
Abstract: Metal dihydrocarbyl dithiocarbamates of formula <FORM:1048982/C2/1> wherein each R individually can be alkyl, aryl, alkaryl or aralkyl; n is an integer of 2 to 4; and M represents a metal of valence n, which may be Mn, Fe, Co, Ni, Cu, Zn, Cd, Hg, Pb, Sn, As, Sb, or Bi, are prepared by reacting an appropriate dihydrocarbylamine with carbon disulphide to give the corresponding dihydro-carbyldithiocarbamic acid, which acid may then be reacted with the metal hydroxide to give the aforesaid salt.  The reaction may be carried out in a one step process.  The metal dihydro-carbyldithiocarbamates are used as additives to polyols when preparing polyurethane foams (see Division C3).ALSO:A composition of a polyol or polyols suitable for use in the preparation of polyurethane foams comprises not more than 0.15% of the weight of polyol of a metal dihydrocarbyldithiocarbamate of structure:  <FORM:1048982/C3/1> wherein each R individually can be alkyl, aryl, alkaryl or aralkyl, n is an integer of 2 to 4, and M is a metal of valence n which may be: Mn, Fe, Co, Ni, Cu, Zn, Cd, Hg, Pb, Sn, As, Sb or Bi.  R is suitably a C1 to C10 alkyl group, C1-C5 groups being preferred, and the most suitable metals are divalent Zn, Pb, or Cd, Pb being preferred.  The metal dihydrocarbyldithiocarbamates can be prepared by known methods, such as reaction of dialkyl amines with CS2, to give the corresponding dialkyldithiocarbamic acid, which is then reacted with an appropriate metal hydroxide (see Division C2).  Suitable polyols contain major amounts of polyoxyalkylene polyols having 2 to 3 alcoholic -OH groups, with oxyalkylene moieties of a preferred 2C to 4C content. Minor amounts (below 50% by weight) of other polyols may be present, e.g. polyhydroxyalkanes, trialkanolamines, and their alkylene oxide adducts, and similar adducts of mono-and poly-amines, non-reducing sugars and their derivatives, and polyphenols.  The polyols should desirably have an -OH number of 25 to 1000, preferably from 35-90. The metal dihydrocarbyldithiocarbamates are used in admixture with the polyols in proportions of not more than 0.15% of the weight of polyol, i.e. 100 to 1500 p.p.m., preferably from 500 to 1100 p.p.m. The polyol composition is used to prepare polyurethane foams by reaction with conventional isocyanates by known procedures, preferably by "one-shot" techniques, with the use of water and/or blowing agents typical of those used in the art. Known polymerization catalysts are usually employed, as are other known additives, namely emulsifying agents and antioxidants.  Four examples comparing the physical properties of "green" foams, and foams cured under wet and dry conditions, with and without zinc or cadmium dihydrocarbyldithiocarbamate are given, and eleven examples comparing physical properties similarly, but employing varying proportions of the zinc or lead compounds, both together and separately. The use of these compositions is to provide polyurethane foams which do not lose load-bearing capacity if cured in humid conditions, and have better load-bearing capacity than usual if cured in dry conditions.