Patent EA-002085-B1 (EA)
Title: Pesticidal 1-arylpyrazoles derivatives
Inventor: PHILLIPS JENNIFER
IPC: C07D231/12
Filed: 1997-12-18
Abstract: 1. A method of control of insects selected from aphids, plant bugs and stinkbugs by means of application of an insecticidally active ingredient having a 1 -arylpyrazole group to a locus where insects are present or expected to be present, characterized in that said active ingredient is a compound which is selected from: 3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4methylsulfinylpyrazole; 3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylthiopyrazole; 3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-ethylsufinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-ethylamino-4- methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-methylamino-4- methylsulfinylpyrazole; 3-acetyl-5-(2-carbamoylmethylamino)- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-(2-ethylsulfonylethylamino)-4- methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-(2-carbamoylethylamino)-4- methylsulfinylpyrazole; 3-acetyl-5-amino- 1 -(2-bromo-6-chloro-4-trifluoromethylphenyl)-4- methylsulfinylpyrazole; 3-acetyl- 1-(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinyl-5- trifluoromethylsulfenylaminopyrazole; 3-acetyl-5-amino-l -(2,6-dichloro-4-pentafluorothiophenyl)-4methylsulfinylpyrazole; and 3-acetyl-5-amino- 1 -(2,6-dichloro-4-pentafluorothiophenyl)-4-methylthiopyrazole. 2. A pesticidal compound which comprises a compound selected from: 3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinylpyrazole; 3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylthiopyrazole; 3-acetyl-5-amino- 1 -(2,6-dichloro4-trifluoromethylphenyl)-4-ethylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro4-trifluoromethylphenyl)-5-ethylamino-4- methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-methylamino-4- methylsulfinylpyrazole; 3-acetyl-5-(2-carbamoylmethylamino)- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4- methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-(2-ethylsulfonylethylamino)-4- methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-(2-carbamoylethylamino)-4- methylsulfinylpyrazole; 3-acetyl-5-amino- 1 -(2-bromo-6-chloro-4-trifluoromethylphenyl)-4- methylsulfinylpyrazole; 3 -acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinyl-5- trifluoromethylsulfenylaminopyrazole; 3 -acetyl-5-amino- 1 -(2,6-dichloro-4-pentafluorothiophenyl)-4-methylsulfinylpyrazole; or 3-acetyl-5-amino- 1 -(2,6-dichloroA-pentafluorothiophenyl)-4-methylthiopyrazole. 3 A compound which is  3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinylpyrazole; 3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylthiopyrazole; 3-acetyl-5-amino- 1 -(2,6-dichloro4-trifluoromethylphenyl)-4-ethylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro4-trifluoromethylphenyl)-5-ethylamino-4-methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-methylamino-4- methylsulfinylpyrazole; 3-acetyl-5-(2-carbamoylmethylamino)- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4- methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-(2-ethylsulfonylethylamino)-4- methylsulfinylpyrazole; 3-acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-5-(2-carbamoylethylamino)-4- methylsulfinylpyrazole; 3-acetyl-5-amino- 1 -(2-bromo-6-chloro-4-trifluoromethylphenyl)-4- methylsulfinylpyrazole; 3 -acetyl- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinyl-5- trifluoromethylsulfenylaminopyrazole; 3 -acetyl-5-amino- 1 -(2,6-dichloro-4-pentafluorothiophenyl)-4-methylsulfinylpyrazole; or 3-acetyl-5-amino- 1 -(2,6-dichloroA-pentafluorothiophenyl)-4-methylthiopyrazole. 4. A compound of claim 3, which is  3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylsulfinylpyrazole; or 3-acetyl-5-amino- 1 -(2,6-dichloro-4-trifluoromethylphenyl)-4-methylthiopyrazole.