Patent GB-939464-A (GB)
Title: Synthetic resins
IPC: C08G18/36
Filed: 1961-05-31
Abstract: The invention comprises reaction products of polyhydroxy compounds with polyisocyanates and, if desired, cross-linking agents, which products contain tall oil in an amount of not less than 10 parts by weight of tall oil per 100 parts of reaction product.  The tall oil can be incorporated by admixture with one or more of the reactants before or during the preparation, or can be incorporated in the reaction product after its production.  In a preferred embodiment a polyhydroxy compound of M.W. above 500 and OH number between 25 and 600 is reacted with a polyisocyanate at an NCO:OH ratio between 1,5 and 5 and the product is reacted with a cross-linking agent such as butanediols, castor oil, bis-b -hydroxyethyldiamine or N,N,N1,N1-tetrakis-(2-hydroxypropyl) ethylene diamine to which the tall oil is added.  As another feature the tall oil can be introduced into a kneader in which the hydroxy compound and polyisocyanate have reacted and the crumbly mass is reacted further with cross-linking agent or polyisocyanate in a rubber mill and the mass is then moulded.  Coatings can be produced by effecting the reaction in a solvent such as xylene, toluene, ethyl acetate and ethylene glycol monoethyl ether acetate.  They can be pigmented with titanium dioxide, iron oxide, copper black, zinc oxide or chromium oxide. Foamed products are obtained by reaction in the presence of water or halogenated hydrocarbon, heat liberated causing reaction also of the tall oil with the polyisocyanate.  In Examples 2 to 31 castings are prepared from prepolymers selected from (A) a reaction product of 4,41-diphenylmethane diisocyanate and a glycol/adipic acid polyester; (B) a toluene 2:4- and 2:6-diisocyanate reacted 1,2,6-hexanetriol/propylene oxide reaction product; (C) as in (B) with the co-reaction of a linear polypropylene ether glycol; (D) a polythiodiglycol/4,41-diphenylmethane diisocyanate reaction product. The prepolymers are reacted in the presence of various tall oils with a second component selected from 1,4-butanediol; N,N,N1,N1-tetrakis-(2-hydroxyethyl- or propyl) ethylene diamine; a polyester from adipic acid, diethylene glycol and trimethylol propane; a polyester from phthalic anhydride, adipic acid and hexanetriol; propylene oxide reaction product of trimethylol propane, piperazine or sorbitol; castor oil.  Foamed products are prepared by reacting (33) a mixture of tall oil, sorbitol/propylene oxide reaction product, tolylene 2,4- and 2,6-diisocyanates, in the presence of N,N,N1,N1-tetramethyl-1,3-butane diamine, a silicone containing polyoxyethylene and polyoxypropylene units, stannous octoate and trichlorofluoromethane; (34) a similar mixture in which, however, a 1,2,6-hexanetriol-propylene oxide reaction product is used.  Specifications 700,610 and 769,682 are referred to.ALSO:The invention comprises reaction products (including cellular products) of polyhydroxy compounds with polyisocyanates and, if desired, cross-linking agents, which products contain tall oil in an amount of not less than 10 parts by weight of tall oil per 100 parts of reaction product.  The tall oil can be incorporated by admixture with one or more of the reactants before or during the prepartaion or can be incorporated in the reaction product after its production.  In a preferred embodiment a polyhydroxy compound of M.W. above 500 and OH number between 25 and 600 is reacted with a polyisocyanate at an NCO : OH ratio between 1,5 and 5 and the product is reacted with a cross-linking agent such as butanediols, castor oil, bisb - hydroxyethyl diamine or N, N, N1, N1- tetrakis (2- hydroxypropyl ethylene diamine to which the tall oil is added.  Foamed products are obtained by reaction in the presence of water or halogenated hydrocarbon, heat liberated causing reaction also of the tall oil with the polyisocyanate.  In examples foamed products are prepared by reacting, 33, a mixture of tall oil, sorbital/propylene oxide reaction product and tolylene 2, 4- and 2, 6-diisocyanates in the presence of N, N, N1, N1-tetramethyl -1, 3- butane diamine, a silicone containing polyoxyethylene and polyoxypropylene units, stannous octoate and tri-chloro-fluoromethane; (34) a similar mixture in which, however, a 1, 2, 6- hexanetriol/propylene oxide reaction product replaces the sorbitol/propylene oxide reaction product. Specifications 700,610 and 769,682 are referred to.