Patent GB-395291-A (GB)
Title: Improvements in and relating to the manufacture of artificial masses
IPC: C08F8/20
Filed: 1933-02-20
Abstract: Artificial masses are manufactured by treating polymers of acrylic acid, its derivatives or homologues, or mixtures thereof, obtained by combination of completed polymers or by combined polymerization, with chlorine, with or without the application of heat or pressure or both, and with or without stirring or agitation.  The chlorination is generally carried out with the polymers in the solid state, e.g. in the form of films, or in solution in solvents which do not react with chlorine or do so only slowly, e.g. chlorinated hydrocarbons such as chloroform, trichlorethylene, carbon tetrachloride or tetrachlorethane, but may also be performed otherwise, e.g. in emulsion.  The absorption of chlorine may be accelerated by the action of light or by the presence of known halogenation catalysts, e.g. metals or metallic salts, preferably iron, non-metals or metalloids such as bromine, iodine, phosphorus, arsenic or sulphur or mixtures thereof.  Especially suitable for chlorination are the polymerized compounds of acrolein, acrylic acid and a -substituted acrylic acids, e.g. a -chloracrylic acid or methacrylic acid, and their p  esters, chlorides, nitriles, amides and anhydrides.  The products may be used for the production of artificial materials such as lacquers, films, intermediate layers for safety glass, articles for electro-technology, threads, artificial leather, oil-cloth, artificial silk, fabrics, sacks, elastic and transparent bandages, handles for knives, umbrellas or brushes, buttons, buckles, billiard balls, drinking cups, playing discs, gramophone records, tooth brushes, rulers, fountain pens, dentures and other dental articles, shoe soles and floor coverings.  They may be mixed at any stage in their production with other chlorinated or non-chlorinated polymers, or other organic or inorganic additional substances such as linseed oil, cellulose derivatives, softening agents such as phthalic acid esters, fillers such as soot, kaolin and dyestuffs.  Examples describe the action of chlorine on: (1) polymerized acrylic acid methyl ester in chloroform solution in the presence of light; (2) polyacrylic acid in aqueous solution; (3) a film of polymerized acrylic acid methyl ester; (4) polymerized acrylic acid methyl ester of low viscosity in chloroform solution in the presence of iron, while heating on the water bath and stirring; (5) polymerized methacrylic and ethyl ester in chloroform solution; (6) polymerized acrylic acid methyl ester in chloroform solution in the presence of sodium carbonate. A lacquer is prepared by dissolving the product of (1) together with polymerized acrylic acid butyl ester in ethyl acetate with the addition of titanium white.ALSO:As constituents of lacquers may be employed chlorination products of polymers of acrylic acid, its derivatives or homologues or mixtures thereof, with or without other polymers or other organic or inorganic additional substances such as linseed oil, cellulose derivatives, softening agents such as phthalic acid esters, fillers such as soot, kaolin and dyestuffs.  In an example the chlorination product of polymerized acrylic acid methyl ester is dissolved together with polymerized acrylic acid butyl ester in ethyl acetate with the addition of titanium white.