Patent GB-1384902-A (GB)
Title: Diorganopolysiloxane impression compositions and their use
Inventor: NITZSCHE S
IPC: C08L83/04
Filed: 1972-02-10
Abstract: 1384902 Organopolysiloxanes WACKERCHEMIE GmbH 10 Feb 1972 [12 Feb 1971] 6268/72 Heading C3T A composition for use as an impression composition for the production of moulds comprises a curable diorganopolysiloxane, a cross-linking agent, a condensation catalyst, a reinforcing filler having a surface area of at least 50 m.<SP>2</SP>/g., preferably in an amount of up to 20% wt. based on the total organosiloxane content and a polyglycol which may be etherified and/or esterified. Preferred diorganopolysiloxanes have the formula (HO) x SiR y O (4-y)/2 ) n H where R is a monovalent optionally substituted hydrocarbon radical, x=0À99-1À01, y=1À99- 2À01, (x+y)=3 and n is at least 50. Some of the Si-bonded hydroxyl groups can be partially replaced by other groups capable of condensation, e.g. oxime, alkoxy or alkoxyalkoxy. Preferably 50% of R are methyl radicals, the remainder preferably being phenyl and/or vinyl radicals. Preferred cross-linking agents are hexaethoxydisiloxane, tetraethyl silicate, polyethyl silicate containing 40% wt. of SiO 2 , 1,1,1 - trimethyl - 3,3,3 - triethoxydisiloxane, and methylhydrogenopolysiloxanes. Preferred condensation catalysts are organo-tin salts such as dibutyltin dilaurate and dibutyl-tin salts of aliphatic carboxylic acids which are branched in the alpha-position to the carboxyl group and possess 9-11 carbon atoms. Preferred reinforcing fillers are SiO 2  produced pyrogenically in the gas phase, SiO 2  aerogel, a precipitated SiO 2  and metal oxides such as TiO 2 , Fe 2 O 3 , Al 2 O 3  and ZnO, the surfaces of which fillers may be treated with trimethylmethoxysilane or hexamethyldisilazane. The reinforcing fillers may be used in an amount of 3-60% wt. based on the organopolysiloxane content, The polyglycol component may be (1) a polyglycol ether of formula RO[(CHR<SP>1</SP>) m O] n <SP>1</SP>H wherein R is a monovalent optionally substituted hydrocarbon radical, R<SP>1</SP> is hydrogen or an alkyl radical, m= 2-5, n<SP>1</SP>=2-100, or (2) a polypropylene oxidepolyethylene-oxide condensate, or (3) an organopoly - siloxane - polyoxyalkylene copolymer preferably of the formula where R is as defined above, p=1-50, A is a radical of the formula -[(CHR<SP>1</SP>) m O] n <SP>1</SP>R<SP>11</SP> where R<SP>11</SP> is hydrogen, a monovalent hydrocarbon radical, an acyl radical, a triorganosilyl radical, a diorgano-(hydrocarbonoxysilyl) radical or a radical of the formula  where B is -SiR 3 , A or -Si(R) 2 A. The polyglycol component is preferably used in an amount of 0À5-30% by weight based on the curable organopolysiloxane content. Optional ingredients include an inert liquid organopolysiloxane as plastieizer; a non-reinforcing filler having a surface area less than 50 m.<SP>2</SP>/g. such as quartz powder, diatomaceous earth, calcium or zirconium silicate, CaCO 3  and calcined aluminium silicate; asbestos, glass fibres and/or organic fibres. In the examples the compositions comprise an hydroxyl terminated dimethylpolysiloxane, pyrogenic SiO 2 , hexaethoxydisiloxane, dibutyl-tin dilaurate and (1) a trimethylsiloxy end-blocked dimethylpolysiloxane as plasticizer, quartz powder, the organopolysiloxanepolyoxyalkylene block copolymer of the formula  (2) a tributyl phenol etherified with a polyethylene.glycol of 13 ethylene oxide units, (3) the plasticizer of Example 1 and the etherified tributyl phenol of Example 2.