Patent TW-357054-B (TW)
Title: Benzylsulfide derivative, process for its production and pesticide
Inventor: TORIYABE KEIJI
IPC: A01N37/28
Filed: 1996-04-26
Granted: 1999-05-01
Abstract: A benzylsulfide derivative or salts thereof of formula (I), in which R1 is C1-6 alkyl, C1-4 cyanoalkyl, C1-4 hydroxyalkyl, C3-6 cycloalkyl, C1-6 haloalkyl, C2-4 ene, C2-4 alkyne, phenyl (substitutable by halogen atom or C1-4 alkyl), cyano, benzyl (substitutable by halogen atom), thiazolyl, C1-4 alkylaminoformyl, or a group with formula -N(R5)r6; R2 and R3 individually are hydrogen atom, halogen atom, cyano, C1-4 alkyl, C1-3 haloalkyl, C1-4 alkylthio, C1-4 alkylcarbonyl, carboxyl, or C1-4 alkoxycarbonyl; or R2 or R3 can form a 3- to 6-member ring with the linked carbon atom; or R1 and R2 can form 3- to 8-member ring having one or more heteroatoms with respectively bonded sulphur atom and carbon atom; R4 is hydrogen, halogen, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy or C1-4 haloalkoxy; R5 and R6 are respectively hydrogen atom, C1-6 alkyl or C1-4 haloalkyl; or R5 and R6 can form 4- to 8-member ring having one or more heteroatoms with respectively linked carbon atom; A is hydrazine arylalkyl having formula (A1) or (A2), where R9 is hydrogen, halogen, nitro, cyano, C1-4 alkyl, C1-4 haloalkyl, C1-4 alkoxy, C1-4 haloalkyoxy, C1-4 alkylthio, C1-4 haloalkylthio, C1-4 alkylsulfuryl, C1-2 alkylsulfurylmethyl, C1-4 haloalkylsufuryloxy, phenyl (substitutable by halogen atom or phenyloxy (substitutable by halogen atom); or two R9 together can form 5 or 6-member ring; R10 is hydrogen or C1-4 alkyl; R11, R12 and R13 are respectively hydrogen, cyano, C1-4 alkyl, C1-4 haloalkyl, C2-10 alkoxyalkyl, C3-8 alkoxyalkoxyalkyl, C2-6 alkylthioalkyl, C2-6 alkenyl, C2-4 alkyne, C1-4 cyanoalkyl, benzyl (substitutable by halogen atom, C1-4 haloalkyl or C1-4 alkyl), -COR14, -CSR14, -COOR15, COSR15, -CON(R16)R17, -CSN(R16)R17, -SN(R18)R19, -SO2R20 or -C(R21)=CNR22, or R12 and R13 can form a 5- to 6-member ring respectively with the linked nitrogen atom; R14 is hydrogen atom, C1-20 alkyl, C1-8 haloalkyl, C2-12 alkoxyalkyl, C2-10 haloalkoxyalkyl, C3-16 alkoxyalkoxyalkyl, C4-22 alkoxyalkoxyalkoxyalkoxy, C2-6 alkylthioalkyl, C3-6 cyclalkyl, C1-6 hydroxyalkyl, C1-6 aminoalkyl, C1-6 amidealkyl, C1-8 cyanoalkyl, C3-12 alkoxycarbonyl alkyl, C2-6 ene, C2-4 alkyne, phenyl (substitutable by halogen atom, nitro, C1-4 alkyl, C1-4 haloalkyl, phenoxy or C1-4 alkoxy), nathphyl (substitutable by halogen atom or C1-4 alkyl), or heteroaromatic ring group of 4- to 8-member ring ocntaining a nitrogen, oxygen or sulfur atom (substitutable by halogen atom or C1-4 alkyl); R15 is C1-20 alkyl, C2-8 haloalkyl, C2-12 alkyalkyalkyl, C2-6 ene, C2-4 alkyne, benzyl (substitutable by halogen atom, C1-4 alkoxy or C1-4 alkyl); R16 is hydrogen or C1-4 alkyl; R17 is hydrogen, C1-6 alkyl or phenyl (substitutable by halogen atom, C1-4 haloalkoxy or C1-4 alkyl); R18 and R19 are respectively C104 alkyl (substitutable by C1-4 alkoxycarbonyl), or C1-5 alkoxyalkyl; or R18 and R19 can form a 5- to 6- member ring together with their bonded nitrogen respectively^ R20 is C1-4 alkyl, C104 haloalkyl or C2-4 dialkylamino; R21 is hydrogen or C1-6 alkyl; R22 is C2-4 acryl or C2-6 alkoxycarbonyl; R23 and R24 are respectively hydrogen atom, halogen atom, C1-6 alkyl or -N(R25)R26; R25 and R26 are respectively hydrogen, C1-4 alkyl, C1-4 alkoxy, C2-22 alkoxyalkyl or -SOwR27, or R25 and R26 can form a 5- to 6-member ring with their bonded nitrogen respectively; R27 is C1-8 alkyl or phenyl (substitutable by halogen atom or C1-4 alkyl); Q1 and Q2 are respectively nitrogen atom or -CR9; m is an integer from 1 to 3; nad n is 0, 1 or 2.