Patent GB-1088406-A (GB)
Title: Paper coating compositions
Inventor: MACGUGAN IAN CAMPBELL
IPC: D21H19/62
Filed: 1966-04-14
Abstract: A paper coating colour composition comprises a pigment, an adhesive, and 0.1-1% by weight, based on the pigment weight, of a polyalkylene oxide condensation product of general formula R(-X-Z-H)x, wherein R is the radical resulting from the removal of H from each OH group of an aliphatic polyhydric alcohol having x hydroxyl groups and up to 6 carbon atoms, x being at least 2, X is a hydrophobic polyalkyleneoxy chain having an O : C atom ratio 0.40, the MW of X and the value of x being such that the molecule excluding Z has a MW between 400 and 25,000, and Z is an hydrophilic heteric polyalkyleneoxy chain which contains ethyleneoxy groups and at least 5% weight higher molecular weight alkyleneoxy groups and which has an average O : C atom ratio > 0.40, Z being 5-90% by weight of the compound R(-X-Z-H)x.  Suitable pigments are clay, T.O2 or CaCO3 and adhesives, starch or protein e.g. casein, the adhesive usually constituting 5-50% by weight, based on the pigment.  The polyol acts as a lubricant.ALSO:An additive for pigmented paper coating compositions comprises a heteric polyol of general formula R(-X-Z-H)x, wherein R is the radical resulting from the removal of H from each OH group of an aliphatic polyhydric alcohol having x hydroxyl groups and up to 6 carbon atoms, x being at least 2, X is a hydrophobic polyalkyleneoxy chain having an O:C atom ratio \sO 0.40, the M.W. of X and the value of x being such that the molecule excluding Z has a M.W. between 400 and 25,000, and Z is a hydrophilic heteric polyalkyleneoxy chain which contains ethyleneoxy groups and at least 5% by weight higher molecular weight alkyleneoxy groups and which has an average O:C atom ratio >0.40, Z being 5-90% by weight of the compound R(-X-Z-H)x.  Preferred polyols are prepared by condensing a polyhydric alcohol with a hydrophobic ingredient containing 70-100 weight per cent propylene oxide and 30-0% by weight ethylene oxide to obtain a condensation product having a M.W. 500-4000 and further condensing the first-obtained product with a hydrophilic ingredient containing 70-95% by weight ethylene oxide and 30-5% by weight propylene oxide to obtain a heteric polyol having a M.W. 1500-8000. Specific polyols within this field are exemplified. Suitably polyhydric alcohol starting materials include ethylene, propylene and the butylene glycols, 1,5-pentane-diol, 1,6-hexanediol, glycerol, trimethylolpropane, sorbitol, pentaerythritol and sucrose.ALSO:A paper coating colour composition comprises a pigment, an adhesive and 0.1 - 1% by weight, based on the pigment weight, of a heteric polyalkylene oxide condensation product of general formula: R(-X-Z-H)x wherein R is the radical resulting from the removal of H from each OH group of an aliphatic polyhydric alcohol having x hydroxyl groups and up to 6 carbon atoms, x being at least 2, X is a hydrophobic polyalkyleneoxy chain having an O:C atom ratio not greater than 0.40, the M.W. of X and the value of X being such that the molecule excluding 2 has a M.W. 4000 - 25000, and Z is a hydrophilic heteric polyalkyleneoxy chain which contains ethyleneoxy groups and at least 5% by wt. higher M.W. alkyleneoxy groups and which has an average O:C atom ratio not greater than 0.40, 2 being 5 - 90% by weight of the compound R(-X-2-H)x.  The composition is coated on to paper by standard procedures which are not specified.