Patent SG-11201808679W-A (SG)
Title: A synthetic zeolite comprising a catalytic metal
Inventor: CORMA CANOS AVELINO
IPC: C07C5/09
Filed: 2017-05-24
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property MD HIM 0 11101 HOE 010 1111 1 0 01 010 1101 010 111111111011110 1111 MI Organization International Bureau (10) International Publication Number (43) International Publication Date ......0\"\"1 WO 2017/202495 Al 30 November 2017 (30.11.2017) WIPO I PCT (51) International Patent Classification: SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, B01J 29/50 (2006.01) CO1B 3 9 / 4 8 (2006.01) TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. BO1J 29/52 (2006.01) BO1J 29/84 (2006.01) BO1J 29/54 (2006.01) BO1J 29/85 (2006.01) (84) Designated States (unless otherwise indicated, for every BO1J 29/56 (2006.01) BO1J 29/86 (2006.01) kind of regional protection available): ARIPO (BW, GH, BO1J 29/58 (2006.01) BO1J 29/87 (2006.01) GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, BO1J 29/70 (2006.01) BO1J 29/88 (2006.01) UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, BO1J 29/72 (2006.01) BO1J 29/89 (2006.01) TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, BO1J 29/74 (2006.01) BO1J 35/00 (2006.01) EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, BO1J 29/76 (2006.01) CO7C 5/09 (2006.01) MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, BO1J 29/78 (2006.01) BO1J 20/18 (2006.01) TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). (21) International Application Number: PCT/EP2017/000621 Published: (22) International Filing Date: — with international search report (Art. 21(3)) 24 May 2017 (24.05.2017) — before the expiration of the time limit for amending the claims and to be republished in the event of receipt of (25) Filing Language: English amendments (Rule 48.2(h)) (26) Publication Language: English (30) Priority Data: 62/340,768 24 May 2016 (24.05.2016) US 16183679.6 11 August 2016 (11.08.2016) EP = Applicant (for all designated States except US): EXXON- = (71) MOBIL CHEMICAL PATENTS INC. [US/US]; 5200 _ Bayway Drive, Baytown, TX 77520-2101 (US). Inventors; and (72) _ (71) Applicants (for US only): CORMA CANOS, Avelino [ES/ES]; Camino de Vera, 46022 Valencia (ES). GUZ- = MAN, Javier [US/US]; 2134 Overlook Circle, Easton, PA 18045 (US). MOLINER MARIN, Manuel [ES/ES]; = = Camino de Vera, 46022 Valencia (ES). SERNA MERINO, = Pedro [ES/US]; 102 Red Crest Ln, Branchburg, NJ 08876 (US). STROHMAIER, Karl G. [US/US]; 47 Rockport = = = Road, Port Murray, NJ 07865 (US). Agent: TROCH, Genevieve; Hermeslaan 2, 1831 Mache- len (BE). (74) _ Designated States (unless otherwise indicated, for every (81) = kind of national protection available): AE, AG, AL, AM, = — AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, = CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, — DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, = _ 1-1 in 0\ 71' ei © (54) Title: A SYNTHETIC ZEOLITE COMPRISING A CATALYTIC METAL ei ---- (57) : A small pore size synthetic zeolite having a degree of crystallinity of at least 80% and comprising at least 0,01 wt% IN based on the weight of the zeolite of at least one catalytic metal selected from the group consisting of Ru, Rh, Pd, Ag, Os, Ir, Pt, Au, C::::) Mo, W, Re, Co, Ni, Zn, Cr, Mn, Ce, Ga and combinations thereof, wherein at least 80% of the catalytic metal is encapsulated in the N zeolite, wherein if the zeolite is an aluminosilicate it has a Si0 2 :A1 2 0 3 molar ratio of greater than 6:1. C