Patent GB-1096066-A (GB)
Title: Improvements in or relating to electrodeposition
IPC: C09D161/20
Filed: 1965-04-29
Abstract: A method for coating and insulating a metal substrate comprises passing electric current between an electrically conductive metal anode and an electrically conductive cathode in contact with a water-dispersed coating composition comprising (a) from 95-50%, by weight of (a) and (b), of an at least partially neutralized interpolymer of from 1-20% by weight of a hydroxyalkyl ester of an a , b - ethylenically unsaturated carboxylic acid, from 1-20% by weight of an ethylenically unsaturated carboxylic acid, and at least one other copolymerizable ethylenically unsaturated monomer; and (b) from 5-50%, by weight of (a) and (b), of an amine - aldehyde condensation product and/or a polyepoxide, whereby there is deposited an adherent film of said coating composition on said anode.  Distilled or deionized water is preferably used in the coating composition which generally has a pH of less than 10.  The metal substrate (anode) may be, for example, of iron, steel, galvanized steel, phosphatized steel, aluminium, zinc or copper.  In Examples, the cathode is of steel or aluminium.  Direct current or, with suitable equipment, alternating current can be used; the voltage may range from 1-1000v., typically from 50-350v., and the initial current density is usually between 0.1-15 amps/sq.ft. In the Examples, the coatings produced have dielectric strengths in excess of 1000v. (D. C.). The coatings are generally cured by baking at 250-800 DEG F., for 1-30 minutes.ALSO:Compositions for coating metal substrates by electrodeposition comprise dispersed in water (a) from 95-50%, by weight of (a) and (b), of an at least partially neutralized interpolymer of from 1-20% by weight of a hydroxyalkyl ester of an a ,b -ethylenically unsaturated carboxylic acid, from 1-20% by weight of an ethylenically unsaturated carboxylic acid, and at least one other copolymerizable ethylenically unsaturated monomer; and (b) from 5-50%, by weight of (a) and (b), of an amine-aldehyde condensation product and/or a polyepoxide. The hydroxyalkyl ester monomers may be derived from acids such as acrylic, methacrylic, ethacrylic, crotonic and similar acids having up to 6 carbon atoms, and also from dibasic acids such as maleic, fumaric or itaconic acid in which case the ester may be a mono- or di-ester. The acid monomer may be any of those previously metioned in connection with the ester monomers, preferably acrylic or methacrylic acid; although a mono-(hydroxy alkyl) ester of a dicarboxylic acid may serve, fully or partly, as both the ester and acid monomer.  Suitable copolymerizable compounds for component (a) include alkyl acrylates, methacrylates and crotonates, vinyl aromatic hydrocarbons such as styrene and alkyl-styrenes, olefins, diolefins and their halogen derivatives such as ethylene, butadiene, vinyl chloride and allyl chloride, nitriles and amides such as acrylonitrile and acrylamide, and vinyl acetate. In examples, the interpolymers are prepared by polymerizing the monomers (a) in ethylene glycol mono-n-butyl ether, with or without 2-butanol, butyl Carbitol (Trade Mark), or diacetone alcohol, using benzoyl peroxide catalyst and (b) in water in the presence of t-dodecyl mercaptan using ammonium persulphate catalyst.  The interpolymer is completely or partly neutralized with a base, before or after formulating the coating composition; suitable bases include ammonia, metal (e.g. alkali metal or alkaline earth metal) hydroxides and mono- or di-amines. The amine-aldehyde condensates include those derived from, on the one hand, formaldehyde, acetaldehyde, crotonaldehyde, acrolein, benzaldehyde or furfural and, on the other, melamine, urea, acetoguanamine, dimethyl urea, benzyl urea, ethylene urea, 1,4-diazine-2,5-dicarboxamide, formoguanamine, benzoguanamine, ammeline, 2 - chloro - 4,6 - diamino - 1,3,5 - triazine, 3,5 - diaminotriazole, 4,6 - diaminopyrimidine and 2,4,6 - triphenylamino - 1,3,5-triazine. The alkylol groups of the condensates may be etherified with alcohols such as methanol and n-butanol.  Suitable polyepoxides include polyglycidyl ethers of polyphenols or polyhydric alcohols, polyglycidyl esters of polycarboxylic acids, and epoxidized olenifically unsaturated compounds (e.g. epoxidized polybutadiene in Example 8).  The coatings produced by electrodeposition are generally cured by baking at 250-800 DEG  F. for 1-30 minutes.