Patent GB-861427-A (GB)
Title: Improvements in or relating to polymeric dispersions and method of coating therewith
IPC: C09D123/08
Filed: 1959-07-13
Abstract: A polyethylene dispersion comprises up to 60% of a linear polyethylene dispersed in the absence of an emulsifying agent, the dispersion being maintained essentially by the action of a liquid medium having a surface tension of 25-42.5 dynes/cm. at 25 DEG  C. and a specific gravity of 0.875-1.025 at 25 DEG  C., said medium being substantially inert to linear polyethylene and having a boiling-point below 230 DEG  C.  The liquid medium may comprise a single liquid, e.g. hexylene glycol or diethylene glycol monobutyl ether, or may be a mixture of liquids, one of which may be water.  A list of suitable liquid medium components is given, including methanol, ethanol and other alcohols, propylene glycol and glycol ethers, e.g. propylene and dipropylene glycol monomethyl ether, glycol mixed ethers and esters, ketones, aldehydes, amines and diamines, petroleum naphtha, mineral oil, nonene, benzene, toluene, xylene, various ethyl benzenes, nitrobenzene and styrene.  The linear polyethylene may be in the form of a fine powder which is screened to a uniform size prior to agitation with the liquid medium.  The dispersion may be allowed to age prior to use as a coating composition for a variety of materials such as various steels and alloys, iron, aluminium, copper, glass, wood, paper, cardboard, cement, canvas, fibre-board, and cinder block.  After application of the coating composition by spraying, dipping or flow coating, the coated article is heated to fuse the polyethylene into a smooth continuous coating.  The composition may also contain small proportions of an anti-oxidant such as substituted phenols, cresols and naphthols and thiols; a rust inhibitor such as sodium nitrite, n-propylamine and calcium stearate; a stabilizer such as 5-chloro-2-hydroxybenzophenone, dibenzoyl resorcinol or phenyl salicylate; graphite or pigments such as cadmium sulphide and selenide, chromic oxide, titanium dioxide, zinc oxide, phthalocyanine blue and green.  The compositions are useful in forming protective coatings in tanks and pipes and on electrical equipment, hand-tools and refrigertor ice-trays.  Specification 799,392 is referred to.ALSO:Various substrates are coated with a polyethylene dispersion in which no dispersing agent is present, the dispersion being maintained essentially by the action of a liquid medium having a surface tension of 25-42.5 dynes/cm. at 25 DEG  C. and a specific gravity of 0.875-1.025 at 25 DEG  C., said medium being substantially inert to linear polyethylene and having a boiling point below 230 DEG C.  The liquid medium may comprise a single liquid, e.g. hexylene glycol or diethylene glycol monobutyl ether, or may be a mixture of liquids, one of which may be water.  A list of suitable liquid medium components is given including methanol, ethanol and other alcohols, propylene glycol and glycol ethers, glycol mixed ethers and esters, ketones, aldehydes, amines and diamines, petroleum naphtha, mineral oil, nonene, benzene, toluene, xylene, various ethyl-substituted benzenes, nitrobenzene and styrene.  The linear polyethylene may be in the form of a fine powder which is screened to a uniform size prior to agitation with the liquid medium.  The dispersion may be allowed to age prior to use on substrates such as various steels and alloys, iron, aluminium, tin plate, aluminium foil, copper, glass, wood, paper, cellulosic fibres, cardboard, cement, fibreboard, cinder block, plywood, glass wool and canvas.  The coating may be applied by dipping, spraying or flow-coating and the substrate is afterwards baked. The dispersion may also contain additives such as rust inhibitors, e.g. sodium nitrite, n-propylamine or calcium stearate; antioxidants, e.g. substituted phenols, thiols, and naphthols; stabilizers, e.g. chlorohydroxy-benzophenone, dibenzoyl resorcinol and phenyl salicylate; slip agents such as graphite and pigments such as cadmium sulphide or selenide, phthalocyanine green or blue, chromic oxide, titanium dioxide or zinc oxide.  The dispersions may be used to form protective coatings in tanks and pipes and on electrical equipment, hand-tools and refrigerator tops. Specification 799,392 is referred to.