Patent GB-1019456-A (GB)
Title: Improvements in preparation of polymeric amino amide compositions
IPC: C08G69/34
Filed: 1962-10-22
Abstract: Epoxy resins are cured by reaction with polymeric amino amides which have been prepared by heating to a reaction temperature an aliphatic polyamine and either a tung oil fatty acid, an ester thereof or a mixture thereof with a less unsaturated acid in an amount of at least 1.5 amino groups of polyamine per acid or ester group of the tung oil material to produce an amino amide which is then heat polymerized at a temperature below 250 DEG  C. until a viscosity measured in poises at 70% solids solution in xylene is reached which is at least three times the initial viscosity. Suitable epoxy resins are glycidyl polyethers of polyhydric alcohols and polyhydric phenols, such as the diglycidyl ether of trimethylol propane, the bis-epoxy-dicyclo-pentyl ether of ethylene glycol, dicyclopentadiene diepoxide and the low viscosity epoxide resin obtained from ten mols. of epihalohydrin per mol. of bisphenol, and heat curable epoxy esters, such as those prepared by epoxidation of unsaturated esters with performic or peracetic acid, e.g. 3,4-epoxy-6-methyl-cyclohexyl-methyl - 3,4 - epoxy - 6 - methyl - cyclohexane-carboxylate. In an example an epoxy resin made from a ratio of 1.22 mols. of epichlorhydrin to 1 mol. of bis-phenol is mixed with 3% of urea-formaldehyde resin for flow control, is pigmented and then mixed with polymeric amino amide curing agent to give an enamel which is cast as a film on to a cold rolled steel panel.ALSO:Polymeric amino amides are prepared by heating to a reaction temperature an aliphatic polyamine and either a tung oil fatty acid or an ester thereof in an amount of at least 1.5 amino groups of polyamine per acid or ester group of the tung oil material to produce an amino amide, followed by heat polymerizing the latter at a temperature below 250 DEG  C. until a viscosity measured in poises at 70% solids solution in xylene is reached which is at least three times the initial viscosity.  The tung oil fatty acid or ester thereof may be admixed with between 0.5 and 25% by weight of less unsaturated acids or esters, e.g. those derived from dehydrated castor, cottonseed, linseed, corn, peanut or perilla oils.  The ester is advantageously a glyceride and in this event the free glycerine which is formed is removed by vacuum distillation prior to the heat polymerization. Specified amine reactants include diethylene triamine, triethylene tetramine, tetraethylene pentamine, 3,3-imino-bis-propyl-amine, 1,4-diamino-butane, 1,3-diamino-butane and hexamethylene diamine. A portion of the amine reactant may be retained and reacted with the polymeric aminoamide after the heat polymerization step. Alternatively, another polyamine reactant may be used for this after-treatment. Prior to the heat polymerization step any imidazolines formed during the preparation of the amino amide may be hydrolysed back to amino amide by heating with a quantity of water.  The polymeric amino amides may be used as curing agents for epoxy resins.ALSO:An epoxy resin made from a ratio of 1,22 mols. of epichlorhydrin to 1 mol. of bis-phenol is mixed with 3% of urea-formaldehyde resin for flow control, is pigmented and then mixed with a polymeric amino amide curing agent (see Division C2) to give an enamel which is cast as a film on to a cold rolled steel panel.