Patent GB-1071294-A (GB)
Title: Improvements in and relating to the manufacture of transistors
Inventor: KLEIN THOMAS
IPC: H01L21/331
Filed: 1963-12-17
Abstract: 1,071,294. Semi-conductor devices. MULLARD Ltd. Dec. 17, 1963, No. 49770/63. Heading H1K. A method of manufacturing a transistor comprises epitaxially depositing a layer of one conductivity type semi-conductor material on a substrate of the same conductivity type semiconductor material containing at least adjacent the layer, an opposite conductivity type impurity which diffuses into part of the epitaxial layer. As shown, Figs. 6 and 8, a transistor of the kind described in Specification 1,071,295 and a resistor are formed in a single substrate. An N- type substrate 1, doped with arsenic and containing boron either distributed throughout its volume or concentrated in a surface layer, has an N-type silicon layer, weakly doped with arsenic, epitaxially deposited on one face. The boron in substrate 1 diffuses into the epitaxial layer during its deposition to form a thin P-type layer 3 overlaid with the remaining N-type layer 4. The epitaxial layer is masked and etched to form two mesas which are then covered with a layer 10 of silicon oxide by heating the wafer in wet oxygen. Aluminium is deposited in a window 11 etched in oxide layer 10 and is alloyed into layer 4 to form a P-type region 12 extending to layer 3. Ohmic connections 16, 17, 18 are produced by depositing gold containing antimony or arsenic in windows 13, 14, 15 and then alloying into the regions 4. Aluminium conductors 19, 20, 21 are deposited on the surface of oxide layer 10 and the base of substrate 1 is alloyed to a gold-plated " Kovar "  (Registered Trade Mark) strip 22. The transistor is formed by the left-hand circular mesa, substrate 1 forming the emitter connection, and its collector is connected by conductor 20 to one side of the resistor formed by the right-hand rectangular mesa.- A NOR gate comprising three transistors and four resistors produced in a single substrate is also described, Figs. 10 and 11 (not shown). A capacitor may be produced by biasing the junction between regions (3) and (4) in a mesa in the reverse direction, Fig. 12 (not shown). Insulated cross-over connections may be formed by heavily doping region (4) of a mesa with phosphorus to form a low-resistivity path which is insulated from a conductor crossing its surface by an oxide layer, Fig. 13 (not shown). In an alternative construction for a transistor and resistor combination, Fig. 16, a substrate 37 comprising an arsenic-doped silicon wafer into which are diffused surface regions of boron has an N-type epitaxial layer deposited on its surface as in the first embodiment. Instead of etching the wafer to form mesas the edges of the P-type regions are extended to the surface of the substrate by diffusing aluminium into the surface to form P-type regions 50, 51. Interconnections are made by soldering wires to various ohmic connections produced as previously described, and this method of interconnection may be used with the other embodiments. Alternatively the metal regions left after the production of regions 50 and 51 may be removed and the silicon surface reoxidized so that deposited interconnections may be formed. Capacitors and crossovers may also be incorporated in this embodiment.