Patent GB-1014175-A (GB)
Title: Improvements in and relating to coating compositions for paper and the like and to their method of production
IPC: C08B31/18
Filed: 1962-06-13
Abstract: A coating composition for paper and the like is made by forming an aqueous slurry comprising starch and an oxidizing agent, capable of oxidizing and thereby decreasing the viscosity of the starch, and heating the slurry to a temperature sufficient to gelatinize the starch and for a time sufficient to consume substantially all the oxidizing agent.  The starch may be raw or derivatized starch, and the oxidizing agent, suitably 0.1-1.0% by weight of the starch, may be sodium hypochlorite, ammonium and potassium persulphates, potassium permanganate, peroxides, or perborates.  The starch slurry may also contain a pigment, e.g. clay, calcium carbonate or titanium dioxide, and also metallic ions, e.g. cupric ions to ensure completion of the oxidation reaction.  The slurry contains alkali to neutralize acidic reaction products, and may also contain hydrogen peroxide, dyes, soaps, surfactants and dispersing agents.  The total solids content may be 50-70%.  In Example 1, an aqueous slurry containing pearl corn starch, clay, sodium hexametaphosphate, sodium hydroxide, soap, ammonium persulphate and hydrogen peroxide is heated by steam injection. The cooked composition is salt-coated on to paper.ALSO:<PICT:1014175/C3/1> <PICT:1014175/C3/2> An aqueous slurry comprising starch and an oxidizing agent, capable of oxidizing and thereby reducing the viscosity of the starch, is heated to a temperature sufficient to gelatinize the starch for a time sufficient to consume substantially all the oxidizing agent. The starch slurry may also contain a pigment. The slurry may be heated to at least 220 DEG  F. by continuously passing it through a heating zone where it is agitated and subjected to shearing forces, either by steam jets or by mechanical means.  The starch may be raw or derivatized starches, and the oxidizing agent, suitably comprising 0.1-1 0% by weight of the starch, may be sodium hypochloride, ammonium and potassium persulphates, potassium permanganate, peroxides or perborates. Specified pigments are clay, calcium carbonate and titanium dioxide. The slurry, which contains alkali to neutralize acidic reaction products and, preferably, to maintain the pH of the slurry at 7 or above, may also contain hydrogen peroxide, for colour stabilization, and metallic ions, e.g. cupric ions, to ensure completion of the oxidation reaction.  Dyes, soaps, surfactants and dispersing agents may also be added to the slurry.  In one embodiment starch slurry is pumped into inlet 15 along pipe 10 and into mixing chamber 1 (Fig. 2), where it is heated and gellatinized by jets of steam issuing from orifices 8 in plate 5 (Fig. 2a), the steam being fed under pressure from inlet 13 into steam chamber 14.  The gelatinized and oxidized slurry emerging from outlet 2 may be fed to a storage tank or direct to a coating device.  In a further embodiment, the starch slurry is indirectly heated by steam in a reactor equipped with revolving scraper blades, and then water-cooled in a unit also provided with rotating blades.  The latter system avoids the dilution of the slurry and necessary flashion of steam consequent upon use of steam injection heating. The starch slurries are used as coating compositions for paper and the like.