Patent DE-102004021566-A1 (DE)
Title: Synergistic composition for control of insects and other animal pests, useful e.g. in plant protection or veterinary medicine, includes anthranilic amide compound and e.g. phenylpyrazolone compound or amitraz
Inventor: FUNKE CHRISTIAN
IPC: A01N43/00
Filed: 2004-05-03
Abstract: Composition (A) contains synergistic amounts of a phenylpyrazolone compound (I) or at least one insecticide (IA) comprising amitraz, buprofezin, triazamate, pymetrozin, pyriproxifen, flonicamide or pirimicarb and at least one anthranilic acid amide compound (II). Composition (A) contains synergistic amounts of a phenylpyrazolone compound of formula (I), its N oxides or salts or at least one insecticide (IA) comprising amitraz, buprofezin, triazamate, pymetrozin, pyriproxifen, flonicamide or pirimicarb and at least one anthranilic acid amide compound of formula (II). [Image] X : halo, alkyl, haloalkyl, alkoxy, haloalkoxy or cyano; W 1>, Y, Z : H or X; A 3> : H, alkyl, alkoxyalkyl or optionally substituted cycloalkyl in which at least one ring atom is optionally replaced by a heteroatom (all optionally substituted by halo); A 4> : H or alkyl, or A 3> + A 4> : a saturated or unsaturated ring optionally containing at least one heteroatom and optionally substituted; D : alkyl, alkenyl, alkoxyalkyl or cycloalkyl in at least 1 ring member is optionally replaced by heteroatoms (all optionally substituted) or H, or D + A 3> : a saturated or unsaturated ring optionally containing at least one heteroatom and optionally substituted; G 1> : e.g. H or COR 20>; R 20> : alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl or polyalkoxyalkyl (all optionally substituted by halo), cycloalkyl optionally including at least one heteroatom (optionally substituted by halo, alkyl or alkoxy), or phenyl, phenalkyl, hetaryl, phenoxyalkyl or hetaryloxyalkyl (all optionally substituted); A 1>, A 2> : O or S; X 1> : N or CR 10>; R 1> : 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl or 3-6C cycloalkyl (all optionally substituted) or H; R 2> : H, 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl, 3-6C cycloalkyl, 1-4C alkoxy, 1-4C alkylamino, 2-8C dialkylamino, 3-6C cycloalkylamino, 2-6C alkoxycarbonyl or 2-6C alkylcarbonyl; R 3> : H, R 11> or 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl or 3-6C cycloalkyl (all optionally substituted), or R 2> + R 3> : a ring; R 4> : e.g. 1-6C alkyl, 2-6C alkenyl, 2-6C alkynyl or 3-6C cycloalkyl (all optionally substituted), or H; R 5>, R 8> : 1-4C alkyl or 1-4C haloalkyl (both optionally substituted), H or halo; R 7> : H, halo or 1-4C alkyl, alkoxy or alkylS(O) x (all optionally substituted), with specified provisos. Full definitions are given in the Definitions Field (Full Definitions). ACTIVITY : Insecticide; Nematocide; Arachnicide; Acaricide; Antifouling. In a test against Aphis gossypii on cotton, results showed that N-(2-methyl-4-chloro-6-(dimethylaminocarbonyl)phenyl-1-(3-chloropyrid-2-yl)-3-trifluoromethyl-pyrrole-5-carboxamide, at 20 ppm, gave 55% kill after 6 days, while flonicamide at 20 ppm gave 40% kill. The specified amounts of both compounds, when applied together, gave a 99% kill, with 73% expected from an additive effect. MECHANISM OF ACTION : None given.