Patent GB-938142-A (GB)
Title: Aqueous polymer blend composition
IPC: C09D125/14
Filed: 1959-12-03
Abstract: An aqueous composition suitable as a paint or, coating composition or, floor polishing composition comprises as essential ingredients (A) an aqueous dispersion of a terpolymer of (1) 42 to 77% by weight of at least one of the monomers styrene, vinyltoluene, vinylidene chloride, isobornyl methacrylate, benzyl acrylate and phenoxyethyl methacrylate, (2) 20 to 46% by weight of an ester of acrylic acid with a C1-C8 saturated aliphatic or cycloaliphatic alcohol, and (3) 3 to 12% by weight of a monoethylenically unsaturated carboxylic acid or salt thereof, and (B) an aqueous dispersion of a copolymer of (1) 10 to 40% of at least one of the monomers in A(1) above, (2) 90-60% by weight of an ester of acrylic acid with a C1 to C8 saturated aliphatic, or cycloaliphatic alcohol, and (3) 0 to 6% by weight of a monoethylenically unsaturated carboxylic acid or salt thereof. Component (3) of the polymers may be methacrylic, acrylic, itaconic, maleic, fumaric, maleamic aconitic, or citraconic acid, or methacrylic acid dimer.  The compositions may also include pigments, fillers, plasticizers, buffering agents, and emulsions and aqueous dispersions of waxes, and/or alkali-soluble resins. The pigments and fillers may be titanium dioxide, carbon black, iron blues, phthalocyanine blues and greens, metal oxides, metal hydroxides, metal salts, aluminium flake, bronze powders, pearl essence, talc, barytes, china clay, or diatomaceous earth. Specified waxes are polyethylene, carnauba wax, montan wax, Japan wax, beeswax, paraffin wax, and candelilla wax.  The alkali-soluble resin may be shellac, Manila gum, Loba gum, alkali-soluble unsaturated alkyl resins, or a resin acid such as abietic or rosin.  Suitable buffering agents are borax, ammonia, diethylamine, triethylamine, morpholine, and triethanolamine.  In floor-polishing compositions the proportions of the main ingredients should be, copolymers (A)+(B)-20 to 90 parts, wax -5 to 60 parts, alkali-soluble resin 5 to 40 parts, dispersing agents 0,5 to 8% of the previous ingredients and water to make total solids 8 to 25%.  In non-bufferable polishing compositions the wax content is not more than 35 parts by weight.  Examples 1, 2, 3, 6, 7, 10 relate to polishing compositions, Example 4 to a coating composition for asbestos-cement shingles consisting of copolymers (A)+(B) followed by a heat-treatment, Example 5 relates to an aqueous flat base paint consisting of copolymers (A)+(B)+TiO2+lithopone+mica, + silica, + diethylene glycol + a formaldehydecondensed sodium naphthalene sulphonate, Example 8 relates to a composition for preventing floor-tiles sticking, p  Example 9 relates to a composition of (A)+(B) for application to tyres as a protection in transit and storage.  U.S.A. Specification 2,606,165 is referred to.ALSO:An aqueous composition comprises a blend of (A) an aqueous dispersion of a terpolymer of (1) 42 to 77% by weight of at least one of the monomers styrene, vinyltoluene, vinylidene chloride, isobornyl methacrylate, benzyl acrylate and phenoxyethyl methacrylate, (2) 20 to 46% by weight of an ester of acrylic acid with a C1-C8 saturated aliphatic or cycloaliphatic alcohol, and (3) 3 to 12% by weight of a monoethylenically unsaturated carboxylic acid or salt thereof, and (B) an aqueous dispersion of a copolymer of (1) 10 to 40% of at least one of the monomers in (A) (1) above, (2) 90-60% by weight of an ester of acrylic acid with a C1 to C8 saturated aliphatic, or cycloaliphatic alcohol, and (3) 0 to 6% by weight of a monoethylenically unsaturated carboxylic acid or salt thereof. Component (3) of the copolymers may be methacrylic acid, acrylic acid, itaconic acid, maleic acid, fumaric acid, maleamic acid, methacrylic acid dimer, aconitic acid, or citraconic acid.  The ter- and copolymers may be made by conventional methods.  The composition may also include pigments, fillers, plasticizers, buffering agents, and emulsions and aqueous dispersions of waxes, and/or alkali-soluble resins.  The pigments and fillers may be titanium dioxide, carbon black, iron blues, phthalocyanine blues and greens, metal oxides, metal hydroxides, metal salts, aluminium flakes, bronze powders, pearl essence, talc, barytes, china clay, or diatomaceous earth. Specified waxes are polyethylene, carnauba wax, montan wax, Japan wax, beeswax, paraffin wax, and candelilla wax.  The alkali-soluble resin may be shellac, Manila gum, Loba gum, alkali-soluble unsaturated alkyd resins, or a resin acid such as abietic or rosin. Suitable buffering agents are borax, ammonia, diethylamine, triethylamine, morpholine, and triethanolamine.  The Specification contains a long list of conventional plasticizers.  The compositions may be used for coating and impregnating textiles, leather, paper, polyethylene sheets, polyethylene glycol terephthalate sheets, and rigid surfaces such as steel, aluminium, copper, brass, bronze, tin, chromium, wrought iron, wood, stone, masonry, glass, and asbestos cement shingles, and also in the manufacture of floor-polishing compositions.  U.S.A. Specification 2,606,165 is referred to.