Patent EP-1813151-A1 (EP)
Inventor: GEWEHR MARKUS DR
IPC: A01N43/56
Filed: 2006-01-26
Abstract: Fungicide mixture for combating plant pathogenic fungus comprises a synergistically active quantity of 1-methyl-pyrazol-4-yl carboxylic acid anilides and at least one active ingredient from azoles (e.g. bitertanole), strobilurins (e.g. azoxystrobin), carboxylic acid amides (e.g. carboxin), heterocyclic compounds (e.g. fluazinam), carbamates (e.g. mancozeb) and other fungicides. Fungicide mixture for combating plant pathogenic fungus comprises a synergistically active quantity of 1-methyl-pyrazol-4-yl carboxylic acid anilide of formula (I) and at least an active substance from azole such as bitertanole, bromuconazole, cyproconazole, difenoconazole, diniconazole, enilconazole, epoxiconazole, fluquinconazole, fenbuconazole, flusilazole, flutriafole, hexaconazole, imibenconazole, ipconazole, metconazole, myclobutanil, penconazole, propiconazole, prothioconazole, simeconazole, triadimefon, triadimenole, tebuconazole, tetraconazole, triticonazole, prochloraz, pefurazoate, imazalil, triflumizole, cyazofamide, benomyl, carbendazim, thiabendazole, fuberidazole, ethaboxam, etridiazole and hymexazole; strobilurin such as azoxystrobin, dimoxystrobin, enestroburin, fluoxastrobin, Kresoxim-methyl, methominostrobin, orysastrobin, picoxystrobin, pyraclostrobin, trifloxystrobin, enestroburin, (2-chloro-5-[1-(3-methyl-benzyloxyimino)-ethyl]-benzyl)-carbaminic acid methylester, (2-chloro-5-[1-(6-methyl-pyridin-2-yl methoxyimino)-ethyl]-benzyl)- carbaminic acid methylester and 2-(ortho-(2,5-dimethylphenyl-oxymethylene)phenyl)-3-methoxy-acrylic acid methylester; carbonic acid amides such as carboxin, benalaxyl, boscalid, fenhexamide, flutolanil, furametpyr, mepronil, metalaxyl, mefenoxam, ofurace, oxadixyl, oxycarboxin, penthiopyrad, thifluzamide, tiadinil, 3,4-dichloro-N-(2-cyanophenyl)-isothiazole-5-carboxylic acid amide, dimethomorph, flumorph, flumetover, fluopicolid (picobenzamide), zoxamide, carpropamide, diclocymet, mandipropamid, N-(2-(4-[3(4-chlorophenyl)-prop-2-ynyloxy]-3-methoxy-phenyl)-ethyl)-2 methanesulfonyl-amino-3-methyl-butyramide, N-(2-(4-[3-(4-chlorophenyl)-prop-2-ynyloxy]-3-methoxy-phenyl)-ethyl)-2-ethanesulfonylamino-3-methyl-butyramide, 3-(4-chloro-phenyl)-3-(2-isopropoxycarbonylamino-3-methyl-butyryl-amino)-propionic acid methylester, organic compound of formula (III), 4-difluoromethyl-2-methyl-thiazole-5-carbonic acid-N-(4'-bromo-biphenyl-2-yl)-amide, 4-difluoromethyl-2-methyl-thiazole-5-carbonic acid-N-(4'-trifluoromethyl-biphenyl-2-yl)-amide, 4-difluoro-methyl-2-methyl-thiazole-5-carbonic acid-N-(4'-chloro-3'-fluoro-biphenyl-2-yl)-amide, 3-difluoromethyl-1-methyl-pyrazole-4-carbonic acid-N-(3',4'-dichloro-4-fluoro-biphenyl-2-yl)-amide, 3-difluoromethyl-1-methyl-pyrazole-4-carbonic acid-N-(3',4'-dichloro-5-fluoro-biphenyl-2-yl)-amide and 3,4-dichloro-isothiazole-5-carbonic acid-N-(2-cyano-phenyl)-amide; hetero-cyclic compound such as fluazinam, pyrifenox, bupirimat, cyprodinil, fenarimol, ferimzon, mepanipyrim, nuarimol, pyrimethanil, triforin, fenpiclonil, fludioxonil, aldimorph, dodemorph, fenpropimorph, tridemorph, fenpropidin, iprodion, procymidon, vinclozolin, famoxadon, fenamidon, octhilinon, probenazol, 5-chloro-7-(4-methyl-piperidin-1-yl)-6-(2,4,6-trifluoro-phenyl)-[1,2,4] triazolo [1,5-a] pyrimidine, anilazine, diclomezine, pyroquilon, proquinazide, tricyclazol, (2-butoxy-6-iodo-3-propyl-chromen-4-on), acibenzolar-S-methyl, captafol, captan, dazomet, folpet, fenoxanil, quinoxyfen and 3-(3-bromo-6-fluoro-2-methyl-indol-1-sulfonyl)-[1,2,4]triazole-1-sulfonic acid dimethylamide; carbamate such as mancozeb, maneb, metam, metiram, ferbam, propineb, thiram, zineb, ziram, diethofencarb, iprovalicarb, flubenthiavalicarb, propamocarb, N-(1-(1-(4-cyanophenyl)ethanesulfonyl)-but-2-yl)carbaminic acid-(4-fluorophenyl)esters, 3-(4-chlorophenyl)-3-(2-isopropoxycarbonylamino-3-methyl-butyrylamino)-propane acid methyl ester and carbamatoximether of formula (IV); and other fungicides such as guanidine, dodine, iminoctadine and guazatine, antibiotics like Kasugamycin, streptomycin, polyoxin and validamycin A, nitrophenyl derivate like inapacryl, dinocap, dinobuton, sulfur containing hetero cyclyic compound like dithianon, isoprothiolane, organometallic compound like fentin salts, organo phospho compound like edifenphos, iprobenfos, fosetyl, fosetyl aluminum, phosphorous acid and its salts, pyrazophos and tolclofos methyl, organochloro compound like chlorthalonil, dichlofluanide, flusulfamide, hexachlorobenzol, phthalide, pencycuron, quintozen, thiophanate methyl and tolylfluanide, inorganic active substances like bordeaux mixture, copper acetate, copper hydroxide, copperoxychloride, basic copper sulfate and sulfur, and other substances like cyflufenamid, cymoxanil, dimethirimol, ethirimol, furalaxyl, metrafenon and spiroxamine; X : O and S; R 1>halo or 1-4C- (halogen)alkyl; R 2>H or halo; R 3>nitro, cyano, halo, 1-4C (halogen)alkyl, 1-4C (halogen) alkoxy or 1-4C alkylthio; R 4>methyl or ethyl; and Z : N or CH. Independent claims are included for: (1) an agent comprising at least a liquid or solid substrate and fungicide mixture; (2) a method for combating plant pathogenic fungus comprising applying (I) and the active substance on fungus, on their habitat or on plants before fungal attack, soil, seeds, surfaces, materials or areas, where fungal growth is noticed; and (3) seeds comprising the herbicide mixture in a quantity of 1-1000 g per 100 kg seeds. [Image] [Image] ACTIVITY : Fungicide; Herbicide. MECHANISM OF ACTION : None given.