Patent GB-394004-A (GB)
Title: Improvements in or relating to the recovery of hydrocyanic acid from complex cyanides and waste liquors
IPC: C01C3/14
Filed: 1931-12-18
Abstract: <PICT:0394004/III/1> Hydrocyanic acid is recovered from complex heavy metal cyanides by heating them in a reducing hydrogen containing atmosphere and in the presence of elemental sulphur or of a second substance which contains available sulphur.  Some ammonia is obtained as a byproduct.  Temperatures of 400-500 DEG  C. are suitable. Suitable substances containing sulphur are iron pyrites and/or sulphocyanides, particularly cuprous sulphocyanide.  Excess of sulphocyanides may be added if available, provided a supplementary addition of finely divided copper or iron is made.  Soluble complex heavy metal cyanides are preferably previously converted into an insoluble form by precipitation with salts of zinc, iron or copper. Coal gas or producer gas may be used as a source of hydrogen. Residual liquor from a gold ore cyanide plant 11 is treated at 13 for the recovery of residual alkali cyanide as described in Specification 362,861, an insoluble residue of zinc ferrocyanide being obtained. Alternatively, the residual liquor is treated with ferrous sulphate in a vat 14 to produce a precipitate of complex ferro-cyanides.  The zinc ferro-cyanide or complex ferro-cyanides are briquetted with ground pyrites and a binder such as sulphite liquor in a drying plant 16, the briquettes being heated at 400-450 DEG  C. with a hydrogenous gas in a retort 17.  The resulting gases containing hydrocyanic acid are scrubbed in a washer 19a with a solution which will retain any ammonia or hydrogen sulphide present, for example an aqueous solution containing free sulphuric acid and copper sulphate.  The hydrocyanic acid is finally converted into alkali or alkaline earth cyanide solution in a scrubber 19 irrigated with aqueous caustic alkali or alkaline earth hydrate.  This may be recirculated through a pipe 22 until sufficiently concentrated and then returned to the ore extraction plant via a pipe 23.  The clear liquor from the precipitation vat 14 is lead to a zinc box 15 where it is acidified to pH4, its gold and silver content being thereby recovered.  The liquor is then returned to the cycle via a pipe 16.  When the concentration sulphocyanides present in the circulating liquor becomes too high, a proportion is withdrawn by a pipe 24 and is precipitated as cuprous sulphocyanide by copper sulphate and a reducing agent such as sulphur dioxide in a vat 25. The precipitate is dewatered in a filter press 26 and may be employed as part of the required sulphur containing substance, being mixed with the precipitate from the vat 14 and fed to the retort 17.  Should the gold and silver values be unprecipitated before the precipitation of the cuprous sulphocyanide, they will be carried down therewith and can be finally recovered from the cuprous sulphide residue in the retort.  The process is also applicable to liquors containing ferrocyanides and sulphocyanides such as gas scrubbing liquors &c. after the removal of ammonia and hydrogen sulphide therefrom.  The Provisional Specification describes also the production of hydrocyanic acid by heating cuprous sulphocyanide with metallic iron or copper in the presence of hydrogen.