Patent GB-375425-A (GB)
Title: Improvements in the production of artificial filaments, threads, ribbons, films and similar materials
IPC: D01F2/30
Filed: 1931-03-27
Abstract: <PICT:0375425/IV/1> <PICT:0375425/IV/2> In the production or treatment of artificial filaments, threads, ribbons, films, and similar materials containing a cellulose ester or ether, stretching tension is applied to the materials whilst they are in a plastic state by means of a moving body of gas opposing the travel of the materials.  The gaseous medium may be air, nitrogen, or carbon dioxide, or the vapours of solvents or non-solvents for the material under treatment.  The gas may contain colouring agents or other gaseous, liquid or solid treating agents.  The gaseous drag may be obtained by passing the threads through two concentric hollow cones forming an ejector device, the rapid flow of gas through the annular space between them inducing a flow of gas through the inner vessel. The gas may issue through a flared tube beyond the end of the inner cone. This causes the velocity of the effluent to be gradually reduced so that the threads entering the apparatus are subjected to a counter-current of gas of increasing velocity.  Alternatively the thread may be drawn through a chamber of low pressure surrounded by a region of higher pressure.  Thus a constant influx is produced and the entering gas flows past the outgoing threads with sufficient velocity to exert a drag.  The threads may enter the chamber through a funnel-shaped vessel through which a slow current of gas flows in the direction of the threads.  The outlet for the threads may consist of an orifice in the end of the chamber or may be prolonged in the form of a tube.  In starting up, the gaseous current may be arranged to travel in the same direction as the threads, and then to be same direction as the threads, and then to be reversed when the thread has reached the drawing device.  When applied to dry spinning processes, the gaseous counter-current which exerts the drag may be set up in the spinning cell.  When applied to wet spinning processes, the threads may be passed while still plastic from the coagulating bath to the ejector or other device.  When the gaseous drag is applied to fully coagulated threads treatment with a solvent or softening agent is generally necessary.  The softening agent may be applied in liquid or gaseous form and it may be introduced into the gaseous counter-current.  The process is applicable to threads and other materials of cellulose acetate, formate, propioate, butyrate, nitrate, or nitro-acetate, or of methyl, ethyl, or benzyl cellulose, or mixed ethers or ether-esters of cellulose.  The solvent or softening agent employed may be acetone, cyclohexanone, diacetone alcohol, an ether of ethylene glycol, dioxane, phenol, tetrachlorethane, acetic acid, formic acid, triacetin, a chlorhydrin, ethyl formate, diethyl tartrate, ethyl lactate, and glycol mono-acetate.  Benzyl and amyl alcohols may be used at raised temperatures.  Mixtures of solvents or latent solvents such as methyl or ethyl alcohol and methylene or ethylene dichloride may be used. Inorganic swelling agents such as zinc chloride, thiocyanates, or calcium chloride and alcohol may also be used.  The threads may be drawn forward by the collecting device such as a bobbin, swift, or spinning box, or by positively driven guide rolls, or by the pull of a liquid moving in the direction of the threads.  Powdered metal, titanium dioxide, barium sulphate, and other substances may be incorporated in the gaseous current.  The process may be associated with processes of delustring, mordanting, weighting, dyeing, saponifying, and sizing.  As shown in Fig. 1, filaments 5 issue from jet 6 in a dry spinning cell 4 and pass through injector devices 9 where they are subjected to the drag of a counter-current of air or other gas.  Gas is introduced through pipe 12 and the rapid upward flow induces an upward current through the inner cones.  As shown in Figs. 2 and 3, the bundle of filaments issues into a chamber 17 with a constricted lower part 18.  The pipe 21 is connected to a suction device and the current of air entering the chamber 17 exerts a drag on the filaments. The chamber is constructed in two removable halves bolted together by bolts 22 and slidable on rods 19.  Specifications 277,089, 323,790, 335,894, 338,989, [all in Class 2 (ii), Cellulose &c.], 340,324, 340,325, 340,436, 340,437, 340,929, 340,930, 341,057, 342,651, 342,712, 343,062, 344,474, and 371,343 are referred to.