Patent GB-435738-A (GB)
Title: Improvements relating to the extraction of halogens from fluids
IPC: C01B7/09
Filed: 1935-03-26
Abstract: Halogens, excepting fluorine, are removed from fluids by contact with polyvinyl alcohol-aldehyde condensation products, particularly a polyvinyl - alcohol - formaldehyde condensation product, which may be used in any suitable physical form, e.g. powder, grains, porous masses, fibres, threads, bands, films, &c. The absorbed halogen is readily removed by treatment by heat, vacuum, solvents or suitable reagents.  Iodine may be removed from water or other liquid by agitation with the finely divided condensation product or by filtration through a porous mass thereof.  The absorption is increased if a soluble halide is present, and the condensation product is capable of absorbing approximately 50--66 per cent of its own weight of the iodine. The process may be used to extract iodine from the mother liquors obtained from the refining of seaweed ashes, or natural saltpetre, or to remove iodine from water to which it has been added for sterilization, thus rendering the water potable. Halogens may similarly be removed from air or other gases.  The products comprising the condensation products having halogens, particularly iodine, sorbed on them may be used as bandages &c. for medical purposes, since they slowly evolve the halogen. Iodine solutions may be prepared by immersion of the products in the solvent, e.g. alcohol.  Water may be sterilized in a similar manner. The products may also be used for inhalation purposes, or to remove impurities which react with halogens, e.g. hydrogen sulphide or sulphur dioxide, from gases.  A suitable filtering mass is prepared by reacting 10 parts of polymerized vinyl alcohol dissolved in 100 parts water with 24 parts of hydrochloric acid (specific gravity 1,19) and 9 parts of 40 per cent formaldehyde. The whole is stirred, and thickens gradually.  When coagulation starts, the mass is moulded to the desired shape and allowed to stand until coagulation is complete.  The mass may be used on a Buchner funnel or other suction filter.ALSO:Halogens, excepting fluorine, are removed from fluids by contact with polyvinyl alcohol-aldehyde condensation products, particularly a polyvinyl-alcohol-formaldehyde condensation product, which may be used in any suitable physical form, e.g. powder, grains, porous masses, fibres, threads, bands, films, &c. The absorbed halogen is readily removed by treatment by heat, vacuum, solvents or suitable reagents.  Iodine may be removed from water or other liquid by agitation with the finely divided condensation product or by filtration through a porous mass thereof.  The absorption is increased if a soluble halide is present, and the condensation product is capable of absorbing approximately 50-60 per cent of its own weight of iodine.  The products comprising the condensation products having halogens, particularly iodine, sorbed on them may be used as bandages &c. for medical purposes, since they slowly evolve the halogen. Iodine solutions may be prepared by immersion of the products in the solvent, e.g. alcohol, water may be sterilized in a similar manner.  The products may also be used for inhalation purposes.  A suitable filtering mass is prepared by reacting 10 parts of polymerized vinyl alcohol dissolved in 100 parts water with 24 parts of hydrochloric acid (specific gravity 1,19) and 9 parts of 40 per cent formaldehyde.  The whole is stirred, and thickens gradually. When coagulation starts, the mass is moulded to the desired shape and allowed to stand until coagulation is complete. The mass may be used on a Buchner funnel or other suction filter.ALSO:Halogens, excepting fluorine, are removed from fluids by contact with polyvinyl alcohol-aldehyde condensation products, particularly a polyvinyl-alcohol-formaldehyde condensation product, which may be used in any suitable physical form, e.g. powder, grains, porous masses, &c.  The absorbed halogen is readily removed by treatment by heat, vacuum, solvents or suitable reagents.  Iodine may be removed from water or other liquid by agitation with the finely divided condensation product or by filtration through a porous mass thereof. The absorption is increased if a soluble halide is present, and the condensation product is capable of absorbing approximately 50-60 per cent of its own weight of iodine.  The process may be used to remove iodine from water to which it has been added for sterilization, thus rendering the water potable.  The products comprising the condensation products having halogens, particularly iodine, sorbed on them may be used to prepare iodine solutions by immersion in the solvent e.g. alcohol.  Water may be sterilized in a similar manner. A suitable filtering mass is prepared by reacting 10 parts of polymerised vinyl alcohol dissolved in 100 parts water with 24 parts of hydrochloric acid (specific gravity 1,19) and 9 parts of 40 per cent formaldehyde.  The whole is stirred, and thickens gradually. When coagulation starts, the mass is moulded to the desired shape and allowed to stand until coagulation is complete.  The mass may be used on a Buchner funnel or other suction filter.