Patent GB-743459-A (GB)
Title: Method of heat supply for a catalytic process
IPC: C10G35/14
Filed: 1953-11-19
Abstract: <PICT:0743459/IV(a)/1> Heat is supplied to an endothermic process for the catalytic treatment of a hydrocarbon feed-stock involving the use of a finely-divided solid catalyst containing particles within the size range of 20 to 200 microns in diameter by maintaining the catalyst in the form of a turbulent fluid bed within a deep reaction zone, continuously introducing into the fluid bed particles of about 300 to 1000 microns of hot inert heatcarrying material which have at least the same particle density as the fluidized catalyst, continuously removing from the bottom of the reaction zone a stream of the coarse particles stripped substantially free from catalyst and hydrocarbon vapours, conveying these particles upwardly through a vertically disposed conduit by the action of a burning stream of air and combustible fuel, heating the particles, separating them from the gas stream and returning the particles downwardly to a point within the reaction zone below the bed level of the fluidized catalyst.  The catalyst is preferably molybdenum oxide or chromium oxide on a carrier such as alumina gel, activated alumina or a zinc aluminate spinel.  The coarse particles may be an inert refractory material such as dead-burnt alumina or aluminium silicate or shot made from a metal such as aluminium, copper, iron, silver or "Monel" (Registered Trade Mark).  In a preferred embodiment, a reactor 10 contains a fluid bed of catalyst 11 which is maintained as a turbulent fluid bed by the continuous supply of reactant gases introduced through lines 12 and 13 and by the addition of regenerated catalyst through line 15.  Heat is supplied to the catalyst by means of hot particles introduced directly into the fluid bed by way of line 20 the particles forming a fairly distinct layer 22 from which particles are continuously withdrawn through line 23 and recirculated through line 25 which serves as a transfer line burner. Additional air or fuel may be added at line 29.  Spent catalyst is removed through stripping well 35 to regenerator 40. Specifications 593,180 and 676,391, [both in Group III], are referred to.ALSO:<PICT:0743459/III/1> Heat is supplied to an endothermic process for the catalytic treatment of a hydrocarbon feed stream involving the use of a finely divided solid catalyst containing particles within the size range of 20-200 mircons in diameter by maintaining the catalyst in the form of a turbulent fluid bed within a deep reaction zone, continuously introducing into the fluid bed particles of about 300-1000 microns of hot inert heat-carrying material which have at least the same particle density as the fluidized catalyst, continuously removing from the bottom of the reaction zone a stream of the coarse particles stripped substantially free from catalyst and hydrocarbon vapours, conveying these particles upwardly through a vertically disposed conduit by the action of a burning stream of air and combustible fuel, heating the particles, separating them from the gas stream and returning the particles downwardly to a point within the reaction zone below the end level of the fluidized catalyst.  The catalyst is preferably molybdenum oxide or chromium oxide or a carrier such as alumina gel, activated alumina, or a zinc aluminate spinel.  The coarse particles may be an inert refractory material such as dead burnt alumina, or aluminium silicate, or shot made from a metal such as aluminium, copper, iron silver or "Monel" (Registered Trade Mark).  In a preferred embodiment, a reactor 10 contains a fluid bed of catalyst 11, which is maintained as a turbulent fluid bed by the continuous supply of reactant gases introduced through lines 12 and 13 and by the addition of regenerated catalyst through line 15.  Heat is supplied to the catalyst by means of hot particles introduced directly into the fluid bed by way of line 20, the particles forming a fairly distinct layer from which particles are continuously withdrawn through line 23 and recirculated through line 25 which serves as a transfer line burner.  Additional air or fuel may be added at line 29.  Spent catalyst is removed through stripping wall 35 to regenerator 40.  Specifications 593,180 and 676,391 are referred to.