Patent GB-1003324-A (GB)
Title: Improvements in and relating to water-resistance
Inventor: MOES GEERT
IPC: C08B31/06
Filed: 1962-06-05
Abstract: An aqueous coating composition for applying to paper and fabrics, comprises a water-soluble starch phosphate ester and a water soluble salt of aluminium, 3-valent chromium or iron, zirconium, titanium, or 4-valent tin.  The starch may be natural starch, modified starch, dextrin, or water-soluble starch derivatives such as ethers and esters.  The phosphate esters may be obtained by heating starch with water-soluble ortho-, pyro-, meta- or poly-phosphates, with alkali metal orthophosphates and urea, or with a phosphoric or pyrophosphoric acid, with or without other inorganic acids, and urea. The metal salt may be a formate, acetate, sulphate, nitrate or chloride.  The composition may be alkaline and may contain emulsified paraffin wax, polyethylene, china clay and chalk.ALSO:A water-resistant amylaceous film is produced on the surface of a base material by applying both an aqueous dispersion of a water-soluble starch phosphate ester and an aqueous solution of a water-soluble salt of aluminium, 3-valent chromium or iron, zirconium, titanium or 4valent tin to the surface, thus forming in situ an insoluble film, and then drying the material. The base material may be paper or textiles. The starch may be natural starch, modified starch, dextrin or water-soluble starch derivatives such as ethers and esters.  The phosphate esters may be obtained by heating starch with water-soluble ortho-, pyro-, meta- or polyphosphates, with alkali metal orthophosphates and urea, or with a phosphoric or pyrophosphoric acid, with or without other inorganic acids, and urea.  The metal salt may be a formate, acetate, sulphate, nitrate or chloride.  The base material may be treated first with the starch phosphate ester and then with the metal salt, and may be dried between the two treatments. Alternatively, the metal salt and the starch phosphate ester may be applied together in an ammoniacal or alkaline solution, and the alkalinity subsequently removed, e.g. by evaporation of ammonia, or by dilute acid.  The aqueous solution of the metal salt may also contain emulsified paraffin wax or polyethylene.  The aqueous dispersion of starch phosphate ester may contain a finely divided mineral pigment, e.g. china clay or chalk.  The method can be used for sizing, finishing and printing the surface of textile materials, for producing water-resistant adhesive bonds, for surface-sizing paper and for coating paper to form, e.g. washable wallpaper.ALSO:A water-resistant amylaceous film is produced on the surface of a base material by applying both an aqueous dispersion of a water-soluble starch phosphate ester and an aqueous solution of a water-soluble salt of aluminium, 3-valent chromium or iron, zirconium, titanium or 4-valent tin to the surface, thus forming in situ an insoluble film, and then drying the material.  The base material may be paper or textiles.  The starch may be natural starch, modified starch, dextrin or water-soluble starch derivatives such as ethers and esters.  The phosphate esters may be obtained by heating starch with water-soluble ortho-, pyro-, meta- or poly-phosphates, with alkali metal orthophosphates and urea, or with a phosphoric or pyrophosphoric acid, with or without other inorganic acids, and urea. The metal salt may be a formate, acetate, sulphate, nitrate or chloride.  The base material may be treated first with the starch phosphate ester and then withthe metal salt, and may be dried between the two treatments.  Alternatively the metal salt and the starch phosphate ester may be applied together in an ammoniacal or alkaline solution, and the alkalinity subsequently removed, e.g. by evaporation of ammonia, or by dilute acid.  The aqueous solution of the metal salt may also contain emulsified paraffin wax or polyethylene.  The aqueous dispersion of starch phosphate ester may contain a finely divided mineral pigment, e.g. china clay or chalk. The method can be used for sizing, finishing and printing the surface of textile materials, for producing water-resistant adhesive bonds, for surface-sizing paper and for coating paper to form, e.g. washable wallpaper.ALSO:A water-resistant amylaceous film is produced on the surface of a base material by applying both an aqueous dispersion of a water-soluble starch phosphate ester and an aqueous solution of a water-soluble salt of aluminium, 3-valent chromium or iron, zirconium, titanium or 4-valent tin to the surface, thus forming in situ an insoluble film, and then drying the material.  The base material may be paper or textiles.  The starch may be natural starch, modified starch, dextrin or water-soluble starch derivatives such as ethers and esters.  The phosphate esters may be obtained by heating starch with water-soluble ortho-, pyro-, meta- or poly-phosphates, with alkali metal orthophosphates and urea, or with a phosphoric or pyrophosphoric acid, with or without other inorganic acids, and urea. The metal salt may be a formate, acetate, sulphate, nitrate or chloride.  The base material may be treated first with the starch phosphate ester and then with the metal salt, and may be dried between the two treatments. Alternatively the metal salt and the starch phosphate ester may be applied together in an ammoniacal or alkaline solution, and the alkalinity subsequently removed, e.g. by evaporation of ammonia, or by dilute acid.  The aqueous solution of the metal salt may also contain emulsified paraffin wax or polyethylene.  The aqueous dispersion of starch phosphate ester may contain a finely divided mineral pigment, e.g. china clay or chalk. The method can be used for sizing, finishing and printing the surface of textile materials, for producing water-resistant adhesive bonds, for surface-sizing paper and for coating paper to form, e.g., washable wallpaper.