Patent DE-102011116207-A1 (DE)
Title: New bisimide compounds comprising aminoperylene-bisimide compounds, diaminoperylene-bisimide compounds and aminonaphthalene-bisimide compounds useful e.g. as pigments and dyes for mass coloring of polymers e.g. PVC, and glue colors
Inventor: LANGHALS HEINZ
IPC: C09B5/62
Filed: 2011-10-14
Abstract: Bisimide compounds (Q) comprising aminoperylene-bisimide compound (VIII), diaminoperylene-bisimide compound (IX) and aminonaphthalene-bisimide compound (XII) are new. Bisimide compounds (Q) comprising aminoperylene-bisimide compound of formula (VIII), diaminoperylene-bisimide compound of formula (IX) and aminonaphthalene-bisimide compound of formula (XII) are new. R1-R12 : H or linear at least to maximum 37C-alkyl, in which 1-10 CH 2units are optionally replaced by carbonyl group, O, S, Se, Te, cis or trans -CH=CH- (in which one CH-unit is optionally replaced by N), CC, 1,2-, 1,3- or 1,4-disubstituted phenyl, 2,3-, 2,4-, 2,5-, 2,6-, 3,4- or 3,5-disubstituted pyridine, 2,3-, 2,4-, 2,5- or 3,4-disubstituted thiophene, 1,2-, 1,3-, 1,4-, 1,5-, 1,6-, 1,7-, 1,8-, 2,3-, 2.6- or 2,7-disubstituted naphthalene (in which one or two CH groups are optionally replaced by N), 1,2-, 1,3-, 1,4-, 1,5-, 1,6-, 1,7-, 1, 8-, 1,9-, 1,10-, 2,3-, 2,6-, 2,7-, 2,9-, 2.10- or 9,10-disubstituted anthracene (in which one or two CH groups are optionally replaced by N), where up to 12 single H atoms of the CH 2group are optionally replaced by F, Cl, Br, I, CN or linear up to 18C-alkyl, in which 1-6 CH 2-units are optionally replaced by carbonyl, O, S, Se, Te, cis or trans-CH=CH- (in which one CH unit is optionally replaced by N), CC, 1,2-, 1,3- or 1,4-disubstituted phenyl, 2,3-, 2,4-, 2,5-, 2,6-, 3,4- or 3,5-disubstituted pyridine, 2,3-, 2,4-, 2,5- or 3,4-disubstituted thiophene, 1,2-, 1,3-, 1,4-, 1,5-, 1,6-, 1,7-, 1,8-, 2,3-, 2.6- or 2,7-disubstituted naphthalene (in which one or two CH groups are optionally replaced by N), 1,2-, 1,3-, 1,4-, 1,5-, 1,6-, 1,7-, 1, 8-, 1,9-, 1,10-, 2,3-, 2,6-, 2,7-, 2,9-, 2.10- or 9,10-disubstituted anthracene (in which one or two CH groups are optionally replaced by N), where up to 12 single H atoms of the CH 2group are optionally replaced by F, Cl, Br, I, CN or linear up to 18C-alkyl, in which 1-6 CH 2-units are optionally replaced by carbonyl, O, S, Se, Te, cis or trans-CH=CH- (in which one CH unit is optionally replaced by N), CC, 1,2-, 1,3- or 1,4-disubstituted phenyl, 2,3-, 2,4-, 2,5-, 2,6-, 3, 4- or 3,5-disubstituted pyridine, 2,3-, 2,4-, 2,5- or 3,4-disubstituted thiophene, 1,2-, 1,3-, 1,4-, 1,5-, 1,6-, 1,7-, 1,8-, 2,3-, 2.6- or 2,7-disubstituted naphthalene (in which one or two CH groups are optionally replaced by N), 1,2-, 1,3-, 1,4-, 1,5-, 1,6-, 1,7-, 1, 8-, 1,9-, 1,10-, 2,3-, 2,6-, 2,7-, 2,9-, 2.10- or 9,10-disubstituted anthracene (in which one or two CH groups are optionally replaced by N), instead of carrying substituents the free valency of the methine group and/or quaternary carbon atom are connected in pairs to form rings e.g. cyclohexane ring and R1-R9 further comprises F, Cl, Br or I. Independent claims are included for: (1) the preparation of (VIII) and (IX); and (2) the preparation of (XII). [Image].