Patent IL-130601-A (IL)
Title: 1-arylpyrazoles, a process for their preparation and pesticidal compositions comprising them
IPC: C07D/
Filed: 1997-12-18
Abstract: A compound of the formula 1838 ז' באב התשס" ד - July 25, 2004 wherein: X is -S(O)mR6 or R7, Y is hydrogen, C-3 to C-6 alkenyl, alkynyl, formyl, alkylcarbonyl, cycloalkylcarbonyl, halocycloalkyl carbonyl, aroyl, arylalkylcarbonyl, alkylsulfonyl, arylsulfonyl, haloalkylcarbonyl, aminoalkylcarbonyl, alkylaminoalkylcarbonyl, dialkylaminoalkylcarbonyl, alkoxyalkylcarbonyl, aryloxyalkylcarbonyl, alkylthioalkylcarbonyl, alkylsulfonylalkylcarbonyl, arylthioalkylcarbonyl, N-alkylcarbamoyl, N-arylcarbamoyl, N-alkylthiocarbamoyl, N-arylthiocarbamoyl, alpha- hydroxyarylalkylcarbonyl, hydroxyalkylcarbonyl, carboxyalkylcarbonyl, alkoxycarbonylalkylcarbonyl, -P(=O)(O- Alkyl)2,-P(=S)(O-alkyl)2, -P(=O)(S-alkyl)2, -P(=S)(S-alkyl)2, trialkylsilyl, alkylcarbonylaminoalkylcarbonyl, alkylcarbonyloxyalkylcarbonyl, aryl, pyridinyl, pyrimidinyl, -C(=O)S-alkyl, -C(=O)S-aryl, -C(=O)S-alkylaryl, alkoxyalkoxycarbonyl, alkylthioalkoxycarbonyl, alkylsulfonylalkoxycarbonyl, arylthioalkoxycarbonyl, alkoxycarbonyl, aryloxycarbonyl and aryloxycarbonylalkylcarbonyl; or alkyl or haloalkyl both of which are unsubstituted or substituted by alkoxy, alkoxycarbonyl, carboxy, cyano, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkylthio, nitro, alkylsulfinyl, alkylsulfonyl, alkylcarbonyl, amino, alkylamino, dialkylamino, hydroxy, alkylcarbonylamino or alkylcarbonyloxy; Z is hydrogen, halogen, -C(O)R7-, S(O)nR8, -C(O)OR9, alkyl, haloalkyl, -OR9, -N=C(R10)(R11), alkenyl, hydrazino, alkylthiocarbonyl, 1H-pyrrol-l-yl or 1H-pyrazol-l-yl, -CHO, -CH=NOH, amino, R12NH or R13R14N-; R1 is hydrogen, alkyl or -NR15R16; R2 is hydrogen or halogen; R3 and R5 are hydrogen, halogen or alkyl; R4 is halogen, haloalkyl, haloalkoxy, R17S(O)p-or SF5; R6 is alkyl or haloalkyl, alkenyl or haloalkenyl, alkynyl or haloalkynyl or cycloalkyl having 3 to 5 carbon atoms; R7 is alkyl or haloalkyl; R8 is R7 or phenyl; R9 and R10 are hydrogen, alkyl or haloalkyl; R11 is alkyl, haloalkyl, alkoxy, or phenyl group which is unsubstituted or substituted by one or more groups selected from hydroxy, halogen, alkoxy, cyano, R7 or -S(O)qR7; R12, R13 and R14, which are identical or different, are R7S(O)r-, formyl, alkynyl, alkoxycarbonyl, alkylthiocarbonyl or aroyl; or alkyl, C-3 to C-6 alkenyl or -C(O) alkyl wherein the alkyl and alkenyl portions are unsubstituted or substituted by one or more R18; or R13 and R14 are joined so as together form a divalent radical having 4 to 7 atoms in the chains, this divalent radical being alkylene, alkyleneoxyalkylene or alkyleneaminoalkylene; R15 and R16 independently hydrogen or alkyl; R17 is haloalkyl; R18 is cyano, nitro, alkoxy, haloalkoxy, -C(O)R7, R8S(O)s-, C(O)OR9, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, halogen, hydroxy, aminosulfonyl, alkylaminosulfonyl or dialkylaminosulfonyl; m, n, p, q, r and s are independent of one another zero, one or two; M is C-halo, C-CH3, C-CH2F, C-CH2Cl, C-NO2, or N; or a geometric isomer, tautomeric form or pesticidally active salt thereof. 1839 ז' באב התשס" ד - July 25, 2004