Patent GB-868974-A (GB)
Title: Tertiary amine catalysts used in preparation of cellular polyurethane elastomers
IPC: C08G18/20
Filed: 1957-09-18
Abstract: A process for the production of foamed polyurethane material by conversion into the foamed condition of the reaction product of an organic diisocyanate and an active hydrogen-containing compound selected from the group consisting of hydroxy-terminated polyesters and polyethers with the aid of a tertiary amine catalyst, is characterized in that the catalyst is a substituted pyridine having an alkyl or hydroxyalkyl group attached to a ring carbon atom and is employed in an amount of from 0,05 to 5% by weight based on the combined weight of the diisocyanate and active hydrogen-containing compound.  Specified polyethers are poly- (ethylene-propylene) ether glycols, polyethylene, poly-propylene, polytrimethylene, poly-tetramethylene and polypentamethylene glycols, and polyneopentylene glycol, and those of molecular weights between 500 and 5000 can be used. Polyesters of molecular weight between 500 and 5000 are referred to.  They preferably have a hydroxyl number of about 40 to 80. Tolylene, naphthalene-1, 5, m-phenylene, bitolylene, hexamethylene and durene diisocyanates and p, p1-diisocyanato diphenyl methane are specified diisocyanates.  They may be used in conjunction with some triisocyanate.  4-Hydroxy propyl pyridine, 4-n-amyl pyridine, 2-hydroxy ethyl pyridine and 2-hydroxy propyl pyridine are specified catalysts.  They can be used in admixture with ordinary tertiary amine catalysts.  Blowing action for the foam can be provided by adding water and by dispersing in the reaction mixture a gas such as dichlorofluoromethane which changes from a liquid to a gas at room temperature or below. Emulsifiers are also preferably present.  The foamed reaction product is cured by heating at 200 DEG to 275 DEG F.  After curing beyond the tacky stage the product is preferably subjected to wringing between tight rolls of a calender mill to break the closed cell structure.  The foamed products can also be prepared by forming a prepolymer and reacting this with water, a cross-linking agent and the specified catalysts.  Fillers, antioxidants such as organic phosphites and plasticizers can be incorporated.  In examples a mixture of an adipic acid/diethylene glycol/trimethylol propane polyester, tolylene diisocyanate and an activator mixture of water, emulsifiers (nonyl phenoxy polyoxyethylene ethanol and sodium dioctyl sulphosuccinate), and the pyridine derivatives specified above are stirred together to give a foam which is cured at 100 DEG C. and subjected to wringing. Specifications 754,502 and 821,342 are referred to.ALSO:A process for the production of foamed polyurethane material by conversion into the foamed condition of the reaction product of an organic diisocyanate and an active hydrogen-containing compound selected from the group consisting of hydroxy-terminated polyesters and polyethers with the aid of a tertiary amine catalyst, is characterised in that the catalyst is a substituted pyridine having an alkyl or hydroxyalkyl group attached to a ring carbon atom and is employed in an amount of from 0,05 to 5% by weight based on the combined weight of the diisocyanate and active hydrogen-containing compound.  Specified polyethers are poly-(ethylene-propylene) ether glycols, polyethylene, polypropylene, polytrimethylene, polytetramethylene and polypentamethylene glycols, and polyneopentylene glycol, and those of molecular weights between 500 and 5000 can be used. Polyesters of molecular weight between 500 and 5000 are referred to.  They preferably have a hydroxyl number of about 40 to 80. Tolylene, naphthalene-1,5, m-phenylene, bitolylene, hexamethylene and durene diisocyanates and p,p1-diisocyanato diphenylmethane are specified diisocyanates.  They may be used in conjunction with some triisocyanate, 4-hydro conjunction with some triisocyanate, 4-hydroxypropyl pyridine, 4-n-amylpyridine, 2-hydroxyethyl pyridine and 2-hydroxypropyl pyridine are specified catalysts.  They can be used in admixture with ordinary tertiary amine catalysts.  Blowing action for the foam can be provided by adding water and by dispersing in the reaction mixture a gas such as dichlorofluoromethane which changes from a liquid to a gas at room temperature or below. Emulsifiers are also preferably present.  The foamed reaction product is cured by heating at 200 DEG  to 275 DEG  F.  After curing beyond the tacky stage the product is preferably subjected to wringing between tight rolls of a calender mill to break the closed cell structure.  The foamed products can also be prepared by forming a propolymer and reacting this with water, a cross-linking agent and the specified substituted pyridine catalysts.  Fillers, antioxidants such as organic phosphites and plasticisers can be incorporated.  In examples a mixture of an adipic/acid/diethylene glycol/trimethylolpropane polyester, tolylene diisocyanate and an activator mixture of water, emulsifiers (nonyl phenoxy polyoxyethylene ethanol and sodium dioctyl sulphosuccinate), and the pyridine derivatives specified above are stirred together to give a foam which is cured at 100 DEG C. and subjected to wringing. Specifications 754,502 and 821,342 are referred to.