Patent GB-811110-A (GB)
Title: Process and apparatus for the production of porous or homogeneous semi-finished or finished articles or products, comprising non-linear cross-linked plastics
IPC: B29B7/32
Filed: 1955-06-03
Abstract: <PICT:0811110/III/1> Apparatus for mixing reactants for the production of cross-linked plastics (see Group IV (a)) consists of a cylinder 4 in which a piston 18 may be caused to move by pneumatic, hydraulic or other means 17.  The piston has a peripheral <PICT:0811110/III/2> <PICT:0811110/III/3> groove 23 or other cavity near its lower face communicating by passages 24 with the cylinder space.  A nozzle 19 in the cylinder wall opens into the groove 23 when the piston is in the raised position and nozzles 25 in the cylinder wall open into the space below the piston in the immediate vicinity of the passages 24. One reactant is fed from a tank 1 by pump 2 and line 3 to nozzle 19 and other reactants are fed by high-speed reciprocating pumps 7 and 8 from tanks 2 and 3 to nozzles 25 by lines 9, 10 and 11.  The reactants issuing from nozzles 25 are thus injected into streams of the reactant from tank 1 issuing from passages 24 into the space below the piston.  The reactant from tank 1 may be injected at a pressure of from 1 to 100 atmospheres and by means of a pump making 50 injections per minute.  A relief valve 32 and return conduit 33 is provided.  The other reactants may be injected at 10-1000 atmospheres pressure by pumps making 50 injections per second.  When the cylinder 4, which may have a variable volume, is filled, the piston 18 is moved down to eject the mixture into a mould 31.  Simultaneously the supply of the reactant from tank 1 is cut-off by the descending piston.  The pumps 7 and 8 and the ejection valve 22 of the cylinder 4 may be controlled by a timing device 27 coupled with the movement of piston 18. Supplementary mixing may be providing it with retractable pins rotatable and providing it with retractable pins or a stream of air or gas may be blown through the material.  The mixing of the reactants may take place in the piston cavity itself.ALSO:Porous or homogeneous cross-linked products are obtained from appropriate reactive components by injecting one or more of these components into a flowing stream of another component, the flowing stream being fed under pressure into a cavity in a piston working in a cylinder, being passed from the cavity into the cylinder space on the ejection side of the piston and being mixed, in the cavity or cylinder space with the other components which are injected into the cylinder.  The resulting mixture is ejected by the piston through an adjustable discharge opening in the cylinder after the feed of the component forming the flowing stream has been cut off by movement of the piston and the injection of the other components by a control device. Suitable apparatus is described (see Group III).  The apparatus may discharge into suitable moulds.  Mixing in the cylinder may be improved by mechanical stirrers or by air or gas streams.  The process may be used to make polyunethanes, a polyester for example being fed to the piston cavity and a polyisocyanate and activator injected into the stream of polyester.  Emulsifiers and water (for foamed products) may also be introduced.  In examples: (1) and 80:20 mixture of two polyesters, one from adipic acid, butylene glycol and hexanetriol and the other from adipic acid, butylene glycol and trimethylol propane, together with silicic chalk containing 10 per cent water, the adipic ester of N-diethyl ethanolamine, diethanolamine oleate and sulphonated castor oil in suitable proportions, is fed over a period of 3 seconds at 15 atmospheres pressure to the mixing chamber of the apparatus which has a volume of 145 c.c.  Tolylene diisocyanate is injected into the polyester mixture over the same period at a pressure of 150 atmospheres, the pressure in the chamber rising to 50 atmospheres.  The final product is a rigid foam.  (2) A semi-regid foam is prepared from a 50 : 50 mixture of a polyester from adipic acid, phthalic acid and hexanetriol and a polyester from adipic acid, butylene glycol and trimethylol propane, tolylene diisocyanate, chalk containing 10 per cent water, the adipic ester of N-diethylethanolamine and sulphonated castor oil. (3) A soft foam is produced from a polyethylene adipate, water, tolylene diisocyanate, sulphonated castor oil, the adipic ester of N-diethylethanolamine and paraffin oil.  (4) A rubber-like polyunethane is obtained from a polyethylene adipate, naphthalene diisocyanate and sulphonated castor oil.  (5) A polyester resin is prepared from an unsaturated polyester and a mixture of styrene with benzoyl peroxide.