Patent GB-1517676-A (GB)
Title: Process for the production of cold-hardening foams containing urethane groups
IPC: C09K23/26
Filed: 1977-02-23
Abstract: 1517676 Polyurethane foams BAYER AG 23 Feb 1977 [27 Feb 1976] 7565/77 Heading C3R A process for the production of a coldhardening urethane group-containing foam comprises reacting at least one polyether containing at least 2 hydroxyl groups and having a molecular weight of from 750 to 100,000 with at least one polyisocyanate in the presence of water and/or an organic blowing agent and a sulphonamide emulsifier corresponding to the general formula wherein R represents an alkyl, chloroalkyl or cycloalkyl radical having from 8 to 30 carbon atoms or an alkaryl radical having from 10 to 30 carbon atoms; R<1> and R<2> each represent a hydrogen atom or a chloromethyl, methyl, ethyl or phenyl radical, m is 0-50; R<3> represents hydrogen or an alkyl, aralkyl, aryl, allyl, cyclohexyl or alkaryl radical or the group and R<4> represents cyclohexyl, phenyl, hydrogen or an alkyl, aralkyl, acyl, carbamoyl, allyl or cyanoalkyl radical having up to 20 carbon atoms. The amount of sulphonamide used is generally from 0À01 to 10% wt., based on the weight of the polyether. The polyisocyanate may be aliphatic, cycloaliphatic, aromatic, araliphatic or heterocyclic and is preferably 2,4- and/or 2,6-tolylene diisocyanate, polyphenyl polymethylene polyisocyanate or a polyisocyanate containing carbodiimide, urethane, urea, biuret, allophanate or isocyanurate groups. A monofunctional isocyanate may be used in an amount of up to 20% wt. of the polyisocyanate. The polyether may be one obtained by the polymerization of epoxides such as ethylene, propylene or butylene oxide, tetrahydrofuran, styrene oxide or epichlorohydrin on their own or by chemical addition, optionally in admixture or in succession, to starter components. Polyethers modified by vinyl polymers may also be used. The polyether may be used in admixture with a compound containing active hydrogen atoms and having a M.Wt. of up to 750, e.g. ethylene or butylene glycol, glycerol, trimethylol propane, castor oil and alkylene oxide adducts thereof, or in admixture with a polyester, polyacetal, polythioether, polyesteramide, polyamide or polycarbonate. Other optional ingredients include conventional catalysts, conventional emulsifiers and foam stabilizers, cell regulators, reaction retarders, fillers, dyes, pigments and flame proofing agents. The reaction may be carried out by the one-shot process or by the prepolymer or semi-prepolymer process preferably in a mould. In a typical example a foam is prepared by mixing (A) a trimethylolpropane-started polypropylene glycol modified with ethylene oxide (OH number 28); a trimethylol-started polypropylene glycol modified with ethylene oxide and grafted with acrylonitrile and styrene; water; diazabicyclo- 2,2,2-octane and 2,2<1>-dimethylamino diethyl ether as catalysts; a siloxane and a polyether polysiloxane, with (B) a sulphonamide of the above general formula wherein R is C12- C18-alkyl, C10-C13-alkyl or dodecylphenyl, R<1> is hydrogen, R<2> is hydrogen and/or methyl, m is 1 to 7, R<3> is hydrogen and R<4> is hydrogen, -COCH3 or -CH2CH2CN, and reacting in a mould with (c) a mixture of 2,4- and 2,6- tolylene diisocyanate and polyphenyl polymethylene polyisocyanate.