Patent GB-1057229-A (GB)
Title: Adsorption-desorption separation process
IPC: B01D53/04
Filed: 1963-12-19
Abstract: Gases are cyclically separated by introducing a mixture into a first zone containing an adsorbent with a displacing agent adsorbed thereon, thereby adsorbing at least one component of the mixture and displacing at least a portion of the displacing agent which is then fed to a second zone wherein the adsorbent contains adsorbed components of the feed, the agent displacing the components while less than 6% of the agent leaves the second zone, the procedure then being reversed.  The pressures and temperatures used for the process may be 0.5 to 500 p.s.i.a. and 70 DEG  to 800 DEG  F. preferably a higher adsorption pressure than desorption pressure is used while the direction of desorption is preferably opposite to that of adsorption. The process may be operated (a) using a single stationary bed with a surge tank to catch the displacing agent; (b) using two or more beds which are operated alternately the displacing agent being returned after separation of the sievate; or (c) using a moving bed preferably moving downwards under gravity, wherein the gas flows countercurrent to the movement of the bed, the bed having two zones divided by a barrier and having inlets for feed and displacing agent, and outlets for desorbate and sievate mixed with displacing agents.  Suitable adsorbents for the process are 5 <\>rA and 13 <\>rA molecular sieves of type A or X, silica gel, alumina, charcoal, magnesia and clays. Suitable displacing agents are polar materials such as NH3, primary, secondary and tertiary C1 to C5 alkyl amines, CO, NO, SO2, CO2, C1 to C5 alcohols, glycols, halogenated or nitrated organic compounds, e.g. CH3Cl, C2H5Cl, CH3F and CH3NO2.  Normal, iso, cyclic and aromatic hydrocarbons preferably containing 2-30C atoms may be separated from each other using this process, also olefins, sulphur, and colour bodies.  The feed stream rate may be 0.01-10 W./W./Hr. while the rate for NH3 (the preferred displacing agent) may be 0.001-5 W./W./Hr.ALSO:Gases are cylically separated by introducing a mixture into a first zone containing an adsorbent with a displacing agent adsorbed thereon, thereby adsorbing at least one component of the mixture and displacing at least a portion of the displacing agent which is then fed to a second zone wherein the adsorbent contains adsorbed components of the feed, the agent displacing the components while less than 6% of the agent leaves the second zone, the procedure then being reversed.  The pressures and temperatures used for the process may be 0.5 to 500 psia and 70 to 800 DEG F. preferably a higher adsorption pressure than desorption pressure is used while the direction of desorption is preferably opposite to that of adsorption. The process may be operated (a) using a single stationary bed with a surge tank to catch the displacing agent; (b) using two or more beds which are operated alternately the displacing agent being returned after separation of the sievate; or (c) using a moving bed preferably moving downwards under gravity, wherein the gas flows countercurrent to the movement of the bed, the bed having two zones divided by a barrier and having inlets for feed and displacing agent, and outlets for desorbate and sievate mixed with displacing agents. Suitable adsorbents for the process are 5  and 13  molecular sieves of type A or X, silica gel, alumina, charcoal, magnesia and clays.  Suitable displacing agents are polar materials such as, NH3, primary, secondary and tertiary C1 to C5 alkyl amines, CO, NO, SO2, CO2, C1 to C5 alcohols, glycols, halogenated or nitrated organic compounds e.g. CH3Cl, C2H5Cl, CH3F and CH3NO2.  Normal iso, cyclic and aromatic hydrocarbons preferably containing 2-30C atoms may be separated from each other using this process, also olefins, sulphur, and colour bodies.  The feed stream rate may be 0.01-10 W/W/Hr while the rate for NH3 (the preferred displacing agent) may be 0.001-5 W/W/Hr.