Patent EP-2730569-A1 (EP)
Inventor: BRETSCHNEIDER DR THOMAS
IPC: C07D417/04
Filed: 2009-06-04
Abstract: Nitrogen-containing heterocyclic compounds (I) and theirs salts or N-oxides are new. Nitrogen-containing heterocyclic compounds of formula (I) and theirs salts or N-oxides are new. In case (i): G 1> : N or C-halide; G 2> : thiazole group of formula (a), [1,3,4]thiadiazole group of formula (b) or 1H-pyrazole group of formula (c); R 1> : H or alkyl; G 3> : C(=X)NR 2>R 3>; X : O or S; either R 2> : alkylcarbonyl, alkoxycarbonyl or cycloalkylcarbonyl (optionally substituted by halo), H, (halo)alkyl, (halo)alkoxy, alkenyl or alkoxyalkyl; and R 3> : alkoxyalkyl, bis(alkoxy)alkyl, alkylthioalkyl, alkylcarbonylalkyl, alkylsulfinylalkyl, alkylsulfonylalkyl, alkoxycarbonylalkyl (all optionally substituted by halo), H, (halo)alkyl, cyanoalkyl, (halo)alkenyl, (halo)alkynyl, (halo)alkoxy, alkynyloxy, alkynyloxycarbonyl, or cycloalkyl, cycloalkylcarbonyl, cycloalkylalkyl, heterocyclyl, arylalkyl or hetarylalkyl (all optionally substituted), or NR 4>R 5>; or R 2>R 3>N : an optionally substituted and optionally further heteroatom containing ring; and either R 4>, R 5> : H, (halo)alkyl, cycloalkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, hetaryl or heterocyclyl; or R 4>R 5>N : an optionally substituted heterocycle. In case (ii): G 1> : CH; G 2> : [1,3,4]thiadiazole group (b) or 1H-pyrazole group (c); R 1> : H or alkyl; G 3> : C(=X)NR 2>R 3>; X : O or S; either R 2> : alkylcarbonyl, alkoxycarbonyl or cycloalkylcarbonyl (optionally substituted by halo), H, (halo)alkyl, (halo)alkoxy, alkenyl or alkoxyalkyl; and R 3> : alkoxyalkyl, bis(alkoxy)alkyl, alkylthioalkyl, alkylcarbonylalkyl, alkylsulfinylalkyl, alkylsulfonylalkyl, alkoxycarbonylalkyl (all optionally substituted by halo), H, (halo)alkyl, cyanoalkyl, (halo)alkenyl, (halo)alkynyl, (halo)alkoxy, alkynyloxy, alkynyloxycarbonyl, or cycloalkyl, cycloalkylcarbonyl, cycloalkylalkyl, heterocyclyl, arylalkyl or hetarylalkyl (all optionally substituted), or NR 4>R 5>; or R 2>R 3>N : an optionally substituted and optionally further heteroatom containing ring; and either R 4>, R 5> : H, (halo)alkyl, cycloalkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, hetaryl or heterocyclyl; or R 4>R 5>N : an optionally substituted heterocycle. In case (iii): G 1> : CH; G 2> : thiazole group (a); R 1> : H or alkyl; G 3> : C(=S)NR 2>R 3>; either R 2> : alkylcarbonyl, alkoxycarbonyl or cycloalkylcarbonyl (optionally substituted by halo), H, (halo)alkyl, (halo)alkoxy, alkenyl or alkoxyalkyl; and R 3> : alkoxyalkyl, bis(alkoxy)alkyl, alkylthioalkyl, alkylcarbonylalkyl, alkylsulfinylalkyl, alkylsulfonylalkyl, alkoxycarbonylalkyl (all optionally substituted by halo), H, (halo)alkyl, cyanoalkyl, (halo)alkenyl, (halo)alkynyl, (halo)alkoxy, alkynyloxy, alkynyloxycarbonyl, or cycloalkyl, cycloalkylcarbonyl, cycloalkylalkyl, heterocyclyl, arylalkyl or hetarylalkyl (all optionally substituted), or NR 4>R 5>; or R 2>R 3>N : an optionally substituted and optionally further heteroatom containing ring; and either R 4>, R 5> : H, (halo)alkyl, cycloalkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, hetaryl or heterocyclyl; or R 4>R 5>N : an optionally substituted heterocycle. In case (iv): G 1> : CH; G 2> : thiazole group (a); R 1> : H or alkyl; G 3> : C(=O)NR 2>R 3>; R 2> : alkylcarbonyl, alkoxycarbonyl or cycloalkylcarbonyl (optionally substituted by halo), H, (halo)alkyl, (halo)alkoxy, alkenyl or alkoxyalkyl; R 3> : alkoxyalkyl, bis(alkoxy)alkyl, alkylthioalkyl, alkylcarbonylalkyl, alkylsulfinylalkyl, alkylsulfonylalkyl, alkoxycarbonylalkyl (all optionally substituted by halo), haloalkyl, cyanoalkyl, haloalkenyl, haloalkynyl, haloalkoxy, alkynyloxy, alkynyloxycarbonyl, cycloalkyl (optionally substituted by halo, CN, (halo)alkyl, (halo)alkoxy, (halo)alkoxycarbonyl or hetaryl (which is optionally substituted by alkyl or halo)), or cycloalkylcarbonyl, cycloalkylalkyl, heterocyclyl, heterocyclylalkyl or hetarylalkyl (all optionally substituted), or arylalkyl (optionally substituted by halo, CN, (halo)alkyl, (halo)alkoxy), or NR 4>R 5>; and either R 4>, R 5> : H, (halo)alkyl, cycloalkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, hetaryl or heterocyclyl; or R 4>R 5>N : an optionally substituted heterocycle. In case (v): G 1> : CH; G 2> : thiazole group (a); R 1> : H; G 3> : C(=O)NR 2>R 3>; and R 2>, R 3> : H or alkyl. An independent claim is included for an agent comprising (I), a diluent and/or surface active substances. [Image] [Image] ACTIVITY : Pesticide; Arthropodicide; Insecticide; Arachnicide; Acaricide; Anthelmintic; Nematocide; Fungicide; Antibacterial; Virucide; Herbicide; Plant Growth Regulant; Antifouling. MECHANISM OF ACTION : None given.