Patent EA-000693-B1 (EA)
Title: Process for dimethyl ether production and recovery from methanol (variants)
Inventor: VAN DIJK CHRISTIAAN P
IPC: C07C41/09
Filed: 1996-03-11
Abstract: 1. A process for producing dimethyl ether (DME) and recovery from methanol comprising the steps of: (1) contacting a feed of methanol (MeOH) comprising a fresh portion of MeOH and a recycled stream composed of MeOH and water (H2O) with a dehydration catalyst to form a product gas composition composed of DME, MeOH and H2O; (2) distilling the product gas composition to separate and recover its DME content from its MeOH and H2O conent; (3) feeding the MeOH and H2O content from the distilling of the product gas composition to a distillation vessel to produce, (a) a bottom stream comprising a sum of H2O equal to that water content of the fresh portion of MeOH and that content of water produced by forming the DME content of the product gas, said bottom stream having a content of MeOH less than 0.5 weight % of the bottom stream, and (b) an overhead stream composed of at least 99 weight % of the MeOH content of the feed to the distillation vessel and having a mole ratio of H20:MeOH of at least 0.25, and (4) recycling the overhead stream from the distillation vessel into combination with a fresh portion of MeOH to form a feed of methanol for contact with the dehydration catalyst. 2. The process of claim 1, wherein said fresh feed portion of MeOH contains from about 3 to about 18 weight % water. 3. The process of claim 2, wherein at least 74 % of the methanol content of the feed of methanol is converted into DME. 4. The process of claim 3, wherein at least 76 % of the methanol content of the feed methanol is converted into DME. 5. The process of claim 2, wherein the overhead stream from the distillation vessel has a mole ratio of H2O:MeOH of 2.0 or less. 6. The process of claim 5, wherein the distillation vessel is operated as a stripper and the overhead stream from the stripper has a mole ratio of H2O:MeOH of at least 0.6. 7. The process of claim 6, wherein the overhead stream from the stripper has a mole ratio of H2O:MeOH of 1.0 or less. 8. The process of claim 5, wherein at least 71.5% of the methanol content of the feed methanol is converted into DME. 9. The process of claim 7, wherein at least 75% of the methanol content of the feed methanol is converted into DME. 10. The process of claim 4, wherein said fresh feed portion of MeOH contains from about 7 weight % water. 11. The process of claim 7, wherein said fresh feed portion of MeOH contains from about-3 to about 10 weight % water. 12. The process of claim 1, further comprising the step of distilling the DME recovered from the product gas composition to separate and recover higher boiling ethers from the DME. 13. The process of claim 6, wherein the bottom stream from the stripper has a content of methanol less than 0.05 weight % of the bottom stream. 14. The process of claim 6, wherein the overhead stream of the stripper is composed of at least 99.5 weight % of the MEOH content of the feed to the stripper. 15. A process for producing dimethyl ether (DME) and recovery from methanol comprising the steps of (1) contacting a feed of methanol (MeOH) comprising a fresh portion of MeOH and a recycled stream composed of MeOH and water (H2O) with a dehydration catalyst to form a product gas composition composed of DME, MeOH and H2O; (2) distilling the product gas composition to separate and recover its DME content from its MeOH and H2O content;  (3) feeding the MeOH and H2O content from the distilling of the product gas composition to a distillation vessel to produce, (a) a bottom stream comprising a sum of H2O equal to that water content of the fresh portion of MeOH and that content of water produced by forming the DME content of the product gas, said bottom stream having a content of MeOH less than 0.5 weight % of the bottom stream, and (b) an overhead stream composed of at least 99 weight % of the MeOH content of the feed to the stripper and having a mole ratio of H2O:MeOH of at least 0.6, and (4) recycling the overhead stream from the stripper into combination with a fresh portion of MeOH to form a feed of methanol for contact with the dehydration catalyst. 16. A process for producing dimethyl ether (DME) and recovery from methanol comprising the steps of: (1) contacting a feed of methanol (MeOH) comprising a fresh portion of MeOH having a water content of from about 15 to about 18 weight % and a recycled stream composed of MeOH and water (H2O) with a dehydration catalyst to form a product gas composition composed of DME, MeOH and H2O; (2) distilling the product gas composition to separate and recover its DME content from its MeOH and H2O content; (3) feeding the MeOH and H2O content from the distilling of the product gas composition to a refluxing distillation column operating at a reflux to distillate ratio (R/D) of 0.5 or less to produce, (a) a bottom stream comprising a sum of H2O equal to that water content of the fresh portion of MeOH and that content of water produced by forming the DME content of the product gas, said bottom stream having a content of MeOH less than 0.05 weight % of the bottom stream, and (b) an overhead stream composed of at least 99 weight % of the MeOH content of the feed to the distillation column and having a mole ratio of H2O:MeOH of at least about 0.25 and (4) recycling the overhead stream from the distillation column into combination with a fresh portion of MeOH to form a feed of methanol for contact with the dehydration catalyst. 17. The process of claim 16, wherein at least 76% of the methanol content of the feed methanol is converted into DME.