Patent GB-1006062-A (GB)
Title: Improvements in or relating to colour image screens
IPC: H04N9/27
Filed: 1962-05-07
Abstract: Phosphor screens for use in colour television tubes of the type in which the beam penetrates the screen to varying extends dependent upon its velocity to excite the various colours, include inert electron energy material (see Division H1), and have the following structures and compositions: three-colour multilayer screen: red phosphor-(0.7 Mg, 0.2 Cd, 0.1 Zn). SiO3 : Mn, density in grms./c.c. 3.83, green phosphor-Zn2SiO4 : Mn, density 3.9, blue phosphor-ZnS : Ag, density 4.1.  Inert separating layers may be of colloidal silica, density 1.64, or fine powder mica may be used.  Any of the phosphors may be diluted by alternate depositions of phosphor and inert material. Two-colour multilayer screen: red phosphor-(0.1 Zn, 0.9 Cd).S : Cu, density 4.76, green phosphor-Zn2SiO4 : Mn, density 3.9, inert separator layer-CaWO4, density 6.06. Silica or mica inert material may be used instead of the calcium tungstate.  The layers may be deposited by evaporation or by a settling technique described in detail.  In one method a slurry type process involves laying down successively thin layers from suspensions of particles in polyvinyl alcohol, or alternatively, gelatin, and water, the face plate meanwhile being spun at high speed.  In another method, particles are adhered to a gelatin film by absorption, a series of alternating particle dispersion and gelatin or acid baths being used after each gelatin solution bath. In an evaporation method a heat-resisting glass cylinder isolates the evaporation region within an evacuated bell-jar from the main volume of the jar.  Evaporated two-colour multilayer screen: red phosphor-ZnS-CdS(1 : 9) : Cu, density 4.8, green phosphor-Zn2SiO4 : Mn, density 3.9, separator-CaWO4, density 6.06.  Three-colour multilayer screen: red phosphor-ZnMgCdSiO3 : Mn, density 3.8, green phosphor-Zn2SiO4 : Mn, density 3.9, blue phosphor ZnS : Ag, density 4.1, separator layers-powdered mica, density 4.1. Phosphor particle sizes range from 0.4 to about 5 or 10 microns in diameter.  Screen formed by particles individually coated with a number of layers-blue phosphor particles 5 to 40 microns in diameter are coated successively with inert, green phosphor, inert and red phosphor layers and then deposited to form the screen. Alternatively, the base particles may be glass beads. In a process for making this screen as described in Specification 1,006,061, the particles are coated successively with gelatin to which succeeding particles adhere.  A final protective coating of gelatin may be provided on the individual particles.  Screen formed by single colour emitting particles deposited in a 1 : 1 : 1 mixture-the particles comprise glass beads coated with phosphor, the green and blue-emitting particles having further inert coatings of suitable thicknesses.  These particles may be used in combination with the multi-coated particles above referred to in order to improve the colours emitted.  The detailed description includes lengthy calculations and much graphical matter, including chromaticity diagrams for determining the specific thicknesses of the various layers involved in the above screens. An experimental method whereby light measurements are taken and comparison made with a standard screen as the screen is built up is also described.  Specification 993,270 is referred to.