Patent GB-723212-A (GB)
Title: Improvements in detergent compositions
Inventor: SCOTT ALAN DALTON
IPC: C11D1/52
Filed: 1951-04-23
Abstract: Detergent compositions contain an organic ionic soapless detergent and a smaller proportion of a compound having the general formula R-(Ar)n-O-R1-CO-NH-R2-OH where R is a straight or branched chain alkyl group, or an acyl group, having 4-10 carbon atoms including at least one straight chain of not less than 4 carbon atoms (counting from and including the carbon atom attached to the aromatic ring) when n is 1, or of 8-14 carbon atoms including a straight chain of at least 8 carbon atoms when n is 0, Ar represents a benzene or naphthalene nucleus, n is 0 or 1, R1 and R2 are alkylene radicals, dialkylene ether radicals or polyalkylene polyether radicals, the alkylene radicals or alkylene portions of dialkylene ether radicals or of polyalkylene polyether radicals in R1 and R2 containing 1-4 carbon atoms each and R1 and R2 containing no more than 10 carbon atoms altogether.  The alkyl or acyl group may be in the o, m, or p-position to the ether linkage when n is 1, the para isomers being generally preferred. Ar is preferably a benzene nucleus which may be further substituted, e.g. by -CH3 or -OH groups.  The alkylene radicals or portions in R1 and R2 may have straight or branched chains and may be substituted by one or more substituents such as chlorine atoms or -OH or -CN groups, provided each alkylene radical or portion does not contain more than 4 carbon atoms.  Examples of compounds which may be used are p-tert.-octylphenoxyacetethanolamide (CH3)3.C, CH2, C(CH3)2 C6H4, OCH2, CONH, CH2CH2OH, p-tert.-octylphenoxyacetisopropenolamide, -alpha-propionethanolamide, -alpha-propionisopropanolamide, and -betaacetisopropanolamide, - alpha - propionethanolamide, - alpha-propionisopropanolamide, and - betapropionethanolamide; also p-nonyl-phenoxyacethanolamide and the corresponding meta-decyl, p-n-octyl, p-capryl compounds and 4-caprylyl-3-hydroxyphenoxyacetethanolamide.  The ionic soapless detergent may be a sodium salt of a sulphonated alkaryl hydrocarbon e.g. of sulphonated dodecyl toluene, sulphonated dodecyl benzene, or of sulphonated keryl benzene, of a sulphated fatty alcohol or of a secondary alkyl sulphate.  A soap may also be present.  Diluents or builders, such as sulphates, silicates, carbonates, phosphates or salts of carboxymethylcellulose may be present, in particular phosphates, such as tetrasodiumpyrophosphate or pentasodium tripolyphosphate.  In an example the composition contains 21.5 per cent. by weight of the sodium salt of a commercial dodecyl (tetrapropylene polymer) toluene sulphonic acid, 1.5 of p-tert. octylphenoxyacethanolamide, 22.5 of tetrasodium pyrophosphate and 54.5 of other inorganic builders (mainly sodium sulphate with some sodium silicate).  In another example the ionic detergent is the sodium salt of a secondary alkyl (C8-C18) sulphuric acid, the other ingredients and their proportions being the same.  Dishwashing tests are described using detergent compositions with and without the amides of the invention and with soft water and hard water.  With soft water the detergent compositions containing the amides give a more persistent lather than those without.  The Provisional Specification describes also the preparation of p-tert.-octylphenoxyacetethanolamide (see Group IV(b)).