Patent GB-987823-A (GB)
Title: Shaped articles of normally crystalline polymers of vinylidene chloride
IPC: C08L21/00
Filed: 1963-06-11
Abstract: Compositions for the production of shaped articles comprise an intimate mixture of a normally crystalline polymer of vinylidene chloride and a minor proportion of an elastomeric material which is natural rubber of a synthetic polymer of one or more ethylenically unsaturated compounds and is compatible with the said crystalline vinylidene chloride polymer at a temperature which corresponds to the crystalline melting temperature of the polymer.  The polymer and elastomeric material may be blended in pulverulent or molten states or in the form of latices.  The vinylidene chloride polymer may be a copolymer of at least 70 weight per cent of vinylidene chloride with not more than 30 weight per cent of vinyl chloride, vinyl acetate, vinyl propionate, acrylonitrile, acrylamide, acrylic acid and the alkyl and aralkyl esters thereof, vinyl alkyl ethers, vinyl alkyl ketones, acrolein, allyl ethers and esters, butadiene and chloroprene.  The elastomeric material may be natural rubber; a polymer of a conjugated diolefin; a copolymer of a conjugated diolefin with vinyl aromatic compounds, alkyl alkenyl ketones, alkyl alkacrylates, alkyl alkenyl ketones and alkyl alkacrylates, acrylonitrile, or alkyl acrylates and alkyl alkenyl ketones; a copolymer of alkyl acrylates with alkyl alkenyl ketones and alkyl alkacrylates; a copolymer of alkyl acrylates with vinyl pyrrolidinone; chlorinated olefin polymers and copolymers; or a copolymer of ethylene with vinyl alkanoates or alkyl acrylates or alkacrylates; many suitable examples being listed.  The compositions may also comprise plasticizers, e.g. dibutyl sebacate and dioctyl phthalate, antioxidants, e.g. 2,4-dimethyl-6-(1-methylcyclohexyl) phenol, and stabilizers, e.g. metal oxides and carboxylates and epoxidized soya bean oil. Examples describe compositions comprising (1) a copolymer of vinylidene chloride and vinyl chloride with a copolymer of butadiene and methyl isopropenyl ketone and dibutyl sebacate; a copolymer of butadiene and methyl methacrylate, dibutyl sebacate and magnesium oxide; a copolymer of butyl acrylate and methyl isopropenyl ketone, dibutyl sebacate and epoxidized soya bean oil; polybutadiene, natural rubber, a copolymer of butadiene, butyl acrylate and methyl methacrylate, a copolymer of butadiene and acrylonitrile or a copolymer of chloroprene and acrylonitrile, all with dibutyl sebacate and magnesium oxide; a copolymer of butadiene and styrene, dibutyl sebacate and epoxidized soya bean oil; a copolymer of ethyl acrylate and vinyl pyrrolidone and magnesium oxide; polychloroprene and dibutyl sebacate; and a copolymer of ethylene and vinyl acetate and dibutyl sebacate; (2) copolymers of vinylidene chloride and vinyl chloride with copolymers of butadiene and methyl isopropenyl ketone; and (3) a copolymer of vinylidene chloride and acrylonitrile, a copolymer of butadiene and acrylonitrile, carbon black, a phthalate ester plasticizer, tetrasodium pyrophosphate and stearic acid.  The compositions may be moulded or extruded to form sheets and oriented films.