Patent GB-685153-A (GB)
Title: Improvements in and relating to softening compositions for rubber
IPC: C08K5/01
Filed: 1950-06-19
Abstract: A composition, particularly suitable as a softener for synthetic rubber, consists of 15-60 per cent naphthenic acids, at least 15 per cent petroleum residue, the remainder being essentially a neutral oil.  The naphthenic acids may be obtained by the acidification of alkali extracts of crude petroleum oils or their distillates, and the petroleum residue may be the remainder after removal of light ends and lubricating oils from crude petroleums; the initial boiling-point is at least 300 DEG  F. at 1 mm. Hg.  The neutral oil is defined as a volatile or distillable mineral oil.  The synthetic rubbers may be polymers of butadiene, methyl butadiene, dimethyl butadiene, pentadiene, and chloroprene, and copolymers of such monomers with vinyl acetylene, isobutylene, vinyl chloride, acrylic acid, acrylonitrile, methacrylic acid, styrene, acrolein, methyl isopropenyl ketone and vinyl ethyl ether.  The rubber may be in solid form or in the form of latex.  Vulcanizing agents and plasticizers such as sulphur, sulphur chloride, sulphur thiocyanate, peroxides, nitrobenzene, tetramethyl thiuram disulphide, zinc dibutyl dithiocarbamate, tetramethyl thiuram monosulphide, dipentamethylene-thiuram tetrasulphide, mercapto - benzthiazole, hexamethylene tetramine, aldehyde-ammonia, diphenylguanidine, diphenylthiourea, benzthiazyl disulphide, piperidinium pentamethylene dithiocarbamate, di-o-tolylguanidine, lead dimethyl dithiocarbamate, zinc oxide, lead oxide, dibutyl phthalate, dioctyl phthalate, tricresyl phosphate, triacetin, tetralin, cumar resins, factice, stearic acid, lauric acid, and pine tar may be added.ALSO:A composition particularly suitable as a softener for natural or synthetic rubber, consists of 15-60 per cent naphthenic acids, at least 15 per cent petroleum residue, the remainder being essentially a neutral oil.  The naphthenic acids may be obtained by the acidification of alkali extracts of crude petroleum oils or their distillates, and the petroleum residue may be the remainder after removal of light ends and lubricating oils from crude petroleums, the initial boiling point is at least 300 DEG  F. at 1 mm. Hg.  The term neutral oil is defined as meaning a volatile or distillable mineral oil.  The synthetic rubbers may be polymers of butadiene, methyl butadiene, dimethyl butadiene, pentadiene, and chloroprene; and copolymers of such monomers with vinyl acetylene, isobutylene, vinyl chloride, acrylic acid, acrylonitrile, methacrylic acid, styrene, acreolin, methyl isopropenyl ketone and vinyl ethyl ether.  The rubber may be in solid form or in the form of latex.  Vulcanizing agents and plasticizers such as sulphur, sulphur chloride, sulphur thiocyanate, peroxides, nitrobenzene, tetramethyl thiuram disulphide, zinc dibutyl dithiocarbamate, tetramethyl thiuram monosulphide, dipentamethylene-thiuram tetrasulphide, mercapto-benzthiazole, hexamethylene tetramine, aldehyde-ammonia, diphenylguanidine, diphenylthiourea, benzthiazyl disulphide, piperidinium pentamethylene dithiocarbamate, di-o-tolylguanidine, lead dimethyl dithiocarbamate, zinc oxide, lead oxide, dibutyl phthalate, dioctyl phthalate, dioctyl phthalate, tricresyl phosphate, triacetin, tetralin, cumar resins, factice, stearic acid, lauric acid, and pine tar may be added.