Patent GB-1116385-A (GB)
Title: Anticorrosion treatment of zinc surfaces
IPC: C25D11/38
Filed: 1965-12-03
Abstract: A water-soluble or dispersible negatively charged "resinate" in an aqueous chromate solution at a pH above 7 is used in depositing a "resinate"-chromate coating on a Zn or Zn alloy surface which is made an anode in the solution (see Division C7). The coating is cured by baking.  Specified "resinates" are ammonium (or amine) salts of polycarboxylic alkyd resin, acrylic acid resin, phenolic resin, carboxylic acid adduct drying oil and epoxy ester resin.  Many such resinates are listed.  Organic solvent may be added to the solution and also a pigment, dye or other tinting agent.  In the detailed examples, resinate solutions are made up from: (1) trimellic acid type alkyd resin (modified with linseed oil fatty acid), butyl alcohol, ammonia water, water and ammonium chromate; (2) trimellitic acid type alkyd resin (modified with dehydrated castor oil fatty acid), butyl ether of ethoxyethanol, dimethylaminoethanol, water strontium chromate and ammonium chromate; (3) fumaric acid tung oil adduct, butyl alcohol, dimethylamine, water, phthalocyanine blue, potassium chromate and bichromate; (4) a mixture of the following three compositions: (a) maleic anhydride linseed oil adduct, ethyl ether of ethoxyethanol, ammonia water and water, (b) phenol resin modified with salicylic acid, ethyl ether of ethoxyethanol, ammonia water and water, and (c) ammonium chromate; (5) acrylic resin (a copolymer of ethyl acrylate, butyl acrylate and ammonium acrylate in a solvent of water and ethanol), sodium chromate and water; (6) acrylic resin (as at 5 above), carbon black, water, an acryl emulsion, and ammonium chromate.ALSO:A resinate-chromate coating is deposited on a Zn or Zn alloy surface by making the surface an anode in an aqueous solution of a chromate and a water soluble or dispersible negatively charged resinate at a pH above 7, passing a current to deposit the resinate-chromate coating, and curing the coating by baking.  The Zn surface to be coated may comprise a film or particles of metallic Zn, e.g. galvanized sheet or metallic plate coated with Zn rich paint.  The chromate in solution may be Na, K or NH4 chromate or bichromate.  The resinate may be an amonium or amine salt of a polycarboxylic alkyd resin, acrylic acid resin, phenolic resin, carboxylic acid adduct drying oil or epoxy ester resin which is soluble in water forming resinate ion or dispersible in water in colloidal state.  Specific examples of these resinates are given. Organic solvent may be added to the solution and also a pigment, dye or other tinting agent, e.g. phthalocyanine blue or carbon black (Examples 3 and 6).  The cathode used in the electrolysis may be Fe, Al, Pt or C.  The composition of the solution may be kept constant during electrolysis by adding lacking ingredients and removing excessive ingredients, e.g. by vaporisation or by using apparatus employing a diaphragm such as a porous porcelain plate, ion exchange membrane, asbestos membrane, nylon membrane or others having selective ion permeability and electro osmotic property.  The resinate coated surface may be given a resin overcoating, e.g. of the following types:- alkyd, aminoalkyd, acryl, phenol, epoxy, urethane or oil.