Patent GB-1036746-A (GB)
Title: Compositions containing gold aryl mercaptides
IPC: B44F1/00
Filed: 1963-04-08
Abstract: An article is coated with a precious metal by applying a composition of a compound Ar-S-Au, a vehicle and a gold flux and/or a liquid bright gold, a liquid bright platinum or a liquid bright palladium and firing it. Ar is a carbocyclic aryl group, to the nucleus of which the S is directly attached. In examples (4) (A) a composition (I) of fluxed Au concentrate (II) sulphurized balsam, cyclohexanone, oil of rosemary, nitrobenzene and oil soluble red dye was brushed on to e.g. plastics, mica, titanium, steel, aluminium, glass, glass-ceramic, quartz or earthenware and fired under various conditions (infra-red, kiln, flash, lehr), (II) consisting of Au p-t-Bu mercaptide (III), Rh, Bi and Cr resinates in appropriate solvents and oil of rosemary; (B) (I) in which nitrobenzene was replaced by chloroform was applied by screening or banding on to glass or glazed earthenware and the product lehr fired to 600 DEG C.;(C) the composition used in (B) was heated on a steam bath and used for stamping, after which the glass article was kiln fired to 600 DEG C.; (D) a composition similar to (I) with addition of Ag resinate and omission of nitrobenzene was brushed on to glass (kiln fired to 600 DEG C.) and glazed earthenware (kiln fired to 740 DEG C.) to give a greenish gold film; (E) purple films were obtained by brushing on to glass and glazed ceramic (kiln fired as before) a composition of (II), Bi resinate/essential oils, rosin/turpentine, chloroform and an oil soluble red dye;(F) matte golden films were obtained by brushing on to glass and glazed earthenware (kiln fired as before) a composition of (II), Pb borate, Bi subnitrate, sulphurized balsam and oil of rosemary;(G) by similar procedures, bright Pt films were obtained using compositions of Pt resinate (or chloroptatinous n-octylmercaptide-ethyl sulphide complex), Rh resinate, a Au concentrate (IV) and a flux concentrate (V),(IV) consisting of (III), Rh resinate, sulphurized balsam and oil of rosemary and (V) consisting of Bi and Cr resinates, sulphurized balsam, cyclohexanone, oil of rosemary and oil soluble red dye;(H) bright Pd films were similarly obtained using a composition of either (IV),(V) and Pd resinate or (IV), dichlorobisdi-n-butyl sulphide Pd and a flux concentrate (VI) of Rh, Bi and Cr resinates, sulphurized balsam and cyclohexanone;(J) a burnished film was obtained by brushing on to glazed ceramic a composition of (III), HgO, Pb borate, Bi subnitrate, rosin/oil of turpentine and toluene, kiln firing to 740 DEG C. and rubbing with wet burnishing sand;(K) a thermoprastic compostion suitable for hot screening was prepared by evaporating on a steam bath a mixture of (III), Rh, Bi and Cr resinates sulphurized balsam, hydrogenated rosin, stearic acid, melamine powder and nitrobenzene, and applied by screening through stainless steel to glass at 85 DEG C. and kiln fired to 600 DEG C.; (L) a matte golden film was obtained by stamping on to glazed earthenware a sulphurized balsam-Rh resinate medium followed by dusting with a mixture prepared by grinding (III), HgO, Pb borate and Bi subnitrate and kiln firing to 740 DEG C.; (5)-(17) matte, dark golden films giving soft, lustrous films on burnishing were obtained by brushing on glazed ceramic, followed by firing as previously stated, compositions (thinned with oil of turpentine) of (VI), rosin and the Au derivatives respectively of o-, m- or p-tolyl, pentachlorophenyl, o-aminophenyl, o-carboxyphenyl, p-chlorophenyl, mixed xylyl, mixed tolyl, 2-naphthyl, phenyl, p-nonylphenyl and o-Me-p-t-Bu phenyl mercaptans (rosin omitted and toluene added in last two instances); (further examples of compositions used analogously to give semi-bright films:-)(10) Au mixed xylylmercaptides, Rh resinate, Pb borate, Bi subnitrate, sulphurized balsam, cyclohexanone and oil of rosemary, (11) Au mixed tolyl mercaptides, Au and Rh resinates (+ essential oils, hydrocarbons), (V) and oil of rosemary, (15) Ph-S-Au, Au t-dodecyl mercaptide/heptane, (VI) and oil of rosemary or Ph-S-Au, Au pinene mercaptide, (V), Rh resinate/essential oils, hydrocarbons, oil of rosemary.ALSO:Compounds of formula Ar-S-Au are prepared by reacting ArSH with Et2S-AuCl complex, e.g. Ar may be Ph; 2-, 3-, 4- or mixed tolyl; 2-naphthyl; 4-chlorophenyl; pentachlorophenyl; 2-carboxyphenyl or 2-aminophenyl.