Patent GB-703463-A (GB)
Title: Fungicidal compositions
IPC: C07D215/20
Filed: 1952-01-21
Abstract: A fungicidal composition comprises a product obtained by interacting a water-insoluble metal quinolinolate, a water-insoluble metal carboxylic acid soap and a phenol.  Metal quinolinolates specified are the calcium, barium, magnesium, beryllium, lead, mercury, manganese, cobalt, nickel, iron, copper, cadmium, silver, thallium, tin, zinc and aluminium salts of 2-hydroxyquinoline, 4-methyl-2-hydroxyquinoline, 4 - hydroxyquinoline, 2 - methyl - 4 - hydroxyquinoline 5 - hydroxyquinoline, 6 - hydroxyquinoline, 7 - hydroxyquinoline and 8 - hydroxyquinoline, and the copper salt of 5, 7 - dichloro - 8 - quinolinolate and 5, 7 - dibromo - 8 - quinolinolate.  Soaps specified are the nickel, calcium, barium, magnesium mercury, lead, cadmium, silver, thallium, manganese, cobalt, iron, copper, tin and aluminium salts of caproic, caprylic, capric, ethylhexoic, lauric, myristic, palmitic, stearic, oleic, linoleic, linolenic, palmitoleic, melissic, hydroxystearic, ricinoleic acid, rosin, mixed higher fatty acids derived from animal or vegetable sources such as sardine and other fish oils, lard, coconut oil, sesame oil, soya bean oil, tung oil and corn oil, fatty acids derived from carnauba, spermaceti, beeswax and candelilla wax, carboxylic acids derived from petroleum, naphthenic acid, tall oil fatty acids and abietic acid.  Phenols specified are phenol, octyl phenol, nonyl phenol, ortho amyl phenol, o-, m-, and p-cresol, p-chloro-m-cresol, tertiary butyl-m-cresol, p-nitro phenol, salicylaldehyde, salicylamide, o-cyclohexylephenol, resorcinol, pyrogallol, 2, 4-dichlorophenol, pentachlorophenol, picric acid, thymol, 2, 3, 4, 6-tetrachlorophenol, tetrachlorohydroquinone, 6-tertiary butyl-3-methylphenol, xylenol, chloroxylenol, 4-phenyl phenol, phenyl salicylate, p-hydroxy propiophenone, methyl salicylate, 2, 22 dihydroxy-5,51 dichlorodiphenyl methane.  The reaction product is soluble in methanol acetone, xylol, benzol, toluol, petroleum solvents, vegetable oils, fish oils, mineral oils, molten rosin and the saturated and unsaturated higher aliphatic acids containing from six to eighteen carbon atoms.  The reaction products also form stable aqueous emulsions. The resulting solutions, dispersions or emulsions may be used in the treatment of canvas, webbing, thread, yarns, rope, cord, wood, paper, leather and resins. The reaction products may be incorporated in varnishes, sealing compositions, lacquers, paints, resins such as phenol-aldehyde resins, ureaaldehyde resins, melamine-aldehyde resins, polyester resins, alkyd resins, vinyl resins, polyethylene resins and mineral and synthetic waxes and greases.  Other additions are plasticizers, e.g. glycol, glycerine, sorbitol, pentaerythritol and mannitol; driers, e.g. zinc naphthenate, lead naphthenate, cobalt naphthenate and zinc octoate; anti-oxidants, e.g. phenyl salicylate, tert-butyl catechol and guaicol; cellulose derivatives, e.g. nitrocellulose, cellulose acetate and ethyl cellulose.  Solutions may be rendered waterproof by the addition of paraffin wax, beeswax, carnauba wax, spermaceti wax and synthetic wax.ALSO:A fungicidal composition comprises a product obtained by interacting a water-soluble metal quinolinolate, a water-insoluble metal carboxylic acid soap and a phenol.  Metal quinolinolates specified are the calcium, barium, magnesium, beryllium, lead, mercury, manganese, cobalt, nickel, iron, copper, cadmium, silver, thallium, tin, zinc and aluminium salts of 2-hydroxyquinoline, 4-methyl-2-hydroxyquinoline, 4-hydroxyquinoline, 2 - methyl - 4 - hydroxyquinoline, 5-hydroxyquinoline, 6 - hydroxyquinoline, 7 - hydroxyquinoline and 8-hydroxyquinoline, and the copper salt of 5, 7-dichloro-8-quinolinolate and 5, 7-dibromo-8-quinolinolate. Soaps specified are the nickel, calcium, barium, magnesium mercury, lead, cadmium, silver, thallium, manganese, cobalt, iron, copper, tin and aluminium salts of caproic, caprylic, capric, ethylhexoic, lauric, myristic, palmitic, stearic, oleic, linoleic, linolenic, palmitoleic, melissic, hydroxystearic, ricinoleic acid, resin, mixed fatty acids derived from animal or vegetable sources such as sardine and other fish oils, lard, coconut oil, sesame oil, soya bean oil, tung oil and corn oil, fatty acids derived from carnauba, spermaceti, beeswax and candelilla wax, carboxylic acids derived from petroleum, naphthenic acid, tall oil fatty acids and abietic acids.  Phenols specified are phenol, octyl phenol, nonyl phenol, ortho amyl phenol, o-, m-, and p-cresol, p-chloro-m-cresol, tertiary butyl m-cresol, p-nitro phenol, salicylaldehyde, salicylamide, o-cyclohexylphenol, resorcinol, pyrogallol, 2, 4-dichlorophenol, pentachlorophenol, picric acid, thymol, 2, 3, 4, 6-tetrachlorophenol, tetrachlorohydroquinone, 6-tertiary butyl-3-methylphenol, xylenol, chloroxylenol, 4-phenyl phenol, phenyl salicylate, p-hydroxy propiophenone, methyl salicylate 2, 21 dihydroxy-5, 51 dichlorodiphenyl methane.  The reaction product is soluble in methanol, acetone, xylol, benzol, toluol, petroleum solvents, vegetable oils, fish oils, mineral oils, molten resin and the saturated and unsaturated higher aliphatic acids containing from six to 18 carbon atoms.  The reaction products also form stable aqueous emulsions.  The resulting solutions, dispersions or emulsions may be used in the treatment of canvas, webbing, thread, yarns, rope, cord, wood, paper, leather and resins.  The reaction products may be incorporated in varnishes, sealing compositions, lacquers, paints resins such as phenol-aldehyde resins, urea-aldehyde resins, melamine-aldehyde resins, polyester resins, alkyd resins, vinyl resins, polyethylene resins and mineral and synthetic waxes and greases.  Other additions are plasticizers, e.g. glycol, glycerine, sorbitol, pentaerythritol and mannitol; driers, e.g. zinc naphthenate lead naphthenate, cobalt naphthenate and zinc octoate; antioxidants, e.g. phenyl salicylate, tertbutyl catechol and guaicol; cellulose derivatives, e.g. nitrocellulose, cellulose acetate and ethyl cellulose, Solutions may be rendered waterproof by the addition of paraffin wax, beeswax, carnauba wax, spermaceti wax and synthetic wax.ALSO:A fungicidal composition comprises a product obtained by interacting a water-insoluble metal quinolinolate, a water-insoluble metal carboxylic acid soap and a phenol.  Metal quinolinolates specified are the calcium, barium, magnesium, beryllium, lead, mercury, manganese, cobalt, nickel, iron, copper, cadmium, silver, thallium, tin, zinc and aluminium salts of 2-hydroxyquinoline, 4-methyl-2-hydroxyquinoline, 4-hydroxyquinoline, 2-methyl-4-hydroxyquinoline, 5-hydroxyquinoline, 6-hydroxyquinoline, 7-hydroxyquinoline and 8-hydroxyquinoline, and the copper salt of 5, 7-dichloro-8-quinolinolate and 5, 7-dibromo-8-quinolinolate. Soaps specified are the nickel, calcium, barium, magnesium, mercury, lead, cadmium, silver, thallium, manganese, cobalt, iron, copper, tin and aluminium salts of caproic, caprylic, capric, ethylhexoic, lauric, myristic, palmitic, stearic, oleic, linoleic, linolenic, palmitoleic, melissic, hydroxystearic, ricinoleic acid, rosin, mixed higher fatty acids derived from animal or vegetable sources such as sardine and other fish oils, lard, coconut oil, sesame oil, soya bean oil, tung oil and corn oil, fatty acids derived from carnauba, spermaceti, beeswax and candellilla wax, carboxylic acids derived from petroleum, naphthenic acid, tall oil fatty acids and abietic acid.  Phenols specified are phenol, octyl phenol, nonyl phenol, nonyl phenol, ortho amyl phenol, o-, m-, and p-cresol, p-chloro-m-cresol, tertiary butyl m-cresol, p-nitro phenol, salicylaldehyde, salicylamide, o-cyclohexyl phenol, resorcinol, pyrogallol, 2, 4-dichlorophenol, pentachlorophenol, picric acid, thymol, 2, 3,4,6-tetrachlorophenol, tetrachlorohydroquinone, 6-tertiary butyl-3-methylphenol, xylenol, chloroxylenol, 4-phenyl phenol, phenyl salicylate, p-hydroxy propiophenone, methyl salicylate, 2, 21 dihydroxy -5, 51 dichlorodiphenyl methane.  The reaction product is soluble in methanol, acetone, xylol, benzol, toluol, petroleum solvents, vegetable oils, fish oils, mineral oils, molten rosin and the saturated and unsaturated higher aliphatic acids containing from six to eighteen carbon atoms. The reaction products also form stable aqueous emulsions.  The resulting solutions, dispersions or emulsions may be used in the treatment of canvas, webbing, thread, yarns, rope, cord, wood, paper, leather and resins.  The reaction products may be incorporated in varnishes, sealing compositions, lacquers, paints, resins such as phenol-aldehyde resins, urea-aldehyde resins, melamine-aldehyde resins, polyester resins, alkyd resins, vinyl resins, polyethylene resins and mineral and synthetic waxes and greases.  Other additions are plasticizers, e.g. glycol, glycerine, sorbitol, pentaerythritol and mannitol; driers e.g. zinc naphthenate, lead naphthenate, cobalt naphthenate and zinc octoate; anti-oxidants, e.g. phenyl salicylate, tert-butyl catechol and guaicol; cellulose derivatives, e.g. nitro-cellulose, cellulose acetate and ethyl cellulose.  Solutions may be rendered waterproof by the addition of paraffin wax, beeswax, carnauba wax, spermaceti wax and synthetic wax.