Patent SG-11201806211V-A (SG)
Title: Small crystal, high surface area emm-30 zeolites, their synthesis and use
Inventor: BURTON ALLEN W
IPC: C07C211/63
Filed: 2017-01-18
Abstract: INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (43) International Publication Date 24 August 2017 (24.08.2017) WI PO I PCT (10) International Publication Number WO 2017/142666 Al 11111111111111011101111111111101011111011101011111011111111111111111111111111110111111 (51) International Patent Classification: C01B 37/02 (2006.01) C01B 39/40 (2006.01) C01B 3 9 / 3 6 (2006.01) CO7C 211/63 (2006.01) (21) International Application Number: PCT/US2017/013879 (22) International Filing Date: 18 January 2017 (18.01.2017) (25) Filing Language: English (26) Publication Language: English (30) Priority Data: 62/297,181 19 February 2016 (19.02.2016) US (71) Applicant: EXXONMOBIL RESEARCH AND ENGIN- EERING COMPANY [US/US]; 1545 Route 22 East P.O. Box 900, Annandale, NJ 08801-0900 (US). (72) Inventors: BURTON, Allen W.; 1238 Fairview Circle, Stewartsville, NJ 08886 (US). STROHMAIER, Karl, G.; 47 Rockport Road, Port Murray, NJ 07865 (US). AFE- WORKI, Mobae; 24 Kyle Drive, Philipsburg, NJ 08865 (US). KLIEWER, Christine E.; 5 Austin Hill Road, Clin- ton, NJ 08809 (US). (74) Agents: NEGRON. Liza et al.; Exxonmobil Research and Engineering Company, 1545 Route 22 East P.O. Box 900, Annandale, NJ 08801-0900 (US). (81) Designated States (unless otherwise indicated, for every kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (84) Designated States (unless otherwise indicated, for every kind of regional protection available): ARIPO (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG). arations under Rule 4.17: as to applicant's entitlement to apply for and be granted a patent (Rule 4.17(ii)) as to the applicant's entitlement to claim the priority of the earlier application (Rule 4.17(iii)) ished: with international search report (Art. 21(3)) before the expiration of the time limit for amending the claims and to be republished in the event of receipt of amendments (Rule 48.2(h)) Decl Publ W O 20 17 / 142666 Al (54) Title: SMALL CRYSTAL, HIGH SURFACE AREA EMM-30 ZEOLITES, THEIR SYNTHESIS AND USE FIG. 3 (57) : A process is disclosed for producing small crystal, high surface area crystalline materials having the MFI and/or MEL framework-type, designated as EMM-30, using as a structure directing agent tetrabutyl ammonium cations and/or tetrabutylphos - phonium cations, or 1,5-bis(N- tributylammonium)pentane dications, and/or 1,6-bis(N-tributylammonium)hexane dications. The com- positions made according to that process, as well as the various dication compositions themselves, are also disclosed.