Patent GB-593091-A (GB)
Title: Improvements in or relating to modified polymeric materials
IPC: C08G69/50
Filed: 1945-04-06
Abstract: N-Alkoxymethyl polyamides are modified by reacting with a substance containing a plurality of hydroxyl groups, which is selected from unsubstituted polyhydroxyalkanes, unsubstituted polyhydroxy cyclo alkanes and unsubstituted polyhydroxy alkenes, such as ethylene glycol, glycerol, butylene glycol, pentamethylene glycol, hexamethylene glycol, pentaerythritol, sorbitol, mannitol, inositol and 1 : 2-dihydroxy-butene-2; a monoglyceride such as the monoglycerides of stearic or palmitic acids and castor oil glycerides; hydroxy ethers such as di-b -hydroxyethyl ether, diethylene glycol; polyethylene oxides; carbohydrates such as glyceraldehyde and glucose (especially the partial acetal or boric acid derivatives of the higher sugars); cellulose derivatives which still have hydroxyl groups; monomeric reaction p  products of formaldehyde with urea and amides; polymeric hydroxyl-containing materials including hydrolysed polymers and copolymers of vinyl esters of organic carboxylic acids and polymers which contain in addition to the hydroxyl groups other groups such as ester or acetal groups, for example, polyvinyl alcohol, partially acetalised polyvinyl alcohol, a partially hydrolysed vinyl ester or a hydrolysed vinyl acetate interpolymer with ethylene, vinyl chloride, acrylonitrile, methyl methacrylate and vinylidene chloride.  The polyamide employed preferably has -CH2OR groups attached to more than 5 per cent of the carbonamide nitrogen atoms and the reaction is preferably carried out in the absence of water.  An acid catalyst may be present, e.g. maleic, p-toluene sulphonic, phosphoric acids, sodium hydrogen phosphate and hydroxylated plasticisers, fillers or pigments may be incorporated.  In the examples, the polymeric materials are prepared from (1) nitrocellulose and a N-butoxymethyl polyhexamethylene adipamide / polyhexamethylene sebacamide interpolymer; (2), (3) cellulose acetate and N-methoxymethyl polyhexamethylene adipamide; (4) finely-divided regenerated cellulose and N-methoxy methyl polyhexamethylene adipamide in the presence of maleic acid; (5) N-methoxymethyl polyhexamethylene adipamide and tetraethylene glycol or any acyclic aliphatic polyhydroxy compound having not more than eight carbon atoms and which may have interlinear oxygen atoms in the chain in the presence of maleic acid. In examples (6) to (12), N-methoxymethyl polyhexamethylene adipamide is reacted with a completely hydrolysed ethylene/vinyl acetate interpolymer, polyvinyl butyral, polyvinyl alcohol, glycerol, hexamethylene glycol and dimethylol urea, respectively.  In examples (2) and (5), yarns are prepared by extruding the filtered solution of the polymer through a spinneret into a heated air atmosphere, soaking the yarn in a bath buffered to a pH of 4, drying and heating in an oven.  The Specification as open to inspection under Sect. 91 comprises also the use of any polyhydroxy compounds, e.g. compounds containing a plurality of alcoholic hydroxyl groups and other substituents such as halogen, nitro, amino, ether, thiol, oxocarbonylic, nitrile and other groups, including mono-chlorodihydroxypropane, tris-(hydroxymethyl) nitromethane, 2 - nitro - 2 - ethyl - 1 : 5 - propanediol and the corresponding amines; triethanolamine; thiosorbitol; polyhydroxythioethers; hydroxy acids such as tartaric acid or their derivatives, such as amide or ester; starch, cellulose; cellulose partial ethers, esters, mixed esters, e.g. cellulose glycollate, cellulose acetobutyrate in amounts varying between 1 to 200 and 200 to 1 parts by weight.  When the time of reaction is short (less than a minute), temperatures of from 250 DEG to 400 DEG  C. may be employed in the production of the cross-linked polymeric composition.  In examples, an N-ethoxymethyl polyamide was applied to a cotton fabric coated with nitrocellulose; a high count sateen fabric was coated with an alcoholic solution containing maleic acid of an N-methoxymethyl polyhexamethylene adipamide; and birch veneers were bonded with an alcoholic solution containing maleic acid and an N-methoxymethyl polyhexamethylene adipamide.  This subject-matter does not appear in the Specification as accepted.