Patent GB-764355-A (GB)
Title: Process for producing thin walled tubes from normally crystalline polymers
IPC: B29C48/03
Filed: 1955-01-28
Abstract: In a process for making resilient tubing from a normally crystalline vinylidene chloride polymer in which the polymer is fused, extruded in tubular form with a wall thickness of at least 0.005 inch downwardly through air into a supercooling bath, and the supercooled tube is withdrawn from the bath at such a rate as to avoid any material stretching of the tube, the tube is passed between pinch rolls in the supercooling bath, a column of inert liquid such as mineral oil is maintained within the tube extending from the pinch rolls upwards towards the extrusion die, but terminating short of the die, the supercooled tube is submerged in and led through an inert liquid bath such as water maintained at above 60 DEG  C. but below the softening point of the polymer, that portion of the tube which is immersed in the hot liquid is filled with more of the liquid and the tube is withdrawn from the hot bath at essentially the same linear rate as it is supplied thereto.  The temperature of the supercooling bath is about 40 DEG  C. or lower and its surface is far enough from the die orifice to ensure that the stretching of the freshly extruded tube is substantially complete before the tube enters the bath.  The hot bath is kept at a temperature that will provide the fastest practical crystallization rate, preferably near 90 DEG  C.  The water inside the tubing during its passage through the hot bath should preferably be at 85-90 DEG  C.  The maximum diameter of the tubing produced is generally limited to one inch.  In the example a copolymer consisting of 85 per cent vinylidene chloride and 15 per cent vinyl chloride is extruded through an annular die having a diameter approximating to the final diameter of the tube (in this case 0.25 inch o.d.) and a width of orifice slit giving an initial wall thickness of the tube somewhat greater than the final thickness (in this case 0.005 inch), the wall thickness being adjusted by the rate of drawdown of the tube into the supercooling bath.  The tube, after passing between the pinch rolls immersed in the supercooling bath, passes over a guide roll positioned above the bath and then to a second pair of pinch rolls before it enters a hotwater bath.  The tube is filled with hot water from the second pair of pinch rolls to a third pair of pinch rolls located beyond the far end of the hot-water bath.  The hot bath is preferably provided with submerged guide rolls to maintain the tube under water.  The tube, after leaving the third pinch rolls, is collected on a wind-up drum.  The hot water is introduced into the tube in the initial stages of operation, when the tube is first led through the apparatus, and thereafter remains confined within the tube between the second and third pinch rolls.  The tubing may be used for forming ampoules whose contents are ejected by pinching the walls together.  U.S.A. Specification 2,452,080 is referred to.ALSO:In a process for making resilient tubing from a normally crystalline vinylidene chloride polymer in which the polymer is fused, extruded in tubular form with a wall thickness of at least 0,005 inch downwardly through air into a supercooling bath, and the supercooled tube is withdrawn from the bath at such a rate as to avoid any material stretching of the tube, the tube is passed between pinch rolls in the supercooling bath, a column of inert liquid such as mineral oil is maintained within the tube extending from the pinch rolls upwards towards the extrusion die, but terminating short of the die, the supercooled tube is submerged in and led through an inert liquid bath such as water maintained at above 60 DEG C. but below the softening point of the polymer, that portion of the tube which is immersed in the hot liquid is filled with more of the liquid and the tube is withdrawn from the hot bath at essentially the same linear rate as it is supplied thereto.  The temperature of the supercooling bath is about 40 DEG C. or lower and its surface is far enough from the die orifice to ensure that the stretching of the freshly extruded tube is substantially complete before the tube enters the bath.  The hot bath is kept at a temperature that will provide the fastest practical crystallization rate, preferably near 90 DEG C.  The water inside the tubing during its passage through the hot bath should preferably be at 85 DEG -90 DEG C.  The maximum diameter of the tubing produced is generally limited to one inch.  In the example a copolymer consisting of 85 per cent vinylidene chloride and 15 per cent vinyl chloride is extruded through an annular die having a p  diameter approximating to the final diameter of the tube (in this case 0,25 inch o.d.) and a width of orifice slit giving an intial wall thickness of the tube somewhat greater than the final thickness (in this case 0,005 inch) the wall thickness being adjusted by the rate of drawdown of the tube into the supercooling bath.  The tube, after passing between the pinch rolls immersed in the supercooling bath, passes over a guide roll positioned above the bath and then to a second pair of pinch rolls before it enters a hot water bath.  The tube is filled with hot water from the second pair of pinch rolls to a third pair of pinch rolls located beyond the far end of the hot water bath.  The hot bath is preferably provided with submerged guide rolls to maintain the tube under water.  The tube, after leaving the third pinch rolls is collected on a wind-up drum.  The hot water is introduced into the tube in the initial stages of operation, when the tube is first led through the apparatus, and thereafter remains confined within the tube between the second and third pinch rolls.  The tubing may be used for forming ampoules whose contents are ejected by pinching the walls together.  U.S.A.  Specification 2,452,080 is referred to.