Patent GB-1079238-A (GB)
Title: Polymers from polymerisable aminodichlorotriazine derivatives
Inventor: HONIG HANS LUDWIG
IPC: D06M15/267
Filed: 1966-02-22
Abstract: The invention comprises polymers derived from olefinically unsaturated monomers of the formula <FORM:1079238/C3/1> where A is an optionally branched alkylene group of 2 to 20 carbon atoms which may be interrupted by oxygen or sulphur atoms, R4 is hydrogen, an alkyl group of 1 to 20 carbon atoms, an optionally substituted aralkyl group, or an optionally substituted phenyl radical, R1 is hydrogen, methyl or X, with the limitation that R2 and R3 are hydrogen when R1 is X, where X is <FORM:1079238/C3/2> R2 is hydrogen or methyl and R3 is hydrogen, methyl or Y, with the limitation that R1 and R2 are hydrogen when R3 is Y, where Y is <FORM:1079238/C3/3> A is preferably of 2 to 4 carbon atoms.  Examples of aralkyl groups are benzyl, chlorobenzyl, nitrobenzyl, and b -phenylethyl. Examples of phenyl radicals are phenyl, alkylphenyl with 1 to 4 carbon atoms in the alkyl group, halogenophenyl, e.g. chlorophenyl, bromophenyl or dichlorophenyl, nitrophenyl and a phenyl carboxylic ester radical with 1 to 4 carbon atoms in the alcohol moiety of the ester group. The monomer may be copolymerized with an a ,b -unsaturated carboxylic acid, or an ester, amide or nitrile thereof, an aliphatic or aromatic vinyl or vinylidene compound, a conjugated diolefine, an a -monoolefine or a divinyl compound.  In the examples methacryloyloxyethylaminodichlorotriazine, methacryloyloxyethyl - N - phenylamino - dichlorotriazine, methacryloylpropylaminodichlorotriazine, methacryloyloxyethyl - N-aminodichlorotriazine, crotonyloxyethylamino-dichlorotriazine and methacryloyloxy - N-methylaminodichlorotriazine are used. Aqueous emulsions of the polymers containing pigments may be used as printing pastes (see Examples 11, 12 and 13).ALSO:Printing pastes comprise aqueous emulsions of polymers derived from olefinically unsaturated monomers having the formula:-  <FORM:1079238/D1-D2/1> where A is an optionally branched alkylene group of 2 to 20 carbon atoms which may be interrupted by oxygen or sulphur atoms, R4 is hydrogen, an alkyl group of 1 to 20 carbon atoms, an optionally substituted aralkyl group or an optionally substituted phenyl radical, R1 is hydrogen, methyl or X, with the limitation that R2 and R3 are hydrogen when R1 is X, where X is:-  <FORM:1079238/D1-D2/2> R2 is hydrogen or methyl and R3 is hydrogen, methyl or Y, with the limitation that R1 and R2 are hydrogen when R3 is Y, where Y is:-  <FORM:1079238/D1-D2/3> The monomers may be copolymerized with an a , b -unsaturated, carboxylic acid, or an ester, amide or nitrile thereof, an aliphatic or aromatic vinyl or vinylidene compound, a conjugated diolefine, an a -monoolefine or a divinyl compound.  In Examples 11, 12 and 13 polymers and copolymers of methacryloyloxyethylaminodichlorotriazine, methacryloyloxy-N-methylaminodichlorotriazine and methacryloyl-propylaminodichlorotriazine are used.  Pigments used are carbon black, copper phthalocyanine dye and the red azo dye of diazotised 9-amino-1-methoxy - benzene-4-sulphodiethylamide and 1-(21,31-hydroxynaphthoxylamino)-2, 4-dimethoxy-4-chlorobenzene.  The pastes are roller-printed, cylinder-printed and screen-printed on to cotton, rayon staple or polyamide fibres.