Patent GB-1098677-A (GB)
Title: Interpolymers
IPC: C09D191/00
Filed: 1965-04-07
Abstract: A substantially amorphous interpolymer of a multi-unsaturated hydrocarbon and at least one monoolefin, having an essentially saturated carbon chain as the polymer backbone, contains therein a substantial proportion of the total carbon atoms in the polymer molecule, is soluble in hydrocarbon solvent, and contains sufficient ethylenically unsaturated groups in the polymer molecule to permit substantial curing of thin films by an oxidative mechanism is made by copolymerizing the hydrocarbon and at least one monooelfin in the presence of vanadium tris(acetylacetonate) or oxybis(acetylacetonate) and an alkyl aluminium halide.  The interpolymer prior to curing may be mixed with at least one other coreactive material such as a reaction product of a glyceride oil or oil-modified alkyd resin and cyclopentadiene or a polymer thereof, or the reaction product of a drying or semi-drying oil and an unsaturated dicarboxylic acid or anhydride, or an epoxidized butadiene polymer, or an epoxy resin, or an aminoplast resin, or the residue from petroleum distillation, or a copolymer of an unsaturated carboxylic acid amide and at least one other copolymerizable ethylenic monomer. The interpolymers prior to curing can be made into clear or pigment coating compositions utilizing conventional pigments and additives. The curing can be accelerated with conventional metal driers.  An extensive list of multiunsaturated compounds are given in the Specification selected from non-conjugated polymers, conjugated alicyclic polyenes, substituted norbornenes, and unsaturated terpenes.  The alphaolefin may be ethylene, propylene, 1-butene, 2-methylpropene, 2-propylhexene-1, 4-methyl-1-pentene, 1-pentene, 1-hexene, 1-octene, 5-methyl -1-nonene, 5,6,6-trimethyl-1-decene, 1-dodecene, -1-tetradecene, 1-octadecene, styrene or vinyl toluene.  Exemplified interpolymers are of ethylene-propylene and as multi-unsaturated hydrocarbon dicyclopentadiene, methylene-2-norbornene, 1,3-cyclopentadiene, 2 - methyl - 1,5 - hexadiene, 1,7 - octadiene, and methylcyclopentadiene dimer.  Exemplified compositions are Example 9, an interpolymer of ethylene, propylene and dicyclopentadiene and the reaction product of dicyclopentadiene and linseed oil and tung oil in a ratio of 1:1, Example 10, same interpolymer as 9, with reaction product of linseed oil and maleic anhydride, Example 11, same interpolymer with a partially polymerized hydrocarbon fraction, Example 12, same interpolymer with an epoxidized butadiene polymer, Example 13, same interpolymer with an alkyd resin of acid number 4.51 composed of glycerol phthalate, ethylene glycol phthalate, excess glycol and soybean oil, Example 14 same interpolymer with a solution of an epoxy resin consisting of the reaction product of bisphenol and epichlorohydrin, Example 15, same interpolymer as 9, and a solution in butyl alcohol of a butylated melamine-formaldehyde resin, and Example 16, the same interpolymer as Example 9 with a solution in a mixture of butanol, xylene, and toluene of an interpolymer of acrylamide, styrene, and methacrylic acid which had been aftertreated with formaldehyde and butanol. The above compositions were respectively coated on phosphatized steel panels and cured by heat.ALSO:Substrates of metals, wood, glass, and plastics are coated with a composition comprising a substantially amorphous interpolymer of a multi-unsaturated hydrocarbon and at least one monoolefin, which is soluble in hydrocarbon solvents and which contains sufficient ethylenically unsaturated groups in the polymer molecule to permit curing of thin films thereof by an oxidative mechanism and at least one other coreactive material excluding unsaturated glyceride oils.  The compositions may be a solution in an organic solvent, or water-in-oil, or oil-in-water emulsion, and may also contain plasticizers, pigments, and conventional additives.  Air curing can be accelerated by heat, or by the addition of conventional metal driers.  In the examples phosphatized steel panels are coated with the following compositions and heat cured.  Example 9 an interpolymer of ethylene, propylene, dicyclopentadiene and the reaction product of dicyclopentadiene: and linseed oil and tung oil in a ratio of 1:1.  Example 10, same interpolymer as 9 with reaction product of linseed oil and maleic anhydride.  Example 11 same interpolymer with a partially polymerized hydrocarbon fraction, Example 12, same interpolymer with an epoxidized butadiene polymer, Example 13, same interpolymer with an alkyd resin of acid number 4.51 composed of glycerol phthalate, ethylene glycol phthalate, excess glycol and soybean oil, Example 14 same interpolymer with a solution of an epoxy resin consisting of the reaction product of bisphenol and epichlorohydrin, Example 15, same interpolymer as 9, and a solution in butyl alcohol of a butylated melamine-formaldehyde resin, and Example 16, the same interpolymer with a solution in a mixture of butanol, xylene, and toluene of a copolymer of acrylamide, styrene, and methacrylic acid which has been aftertreated with formaldehyde and butanol.