Patent GB-1024918-A (GB)
Title: Adhesive tapes or sheets
IPC: C09J7/22
Filed: 1963-03-04
Abstract: A normally tacky and pressure-sensitive adhesive composition comprises an elastomer, a tackifier resin, an oil-soluble heat and elastomer reactive formaldehyde resin curing agent, and a compatible acid accelerator which comprises dissolved in a suitable solvent, an alphasulphonated fatty acid having the general formula <FORM:1024918/C3/1> examples of which are given.  The curing agent may be an alkylphenol-formaldehyde resin, or an urea-formaldehyde-alcohol resin.  The accelerator may be present in amount from 0.5 to 30 parts by weight per 100 parts by weight of the elastomer.  The composition may contain from 20 to 300 parts by weight of tackifier resin, e.g. 30 to 100 parts by weight of a solid tackifier resin or 40 to 200 parts by weight of a liquid tackifier resin, per 100 parts by weight of the elastomer.  The elastomer may be natural rubber, synthetic rubber, or mixtures thereof. The tackifier resin may be a polymerized terpene resin, e.g. polymerized beta pinene, coumarone-indene resins, esters of hydrogenated rosins, chlorinated paraffins, epoxy resins, liquid polyisobutylene resins, dehydroabietic acid, diethylene glycol or glycerol ester of dehydroabietic acid, and hydrocarbon resins derived from petroleum. The adhesive composition may also contain pigments, e.g. carbon black, titanium dioxide, fillers, e.g. silicates, antioxidants and metal chelating agents.ALSO:A normally tacky and pressure sensitive adhesive tape or sheet comprises a thin flexible backing and a cured normally tacky and pressure sensitive adhesive coating applied on at least one surface of the backing, the adhesive coating having been formed from a composition comprising an elastomer, a tackifier resin, an oil-soluble heat and elastomer reactive formaldehyde resin curing agent, and a compatible acid accelerator which comprises, dissolved in a suitable solvent, an alpha-sulphonated fatty acid having the general formula:-  <FORM:1024918/B1-B2/1> examples of which are given.  The composition of the adhesive coating may be capable of being cured at 250 DEG F. in less than 2 minutes.  The curing agent may be an alkylphenol-formaldehyde resin, or an urea-formaldehyde-alcohol resin.  The accelerator may be present in amount from 0,5 to 30 parts by weight per 100 parts by weight of the elastomer.  The composition may contain from 20 to 300 parts by weight of tackifier resin e.g. 30 to 100 parts by weight of a solid tackifier resin or 40 to 200 parts by weight of a liquid tackifier resin, per 100 parts by weight of the elastomer.  The adhesive composition may be coated on the backing in an amount from 0,5 to 5 ounces per square yard.  A primer coating may be present on the surface of the backing beneath the adhesive composition.  One surface of the backing may be coated with the adhesive composition and the other surface coated with a release coating.  The elastomer may be any aldehyde resin reactive elastomer, a natural rubber, e.g. wild, plantation, crepe or reclaimed rubber; a synthetic rubber e.g. copolymers of butadiene and styrene or acrylonitrile, neoprene, butyl rubber, interpolymers of acrylic acid esters e.g. interpolymers of 2.ethylhexyl acrylate and allyl acrylate, or mixtures thereof. The tackifier resin may be a polymerized terpene resin, e.g. polymerized beta pinene, coumarone-indene resins, esters of hydrogenated rosins, chlorinated paraffins, epoxyresins, liquid polyisobutylene resins, dehydroabietic acid, diethylene glycol or glycerol ester of dehydroabietic acid, and hydrocarbon resins derived from petroleum. The adhesive composition may also contain pigments e.g. carbon black, titanium dioxide; fillers e.g. silicates; antioxidants and metal chelating agents.  The adhesive composition may be applied by direct or reverse roll, rubber roll and knife, or knife and rubber blanket. The backing may be fibrous or nonfibrous, or combinations thereof, e.g. films of ethyl cellulose, regenerated cellulose, cellulose acetate, acetate-butyrate, or propionate, vinylidene chloride-vinyl chloride and/or acrylonitrile copolymers, vinyl chloride-vinyl acetate copolymer, polyethylene, polypropylene, chlorinated polyethylene, polytetrafluoroethylene and polytrifluoromonochloroethylene, polyvinyl alcohol, polyamides e.g. nylon, styrene-acrylonitrile copolymers, polyvinyl acetals e.g. butyral, polyesters, and metallized polyesters, metals e.g. aluminium, copper, lead, iron and zinc; non fibrous films may be molecularly directed in one or more directions; fibrous backings may be of polyamide e.g. nylon, asbestos, polyester, cotton, linen, rayon, glass, glassine, paper, impregnated or unified paper, rope paper, and non woven fibres bonded at intervals adhesively or any other coated, impregnated or treated fibrous woven or non woven backing.  The adhesive tape or sheet may be produced by applying a coating of the adhesive composition to at p  least one surface of the backing and curing the coated backing at a temperature below that temperature at which the backing is adversely affected.