Patent GB-475416-A (GB)
Title: Method of and apparatus for treating waste liquor
IPC: D21C11/12
Filed: 1936-05-16
Abstract: Weak black liquor from the paper pulp industry containing sodium carbonate and sulphate, after a preliminary concentration to about 50 per cent solids, is sprayed into the upper section of a furnace in which it is converted by the action of hot combustion gases into a carbonaceous residue which falls on to a grate in the lower section of the furnace and is burnt.  The molten residue of inorganic chemicals flows into a dissolving tank in which it is dissolved in weak green liquor, a solution of predetermined concentration being withdrawn.ALSO:<PICT:0475416/III/1> <PICT:0475416/III/2> Waste liquors containing inorganic chemicals and combustible organic matter are treated in a furnace for the recovery of the inorganic chemicals by introducing the liquor in a spray, directed across the upper section of the furnace and depositing on an arresting furnace in the upper section after passing through and being heated by an ascending stream of high temperature gases, varying the path of the spray to cause the spray particles to deposit on the arresting surface over an extended area, supplying air to the furnace for the combustion of dehydrated material separating from the surface and collecting in the lower section of the furnace, and withdrawing the high temperature gases generated from the upper section of the furnace after contacting with the liquor being sprayed across the upper section of the furnace. Weak black liquor from the paper pulp industry containing sodium sulphate and carbonate after an initial concentration to about 50 per cent solids is sprayed into a vertical furnace 1 through a spray nozzle 24.  The nozzle is constructed, and is provided with mechanism for varying its position, as set forth in Specification 475,548, [Group XXIX].  The spray deposits on the side walls 7 and 8 and the rear wall 6 of the furnace as a solid carbonaceous residue which falls on to an inclined hearth 10 where it is burnt by means of air introduced through ports 67.  The resulting molten chemicals flow out through a spout 81 into a dissolving tank 91 where it is dissolved in weak green liquor entering through a pipe 92, a solution of a predetermined concentration leaving through a pipe 93.  The air for combustion is forced by a fan 60 through dampers 59, a steam-air tubular heater 62, conduits 65 and wind box 66 to the ports 67.  Secondary air may be supplied through vertical pipes 7 and ports 73 above the spray.  The combustion gases, after contacting with an inclined tube bank 100 and a steam super heater 105, a multi-pass flow being caused by baffles 103 and 104, pass into a spray tower 3.  The spray tower is divided by a baffle 112 into a narrow downflow pass 113 and a wide upflow pass 114.  Spray nozzles 115 deliver weak black liquor across the pass, evaporated liquor flowing away through a pipe 117 while the gases pass through dampers 120 to a fan 121 and a stack connection 123.  The spray tower and the fan 121 may be byepassed by operating dampers 125 and 127.  As shown in Fig. 3, the side walls 7 and 8 are provided with a row of horizontally spaced vertical water tubes 11 having numerous stud projections for supporting a layer of plastic chrome refractory 13. The lower ends of both rows of tubes are bent to a common inlet header 14, while the upper ends connect with an outlet header 15. The headers 14 and 15 are connected to the boiler circulation.  The front and rear walls are similarly provided with tubes.  The side and rear walls are provided with an inclined projecting ledge 55 whereby charred material dropping from the walls is deflected inwardly away from the walls.  The spout 81 is surrounded with a hollow jacket through which cooling fluid flows.  According to a modification, two spray nozzles are provided mounted at opposite ends of the side walls, the nozzles being preferably provided with mechanism which permits vertical oscillations only.  Specification 397,787 also is referred to.