Patent GB-607327-A (GB)
Title: Improvements in or relating to the production of viscous aqueous solutions of proteins
IPC: D01F4/00
Filed: 1946-01-30
Abstract: Stable and spinnable aqueous saline solutions of vegetable globulins are produced by incorporating into a plastic mass of about 60 per cent globulin content by weight, obtained by heating with agitation, an aqueous suspension of about 30 per cent or less concentration by weight of washed, undried vegetable globulins that have been precipitated at their isoelectric region from solution, to a temperature between 40 DEG  and 60 DEG  C. for a period of time at least sufficient for the globulins to collect into the said plastic mass, and rejecting the exuded water, an alkali metal salt of a mineral inorganic acid in such quantity that there is formed in the water retained in the said plastic mass an aqueous solution of the said salt of sufficient concentration to dissolve the vegetable globulins and thus form an aqueous saline protein solution containing about 60 per cent by weight of the globulins. The salt used may be, for example, sodium chloride or sodium sulphate.  The solutions may be extruded in filamentary form and the filaments can be dry spun or coagulated in an acidified concentrated aqueous saline solution containing an organic compound, e.g. ethyl alcohol or acetic acid. In an example, a peanut globulin-water mixture, prepared from peanut meal by removing the oil and then extracting with sodium hydroxide solution and precipitating from the filtered extract with sulphur dioxide at pH 5.0-5.2, is heated to 55 DEG  C.  The exuded water is removed and common salt is added to the plastic mass to form a viscous semi-transparent material which can be extruded through a spinneret into a coagulating bath consisting of sodium sulphate, concentrated sulphuric acid, ethyl alcohol and water.ALSO:Stable and spinnable aqueous saline solutions of vegetable globulins are produced by incorporating into a plastic mass of about 60 per cent globulin content by weight, obtained by heating with agitation, an aqueous suspension of about 30 per cent or less concentration by weight of washed, undried vegetable globulins that have been precipitated at their iso-electric region from solution, to a temperature between 40 DEG  and 60 DEG  C. for a period of time at least sufficient for the globulins to collect into the said plastic mass, and rejecting the exuded water, an alkali metal salt of a mineral inorganic acid in such quantity that there is formed in the water retained in the said plastic mass an aqueous solution of the said salt of sufficient concentration to dissolve the vegetable globulins and thus form an aqueous saline protein solution containing about 60 per cent by weight of the globulins. The salt used may be, for example, sodium chloride or sodium sulphate.  The solutions may be extruded in filamentary form and the filaments can be dry spun or coagulated in an acidified concentrated aqueous saline solution containing an organic compound, e.g. ethyl alcohol or acetic acid. In an example, a peanut globulin-water mixture, prepared from peanut meal by removing the oil and then extracting with sodium hydroxide solution and precipitating from the filtered extract with sulphur dioxide at pH 5.0-5.2 is heated to 55 DEG  C.  The exuded water is removed and common salt is added to the plastic mass to form a viscous semi-transparent material which can be extruded through a spinneret into a coagulating bath consisting of sodium sulphate, concentrated sulphuric acid, ethyl alcohol and water.