Patent GB-1467485-A (GB)
Title: Process for forming a free-flowing particulate polymer mixture from a viscous tacky polymer
IPC: C08K9/08
Filed: 1974-02-25
Abstract: 1467485 Particulate polymer mixture GENERAL ELECTRIC CO 25 Feb 1974 [5 March 1973] 8360/74 Headings C3T and C3P A process for producing a free-flowing particulate mixture from a viscous, tacky and cohesive polymer and a filler comprises (a) reducing the polymer by the application of shearing force to particles of the size ranging from 0À1 micron to 25À4 mm.; and then (b) mixing the polymer particles with at least 15 p.b.w. of filler per 100 p.b.w. of polymer; and (c) recovering the resultant free-flowing particulate mixture. The polymer may be a silicone polymer in which case the process is generally carried out at 0‹ to 100‹ C., or it may be a natural or synthetic rubber, e.g. polyisoprene, polychloroprene, ethylene propylene rubber, polybutadiene, butadiene/styrene copolymer, cispolyisoprene and butadiene/acrylonitrile copolymer, or a thermoplastic polymer, in which case the process is generally carried out at 50-200‹ C. The reduction may be carried out with high speed mechanical agitators, or by high velocity impingement of a polymer stream on a solid surface in a chamber containing a dense cloud of filler. The particles are generally spherical agglomerates of a uniform composition with an internal portion of polymer uniformly covered with filler and when shearing force is applied the particles form a cohesive mass. The polymer is preferably an organopolysiloxane having a viscosity of 100,000 to 2 Î 10<SP>8</SP> Cp at 25‹C. and having the formula or one having a viscosity of 1000 to 10<SP>7</SP> Cp at 25‹ C. and having the formula wherein R is a monovalent hydrocarbon or halohydrocarbon or cyanoalkyl radical, n is 1À95 to 2À01, and t is 300 to 5210. Preferably 20-900 p.b.w. of filler per 100 p.b.w. of polymer is used. The polymer is preferably sizereduced with mechanical shear means having a mixing blade radius of from 1 to 108 inches and a blade speed of from 40 to 25,000 rotations per minute. The filler may be a reinforcing filler or an extending filler. Suitable reinforcing fillers are optionally chemically modified fumed silica, precipitated silica and silica aerogel. Suitable extending fillers are TiO 2 , lithopone, ZnO, zirconium silicate, iron oxide, diatomaceous earth, CaCO 3 , glass fibres, MgO, chromic oxide, zirconium oxide, aluminium oxide, calcined clay, crushed quartz, asbestos, carbon, graphite, cork, cotton and synthetic fibres. Optional additives such as self-bonding additives, heat stabilizers, flame retardants, process aids and a curing catalyst, e.g. an organo peroxy compound may be added before or at the same time as the polymer is being reduced to particles. The catalyst may be added after the size-reduction. In a typical example a particulate silicone mixture of particle size 10-80 microns is prepared by mixing in a Henschel mixer a mixture of a vinyl-dimethylsiloxy - terminated - dimethylpolysiloxane (15 x 10<SP>6</SP> Cp), a reinforcing silica aerogel, a process aid comprising a mixture of and then adding more of the silica filler and process aid and continuing the mixing. The resulting powder is roll-milled and then plasticized on the same mill. The resulting mass is then milled with a dicumyl peroxide catalyst and press-cured into sheets.