Patent EA-001297-B1 (EA)
Title: Selective removal and recovery of sulfur dioxide from effluent gases using organic phosphorous solvents
Inventor: BURMASTER BRIAN M
IPC: B01D53/34
Filed: 1997-08-12
Abstract: 1. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing source gas comprising: contacting a process feed gas stream comprising said source gas with a liquid solvent for selective absorption of sulfur dioxide in a sulfur dioxide absorber, thereby transferring sulfur dioxide from said process feed gas stream to said solvent and producing an exhaust gas from which sulfur dioxide has been substantially removed and a sulfur dioxide-rich solvent, said liquid solvent comprising at least one substantially water immiscible organic phosphonate diester of the formula    wherein R<1>, R<2> and R<3> are independently aryl or C1 to C8 alkyl, said organic phosphonate diester having a vapor pressure less than about 1 Pa at 25 degree  C, the solubility of water in said organic phosphonate diester being less than about 10 weight percent at 25 degree C; stripping sulfur dioxide from said rich solvent in a sulfur dioxide stripper to produce a lean solvent and a sulfur dioxide-enriched stripper gas, the ratio of the concentration of sulfur dioxide in said stripper gas to the concentration of sulfur dioxide in said source gas being greater than about 1.1; and recycling said lean solvent to said sulfur dioxide absorber for further selective absorption of sulfur dioxide from said source gas. 2. A process as set forth in claim 1 wherein said at least one organic phosphonate diester is a dialkyl alkyl phosphonate and R<1>, R<2> and R<3> are independently C1 to C6 alkyl. 3. A process as set forth in claim 2 wherein R<1>, R<2> and R<3> are identical and each contain more than three carbon atoms. 4. A process as set forth in claim 3 wherein said liquid solvent comprises dibutyl butyl phosphonate. 5. A process as set forth in claim 1 wherein said source gas contains from about 0.1 to about 5 volume percent sulfur dioxide. 6. A process as set forth in claim 5 wherein the ratio of the concentration of sulfur dioxide in said sulfur dioxide-enriched stripper gas to the concentration of sulfur dioxide in said source gas is at least about 5. 7. A process as set forth in claim 6 wherein said sulfur dioxide-enriched stripper gas contains at least about 8 volume percent sulfur dioxide. 8. A process as set forth in claim 5 wherein said sulfur dioxide-containing source gas comprises flue gas from the combustion of a sulfurous fuel or the gaseous effluent from a metal roasting operation, the incinerator of a Claus plant or the sulfur trioxide absorber of a sulfuric acid plant. 9. A process as set forth in claim 1 wherein the temperature in said sulfur dioxide absorber is maintained from about 10 degree  to about 50 degree C. 10. A process as set forth in claim 9 wherein the process fed gas stream further comprises water vapor and the temperature of said liquid solvent contacted with said process feed gas stream in said sulfur dioxide absorber is above the dew point of said process feed gas stream. 11. A process as set forth in claim 1 wherein sulfur dioxide is stripped by contacting said rich solvent with a non-condensable, oxygen-containing stripping gas in said sulfur dioxide stripper, sulfur dioxide being transferred from said rich solvent to said stripping gas to produce said sulfur dioxide-enriched stripper gas and said lean solvent. 12. A process as set forth in claim 11 wherein said non-condensable, oxygen-containing stripping gas comprises air. 13. A process as set forth in claim 12 wherein the temperature in said sulfur dioxide stripper is maintained from about 80 degree  to about 120 degree  C. 14. A process as set forth in claim 1 wherein said sulfur dioxide-enriched stripper gas is introduced into a catalytic converter for oxidation of sulfur dioxide to sulfur trioxide as part of an oxygen-containing converter feed gas stream thereby producing a conversion gas comprising sulfur trioxide, said conversion gas being contacted with sulfuric acid in a sulfur trioxide absorber for absorption of sulfur trioxide therefrom to produce sulfuric acid or oleum and a sulfur trioxide absorber depleted gas stream which exits said sulfur trioxide absorber. 15. A process as set forth in claim 14 wherein said sulfur dioxide-containing source gas comprises said sulfur trioxide absorber depleted gas stream such that sulfur dioxide is recovered from said depleted gas for ultimate conversion to sulfuric acid or oleum. 16. A process as set forth in claim 15 wherein sulfur dioxide in said sulfur dioxide-enriched stripper gas is converted to sulfuric acid in a contact sulfuric acid process comprising a single sulfur trioxide absorber. 17. A process as set forth in claim 15 wherein said catalytic converter comprises less than four catalyst beds. 18. A process as set forth in claim 1 wherein said liquid solvent comprises dibutyl butyl phosphonate, the process further comprising: introducing an oxygen-containing converter feed gas stream comprising said stripper gas into a catalytic converter for oxidation of sulfur dioxide to sulfur trioxide, thereby producing a conversion gas comprising sulfur trioxide; and contacting said conversion gas with sulfuric acid for absorption of sulfur trioxide therefrom in a sulfur trioxide absorber to produce sulfuric acid and/or oleum and a sulfur trioxide absorber depleted gas stream which exits said sulfur trioxide absorber, said sulfur dioxide-containing source gas comprising said sulfur trioxide absorber depleted gas stream such that sulfur dioxide is recovered from said depleted gas for ultimate conversion to sulfuric acid or oleum. 19. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing source gas comprising: contacting a process feed gas stream comprising said source gas with a liquid solvent for selective absorption of sulfur dioxide in a sulfur dioxide absorber, thereby transferring sulfur dioxide from said process feed gas stream to said solvent and producing an exhaust gas from which sulfur dioxide has been substantially removed and a sulfur dioxide-rich solvent, said liquid solvent comprising an organic phosphorous compound selected from phosphate triesters, phosphonate diesters, phosphinate monoesters and mixtures thereof, the substituents bonded to the phosphorous atom and the organic radicals of the ester functionality being independently aryl or C1 to C8 alkyl; stripping sulfur dioxide from said rich solvent in a sulfur dioxide stripper by contacting said rich solvent with a non-condensable, oxygen-containing stripping gas in said sulfur dioxide stripper, sulfur dioxide being transferred from said rich solvent to said stripping gas to produce a lean solvent and a sulfur dioxide-enriched stripper gas; and recycling said lean solvent to said sulfur dioxide absorber for further selective absorption of sulfur dioxide from said source gas. 20. A process as set forth in claim 19 wherein said non-condensable, oxygen-containing stripping gas comprises air. 21. A process as set forth in claim 1 wherein said sulfur dioxide-enriched stripper gas is fed to a Claus plant for the preparation of elemental sulfur. 22. A process as set forth in claim 21 wherein said Claus plant comprises an incinerator, said sulfur dioxide-containing source gas comprising gaseous effluent from said Claus plant incinerator such that sulfur dioxide is recovered from said Claus plant incinerator effluent for ultimate conversion to elemental sulfur. 23. A process as set forth in claim 1 wherein sulfur dioxide is stripped from said rich solvent under non-reducing conditions. 24. A process as set forth in claim 23 wherein at least about 90% of the sulfur dioxide absorbed in said rich solvent introduced into said stripper is transferred to said sulfur dioxide-enriched stripper gas. 25. A process as set forth in claim 18 wherein sulfur dioxide is stripped from said rich solvent under non-reducing conditions. 26. A process as set forth in claim 25 wherein at least about 90% of the sulfur dioxide absorbed in said rich solvent introduced into said stripper is transferred to said sulfur dioxide-enriched stripper gas. 27. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing source gas comprising: contacting a process feed gas stream comprising said source gas and water vapor with a liquid solvent for selective absorption of sulfur dioxide in a sulfur dioxide absorber, thereby transferring sulfur dioxide from said process feed gas stream to said solvent and producing an exhaust gas from which sulfur dioxide has been substantially removed and a sulfur dioxide-rich solvent, the temperature of said liquid solvent contacted with said process feed gas stream in said absorber being above the dew point of said process reed gas stream, said liquid solvent comprising at least one substantially water immiscible organic phosphonate diester of the formula   wherein R<1>, R<2> and R<3> are independently aryl or C1 to C8 alkyl, said organic phosphonate diester having a vapor pressure less than about 1 Pa at 25 degree C, the solubility of water in said organic phosphonate diester being less than about 10 weight percent at 25 degree C; stripping sulfur dioxide from said rich solvent in a sulfur dioxide stripper to produce a lean solvent and a sulfur dioxide-enriched stripper gas; and recycling said lean solvent to said sulfur dioxide absorber or further selective absorption of sulfur dioxide from said source gas. 28. A process for selectively removing and recovering sulfur dioxide from a sulfur dioxide-containing source gas comprising: contacting a process feed gas stream comprising said source gas with a liquid solvent for selective absorption of sulfur dioxide in a sulfur dioxide absorber, thereby transferring sulfur dioxide from said process feed gas stream to said solvent and producing an exhaust gas from which sulfur dioxide has been substantially removed and a sulfur dioxide-rich solvent, said liquid solvent comprising at least one substanti