Patent GB-1317576-A (GB)
Title: Magnesium hydroxide production
IPC: C01F5/22
Filed: 1969-10-17
Abstract: 1317576 Low boron Mg(OH) 2  BRITISH PERICLASE CO Ltd 14 Got 1970 [17 Oct 1969] 51019/69 Heading C1A A process for producing magnesium hydroxide having a low boron content from brine or sea water comprises treating brine or sea water with alkali to precipitate magnesium hydroxide, separating said precipitated magnesium hydroxide from a large part of the spent brine or sea water on which it is suspended and subsequently washing the precipitated magnesium hydroxide with aqueous alkali. Preferably the brine or sea water is added to the alkali with the result that the magnesium hydroxide is largely precipitated at a pH greater than that at equivalence. The amount of aqueous alkali used to precipitate the magnesium hydroxide is preferably up to about 5% by weight in excess of the stoichiometric weight necessary to precipitate all of the magnesium ions as magnesium hydroxide. More particularly, the precipitation of the magnesium hydroxide. may be effected in two stages by: (a) mixing, in an alkaline medium, brine or sea water with an amount of alkali in excess of the stoichiometric amount necessary to precipitate all of the magnesium ions in the brine as magnesium hydroxide and thereafter, (b) mixing fresh brine in a single stage or in two or more sub-stages, separate quantities of fresh brine being added at each sub-stage, with the alkaline suspension produced in stage (a) containing the precipitated magnesium hydroxide to precipitate further quantities of magnesium hydroxide. The alkali used for precipitating the magnesium hydroxide may be calcium or sodium hydroxide. Desirably the amount of alkali used in stage (a) is 10 to 60% by weight, in excess of the stoichiometric weight necessary to precipitate all of the magnesium ions as magnesium hydroxide. Stage (b) may comprise a number of sub-stages, e.g. from 2 to 4, preferably 1 or 2, separate quantities of fresh sea water being added at each sub-stage. Preferably at the end of the final sub-stage the total amount of sea water which has been added gives within 5% by weight of the stoichiometric weight of magnesium ions necessary to react with the alkali present in the suspension containing magnesium hydroxide. If two substages are used preferably 40 to 70% by weight of the sea water which is to be added during stage (b) is added at the first of the two substages. The washing step is carried out after separating the magnesium hydroxide precipitate from a large part of the spent sea water in which the magnesium hydroxide is suspended, the separation may be accomplished by settling or centrifugal means. Desirably the degree of separation is such as to yield a suspension containing 25 to 300 g. of magnesium hydroxide per litre of suspension. The washing operation is preferably carried out by agitating the magnesium hydroxide in admixture with the aqueous alkali (e.g. sodium or cadmium hydroxide) in a suitable vessel, e.g. a wash tank. Desirably the magnesium hydroxide content of the suspension during washing is 2 to 100 g./litre and the pH of the suspension during washing with alkali is preferably 11À5 to 13. If an aqueous solution of lime or sodium hydroxide is used during the washing step the liquors therefor may be used as, or part of, the alkali used at the beginning of the process to precipitate the magnesium hydroxide. Preferably after the alkali wash the product is subsequently washed with water. The water wash liquor may then be used in making up the alkali used at the beginning of the process before it is so used. In the two stage precipitation method part of the magnesium hydroxide suspension obtained in stage (b) may be returned for use in stage (a). Preferably the amount of magnesium hydroxide suspension by weight which is recycled to the start of the process to the amount by weight which is retained and from which product material is eventually recovered is in the range 1 : 1 to 30 : 1. In a modification of the process at least part of the sea water is first contacted with magnesium hydroxide whereby the boron in the sea water is absorbed on the magnesium hydroxide. The magnesium hydroxide obtained may be calcined to give an active magnesia suitable for example as fillers and as an intermediate for making magnesium salts. The calcined material may also be pelletized and dead-burned or just deadburned to give a high purity magnesia suitable for manufacturing refractory shapes.