Patent ES-357671-A1 (ES)
Title: Continuous process for preparing alkali metal dispersions and apparatus
IPC: C09K23/00
Filed: 1968-08-16
Abstract: Finely divided alkali metal dispersions with a particle size range of 1 to 10 microns are prepared by stirring in a mixing vessel a molten alkali metal in an inert organic medium in the presence of a dispersing aid and if necessary a stabilizing agent, passing the resulting dispersion to a classifier section of the mixing vessel, classifying the dispersion therein into a relatively coarse and a relatively fine fraction and continuously transferring the relatively coarse fraction therefrom under positive pressure through high shear equipment such as a high-pressure homogenizer or a colloid mill, for final particle size reduction, continuously passing the resulting fine dispersion from the said equipment to the mixing vessel, and continuously discharging the relatively fine fraction from the classifier section by displacement. Alloys or mixtures of two or more alkali metals may be dispersed. The dispersing aid may be compounds which act as dispersing aid and stabilizing agent, e.g. organic salts wherein the metal is displaceable by the alkali metal being dispersed such as salts of acids, alcohols, glycols and ketones of formula R-COOM, R-OM, <FORM:1070851/C1/1> , where R is an alkyl radical of from 4 to 36 carbon atoms and M is the metal, e.g. copper, aluminium, calcium, zinc, lead, and specifically copper oleate, aluminium distearate, aluminium dilaurate, calcium monostearate, lead naphthenate, zinc stearate. Compounds functioning primarily as dispersing aids, e.g. C4 to C36 acids, alcohols, glycols, ketones, diner acids of unsaturated fatty acids such as oleic or linoleic, lecithin, polymers, rubbers, must be used in conjunction with a stabilizing agent such as an inorganic salt containing metal lower in the electronegative series than the alkali metal being dispersed, e.g. magnesium chloride, cupric chloride, cuprous chloride, ferric chloride, cupric bromide, ferric sulphate. Examples of organic medium are kerosene, C12 to C20 saturated hydrocarbon alkylation products, benzene, hexane, xylene, ethers, mineral spirits, toluene. An inert gas atmosphere may be maintained in the mixing vessel, e.g. nitrogen, argon. The equipment and circulating system may be operated at any temperature between the melting point of the alkali metal and the boiling point of the organic medium. In Fig. 1 (not shown) the mixing tank, circulating conduits 8 and 10, and high shearing device 9 are charged with hydrocarbon-dispersing aid mixture. The jacket 11 of the mixing vessel is filled with heating medium, e.g. steam or oil. Molten sodium and hydrocarbon-dispersing aid are added at 1 and 2 respectively. Agitator 4 disperses molten sodium. After treatment in the high shearing device 9, the material is transported through 10 to the mixing chamber in the mixing tank. Baffle plate 5 encompasses settling section 6 in the mixing tank where the coarse material settles out and returns to the high shearing device 9 for further treatment whilst the fine dispersion in 6 is displaced through the discharge port 7, the maximum upflow in 6 being less than 0.5 feet per second by proper positioning of the baffle.