Patent GB-831898-A (GB)
Title: Compositions comprising a thermoplastic copolymer and a thermosetting aminoplast resin
IPC: C09D133/06
Filed: 1957-07-17
Abstract: Surfaces of iron, steel, copper, brass, aluminium, chromium, nickel, glass, porcelain, wood, cardboard and methyl methacrylate polymers are coated with compositions comprising (a) 5 to 95 parts by weight of a linear, water-insoluble, thermoplastic copolymer of (1) 1 to 10 mol. per cent of acrylic, methacrylic or itaconic acid; and (2) 90 to 99 mol. per cent of at least one alkyl ester of acrylic or methacrylic acid; and (b) 95 to 5 parts by weight of a thermosetting resin-forming alkoxymethyl aminoplast condensate in which the alkoxymethyl group has from 2 to 19 carbon atoms, the amount of aminoplast being at least sufficient to provide 1.5 equivalents of oxymethyl groups per equivalent of carboxyl groups in the copolymer, and the sum of the parts of copolymer and aminoplast being 100.  The compositions may also contain specified pigments and solvents (see Group IV (a)).  The compositions may be applied by spraying, dipping, brushing or oil transfer, then dried by means of infra-red rays, radio-frequency currents or heated air and then cured by heating to a temperature of from 200 DEG  to 400 DEG  F.ALSO:Textiles are sized or pigment printed or dyed by applying thereto compositions comprising (a) 5 to 95 parts by weight of a linear, water-insoluble thermoplastic copolymer of (1) 1 to 10 mol. per cent of acrylic, methacrylic or itaconic acid and (2) 90 to 99 mol. per cent of at least one alkyl ester of acrylic or methacrylic acid; and (b) 95 to 5 parts by weight of a thermosetting resin - forming alkoxymethyl aminoplast condensate in which the alkoxymethyl group has from 2 to 19 carbon atoms, the amount of aminoplast being sufficient to provide 1.5 equivalents of oxymethyl groups per equivalent of carboxyl groups in the copolymer and the sum of the parts of copolymer and aminoplast being 100.  In the case of dyeing or printing the compositions contain pigments such as titanium dioxide, copper phthalocyanine, ultramarine, zirconium oxide, lead chromate, barium sulphate, zinc chromate and carbon black and specified solvents (see Group IV (a)). After application the compositions are dried and cured by heating to a temperature of 200 DEG  to 400 DEG  F.ALSO:Compositions comprise (a) 5 to 95 parts by weight of a linear, water-insoluble, thermoplastic copolymer of (1) 1 to 10 mol. per cent of acrylic, methacrylic or itaconic acid; and (2) 90 to 99 mol. per cent of at least one alkyl ester of acrylic or methacrylic acid; and (b) 95 to 5 parts by weight of a thermosetting resin-forming alkoxymethyl aminoplast condensate in which the alkoxymethyl group has from 2 to 19 carbon atoms, the amount of aminoplast being sufficient to provide 1.5 equivalents of oxymethyl groups per equivalent of carboxyl groups in the copolymer and the sum of the parts of copolymer and aminoplast being 100.  Suitable copolymers are those derived from acrylic or methacrylic esters in which the alkyl group contains from 1 to 18 carbon atoms and mixtures of such esters, e.g. a mixture of methyl methacrylate and ethyl acrylate.  The copolymer may be of the normal type or a graft or block copolymer.  Aminoplast condensates specified are the condensation products of urea, melamine, alkyl or aryl melamines, dicyandiamide, formoguanamine, benzoguanamine, ammeline and substituted triazines (listed) with aldehydes such as formaldehyde, acetaldehyde, crotonaldehyde, acrolein, benzaldehyde, furfural or compounds which engender aldehydes, such as hexamine, paraldehyde, paraformaldehyde and trioxymethylene, the alkoxymethyl derivatives of these aminoplasts being formed with alcohols such as methyl, ethyl, butyl, 2-ethyl-butyl, 2-ethyl-hexyl, benzyl, lauryl, cetyl and stearyl alcohols, which alcohols may also be present in the compositions as a solvent for the copolymer and the aminoplast, as may other solvents such as ethyl, ethoxyethyl and butoxyethyl acetates, acetone, butanone, methyl ethyl ketone, dioxane, dimethyl formamide, dimethyl acetamide, nitroethane, nitropropane, acetonitrile, benzene, toluene, xylene, chloroform, carbon tetrachloride and ethylene dichloride.  Also present may be pigments such as titanium dioxide, copper phthalocyanine, ultramarine, zirconium oxide, lead chromate, barium sulphate zinc chromate and carbon black.  The compositions, which are used in coating applications, may be heat-cured to an insoluble, infusible state by co-reaction between the aminoplast and the copolymer.