Patent GB-1196022-A (GB)
Title: Membrane Separation.
IPC: B01D69/10
Filed: 1967-06-20
Abstract: 1,196,022. Dialysis unit; membrane separation units; coating apparatus. DORR-OLIVER Inc. 20 June, 1967 [7 July, 1966], No. 28407/67. Headings B1X, B2L and B2K. A membrane separation .unit for use in apparatus for separating a feed liquid into a concentrated mother liquor and a liquid effluent is produced by combining a plurality of .porous plates 22 in Figure 1 having fluid conducting interstices with a liquid impermeable partition 28 such that the ends of the plate 22 extend through partition 28, and subsequently dipping the assembly in a bath of a selectively-permeable, membrane-forming liquid, withdrawing .the assembly and treating the liquid coating to form a selectively-permeable membrane adhering to the surfaces of plates 22 e.g. by dipping in a water bath. The unit is disposed in a housing 21 provided with feed inlet 23, concentrate outlet (25) and an effluent outlet 27. The partition 28 is provided with an 0-ring 29 engaging housing 21 to seal channels 24 from effluent outlet. 27. A partial vacuum Imay 'be applied to the interior of the porous plates during dipping. The plates may be pre-treated e.g. by dipping in water or a silicon treatment to prevent impregnation of the membrane-forming liquid. They may comprise a laminated sheet .structure having an open porous core lamina, .the opposite sides of the core lamina being covered 'by outer laminae having .relatively fine pores. The core and the outer laminae may comprise a phenolic -resin-treated paper bonded together by heat and not greater than 10-lbs. in<SP>2</SP>, pressure. The edges are sealed with a membranecompatible liquid. Selectively permeable membrane materials mentioned are cellulose, cellulose acetate, acrylics, polyvinyl acetate, protein resins, nylon, urea- and melamine--formaldehyde resins. The unit is assembled by inserting the plates in pre-cut slots in the impermeable partition using an adhesive to secure the members together. Alternatively the partition may 'be moulded or east about the edges of the .plates and a material capable of bonding with the plates and the partition applied at the line .of intersection between the sheet and the partition. Sealant material may be applied subsequent to applying the membrane. In a further embodiment (Figs. and 4 not shown) a membrane separation unit incorporates membrane-supporting members which are spirally configured and have inner ends extending .through an impermeable .partition in theform of a closed end tube. Coaling apparatus. In Fig. 9 dipping apparatus 150 comprises a plurality of rail sections 152, 154, 156, 158, 160 .supporting a plurality of wheeled carriages 162 adapted to mount assembled membrane separation units structures for dipping in a membrane-forming bath, each carriage 162 being provided with internal passageways 164 leading to one or more retainers 165 which sealingly mount the unit structures on the carriage with the effluent spaces in communication with passageways 164. Each carriage passageway 164 has an opening 166 adapted for connection to conduits 170 and 172. In a pretreatment step wherein the porous sheets are treated to prevent impregnation of the membrane-forming liquid into the porous sheet the carriage is moved to station 154 where the cartridge structures are .lowered by screw assembly 175 to dip the exposed portions of .the porous sheets in a first water bath 173. The carriage then moves, to station 156 where the cartridges are dipped into a bath 174 of a filmforming liquid. Screw jack asserablys are adapted to permit control of the rate of immersion and rate of withdrawal from this bath. At this dipping .station .passageways 164 and the carriage are connected to a conduit .170 and a slight vacuum - is applied .through conduit 170. The carriage then moves to station 158 where the coated cartridges are dipped in a bath 177 e.g. of water.