Patent GB-913731-A (GB)
Title: Separating hydrocarbons by a solvent extraction process
Inventor: JONES EVAN ARTHUR
IPC: C07C7/10
Filed: 1961-08-08
Abstract: <PICT:0913731/III/1> In the separation of aromatic from nonaromatic hydrocarbons the feed is introduced by line 2 into an extraction zone 1 where it is contacted in countercurrent with a solvent selective for aromatics boiling above the aromatic components of the feed and containing water introduced by line 3, the raffinate (line 5) and extract (line 7) are separately removed and the extract is distilled in a column 11 to separate an overhead (line 13) containing only a part of the aromatics and a vaporous side stream (line 30) from the solvent recovered as bottoms (line 26) and the vaporous side stream is introduced directly into a rectifying zone 32 where water is separated overhead (line 34) from the aromatic hydrocarbons (line 38) and the aqueous distillate is used to wash the raffinate from line 5 and the aromatic concentrate from line 38.  Suitable solvents are alcohols, glycols, glycol-ethers and -esters, sulphones, phenols and their ethers, nitriles and cyano-ethers and amines, which contain 2-25% by weight of water. Extraction is effected at 0,7-20 atmospheres (to maintain liquid phase) and 100 DEG -300 DEG C. with 5-15 volumes of solvent per volume of feed.  The overhead from column 11 containing light paraffins and some light aromatics (the remainder being forced into the side cut) is condensed in vessel 16 and after removal of water is returned to the extraction by line 4 as reflux. Aromatic hydrocarbons in the overhead from column 32 are separated from water in vessel 37 and returned to the column as reflux and joined with higher boiling aromatics in line 38.  The water from vessel 37 in line 45 may wash first the aromatics and then the raffinate before being fed to the reboiler in column 11 but preferably is divided into two parts as shown to contact raffinate in tower 6 and aromatics in tower 40 in each of which any solvent is recovered from the hydrocarbons by the washing water.  Water from tower 6 which may contain some non-aromatics is fed to vessel 16 where non-aromatics are displaced by aromatics and returned to the extraction with the reflux.  Water from vessel 16 and tower 40 are mixed and fed to column 11, if desired after converting to steam. Solvent in line 26 is returned to the extraction.ALSO:<FORM:0913731/IV (b)/1> In the separation of aromatic from non-aromatic hydrocarbons the feed is introduced by line 2 into an extraction zone 1 where it is contacted in countercurrent with a solvent selective for aromatics boiling above the aromatic components of the feed and containing water introduced by line 3, the raffinate (line 5) and extract (line 7) are separately removed and the extract is distilled in a column 11 to separate an overhead (line 13) containing only a part of the aromatics and a vaporous side stream (line 30) from the solvent recovered as bottoms (line 26) and the vaporous side stream is introduced directly into a rectifying zone 32 where water is separated overhead (line 34) from the aromatic hydrocarbons (line 38) and the aqueous distillate is used to wash the raffinate from line 5 and the aromatic concentrate from line 38. Suitable solvents are alcohols, glycols, glyco-ethers and -esters, sulphones, phenols and their ethers, nitriles and cyano-ethers and amines, which contain 2-25% by weight of water. Extraction is effected at 0.7-20 atmospheres (to maintain liquid phase) and 100-300 DEG C. with 5-15 volumes of solvent per volume of feed.  The overhead from column 11 containing light paraffins and some light aromatics (the remainder being forced into the side cut) is condensed in vessel 16 and after removal of water is returned to the extraction by line 4 as reflux.  Aromatic hydrocarbons in the overhead from column 32 are separated from water in vessel 37 and returned to the column as reflux and joined with higher boiling aromatics in line 38.  The water from vessel 37 in line 45 may wash first the aromatics and then the raffinate before being fed to the reboiler in column 11 but preferably is divided into two parts as shown to contact raffinate in tower 6 and aromatics in tower 40 in each of which any solvent is recovered from the hydrocarbons by the washing water.  Water from tower 6 which may contain some non-aromatics is fed to vessel 16 where non-aromatics are displaced by aromatics and returned to the extraction with the reflux.  Water from vessel 16 and tower 40 are mixed and fed to column 11, if desired after converting to steam. Solvent in line 26 is returned to the extraction.