Patent GB-907688-A (GB)
Title: Improvements in or relating to the production of cured coatings of polymeric material
Inventor: HUGHES THOMAS PICTON
IPC: G21K5/10
Filed: 1960-03-24
Abstract: An article or surface is provided with a cured coating by exposing liquid polymeric coating material of a kind that undergoes radiation curing to the action of a beam of electrons sufficient eventually to cause at least partial curing of the material, and subsequently applying this irradiated material to the article or surface before the curing process initiated by the beam of electrons has proceeded far enough to cause gelation of the material.  The <PICT:0907688/III/1> coating material may be exposed to the electron beam while freely suspended or falling in a gaseous atmosphere, which may be of air or of an inert gas such as nitrogen, carbon dioxide or argon.  As illustrated a polyester paint incorporating styrene monomer is forced under pressure through a slot 2 in a container 1, and issues as a falling curtain 3 bounded by vertical guide wires W. The curtain is scanned by a beam 8 of electrons from an electron generator 9.  Articles 6, to be coated, are traversed through the curtain by conveyers 4 and 5 between which is a gap permitting unused paint to fall into a trough 7.  The electron beam may be shut off when an article is not present, thus enabling the surplus paint to be re-used.  In another embodiment, paint sprayed from an ordinary spray-gun fed with compressed air or with an inert gas, such as nitrogen, may be subjected to an electron beam during its passage to an article to be coated.  The article may be given a positive potential so as to attract the paint particles, which acquire a negative charge.  The rate of curing may be varied by heating or cooling the paint, by heating the article before or after coating, or by altering the composition of the paint. Suitable paints include polymers containing olefinic unsaturation, either alone or mixed with reactive monomers, and polymers based on polysiloxanes.  According to the Provisional Specification, gamma rays and X-rays can be used for irradiating the coating material.ALSO:An article or surface is provided with a cured coating by exposing liquid polymeric coating material of a kind that undergoes radiation curing to the action of a beam of electrons sufficient eventually to cause at least partial curing of the material, and subsequently applying this irradiated material to the article or surface before the curing process initiated by the beam of electrons has proceeded far enough to cause gelation of the material.  The coating material may be exposed to the electron beam while freely suspended or falling in a gaseous atmosphere, which may be of air or of an inert gas such as nitrogen, carbon dioxide or argon.  The rate of curing may be varied by heating or cooling the paint, by heating the article before or after coating, or by altering the composition of the paint.  Suitable paints include polymers containing olefinic unsaturation, e.g. unsaturated polyesters either alone or mixed with reactive monomers, e.g. styrene, and polymers based on polysiloxanes. According to the Provisional Specification, gamma rays and X-rays can be used for irradiating the coating material.