Patent GB-1122073-A (GB)
Title: Siloxane release agents
IPC: B29C33/64
Filed: 1966-01-06
Abstract: An antisticking agent comprises by wt. (a) 100 pts. of a poly-siloxane curable to an elastomer and consists essentially of 0 to 15 mol per cent of units selected from <FORM:1122073/C3/1> and [(C6H5)2SiO], the remaining units having the formula <FORM:1122073/C3/2> where R is a methyl or ethyl radical, and (b) from 0.5 to 100 pts. of a polymer consisting essentially of units selected from butylene and propylene and having a molecular wt. of over 400. Siloxane (a) may contain (i) terminal acetoxy radicals and will cure on exposure to atmospheric moisture; (ii) trimethyl-siloxy terminal groups and will cure on heating with t-butyl peroxide; (iii) terminal vinyl radicals and will cure on mixing with a siloxane containing Si-bonded H, in the presence of chloroplatinic acid, and (iv), which is preferred, terminal OH radicals and will cure on heating with ethyl-polysilicate as cross-linking agent.  Polymer (b) preferably contains more than 60 mol per cent of isobutylene units and preferably has a M.W. of over 800 but not more than 2000. Ingredients (a) and (b) can be mixed by melting the ingredients, if they are not already liquid, but are best mixed by dissolving or dispersing them together in a solvent, e.g. xylene, ethanol, b -methoxyethanol, benzene, hexane, heptane, diethylether, methylethylketone, tetrahydrofuran, cyclopentane, cycloheptane or isopropanol. In examples, a silicone composition consisting of an OH-terminated dimethylpolysiloxane, a methylhydrogenpolysiloxane, SiO2 as stabilizer and dibutyl tin dioctoate as curing catalyst, was mixed with varying proportions of (1, 2, 4) polyisobutylenes of different molecular wts., or (3) polypropylene; (5) an acetoxyterminated dimethyl-polysiloxane was mixed with a polymer containing equimolar proportions of propylene and isobutylene units. Uses.-For applying to various substrates to provide abhesive surfaces thereon (see Division B2).ALSO:A substrate, e.g. glass, stone, plastic, rubber, metal, or wood, but preferably a cellulosic sheet material such as regenerated cellulose, corrugated paper, kraft paper, cardboard, cellulose acetate, wrapping paper or cotton fabric, is rendered adhesive (1) by coating it with a curable film comprising, by wt., (a) 100 pts. of an elastomer-forming polysiloxane consisting essentially of 0 to 15 mol% of units selected from <FORM:1122073/B1-B2/1> and [(C6H5)2 SiO] units, the remaining units having the formula <FORM:1122073/B1-B2/2> , where R is -CH3 or -C2H5, and (b) from 0.5 to 100 pts. of a polymer consisting essentially of units selected from butylene and propylene, and having a mol. wt. of over 400, (see Division C3), and (2) curing the film, whereby an abhesive surface is formed.  The release agent is preferably used in the form of a dispersion of from 1 to 40% (wt.) of the composition in 60 to 99% of a volatile organic solvent, as the means of applying the composition to the substrate on which it is to be cured, and curing can be effected at room or elevated temperature.  In a typical Example (1) a xylene dispersion of a hydroxy-terminated dimethylpolysiloxane, a methylhydrogenpolysiloxane, silica (as stabiliser), dibutyltridioctoate and a polyisobutylene (M.W.=1500) was used to coat stiff paper by drawdown with a Mayer rod, with subsequent curing at 120 DEG C. for 2 mins.