Patent GB-799627-A (GB)
Title: Recovery of uranium from aqueous solutions
IPC: C10M137/10
Filed: 1956-11-19
Abstract: Uranium ions are recovered from an aqueous solution containing them by adding to the aqueous solution a water-soluble alkali metal salt or alkaline earth metal salt of a dialkyl dithiophosphate containing from 1 to 6 carbon atoms in each alkyl group and then extracting the resultant uranium dialkyl dithiophosphate from said aqueous solution with a water-immiscible ether to recover the uranium ions.  The aqueous solution may contain ions of other metals in addition to uranium ions, e.g. alkali metal, alkaline earth metal and heavy metal ions, and water-insoluble material which is formed when heavy metal ions are present is separated by filtration or by extraction with a water-immiscible non-polar organic solvent, e.g. a saturated aliphatic hydrocarbon, before extracting the uranium dialkyl dithiophosphate with the water-immiscible ether.  The process is applicable to the recovery of uranium from aqueous solutions obtained from conventional uranium ore refining operations or to various wash solutions produced in the separation of uranium 235 from naturally occurring uranium.  Specified metals which may be present in addition to uranium are iron, antimony, cadmium, manganese, calcium, cobalt, nickel, chromium, mercury, copper, silver, lead, tin, barium, vanadium, indium, sodium and potassium.  Specified dialkyl dithiophosphates which may be used are potassium diisopropyl-, sodium dimethyl-, calcium dihexyl-, barium dibutyl-, and potassium methyl propyl dithiophosphates.  It is preferred that the pH of the aqueous solution to which the dialkyl dithiophosphate is added be in the range of 6 to 9 and an inorganic acid or base, preferably an alkali metal base or alkaline earth metal base, may be added to the aqueous solution to adjust the pH to within this range.  The amount of dialkyl dithiophosphate added should generally be sufficient to combine with all the metal ions present and a stoichiometric excess may be employed.  Suitable water-immiscible ethers are dialkyl ethers of the formula R1OR11 where R1 and R11 are alkyl groups each containing 2 to 10 carbon atoms, e.g. diethyl, dipropyl, dibutyl, dihexyl, and ethyl butyl ether.  The uranium dialkyl dithiophosphate may be recovered from the extract by volatizing the polar solvent by evaporation, distillation or stripping.  Any alkali or alkali earth metals present in the original aqueous solution will remain in the aqueous solution after extraction of the uranium dialkyl dithiophosphate.  Specific non-polar organic solvents which may be used to extract any heavy metal complexes formed prior to the uranium extraction step are hexane, heptane, octane and decane.  The process of the invention is generally carried out at between 32 DEG  and 212 DEG  F. and preferably at about 50 DEG  to 100 DEG  F. and it is usually operated at atmospheric pressure although higher or lower pressures may be used.  Examples are given for the recovery of uranium from (1) an aqueous solution of uranyl acetate, and (2) an aqueous solution containing uranyl acetate and nickel nitrate using potassium diisopropyl dithiophosphate and diethyl ether as the extractant for the uranium diisopropyl dithiophosphate formed.  In (2) the nickel-containing product formed is extracted with hexane prior to the extraction with diethyl ether.  The uranium dialkyl dithiophosphates may be used as additives for hydrocarbon lubricating oils (see Group III).ALSO:Uranium dialkyl dithiophosphates in which the alkyl groups contain 1 to 6 carbon atoms and which are formed in the recovery of uranium ions from an aqueous solution containing them by the addition to the solution of a water-soluble alkali metal salt or alkaline earth metal salt of a dialkyl dithiophosphate containing 1 to 6 carbon atoms in each alkyl group (see Group IV (b)), may be used as additives for hydrocarbon lubricating oils.  Specified uranium dialkyl dithiophosphates are the diisopropyl, diethyl, dimethyl, dibutyl, diamyl, dihexyl, and propyl butyl dithiophosphates.