Patent GB-1014302-A (GB)
Title: Aqueous emulsions containing polymers
IPC: C08G63/02
Filed: 1961-11-20
Abstract: An aqueous emulsion comprises (1) a water-insoluble polymer having more than 1 carboxyl group per molecule and a particle size in the emulsion of 5-20 microns, said polymer being a branched polyester from a hydroxy acid or a diol and dicarboxylic acid together with a compound having a functionality of 3-6 due to COOH, OH or carboxylic anhydride groups, a polymerized polyene fatty acid, an addition copolymer of an a ,b -unsaturated mouocarboxylic acid and a diene, or a carboxyl terminated low molecular weight polymer of a mono- or di-olefin; (2) a curing agent for the polymer of formula:- <FORM:1014302/C3/1> in which n is 2, 3 or 4, each nitrogen being linked to a carbon or a phosphorus atom, R1 and R11 are each H1 or alkyl with not more than 4 carbon atoms, and Q is either an n-valent radical free of active hydrogen but which may contain O, S, P, or N, or is  <FORM:1014302/C3/2> and (3) an emulsifying agent.  The emulsions are prepared by mixing the ingredients with water and vigorous agitation.  They are self-curing at room temperature up to 150 DEG  C. Retardation may be effected by cooling or by making the emulsion alkaline, or the emulsion may be prepared just before use. Lists of ingredients for the polyester are given.  Part of the diol or dicarboxylic acid may be replaced by hydroxy or amino acid. Suitable polymerized fatty acids are known as "Emery Dimer or Trimer Acid."  Suitable copolymers may be made from acrylic acid and butadiene or methacrylic acid and isoprene.  The carboxyl terminated poly-olefin may be anionically polymerized butadiene into which terminal COOH groups have been introduced.  Many suitable polyalkyleneimino curing agents are mentioned.  The emulsions may include conventional adjuvants, e.g. fillers dyes, accelerators, antioxidants or catalysts. Fillers mentioned are calcium carbonate, iron oxide, titanium dioxide, carbon black, silica.  Some suitable emulsifying agents are morpholine oleate or stearate; acetates of n-dodecyl, n-octadecyl, n-octadicenyl or n-octadienyl amine; hexaethylene glycol monooleate; soaps of alkali metals, alkanolamines, borax, morpholine or ammonia; di-n-octyl sodium sulphosuccinate; sodium salt of sec. alkyl sulphate; potassium oleate; sodium lauryl sulphate; sodium salt of alkyl sulphonate from kerosene; lithium perfluorooctane sulphonate; potassium salt of N-ethyl-N-perfluorooctanesulphonyl glycerine.  If desired the polymer or curing agent may be dissolved in an organic solvent before dispersion.  In examples the emulsions contain water and (I) a polyester of acid number 27.9 from adipic acid, diethylene glycol, trimethylol propane and triphenyl phosphite catalyst, N,N1-bis-1,2-ethyleneisosebacamide, toluene and sodium lauryl sulphate; (III) the polyester of Example (I), silica, Agerite White antioxidant, toluene, bis-ethylene-iso-sebacamide, sodium lauryl sulphate. Example (IV) mentions also the use of Emery Dimer acid, a butadiene-acrylic acid copolymer, and, as polyesters of neopentyl glycol sebacate and isosebacate (prepared with trimethylol propene); 3,31-oxy-bis-tetrafluoropropanol adipate (prepared with trimethylolpropane; and a copolymer of dimethyl diethoxysilane, b -carboethoxypropyl methyl disiloxane and diethylene glycol adipate (prepared with trimethylol propane).  Curing agents mentioned in this example are N,N1-bis-1,2-butyleneisosebacamide, N,N1-bis-1,2-ethylene-, or propylene-isosebacamide or isophthalamide, tris-aziridinyl phosphine oxide, and the bis-ethylene carbamate of bis-phenol A.  Uses.-The compositions are useful for coating or impregnating films, paper, metal or leather, or adhesives, e.g. for fluorinated polymer films to metal, glass or plastic surfaces, or plasticizers for other resins, or for making plastisols by including a vinyl plastic or elastomer in the emulsions.ALSO:Aqueous emulsion containing carboxyl group containing polymers, polyalkyleneimine curing agents for the polymers and emulsifying agents can be applied as coatings to various surfaces, e.g. fabrics, paper, metal, and especially leather to give scuff-resisant, waterproof finishes.  The emulsions may be used as a base coat, primer coat, adhesive coat or top coat.  The emulsions may include dyes, pigments and other conventional additives and may be applied by spraying, swabbing or brushing. In Example III a carboxyl-containing polyester, silica and Agerite White antioxidant, bis-ethylene-iso-sebacamide and toluene were dispersed in water containing sodium lauryl sulphate and coatings of the emulsion were spread by brush on to leather and cured with infra-red lamps.