ahmedabdelwahed/Medical_papers_title_and_abstract_NLP_dataset huggingface dataset:
Geopolymer concrete with metakaolin for sustainability: a comprehensive review on raw material's properties, synthesis, performance, and potential application

In the last three decades, the gigantic demand for sustainable and environmentally friendly concrete with reduced environmental footprints has resulted in the development of low carbon concretes such as geopolymer concrete. Metakaolin which is commonly used as an admixture or partial replacement of cement owing to its most effective pozzolanic properties, which improve the microstructure and strengthen the mechanical and durability properties of cement concrete, has been investigated as a precursor in geopolymer concrete. Several studies have been conducted to comprehend the effect of metakaolin as an additive in geopolymer mortar and concrete prepared with various aluminosilicate sources as precursors such as fly ash and rice husk ash to enhance geopolymerization, densify microstructure, and elevate durability. The present paper recapitulates these investigations primarily concentrating on the various properties of metakaolin-based concrete. The effect of various factors such as alkali content, solids/liquids ratio, alkali reactant ratio, molar ratio, water content, and curing regime has been compiled. Most of them revealed that metakaolin is used as a precursor and yields better geopolymer products. XRD studies reported the peaks demonstrating the development of enhancement in hydration products in comparison to other precursors. Examination of SEM graphs reveals that the addition of a smaller quantity of silica-rich materials densifies the microstructure of geopolymers and produces higher mechanical strength. Durability studies reveal that metakaolin geopolymers possess better water resistance, thermal resistance, and anti-corrosion properties. The possible applications of metakaolin-based geopolymeric materials are also pointed out. The comprehensive knowledge presented here is expected to support the prospective researchers to decide their future course of the research area. Graphical abstract.
Performance amelioration of single basin solar still integrated with V-type concentrator: Energy, exergy, and economic analysis

Solar desalination is one of the most sustainable solutions to produce freshwater from brackish water. The present research work aims to experimentally investigate the effect of a V-shape concentrator integrated with solar still (SS). The V-shape concentrator integrated with the conventional solar still (CSS) is used to supply the saline water at elevated temperature to the basin of SS, which augments the freshwater yield compared to CSS. The experimental investigation was performed at different brackish water depths of 0.01, 0.02, and 0.03 m, respectively. The SS system was evaluated based on water yield, energy, exergy, concentrator efficiency, and economic analysis. The freshwater yield of the solar still integrated with V-shape concentrator (SSVC) was found to be 5.47, 5.10, and 4.89 L/m(2).day, whereas the yield of the CSS was 3.73, 3.27, and 2.91 L/m(2).day at the water depths of 0.01, 0.02, and 0.03 m, respectively. The daily energy and exergy efficiency of CSS were 38.5, 33.5, and 29.4% and 1.9, 1.5, and 0.97 % in the case of 0.01, 0.02, and 0.03m water depth , respectively. However, the integration of concentrator significantly augmented the energy efficiency to 57.4, 51.7, and 44.9% and exergy efficiency to 3.8, 3.3, and 2.8% for the respective water depths . Life cycle studies demonstrated that the freshwater cost per liter for CSS and SSVC were 0.0102 $ and 0.0117 $ respectively, at a water depth of 0.01 m. It was concluded that the addition of V-shape concentrator and minimum water depth is useful to augment the energy efficiency, exergy efficiency, and yield of the SS in the very economical way.
A comparative techno-economic assessment of biochar production from different residue streams using conventional and microwave pyrolysis

A comparative techno-economic assessment and Monte Carlo risk analysis is performed on large scale (3 tonne/ h) biochar production plants for conventional (CPS) and microwave (MWP) pyrolysis using six different residue streams. Both plants are viable with minimum selling prices between Euro 436/tonne and Euro 863/tonne for CPS, and between Euro 564/tonne and Euro 979/tonne for MWP. The CPS is therefore more viable than MWP as it is a simpler and more established technology. However, a 20% biochar price increase due to higher biochar quality makes the MWP technology more viable. Nevertheless, the discounted payback period remains higher than this of CPS due to the increased CAPEX. Biochar price is the most important determinant of a biochar production plant's feasibility, motivating the need for economic and market research on biochar prices in function of biochar characteristics to reduce fluctuations in widely varying biochar prices.
Imidazole Compounds: Synthesis, Characterization and Application in Optical Analysis

Imidazole is a five-membered heterocyclic ring containing three carbon atoms, two nitrogen atoms, and two double bonds. Among two nitrogen atoms, one of which carries with a hydrogen atom is a pyrrole-type nitrogen atom, another is a pyridine type nitrogen atom. Hence, the imidazole ring belongs to the π electron-rich aromatic ring and can accept strong suction to the electronic group. Moreover, the nitrogen atom of the imidazole ring is coordinated with metal ions to form metal-organic frameworks. In recent years, because of imidazole compounds' unique optical properties, their applications have attracted more and more attention in optical analysis. Thus, this review has summarized the synthesis, characterization, and application with emphasis on the research progress of imidazole compounds in optical analysis, including fluorescence probe, colorimetric probe, electrochemiluminescence sensor, fiber optical sensor, surface plasmon resonance, etc. This paper will suggest the direction for the development of imidazole-containing sensors with high sensitivity and selectivity.
Relationship between greenhouse gas emission, energy consumption, and economic growth: evidence from some selected oil-producing African countries

This paper investigates the relationship between greenhouse gas emissions, energy consumption, and output growth among African OPEC countries (Libya, Nigeria, Angola, Algeria, Equatorial Guinea, and Gabon) using the panel autoregressive distributed lag model (PARDL) estimated by means of mean group (MG) and pooled mean group (PMG) for the period 1970-2016. The paper estimated three panel models comprising the components of greenhouse gasses which includes nitrous oxide, carbon dioxide (CO2), and methane and examined their relationship with economic growth and energy consumption. The findings of the study showed evidence of a positive impact of economic growth on both CO2 and methane emissions in the long run. Its impact on nitrous oxide emissions although positive was found to be statistically insignificant. Energy consumption was also found to produce an insignificant positive impact on CO2, methane, and nitrous oxide emissions in the long run. In the short run, economic growth exerts a significant positive effect on methane emissions; however, its effect on CO2 and nitrous oxide emissions although positive was found to be statistically insignificant. Energy consumption produces an insignificant impact on all components of greenhouse gasses in the short run. In addition, our empirical results showed the presence of a non-linear relationship between methane emissions and economic growth, confirming the existence of the environmental Kuznets curve (EKC) only in the case of methane emissions model.
The nexus of carbon emissions, financial development, renewable energy consumption, and technological innovation: What should be the priorities in light of COP 21 Agreements?

This study analyses the dynamics of carbon emissions for N-11 countries from 1990 to 2017. We introduce some innovative factors such as financial development, human capital, renewable energy consumption, and gross domestic product as determinants of carbon dioxide (CO2) emissions. The empirical estimations are based on Pesaran (2007) unit root test, common correlated effect mean group, and augmented mean group. The findings reveal a positive relationship between carbon emissions and financial development as well as a gross domestic product. In contrast, technological innovation and renewable energy consumption are adversely related to carbon emissions. These findings have important implications, and we recommend the promotion of technological innovation and the use of renewable energy consumption. This will help in achieving the goals set by COP21.
A supply curve of electricity-based hydrogen in a decarbonized European energy system in 2050

Alongside substituting fossil fuels with renewable energies and increasing energy efficiency, the utilization of electricity-based hydrogen or its derived synthetic fuels is a potential strategy to meet ambitious European climate protection targets. As synthetic hydrocarbons have the same chemical properties as their fossil substitutes, existing infrastructures and well-established application technologies can be retained while CO2 emissions in energy conversion, transport, industry, and residential and services can be reduced. However, the conversion processes, especially the generation of hydrogen necessary for all e-fuels, are associated with energy losses and costs. To evaluate the techno-economic hydrogen production potential and the impact of its utilization on the rest of the energy system, a supply curve of electricity-based hydrogen in a greenhouse gas emission-free European energy system in 2050 was developed. It was found that hydrogen quantities of the order of magnitude envisaged in the 1.5 degrees C scenarios by the European Commission's long-term strategic vision (1536-1953 TWh(H2)) induce marginal hydrogen production costs of over 110 (sic)(2020)/MWh(H2) and electrolyzer capacities of more than 615 GW(el). Although the generation of these amounts of hydrogen using electrolysis provides some flexibility to the electricity system and can integrate small amounts of local surplus electricity, an additional 766 GWel of wind power and 865 GWel of solar power must be installed to cover the additional electricity demand for hydrogen production. It was furthermore found that the most important techno-economic properties of electrolyzers used in an energy system dominated by renewable energies are the ability to operate flexibly and the conversion efficiency of electricity into hydrogen. It is anticipated that the shown analysis is valuable for both policy-makers, who need to identify research, subsidy and infrastructure requirements for a future energy system, and corporate decision-makers, whose business models will be significantly affected by the future availability of electricity-based fuels.
Thermodynamic analysis and performance optimization of the supercritical carbon dioxide Brayton cycle combined with the Kalina cycle for waste heat recovery from a marine low-speed diesel engine

With the continuous rise in world oil prices and increasing environmental awareness, how to improve ship energy efficiency and reduce ship pollution emissions has become a common concern of the shipping industry. Waste heat recovery technology is an effective method to improve the fuel economy of ships and help the future ships to meet the increasingly stringent Energy Efficiency Design Index of the International Maritime Organization. Under the thermodynamic analysis results of the 8S90ME-C10.2 low-speed marine diesel engine, this paper proposed a waste heat recovery scheme that combined the supercritical carbon dioxide Brayton cycle power generation system with the Kalina cycle power generation system. According to the energy and exergy balances of the combined cycle system, a MATLAB program based on the REFPROP database was established. With the application of control variate method, the influence of the key operating parameters including the main compressor inlet temperature, the turbine inlet temperature, the main compressor outlet pressure, the expander inlet pressure, and the ammonia solution mass concentration on the system performance was thoroughly analyzed. Moreover, the multi-objective optimization matching between the diesel engine and the combined power generation system was carried out from the viewpoints of the thermodynamic performance and economic performance and the impact of the system on the fuel economy and the Energy Efficiency Design Index of the ship was calculated. The results showed that the combined power generation system was used to recycle the waste heat of diesel engine exhaust gas and bypass exhaust gas to generate electricity, which reduced the annual fuel consumption and the Energy Efficiency Design Index to 16.62% and 15.01%, respectively. Finally, this study provides a reference for researchers to study the combined use of supercritical carbon dioxide Brayton cycle and Kalina cycle to recycle the waste heat of the marine diesel engine.
Role of necroptosis of alveolar macrophages in acute lung inflammation of mice exposed to titanium dioxide nanoparticles

Titanium dioxide (TiO2) nanoparticles are indispensable for daily life but induce acute inflammation, mainly via inhalation exposure. TiO2 nanoparticles can be phagocytosed by alveolar macrophages (AMs) in vivo and cause necroptosis of exposed cells in vitro. However, the relationship between localization of TiO2 nanoparticles in the lungs after exposure and their biological responses including cell death and inflammation remains unclear. This study was conducted to investigate the intra/extracellular localization of TiO2 nanoparticles in murine lungs at 24 h after intratracheal exposure to rutile TiO2 nanoparticles and subsequent local biological reactions, specifically necroptosis of AMs and lung inflammation. We found that TiO2 exposure induced leukocyte migration into the alveolar region and increased the secretion of C-C motif ligand (CCL) 3 in the bronchoalveolar lavage (BAL) fluid. A combination of Raman spectroscopy and staining of cell and tissue samples confirmed that AMs phagocytose TiO2. AMs that phagocytosed TiO2 nanoparticles showed necroptosis, characterized by the expression of phosphorylated mixed lineage kinase domain-like protein and translocation of high mobility group box-1 from the cell nucleus to the cytoplasm. In primary cultured AMs, TiO2 also induced necroptosis and increased the secretion of CCL3. Necroptosis inhibitors suppressed the increase in CCL3 secretion in both the BAL fluid and culture supernatant of AMs and suppressed the increase in leukocytes in the BAL fluid. These data suggest that necroptosis of AMs that phagocytose TiO2 nanoparticles is involved as part of the mechanism by which TiO2 induces acute lung inflammation.
An insight into the pharmacological and analytical potential of Andrographolide

Andrographis paniculata is an annual medicinal herb from the family Acanthaceae. Andrographolide is generally considered an essential bioactive component of plant A. paniculata. Since ancient times, it has been widely recognized for its therapeutic qualities and has attracted the scientific and medical communities' attention. This review summarizes the molecular, clinical, and in vitro research of compound andrographolide and its mechanism of action. Andrographolide, when combined with other enhancing agents, offers a wide variety of health benefits. The therapeutic potential of andrographolide has been exemplified and exhibited by directly regulating genes and indirectly interacting with small molecules and different enzymes. This review compiles and consolidates the pharmacological action of andrographolide and its analogs and deciphers the gaps that have hindered its use in medicinal research.
Optimisation of a hydrogen production - storage - re-powering system participating in electricity and transportation markets. A case study for Denmark

The power capacity of renewable energy sources is constantly increasing through the installation of new units, primarily comprising the most mature technologies such as wind and solar energy converters, as well as through the implementation of innovative technologies that are currently at an infant stage of development. The aim of this study was to investigate the prospects of implementing hydrogen technologies in the electricity network as an electricity production unit or/and utilise the produced hydrogen as transportation fuel. Three main scenarios were identified to be the most appropriate for this: (1) Support of the electrical grid via a fuel cell; (2) participation of a hydrogen production and fuel cell system in the electricity and transportation markets; and (3) participation in the transportation market. The results indicated that a fuel cell generator providing ancillary services is not economically viable in the investigated case study, while implementing a hydrogen production unit with a hydrogen fuel selling price between 4 and 114 (sic)/kgH(2), depending on the electrolyser's power input, will yield positive results. For the third scenario, the hydrogen fuel price ranged between 3.6 and 15.0 (sic)/kgH(2). This research shows that hydrogen technologies can be used in the electricity and transportation markets from a technical point of view. However, from an economic point of view, a hydrogen system used only for a single application does not seem to be financially appealing. This suggests that reducing the investment cost and/or limiting operating costs is mandatory to support this type of investment.
Earthworms and vermicompost: an eco-friendly approach for repaying nature's debt

The steady increase in the world's population has intensified the need for crop productivity, but the majority of the agricultural practices are associated with adverse effects on the environment. Such undesired environmental outcomes may be mitigated by utilizing biological agents as part of farming practice. The present review article summarizes the analyses of the current status of global agriculture and soil scenarios; a description of the role of earthworms and their products as better biofertilizer; and suggestions for the rejuvenation of such technology despite significant lapses and gaps in research and extension programs. By maintaining a close collaboration with farmers, we have recognized a shift in their attitude and renewed optimism toward nature-based green technology. Based on these relations, it is inferred that the application of earthworm-mediated vermitechnology increases sustainable development by strengthening the underlying economic, social and ecological framework. Graphic abstract
History of GH treatment in Japan

In Japan, a pituitary-extracted human GH (phGH), Crescormon®, was approved for the treatment of pituitary dwarfism in 1975. The Study Group of Pituitary Dysfunction was organized by the Ministry of Health and Welfare (MHW) in 1973 and prepared the "Diagnostic Handbook: Pituitary Dwarfism" guidelines in 1974. Eligibility assessments for phGH treatment were conducted by the research group on pituitary dwarfism (later the Foundation for Growth Science [FGS] GH Treatment Eligibility Assessment Committee); however, there were 200-300 patients on the waiting list. GH treatment has been financially supported by the Grant-in-Aid Program for Chronic Diseases in Childhood, MHW, since 1974. In 1984, phGH was discontinued in the United States due to reports of the onset of Creutzfeldt-Jakob disease in patients treated with phGH. Japan approved the use of methionyl hGH in 1986 and recombinant hGH in 1988. As a result, the phGH disappeared from the market. The role of the Eligibility Assessment Committee of the FGS shifted to the provision of second opinions about diagnoses and treatment appropriateness. Since then, the indications for GH treatment of pediatric growth disorders have expanded to include other pediatric growth disorders such as Turner syndrome, achondroplasia/hypochondroplasia, etc.
Quantifying the dynamics of nearly 100 years of dominance hierarchy research

Dominance hierarchies have been studied for almost 100 years. The science of science approach used here provides high-level insight into how the dynamics of dominance hierarchy research have shifted over this long timescale. To summarize these patterns, I extracted publication metadata using a Google Scholar search for the phrase 'dominance hierarchy', resulting in over 26 000 publications. I used text mining approaches to assess patterns in three areas: (1) general patterns in publication frequency and rate, (2) dynamics of term usage and (3) term co-occurrence in publications across the history of the field. While the overall number of publications per decade continues to rise, the percent growth rate has fallen in recent years, demonstrating that although there is sustained interest in dominance hierarchies, the field is no longer experiencing the explosive growth it showed in earlier decades. Results from title term co-occurrence networks and community structure show that the different subfields of dominance hierarchy research were most strongly separated early in the field's history while modern research shows more evidence for cohesion and a lack of distinct term community boundaries. These methods provide a general view of the history of research on dominance hierarchies and can be applied to other fields or search terms to gain broad synthetic insight into patterns of interest, especially in fields with large bodies of literature. This article is part of the theme issue 'The centennial of the pecking order: current state and future prospects for the study of dominance hierarchies'.
Working from home during the corona-crisis is associated with higher subjective well-being for women with long (pre-corona) commutes

Much research has been devoted to assessing the effect of commute duration on the subjective well-being of people, but as of yet, the respective body or research has been inconclusive as to whether there is indeed a (large) negative effect or not. To control the spread of COVID-19 governments around the world have taken unprecedented measures to control the outbreak of the Corona-virus. Forcing or strongly advising people to work from home (i.e. at least those who can) is often one of these. The ensuing situation can be considered a natural experiment; the government's intervention effectively cancels people's commuting trip and can be considered completely exogenous. Should commuting time indeed have an adverse effect on well-being, it may be expected that those workers with long (pre-corona) commutes who have transitioned to working from home will experience an increase in their well-being. This idea is tested by combining several surveys -timed before and after the crisis- from the Longitudinal Internet Studies for the Social sciences (LISS) panel, a panel that is representative of the Dutch population. In line with expectations, the results indicate that workers with a long commuting duration who transitioned to working from home indeed increased their subjective well-being. However, this effect was found to be significant only for women and not for men. A more general finding of interest is that subjective well-being did not change much between the measurements before and during the corona-crisis.