abdelmo/pubmed-dataset · Datasets at Hugging Face

title stringlengths 3 689	abstract stringlengths 1 512	pmid stringlengths 5 8	abstract embedding sequence	title embedding sequence
Adsorption of CaCO3 Particles on Cationic Cellulose Graft Copolymers	; the agitation; and the ionic strength of the suspension. Kinetic models have shown that the weakly charged copolymers present a high-affinity-type kinetics when the CaCO3 particle average diameter is small (20 to 30 μm). For an average particle diameter equal to 72 μm; the kinetics corresponds to an adsorption with a lower affinity. The rate constants are 6.6 x 10(-12); 2.9 x 10(-12); and 1.2 x 10(-12) m3/s for particles with average diameters of 20; 30; and 72 μm; respectively. We have also noted that th	8978546	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
Adsorption of CaCO3 Particles on Cationic Cellulose Graft Copolymers	e adsorption increases with agitation and reaches a plateau after 5 min. The ionic strength influences the electrostatic interactions between the positive sites of the graft and the anion of the adsorbate. Indeed a decreasing adsorption is observed when the ionic strength increases.	8978546	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
Energetic Classification of Adsorption Isotherms	The new model describes adsorption isotherms with a two-parameter function. The parameters are easy and precise to calculate from the excess surface work of the adsorbed layer. The excess surface work is defined as the product of adsorbed amount and the change of the chemical potential. The differential form yields a minimum at the first layer. It is possible to linearize the corresponding integral form. The physical meanings of the two parameters are the monolayer capacity and the chemical potential; which	8978547	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
Energetic Classification of Adsorption Isotherms	is necessary for adsorption. The new model allows an energetic classification of adsorption phenomena of surface films in the energetic range from weak physisorption to chemical adsorption	8978547	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
Electrochemical Studies of the Interfacial Behavior of Insulin	The interfacial behavior of insulin and chain A and chain B of insulin was investigated at the platinum electrode in a phosphate buffer; pH 7.0; using cyclic voltammetry. The enthalpy of adsorption; DeltaHADS; calculated from a linear van't Hoff relationship over the temperature range 299 to 333 K gave values of -22 ± 1; -17 ± 1; and -9 ± 1 kJ mol-1 for insulin; chain B and chain A; respectively. Above these temperatures denaturation of insulin occurs; and for all three molecules the su	8978548	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
Electrochemical Studies of the Interfacial Behavior of Insulin	rface adsorption measured by the surface charge densities showed an immediate decrease followed by a slight increase. The surface concentrations of insulin of 2.9 ± 0.2 mg m-2 at 299 K and 3.2 ± 0.3 mg m-2 at the physiological temperature of 310 K agreed well with the calculated value determined from geometrical dimensions. Similar calculations from experimental surface charge densities for chain A and chain B indicated that a more efficient packing prevailed with the individual polypeptides.	8978548	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
Electrochemical Studies of the Interfacial Behavior of Insulin	From a consideration of the mechanism of adsorption based on cyclic voltammetric measurements; an estimation of the number of carboxylate groups on insulin was determined to be 6 ± 2; which agrees with the known number of acidic residues on the protein. Similar calculations for chain A gave 2 ± 0.4; which indicates that this peptide remains as a monomer in the phosphate buffer. However; the value obtained for chain B under similar experimental conditions was 6 ± 2; indicating that this	8978548	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
Electrochemical Studies of the Interfacial Behavior of Insulin	peptide appears to dimerize in the phosphate buffer. Dimer formation of insulin is known to occur through hydrophobic interactions and four hydrogen bonds between the B chains.	8978548	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution	A molecular model based in statistical thermodynamics is used to study salt effects on the lower consolute boundary of the aqueous non-ionic surfactant C8E5. The C8E5 micelles are modeled as hard spheres interacting via a temperature-dependent Yukawa attraction and the salt ions are modeled as positively and negatively charged hard spheres interacting via a Coulombic potential. The excess thermodynamic properties due to the Coulombic and Yukawa potentials are evaluated using the analytical solutions to the	8978549	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution	Ornstein-Zernike equation obtained for the mean spherical approximation closure. The Yukawa parameters for the micelle-micelle attractions are determined by fitting the theoretical phase diagram for a pure Yukawa fluid to the experimental lower consolute boundary for a salt-free C8E5 micelle-water solution. Ion-solvent interactions are indirectly accounted for by using previously determined adjusted values for the cation size and the dielectric constant of the medium. We evaluate theoretical coexistence cur	8978549	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution	ves for the C8E5 micelle-salt-water mixtures in the temperature-micelle volume fraction and temperature-salt molarity planes. We calculate the changes in the lower critical solution temperature (LCST) for the C8E5 micelle-salt-water mixture as a function of salt concentration for the salts NaF; NaCl; NaBr; NaI; and Na2SO4 and compare the trends seen with experiments. When ion-solvent interactions are indirectly accounted for; the theory correctly predicts the salting-out trends exhibited by NaF; NaCl; and N	8978549	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution	aBr. For the 1:2 salt (Na2SO4); charge effects resulting from the higher charge on the ions play a more important role in salting-out than ion-solvent interactions do. The theory; however; cannot predict the salting-in phenomena exhibited by NaI; thus indicating that salting-in is the result of variations in the intermicellar attraction as a function of the salt type and salt concentration. The theoretical results also indicate that excluded-volume forces resulting from the different sizes of the salt ions	8978549	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]	[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]
The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution	cannot alone account for the salting-in and salting-out phenomena seen in aqueous nonionic micellar solutions.	8978549	[ -0.06775187, -0.0030882019, -0.06574049, -0.0017599608, -0.008846119, -0.023726389, 0.070133775, 0.005362587, -0.043721132, -0.053037014, -0.0002342617, -0.0062260265, 0.008687325, 0.02326324, 0.054069173, 0.00655023, -0.025221694, 0.0043668197, -0.05377805, -0.005574312, 0.024626218, -0.06113548, -0.028397562, -0.03056774, -0.017718703, 0.05107856, 0.018856723, -0.023792552, -0.028212303, -0.17710763, -0.0153500335, 0.009646703, -0.026902258, -0.03617844, 0.066111006, 0.009937824, -0.035013955, 0.010156165, -0.008409437, -0.015985208, 0.04295363, -0.00064096315, -0.007608853, 0.023077982, 0.026690533, -0.06923395, 0.01988888, -0.0009808803, 0.051475544, -0.031970415, -0.00833004, 0.0011851615, -0.02036526, -0.0037415707, -0.02197966, 0.06716963, -0.016739476, 0.029800238, 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Adsorption of Nonionic Surfactants on Kaolins	Adsorption of nonionic surfactant on kaolins of different origins was studied. The shape of the isotherm differs only slightly according to the origin of the kaolin; but the amount adsorbed is quite different. The relation between the morphology of the kaolin particles and the shape of the isotherm is not clear. Fluorescence studies show two different solubilization sites for adsorbed pyrene molecules. However; these two environments could not be correlated to the basal and lateral surfaces of the mineral p	8978550	[ -0.010825889, 0.026998226, -0.006902502, 0.058677915, -0.005456168, -0.03354164, 0.048543606, -0.0040231347, -0.07511625, -0.042345986, 0.030003939, -0.07208393, -0.021784775, 0.012002906, 0.017528897, 0.021332588, 0.0053065475, 0.02576136, -0.022369958, 0.002388944, 0.053251673, -0.038462497, -0.009236585, -0.023274332, -0.025881058, 0.05506042, 0.0005440375, 0.016198935, -0.041361813, -0.22215682, -0.01880566, -0.0081526665, -0.033914026, -0.03447261, 0.008325561, 0.044660117, -0.011796761, 0.002886017, -0.052719686, -0.012554839, 0.05202811, 0.036706947, -0.012162501, -0.0016034353, 0.014031097, -0.037185732, 0.03731873, 0.009535827, 0.0837876, -0.048915997, 0.04984697, -0.0050472054, 0.013964599, -0.011637166, -0.014137494, -0.027024824, -0.008072868, 0.016238835, 0.023394028, 0.009356282, -0.022236962, 0.026319945, -0.16885196, 0.08937343, 0.068094045, 0.033328842, 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0.014669479, -0.050405554, 0.04391534, -0.0015294561, -0.0348982, -0.0079199225, -0.0044121486, 0.08054249, 0.022157164, 0.0015419245, -0.045803886, 0.023061538, 0.03425982, 0.05016616, 0.013898101, 0.018699264, -0.019390844, -0.031786088, 0.06091225 ]	[ -0.0107389325, 0.026996946, -0.006875577, 0.05872833, -0.0054559098, -0.033566646, 0.048541307, -0.0040329183, -0.075112686, -0.04231738, 0.02994932, -0.07213371, -0.02181034, 0.011982388, 0.017528066, 0.02129168, 0.0053195953, 0.025786737, -0.0223556, 0.0024104416, 0.053169355, -0.038460672, -0.009295993, -0.023233332, -0.02587983, 0.055004615, 0.00051117985, 0.01629126, -0.041333254, -0.2221463, -0.018764872, -0.008158929, -0.033965614, -0.03444438, 0.008365064, 0.04457821, -0.011842749, 0.002884218, -0.05271719, -0.0124811, 0.05205224, 0.036731806, -0.012168574, -0.0015634623, 0.014096927, -0.03715737, 0.03731696, 0.009561973, 0.08378363, -0.048940275, 0.049871206, -0.005043641, 0.014003835, -0.011663212, -0.014163422, -0.027023545, 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0.0027262925, 0.0841028, 0.02419086, 0.05851555, 0.057026062, 0.031864375, -0.002202645, 0.0034776854, -0.080379084, -0.046041097, 0.022222608, 0.033194274, 0.052132033, -0.023619004, 0.04008315, 0.014389505, 0.05412688, -0.061707303, -0.08915642, -0.27874678, -0.033699635, 0.030055713, -0.038859643, 0.17320602, 0.031066436, -0.00068863825, 0.021664051, 0.045535736, -0.04495058, 0.027528904, 0.030800456, 0.011596718, 0.012115378, 0.03744995, 0.022222608, 0.045695323, -0.004401965, 0.008119032, -0.052531004, 0.00015792549, -0.0050137183, -0.041758824, 0.032289945, 0.06638855, 0.004155934, 0.13160679, 0.01210208, -0.03721057, 0.05154688, 0.027874678, 0.009056611, -0.03893944, -0.10649829, -0.012860121, -0.022116218, 0.02667777, -0.006942072, -0.022781167, 0.0047477386, -0.028193854, 0.020320853, 0.029975919, -0.026265502, -0.049525432, -0.029709939, -0.0249622, 0.027156534, -0.01788714, 0.023020549, 0.018153118, 0.011576769, 0.034072008, -0.0063668904, 0.0030288445, 0.013711257, 0.062026482, -0.0012218446, -0.03638603, 0.029656744, -0.0014130175, 0.030082311, 0.02208962, -0.028433237, -0.005612173, -0.004807584, -0.027502308, -0.027395915, 0.037689332, -0.03798191, -0.0107189845, 0.09474199, -0.0022442043, 0.014269814, -0.022927456, 0.010479603, 0.015892291, 0.032130357, 0.039072428, 0.041891813, -0.00045549034, -0.015001259, 0.05676008, 0.022781167, 0.03465716, 0.029550351, -0.027821483, -0.056813277, -0.010612592, 0.0014844995, 0.01997508, 0.034284793, -0.043141916, -0.023898281, -0.014868269, 0.051866055, -0.27640617, 0.012866771, 0.0020231085, 0.093199305, -0.03848727, -0.048833884, 0.07979393, 0.024377044, 0.030534476, 0.018339304, -0.01892446, -0.0017155694, -0.00894357, -0.0017338556, -0.025746841, -0.03654562, -0.0019416523, -0.06239885, -0.0223556, -0.03771593, 0.026784161, -0.009302642, 0.1775681, -0.038221292, -0.06239885, -0.041865215, 0.040136345, 0.017807346, -0.020586833, -0.007813156, 0.0077333613, 0.011357335, 0.071176186, -0.08553909, 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Adsorption of Nonionic Surfactants on Kaolins	articles.	8978550	[ 0.007088026, -0.018813571, 0.0060208696, -0.0062349597, 0.045769148, 0.050327618, -0.024689518, 0.03981415, 0.060656637, 0.045505654, -0.061605223, 0.047139324, 0.031145155, 0.024175702, 0.03644141, 0.037073802, 0.017324822, -0.06708592, -0.01569115, -0.00087200507, 0.05319972, -0.035097584, 0.033911858, -0.024294274, -0.006389763, 0.013161594, -0.002182071, 0.022634253, -0.04895744, -0.066769734, -0.075043485, -0.017561967, 0.0081683565, 0.01878722, -0.010203859, -0.0032903985, -0.0129507985, 0.061605223, -0.008392328, 0.027113676, 0.06339699, 0.012917861, -0.08041879, -0.008860032, 0.04063099, 0.020842485, -0.006290952, -0.0032508743, 0.03778524, -0.027877811, -0.02132995, 0.008629474, -0.007687478, -0.03022292, 0.0125292055, 0.002975851, 0.057283897, 0.019525008, 0.0285629, 0.057810888, 0.036230616, 0.057336595, -0.15103556, 0.13585822, -0.034149002, -0.014320974, -0.057916287, 0.003682348, -0.021224553, 0.028800046, 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Mechanism of Particle Flocculation by Magnetic Seeding	Magnetic seeding flocculation of micrometer-sized particles in liquid suspensions is investigated. Primary forces acting on individual particles; including gravity and magnetic attraction; as well as van der Waals; electrostatic; magnetic dipole; and hydrodynamic interparticle forces; are examined and quantified. A mathematical statement of the overall relative velocity is developed from the net force acting on a particle. 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Mechanism of Particle Flocculation by Magnetic Seeding	es is derived. A computer model is then used to solve this equation repeatedly to find the particle trajectory borderline between collision and noncollision; thus determining the collision efficiency and collision frequency. The effects of a variety of parameters on flocculation performance are then explored. It is found that some factors have unexpected and complex influences on the collision efficiency and collision frequency; particularly the particle size ratio and the direction of the magnetic field.	8978551	[ -0.074539796, 0.01454985, 0.03724337, -0.019006321, -0.0060712793, -0.028012108, 0.05239007, 0.016817875, -0.02261394, -0.03612925, -0.014788589, -0.05920741, 0.04469735, 0.0018949952, -0.023555636, -0.011121284, 0.0050765313, 0.01431111, -0.044883035, -0.0044365767, 0.027481575, -0.035015136, -0.0076396656, 0.03167278, 0.027614208, 0.07273599, -0.012712881, -0.025253339, -0.066157386, -0.21730605, 0.04493609, -0.036712836, 0.046527687, 0.0026427142, -0.056236427, 0.008276304, 0.0045161564, 0.02096929, -0.0360762, -0.017268827, 0.020412233, 0.06292114, -0.024881966, -0.029073173, 0.0066416017, 0.0108361235, 0.032733846, 0.00925779, 0.023303634, 0.012726145, -0.014828379, -0.081755035, -0.04040004, 0.013296467, 0.0076794554, 0.027043886, -0.015770074, -0.005908804, -0.000978169, 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Comparison of Solubilization of Hydrocarbons in (PEO-PPO) Diblock versus (PEO-PPO-PEO) Triblock Copolymer Micelles	The solubilization of hydrocarbons by micelles formed of diblock and symmetric triblock copolymers in water are compared in the framework of a mean-field theory of solubilization. The block copolymers contain poly(ethylene oxide) as the hydrophilic block and poly(propylene oxide) as the hydrophobic block and are designated as EXPYEX or EWPZ (where E and P denote ethylene and propylene oxides and the subscripts denote the number of segments). In the presence of a variety of aromatic and aliphatic hydrocarbon	8978552	[ -0.067354925, 0.013404691, -0.025045954, -0.005628379, 0.015327223, 0.020909196, -0.023932211, 0.008034859, -0.02120089, -0.008200594, -0.06783224, -0.0616271, -0.027061298, -0.03805288, 0.03595798, 0.037257347, -0.039246175, 0.02521832, -0.0403334, 0.026186215, 0.023574222, -0.084485345, -0.04306472, -0.048606917, -0.020392101, 0.051285204, 0.01157497, 0.0032417872, -0.009460185, -0.2193543, -0.0078094583, -0.010640222, -0.019981077, -0.018164614, 0.0563766, -0.010196051, 0.016321635, 0.025735414, -0.04781139, 0.04208357, -0.013212437, 0.0032533887, -0.014995751, 0.0038450644, 0.04985325, -0.0080216, -0.004547783, -0.0040273736, 0.0100899795, -0.03266979, 0.0034539285, 0.03012409, 0.0025473551, -0.049216826, -0.007690129, 0.022274856, 0.011071133, -0.0044317683, -0.036143605, -0.0011087707, -0.031529527, 0.07424952, -0.10304773, 0.08358374, 0.035162453, -0.008001712, 0.0018313777, 0.033147108, 0.0068216748, 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0.07848686, 0.099222235, 0.00483251, 0.019369815, 0.008067441, -0.026608637, 0.00794812, -0.019979678, -0.07031998, -0.027258273, 0.016612168, 0.06798659, -0.0014873723, 0.00009425549, -0.018242892, 0.12218495, -0.07732016, -0.037042614, -0.27618888, -0.045872387, -0.0017218718, -0.057327226, 0.09280541, 0.037758544, 0.053084694, -0.008955722, 0.009486038, 0.015153797, 0.04725121, 0.029034834, -0.018614113, 0.0071393875, -0.031341713, -0.033542525, 0.051599808, 0.0117664, 0.012323232, 0.06607745, -0.036273655, -0.04629664, -0.011826061, 0.033675104, 0.07074424, -0.0044182003, 0.121442504, 0.014106422, -0.017526964, 0.021398276, -0.007026695, 0.048736095, -0.02715221, -0.096835814, -0.001930684, -0.0066919327, 0.028663613, -0.025229814, 0.023320673, -0.016227689, -0.03409936, 0.04825881, 0.032800082, -0.031712934, -0.031845514, -0.006466548, -0.004063551, 0.06257736, -0.018561082, 0.0029150841, 0.046137545, -0.012893323, 0.02574687, -0.0360085, 0.00010761699, 0.01748719, 0.0267147, 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Comparison of Solubilization of Hydrocarbons in (PEO-PPO) Diblock versus (PEO-PPO-PEO) Triblock Copolymer Micelles	solubilizates; the core radius; corona thickness; and aggregation number of the micelle and also the volume fraction of the hydrocarbon solubilized in the core are predicted. The calculations show that for identical molecular weights and block compositions; the diblock (E200P64) copolymer micelles have a much larger core radius; corona thickness; aggregation number; and volume fraction of the hydrocarbon solubilized in the core compared with the symmetric triblock (E100P64E100) copolymer micelles. In contr	8978552	[ -0.08151912, 0.007891716, -0.042582247, -0.015334364, -0.01617967, 0.046227627, 0.008888912, 0.030272491, -0.013868288, -0.026310124, -0.029823422, -0.07591897, -0.013630546, 0.003325087, 0.0005584462, 0.0035463192, -0.00032400613, -0.025861055, -0.014515474, -0.004741634, 0.0035958488, -0.09245525, -0.053016484, -0.049159776, 0.024025157, 0.047997482, 0.03251783, -0.020762809, -0.035634894, -0.2605653, 0.0065346053, 0.00002816996, 0.013392803, -0.04588422, 0.018108021, -0.0057553393, 0.03304615, 0.06244692, -0.056371287, 0.015149454, 0.035846222, -0.02218926, -0.01410603, -0.0037345318, 0.06049215, -0.042344507, -0.0089153275, 0.002218926, 0.035317905, -0.041287873, 0.048737124, -0.01894012, -0.01281826, 0.0020703373, -0.03109138, 0.019732593, -0.026970517, -0.008565319, 0.012362588, 0.024593096, 0.0012836421, 0.048235226, -0.11739175, 0.07259058, 0.032174427, -0.00018057667, -0.038197227, 0.01313525, 0.011622946, 0.08130779, 0.045937054, 0.045725726, -0.021264708, 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-0.044352107, 0.0065346053, 0.019600512, -0.009575723, -0.010823868, -0.00112102, 0.01636458, 0.0070265993, 0.016021173, -0.00041604863, 0.07385854, 0.09536099 ]	[ -0.08151482, 0.007878093, -0.042580005, -0.015320349, -0.016152402, 0.046198778, 0.008914858, 0.030244483, -0.013867557, -0.026269116, -0.029795436, -0.07591497, -0.013563791, 0.0033298647, 0.00054066966, 0.0035725469, -0.0003336881, -0.025859693, -0.014527917, -0.004718271, 0.003622074, -0.09245038, -0.052987274, -0.049130775, 0.024037099, 0.047994956, 0.03251612, -0.020774921, -0.035659432, -0.2607629, 0.00651445, 0.000053396285, 0.013372287, -0.045908216, 0.018120274, -0.0057517346, 0.03304441, 0.06244363, -0.056368317, 0.015082619, 0.03587075, -0.022135263, -0.014118494, -0.0037145242, 0.060541794, -0.042342275, -0.008901651, 0.002205602, 0.03528963, -0.041285697, 0.048787385, -0.018978743, -0.012817585, 0.002137915, -0.031089742, 0.01974476, -0.026942683, -0.008578075, 0.012348729, 0.024578594, 0.0013075125, 0.04820627, 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Comparison of Solubilization of Hydrocarbons in (PEO-PPO) Diblock versus (PEO-PPO-PEO) Triblock Copolymer Micelles	ast; the diblock copolymer (E100P32); having the same block composition but half the molecular weight of the symmetric triblock copolymer (E100P64E100); gives rise to micelles having the same core radius; corona thickness; and volume fraction of the hydrocarbon solubilized as the micelles formed of the triblock copolymer; and an aggregation number twice that of the triblock copolymer micelle.	8978552	[ -0.07109723, 0.02632836, -0.028353618, -0.038639802, -0.030592063, 0.030831896, 0.060597867, 0.066513754, -0.018720318, 0.007954469, 0.027740711, -0.09321519, -0.052869905, -0.0078079044, 0.028247027, 0.0062489887, -0.025915315, -0.015629133, -0.020838844, 0.028113786, 0.031231618, -0.110003516, -0.011425389, -0.029899212, -0.0081609925, 0.04794, -0.007934483, -0.02734099, -0.0029063127, -0.16298002, 0.026021907, 0.0126178935, -0.02275751, -0.033176932, 0.037227448, 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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode	An experimental investigation was performed on electrosprays of low electric conductivity liquids (heptane with different amounts of an antistatic additive) that were operated in the cone-jet mode. The effects of liquid flow rate; applied voltage; and liquid electric conductivity on droplet size and spray monodispersity were systematically investigated. The droplet size was found to be dominantly controlled by the liquid flow rate and secondarily by the applied voltage. 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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode	size. For a given liquid; stable and monodisperse electrosprays could be established only within certain ranges of liquid flow rates and applied voltages; that defined a cone-jet domain. This domain was affected by the electric conductivity of the liquid. As the liquid electric conductivity increased; the domain shifted toward smaller flow rates which implies that smaller droplets were generated in the spray. An increase in the capillary diameter caused a narrowing of this domain. 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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode	n; electrosprays were unstable and polydisperse with different instability patterns that depended on the applied voltage and the liquid flow rate. Experiments also showed that the droplet size and the spray monodispersity were independent of the electrode configuration; as long as the electrospray was operated at the onset voltage condition; that is defined as the minimum voltage at which the cone-jet mode was established. By using dimensional analysis the controlling variables were combined into a few dime	8978553	[ -0.030466374, -0.0086678425, 0.011550511, 0.002510765, -0.0018347263, 0.023524167, 0.031603575, 0.023352263, -0.032820113, 0.026552292, -0.019993559, -0.0015545586, -0.012218285, 0.006492617, -0.025375422, 0.050962415, 0.006968654, -0.017044773, -0.06675098, 0.060298033, 0.07177582, -0.04712767, 0.013190194, -0.049904555, 0.014373676, 0.048476443, 0.02199027, -0.076906435, 0.010287691, -0.23569125, 0.0014983598, 0.023828302, -0.06008646, -0.042261515, -0.011735637, -0.063365825, -0.013395155, -0.020985302, -0.039537527, -0.028244868, -0.008310814, -0.040806957, -0.049507856, -0.027001882, 0.012727381, -0.042552426, -0.07405022, 0.000051550025, 0.04178548, -0.0059736045, -0.017494364, -0.051200435, 0.00022913418, 0.035068065, -0.022572093, -0.03578212, 0.022096055, -0.004142184, -0.012581925, -0.046889655, -0.028509332, 0.039378848, -0.13191517, 0.026327496, 0.067861736, -0.0033372184, 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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode	nsionless groups and an empirical fit was derived and was shown to correlate well all the experimental data.	8978553	[ 0.026821733, 0.09627902, -0.06631599, -0.018310733, 0.036030795, 0.010531357, 0.03372182, 0.01561245, -0.009625217, -0.039655354, 0.07458536, -0.019330978, 0.063684836, -0.017250214, -0.03903784, -0.02609682, 0.014914387, -0.010101779, -0.06835649, 0.013947838, -0.07480015, -0.103420734, 0.05831512, -0.017491851, 0.08446564, 0.08446564, -0.016149422, -0.058261424, 0.009752748, -0.15078163, -0.056167234, -0.0073430873, 0.06792691, 0.033345938, -0.030419443, 0.04658229, 0.005668407, -0.008658668, -0.07088026, -0.0138538685, 0.009497686, 0.025533002, -0.008014302, 0.041749544, 0.0099339755, -0.013625655, 0.02233802, -0.031493388, 0.003832635, -0.0061516813, 0.031198053, -0.04105148, -0.013907566, 0.09069451, 0.017881155, 0.060892582, -0.035305884, -0.016243393, -0.036326133, 0.0011628792, 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Contact Angle Studies of Ethyl Xanthate Coated Galena Particles	The wettability of ethyl xanthate coated galena particles has been determined from measurements of the equilibrium capillary pressure across a packed bed. Both the advancing liquid powder contact angle; thetap; and the specific wettable surface area; Awet; of galena particles have been obtained. The influence of particle size and ethyl xanthate surface coverage on the powder contact angle have been investigated and compared with floatability. Ethyl xanthate at a surface coverage of less than ten percent of	8978554	[ -0.009408793, 0.018128976, 0.034986675, 0.00859438, -0.0026683628, -0.026590932, 0.05066579, 0.035648797, -0.070344135, -0.021201236, -0.058478862, -0.034192123, 0.005767107, -0.016685545, -0.018221674, 0.052890528, -0.0032228923, 0.017149031, -0.04399157, 0.050745245, 0.033079755, -0.013997318, -0.026418779, -0.04298514, -0.025875837, 0.023545157, -0.046348736, -0.054294232, -0.042561382, -0.22120264, -0.0013275602, -0.04939451, -0.047567043, -0.02165148, -0.02643202, 0.07680648, 0.005856494, -0.007342964, -0.002636912, -0.010494678, -0.0067669153, 0.05667788, -0.07516441, 0.030060465, -0.029583735, -0.013341814, -0.020340472, 0.028974582, 0.07574707, 0.017691974, 0.07346936, -0.016407453, 0.06515308, -0.035092615, -0.048255656, 0.04187277, 0.022061998, -0.012335385, -0.012381733, 0.035092615, -0.04833511, -0.035648797, -0.13454376, 0.12712796, 0.06690109, 0.02643202, -0.0308815, -0.01936053, 0.06160409, 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Contact Angle Studies of Ethyl Xanthate Coated Galena Particles	an equivalent monolayer significantly increases both thetap and particle floatability.	8978554	[ -0.04362837, -0.009239724, 0.0043035233, -0.011691349, -0.041229468, 0.03413821, 0.07650123, 0.019573454, -0.031343885, -0.055359263, -0.001631121, -0.019296657, 0.0220778, 0.063056834, 0.07196704, -0.009694461, 0.02596613, 0.0111245755, -0.08593866, 0.040043198, 0.00798755, -0.065271206, 0.0106039345, -0.06569299, 0.024938028, 0.046791755, -0.028997708, -0.03411185, -0.026796518, -0.2418936, 0.021695558, -0.05245949, -0.018268555, -0.023712218, -0.024134003, -0.007671212, -0.008712493, -0.008422516, -0.009252905, 0.00036576655, -0.040306814, 0.0078162, -0.02069382, 0.012244942, 0.011770434, -0.02069382, 0.014551577, -0.021985535, 0.0095692435, -0.021866908, 0.009305628, -0.023000455, -0.015329243, -0.0048834775, -0.0026954687, 0.03769702, -0.037407044, 0.06848732, 0.011091623, 0.018123567, -0.031449333, 0.03687981, -0.0675383, 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Optimization of Long-Term Stability of Magnetic Fluids from Magnetite and Synthetic Polyelectrolytes	Nanometer-sized suspensions of magnetite (Fe3O4) stabilized with polymeric surfactants; principally poly(methacrylic acid) (PMAA); were prepared by precipitation or sonication and studied by a variety of techniques. The long-term stability of the ferrofluids made with PMAA was optimal at pH 7 (close to the measured isoelectric point of the magnetite; 5.9) and improved at all pH values with increasing surfactant concentration. With extended times of sonication the molecular weight and polydispersity of the P	8978555	[ -0.04029251, 0.031556286, 0.0072801835, -0.026393976, -0.07767294, 0.026063059, 0.002059961, 0.02561301, -0.07767294, -0.0115225455, -0.022092048, -0.051014233, 0.057870843, -0.016373795, -0.016241428, 0.059141565, 0.0024256248, 0.048313946, -0.022912724, 0.035500824, 0.033753578, -0.020490408, -0.029994357, -0.006489291, 0.0030212763, 0.047863897, -0.014123556, 0.027955905, -0.075766854, -0.20924571, -0.01727389, -0.06681885, 0.0026192116, -0.036295027, 0.0053012976, 0.015142783, -0.019471182, -0.029411942, -0.046593174, 0.03851879, 0.010562885, 0.011681385, -0.0022833303, -0.003330684, -0.0042754533, -0.008656801, 0.018809346, -0.0034084497, 0.07190174, -0.012091723, 0.05082892, -0.006055789, -0.00097124267, -0.003234718, -0.052258484, 0.06623644, -0.02336277, -0.004205961, 0.062636055, -0.006340378, -0.022012629, 0.023984896, -0.17027688, 0.12188351, 0.061630063, 0.06533634, -0.017909251, 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Optimization of Long-Term Stability of Magnetic Fluids from Magnetite and Synthetic Polyelectrolytes	MAA decreased; although magnetite in the ferrofluid was not oxidized (X-ray). Particle diameters of 9-38 nm were measured by saturation magnetization; electron microscopy; and dynamic light scattering. Centrifugation at 8;000 rpm removed the magnetite from the suspensions together with roughly one molecule of PMAA for each magnetite particle in the fluid; with the average number increasing with higher concentrations and average molecular weights of the polymer.	8978555	[ -0.056241598, 0.0477016, 0.007961352, -0.03660759, -0.051426213, 0.006903829, 0.043817367, 0.013481755, -0.056933314, 0.00044188165, -0.0042334176, -0.08944383, 0.06283948, -0.018756067, -0.052623406, 0.018197376, 0.02439619, 0.030222543, -0.06736222, 0.04102391, 0.026271798, -0.031127091, -0.01613554, 0.02103074, 0.03599569, 0.090986885, -0.031685784, -0.014911739, -0.057731442, -0.22645624, -0.016827252, -0.057731442, 0.014565882, -0.057625026, 0.025087904, 0.0026754, -0.02432968, -0.0035317277, -0.03796441, 0.022267843, 0.08300558, 0.045014564, -0.00008059248, 0.0014283211, -0.017266225, 0.01057523, 0.051745463, 0.01204512, 0.07544994, 0.0005520403, 0.05948733, -0.035197556, 0.008340464, 0.030408774, -0.03612871, 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Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles	Microviscosity; micellar aggregation number (N); and critical micelle concentration (cmc) were determined in solutions of sodium N-dodecanoyl-glycinate (Lau-Gly); -valinate (Lau-Val); -leucinate (Lau-Leu); and -phenylalaninate (Lau-Phe) as a function of NaCl using fluorescent probes (auramine; pyrene). The microviscosity increased with increasing concentration of NaCl and reached a saturated value. In addition; two breakpoints were found on the curve of microviscosity vs NaCl concentration and by comparison	8978556	[ -0.030366015, -0.02160355, -0.040233653, 0.0025294048, 0.02044575, -0.0022712017, 0.03381311, 0.033944678, -0.046575256, -0.028234605, 0.00069936895, -0.06673156, -0.005798883, 0.03757597, 0.008972974, -0.019116906, -0.011400413, -0.030523896, -0.0627845, -0.017867004, 0.04041785, -0.029708173, -0.01588032, -0.058995325, 0.024984863, 0.03841801, -0.013097647, -0.020629944, -0.025379568, -0.25429565, -0.016288184, 0.0036345804, 0.0098544825, 0.010834668, 0.008334866, -0.024905922, 0.02586637, -0.03515511, -0.02674788, 0.024063883, 0.07136276, -0.033918366, -0.0005821907, 0.014801458, 0.0064665927, -0.037391774, 0.016827613, -0.014275185, 0.05767964, -0.0408915, 0.011393834, -0.05128541, -0.020735199, 0.023445511, -0.02883982, 0.03310264, -0.0453122, 0.00978212, 0.012281922, -0.0074796705, 0.052969486, 0.024221765, -0.1541983, 0.10346548, 0.015932947, -0.0018090672, 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0.00052296696, -0.005038902, 0.01689282, -0.011117159, -0.04065328, -0.015840309, -0.0540465, 0.0215765, -0.056098897, 0.019576726, 0.026996937, -0.03649586, 0.07241283, -0.031864807, 0.049573325, -0.04044278, -0.09567335, -0.2919669, -0.011275036, 0.023444708, -0.037390493, 0.06846592, -0.059466936, 0.026825903, 0.014603606, 0.0045356695, -0.06841329, 0.06409799, 0.066834524, -0.035838038, -0.033759326, 0.016221844, 0.058940683, -0.0004826755, -0.014340478, 0.053309742, 0.04899444, 0.038653508, -0.017471703, 0.026970625, 0.02870727, 0.074991494, 0.015879776, 0.14977248, 0.017787455, -0.061835088, -0.00994624, 0.011242146, 0.018195303, -0.071676075, -0.11598684, -0.042021547, -0.029496653, -0.017642735, -0.0044665984, -0.04307406, 0.005617784, 0.008762164, 0.0025704321, 0.0064334804, -0.058414426, -0.0047297264, -0.041258477, 0.013011682, 0.03454871, 0.024286719, -0.012373596, -0.017090166, 0.003828513, 0.024102528, -0.034180332, 0.0072425995, 0.023299988, 0.025207667, -0.006403879, -0.055783145, 0.012702506, -0.026457524, 0.02731269, 0.02416831, -0.084674604, 0.0043712147, -0.020931836, 0.010459339, -0.027707383, 0.06251922, -0.011584212, 0.017142791, 0.105830096, -0.027260065, -0.025418168, -0.00070427865, 0.054572757, 0.019037314, -0.05273086, -0.06999206, 0.029680843, 0.004746172, 0.029417714, 0.046678916, -0.0027003514, 0.012255188, 0.056309402, -0.006456504, -0.033206757, 0.015813995, 0.019734602, -0.016761256, -0.009005557, -0.013551094, -0.0822012, -0.021813314, 0.026431212, -0.26944312, 0.00471657, 0.008038562, 0.02702325, -0.016734943, -0.0016453725, 0.078464784, -0.050257456, -0.044494953, 0.021892253, 0.0021527163, -0.0058381534, 0.04317931, 0.049994327, 0.029943971, 0.032996256, 0.02965453, -0.01744539, 0.03444346, 0.02266848, 0.038364068, -0.06878167, 0.20502937, 0.009933083, -0.044337075, 0.015471929, 0.06436112, -0.030996483, 0.004841556, 0.02482613, -0.021260746, 0.026917998, 0.042389926, -0.041442666, 0.08088556, 0.078885786, -0.04062697, -0.01843212, 0.028786208, 0.033706702, 0.06572939, -0.029286152, -0.07857003, -0.009130543, 0.07641238, -0.017063854, -0.023589429, -0.04920494, -0.0057033002, -0.0038022, -0.09314733, 0.016024498, 0.002047465, -0.032233186, -0.008827946, -0.005706589, -0.067413405, 0.07162345, 0.011689464, 0.017905863, -0.010051491, -0.01637972, -0.0020491097, 0.04625791, 0.04965226 ]
Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles	with the data of N and solution viscosity. The first and second breakpoints were explained; respectively; as the beginnings of micellar growth and intermicellar interaction. The value of N increased steeply above the first breakpoint and the solution viscosity began to increase at the second breakpoint. The NaCl concentrations at the first and second breakpoints increased in the order Lau-Phe < Lau-Leu < Lau-Val approximately Lau-Gly. The absolute value of the slope of the Corrin-Harkins plot of the cmc wa	8978556	[ -0.07404272, 0.011597454, -0.079951234, -0.012542283, -0.013354039, 0.00082215166, 0.039576393, 0.046709195, -0.00841697, 0.0012217914, 0.024525654, -0.07510732, 0.057594698, 0.028398126, 0.015662884, -0.00996729, 0.018856674, -0.028371511, -0.06004327, 0.017406162, 0.014052681, -0.03231052, 0.0031305805, -0.09714448, 0.07377657, -0.0071261465, -0.060149733, 0.021944007, -0.009288609, -0.24294104, 0.018750215, 0.04080068, 0.02291545, -0.055305816, -0.02171778, 0.035530925, 0.013520382, -0.03875133, -0.03462602, -0.0021924046, 0.041492667, 0.01137788, 0.008377048, 0.017871922, 0.021464938, -0.007625176, 0.0068666507, 0.006414197, 0.06424843, -0.011637376, 0.029702257, -0.035078473, 0.002202385, 0.03912394, -0.048013326, 0.010326591, -0.031485457, -0.012934853, -0.025324102, 0.02366067, 0.008935961, -0.015223738, -0.15064047, 0.072818436, 0.035797074, 0.063609675, -0.015103971, -0.015064048, 0.0033751053, 0.049290843, -0.045671213, 0.043914627, -0.0043082912, 0.01940228, 0.056210723, 0.0014729698, -0.07409595, 0.043914627, -0.005372888, 0.0020659836, 0.03545108, -0.052165255, -0.005173276, -0.07925925, -0.025057953, -0.011324651, 0.0076917135, 0.020413648, 0.041545898, -0.059085134, 0.025776556, -0.061427247, -0.01667425, 0.0019229284, -0.01198337, 0.05461383, 0.0068666507, -0.03986916, 0.014358752, 0.3864487, -0.054161374, -0.013786531, -0.071328, -0.0036495717, 0.009687833, 0.027133916, 0.026841152, 0.008656505, 0.0693585, -0.029276418, 0.04316941, 0.011218191, -0.016301641, -0.055944573, -0.06685669, 0.006297757, 0.09698479, -0.07947217, -0.014611594, 0.0120831765, -0.02805213, -0.024831725, 0.0149442805, -0.033188812, -0.01431883, 0.028903808, -0.012675358, 0.012415863, 0.047481027, -0.017911844, 0.012761856, -0.027280299, -0.0007643474, -0.024099816, 0.023101754, -0.024365963, 0.018271146, -0.013986143, 0.00707957, 0.03420018, -0.035264775, -0.03587692, -0.035956763, -0.07526701, 0.0086165825, 0.03949655, 0.007625176, -0.01982812, 0.019894658, 0.00033809274, 0.007532024, 0.02680123, 0.037101205, 0.058020536, 0.011843642, 0.010339899, 0.0091222655, 0.000278625, -0.0066271164, -0.03986916, -0.027945671, 0.010206824, 0.02444581, 0.09661218, -0.025310794, -0.025191028, -0.027054071, 0.021198789, 0.0022739128, -0.009049075, 0.035797074, 0.0032736359, 0.007824788, -0.047481027, 0.034226794, -0.016115338, 0.017246472, -0.010905466, -0.017419469, 0.013813146, 0.019176053, 0.032683127, 0.054507367, 0.043808166, 0.07010371, -0.034759093, -0.005123373, 0.017446084, 0.0059351283, 0.05583811, -0.08319826, -0.058180228, -0.002475188, 0.028770734, -0.00970114, -0.021039099, -0.033588037, 0.0019528702, -0.0032054351, 0.026787922, 0.05668979, 0.057541467, -0.0037560314, -0.0077116746, 0.055199355, 0.039736085, 0.030181326, -0.031405613, 0.0048871655, -0.008962576, -0.060362652, -0.027040765, -0.04069422, -0.06089495, -0.028078746, 0.05700917, 0.08016416, -0.02831828, 0.066750236, -0.014026065, 0.071913525, -0.025537021, -0.08138844, -0.29659674, -0.043062948, 0.030447476, -0.0285312, 0.12647413, -0.10347883, 0.06052234, 0.023500979, 0.033588037, -0.07925925, 0.063077375, 0.017659003, -0.031378996, -0.011544224, -0.027599677, -0.011364574, 0.0427968, 0.016873863, 0.038831174, 0.07100862, -0.0007256726, 0.027027456, -0.013420576, 0.06541949, 0.06712284, 0.015183815, 0.10566125, -0.010972003, -0.061640166, -0.016128644, -0.008383702, -0.0015677854, -0.049690064, -0.05791408, -0.034439713, 0.010180209, -0.0058552837, -0.031192692, 0.003742724, -0.006064876, -0.055518735, 0.009820907, 5.198228e-7, -0.074255645, -0.040481303, -0.0041253134, -0.005123373, 0.01883006, -0.008210705, -0.037207667, -0.00529637, 0.022928758, -0.012336018, -0.050940968, 0.022955373, -0.0066504045, -0.0068666507, -0.0486787, -0.0058386493, 0.028903808, -0.021983929, 0.036595523, 0.07984477, -0.039203785, -0.030926544, -0.002525091, 0.03587692, -0.005918494, -0.0063842554, 0.039203785, -0.02574994, 0.08287888, -0.046017207, 0.019907964, 0.019295821, 0.02569671, -0.039895773, -0.06275799, -0.028131977, 0.012422516, -0.012449131, -0.026668156, 0.05738178, 0.004451346, 0.021265326, 0.026841152, -0.0043448866, -0.05748824, -0.0007730804, -0.007352373, 0.014744668, -0.007784866, -0.03129915, -0.035051856, -0.028504586, 0.018696984, -0.2953192, 0.024658728, 0.008317164, 0.06653731, 0.014119218, 0.051420037, 0.041093446, -0.03848518, -0.055891342, 0.063077375, -0.045857515, -0.0063776015, 0.026548387, 0.0068932655, 0.048971463, 0.008709734, 0.024352657, -0.05176603, -0.0026465217, 0.023926819, 0.041279748, -0.024778496, 0.17320994, 0.044367082, -0.029755486, 0.026495159, 0.039949004, -0.015915725, -0.022356538, -0.010965349, -0.008656505, 0.06398228, 0.034812324, -0.034067106, 0.05248463, 0.08628559, -0.046815652, -0.016754096, 0.0025300814, 0.049556993, 0.06398228, 0.0076717525, -0.097570315, -0.022649301, 0.12423847, -0.04599059, -0.027107302, -0.03550431, 0.022103695, -0.00061754946, -0.02596286, -0.003117273, 0.007838096, -0.0010687556, 0.03172499, -0.0025932917, -0.028930424, 0.017525928, 0.0019961195, -0.0008150821, 0.05770116, -0.02029388, -0.02821182, 0.00089825375, 0.07697036 ]	[ -0.07398999, 0.01157757, -0.07995177, -0.012509098, -0.013360782, 0.00085750537, 0.039550044, 0.04673612, -0.008403719, 0.0011660742, 0.024499202, -0.07510782, 0.057595085, 0.028345086, 0.01564968, -0.009914126, 0.018843494, -0.028371701, -0.060096905, 0.017379662, 0.014012852, -0.032337353, 0.0031256112, -0.097145125, 0.073777065, -0.007179424, -0.060203366, 0.021970768, -0.009308632, -0.24294266, 0.018763648, 0.040854186, 0.022955528, -0.055252954, -0.021704618, 0.035477933, 0.013467243, -0.03875159, -0.03462625, -0.0021325352, 0.041546177, 0.011391264, 0.008403719, 0.017898656, 0.021465082, -0.007658496, 0.0068467353, 0.0064308746, 0.06419563, -0.011637454, 0.029675841, -0.035078708, 0.002222361, 0.03909759, -0.048013646, 0.010359929, -0.031538896, -0.012875057, -0.025350885, 0.023674134, 0.008909406, -0.015197224, -0.15064149, 0.072872154, 0.0357707, 0.0636101, -0.015064148, -0.0150508415, 0.003390099, 0.04929117, -0.045698132, 0.043941535, -0.0042617433, 0.01940241, 0.0562111, 0.0014979313, -0.07409645, 0.04391492, -0.0053895586, 0.0020842953, 0.03545132, -0.052165605, -0.0051832916, -0.079259776, -0.025111351, -0.011291457, 0.0076851114, 0.020427093, 0.041546177, -0.05919199, 0.025803342, -0.06142766, -0.01668767, 0.0019645274, -0.012083257, 0.054614194, 0.0069066193, -0.03984281, 0.014318926, 0.3862384, -0.05413512, -0.013826546, -0.071328476, -0.0036762112, 0.00967459, 0.027160713, 0.026934486, 0.008663217, 0.06930573, -0.029276613, 0.0431697, 0.0111583825, -0.016261829, -0.05594495, -0.066857144, 0.0063044527, 0.09698544, -0.0794727, -0.014651614, 0.012063296, -0.028025704, -0.024805278, 0.014931073, -0.033135805, -0.014358848, 0.028957233, -0.012722019, 0.0124159455, 0.04745473, -0.017925272, 0.012735327, -0.027333712, -0.0007402326, -0.02408667, 0.023101911, -0.024339512, 0.01825796, -0.013959622, 0.0070796176, 0.034227025, -0.035211783, -0.03593039, -0.035983622, -0.07532074, 0.008643255, 0.039496813, 0.0076451884, -0.019801637, 0.019868175, 0.0003245795, 0.007512113, 0.026774794, 0.037101455, 0.058020927, 0.011830414, 0.010359929, 0.009109019, 0.00031439093, -0.006627161, -0.039816193, -0.027919244, 0.010246815, 0.024432665, 0.09666605, -0.025284348, -0.025257733, -0.027054252, 0.021185622, 0.002243986, -0.009062443, 0.03582393, 0.0033052631, 0.007784918, -0.047534574, 0.03425364, -0.01608883, 0.017246587, -0.010885578, -0.017432893, 0.013826546, 0.01918949, 0.032656733, 0.054507732, 0.04386169, 0.070157416, -0.034759324, -0.0051832916, 0.017419586, 0.005931841, 0.055838488, -0.08330528, -0.058180615, -0.002536752, 0.028744312, -0.009687898, -0.021052547, -0.033561647, 0.0019794984, -0.0032137737, 0.026814718, 0.056796633, 0.057488624, -0.0037494027, -0.0076984186, 0.055199724, 0.039762966, 0.030208142, -0.031379208, 0.004953736, -0.008962636, -0.060363054, -0.027080867, -0.040667877, -0.060895357, -0.028078934, 0.05700955, 0.08011146, -0.028291855, 0.06680391, -0.014026159, 0.07186078, -0.025510577, -0.08138899, -0.2965987, -0.04308985, 0.030447679, -0.028504776, 0.12647498, -0.103532754, 0.060469516, 0.023461213, 0.033614878, -0.07920655, 0.06307779, 0.017672429, -0.031325977, -0.01152434, -0.027573247, -0.011377957, 0.042876933, 0.016860668, 0.038831435, 0.07106233, -0.0007477181, 0.027080867, -0.013473896, 0.065313466, 0.067123294, 0.015157302, 0.10566196, -0.011005346, -0.06169381, -0.016128752, -0.008330528, -0.0015727862, -0.049717013, -0.057914466, -0.03441333, 0.010173623, -0.0058453423, -0.031219516, 0.0037194607, -0.0060981857, -0.05557234, 0.009860896, -0.0000036972642, -0.07425614, -0.04050819, -0.0041319947, -0.0050834846, 0.018816879, -0.008237375, -0.037207916, -0.0053596166, 0.022875682, -0.0123361, -0.050941307, 0.022915604, -0.006623834, -0.006860043, -0.048732255, -0.0058653033, 0.028930617, -0.021970768, 0.03654254, 0.07979208, -0.039177433, -0.030953366, -0.0025134638, 0.035903774, -0.0059185335, -0.006410913, 0.039230663, -0.025803342, 0.08287943, -0.046017513, 0.019881483, 0.019269336, 0.025723498, -0.03989604, -0.062758416, -0.02815878, 0.0124226, -0.0124159455, -0.026668334, 0.057435393, 0.004487972, 0.021225546, 0.026814718, -0.0043382617, -0.057488624, -0.0007485498, -0.007325807, 0.014744768, -0.007811533, -0.031325977, -0.03499886, -0.028504776, 0.018723726, -0.2953212, 0.02468551, 0.008330528, 0.06659099, 0.014159235, 0.051446997, 0.04114695, -0.03843221, -0.05589172, 0.063024566, -0.045857824, -0.0063776444, 0.026575182, 0.0068866583, 0.04897179, 0.008696485, 0.02440605, -0.05173976, -0.0026531932, 0.023993516, 0.04125341, -0.024791969, 0.17331755, 0.044393994, -0.0297823, 0.026495336, 0.03989604, -0.015942447, -0.022356687, -0.010945462, -0.008636601, 0.06398271, 0.034839172, -0.034120563, 0.052484985, 0.086286165, -0.04678935, -0.01679413, 0.0024868487, 0.04963717, 0.063929476, 0.0076451884, -0.09767743, -0.022596223, 0.1242393, -0.046017513, -0.027094176, -0.03550455, 0.022090536, -0.0006321087, -0.025976341, -0.0031588802, 0.007844802, -0.0010729213, 0.03175182, -0.0025933092, -0.028930617, 0.017539354, 0.001989479, -0.00078306627, 0.057701543, -0.020320632, -0.02821201, 0.0009182211, 0.07702411 ]
Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles	s smaller for Lau-Leu and -Phe than for Lau-Gly and -Val. Larger absolute values of the slope (1.2 approximately 2); which suggested the contribution of a salting out effect on cmc; were observed at high NaCl concentration for Lau-Gly and -Val. The micellar growth and intermicellar interaction occurred at lower NaCl concentration with increased size of the amino acid residue when the amino acid of the amino acid surfactant was larger than valine; that is; the hydrophobicity of the amino acid residue was the	8978556	[ -0.019874915, 0.026464812, -0.05253502, -0.015639493, -0.014179457, 0.050667226, 0.03664561, -0.0015126507, 0.016770694, -0.029384887, -0.02283445, -0.04993063, 0.092074394, 0.000019999978, 0.0140216155, -0.0029019876, -0.0006190359, 0.04740516, -0.036777146, 0.048010223, 0.011377765, -0.053271614, 0.028122151, -0.044774465, 0.02864829, 0.00078797597, -0.031831436, -0.039986596, -0.014600368, -0.18551676, -0.004047985, -0.0010317265, 0.082446046, -0.022413539, -0.00516932, 0.00090348005, -0.008687877, -0.031805128, -0.07381736, 0.02539938, -0.0052646827, 0.008549766, 0.010029533, 0.010193951, -0.010042686, 0.023597352, -0.02909551, 0.0115947975, -0.009556007, -0.014823978, 0.005517887, 0.010036109, -0.019388238, 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-0.06129524, 0.038355563, 0.0005734097, 0.005488292, 0.0057250545, 0.013120602, 0.058033176, -0.07523794, 0.03943415, 0.051956266, -0.016612852, -0.04053904, 0.043459114, 0.010851625, -0.061716154, 0.009108788, 0.015692107, -3.018622e-7, 0.029674264, 0.011621105, 0.043722186, 0.0030713389, 0.015665801, -0.36977077, -0.020032758, -0.036435153, -0.013837467, 0.035987936, -0.061716154, 0.01845434, -0.021755865, -0.06750368, 0.015981484, -0.06687232, 0.05550771, -0.062294908, 0.0036862642, -0.043538038, 0.0036599573, -0.008069663, -0.029121816, -0.0247154, 0.005037785, -0.030200401, 0.052929625, -0.000053538795, 0.0005290167, 0.06545174, 0.04048643, 0.15942024, -0.059979893, -0.038145106, 0.07213371, 0.037145443, 0.03761897, -0.022413539, -0.023465818, 0.03185774, 0.026477966, 0.02962165, -0.08986461, -0.04551106, -0.016783847, 0.050141085, -0.024110338, 0.002602746, 0.017757205, -0.089496315, -0.019296164, 0.011561913, 0.02864829, -0.05237718, 0.052324563, 0.064399466, -0.05650737, 0.02535992, 0.022137316, 0.024662785, -0.02864829, -0.046879023, 0.009056174, -0.06818767, 0.06550436, -0.02313698, 0.00023183018, 0.014692443, -0.05619169, -0.004209115, -0.019572387, -0.0031946527, 0.016257707, 0.005402794, 0.0037849154, -0.016113019, 0.08639209, -0.047089476, -0.026162282, 0.004215692, 0.013574397, -0.020203754, 0.06397855, -0.041038875, -0.013837467, 0.027385557, 0.0052022035, -0.0075172167, 0.019164627, -0.019033093, -0.059506368, 0.0072212634, 0.019874915, 0.021137651, 0.017573057, -0.03985506, 0.025451994, -0.042669907, -0.0294375, 0.0032406899, -0.0005261394, -0.3158941, 0.016323475, -0.007300184, -0.011542183, -0.04811545, 0.019072553, 0.04069688, -0.032436494, -0.12785187, -0.03648777, 0.020335289, 0.010838472, 0.036145777, -0.0004862679, 0.027148794, -0.029937332, 0.019795995, -0.060979556, 0.04064427, -0.06292627, 0.03840818, 0.094757706, 0.18309651, -0.013469169, 0.001966446, 0.037092827, 0.01867795, 0.009378435, -0.048220675, -0.056717828, -0.015744722, 0.019309316, 0.09791455, -0.023676274, 0.03354139, 0.060663875, 0.016731232, -0.021216571, 0.008562919, -0.015573727, 0.0150738945, 0.041065183, -0.061926607, -0.0482996, 0.13279758, -0.053929288, 0.024399715, 0.018862098, 0.073396444, -0.015336964, 0.026425352, 0.053876676, 0.017612517, 0.035014577, 0.008523459, -0.028753519, -0.030331938, 0.009253477, 0.03343616, -0.023571046, -0.018046582, 0.0031058667, -0.016126173, 0.054823726, 0.035961628 ]	[ -0.019875009, 0.026464935, -0.052535262, -0.01565272, -0.014153216, 0.050720073, 0.036672086, -0.0015036147, 0.01677077, -0.029332409, -0.022795096, -0.04985194, 0.09207483, 0.000010115642, 0.014021681, -0.0029365292, -0.0006046521, 0.047379073, -0.03675101, 0.04803675, 0.011390971, -0.053271864, 0.028095976, -0.04477467, 0.028701037, 0.0008142867, -0.031884197, -0.039960474, -0.014587283, -0.18551761, -0.0040973295, -0.001020222, 0.082446426, -0.022374183, -0.005189074, 0.00084758166, -0.008668187, -0.03185789, -0.0738177, 0.025399499, -0.0052712834, 0.008576112, 0.010029579, 0.010240036, -0.010055886, 0.023544848, -0.029095644, 0.011627735, -0.009562628, -0.014784586, 0.005514624, 0.0100230025, -0.019440942, 0.059401415, 0.049167957, 0.048720736, 0.006678713, -0.011522506, -0.018270276, -0.012022342, 0.0015282776, 0.04469575, -0.098651595, 0.03177897, 0.1042287, 0.038197897, -0.014192676, -0.005419261, -0.007727708, 0.024899663, -0.007155529, 0.038829267, -0.022966092, 0.011456739, 0.030358385, 0.017573137, -0.0061131106, -0.022150572, -0.0021292302, 0.015981559, 0.06576773, -0.014350519, -0.019704012, -0.033068016, -0.02678062, -0.05200912, 0.02243995, -0.037119307, -0.05374539, -0.00027108638, -0.0055343546, -0.029411329, 0.046826623, 0.0031996001, -0.0052252463, 0.022755634, 0.053534932, 0.010266343, -0.037592836, 0.3910286, 0.00072262296, 0.03864512, 0.013206161, 0.013008857, 0.0023413312, 0.01865173, 0.008582689, 0.029727014, 0.019467248, 0.011877652, 0.054403067, 0.00094458903, -0.006218339, -0.031515896, 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-0.009779662, -0.0058303094, -0.022176879, -0.05348232, 0.02637286, -0.061400753, 0.028885188, -0.011404125, -0.023873687, -0.0025813833, 0.023676382, -0.011134476, 0.041091677, -0.061242912, 0.03835574, 0.0005314855, 0.005514624, 0.0056593134, 0.013127239, 0.05808606, -0.07523829, 0.039434332, 0.051982816, -0.016626082, -0.04053923, 0.043406703, 0.010812215, -0.061769053, 0.009075947, 0.015705334, 0.00003157365, 0.029700708, 0.011614582, 0.043669775, 0.0030598438, 0.015600106, -0.3697725, -0.020006543, -0.036487937, -0.013863837, 0.035961796, -0.061769053, 0.018467579, -0.02180858, -0.067503996, 0.016007865, -0.06692524, 0.055560578, -0.062242582, 0.003682993, -0.043564547, 0.0036862814, -0.008082855, -0.029121952, -0.024662899, 0.005027943, -0.030174235, 0.05295618, -0.00001023125, 0.00047969338, 0.065346815, 0.040512923, 0.15942098, -0.060085397, -0.038118977, 0.07208143, 0.037145615, 0.037645448, -0.022374183, -0.02340016, 0.031884197, 0.026451781, 0.02959548, -0.08986503, -0.045537576, -0.016744465, 0.05014132, -0.024215678, 0.0026652373, 0.017678367, -0.089444116, -0.01932256, 0.011489622, 0.028622117, -0.052351113, 0.0522985, 0.06445238, -0.056507636, 0.025320577, 0.022137418, 0.024662899, -0.028648423, -0.046905547, 0.009102254, -0.06818798, 0.06550466, -0.023123935, 0.00019761147, 0.014626743, -0.05619195, -0.004195981, -0.019598784, -0.003214398, 0.01624463, 0.005386377, 0.003768491, -0.016139401, 0.08639249, -0.04703708, -0.026096636, 0.004245307, 0.0135613065, -0.020203847, 0.06397885, -0.041065373, -0.013863837, 0.027359376, 0.0052384, -0.0074580605, 0.019164717, -0.018980566, -0.059454028, 0.0072673345, 0.019835548, 0.021150902, 0.017573137, -0.039855246, 0.025465265, -0.042696413, -0.029385023, 0.003276877, -0.0005129883, -0.31589556, 0.016310398, -0.0072936416, -0.011515929, -0.04811567, 0.019112103, 0.040670764, -0.03248926, -0.12774724, -0.03646163, 0.02036169, 0.0108056385, 0.03619856, -0.0005224424, 0.02714892, -0.029911164, 0.01976978, 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Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles	dominant factor rather than steric hindrance.	8978556	[ -0.04345734, 0.03816874, 0.056198064, -0.005866207, 0.019765478, -0.03288014, 0.007485507, -0.032212388, -0.06917918, -0.03782151, -0.030476231, -0.07446778, -0.049386986, 0.05040197, -0.033788282, 0.02122118, 0.015024435, 0.03280001, -0.06255507, -0.03504366, 0.04989448, 0.007011403, -0.011091371, -0.07142282, 0.015064499, 0.009361892, -0.019097725, -0.069659956, -0.026389584, -0.18194924, 0.050882753, -0.038783073, 0.0021368084, -0.058869075, -0.027858641, -0.0061700344, -0.03274659, 0.05748015, -0.04770425, -0.023010757, 0.02796548, 0.0075656376, 0.016066128, -0.0150778545, 0.008273455, -0.032212388, 0.031838447, -0.0034789913, 0.066347905, 0.02610913, 0.062448226, -0.0036292356, 0.014837463, -0.033734865, -0.026870366, 0.005552363, 0.06848471, 0.0123934895, 0.07291859, 0.012346746, 0.046502296, 0.039450828, -0.14968343, 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Zeta Potential Measurements on Three Clays from Turkey and Effects of Clays on Coal Flotation	There is a growing trend of characterizing coal and coal wastes in order to study the effect of clays present in them during coal washing. Coarse wastes from the Zonguldak Coal Washery; Turkey; were characterized and found to contain kaolinite; illite; and chlorite. These three clays; obtained in almost pure form from various locations in Turkey; have been subjected to X-ray diffraction (XRD) analysis to assess their purity and zeta potential measurements in order to evaluate their properties in terms of th	8978557	[ -0.05270472, 0.03825558, -0.013256158, 0.020820633, -0.030471168, -0.026672268, 0.042574327, 0.01660852, -0.04670646, 0.011136772, 0.011463344, -0.083869025, -0.054704145, 0.030071285, -0.07203245, 0.036309477, 0.00011100949, 0.0024542885, -0.10253028, 0.046039987, 0.050065488, -0.027751956, 0.0056150393, -0.034283396, 0.020940596, 0.042600986, 0.012616343, -0.03593625, -0.02616575, -0.23779774, 0.021980295, -0.014102579, -0.0009547233, 0.02136714, -0.07619125, 0.009217328, -0.058756303, 0.045800056, -0.055130687, -0.05227818, 0.02737873, 0.043400753, 0.0054984065, 0.0005023544, -0.015422196, -0.04198783, -0.0007785243, -0.007857722, 0.060249202, -0.023619821, 0.08173631, -0.00672805, 0.008437554, -0.006801362, -0.0679803, 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Zeta Potential Measurements on Three Clays from Turkey and Effects of Clays on Coal Flotation	eir surface charge and point of zero charge (pzc) values. It was found from XRD data that these clays were almost pure and their electrokinetic potential should therefore be representative of their colloidal behavior. All three clay minerals were negatively charged over the range from pH 2.5 to 11. Chlorite and illite have pzc at pH 3 and pH 2.5; respectively; whereas kaolinite has no pzc. 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Zeta Potential Measurements on Three Clays from Turkey and Effects of Clays on Coal Flotation	ial mixtures of Zonguldak clean coal (4.5% ash) and individual clay. The flotation tests on coal/individual clay revealed that each clay influences coal flotation differently according to its type and amount. Illite had the worst effect on coal floated; followed by chlorite and kaolinite. The loss of yield in coal was found to be 18% for kaolinite; 20% for chlorite; and 28% for illite; indicating the worst effect of illite and least for kaolinite during coal flotation.	8978557	[ -0.038310308, 0.004948083, 0.060425684, -0.026376503, 0.017801153, 0.007685956, 0.043593574, 0.02944292, -0.03682356, 0.018624173, -0.0655762, -0.027849976, 0.011522297, -0.04691221, -0.008349683, 0.008197025, 0.036451872, 0.027186248, -0.026270306, 0.041283805, 0.030372137, -0.03823066, -0.011024501, -0.03483238, -0.03769968, 0.057345994, 0.018783467, 0.019885253, -0.10274491, -0.21260495, 0.014548891, -0.069346175, 0.016181659, 0.01700468, -0.014548891, -0.02769068, 0.055009674, 0.007194798, -0.043805968, 0.011920533, -0.0025536888, -0.0037334631, 0.013354182, -0.053814966, 0.008124015, 0.030239392, 0.022726005, 0.040089097, 0.010241304, -0.031088961, 0.023947261, -0.024610989, 0.017774602, -0.02402691, 0.0088076545, 0.07327543, -0.009942627, 0.026164109, 0.018159565, 0.0010926602, 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The Conductivity Confined Temperature Dependence of Water-Free Electrorheological Fluids	The shear stresses and the current densities of four sorts of water-free ER fluids; two oxidized polyacrylonitriles-based and two aluminosilicates-based; were investigated at elevated and reduced temperatures in order to elucidate the operating mechanism. The complicated relationships among the mechanical properties; the current density; and temperature were especially addressed. The Wagner model was introduced to interpret our observations; instead of the commonly used conductivity model. It is found that	8978558	[ -0.038196497, 0.02314819, 0.013241718, -0.025887854, 0.02071293, 0.00008416696, -0.042669963, -0.018727666, 0.0007771485, -0.020434994, -0.030890722, -0.032267172, -0.035073016, 0.03986412, 0.024934927, 0.034728903, -0.0023856268, 0.021798208, -0.07041073, -0.00764327, -0.028746637, -0.02263202, 0.020884987, -0.04658755, -0.012798341, 0.03457008, -0.068399, -0.013777738, -0.03959942, -0.2045617, 0.06628138, 0.025040809, 0.07353421, -0.060034413, 0.04502581, -0.005383377, -0.007934443, 0.01091234, -0.09497508, 0.008801341, 0.018304143, -0.0067432835, -0.039202366, -0.00044130784, -0.0029530816, -0.04510522, -0.013440244, 0.0033368994, -0.013056425, -0.04015529, 0.050955135, -0.08814576, -0.047514006, -0.007352098, 0.013327746, -0.0038117087, 0.049763974, 0.024974633, 0.067287244, -0.0091388365, 0.04489346, 0.025014339, -0.13828032, 0.004334495, 0.10731019, -0.01166674, 0.02779371, -0.014823312, 0.014135087, 0.020209998, -0.01064102, 0.04214056, 0.044469934, 0.08899281, -0.032611284, -0.0008826157, -0.029355451, -0.03306128, -0.025464332, 0.047461066, 0.0024187146, -0.0019223982, 0.01995853, -0.05339039, -0.09418097, 0.018158557, -0.0037025192, -0.07125778, 0.002049786, 0.0090858955, 0.02374377, -0.021361452, -0.044522874, 0.035046544, -0.0476993, 0.003386531, 0.021679094, 0.013698328, 0.06628138, 0.3644417, -0.033881854, 0.0019885737, 0.044152293, 0.001524518, -0.035549477, 0.034834784, -0.04142586, -0.03856708, 0.01796003, 0.0044337586, 0.061940268, -0.064746104, 0.04666696, 0.022287907, -0.060087353, -0.0065778447, -0.031155424, 0.022751136, -0.049949266, -0.016848281, -0.02076587, 0.017523272, -0.011024838, -0.015048308, 0.03187012, 0.0056944015, -0.030970134, 0.08385759, 0.01191159, -0.030652491, -0.0098005915, 0.0031267924, 0.012692461, -0.025556978, -0.019998236, -0.050663963, 0.0017701946, -0.016570345, -0.0362377, 0.030811312, -0.08237526, 0.005793665, -0.009330745, -0.110751316, -0.040499404, 0.081316456, -0.009707945, -0.019865885, 0.009562359, -0.04881105, -0.026999604, 0.0556933, -0.03703181, 0.041796446, 0.01653064, 0.024405524, -0.030334849, 0.071946, -0.018965898, 0.030255439, -0.03311422, -0.013989501, -0.03155248, 0.10519257, 0.04240526, -0.0039374423, 0.007438126, -0.017483566, 0.057599153, -0.01982618, 0.016861517, 0.02071293, 0.005171615, -0.093280986, 0.06898134, 0.02187762, 0.010581463, 0.016702697, 0.03332598, 0.029302511, 0.04362289, 0.04687872, 0.0008702078, 0.04235232, 0.06765783, -0.05955795, -0.06220497, -0.0172321, -0.014690961, 0.03435832, -0.048546344, -0.03954648, -0.022843782, 0.028031942, 0.02200997, -0.046084616, 0.049896326, -0.03862002, -0.0667049, 0.01393656, -0.026589315, 0.015564477, -0.0452111, 0.0026288216, 0.043093484, 0.017946795, 0.07358716, -0.000014734388, 0.029964266, -0.058552083, 0.014413023, -0.055163894, -0.0045661093, 0.00664402, 0.025265805, -0.04031411, 0.028931929, -0.026430493, 0.006174174, -0.0042286143, 0.059187368, -0.057440333, -0.047461066, -0.3004897, -0.09010456, 0.032690696, -0.029964266, 0.07099307, -0.02236732, 0.061410863, 0.002865399, -0.004658755, -0.07051661, 0.06268143, -0.0002663564, 0.0029977502, -0.08359289, 0.07639299, -0.060616758, -0.006203953, 0.059981473, -0.020090882, 0.04891693, -0.023042308, -0.03480831, 0.054105088, 0.033458333, 0.00856311, -0.012705696, 0.114880666, -0.026126087, -0.004787797, 0.012090264, 0.034993604, 0.00071262737, 0.023889355, -0.030758372, -0.028402524, -0.0043179514, 0.068399, -0.020236468, -0.05564036, 0.0073322454, -0.038143557, 0.04489346, 0.014426258, -0.059240308, -0.03221423, -0.010952045, -0.014743901, 0.030070147, -0.0099925, 0.020858517, 0.0901575, 0.010250585, 0.006677108, -0.025583448, 0.07120483, 0.0029547361, 0.022512905, 0.03954648, -0.08332819, -0.012553492, 0.027317246, -0.014082146, 0.0474346, 0.026827548, 0.007305775, 0.019455597, 0.0037422245, -0.00078624766, -0.0054727136, 0.02779371, 0.04510522, 0.1273746, -0.04515816, 0.0035172277, 0.012017471, -0.04529051, 0.025504038, -0.014479199, -0.03991706, -0.017629152, 0.05151101, -0.104186706, 0.06432258, 0.06321084, -0.007788856, 0.032717165, -0.02206291, -0.041955266, -0.009271188, -0.02244673, -0.04513169, 0.0334848, -0.06898134, -0.006571227, 0.020024706, 0.0001314204, -0.28291348, 0.013923325, 0.011229982, 0.031976, -0.008953545, 0.003748842, 0.08872811, 0.016874753, 0.008728548, 0.0829576, -0.0522257, 0.009595447, -0.012692461, 0.07432832, -0.014942427, 0.048466936, 0.04240526, -0.017999735, -0.03353774, -0.052622758, 0.033802446, 0.02255261, 0.16940928, -0.014068911, -0.0063991705, -0.0019521771, 0.03189659, 0.03843473, -0.0034444346, 0.045978736, -0.010243967, 0.035178896, 0.060722638, -0.007001368, -0.012037323, 0.040181763, -0.00000197751, -0.006395862, 0.03343186, -0.024418758, 0.02377024, -0.020289408, 0.01301672, -0.054740373, 0.024352584, -0.056116823, -0.028720167, -0.047461066, 0.0051352186, 0.03827591, -0.056063883, 0.018701196, 0.09354568, 0.018542375, 0.021083513, -0.004384127, -0.05074337, -0.02776724, 0.045952268, 0.028217232, 0.01458508, -0.05585212, -0.025570212, 0.04775224, 0.028137822 ]	[ -0.03819507, 0.023081152, 0.013247839, -0.025939826, 0.020725392, 0.000066845096, -0.042694837, -0.018713731, 0.00078001455, -0.020368056, -0.030836629, -0.032292437, -0.035045233, 0.03991557, 0.02494723, 0.034727603, -0.0023756116, 0.021823864, -0.070461035, -0.00762975, -0.028719092, -0.02261794, 0.020884207, -0.04658581, -0.012791245, 0.03451585, -0.06839644, -0.013777223, -0.039571468, -0.20455405, 0.06633184, 0.025053106, 0.07347853, -0.060032167, 0.04491825, -0.005369941, -0.0078944415, 0.010905314, -0.09502447, 0.008794395, 0.018343162, -0.0067761177, -0.0392009, -0.0004694149, -0.0029033415, -0.045077063, -0.01339342, 0.003328503, -0.013082407, -0.040127322, 0.05087382, -0.08814247, -0.0475387, -0.007351823, 0.0133206295, -0.0038181834, 0.049788583, 0.024960466, 0.06728473, -0.009118643, 0.04489178, 0.024986934, -0.13816927, 0.0043508764, 0.107412055, -0.011613366, 0.02781914, -0.014730115, 0.014121324, 0.020196008, -0.010634005, 0.042138983, 0.044388864, 0.08898948, -0.032583598, -0.00087017525, -0.029327884, -0.033033572, -0.02546338, 0.047459293, 0.0024599822, -0.0019223264, 0.019957785, -0.053414866, -0.09423038, 0.018118175, -0.0037222325, -0.071308054, 0.002062944, 0.009039235, 0.02376935, -0.021334182, -0.04454768, 0.035071705, -0.047750454, 0.0034112195, 0.021678282, 0.013711051, 0.06633184, 0.36421633, -0.033880588, 0.002001734, 0.044150643, 0.00153935, -0.03554815, 0.03483348, -0.04142431, -0.038618576, 0.018025532, 0.0044534444, 0.06193795, -0.06474369, 0.046691686, 0.022260606, -0.060085107, -0.006600759, -0.03115426, 0.02276352, -0.0499474, -0.016834417, -0.02077833, 0.017575555, -0.010997957, -0.015021277, 0.031868927, 0.0056974976, -0.031048384, 0.08385446, 0.011964083, -0.030730752, -0.0097869905, 0.003169688, 0.012751542, -0.025542788, -0.019957785, -0.050662067, 0.0017618568, -0.016569726, -0.036209878, 0.03081016, -0.08242512, 0.0057471273, -0.009303927, -0.11074717, -0.040550828, 0.08136635, -0.009727434, -0.019878376, 0.009601706, -0.048756283, -0.026998594, 0.055691216, -0.037030425, 0.04179488, 0.016543256, 0.024417846, -0.030254306, 0.07194331, -0.018991658, 0.030254306, -0.033139452, -0.013975743, -0.031577766, 0.105347455, 0.04248308, -0.0038909737, 0.0074510826, -0.017496148, 0.057597, -0.019812204, 0.016860887, 0.020685688, 0.0051648044, -0.093330435, 0.0690317, 0.02190327, 0.010514894, 0.016688837, 0.033324733, 0.029274946, 0.04359479, 0.04692991, 0.00086024933, 0.042377204, 0.06754942, -0.05955572, -0.062149704, -0.01719175, -0.014690411, 0.034357034, -0.04859747, -0.03951853, -0.022869397, 0.027977955, 0.021969445, -0.046082895, 0.04989446, -0.038618576, -0.06675535, 0.013936039, -0.02661479, 0.01557713, -0.04523588, 0.0026303777, 0.043118343, 0.017999062, 0.073637344, -0.000024272058, 0.029963145, -0.058549892, 0.014452188, -0.05521477, -0.0045196177, 0.00669671, 0.025304565, -0.040312607, 0.028930847, -0.026482444, 0.0061441655, -0.004251617, 0.059185155, -0.057385247, -0.047432825, -0.30047846, -0.09015413, 0.032636534, -0.029963145, 0.070937485, -0.022392951, 0.061461505, 0.0029083043, -0.0046552722, -0.07051398, 0.06262615, -0.00020751447, 0.0030571937, -0.08348389, 0.07623132, -0.060561553, -0.0062037213, 0.05997923, -0.020103365, 0.048941568, -0.023067916, -0.034780543, 0.05420894, 0.033430614, 0.008529703, -0.012711838, 0.11498225, -0.026151579, -0.0048041614, 0.01214275, 0.034992296, 0.0007361749, 0.02396787, -0.030730752, -0.028348524, -0.004231765, 0.06839644, -0.02028865, -0.05558534, 0.007325354, -0.03819507, 0.04494472, 0.014412485, -0.05923809, -0.032292437, -0.010951635, -0.0147433495, 0.030095492, -0.0100252135, 0.020857736, 0.09015413, 0.010223732, 0.006700019, -0.025622195, 0.0710963, 0.002946354, 0.022525297, 0.039545, -0.08332507, -0.012579492, 0.027289756, -0.014068385, 0.047432825, 0.026773605, 0.0072657983, 0.019454869, 0.0036825289, -0.00082592206, -0.0054989783, 0.02779267, 0.045130003, 0.12736984, -0.04520941, 0.0035237137, 0.012010404, -0.045341756, 0.02548985, -0.014505127, -0.039968506, -0.017628495, 0.051482614, -0.10418281, 0.06426724, 0.06326141, -0.007768713, 0.032689475, -0.022088556, -0.041953698, -0.009284075, -0.022485593, -0.045103535, 0.03351002, -0.068978764, -0.006584216, 0.019984253, 0.00015230135, -0.28311467, 0.013962508, 0.0112097105, 0.031948335, -0.00895321, 0.0037255413, 0.08877773, 0.016860887, 0.00878116, 0.08300744, -0.05222375, 0.00956862, -0.012672135, 0.07432554, -0.01488893, 0.048438653, 0.042456612, -0.017946124, -0.03353649, -0.05256785, 0.03377471, 0.022578236, 0.16940294, -0.014055151, -0.0063724625, -0.0019322523, 0.0318954, 0.038406823, -0.0034376886, 0.04597702, -0.010236967, 0.03517758, 0.06072037, -0.006954785, -0.012056725, 0.04020673, -0.000010753117, -0.0064055487, 0.03340414, -0.024391377, 0.023795819, -0.020301884, 0.013016234, -0.054791264, 0.024391377, -0.056061786, -0.028692624, -0.04748576, 0.005121792, 0.03827448, -0.05600885, 0.018700497, 0.09354219, 0.018488742, 0.021056257, -0.0044236667, -0.050794415, -0.027713263, 0.045950547, 0.02813677, 0.014624238, -0.055902973, -0.025595726, 0.047750454, 0.02818971 ]
The Conductivity Confined Temperature Dependence of Water-Free Electrorheological Fluids	the conductivity of the dispersed particles determines the temperature dependence of the shear stress and the current density of an ER fluid. Our findings have direct implication for the design of industrially required ER fluids and would be significant for ER applications.	8978558	[ -0.015753368, 0.05985745, -0.0068603377, -0.040707346, 0.027494844, -0.04656471, 0.026906433, -0.013948016, -0.015352179, -0.02685294, -0.0542408, -0.03196142, 0.037524577, 0.027628573, 0.018120386, -0.013105518, -0.017077293, -0.08676388, -0.10559303, -0.010203582, 0.001323089, -0.019150104, 0.0377118, -0.05504318, 0.028270476, 0.0020694684, -0.01889602, 0.013553513, -0.04602979, -0.085426584, 0.043274958, -0.06600902, -0.019270461, -0.004316129, -0.05474897, 0.0032646784, -0.035010457, 0.011621118, -0.0774028, 0.0007881699, 0.010384117, -0.037310608, -0.011226615, -0.017759316, 0.017130785, -0.014055, -0.02137002, 0.0456286, -0.002367017, -0.012884865, -0.0043963664, 0.051994137, 0.005362564, 0.046912406, 0.014509682, -0.011968816, 0.030196184, -0.004881137, -0.013573573, -0.006044586, 0.0020477374, 0.0046872287, -0.12987836, -0.018000029, 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Surface Tension of Aqueous Solutions of Electrolytes: Relationship with Ion Hydration, Oxygen Solubility, and Bubble Coalescence	The surface tension of aqueous solutions of simple inorganic electrolytes (36 in total) have been measured by the maximum bubble pressure method as a function of electrolyte concentration up to 1 M. In most cases the surface tension increased; however in a minority of cases; certain combinations of cations and anions had a negligible effect or decreased surface tension. Results were analysed in terms of surface tension/electrolyte concentration gradients (d(Deltagamma)/dc) and this parameter was found to co	8978559	[ -0.094526604, 0.06511359, -0.041801646, -0.03828487, 0.0139605235, 0.03372905, 0.054030426, 0.006300885, -0.06010485, -0.06340849, -0.053550866, -0.08680036, 0.009564557, 0.005225206, 0.034022115, -0.015958691, -0.01992838, -0.022272896, -0.02866703, 0.01775704, 0.014453405, -0.071667574, -0.03932392, 0.0179835, 0.024137853, 0.026002808, 0.027627984, -0.0024161164, -0.051792476, -0.2147363, 0.02483055, 0.022845704, -0.054163635, 0.007839474, 0.054376774, -0.001763382, -0.005791353, -0.041082304, -0.053550866, -0.0035400852, 0.03732575, -0.012455238, 0.03468817, -0.01571891, 0.052431893, 0.0023728227, 0.019368894, 0.012488541, 0.04976767, -0.057440627, 0.06788438, 0.010450412, 0.03721918, -0.05046037, -0.006067766, 0.06660555, -0.029253159, 0.026415762, -0.010790099, 0.033915546, 0.01368078, 0.042627554, -0.13438337, 0.086906925, 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Surface Tension of Aqueous Solutions of Electrolytes: Relationship with Ion Hydration, Oxygen Solubility, and Bubble Coalescence	rrelate with the entropies of ion hydration; Jones-Dole viscosity coefficients and dissolved oxygen gradients. Calculation of Gibbs surface deficiencies for selected electrolytes were carried out using the raw surface tension data. Discussion of the surface tension/electrolyte concentration gradients was extended to the mechanism of inhibition of bubble coalescence by electrolytes. The Gibbs-Marangoni effect did not provide a satisfactory explanation for the inhibition of coalescence for all electrolytes an	8978559	[ -0.0040352447, 0.019604592, -0.0248406, -0.06754045, 0.0048842356, 0.011601751, 0.005814405, -0.014963891, -0.019753419, -0.006419861, 0.011398804, -0.13908571, 0.1127839, -0.00025685364, 0.04556816, 0.04034568, -0.014625647, -0.02795244, -0.0017707045, 0.012880311, 0.0435387, -0.09357167, 0.02592298, -0.015653908, 0.01064114, 0.014815064, 0.005019533, 0.03255255, -0.006683691, -0.1361633, -0.022053475, -0.030577209, -0.035447914, -0.02180994, 0.04924825, 0.008949922, 0.019306937, -0.059097897, 0.014815064, -0.045270506, -0.051142413, 0.071707614, -0.032741968, 0.018305736, 0.010187893, -0.048030574, 0.03406788, 0.0138138635, 0.07544182, -0.08913392, -0.04648818, 0.020957565, 0.03003602, -0.009565526, -0.0040183323, 0.11159328, -0.047651738, 0.05736609, 0.012880311, -0.036800887, -0.027735963, -0.008341084, -0.10748024, 0.07186997, 0.13897748, 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Surface Tension of Aqueous Solutions of Electrolytes: Relationship with Ion Hydration, Oxygen Solubility, and Bubble Coalescence	d from the present study we suggest that dissolved gas (microbubble) gradients between macroscopic bubbles plays an important role in the coalescence process.	8978559	[ -0.03285606, -0.08404792, 0.04819772, -0.006736817, -0.03142523, -0.0024592362, 0.011373761, 0.02951746, -0.006809683, -0.06650703, 0.008565098, -0.045601033, 0.05161581, 0.060677722, 0.014321532, 0.0025436948, 0.024297586, 0.041255552, -0.06666601, 0.034419373, 0.041467525, -0.017726375, -0.021462426, 0.008055034, -0.025529688, 0.060253773, 0.026152363, -0.0067765624, -0.058451988, -0.22617687, 0.06926269, 0.028404593, 0.03826141, 0.004908536, 0.0066175815, 0.026245102, -0.035134785, 0.06163161, -0.06396333, 0.01793835, 0.034286886, 0.034657843, -0.034869816, -0.028139625, -0.0025354146, -0.021064974, 0.020349558, -0.005537836, 0.051642306, 0.0062698107, -0.01726268, -0.06597709, 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Anomalous Adsorption of Copper(II) on Goethite	The adsorption of copper(II) onto goethite is qualitatively different from that of other metal-mineral systems. At pH 5.0 the adsorption isotherms are sigmoid rather than hyperbolic; and the corresponding graphs of C/N versus C (where C is concentration and N adsorption density) have distinct minima. At pH 5.5 the isotherms have the more usual shape. The experimental data can be fitted by a model in which monomeric CuOH+ and dimeric Cu2(OH)2+2 compete for surface sites; the dimer adsorbing more strongly to	8978560	[ -0.07828883, 0.0012215975, 0.02789939, -0.02454187, 0.0037205848, 0.0066517526, -0.027126627, 0.05606525, -0.08718892, 0.007267964, -0.016267981, -0.06869592, -0.039410885, -0.014549252, 0.011091806, -0.029364973, 0.06645757, 0.033921607, -0.06022218, -0.014855692, 0.04705857, -0.091772206, -0.04306152, 0.0072613023, 0.030217677, 0.09496984, 0.04378099, -0.035014134, -0.001980204, -0.22980356, 0.023169551, 0.036239896, 0.032189555, -0.024595164, 0.0379453, -0.034561135, 0.0038271728, 0.00047798024, -0.07871518, 0.0116114225, 0.039837237, -0.042768404, 0.008840136, 0.010485588, 0.04873733, -0.038691416, -0.03829171, -0.0067616715, 0.029231738, -0.06048865, 0.071733676, 0.04644569, 0.022476729, -0.013856431, -0.03461443, 0.021424172, 0.04599269, -0.016547775, 0.037305772, -0.0029211754, -0.015415279, 0.05617184, 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-0.063366525, -0.121616825, 0.06752345, -0.035893485, 0.00999928, -0.007434508, 0.0009517969, -0.041436058, 0.012723934, 0.03938424, -0.013656578, 0.015028898, 0.030217677, -0.036080014, -0.0423687, -0.014442664, -0.0014472642, 0.038504887, 0.019825354, 0.030857205, -0.038078535, -0.0069482005, 0.030537441 ]	[ -0.07828427, 0.001207371, 0.027924411, -0.024567086, 0.0037703284, 0.0065980745, -0.027151693, 0.056061983, -0.087130554, 0.007307509, -0.016213745, -0.06863863, -0.039435238, -0.014521759, 0.011084499, -0.029389909, 0.06640041, 0.033919632, -0.060218673, -0.014814859, 0.047082476, -0.09171357, -0.04308566, 0.007280864, 0.030215917, 0.09485773, 0.04377844, -0.03498545, -0.0019301283, -0.22979018, 0.023101587, 0.036237784, 0.032187678, -0.02458041, 0.037916448, -0.034505833, 0.003836942, 0.00049044244, -0.07881718, 0.0115841, 0.039834917, -0.04279256, 0.008839621, 0.010484977, 0.04873449, -0.038689163, -0.038289484, -0.0067346324, 0.02920339, -0.060485125, 0.071729496, 0.04641634, 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Anomalous Adsorption of Copper(II) on Goethite	the surface. As the concentration increases the proportion of the dimeric species increases; which leads to enhanced adsorption. At pH 5.5 adsorption of the monomer is sufficiently strong that normal behavior is observed at low concentrations; before there is sufficient dimer to compete effectively for sites. Data are presented for adsorption of Cu(II) to goethite at pH 5.0 and pH 5.5; at temperatures between 25 and 70°C. Adsorption is endothermic for both monomer and dimer. Enthalpies of adsorption ran	8978560	[ -0.0037879834, 0.022077775, 0.0580603, -0.032957446, 0.039034143, -0.051930536, 0.04736638, 0.03279823, -0.07031983, -0.0062657627, -0.01738094, -0.038954534, -0.019251714, 0.021746077, -0.040652826, 0.0035690633, 0.05219589, 0.085869804, -0.05699887, -0.017540155, 0.08480837, 0.01769937, -0.017526887, -0.011815059, 0.011489996, 0.019517072, 0.028313685, -0.031657193, -0.04603959, -0.124187484, 0.00919465, -0.010494904, 0.039591394, -0.038874928, -0.0038841758, 0.0009992382, 0.015855132, -0.009559517, -0.07966043, 0.025182461, 0.06533111, -0.042669546, -0.027729897, 0.036831673, -0.01914557, 0.0048062946, -0.030595763, 0.006743407, 0.006070061, 0.00699218, 0.0077948873, -0.050975244, -0.035053775, 0.00019798185, -0.01287649, 0.029799689, 0.081411794, 0.031577587, 0.036380563, 0.004378405, 0.0010050429, 0.05668044, -0.11251174, 0.009712098, 0.02778297, 0.0037150101, 0.022873849, -0.09324676, 0.019464, -0.002784599, -0.000304125, 0.010315787, 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-0.062942885, 0.03324934, 0.047897097, -0.012531525, 0.0072111, -0.034125023, -0.00018803093, 0.06602104, 0.05630894, 0.0069258404, 0.019211909, 0.016850224, 0.04919735, 0.0073106093, 0.03338202, 0.0046537137, 0.020485627, -0.0018110675, 0.03439038, -0.023338225, 0.032532874, 0.043598298, -0.03563756, -0.28849706, 0.041528504, 0.0371501, 0.05466372, 0.0011841594, -0.048029773, 0.034178093, 0.01064085, 0.011324147, 0.015377488, -0.023470903, 0.03213484, -0.001195769, -0.01174872, -0.0014909796, 0.012418748, 0.07090362, 0.0018525296, 0.0011368926, -0.052302036, -0.0018856993, -0.07488399, 0.21048187, -0.007801521, -0.10237507, 0.01272391, 0.032108303, -0.006687018, -0.043545227, -0.020883664, 0.10179128, 0.014899844, 0.053257324, -0.017248262, -0.035557956, 0.07615771, -0.0085047195, -0.06931148, -0.014873308, 0.036354028, -0.019623214, -0.06002395, -0.09462661, -0.057794943, 0.100570634, -0.03513338, -0.018349497, -0.0090354355, -0.021122485, -0.007350413, -0.0048328303, 0.040865112, -0.02719918, -0.025235534, 0.016160294, -0.01319492, -0.07000141, 0.03704396, 0.003363411, 0.030489618, -0.020551967, -0.040838577, -0.020671377, 0.019636482, -0.008590961 ]	[ -0.0037748339, 0.022091735, 0.05806212, -0.032958478, 0.03908844, -0.05193216, 0.047367863, 0.032825798, -0.07032204, -0.006319032, -0.017394753, -0.03892922, -0.019278852, 0.021746758, -0.04070717, 0.0035426384, 0.052197527, 0.08587249, -0.057000656, -0.017553972, 0.08481103, 0.017660119, -0.017553972, -0.011795526, 0.011463819, 0.01953095, 0.028341107, -0.031578574, -0.04604103, -0.12419137, 0.009115328, -0.010495232, 0.039566096, -0.03890268, -0.003857761, 0.0009868304, 0.015908703, -0.009520012, -0.07966293, 0.025143446, 0.06533315, -0.042723954, -0.02770423, 0.036832824, -0.019172706, 0.0047566886, -0.03059672, 0.0067900573, 0.0060403976, 0.0070255697, 0.0078017656, -0.050976843, -0.035054874, 0.00014450018, -0.012784015, 0.029800622, 0.08141434, 0.031578574, 0.03632863, 0.0043586395, 0.0009785378, 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-0.0011535136, -0.0484824, -0.04142366, 0.036381703, 0.031260137, -0.09924695, -0.025833398, -0.025223056, -0.013613285, 0.018522559, 0.10582803, -0.04975616, 0.03059672, -0.008040595, -0.06671306, 0.004614054, 0.043493517, -0.058486708, -0.058592852, 0.008717279, -0.019199243, 0.036116336, 0.01271104, 0.0019902464, -0.006780106, 0.051587187, -0.0519587, -0.013613285, 0.11559351, -0.04487342, -0.0011336112, -0.0088234255, 0.0002454637, 0.052356746, 0.016691532, 0.023962567, 0.0058181533, 0.0127176745, 0.034630287, -0.0017381485, 0.012823821, -0.03792083, 0.07929141, -0.06135266, 0.029588329, 0.097230166, 0.03128667, -0.05251597, 0.0034862482, 0.01015689, -0.032295063, -0.06512086, 0.025010763, -0.012910064, 0.041025613, 0.00027987838, 0.052914016, -0.06597003, 0.042193223, 0.04487342, 0.024732128, -0.02762462, 0.026112031, -0.07791151, 0.02244998, 0.013016211, 0.0013483919, 0.0051282016, 0.041052148, 0.087783135, -0.011344404, 0.008213083, -0.018164314, 0.03627556, 0.0089163035, -0.0048661525, -0.042087074, 0.0043586395, 0.0058546416, -0.03555907, -0.045642983, 0.046545226, 0.007815034, -0.0019239048, -0.04434269, 0.041556343, 0.037018582, -0.051348355, -0.32671884, -0.017925486, 0.027200034, 0.03131321, 0.096115634, -0.060715783, 0.081095904, 0.017235534, -0.02016783, -0.03744317, 0.043413907, 0.014130749, -0.010057379, 0.029322963, 0.0069724964, 0.05986661, 0.033489212, 0.02087105, -0.0067137643, 0.0218131, 0.009672597, 0.043573126, 0.011457185, 0.0016344899, 0.0039373706, 0.02189271, 0.15699063, -0.013367821, -0.0414502, -0.0096593285, -0.0016759533, -0.031578574, -0.015178946, -0.121962294, -0.0058148364, 0.004614054, -0.09218821, 0.021547733, -0.01984939, -0.017898949, 0.078442246, 0.005954154, -0.044820346, -0.077433854, -0.033489212, -0.04906621, -0.042405516, 0.07095892, -0.019398268, 0.007397082, 0.025236323, 0.020141292, 0.0059972755, 0.051826015, -0.026496813, -0.02660296, -0.00024359785, -0.055726897, -0.06283871, 0.004680396, 0.027438862, 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Anomalous Adsorption of Copper(II) on Goethite	ge from 50 to 91 kJ mol-1; and entropies from 240 to 470 J K-1 mol-1.	8978560	[ -0.07053859, 0.040455952, 0.020733343, 0.018366098, -0.03165193, -0.051600624, 0.02661156, 0.022528727, -0.00018816191, 0.01606535, -0.016291434, -0.03864727, -0.02706373, 0.036599204, 0.015400392, 0.0010464753, 0.0071748807, 0.024470398, -0.08075232, -0.0039199186, 0.052983735, -0.02538804, 0.012447986, -0.005672079, 0.03455114, 0.09990306, -0.013518565, 0.011736482, -0.05644151, -0.21278608, -0.046786338, -0.008072572, 0.03899305, -0.03593425, -0.010386621, 0.045589417, -0.049898334, -0.015267401, -0.07676258, -0.006207369, 0.03425856, 0.009116554, -0.0031851416, 0.029683659, 0.009103254, -0.016078647, -0.0048541822, -0.001440462, 0.01115132, 0.02766219, 0.065591305, -0.0427966, -0.02936448, -0.026199287, -0.011237765, 0.04553622, 0.04311578, 0.011124722, 0.014775333, 0.041493285, 0.034098968, -0.02384534, -0.100222245, 0.101445764, 0.091604404, -0.002914172, 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Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles	The interface polarity of benzyl-n-hexadecyldimethylammonium chloride (BHDC) cationic reversed micelles in benzene was studied and compared with those of the anionic systems of sodium 1;4-bis-2-ethylhexylsulfosuccinate (AOT) in benzene and hexane. The nonionic reversed micelles of the poly(oxyethylene)n dodecyl ethers type surfactants Brij 30 in benzene; cyclohexane; and decane and C12E5 in hexane; heptane; and decane were also investigated. 1-Methyl-8-oxyquinolinium betaine (QB) was used as optical probe.	8978561	[ -0.062182434, 0.031887747, 0.04641114, -0.017244872, 0.008416666, -0.0719001, 0.051641688, 0.0036175733, -0.028621975, 0.032817032, -0.0012744479, -0.058996316, -0.011217796, 0.023404704, -0.019209646, -0.018771555, 0.027095292, 0.0018336782, -0.087193474, 0.03138328, 0.054748155, -0.0010545724, 0.021546135, 0.004105448, 0.03348081, 0.0932471, -0.03937513, -0.011921397, -0.06951051, -0.20571713, -0.05623501, -0.03390562, 0.020377891, 0.009073803, -0.025608437, 0.023909172, -0.04205678, -0.04203023, -0.03754311, -0.035790745, 0.038525496, 0.02023186, -0.039746843, 0.006385515, -0.001984687, -0.0001922873, -0.02583412, 0.024679152, 0.009093717, 0.048535224, 0.087246574, 0.01984687, 0.036109354, -0.014749079, 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Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles	The influence of surfactant concentration and W = [H2O]/[surfactant] were analyzed as a function of the absorption bands shifts in the visible; B1; and in the UV; B2; and the absorbances ratio of these bands. At W = 0 the polarity sensed in the micelle interfaces of AOT-hexane and AOT-benzene is entirely similar while for BHDC-benzene is quite smaller. 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-0.00042032677, -0.046184342, -0.02868543, 0.03795426, 0.0065354574, -0.022732604, -0.04075089, -0.0036289599, -0.031934846, 0.008543038, 0.049460392, 0.0010770353, -0.05089866, 0.01897713, -0.013303967, -0.08512408, 0.03691551, 0.011359643, -0.023904525, 0.07590852, -0.027220529, 0.007997029, 0.057264324, -0.014249494, 0.0075708763, -0.02098804, 0.026847646, 0.028019566, 0.021187799, 0.035423975, 0.036169745, 0.0016696545, -0.021294337, 0.048874434, 0.031615235, -0.06813122, 0.012777935, 0.023624862, 0.011645965, 0.0330535, 0.002270597, -0.02025559, 0.0048108688, 0.04128358, -0.297881, -0.006159244, 0.056518555, 0.048821166, -0.051804237, -0.017778575, 0.124010555, -0.0063590035, -0.008922581, -0.010800318, -0.070102185, 0.07526929, -0.027380336, 0.033666097, 0.0033676082, -0.013703486, -0.013889927, -0.047063284, 0.01171921, 0.03188158, 0.033985708, -0.019336697, 0.17078085, -0.0039752093, -0.022186596, 0.0338259, -0.01265142, 0.050445873, 0.016646605, 0.03731503, 0.014103004, 0.0061359387, 0.045518477, -0.049273953, 0.047675878, -0.01917689, 0.00848311, 0.010793659, 0.04519886, 0.0017861808, 0.04693011, -0.027992932, -0.02137424, -0.048102032, 0.026661204, -0.048288472, -0.019003766, -0.0438405, 0.049060877, -0.0109268315, -0.015967423, 0.0089625325, 0.035530515, -0.022919046, 0.07058161, 0.012491613, 0.0118856765, -0.010627193, 0.027620047, 0.033959076, -0.013130843, 0.004384716, -0.04908751, -0.0043913745, 0.10387482 ]
Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles	t. At W >/= 10 once the polar heads of the surfactants are completed hydrated; the anionic as well as the cationic surfactants show the same behavior. The polarity of Brij 30 and C12E5 in the aliphatic hydrocarbons is comparable. However at W = 0 their micropolarity is higher than that of AOT-hexane; showing that the formation of hydrogen bond between QB and the free OH groups of these surfactants is the major factor affecting the microenvironment. In all the studied systems even at the maximum possible W;	8978561	[ -0.040414706, 0.0124685075, -0.016128682, -0.00057418575, -0.029998818, -0.018360658, 0.042221542, -0.056543387, -0.043071818, -0.032469932, 0.028298264, -0.088481896, 0.010681598, -0.006842069, 0.008907975, 0.03998957, 0.0013783779, 0.031779084, -0.09549668, 0.009499183, 0.015424547, -0.074930616, -0.03260279, -0.05473655, 0.009339756, 0.058190797, -0.01252165, -0.02084506, 0.011930442, -0.20959316, 0.022957465, 0.06563072, 0.010814454, -0.015079122, 0.035445902, 0.02585372, 0.05083059, -0.025003443, -0.071688935, -0.024910444, 0.026265573, 0.030105103, 0.011990227, 0.031061664, 0.045808647, -0.019064793, 0.025123013, 0.03781073, 0.039298717, -0.025813863, 0.050936878, -0.0018616405, -0.04259354, 0.0067125345, -0.01709853, 0.024990158, 0.008250339, -0.050006885, 0.002373135, -0.005516833, 0.008004556, 0.06653414, -0.14369673, 0.07896943, 0.0871002, 0.024538448, 0.0022502434, -0.034064204, 0.043071818, 0.050033458, -0.025441866, 0.037146453, 0.008403123, -0.05154801, 0.036907315, 0.011837443, -0.04820005, 0.03496762, -0.015544117, -0.041955832, -0.0052245506, -0.022080617, -0.010183389, -0.039219003, -0.051521443, -0.007419991, 0.040122423, -0.029865962, 0.019968212, 0.005480298, 0.0026953102, -0.038501583, -0.028935973, 0.025906863, -0.017085243, -0.008755191, 0.05173401, 0.001566867, 0.03565847, 0.39282775, -0.059306785, -0.023940597, -0.025415296, -0.05850965, -0.054683406, 0.00066843024, -0.04192926, -0.023940597, 0.00021651328, 0.020287067, 0.07083866, -0.0025906863, 0.00022523194, -0.055321116, -0.05941307, -0.028803116, 0.055586826, 0.02051292, 0.008303481, -0.06839412, -0.015769972, -0.017032102, 0.031858798, 0.0237546, 0.03074281, 0.013591139, -0.011286092, 0.05383313, 0.047828052, -0.042115256, 0.015065837, -0.0097914655, 0.028723404, -0.0461275, -0.00065348396, -0.045782074, 0.06679985, -0.02129677, 0.0026039719, 0.048545472, -0.002864701, -0.06499301, -0.002268511, -0.08539964, -0.022798039, 0.06685299, 0.0026687388, 0.017629951, -0.02816541, 0.04543665, 0.050299168, 0.10936681, -0.015557403, 0.01502598, 0.032948215, 0.00839648, 0.057393663, -0.016022397, 0.026544569, -0.019476647, 0.0010686581, 0.063770734, 0.011810872, 0.11213021, 0.0012430311, -0.01559726, 0.04405495, -0.021177199, -0.006377074, 0.010336174, 0.051308874, 0.016660105, -0.028989114, -0.033957917, 0.005516833, 0.016274823, -0.01523855, 0.03937843, 0.04081327, 0.019383647, 0.018546656, 0.029573679, -0.027315132, 0.026026431, 0.034329914, -0.022625327, -0.094486974, -0.017191527, -0.01838723, 0.057393663, -0.045596078, -0.035844468, 0.0004998696, 0.096825235, -0.01643425, 0.016168538, 0.0049854103, -0.014986123, -0.06520558, -0.026172573, 0.0781723, 0.006861997, -0.051601157, 0.0104956, 0.020552777, 0.044798944, 0.04804062, 0.042008974, 0.027288562, -0.0008826601, -0.062814176, -0.0540457, -0.04758891, -0.041078985, -0.019742357, 0.013803707, 0.10878225, 0.028032552, 0.0019861928, -0.02141634, 0.036402464, -0.044905227, -0.0881099, -0.29036942, -0.041397836, 0.006363788, -0.0072605642, 0.12212096, -0.020911487, 0.05548054, -0.01070817, -0.043284386, -0.068447255, 0.07083866, 0.0057991515, -0.10171433, -0.036163323, -0.020419922, 0.007207422, 0.07689688, -0.0093928985, -0.0029560393, 0.06600271, 0.010176747, 0.028298264, -0.025348868, 0.055693112, 0.035738185, 0.0010968898, 0.14380302, -0.019184364, -0.053965986, 0.027208848, -0.01264122, 0.028829688, -0.014056133, -0.02447202, -0.011139951, 0.01082774, -0.013112858, -0.05749995, 0.10288346, -0.054417696, -0.02774027, 0.016580392, 0.011545161, 0.007944771, -0.041610405, -0.024631448, -0.038289014, -0.04703092, -0.047615483, -0.04466609, 0.017018816, 0.023688171, 0.00066884543, -0.010190032, -0.007997913, 0.028431121, -0.014494557, -0.05824394, -0.067118704, 0.00674907, -0.020194067, 0.013923278, 0.04729663, 0.017497096, 0.013777137, -0.039776996, -0.018945223, -0.012588078, -0.011412305, -0.0031503409, -0.014653984, 0.045516364, -0.029520538, -0.019875214, 0.03608361, -0.00060989073, 0.013750565, -0.05659653, -0.035445902, 0.044400375, 0.00058373477, -0.030609954, 0.03308107, -0.0049455534, -0.0025275797, 0.00698821, 0.012315724, -0.05749995, -0.011046952, -0.026318714, 0.0047163772, 0.0057327235, 0.016062254, -0.045994643, 0.01409599, 0.050458595, -0.29547107, 0.023329461, 0.026159288, 0.070254095, 0.0048625185, 0.0063737524, 0.1080914, 0.029679963, -0.041769832, -0.004128491, -0.018533371, 0.020021355, -0.04942232, 0.04049442, 0.022306472, 0.0051215873, 0.048837755, -0.079128854, -0.032921642, 0.011870657, 0.03419706, -0.0038029945, 0.171437, 0.034808192, -0.0366416, 0.028776545, -0.012342295, 0.010508887, 0.045728933, 0.024817444, -0.023568602, 0.046712063, 0.035499044, -0.024565019, 0.046021216, 0.0040819915, 0.001643259, 0.001629143, 0.038607866, -0.010203318, 0.009811394, 0.004799412, -0.0540457, -0.05893479, 0.056809098, -0.033878203, -0.007592703, -0.08077627, 0.034542482, 0.028298264, -0.014733697, -0.021004487, 0.059359927, -0.0033928026, 0.03281536, -0.0013053073, -0.030902237, -0.042035546, 0.016925817, -0.018360658, -0.014122562, 0.008031127, -0.009665253, -0.005380656, 0.029865962 ]	[ -0.040413927, 0.012428412, -0.016128372, -0.00054054626, -0.030024812, -0.01837359, 0.04222073, -0.0565423, -0.04309756, -0.03249588, 0.028324291, -0.0884802, 0.010654822, -0.0068485797, 0.008934374, 0.04001537, 0.0013891457, 0.0317519, -0.095494844, 0.009538856, 0.01539768, -0.07492918, -0.03254902, -0.054735497, 0.009352862, 0.05818968, -0.012521409, -0.020844659, 0.011943498, -0.20958912, 0.022943739, 0.06562945, 0.0108009605, -0.015078832, 0.03544522, 0.025879793, 0.050829615, -0.025002962, -0.07163442, -0.024883395, 0.026251782, 0.030051382, 0.012036495, 0.031034496, 0.045834336, -0.019011285, 0.02512253, 0.037783436, 0.039324533, -0.025826652, 0.050962467, -0.0018682474, -0.04259272, 0.0067522614, -0.0170982, 0.024989678, 0.008270108, -0.050059065, 0.002339876, -0.0054901564, 0.0079911165, 0.06653286, -0.14380024, 0.078967914, 0.087098524, 0.024537977, 0.0022867348, -0.034010407, 0.04307099, 0.050032496, -0.025414808, 0.03714574, 0.008383034, -0.05154702, 0.036906604, 0.011804002, -0.048172552, 0.03496695, -0.015530533, -0.041981593, -0.0052576633, -0.022053622, -0.010163266, -0.03921825, -0.051520452, -0.007466347, 0.040121652, -0.029838817, 0.019981114, 0.0054735495, 0.0026969188, -0.038474273, -0.028961986, 0.025866508, -0.017071629, -0.00874838, 0.051679876, 0.0015435875, 0.035710927, 0.39282018, -0.059305646, -0.023966707, -0.025441378, -0.058508527, -0.054682355, 0.0006231643, -0.04192845, -0.023926852, 0.0001885892, 0.020286676, 0.0708373, -0.0026138856, 0.00020550721, -0.05532005, -0.059411928, -0.028829133, 0.055585757, 0.020512525, 0.008336535, -0.0683928, -0.015796239, -0.016965346, 0.031884756, 0.023727572, 0.030715648, 0.013590877, -0.011319088, 0.053832095, 0.047827132, -0.042141017, 0.015092118, -0.009791277, 0.02866971, -0.046179753, -0.0006543017, -0.045754623, 0.06679856, -0.02129636, 0.0026271709, 0.048650824, -0.0028613247, -0.0650449, -0.0022850742, -0.08534486, -0.022864027, 0.066851705, 0.0026869548, 0.017616328, -0.028164867, 0.045462348, 0.05027163, 0.10947099, -0.015570389, 0.015065547, 0.03294758, 0.008402961, 0.05739256, -0.016008804, 0.026544059, -0.019462986, 0.0010678072, 0.06371637, 0.011770789, 0.11212806, 0.0012156063, -0.015610245, 0.044027533, -0.021203361, -0.0063669872, 0.010369188, 0.051334456, 0.016659785, -0.028988557, -0.033957265, 0.0055266907, 0.016287796, -0.015224971, 0.039377674, 0.040812485, 0.01936999, 0.018559584, 0.02954654, -0.027288036, 0.026025932, 0.034355823, -0.022638176, -0.0945383, -0.017177911, -0.018413447, 0.05739256, -0.0455952, -0.03581721, 0.00052186375, 0.09682337, -0.016487075, 0.016168227, 0.004968708, -0.014932694, -0.06520432, -0.02617207, 0.07817079, 0.0068884357, -0.051573593, 0.010515327, 0.020512525, 0.04479808, 0.048039697, 0.042034734, 0.027288036, -0.00091502606, -0.06270669, -0.0540978, -0.047588, -0.04107819, -0.019715408, 0.013816727, 0.108727016, 0.028005444, 0.0020127252, -0.021442497, 0.036401764, -0.044957504, -0.088108204, -0.29015127, -0.041476753, 0.0063238097, -0.007313566, 0.122118615, -0.020937655, 0.055479474, -0.010721249, -0.043283556, -0.06844594, 0.07089044, 0.005792397, -0.10171237, -0.0361892, -0.020432813, 0.0072604246, 0.076948546, -0.009366147, -0.0029128052, 0.066001445, 0.0101765515, 0.02829772, -0.025361666, 0.05574518, 0.035737496, 0.0010993598, 0.14380024, -0.019157425, -0.05396495, 0.02716847, -0.012634334, 0.028829133, -0.014095719, -0.024484836, -0.011133093, 0.010860745, -0.013066107, -0.0574457, 0.10288148, -0.05439008, -0.027792878, 0.016580073, 0.0115582235, 0.007911405, -0.041609604, -0.02464426, -0.038261708, -0.047030013, -0.047588, -0.044691797, 0.016991917, 0.023727572, 0.0006692477, -0.010169908, -0.00802433, 0.028457144, -0.014507564, -0.05829596, -0.06711741, 0.006729012, -0.02019368, 0.013962866, 0.04729572, 0.01752333, 0.013763586, -0.039776232, -0.018958144, -0.012601121, -0.0114320135, -0.003186815, -0.014680273, 0.04551549, -0.02951997, -0.019901402, 0.036082916, -0.00064433774, 0.01372373, -0.05659544, -0.03547179, 0.04442609, 0.0005538316, -0.030556224, 0.033133574, -0.0049255304, -0.0025507803, 0.0070080035, 0.012315487, -0.057551984, -0.011040096, -0.026358064, 0.0047096442, 0.0056960788, 0.01602209, -0.04599376, 0.014135575, 0.050510768, -0.2954654, 0.023329012, 0.0261455, 0.07025275, 0.004869068, 0.006393558, 0.108142465, 0.029626252, -0.0417956, -0.0041416967, -0.0185463, 0.02004754, -0.04942137, 0.04049364, 0.022266187, 0.0050949184, 0.048836816, -0.079127334, -0.03297415, 0.011863786, 0.03416983, -0.0038128854, 0.17153998, 0.034860667, -0.03672061, 0.028775992, -0.012361986, 0.010581753, 0.045754623, 0.024816968, -0.023568148, 0.046684597, 0.03544522, -0.024564547, 0.0460469, 0.0040885555, 0.0016598341, 0.0016880654, 0.038607124, 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Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles	the polarity sensed by QB never reaches the value of pure water; that is; never reaches the bulk water phase prevailing in the micellar core.	8978561	[ -0.07480957, 0.015859524, -0.011608382, -0.022545531, 0.01158864, 0.015530488, 0.037457433, 0.032719318, -0.038405053, -0.025151493, -0.016859792, -0.071282305, -0.0013424659, 0.024296, 0.027349453, 0.007370401, -0.0039813328, -0.0072190445, -0.077441856, 0.008594414, 0.030350259, -0.0658598, 0.0112530235, -0.033272095, 0.016820308, -0.013648404, -0.012338841, -0.02328257, -0.057436485, -0.2179533, 0.011713673, -0.01260865, -0.008153507, -0.034904115, 0.011983482, -0.044827834, 0.034193397, -0.021742683, -0.032614026, 0.0045143706, 0.03974752, -0.0029284183, -0.037641693, 0.020637123, 0.029876448, -0.07180876, 0.011562317, 0.0052645723, 0.04230084, -0.024361808, 0.053567022, -0.0062154857, -0.019715823, 0.042722005, -0.037088912, 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Micromechanics: A New Approach to Studying the Strength and Breakup of Flocs	Micromechanical techniques were developed to pull apart single floc particles 6 to 40 μm in size in order to measure floc strengths and fractal dimensions. Flocs were formed by aggregating aqueous precipitated calcium carbonate sols with two water-soluble polymers. The tensile strengths ranged from 20 to 200 nN and showed no correlation with floc sizes when plotted on logarithmic scales. Flocs created by the two flocculant systems were found to have fractal dimensions of 1.8 and 2.4 based on analysis of	8978562	[ -0.07744106, -0.021720625, 0.006975, 0.01397652, 0.01775575, 0.00873864, 0.021455416, 0.002083549, 0.03519325, -0.0020189043, -0.05532262, -0.06980304, 0.008705489, -0.027210455, -0.043255605, 0.02678612, -0.0010467472, -0.013048288, -0.009839258, 0.039675284, 0.054261785, -0.029809505, -0.009288949, -0.003981452, -0.030021671, 0.022516254, 0.018697241, -0.002413403, -0.0011064193, -0.1893593, 0.039993532, 0.0048864777, -0.0122592915, -0.025446814, 0.0197846, -0.041770436, 0.038455322, 0.02064653, -0.029623857, -0.0055826516, -0.009633721, 0.026706558, -0.0077043246, 0.0012199619, 0.029146481, -0.035670627, -0.007081083, 0.032832887, 0.06555969, -0.08311653, 0.06555969, -0.111069575, -0.016694913, -0.0055461857, -0.051371004, -0.03895922, -0.016031891, -0.031665966, -0.0051483717, 0.009162975, 0.031268153, -0.006613652, -0.09441444, 0.10672014, 0.025791585, 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Micromechanics: A New Approach to Studying the Strength and Breakup of Flocs	fragment sizes. The compact flocs favored breakup by surface erosion; whereas flocs characterized by the lower fractal dimension tended to undergo large scale fragmentation. Comparison of the two polymeric flocculants revealed that both the fractal dimension and the tendency for ruptured fragments to reflocculate were sensitive to the polymer used.	8978562	[ -0.06385842, 0.001378836, 0.07762872, -0.06370074, -0.03137735, -0.020142995, 0.086248286, 0.0599691, 0.0284078, -0.04611997, 0.06201888, -0.11583865, 0.043492053, -0.022021957, 0.026252907, 0.039576452, 0.04194158, 0.026476279, -0.06643378, 0.06322772, 0.0985995, -0.02616093, -0.012305229, -0.06885146, 0.0139936665, 0.038157377, 0.013730874, -0.02706756, -0.047328815, -0.059706308, 0.017173449, 0.0132512795, 0.013113313, -0.021877421, -0.025411973, -0.05965375, -0.0025917846, 0.022337308, -0.009979521, -0.057551417, -0.006806309, -0.032717586, -0.031140834, -0.040417388, -0.082464084, -0.017593915, -0.100754395, 0.022770913, -0.0052131335, 0.012193542, 0.011451155, 0.051113017, -0.027225235, -0.0074041607, -0.0021631054, 0.064384006, 0.039261103, -0.03644923, 0.03744784, 0.020510904, -0.013060755, 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0.012173779, 0.011444535, 0.051060233, -0.027225118, -0.0073384307, -0.002233721, 0.06438372, 0.03931349, -0.03650163, 0.037447676, 0.020537093, -0.013054129, 0.037999537, -0.111633494, 0.011359128, 0.031561162, 0.090978146, 0.004411599, -0.10858512, -0.056500003, 0.03421535, 0.03500372, -0.020287443, -0.008153082, 0.037552793, -0.0021417444, -0.016792327, 0.0009788953, -0.05232163, 0.007095349, 0.0011020786, -0.0115365125, 0.013993605, -0.023375234, -0.02349349, -0.042677213, 0.00082450587, 0.0077457563, -0.04554163, -0.031534884, 0.03534535, -0.03421535, 0.04409628, -0.004046977, 0.009828373, -0.08635303, 0.016884303, 0.07400186, -0.02064221, -0.0029416136, 0.3273321, -0.04977256, 0.0027116716, 0.010078024, -0.028433954, -0.026646977, 0.00764064, 0.031272095, -0.08088698, -0.048195817, -0.016726628, 0.03219186, 0.00877721, 0.0649093, -0.05066605, 0.030089537, 0.015031628, 0.010544477, 0.004523285, -0.018579302, -0.014742559, 0.048747677, 0.05174349, 0.027330235, -0.006760291, 0.01781721, -0.048248373, 0.01555721, 0.12456279, -0.020458257, 0.085249305, 0.0033768606, -0.03684326, -0.013651977, 0.027540466, 0.009742966, -0.03308535, 0.00026135356, -0.022521164, -0.06054698, -0.011865, -0.11510233, -0.043413024, -0.057288375, 0.015438954, 0.038314886, 0.0004980705, -0.08172791, 0.0022419333, 0.017068256, 0.035739537, 0.015701745, 0.012765058, -0.012548257, -0.016293025, 0.030194653, 0.075000465, -0.0015381469, -0.02685721, -0.0038268897, -0.016082792, 0.06864093, -0.029090932, 0.049693722, 0.121409304, -0.008823198, 0.0011685975, -0.026423605, 0.011148896, 0.015951397, -0.008501279, 0.056973025, -0.004966744, -0.042283025, -0.01244971, 0.0065993317, -0.05040326, 0.025057094, 0.008888896, -0.019039188, 0.023677442, 0.014768838, -0.028985815, -0.042545814, 0.01609593, 0.03650163, 0.0044313082, -0.05912791, 0.04698698, 0.03563442, 0.030693956, 0.042756047, 0.061230235, -0.031350933, -0.028486513, -0.026752094, -0.029590234, -0.0011579215, 0.00466782, -0.037211165, 0.06112512, 0.022402909, 0.018224536, -0.022875931, 0.06638093, 0.096759535, 0.012016105, 0.008987443, -0.019420233, -0.03613372, 0.027882094, -0.069219075, -0.02459721, 0.048879072, -0.011674477, -0.0004549564, -0.024295, 0.007325291, 0.018789535, -0.0024357415, 0.029563954, 0.026962327, -0.0039977035, 0.034057677, -0.3273321, 0.0077391863, 0.014019884, -0.04525256, -0.024781164, 0.024255583, 0.057761397, 0.0025950582, -0.008159651, 0.032139305, 0.007246454, -0.04782791, -0.024452675, -0.015728025, 0.017961744, 0.0062675583, 0.049562328, -0.014190698, -0.02827628, -0.002301061, 0.046040934, 0.04667163, -0.04241442, 0.00094686775, 0.04633, 0.0003295149, 0.18037954, 0.08130745, 0.044306513, -0.0077457563, 0.009151686, 0.083514884, -0.029511396, -0.072740465, 0.030877909, -0.012962151, -0.04601465, -0.024478955, -0.027619304, -0.029563954, 0.053635582, 0.07631442, -0.015622907, -0.048773956, 0.0072004655, -0.055553954, -0.036895815, -0.0041389535, -0.025832327, 0.05996884, 0.0024209593, -0.08645815, 0.036081165, 0.014834535, -0.007377849, 0.014637442, -0.06102, -0.032296978, -0.032559767, -0.013178954, -0.04102163, -0.015964536, -0.035503026, -0.0115825, -0.061703257, 0.024439536, -0.028933257, -0.0735814, 0.00877064, -0.051901165, -0.006530349, -0.015938256, -0.0154652335, 0.0266207, 0.05823442, 0.0024242443, -0.07557861, 0.053188838, -0.03765791, -0.027198838, 0.09786326, -0.031929072, 0.024557792, -0.011221163, 0.039497443, 0.0014560248, 0.0012802834, 0.040863954, -0.007864012, 0.023874536, -0.015097327, 0.00018179779, -0.03311163, -0.021351745, 0.021667093, -0.017423024, -0.3124056, 0.029931862, -0.050376978, 0.023782559, -0.022954768, 0.08020373, 0.029563954, 0.021430582, -0.07279303, -0.038104653, 0.009499884, 0.04278233, 0.019131163, -0.006438372, -0.023572326, 0.0000922847, 0.046540234, -0.019328257, 0.0095524425, -0.07006, 0.038341165, 0.09470977, 0.15536186, -0.034399305, 0.009953198, -0.0062379944, -0.024951978, 0.06653861, -0.052190233, 0.000042549513, 0.030457443, 0.009887501, 0.072109774, -0.011681047, -0.013047558, 0.05176977, -0.020497676, 0.018290233, 0.011556221, -0.0068259886, -0.0013607631, -0.038367443, -0.026265932, 0.030851629, 0.09528791, 0.05918047, 0.007988838, 0.00081670424, -0.010859826, 0.00410282, 0.045489073, -0.049325816, 0.004996308, 0.039129537, 0.023440931, -0.0010897602, -0.008429012, 0.057866514, 0.036685582, -0.0774707, -0.05886512, -0.06438372, 0.06963954, -0.011924128, 0.0334007 ]
Characterization of Silylated Silicas by Inverse Gas Chromatography: Modelization of the Poly(dimethylsiloxane) Monomer Unit/Surface Interactions Using Poly(dimethylsiloxane) Oligomers as Probes	Inverse gas chromatography (IGC) at infinite dilution was used to characterize the fumed silica surface. The silica was modified by chemical treatment with either dimethyldichlorosilane or trimethylchlorosilane. To observe the silica and poly(dimethylsiloxane) (PDMS) interactions; we used apolar (alkanes) and polar probes (chloroform; benzene; tetrahydrofuran; etc.); but also model molecules of PDMS such as linear and cyclic oligomers of PDMS with two to five monomer units. It is shown that PDMS oligomers a	8978563	[ -0.075964145, -0.0051218853, -0.040471833, -0.031148478, -0.017335612, -0.0039200466, 0.047225967, 0.061290458, -0.01791832, -0.031280912, -0.014753148, -0.095776275, 0.028897101, 0.0005198035, 0.03959777, -0.0025923958, 0.051861156, -0.018951306, -0.082373954, 0.028393852, 0.06303859, -0.040471833, -0.016421817, -0.037055034, 0.09365733, 0.02558625, 0.017825617, 0.0483649, -0.080784746, -0.2163442, -0.022964057, -0.07940743, 0.009753765, 0.010362961, 0.018289136, 0.062085062, 0.030433334, -0.059171513, 0.011071483, 0.019136714, 0.02807601, 0.03941236, -0.033240937, 0.014501524, 0.0026983428, -0.0023656024, -0.031492807, 0.00044944792, 0.079036616, 0.029426835, 0.026076255, 0.027890602, 0.003953155, 0.088783756, -0.011104591, -0.035863128, -0.0036982195, -0.039306413, 0.023970556, 0.04719948, -0.0024003664, 0.030433334, -0.12840801, 0.1272426, 0.030618742, 0.04158428, 0.04264375, -0.040206965, 0.06558132, 0.056522835, -0.032340385, 0.07320952, -0.026354367, 0.008972404, 0.02418245, -0.02301703, -0.010621208, -0.017971294, 0.037319902, 0.038220454, -0.0044497824, 0.012879207, 0.03708152, -0.033850133, -0.01962672, 0.021215929, -0.008621454, -0.004290862, 0.043835655, 0.048921123, 0.0053569553, -0.08014906, -0.06017801, 0.042458344, -0.043650247, 0.0014898826, -0.07162031, -0.035624746, 0.03313499, 0.3981496, -0.0035260555, 0.010389448, 0.016170193, -0.038935598, -0.048258953, -0.0021950935, 0.024076503, 0.027016537, 0.0010917528, 0.042749695, -0.0028324323, 0.026314637, -0.008786996, -0.07379223, -0.015799377, -0.0063270344, 0.03567772, -0.059754223, 0.014594227, 0.05090763, -0.023917582, 0.010568234, 0.009363084, -0.024659213, 0.021255659, 0.020010779, 0.035783667, 0.058217987, 0.03716098, -0.0078069847, 0.006721026, 0.019282391, -0.06383319, -0.024513535, -0.0028522974, 0.02464597, 0.008687671, -0.025533276, 0.06770027, 0.0017878591, -0.010290123, 0.0005417379, -0.08523453, -0.10705965, -0.017746156, 0.05149034, -0.011131078, 0.04770273, -0.05048384, -0.0758582, 0.016130462, 0.078718774, 0.0022795203, -0.002110667, 0.028393852, -0.011316486, -0.038220454, 0.007442791, 0.012276633, -0.02955927, -0.061502352, -0.015825864, -0.0030741245, 0.113257565, -0.0024003664, -0.01519018, -0.045107022, -0.053556312, 0.012952046, 0.030565768, 0.0016372154, 0.01966645, -0.026010038, -0.07320952, -0.011005266, 0.010958914, -0.012647447, -0.011806492, -0.012051495, -0.033108503, -0.023573253, 0.013455295, -0.03146632, 0.034167975, 0.030936584, -0.050536815, -0.021043764, 0.031360373, -0.048232466, 0.01378638, -0.071302466, 0.013170562, -0.07426899, 0.02865872, -0.0692365, 0.0039399117, -0.039068032, 0.013627459, -0.0634094, -0.034883115, 0.06383319, -0.014210169, -0.013627459, 0.042908616, 0.037717205, 0.04272321, 0.003982953, 0.076387934, 0.08417506, 0.068124056, -0.031519294, 0.025400842, -0.07209707, -0.056416888, -0.0025957066, 0.0019318811, 0.034115, -0.015176937, 0.08099664, -0.03305553, 0.033505805, -0.025030028, -0.06589916, -0.30915394, -0.008349964, 0.01436909, 0.0075686034, 0.09106162, -0.04248483, -0.026513288, 0.01515045, 0.023904338, -0.037690718, 0.0987428, 0.018527517, -0.02815547, -0.009084973, 0.007853337, 0.018606978, 0.024050016, -0.04065724, -0.0041451845, 0.006078721, 0.035969075, 0.035624746, 0.003006252, 0.06987218, 0.08131448, -0.011501893, 0.11368135, -0.021215929, -0.034009054, 0.01677939, 0.020672949, 0.020434568, -0.023427576, -0.04057778, -0.04870923, -0.025652466, 0.00014205616, 0.0054629026, 0.017825617, -0.023838121, 0.0032744308, 0.052973602, -0.00041613248, -0.03525393, -0.024328128, 0.006668052, 0.0025725306, -0.0058469614, -0.07220302, -0.0065058204, 0.08104961, -0.036392864, -0.004909991, -0.027334379, 0.023348115, -0.093869224, 0.011753518, -0.012958667, -0.047835164, 0.02702978, -0.020884844, 0.010760263, 0.036048535, -0.005522498, -0.06076072, 0.025109489, 0.017653452, 0.0019136714, 0.01090594, -0.005267563, 0.0051417504, 0.06902461, 0.017176691, 0.01697804, 0.055463362, 0.017666696, -0.004131941, -0.020156456, -0.022884596, -0.006098586, 0.061290458, -0.01896455, 0.027784655, -0.031174965, 0.037293416, 0.060389906, 0.010819858, -0.026513288, 0.0118793305, 0.031784162, -0.023944069, -0.023454063, -0.07151436, -0.01970618, 0.009349841, 0.01958699, -0.27397949, 0.03599556, 0.055251468, 0.04820598, -0.061290458, -0.00017413002, 0.011329729, 0.007926175, -0.025334625, 0.018805629, -0.018037511, 0.020487541, 0.056522835, 0.057794202, -0.0327112, 0.026301393, -0.010925805, -0.0028837505, -0.019454556, -0.04084265, 0.021176198, -0.01207136, 0.15245803, -0.033664726, -0.007760633, 0.059383407, -0.021215929, 0.022129722, -0.06351535, -0.009806738, 0.07601712, 0.014978286, 0.016527764, 0.0075487383, 0.033108503, 0.028870614, 0.012455419, -0.023083247, -0.03453879, -0.021984044, 0.03313499, -0.055251468, -0.032525793, -0.059966117, 0.01179987, -0.061979115, -0.0011985278, -0.0065687266, 0.027201945, -0.05040438, -0.01144892, 0.030168466, 0.0229773, -0.016580738, 0.023944069, -0.010568234, -0.0037511932, -0.017507775, -0.057423387, -0.000679552, 0.053450365, 0.017693182, -0.04142536, -0.018911576, 0.05172872 ]	[ -0.07591207, -0.0050755935, -0.040392853, -0.031148849, -0.017375547, -0.0039300257, 0.047173552, 0.061291188, -0.017958265, -0.031281285, -0.01474008, -0.09588336, 0.028897444, 0.0005380195, 0.03957175, -0.0025626284, 0.05188826, -0.018925045, -0.08237493, 0.028394189, 0.06309231, -0.040472314, -0.016408768, -0.037055474, 0.09371141, 0.025546823, 0.017786099, 0.048365474, -0.08083868, -0.21655867, -0.022951085, -0.0793554, 0.009780368, 0.010363084, 0.018249623, 0.0620858, 0.030433696, -0.059172217, 0.011071615, 0.019110454, 0.028129317, 0.039386343, -0.03324133, 0.014501696, 0.002653678, -0.002378874, -0.03149318, 0.00048587302, 0.079037555, 0.029453672, 0.026063323, 0.02791742, 0.0039664456, 0.08883779, -0.011144454, -0.03591653, -0.00368502, -0.03930688, 0.02397084, 0.04720004, -0.0023705969, 0.030433696, 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Characterization of Silylated Silicas by Inverse Gas Chromatography: Modelization of the Poly(dimethylsiloxane) Monomer Unit/Surface Interactions Using Poly(dimethylsiloxane) Oligomers as Probes	re very appropriate to discriminate the silylated silicas.	8978563	[ -0.07634851, -0.016263824, -0.0042614667, 0.025157895, -0.014023737, -0.026152017, 0.035841387, 0.049759082, -0.023554048, -0.018000223, -0.019418502, -0.08907326, 0.016807277, 0.04747923, 0.024892796, -0.016091509, 0.02267922, -0.009609839, -0.05911708, 0.011134158, 0.060177475, 0.0072173206, -0.00934474, -0.027755866, 0.041434973, -0.0016833787, 0.017363984, 0.049520493, -0.05031579, -0.23201466, -0.023434753, -0.033667576, 0.04538495, 0.010941962, 0.008290972, 0.05317886, 0.0026791568, -0.017695358, -0.016449394, 0.023090124, 0.013354362, 0.074333765, -0.01598547, 0.022082748, 0.0006743456, -0.004493428, -0.0061900616, -0.024773503, 0.076030396, 0.04281349, 0.008562698, 0.043714825, -0.0021075371, 0.068978764, -0.017973712, 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Measurement of Interaction Forces between Silica and alpha-Alumina by Atomic Force Microscopy	Interaction forces between a silica sphere and an alpha-alumina substrate at various pH values were measured by atomic force microscopy (AFM). As expected; at pH values of 10.8 and 10.2 when the surfaces are similarly charged; a repulsive force was observed. On the other hand; at pH values of 5.5; 6.4; and 8.6 when the surfaces are oppositely charged; attractive forces were observed. Experimental force vs separation distance curves were found to be in good agreement with theoretical predictions based on ele	8978564	[ -0.005824261, -0.023390338, -0.036038447, 0.04368862, 0.01644654, -0.068505034, 0.03398596, -0.0053711147, 0.016073361, -0.041156333, -0.00699711, -0.04142289, 0.035585303, 0.022070883, 0.06631927, -0.002938786, -0.019978415, 0.008476499, -0.07970041, 0.023350354, 0.02601592, -0.075648755, 0.010515656, -0.062374234, 0.04155617, 0.060774896, -0.016673112, 0.021804327, -0.0318002, -0.15513591, 0.035265435, -0.013887597, 0.02099133, 0.03374606, 0.03142702, 0.06434675, -0.04571445, -0.014394054, -0.07149047, 0.013834286, 0.04552786, 0.026522378, -0.05650999, 0.048273392, 0.006677242, -0.0026805594, 0.025762692, -0.03707802, 0.109821305, 0.00355853, 0.019618563, 0.011548563, 0.049899388, 0.04198266, -0.044381667, -0.04424839, 0.021271214, -0.017152915, 0.039077193, 0.030520726, 0.016952997, 0.008929645, -0.074849084, 0.03387934, 0.13732994, 0.013487762, 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Measurement of Interaction Forces between Silica and alpha-Alumina by Atomic Force Microscopy	ctrostatic and van der Waals interactions. Interestingly; when the force/radius values at a particular separation distance were plotted against pH; the transition from an attractive to a repulsive force occurred at pH 9.3; which is very close to the point of zero charge (pzc) of alpha-alumina as determined from electrophoresis experiments. These results suggest that AFM force measurements can be used to estimate the pzc of materials. This method may be of particular significance for soluble salt minerals wh	8978564	[ -0.05430503, -0.0042609177, -0.0050844285, 0.02361842, -0.029179618, -0.06321362, 0.0013011135, -0.025392136, -0.011942572, -0.00091353006, 0.049584012, -0.09708758, 0.033340514, 0.027685963, 0.009802111, 0.072708994, -0.04270253, -0.03758143, -0.07484279, 0.025258774, 0.005517855, -0.05078427, -0.031953547, -0.03782148, 0.0840181, 0.075056165, 0.014389765, 0.010008822, -0.02843279, -0.23066302, -0.008181762, -0.0032023564, 0.024018506, -0.05521189, 0.011275762, 0.027472584, -0.022644877, -0.0038508293, -0.09900799, 0.0065014004, 0.031793512, 0.014176386, -0.025698869, -0.0030906657, -0.048650477, -0.008721879, 0.0004102967, 0.011449132, 0.021924721, 0.036887944, 0.1091435, -0.0049077235, -0.07345582, -0.047530238, -0.029179618, 0.03592774, -0.004037536, 0.047210168, 0.072708994, 0.041768994, -0.05430503, 0.015309964, -0.13656275, 0.05102432, 0.15598026, 0.061773304, 0.008828568, -0.04059541, 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Measurement of Interaction Forces between Silica and alpha-Alumina by Atomic Force Microscopy	ere conventional electrophoretic measurements are not possible at high ionic strengths. Finally; results from transmittance studies further confirmed the interaction between silica and alpha alumina particles in suspensions at various pH values as would be expected based on the results from atomic force microscopy measurements.	8978564	[ -0.010666537, 0.06118768, -0.004886886, 0.0015731642, -0.0054431986, 0.014204283, 0.021173175, 0.0145107545, -0.044504978, 0.013671289, 0.027062757, -0.08320032, 0.046343803, 0.041360315, -0.024637636, 0.039708033, 0.009620537, -0.064598836, -0.09204802, 0.025503749, 0.048688978, -0.032805763, -0.002250233, -0.06646432, 0.04930192, 0.017149074, -0.019321023, 0.02635654, -0.038881894, -0.17098439, 0.026596388, -0.00094106706, 0.015070397, -0.018241711, -0.027369227, 0.072700344, -0.049888212, -0.025410475, -0.09087543, 0.012925098, 0.072966844, 0.0043039243, -0.10062922, -0.014350856, -0.021572921, -0.012092295, 0.01408436, 0.029687751, 0.026316565, 0.021826094, 0.041013867, -0.009387352, -0.009760448, -0.001988733, -0.048182633, 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Apparent Dipole Moments of Aerosol OT Reversed Micelles in Cyclohexane Determined at a Frequency of 1 MHz and at a Temperature of 298.15 K	Precise determinations of dielectric constants were carried out for Aerosol OT reversed micelles in cyclohexane at a frequency of 1 MHz and at a temperature of 298.15 K for molalities of AOT from 0 to 0.04 mol kg-1. The ratio of the amount of water; r; to that of AOT was varied from 0 to 25 and the apparent dipole moments for the mixed solute (AOT + r·H2O) were calculated. Discontinuous change in the limiting dipole moment with increasing r was found and was related to the characteristic of water to	8978565	[ -0.00039775885, 0.015420166, 0.002543995, 0.029856632, -0.03676912, -0.023329647, 0.009930055, -0.00091889565, -0.07704765, 0.024060776, 0.024419693, -0.06316951, 0.044638723, 0.026360508, 0.0011656516, 0.049317945, -0.027384087, -0.03206331, -0.083747454, 0.04229911, 0.048998907, -0.034828305, -0.026134523, -0.005586487, 0.09385032, 0.09656214, 0.010062988, 0.023143543, -0.039294835, -0.17781046, 0.01224308, 0.010116161, 0.033525568, -0.023635393, 0.026107935, 0.029005863, -0.021561645, -0.023981016, -0.036822293, 0.02964394, 0.041474927, -0.019620832, -0.013080554, -0.03291408, 0.01883653, -0.030122496, 0.007158413, 0.026294041, 0.04971674, 0.00032838472, 0.06614719, -0.010016461, -0.05093972, -0.036184218, 0.008859949, 0.033818018, 0.019315086, 0.031053023, 0.111556925, -0.000494758, -0.04570218, 0.02521729, -0.13006112, 0.04253839, 0.10735626, 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Apparent Dipole Moments of Aerosol OT Reversed Micelles in Cyclohexane Determined at a Frequency of 1 MHz and at a Temperature of 298.15 K	bind to the head group of AOT. The process of forming W/O microemulsion and the molecular interactions in the micellar core are discussed in terms of the hydration of AOT.	8978565	[ 0.027865592, -0.0034132018, 0.00013030748, 0.04805148, -0.026332319, -0.043491658, 0.097542904, -0.010879581, -0.06261092, -0.009966282, 0.03309206, -0.06570414, 0.02885222, 0.039811797, 0.011452892, 0.024239065, -0.021825826, 0.0821835, -0.059837695, 0.011539555, 0.034025356, -0.011726215, -0.0116595505, -0.004276502, 0.032558747, 0.045331586, -0.034931988, 0.0055431197, -0.051758006, -0.22271141, -0.056051172, -0.033225387, -0.062077608, 0.044531617, 0.040638432, 0.093703054, -0.023239104, -0.022292474, -0.020185888, 0.017092675, 0.02378575, 0.034718663, 0.006073099, 0.07173057, -0.02051921, -0.004996474, 0.06090432, -0.031092135, 0.018665947, -0.010139609, 0.06271758, -0.009946283, 0.030105507, 0.043944973, 0.0018665948, 0.080903545, -0.0045931563, 0.0019549245, 0.048344802, -0.0049698083, 0.0024965703, 0.07658371, -0.15274078, 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Decylammonium Chloride and Cesium Perfluorooctanoate Surface Free Energy and Their Critical Micelle Concentration	Measurements of the surface tension of decylamine and perfluoroheptane and interfacial tension of water-perfluoroheptane were carried out. Measurements of the contact angle were also made for water; glycerol; formamide; diiodomethane; bromoform; and benzene on DACl and CsPFO layers formed on Teflon and on DACl and CsPFO pellets; as well as of zeta potential for surfactants adsorbed on latex. From the results obtained and the literature data the surface free energy of DACl and CsPFO for both tails and heads	8978566	[ -0.072121814, 0.0061476454, -0.044482157, 0.028748408, -0.007668882, -0.0055866684, 0.09387451, 0.031520292, -0.03790883, -0.059978314, 0.026148116, -0.040891904, 0.01883562, 0.044270966, -0.0034186584, -0.011120539, 0.07064347, 0.010731155, -0.07444491, -0.01643332, -0.008513647, 0.010995144, 0.010024984, 0.016816104, -0.0051081884, 0.012202894, 0.0051510865, 0.038753595, -0.07164663, -0.21129684, 0.04287182, -0.021567905, -0.0139782205, -0.030965917, -0.014176212, 0.017172487, -0.025620138, 0.028986, -0.031757884, -0.016552115, -0.016618112, 0.033183426, -0.012209494, 0.023811813, -0.008738038, 0.0061377455, -0.010295574, 0.027138075, 0.090812236, -0.06636685, 0.018664027, 0.028801206, 0.021383114, 0.056863245, -0.010097582, 0.026359307, 0.01738368, 0.003332862, -0.0216999, 0.06203743, 0.033157025, 0.057285625, -0.13959742, 0.074233726, 0.072808184, 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-0.07528968, -0.0035737518, -0.068373166, -0.03405459, 0.027375665, 0.0042271246, -0.0013537689, -0.037116863, 0.009114223, 0.08247018, 0.049841136, -0.031995475, -0.0050751898, 0.038146418, 0.014743789, -0.008566445, 0.029302785, -0.027349267, 0.041103095, 0.071277045 ]	[ -0.072114915, 0.0061668544, -0.044451505, 0.028719263, -0.0076549505, -0.0055861343, 0.09391832, 0.031543676, -0.037905205, -0.05986699, 0.026158813, -0.0408352, 0.01882062, 0.044240333, -0.0033820362, -0.011132673, 0.07063672, 0.0108159175, -0.0744378, -0.016418548, -0.008545828, 0.01101389, 0.009984431, 0.016827693, -0.005120898, 0.012175331, 0.005170391, 0.03880268, -0.07169257, -0.21138223, 0.042894118, -0.021499852, -0.013924091, -0.030936558, -0.014188055, 0.017157648, -0.025551697, 0.02895683, -0.03167566, -0.016576927, -0.016603325, 0.03320665, -0.0122215245, 0.023835933, -0.008717405, 0.006163555, -0.010228598, 0.027161876, 0.09080355, -0.0664133, 0.01860945, 0.028798452, 0.021394268, 0.056857806, 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0.016603325, 0.019810485, -0.011931164, -0.047803845, 0.0061470573, -0.039436195, 0.0141616585, -0.015006343, -0.077552564, 0.007833126, 0.049123663, -0.07538807, -0.0036064056, -0.068472214, -0.034077726, 0.02734665, 0.004253117, -0.0013742616, -0.03713971, 0.009139747, 0.082462296, 0.049889162, -0.03201881, -0.005084603, 0.03814277, 0.014742379, -0.008526031, 0.029273586, -0.027373048, 0.041125562, 0.07127023 ]
Decylammonium Chloride and Cesium Perfluorooctanoate Surface Free Energy and Their Critical Micelle Concentration	parts of their molecules; and their free energy of interaction through water were determined. It was shown that the free energy of interaction between -CH2- groups through water; determined from interfacial tension; is in agreement with that obtained from the relationship between logCMC and the number of carbon atoms in the chain of molecules of surfactants having the same head. It was also shown that there is agreement between the total free energy of interaction between molecules of surfactants through wa	8978566	[ -0.0547721, 0.0010755952, -0.02943734, 0.036390413, -0.028797979, -0.03756258, 0.079760544, 0.007865498, -0.03785562, -0.05621067, 0.014745311, -0.05839516, 0.04821863, 0.075657964, 0.026799968, -0.013653065, 0.051335525, -0.014971752, -0.06857169, 0.017249482, 0.012314399, 0.05208145, 0.009790247, 0.005301385, -0.012174538, -0.000012494063, -0.033300158, -0.031009108, -0.07629733, -0.20640771, 0.034099363, 0.042997167, -0.017755644, 0.0037329479, -0.012800581, 0.002725618, -0.03716298, 0.018062007, 0.00420248, 0.006043979, 0.014199188, 0.042650845, -0.0075990963, 0.0053579956, -0.0069996933, -0.009324045, -0.01641032, 0.034312483, 0.09974064, -0.057222992, 0.043609887, 0.027865574, -0.038042102, 0.06265758, 0.0026806628, 0.0419582, -0.009057644, 0.04163852, 0.013386664, -0.009630406, 0.03809538, 0.005667687, -0.08189175, 0.08253112, 0.034232564, 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Decylammonium Chloride and Cesium Perfluorooctanoate Surface Free Energy and Their Critical Micelle Concentration	ter and their critical micelle concentration (CMC).	8978566	[ -0.06927428, 0.013920956, -0.011931304, 0.0014996757, 0.0054864166, -0.023690743, 0.058539405, 0.046244543, -0.06261125, -0.016525352, -0.0023697354, -0.03323579, -0.020372454, 0.017688736, 0.043071676, 0.014476208, 0.008877419, 0.0028952416, -0.06715903, -0.0124733355, 0.05647704, -0.05259028, -0.021033468, 0.029904276, 0.028079877, -0.043891333, -0.0135309575, 0.0068414956, -0.067846484, -0.200631, -0.04516048, -0.005222011, 0.03889407, -0.041538123, 0.005876415, -0.009188095, -0.003906593, -0.0016707131, 0.014357225, -0.0032373164, -0.006428362, 0.00011733, -0.015599932, 0.024986332, -0.026956154, -0.0677936, 0.0022838037, -0.007753695, 0.044499468, 0.00019365647, 0.048121825, 0.011323171, 0.037677802, 0.012506386, -0.02871445, 0.040612705, -0.055207893, -0.03714899, 0.03947576, 0.040771347, 0.012803842, 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Numerical Simulation of Bubble Motion in Water	This paper presents the results of numerical simulations for bubble motion in water. The motion is axisymmetric and steady in the bubble's frame of reference. It is assumed that the liquid is quiescent except for the motion created by the bubble. The bubble Reynolds numbers range up to roughly 600. The results for clean interfaces are compared with Duineveld's experiments. The insoluble surfactant model is used to model the behavior of bubbles in contaminated water. 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Numerical Simulation of Bubble Motion in Water	d.	8978567	[ -0.08931429, 0.05603308, -0.040688798, 0.0055457666, -0.004543759, -0.03359868, 0.096668966, -0.0049075237, -0.0018601632, -0.016627379, 0.0626999, -0.07042495, 0.03952475, 0.026561478, 0.003750089, -0.018611552, -0.011944728, 0.026627617, -0.058149528, 0.0009805127, -0.03724956, -0.013928902, -0.021508448, -0.058837377, 0.03793741, 0.099208705, -0.026521794, -0.003978269, -0.048387393, -0.19693589, -0.059948515, 0.016852252, 0.07243558, 0.02051636, 0.001724578, 0.016600924, -0.052223463, -0.00315153, -0.081483416, -0.0038195353, 0.042752337, 0.008207867, -0.03148223, 0.015674975, -0.02283123, -0.028836664, -0.050556757, -0.023042874, -0.010906343, 0.03761994, 0.04767309, 0.014458016, -0.043122716, 0.040768165, 0.007731665, 0.050980046, 0.0123151075, 0.05619181, -0.0061542466, -0.045636006, 0.007129799, 0.04486879, -0.14296636, 0.09037252, 0.11333603, -0.006746192, 0.03873108, -0.02337357, 0.027222868, 0.04359892, -0.04558309, 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Analysis of Initial Protein Surface Coverage on Fouled Ultrafiltration Membranes	Internal surface coverage of protein in membranes during the initial phase of ultrafiltration was analyzed. Bovine serum albumin (BSA); in solutions of pH 5 and 7 with 0.05 and 0.15 M NaCl; were ultrafiltered with 100;000-MWCO polysulfone membranes. Mass uptake of the membranes was determined using electron paramagnetic resonance spectroscopy for separate membranes for fractions of an hour for up to 4 h. The resulting data were compared with models for surface coverage. The results showed a significant amou	8978569	[ -0.064258166, 0.047131505, -0.03972323, 0.0068971314, 0.000248934, -0.02206551, 0.06765694, 0.024760636, 0.02651313, -0.018321542, 0.050902024, -0.027482314, 0.03903285, 0.022331038, -0.007414914, -0.0013674775, 0.009054559, 0.017697548, -0.044662077, 0.029659657, -0.034837484, -0.033350516, -0.054964628, -0.011630196, 0.021653939, 0.10100746, -0.014683787, 0.018733114, -0.059266206, -0.21476033, -0.009625448, -0.007793294, 0.044662077, 0.005589398, 0.0042152824, 0.019675743, -0.042644054, -0.01467051, -0.0681349, 0.016250411, 0.030562457, -0.0028461453, -0.018547243, -0.016051264, 0.012247553, -0.024468552, -0.030562457, -0.032792903, 0.0016969001, 0.0033689067, 0.017936524, 0.023087798, -0.026353812, 0.023127628, 0.012247553, 0.07880919, 0.0043613235, 0.04853881, -0.009273621, 0.0116899405, 0.01964919, 0.04413102, -0.11269076, 0.066276185, 0.095165804, 0.025862582, 0.022596568, -0.037811413, -0.0070232577, 0.09989224, -0.029526891, 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0.011816067, 0.016237134, 0.010481781, 0.03289912, -0.038953193, -0.034439187, 0.09617482, 0.0024528296, 0.027907161, 0.06510786, 0.025517395, 0.013674774, 0.00012332606 ]	[ -0.06425988, 0.047159318, -0.03972429, 0.006903954, 0.00025246732, -0.022092653, 0.06765875, 0.024774574, 0.02651384, -0.01824237, 0.050903384, -0.027483048, 0.039033893, 0.022305083, -0.007441666, -0.0013492584, 0.009068078, 0.017671468, -0.044610165, 0.029633895, -0.03481186, -0.03335141, -0.054966096, -0.0116636995, 0.021694347, 0.10095705, -0.014684179, 0.01870706, -0.05926779, -0.21476607, -0.009572598, -0.007766948, 0.04463672, 0.0056360164, 0.004185522, 0.019689545, -0.04261864, -0.014631072, -0.06808361, 0.016237568, 0.030536719, -0.0028429022, -0.018547738, -0.01606497, 0.01224788, -0.024442652, -0.030563273, -0.03276723, 0.001690307, 0.0033872523, 0.018003387, 0.023088416, -0.02630141, 0.023128245, 0.012234603, 0.07881129, 0.0043315673, 0.048487, -0.009300423, 0.011650423, 0.019570054, 0.044158753, 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Analysis of Initial Protein Surface Coverage on Fouled Ultrafiltration Membranes	nt of protein loading exists in a very short time of exposure during ultrafiltration. The amount of material found in this period was not a function of solution properties; however; solution properties did affect the resistance per mass for adsorbed species when the pH was near the isoelectric point of BSA. The modeling comparison implied that the entrained solute from pH 7 appeared to behave as though it was lodged in the ultrathin skin area of the membrane. Solute in the membrane at pH 5 and low ionic str	8978569	[ -0.033907466, 0.039669346, -0.04330703, 0.0012164336, 0.0025141842, -0.060592666, 0.022928031, 0.013860374, -0.036615815, -0.045351565, 0.043625657, -0.053821795, -0.019157585, -0.027587984, -0.009758022, 0.00007307107, 0.01257258, 0.037199967, -0.013209838, 0.013010696, -0.018148592, 0.053928006, -0.086295426, -0.024879636, 0.044050496, 0.034491617, 0.003919804, 0.004646677, -0.03167706, -0.18246837, -0.04322737, -0.035420954, 0.03823551, 0.00091854844, -0.012167656, 0.031013248, -0.021056084, 0.01998071, -0.07870143, 0.07657724, 0.010786928, 0.03430575, -0.008749029, 0.023127174, 0.040253498, 0.0032427167, -0.029844942, -0.018892061, -0.0014305126, 0.04073144, 0.06006162, -0.024375139, -0.0019134352, 0.07243506, 0.049812376, -0.0014454484, -0.0033173955, 0.04930788, 0.040120736, 0.0027697512, 0.029154578, 0.031411536, -0.124796465, 0.058149844, 0.07498409, 0.011417549, -0.016701484, -0.06446932, -0.0110458145, 0.053025223, 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Analysis of Initial Protein Surface Coverage on Fouled Ultrafiltration Membranes	ength appeared to be lodged and adsorbed throughout the membrane substructure.	8978569	[ -0.018276997, -0.0010297366, -0.0091980975, 0.020144429, -0.0477321, -0.03213043, 0.019561686, 0.039520696, 0.07072403, -0.048791636, -0.0046884473, -0.062247746, 0.035176598, 0.029428614, 0.034540877, -0.026991682, 0.010502651, 0.04044779, -0.093927875, -0.009794086, 0.0003238621, -0.05056636, -0.017283682, -0.07967711, -0.00022328895, 0.018594857, -0.07236631, -0.028104195, -0.08566349, -0.02966701, 0.047308285, -0.020025233, -0.05056636, 0.045189213, 0.0025991744, 0.029428614, -0.012297241, 0.0048573106, -0.025865925, 0.013694504, 0.013879922, -0.018197533, -0.05551969, -0.0429377, -0.010833756, -0.038752533, -0.066379935, 0.041639768, 0.011072152, 0.025309669, -0.012270752, 0.0356269, -0.030196778, 0.020038476, -0.029243195, -0.001847566, 0.054989923, 0.0037017541, 0.08211405, -0.033401877, 0.005065907, 0.03411706, 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Formation Mechanism of Monodispersed alpha-Fe2O3 Particles in Dilute FeCl3 Solutions	Some ambiguity is still involved in the interpretation of the growth mechanism of monodispersed hematite (alpha-Fe2O3) particles in dilute FeCl3 solutions. Namely; there are two entirely different proposals on this issue; viz. aggregation of preformed primary particles of alpha-Fe2O3 itself and reprecipitation of the ionic species through dissolution of the preformed beta-FeOOH particles. In order to resolve this problem; the formation process was followed in detail through TEM; Electron Diffraction; XRD; F	8978568	[ -0.03428669, -0.009472579, 0.027993396, -0.06580537, 0.03799477, 0.040945563, 0.078862, 0.0050822897, 0.046768818, 0.008016765, -0.0047526103, -0.09823802, 0.043191303, 0.028045623, 0.022927428, 0.020538066, -0.05421109, -0.021922067, -0.068886735, 0.014518963, 0.06658877, -0.06355964, 0.02291437, -0.025068713, 0.04123281, 0.04073666, -0.012912999, -0.014858435, -0.03945711, -0.075415045, -0.01727391, 0.0068220845, 0.07144583, -0.024677014, -0.007840501, 0.02129535, -0.013631113, 0.014727869, 0.06543978, -0.063664086, -0.027079433, -0.044314172, -0.004768931, -0.054472223, 0.02106033, -0.03961379, -0.045149796, 0.026661621, 0.020642519, -0.028332869, -0.052122034, -0.036297407, 0.035174537, 0.04661214, 0.040788885, 0.098603606, 0.054054413, -0.004563289, 0.030448042, 0.058754794, 0.04833561, 0.01147677, -0.15218797, 0.031936496, 0.01630772, 0.007605482, 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Formation Mechanism of Monodispersed alpha-Fe2O3 Particles in Dilute FeCl3 Solutions	T-IR; and ICP spectrometry along with quantitative analyses on seed effects. As a result; it has been concluded that the nuclei of the hematite particles are initially generated with the formation of beta-FeOOH particles and that they are grown by deposition of the solute originally present in the solution phase and indirectly furnished from the beta-FeOOH by dissolution. As the concentration of the solute is lowered by the growth of the hematite particles; they continue to grow with the solute provided mai	8978568	[ -0.0609655, -0.018539684, 0.021146411, -0.0066830637, 0.015853157, 0.029924165, 0.018898774, 0.039712694, -0.042904604, -0.070168845, 0.032291498, -0.046149712, 0.0028976568, 0.0070155542, -0.040723465, -0.032823484, 0.012129262, -0.02763663, -0.077723034, 0.006536768, -0.008897452, -0.043941975, 0.032158505, -0.029232586, 0.029924165, -0.016185649, -0.008219171, 0.0047612675, -0.029870966, -0.15374371, 0.028993191, -0.014509896, -0.061125096, 0.012973788, -0.05931635, -0.022077385, -0.011038693, -0.021146411, -0.061923075, 0.06788131, 0.014150806, 0.06351903, -0.010859148, 0.02763663, 0.04027128, -0.013173283, -0.07288197, -0.0036041995, 0.102034755, 0.031360526, -0.018366788, -0.018845575, 0.016624536, 0.039659493, 0.0048111407, -0.043011002, 0.06687053, 0.022010887, -0.02936558, 0.068732485, 0.015121679, 0.06304024, -0.11458961, 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0.026373165, 0.06527458, -0.12916599, -0.015826559, -0.045378335, 0.025295895, 0.030722143, 0.038781717, 0.013366127, 0.013818315, -0.0050871084, 0.06724293, -0.024351621, 0.04769247, -0.02472401, 0.028275011, -0.0012526588, -0.055432856, 0.006064631, -0.06788131, 0.05138977, 0.051522765 ]	[ -0.06096469, -0.018552735, 0.021212626, -0.0067494716, 0.015879545, 0.029897168, 0.018871922, 0.039712165, -0.04290403, -0.07016791, 0.03231767, -0.046175696, 0.0028610446, 0.007015461, -0.040696323, -0.032876246, 0.012142399, -0.027609661, -0.077775195, 0.0065699294, -0.008930582, -0.04394139, 0.032104876, -0.029232195, 0.029923767, -0.016198732, -0.008258959, 0.0047645285, -0.029897168, -0.15374166, 0.028939607, -0.0144831035, -0.061017886, 0.012953666, -0.05920916, -0.02209039, -0.011005296, -0.021172727, -0.06192225, 0.0678804, 0.01407082, 0.063464984, -0.010865652, 0.027689459, 0.040270742, -0.013246254, -0.0728278, -0.0035842024, 0.101980194, 0.03136011, -0.018300045, -0.018818725, 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Formation Mechanism of Monodispersed alpha-Fe2O3 Particles in Dilute FeCl3 Solutions	nly from the beta-FeOOH in a steady-state of the dissolution of beta-FeOOH and growth of alpha-Fe2O3. The basic formation mechanism is common to the ellipsoidal particles grown in the presence of phosphate ions and spherical particles in their absence.	8978568	[ -0.023456577, -0.06747783, -0.0060348473, 0.045011993, 0.032748166, -0.030016921, -0.04383381, 0.047475472, -0.0031211842, -0.06817403, 0.055160444, -0.004351249, -0.00759795, -0.022265006, -0.015517223, -0.052054323, 0.00018566026, -0.092433915, -0.031302214, 0.036443383, -0.016909622, -0.03695214, 0.0058574504, -0.02309509, 0.02448749, 0.028222868, 0.019225825, 0.023992116, -0.013656227, -0.20736043, -0.03558652, 0.0127592, 0.026268154, -0.04045992, -0.05826657, -0.047850348, -0.00555621, 0.06694229, -0.027821215, 0.017177392, 0.036737926, 0.040058266, -0.025156911, 0.01328135, 0.0069820806, -0.049055308, -0.076260656, -0.02613427, 0.04677927, 0.06388972, 0.043298274, -0.07995587, -0.001636739, 0.07010196, 0.010155145, -0.0071896017, -0.02014963, -0.046832826, -0.032185853, 0.044663895, -0.024527654, 0.032159075, -0.21828541, 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Tl+/Na+ Competitive Binding at the Surface of Dodecylsulfate Micelles in Water-Urea Mixtures	The effect of urea on the competition between Tl+ and Na+ ions to bind with the surface of dodecylsulfate micelles in aqueous solution has been studied by fluorescence techniques; employing methods based on fluorescence quenching data (FQD) and critical micelle concentration measurements (CMCM). The results obtained are interpreted in terms of selectivity coefficients K (Tl+/Na+) defined within the framework of the pseudophase ion-exchange formalism. It is found that the ion specificity observed in the abse	8978570	[ -0.04382425, -0.05353029, -0.019452192, -0.001105466, 0.008469391, -0.031176982, 0.030535262, 0.08449337, -0.028102066, -0.074011914, 0.0795735, -0.019091222, 0.011477461, -0.019238284, -0.005110378, -0.04722003, 0.043396436, 0.008014837, -0.032326736, -0.013135242, -0.057487577, -0.033663657, 0.007921253, -0.018663408, -0.010220756, -0.0019953537, -0.012580421, -0.036845524, -0.07930612, -0.15401323, -0.05224685, -0.0069586704, 0.023462953, -0.048476733, 0.0008326507, -0.026150163, -0.03395778, 0.061926153, -0.07342367, 0.041444533, 0.026257116, 0.0012675676, 0.011457408, 0.03930546, 0.015214154, -0.03475993, -0.040027395, -0.011089754, 0.08235429, 0.0618192, 0.04687243, -0.05925231, -0.019224916, 0.03823592, -0.0064573255, -0.042380378, 0.024559228, -0.044546187, -0.0062166797, 0.046765476, 0.024813242, 0.035535343, -0.18791753, 0.053289644, -0.039358936, -0.029144865, 0.0076137614, -0.031096768, 0.062086582, 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Tl+/Na+ Competitive Binding at the Surface of Dodecylsulfate Micelles in Water-Urea Mixtures	nce of urea [K(Tl+/Na+) = 3.8 +/- 0.3 (from FQD); K(Tl+/Na+) = 2.5 +/- 0.3 (from CMCM] is progressively lost in the presence of increasing concentrations of urea. Typically; values of K (Tl+/Na+) = 1.4 +/- 0.2 (from FQD) and K (Tl+/Na+) = 1.2 +/- 0.2 (from CMCM) in a water-urea mixture at 8 M urea; were obtained. The results are discussed in terms of urea association to the micellar interface and changes in the characteristics of the external medium.	8978570	[ -0.048479363, 0.011940337, 0.014679434, 0.014466689, 0.007419497, -0.03130017, 0.00456073, 0.077864826, -0.0510589, -0.06999324, 0.041219424, 0.00017223238, 0.0075990004, -0.009061625, -0.009792938, -0.003812797, 0.0030814845, 0.0038759557, -0.057547636, 0.044995658, -0.013442852, -0.034863655, 0.042708643, 0.0023601444, -0.0010412891, 0.0036233205, -0.024851324, -0.026460212, -0.072067514, -0.20710766, 0.02837492, 0.006359094, -0.029864138, -0.030954458, 0.029970512, -0.00795136, -0.002326903, 0.026992075, -0.084885426, 0.010258318, -0.0012681622, 0.083396204, -0.018522149, 0.01812325, 0.016886668, -0.04475632, -0.09424622, 0.01733875, 0.059728276, 0.048692107, 0.0048599034, -0.010145297, 0.04510203, 0.030502375, -0.011162486, -0.07111016, 0.0047036684, -0.013469445, 0.011282155, -0.0007724487, -0.02794943, -0.004108646, -0.17519586, 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Effects of Monovalent, Exchangeable Cations and Electrolytes on the Infrared Vibrations of Smectite Layers and Interlayer Water	Infrared spectroscopy was used to investigate how nuSi-O; the frequency of Si-O stretching; in layers of Li- and Na-montmorillonite and nu2; the frequency of H-O-H bending; in the interlayer water were affected by increasing the concentration; C; of LiCl and NaCl; respectively. Oriented gels of Li- and Na-montmorillonite equilibrated with solutions having various values of C were obtained by using a miniature pressure membrane apparatus. 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Effects of Monovalent, Exchangeable Cations and Electrolytes on the Infrared Vibrations of Smectite Layers and Interlayer Water	mc; the water content. The other part was transferred to an FTIR spectrometer where the spectrum of the gel was measured by attenuated total reflectance. Thus; the dependence of both nuSi-O and nu2 on mw/mc was determined in the same samples. The results showed that increasing C had little or no effect on the relation between nuSi-O and mw/mc; or on the relation between nu2 and mw/mc. The vibrational coupling of Si-O stretching in the montmorillonite layers and H-O-H bending in the interlayer water was demo	8978572	[ -0.04218659, -0.066601984, -0.02548273, 0.027510675, -0.026603436, -0.015596498, 0.056302156, 0.1153794, -0.035515722, -0.021053271, 0.015823308, -0.00014665494, 0.0066175046, -0.0117073795, -0.005930405, 0.0045695473, 0.044347957, -0.012327771, -0.044721525, -0.009559359, -0.026389968, -0.0013233342, 0.020226084, -0.017210849, 0.012694669, 0.065481275, -0.012521226, -0.013795363, -0.029752087, -0.1502814, 0.026336601, 0.043414034, -0.0009931261, -0.08805551, 0.023241317, -0.006614169, 0.017157482, 0.04704299, -0.024989085, -0.014088881, 0.00979284, 0.036076073, -0.038157385, 0.02701703, 0.009085727, -0.010573331, -0.09125753, -0.035862606, 0.06836309, 0.058223367, 0.026189843, -0.02388172, 0.04141277, 0.046509318, 0.020065982, -0.07407336, 0.008431982, -0.009926257, -0.017264215, 0.048270427, -0.0024281973, 0.05854357, -0.13192315, 0.0106800655, 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Effects of Monovalent, Exchangeable Cations and Electrolytes on the Infrared Vibrations of Smectite Layers and Interlayer Water	nstrated. It was essentially independent of the species of exchangeable cation and C. Thus neither the species of exchangeable cation nor C had any specific effect on the structure of the clay layers or the structure of the interlayer water.	8978572	[ -0.059237048, -0.021966849, 0.03811148, 0.02222057, -0.045669682, -0.029458279, 0.06351023, 0.07777199, -0.04793981, -0.03215573, 0.000273751, 0.03688294, -0.019149218, -0.0178272, -0.016945856, 0.041182835, 0.05736753, -0.07157587, 0.008800093, 0.060625833, -0.012398917, -0.042304546, 0.0370966, -0.030045843, -0.011370682, 0.049568962, 0.018628422, -0.010295709, -0.026480403, -0.14357907, 0.056779966, 0.0020180792, 0.0432126, -0.03079365, -0.06607415, -0.0104426, -0.070614405, -0.012038368, 0.016385, 0.020404465, 0.03669599, 0.05416264, -0.01318011, -0.030980602, -0.06756976, 0.011931538, -0.06687537, -0.021793252, 0.08081664, 0.0745671, 0.05539118, 0.007678382, 0.021058798, 0.03805807, -0.008245914, -0.044040527, -0.051919214, 0.021526176, -0.04110271, 0.058008507, -0.030259501, 0.06895855, -0.1253112, 0.03423891, 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Self-Association of Phenothiazine Drugs: Influence of the Counterion on the Mode of Association	The association characteristics of the phenothiazine drug trimeprazine tartrate in water and aqueous electrolyte solution have been examined using static and dynamic light scattering techniques and compared with those reported for the structurally related drug promethazine hydrochloride; to identify differences in association pattern arising from differences in the counterions of the two drugs. The association of trimeprazine tartrate was micellar in water and in the presence of added electrolyte. A progres	8978571	[ -0.072818846, 0.0073956638, 0.025098406, 0.024911005, -0.017388176, -0.060557432, 0.048296027, 0.037292887, -0.057291295, -0.06869601, -0.01417558, 0.042700756, 0.0062143654, 0.027146436, 0.027655097, 0.02786927, 0.028966907, 0.023304706, -0.03212596, 0.0616283, -0.08127868, -0.0030569858, 0.04098737, -0.023973998, 0.0540787, 0.037748, -0.0017518688, -0.004855705, -0.042540126, -0.1296818, 0.05504248, -0.07640624, 0.033732258, 0.02006534, -0.05734484, 0.005444681, -0.003292911, 0.017655892, -0.045217287, 0.010929519, 0.0007374748, 0.03426769, 0.0015201268, -0.023478722, -0.042272408, 0.04719839, 0.012181093, 0.00964448, 0.08877473, 0.023331478, 0.048296027, -0.055363737, -0.007268498, 0.045377918, -0.010661803, -0.056809407, -0.10783614, -0.0062210583, -0.03132281, 0.103231415, -0.034053516, 0.08486608, -0.09669914, 0.036409423, 0.05932594, 0.0014473414, 0.026892105, -0.029903915, 0.097770005, 0.116081804, 0.015500776, 0.036677137, -0.003500391, 0.08309915, 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Self-Association of Phenothiazine Drugs: Influence of the Counterion on the Mode of Association	sive increase of aggregation number and micellar radius was observed with increase of sodium chloride concentration over the range 0.05 to 0.60 M NaCl. This behavior is in contrast to that of promethazine hydrochloride which exhibits continuous association above the critical concentration in electrolyte of concentrations >/=0.2 M NaCl. Moreover; static light scattering curves for trimeprazine tartrate showed a single discontinuity corresponding to the onset of micellization; whereas the association behavior	8978571	[ -0.057341725, -0.005429377, -0.0050475453, -0.052706156, -0.010731477, -0.03772764, 0.038879834, -0.0011044645, -0.026353078, -0.010570706, 0.020176785, -0.024852546, -0.012680828, 0.036468264, 0.024691775, 0.0019995917, 0.04458721, -0.0055767507, -0.055090927, 0.017725024, -0.049919453, 0.041103832, 0.011414754, 0.009927621, 0.013330611, -0.033547588, -0.028054573, 0.003761376, -0.080332, -0.15862757, 0.038477905, -0.03298489, -0.06677363, -0.008540969, 0.030975249, -0.0107984645, -0.015876155, 0.040943064, 0.008654849, 0.024531003, -0.05308129, 0.049008418, 0.039415736, 0.066505685, 0.029608695, -0.07357962, -0.027250716, -0.019011194, 0.14126429, 0.02203905, -0.010275958, -0.019614086, 0.058788665, 0.009545789, -0.035128504, -0.06468361, -0.03215424, 0.066880815, 0.04437285, 0.054983746, 0.037700843, 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Self-Association of Phenothiazine Drugs: Influence of the Counterion on the Mode of Association	of promethazine hydrochloride (and other phenothiazine drugs with chloride counterions); in water and dilute electrolyte (0.05-0.1 M NaCl); is complex; with discontinuities in solution properties at several critical concentrations. The results of this study highlight the influence of the counterion on the association characteristics of this class of amphiphile.	8978571	[ -0.0013512091, -0.045578048, 0.033171568, -0.027178606, 0.012156775, 0.014995546, 0.05530347, 0.067236826, -0.027756874, -0.026705477, -0.0447895, -0.04045249, 0.02794087, 0.044132378, 0.011401083, 0.031699613, 0.00080210075, 0.03501151, -0.003251116, 0.045656905, -0.012012208, 0.010816244, -0.018530868, -0.018123452, -0.0690242, -0.012261915, -0.0012690687, 0.016585784, -0.025798649, -0.10298431, -0.049363077, -0.014680128, -0.017387474, -0.01918799, 0.026968326, -0.014824694, -0.0031804752, 0.031515617, 0.059719335, -0.022526175, 0.04055763, 0.0400845, -0.062242687, -0.07669939, 0.006853793, 0.00044930784, -0.024037559, 0.03164704, 0.11638962, -0.047575705, 0.018741148, -0.041214753, 0.0012690687, 0.02180334, 0.029728243, -0.032304164, 0.066027716, -0.02297302, 0.019621693, 0.0001230052, 0.016690923, 0.02394556, -0.09183951, 0.02105422, 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Adsorption of Glycosidic Surfactants at the Mercury Electrode	The adsorption of glycosidic surfactants from aqueous electrolyte solutions on a mercury electrode was studied by means of differential capacitive measurements (tensammetric method). The adsorption behavior of the mono- and disaccharidic surfactants studied is discussed in relation to their micellar properties; in particular their respective critical micellar concentration (CMC). 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Adsorption of Glycosidic Surfactants at the Mercury Electrode	on of a monolayer called hemimicelle at the mercury electrode. For disaccharidic compounds; the split capacity peak observed at concentrations above the CMC suggests the formation of a multilayer of micelles throughout the electrical double layer.	8978573	[ -0.04465508, 0.028193364, -0.021539196, -0.08417924, 0.031587258, 0.026483055, 0.052618705, 0.045804195, -0.056279834, -0.038588833, -0.0123329265, 0.01040883, 0.020617234, 0.028220087, -0.031052787, -0.027685616, -0.032175176, 0.059967685, -0.09134115, -0.00030982637, -0.05251181, -0.017209979, 0.030518316, -0.06525895, 0.015232434, 0.004396027, -0.042864602, -0.025627902, -0.09786171, -0.1753066, -0.018185388, -0.0027876021, 0.0014748069, -0.0040686633, -0.035088044, -0.0014322163, 0.019868974, -0.017704364, -0.01699619, 0.012914164, -0.019307777, 0.058845297, 0.021886602, 0.11790438, 0.039497435, -0.02231418, -0.06889336, -0.018947009, 0.02875456, 0.02232754, 0.009092694, -0.056707412, -0.025788244, 0.071138136, -0.03495443, -0.018038409, 0.03062521, 0.011791774, 0.030518316, 0.03166743, 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0.036290605, -0.0005804025, -0.024064573, 0.08321719, -0.1017099, 0.012680333, -0.043612864, -0.018987095, -0.026683483, -0.046686072, 0.02606884, 0.045777474, -0.09235665, -0.019414673, -0.06638134, 0.020269826, -0.010749555, 0.03166743, -0.03535528, 0.00531799, -0.02995712, -0.08498095, 0.08786709, -0.016448356 ]	[ -0.044630833, 0.028194927, -0.021567114, -0.0841839, 0.031562284, 0.02647116, 0.052675072, 0.04572656, -0.056336403, -0.03853752, -0.012340291, 0.010402725, 0.020618375, 0.028194927, -0.031107957, -0.027687151, -0.032203685, 0.059917558, -0.09129277, -0.00032299728, -0.05251472, -0.017170845, 0.03054673, -0.06526257, 0.015206553, 0.004402952, -0.042893704, -0.025589235, -0.09792058, -0.17531632, -0.018146308, -0.0028178224, 0.0014022299, -0.0040288013, -0.03514344, -0.0014807348, 0.019870074, -0.017745433, -0.01694368, 0.012901518, -0.019308848, 0.05879511, 0.021821002, 0.117910914, 0.039526347, -0.022288691, -0.06884372, -0.018907972, 0.028756153, 0.022288691, 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0.055481203, 0.0022883322, -0.0074362447, -0.002174751, -0.090918615, 0.004366205, 0.0026574722, 0.022849917, -0.017331194, -0.022275329, -0.01757172, -0.042279027, 0.014324626, 0.0026725049, 0.012420466, -0.0278475, -0.036185715, 0.031455383, -0.023036992, 0.06531602, 0.020845538, -0.009727918, -0.0148724895, -0.06670572, -0.04324113, 0.0059830705, 0.03712109, 0.03557104, 0.06387287, -0.032470934, -0.022315416, 0.01582123, -0.011130983, 0.027286274, -0.007877208, -0.004346161, -0.007075457, -0.02482757, 0.016649706, -0.080923446, 0.034314964, 0.022689566, -0.24864985, 0.006901744, 0.005542107, -0.040728975, -0.079213046, -0.01667643, 0.023437867, -0.013208856, -0.0069151064, 0.07857165, 0.04382908, 0.046287786, 0.0278475, 0.015941491, 0.013248943, -0.057245053, 0.033700287, 0.0013629775, 0.033245962, 0.014097463, 0.052781973, -0.029825155, 0.11203141, -0.01307523, 0.022302054, 0.017558357, -0.02143349, 0.027232824, -0.002472067, 0.07124898, 0.018694172, 0.031882983, 0.026965573, 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Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle	The proton affinity of individual surface groups has been calculated with a redefined version of the multi site complexation (MUSIC) model. In the new approach the proton affinity of an oxygen originates from the undersaturation of the oxygen valence. The factors valence and coordination number; which are the basis of Pauling's definition of bond valence; in combination with the number of coordinating (Me and H) ions; are dominant in determining the proton affinity. The neutralization of an oxygen by Me ion	8978574	[ -0.0012708992, -0.0011365493, 0.061577275, 0.015047179, -0.0024132899, -0.025287805, 0.02488726, 0.04048185, -0.030521607, -0.052631747, 0.06398055, 0.03717067, 0.01713002, 0.009139125, -0.082993135, 0.035568487, 0.015073882, -0.015768161, -0.04830585, -0.0033929585, -0.092659645, 0.043526, -0.0121031655, -0.010207248, -0.021803055, -0.009766648, -0.053219214, 0.016142005, -0.055649195, -0.15551867, 0.042164143, 0.0018575322, -0.04248458, -0.028225143, -0.029613703, -0.012123193, -0.038051873, -0.011502347, -0.032310713, 0.00083488814, -0.017797595, 0.1053169, 0.0035915626, 0.05778544, -0.029106345, 0.0128575275, -0.01835836, -0.022564093, 0.12764066, -0.00029060448, 0.006048245, -0.056877535, 0.026996803, 0.07973536, 0.025554836, -0.026262468, 0.07044269, 0.026102249, -0.013571834, 0.026916692, -0.031990275, 0.023311779, -0.11065751, -0.036155954, 0.015127288, -0.044967968, -0.046703666, -0.013298128, 0.029693812, 0.078346804, 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Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle	(s) is calculated on the basis of the actual bond valence; which accounts for structural details; resulting from an asymmetrical distribution of charge in the coordination environment. An important role in the new version of the MUSIC model is given to the H bonds. The model shows that the proton affinity is determined not only by the number of donating H bonds but also by the number of accepting H bonds. The proton affinity of surface groups and of solution complexes can be understood in one theoretical fr	8978574	[ -0.033342324, 0.030369123, -0.0086475015, -0.008129846, -0.0067461133, -0.0023228133, -0.01575531, 0.05200447, 0.041837186, -0.058614533, 0.07794034, 0.044943117, 0.011600793, 0.01785248, -0.05452638, 0.03963383, 0.01892761, -0.071728475, -0.045022756, -0.019604543, -0.073958375, -0.061216082, 0.09365583, 0.01765338, 0.0006611722, 0.007983841, -0.043270692, 0.012536555, -0.057924327, -0.112663075, -0.021993723, -0.028059583, 0.019843461, 0.007452912, -0.019047068, -0.022949394, -0.020560216, 0.050624054, -0.027475562, 0.015038556, 0.015742037, -0.011952533, -0.0032751667, -0.07815271, -0.028802885, -0.039421458, -0.007406456, -0.081072815, 0.037510116, 0.015888043, -0.052137204, -0.045898788, 0.002613165, 0.03881089, -0.008733777, 0.010990225, 0.06095062, 0.0015181244, -0.015994228, 0.01117605, 0.011965807, 0.031032784, -0.14271365, -0.017002992, 0.06318052, 0.012583011, 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Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle	amework; on the basis of a different number of donating and accepting H bonds. The MUSIC model predicts the variation in proton affinity constants for surface groups in particular those with the same number of coordinating Me ions but with a different structural position. The model is able to predict on the basis of the proton affinity of the individual groups the correct PZC of Me hydroxides; oxohydroxides; and oxides; and explains previous exceptions. The model can also be applied in general to other mine	8978574	[ -0.037365995, -0.019527957, 0.016926017, 0.023860052, 0.019192655, -0.026381519, 0.053138576, 0.023578398, -0.023229685, 0.0037553762, 0.06013967, -0.034710407, 0.016322475, 0.0492759, -0.061480876, 0.011386838, 0.007094979, 0.023578398, -0.023055328, -0.0049926387, 0.0010805089, 0.017998982, -0.0054385895, 0.005763832, -0.028058026, -0.02899687, 0.036775865, 0.010736353, -0.034817703, -0.1370176, -0.009991983, -0.06872339, -0.06931352, -0.031223271, 0.041845623, -0.08004317, -0.0026874412, -0.023256509, 0.0056196526, -0.0101797525, -0.020305857, 0.082671925, 0.022264017, 0.05885211, 0.051824193, -0.04659349, -0.004566806, 0.0015348424, 0.14656697, 0.06453882, -0.021781182, 0.029962538, 0.026555875, 0.0015591518, 0.013163935, -0.09656682, -0.00040026612, 0.01433749, 0.057457257, 0.05292398, 0.056920774, 0.07162039, -0.12296175, -0.014981269, -0.0042549754, -0.029640649, -0.012560393, -0.02867498, 0.09946382, -0.008550188, 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Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle	rals.	8978574	[ -0.03541898, 0.025570065, 0.06389202, 0.034650154, -0.01870366, -0.0018557848, 0.060710676, 0.04525464, 0.0028019038, -0.011472727, 0.075928114, 0.01475349, 0.002389323, 0.05029177, -0.058960937, 0.03963426, -0.002685917, -0.00016393457, -0.043876056, 0.004583126, -0.042020272, -0.0293214, 0.008099175, -0.007264072, 0.027598172, -0.005627005, 0.005279045, 0.021858495, -0.054135896, -0.17412564, -0.004679229, -0.061081834, -0.059915338, -0.026590746, 0.04504255, -0.053738225, -0.019830387, 0.03875939, -0.029347911, -0.0027107715, 0.010485184, 0.09899287, 0.05795351, 0.039952397, 0.022945454, -0.014713722, -0.045731843, -0.05885489, 0.14952324, 0.04440628, -0.055514477, 0.01770949, 0.055196345, 0.026763069, 0.005421543, -0.058430713, 0.011744467, 0.01215539, 0.06367993, 0.050159212, 0.019565275, 0.070413776, -0.1461298, -0.0022617378, 0.0017928208, -0.033351105, 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Coarsening Due to Thermally Induced Marangoni Convection	The growth of closely packed droplets in a decomposing butoxyethanol/water mixture is studied at reduced gravity during scaled times t* = t(D/xi2) on the order of t* = 10(6) (t; time; D; diffusion coefficient; xi; correlation length). Thermally induced Marangoni convection at the surfaces of the droplets causes an enhancement of the coarsening process.	8978575	[ -0.12499807, -0.022183958, 0.00447612, 0.0146382125, -0.024796972, 0.0066825175, 0.08670941, 0.03378254, 0.028289879, -0.035142377, 0.03884859, -0.028049909, -0.023237163, 0.04682095, -0.011398608, 0.026023488, 0.03132951, 0.022157295, -0.030849567, 0.017104577, -0.021704016, -0.063352264, 0.06687184, -0.036635526, 0.08654943, 0.027223343, -0.036715515, 0.022277279, 0.012111854, -0.1568875, 0.05439336, -0.01493151, -0.048687387, -0.040848345, -0.029729703, -0.028503185, -0.0032646013, -0.037968695, 0.02986302, -0.01184522, 0.038102012, 0.053753436, -0.030262971, 0.036955487, 0.056313124, -0.08329649, -0.10137428, -0.03932853, 0.0398618, 0.07268446, 0.0006482542, -0.047194235, 0.02946307, 0.064472124, -0.051407054, -0.012071859, -0.039435185, 0.06617858, 0.061752457, 0.033515908, 0.026756732, 0.015931388, -0.14899513, 0.03588895, 0.037062142, 0.007605738, 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Biochemical modulation: its pharmacological basis and clinical applications. Proceedings of a meeting. Singapore, October 19, 1995.	nan	8978576	[ -0.049932905, -0.015686769, -0.057981476, -0.034735933, 0.045908622, -0.025310636, 0.08869313, -0.0139393825, -0.044320088, 0.026925644, 0.03203543, -0.088587224, 0.005986786, -0.04561739, 0.0020319992, -0.03905145, -0.01270165, -0.008379514, -0.025443014, 0.0018168853, -0.009160544, -0.012800933, 0.053083498, -0.020267041, 0.023391157, 0.048211996, 0.012033142, -0.020306755, -0.011073403, -0.19305979, -0.00036962362, -0.04381705, 0.033597484, -0.081491776, -0.044108283, -0.020439133, -0.03465651, 0.04042818, -0.006512988, 0.035583153, 0.016004477, -0.03327978, -0.009769482, -0.0049277637, 0.044876073, -0.00092995405, -0.036774553, -0.07328435, 0.030420419, 0.00036135002, -0.024132473, -0.055492774, 0.037357014, 0.061688054, 0.03343863, -0.030314516, 0.028620081, 0.017460631, 0.008928883, 0.074290425, 0.025588628, 0.024887027, -0.11892822, 0.04238737, 0.05872279, 0.013687865, 0.011953715, -0.056975406, 0.05671065, 0.023245541, -0.028064093, 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A comparative, randomized trial of UFT and 5-fluorouracil in combination with cyclophosphamide and doxorubicin in the treatment of advanced breast cancer patients at The Philippines General Hospital.	A comparative; randomized trial was conducted to determine the efficacy of oral UFT (Tegafur and Uracil) versus 5-fluorouracil (5-FU) in combination with cyclophosphamide and doxorubicin in patients with metastatic breast cancer. Of 62 evaluable patients; 31 received UFT (350 mg/m2/day orally x 14 days); doxorubicin (50 mg/m2 intravenously [I.V.] day 1) and cyclophosphamide (500 mg/m2 I.V. day 1). The other 31 patients received 5-FU (500 mg/m2 I.V. days 1 and 8); doxorubicin (50 mg/m2 I.V. day 1); and cyclo	8978577	[ -0.04094875, 0.011862032, -0.018655619, 0.004546889, 0.00029253884, -0.002325266, 0.038167123, 0.06435186, -0.06884525, -0.0051587136, 0.031721238, -0.0133798905, 0.008939987, -0.038648557, -0.035626214, 0.0064492277, -0.0072482764, 0.013620608, -0.10709262, 0.0106918765, -0.029581526, -0.08986793, 0.026947005, -0.05857463, 0.022105906, -0.05547205, -0.016729878, 0.0072148433, -0.0517543, -0.13137835, 0.006763498, -0.033245783, 0.020929065, 0.00718141, -0.04271401, -0.012570811, -0.009575214, -0.013908132, -0.02872564, 0.021905309, 0.025663178, 0.050336737, 0.00008138848, 0.039290473, 0.049908794, -0.027816264, -0.088423625, -0.021517485, 0.034422625, 0.008077415, 0.09115176, -0.077297114, -0.02963502, 0.06258659, -0.033780713, -0.021423873, -0.028698895, 0.03966492, 0.0221594, 0.029501287, -0.00078316825, 0.063442476, -0.1288107, 0.07558535, 0.044345543, 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A comparative, randomized trial of UFT and 5-fluorouracil in combination with cyclophosphamide and doxorubicin in the treatment of advanced breast cancer patients at The Philippines General Hospital.	phosphamide (500 mg/m2 I.V. day 1). Regimens were repeated for a total of six cycles. The two groups were comparable in terms of age; gender; performance status; menopausal status; and number and sites of metastases. No statistical difference in overall response rates was seen (UFT arm; 48.4% vs. 5-FU arm; 35 %; p = 0.30). Median response duration was 16 weeks (range; 4-30) for both arms. The toxicity profile (alopecia; anemia; leukopenia; thrombocytopenia; diarrhea) was similar in both groups and both regi	8978577	[ -0.039755903, -0.027010549, -0.03844937, -0.001936467, 0.0047961725, 0.019437997, 0.052634574, 0.0733791, -0.07636546, -0.008832423, -0.051807992, 0.02593066, -0.012218741, -0.016438305, -0.016184999, -0.034449782, -0.05770072, 0.02661059, -0.12841342, 0.034743086, -0.06367344, -0.048848297, 0.042475622, -0.07161929, 0.0062360237, -0.029863589, 0.009065732, 0.008092499, -0.06585988, -0.14697152, 0.020597877, -0.016384978, 0.044768717, -0.0050328146, 0.012612034, 0.0031163455, -0.016664948, -0.027650483, -0.0300769, -0.0033863175, 0.042235646, 0.023384256, 0.012878672, 0.037782773, 0.041382402, -0.018118132, -0.095083535, -0.017518194, 0.05340783, -0.03756946, 0.068686254, -0.08532454, -0.032823283, 0.058287326, -0.025544034, -0.056367524, 0.020464556, 0.008785761, 0.030050235, 0.067619696, 0.025877332, 0.03538302, -0.084737934, 0.074605644, 0.07935182, 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A comparative, randomized trial of UFT and 5-fluorouracil in combination with cyclophosphamide and doxorubicin in the treatment of advanced breast cancer patients at The Philippines General Hospital.	mens were well tolerated. Anemia and stomatitis were significantly more common in the 5-FU arm (p = 0.02). Thus; oral UFT has response rates and duration of response that are comparable to 5-FU in a combination regimen for advanced breast cancer.	8978577	[ -0.03428669, -0.009472579, 0.027993396, -0.06580537, 0.03799477, 0.040945563, 0.078862, 0.0050822897, 0.046768818, 0.008016765, -0.0047526103, -0.09823802, 0.043191303, 0.028045623, 0.022927428, 0.020538066, -0.05421109, -0.021922067, -0.068886735, 0.014518963, 0.06658877, -0.06355964, 0.02291437, -0.025068713, 0.04123281, 0.04073666, -0.012912999, -0.014858435, -0.03945711, -0.075415045, -0.01727391, 0.0068220845, 0.07144583, -0.024677014, -0.007840501, 0.02129535, -0.013631113, 0.014727869, 0.06543978, -0.063664086, -0.027079433, -0.044314172, -0.004768931, -0.054472223, 0.02106033, -0.03961379, -0.045149796, 0.026661621, 0.020642519, -0.028332869, -0.052122034, -0.036297407, 0.035174537, 0.04661214, 0.040788885, 0.098603606, 0.054054413, -0.004563289, 0.030448042, 0.058754794, 0.04833561, 0.01147677, -0.15218797, 0.031936496, 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Mechanism-based improvement in the therapeutic selectivity of 5-FU prodrug alone and under conditions of metabolic modulation.	To compare the antitumor activity of Tegafur (150 mg/kg/day) with continuous intravenous infusion of 5-fluorouracil (5-FU) (12.5 mg/kg/day) and with oral UFT (60 mg/kg/day) with and without low- or high-dose leucovorin (50 or 200 mg/kg/day); rats with advanced colon cancer were treated with Tegafur or UFT 3 times daily for 28 days and 5-FU by continuous intravenous infusion for 28 days. UFT alone had a complete remission (CR) rate of 38%; whereas Tegafur and 5-FU produced no CRs. 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Mechanism-based improvement in the therapeutic selectivity of 5-FU prodrug alone and under conditions of metabolic modulation.	as added; the CR rate for UFT increased to 75%; Tegafur plus high-dose leucovorin resulted in only a partial remission rate of 50%; with no CRs; low-dose leucovorin was not as effective as the high dose. Hence; UFT clearly offers significant therapeutic advantages over Tegafur and protracted infusion of 5-FU. High-dose leucovorin is essential for significant modulation of drug action in this tumor.	8978578	[ -0.076980725, -0.011442719, -0.044994645, 0.06809422, -0.020355996, -0.00095857866, 0.055246253, 0.06814775, -0.032360815, -0.058511775, 0.034020342, -0.04253212, 0.030540684, -0.01988758, -0.053640254, -0.0039045769, -0.00034127408, -0.016046574, -0.053613488, 0.01713062, -0.08945396, 0.015578158, -0.058458243, -0.01940578, 0.02374197, 0.0088731265, -0.007963062, -0.0037205566, -0.06852248, -0.19036402, 0.0047309957, 0.0013366569, 0.004132093, -0.06627409, -0.030058885, -0.02220289, -0.002358806, 0.03284261, -0.008344485, -0.002000803, -0.039748393, 0.051927194, -0.008190578, 0.06172377, -0.012272484, -0.021359742, -0.0495985, 0.00008134535, 0.05422912, 0.021332975, 0.05487152, -0.045235544, 0.0028506424, 0.054523554, 0.010445664, 0.000561262, -0.03519807, 0.066059954, -0.038088866, 0.04512848, 0.017719485, 0.003086523, -0.11134903, 0.029416487, 0.06215203, -0.0066548446, 0.016180407, 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Clinical application of biochemical modulation in cancer chemotherapy: biochemical modulation for 5-FU.	The addition of Uracil to Tegafur; a prodrug of 5-fluorouracil (5-FU); has been shown to enhance the antineoplastic effect of 5-FU while reducing the side effects attributed to 5-FU catabolism. Studies of 5-FU levels have shown that the 5-FU concentration in the tumor tissues of patients with head and neck cancer was 16.9 times greater than that in serum and approximately 2-6 times greater than in normal tissue. Similar observations have been made in tumor tissues of patients with breast cancer. 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Clinical application of biochemical modulation in cancer chemotherapy: biochemical modulation for 5-FU.	l efficacy of UFT; the combination of Uracil and Tegafur in a molar ratio of 4:1; has been studied in a variety of tumor types. An overall response rate of about 23% was obtained; with responses exceeding 30% in patients with head and neck; breast; and bladder cancer. Side effects are predominantly that of gastrointestinal toxicity. Hematologic toxicity is minimal and hepatotoxicity is rare. The UFT combination produces a good clinical effect in a variety of tumor types and is well tolerated.	8978579	[ 0.031122755, 0.017913524, 0.050498065, 0.026617795, 0.037262257, 0.013780656, 0.020624474, 0.014750751, -0.002837194, -0.013262386, 0.029554658, -0.04260442, 0.04993993, 0.039574537, -0.04244495, -0.019694244, -0.014325504, -0.010239148, -0.08175371, 0.04273731, 0.017222498, 0.004033201, 0.0011195953, -0.03609283, 0.009727522, -0.012757406, 0.0042624352, 0.0035082866, -0.036837008, -0.16488947, 0.0035215756, -0.027016465, -0.05278377, -0.006421892, 0.011315553, -0.0036046316, -0.0048438273, 0.012671027, 0.0068105944, -0.01424577, 0.040265564, 0.033408456, -0.035508115, 0.016345426, 0.018551394, -0.0017425155, -0.027959982, -0.032797165, 0.05905616, -0.010013235, 0.024810497, -0.007076374, 0.09158754, 0.044464875, -0.05132198, -0.016770674, 0.06697638, 0.066551134, 0.056292053, 0.064478055, -0.05969403, 0.05799304, -0.1088632, 0.02578059, 0.07659759, 0.0009999946, 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Phase II study of UFT plus leucovorin in colorectal cancer.	The activity and toxicity of UFT (Tegafur and Uracil) in a 4:1 molar concentration; plus leucovorin (LV); were evaluated in the treatment of 45 patients with advanced; bidimensionally measurable metastatic colorectal carcinoma. Initially 350 and later 300 mg/m2/day; plus 150 mg LV; as administered in divided doses every 8 h for 28 days. After two courses of treatment; responses were evaluated. The overall response rate was 42.2%; with responses observed in liver (n = 18); lung (n = 6); and bone (n = 1). 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Phase II study of UFT plus leucovorin in colorectal cancer.	e of the 7 patients who received 350 mg/m2 UFT experienced prolonged grade 3 diarrhea; resulting in a dose reduction to 300 mg/m2; 9 patients in the 300-mg/m2 group experienced grade 3 diarrhea; vomiting; abdominal cramping; and fatigue. Minor toxic effects included oral mucositis and rash. The oral regimen of 300 mg/m2/day UFT; plus 150 mg/day LV; administered for 28 days appears to have significant activity against metastatic colorectal carcinoma. The treatment is well tolerated; neutropenia did not occur	8978580	[ -0.03428669, -0.009472579, 0.027993396, -0.06580537, 0.03799477, 0.040945563, 0.078862, 0.0050822897, 0.046768818, 0.008016765, -0.0047526103, -0.09823802, 0.043191303, 0.028045623, 0.022927428, 0.020538066, -0.05421109, -0.021922067, -0.068886735, 0.014518963, 0.06658877, -0.06355964, 0.02291437, -0.025068713, 0.04123281, 0.04073666, -0.012912999, -0.014858435, -0.03945711, -0.075415045, -0.01727391, 0.0068220845, 0.07144583, -0.024677014, -0.007840501, 0.02129535, -0.013631113, 0.014727869, 0.06543978, -0.063664086, -0.027079433, -0.044314172, -0.004768931, -0.054472223, 0.02106033, -0.03961379, -0.045149796, 0.026661621, 0.020642519, -0.028332869, -0.052122034, -0.036297407, 0.035174537, 0.04661214, 0.040788885, 0.098603606, 0.054054413, -0.004563289, 0.030448042, 0.058754794, 0.04833561, 0.01147677, -0.15218797, 0.031936496, 0.01630772, 0.007605482, 0.027784491, -0.061313894, -0.020825312, 0.05217426, 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Phase II study of UFT plus leucovorin in colorectal cancer.	; and oral mucositis was not significant; even though both are characteristic of intravenous schedules of 5-fluorouracil plus LV. The results of this trial constitutes the basis of phase III clinical trials comparing this oral schedule with intravenous 5-FU and LV to compare clinical efficacy; impact on well-being; and cost. In addition; the current National Surgical Adjuvant Breast and Bowel Project (NSABP) adjuvant colon clinical trial (CO-6) will compare this 28-day schedule of UFT plus oral leucovorin w	8978580	[ 0.0076639797, 0.009056248, -0.0074883197, -0.044682693, -0.026544174, -0.00172407, 0.12449738, 0.022978926, 0.054545674, 0.02054571, -0.0012686553, -0.10081581, 0.0495231, 0.029276662, 0.014508212, 0.021898942, 0.0076574734, -0.0038742782, 0.008269031, 0.07146108, 0.07140903, 0.011235733, 0.010845377, -0.000051005434, 0.023096032, 0.07479211, -0.030629894, -0.014169904, -0.05030381, -0.075364634, -0.020311497, 0.01716263, 0.043251388, 0.030421704, -0.023043986, -0.0042678867, 0.014716402, 0.0021713525, -0.024943715, -0.011632593, 0.03476766, 0.011034048, -0.026075747, 0.017891293, 0.019673917, -0.0064506247, -0.015314947, 0.010214302, 0.010149242, -0.019582834, -0.015210852, -0.07375117, -0.03172289, 0.055066146, 0.0334925, 0.048013724, 0.049679242, -0.05113657, 0.06021884, 0.05126669, 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Phase II study of UFT plus leucovorin in colorectal cancer.	ith a weekly regimen of intravenous 5-fluorouracil plus leucovorin in the postoperative adjuvant therapy of Dukes' B and C colon cancer patients.	8978580	[ -0.03428669, -0.009472579, 0.027993396, -0.06580537, 0.03799477, 0.040945563, 0.078862, 0.0050822897, 0.046768818, 0.008016765, -0.0047526103, -0.09823802, 0.043191303, 0.028045623, 0.022927428, 0.020538066, -0.05421109, -0.021922067, -0.068886735, 0.014518963, 0.06658877, -0.06355964, 0.02291437, -0.025068713, 0.04123281, 0.04073666, -0.012912999, -0.014858435, -0.03945711, -0.075415045, -0.01727391, 0.0068220845, 0.07144583, -0.024677014, -0.007840501, 0.02129535, -0.013631113, 0.014727869, 0.06543978, -0.063664086, -0.027079433, -0.044314172, -0.004768931, -0.054472223, 0.02106033, -0.03961379, -0.045149796, 0.026661621, 0.020642519, -0.028332869, -0.052122034, -0.036297407, 0.035174537, 0.04661214, 0.040788885, 0.098603606, 0.054054413, -0.004563289, 0.030448042, 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UFT modulated with leucovorin in advanced colorectal cancer: Oncopaz experience.	A phase II trial of UFT (Tegafur and Uracil) modulated by leucovorin was undertaken by the Oncopaz Cooperative Group to assess the efficacy and toxicity of this combination in patients with advanced colorectal cancer. A total of 75 patients were given 500 mg/m2 intravenous leucovorin and 195 mg/m2 of oral UFT on day 1; followed by oral leucovorin 15 mg/12 h and 195 mg/m2/12 h of oral UFT on days 2-14. An overall response rate of 39% was obtained; with seven complete responses (9%); and 22 partial responses	8978581	[ -0.028205143, -0.04405728, 0.010026875, -0.008303816, -0.0644689, 0.0084164785, 0.036078196, 0.016978754, -0.035362463, 0.0028761823, 0.071626216, -0.09309818, 0.044773012, -0.008787598, -0.020941788, 0.012048155, -0.064521916, 0.027807513, -0.03295018, -0.012644599, -0.00024768966, -0.055986147, -0.0021273147, -0.017084789, 0.026362795, -0.006746437, 0.043686163, -0.03594565, -0.026442321, -0.185136, -0.0012102829, -0.0024205658, -0.0011456682, -0.04273185, 0.02862928, -0.10470894, -0.0006043131, 0.023486612, -0.058265887, 0.015109898, 0.024666246, 0.02449394, -0.04506461, 0.03446117, 0.0465756, 0.0021157172, -0.07549647, -0.04222819, 0.06261329, 0.0024570152, 0.0059412383, -0.008721327, 0.013028974, 0.03295018, -0.03165126, -0.023857733, -0.0030716832, 0.0012906371, 0.027807513, 0.038490478, -0.004715216, 0.018595777, -0.10513308, 0.061924074, 0.0521424, 0.065052085, 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UFT modulated with leucovorin in advanced colorectal cancer: Oncopaz experience.	(29%). The primary toxicity was gastrointestinal; with grade 1-2 diarrhea occurring in 8.5% of courses; and grade 3-4 in 3.5%. Hematologic toxicity was minimal; and there were no deaths due to toxicity. This regimen was active and well tolerated in patients with advanced colorectal cancer; including those 70 years of age or older.	8978581	[ -0.04046798, -0.03072913, -0.012737463, 0.01590856, -0.035797577, 0.012963022, 0.01995536, 0.0075031617, -0.012087322, -0.03285204, 0.06565101, -0.06278508, 0.048800405, 0.006458292, -0.026443504, 0.042060163, -0.06145826, 0.018363176, -0.022343634, 0.0073373094, -0.0018907172, -0.032825503, 0.027226327, -0.022051733, 0.020698378, 0.011476985, 0.052621644, 0.00795428, -0.004332064, -0.19127424, 0.006624144, 0.040600665, 0.025687218, 0.015815683, -0.009632707, -0.06225435, 0.01723538, -0.008783543, 0.04885348, 0.032082487, 0.091179006, 0.029826893, -0.029747283, -0.02765091, 0.052993152, 0.0035293386, -0.031206785, -0.055832546, 0.04328084, 0.0048362557, -0.024771713, -0.027703982, 0.0033269988, 0.06692475, 0.008266083, -0.004743378, 0.033409305, 0.007788428, 0.0063455123, 0.044713803, 0.01854893, 0.038769655, -0.0676147, 0.008551349, 0.062732, 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Experience of Oncopaz Cooperative Group with oral fluoropyrimidines in tumors of the stomach, lung, head and neck, and breast.	The Oncopaz Cooperative Group designed a chemotherapy regimen to modulate UFT (Tegafur and Uracil) with leucovorin. The regimen consisted of a high intravenous dose of leucovorin; followed by oral UFT and oral leucovorin twice daily for 14 days. Based on the promising results obtained with this regimen in patients with advanced colorectal cancer; the Oncopaz group performed several phase II trials using this combination with other drugs to treat advanced gastric; lung; head and neck; and breast cancers. 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Experience of Oncopaz Cooperative Group with oral fluoropyrimidines in tumors of the stomach, lung, head and neck, and breast.	n combined with etoposide in gastric cancer; the regimen was shown to be active and well tolerated. However; when used with cisplatin to treat non-small cell lung cancer; a low response rate and high toxicity precluded its recommendation for further study. The addition of carboplatin in the treatment of head and neck cancer demonstrated moderate activity with low toxicity. In an ongoing trial of advanced breast cancer; preliminary results indicate that the combination of idarubicin; UFT; and leucovorin is a	8978582	[ -0.044216648, -0.006379698, 0.03293689, 0.0049266, 0.0011636397, 0.016548067, -0.012912004, 0.052895427, -0.02194908, 0.006708138, -0.010569796, -0.03691798, -0.006426144, 0.03543171, -0.001132952, -0.0021481302, -0.054992136, 0.0788256, -0.10802026, -0.0394128, -0.0072256797, -0.014530981, -0.010138511, -0.049843255, 0.032644946, 0.052762724, -0.007371653, 0.021550972, -0.053346615, -0.14788425, 0.034794733, 0.021325376, -0.041536048, 0.028849637, 0.0059318254, -0.030627858, -0.054248996, -0.0073517477, -0.043208104, 0.016972717, -0.007643694, 0.014411548, -0.028212663, -0.036307547, 0.06544913, 0.0015741896, 0.006037988, 0.015725309, -0.010450363, 0.02279838, 0.017065609, -0.03468857, -0.021750025, 0.007583978, 0.036572956, -0.0125138955, 0.006110974, 0.053558942, 0.07383596, -0.034396626, 0.023475165, 0.04469438, -0.09082195, 0.03957204, 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Experience of Oncopaz Cooperative Group with oral fluoropyrimidines in tumors of the stomach, lung, head and neck, and breast.	ctive; with moderate; primarily hematologic toxicity. Trials of new combinations are warranted to take advantage of the pharmacokinetic properties and oral bioavailability of UFT and leucovorin.	8978582	[ -0.076788016, -0.030678215, -0.006269084, 0.011818115, -0.040296536, 0.05408984, 0.04629477, 0.046506163, -0.04021726, -0.0525044, 0.03921315, -0.026212566, 0.00022873237, 0.0386054, -0.018985612, -0.024997063, -0.023451261, 0.07784498, -0.033294186, -0.024125073, -0.005010643, -0.070499115, 0.0272431, -0.065267175, 0.013231796, -0.010728126, 0.018325014, -0.039266, 0.015973281, -0.19035819, -0.0036266882, -0.021112742, -0.044445097, 0.018932765, 0.018470345, 0.0020841896, -0.017875807, 0.0040131384, -0.02024075, 0.044312976, 0.08138579, -0.004838887, -0.0148899, -0.016924545, 0.1037933, -0.007484586, -0.00984953, -0.066218436, 0.09697592, -0.006784351, 0.016832061, -0.078373455, -0.012531562, 0.07768644, 0.011434968, 0.012663681, 0.0040098354, -0.011111274, 0.025274515, 0.0015524075, 0.053455666, 0.012069142, -0.087991774, 0.04053435, 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Comparison of two different doses of ondansetron plus dexamethasone in the prophylaxis of cisplatin-induced emesis.	This study was conducted to evaluate the efficacy of two different doses of ondansetron (8 mg vs. 24 mg) plus dexamethasone in the prevention of cisplatin (CDDP)-induced emesis and nausea (acute and delayed). The persistence of the anti-emetic efficacy during the second cycle of chemotherapy was also assessed. Eighty patients receiving high-dose CDDP (>80 mg/m2) were randomized to have either ondansetron 8 mg plus dexamethasone 20 mg (8 mg group) or ondansetron 24 mg plus dexamethasone 20 mg (24 mg group);	8978584	[ -0.052357215, -0.04396205, -0.02637723, 0.003717574, -0.0018422351, 0.037950374, 0.06784987, 0.027992703, -0.007978053, -0.065413415, 0.03225649, -0.026695028, -0.015969347, 0.06430112, 0.0333423, -0.030905852, -0.03556689, 0.033845484, -0.029767076, -0.00010231191, 0.016896259, -0.0679558, 0.066525705, -0.018988429, 0.0051642167, 0.044067983, -0.021623503, -0.08649401, 0.022563655, -0.1939627, 0.006369201, -0.014036076, -0.09062538, 0.015969347, -0.01925326, -0.0064916853, 0.008223022, 0.0037904028, -0.002284173, 0.03540799, 0.04414743, 0.017293505, 0.0057468466, -0.05667397, 0.036202483, 0.009884841, -0.032018144, -0.057786264, 0.042743824, -0.01892222, 0.019690232, -0.053151708, 0.008461371, 0.04864957, 0.013340893, -0.014353874, -0.02293442, -0.0006471823, 0.02620509, 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0.045418117, -0.009527211, -0.009255762, 0.08352696, -0.0041081547, 0.013526124, 0.007335754, -0.009997282, 0.03381862, -0.023993477, -0.059692383, 0.045682944, -0.0048728473, -0.018074557, -0.014923096, 0.013784332, 0.02114657, 0.015081992, 0.066736825, 0.055561054, 0.076270655, -0.03196482, -0.023861064, -0.32309097, -0.007097408, 0.0015293856, -0.020458015, 0.004048568, 0.013744608, 0.053919118, 0.028627979, -0.041789964, -0.031911854, 0.006511475, 0.050661724, -0.039962646, -0.04306114, 0.016604757, 0.06684276, 0.031249782, -0.028283702, 0.03175296, 0.039141677, 0.015081992, 0.03932706, 0.005346229, -0.014181575, -0.014711233, 0.0011296598, 0.12584658, 0.033474345, 0.032573927, -0.023410855, -0.017452208, 0.05820934, -0.016181031, -0.009255762, 0.01053356, 0.0125330165, 0.008461276, -0.04647743, -0.010752044, -0.023728648, 0.010301835, -0.015413028, -0.03410993, -0.11504158, -0.047430813, -0.035063315, -0.02114657, -0.0083023785, 0.028654462, 0.015942685, 0.050132066, -0.061652113, -0.006825959, -0.0100171445, -0.047430813, -0.008613552, -0.009401417, -0.004813261, -0.052727386, 0.06763724, -0.0019829047, -0.012235085, 0.020749327, -0.04925813, 0.00040696718, 0.023198992, 0.029157637, -0.018154005, 0.062552534, 0.0076469276, -0.037128977, 0.0777537, 0.05810341, 0.07642955, 0.024377478, -0.041869413, -0.02153057, -0.008937968, -0.028733911, -0.030375848, 0.034904417, -0.025992934, 0.060539834, -0.0073225126, -0.024523135, -0.05582588, 0.029819708, -0.018127521, 0.018021591, -0.0055481605, -0.013155364, 0.028601496, -0.055296227, -0.060275003, 0.08951209, 0.028442599, -0.25444737, 0.013625435, 0.0626055, 0.035619456, -0.054819535, 0.014737715, 0.039512437, -0.028813358, -0.02725087, 0.026853627, 0.007461548, 0.0044292593, 0.023966994, 0.055561054, 0.012248326, 0.02225885, 0.1151475, -0.06689572, 0.010056869, -0.013287778, 0.009017416, -0.01561165, 0.17616403, 0.021729192, 0.059480518, 0.04110141, -0.028707428, -0.03103792, 0.019504631, -0.012519775, 0.030799573, 0.041816447, -0.0057236096, 0.016128065, 0.034957383, 0.09952261, 0.012672052, -0.0029776674, -0.06557158, -0.044491217, -0.027356802, -0.025503, -0.00471395, -0.012175498, 0.07070925, -0.037632152, -0.10995686, 0.048225302, -0.012817708, 0.03397752, -0.029766742, 0.021504087, 0.07939564, -0.03352731, 0.040651202, 0.02031236, 0.022033745, -0.09210741, -0.044835493, 0.020947948, -0.013201709, -0.059374586, -0.028230736, 0.03612263, 0.014287506 ]

Adsorption of CaCO3 Particles on Cationic Cellulose Graft Copolymers

; the agitation; and the ionic strength of the suspension. Kinetic models have shown that the weakly charged copolymers present a high-affinity-type kinetics when the CaCO3 particle average diameter is small (20 to 30 μm). For an average particle diameter equal to 72 μm; the kinetics corresponds to an adsorption with a lower affinity. The rate constants are 6.6 x 10(-12); 2.9 x 10(-12); and 1.2 x 10(-12) m3/s for particles with average diameters of 20; 30; and 72 μm; respectively. We have also noted that th

8978546

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Adsorption of CaCO3 Particles on Cationic Cellulose Graft Copolymers

e adsorption increases with agitation and reaches a plateau after 5 min. The ionic strength influences the electrostatic interactions between the positive sites of the graft and the anion of the adsorbate. Indeed a decreasing adsorption is observed when the ionic strength increases.

8978546

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Energetic Classification of Adsorption Isotherms

The new model describes adsorption isotherms with a two-parameter function. The parameters are easy and precise to calculate from the excess surface work of the adsorbed layer. The excess surface work is defined as the product of adsorbed amount and the change of the chemical potential. The differential form yields a minimum at the first layer. It is possible to linearize the corresponding integral form. The physical meanings of the two parameters are the monolayer capacity and the chemical potential; which

8978547

[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]

Energetic Classification of Adsorption Isotherms

is necessary for adsorption. The new model allows an energetic classification of adsorption phenomena of surface films in the energetic range from weak physisorption to chemical adsorption

8978547

[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]

Electrochemical Studies of the Interfacial Behavior of Insulin

The interfacial behavior of insulin and chain A and chain B of insulin was investigated at the platinum electrode in a phosphate buffer; pH 7.0; using cyclic voltammetry. The enthalpy of adsorption; DeltaHADS; calculated from a linear van't Hoff relationship over the temperature range 299 to 333 K gave values of -22 ± 1; -17 ± 1; and -9 ± 1 kJ mol-1 for insulin; chain B and chain A; respectively. Above these temperatures denaturation of insulin occurs; and for all three molecules the su

8978548

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Electrochemical Studies of the Interfacial Behavior of Insulin

rface adsorption measured by the surface charge densities showed an immediate decrease followed by a slight increase. The surface concentrations of insulin of 2.9 ± 0.2 mg m-2 at 299 K and 3.2 ± 0.3 mg m-2 at the physiological temperature of 310 K agreed well with the calculated value determined from geometrical dimensions. Similar calculations from experimental surface charge densities for chain A and chain B indicated that a more efficient packing prevailed with the individual polypeptides.

8978548

[ null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null, null ]

Electrochemical Studies of the Interfacial Behavior of Insulin

From a consideration of the mechanism of adsorption based on cyclic voltammetric measurements; an estimation of the number of carboxylate groups on insulin was determined to be 6 ± 2; which agrees with the known number of acidic residues on the protein. Similar calculations for chain A gave 2 ± 0.4; which indicates that this peptide remains as a monomer in the phosphate buffer. However; the value obtained for chain B under similar experimental conditions was 6 ± 2; indicating that this

8978548

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Electrochemical Studies of the Interfacial Behavior of Insulin

peptide appears to dimerize in the phosphate buffer. Dimer formation of insulin is known to occur through hydrophobic interactions and four hydrogen bonds between the B chains.

8978548

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The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution

A molecular model based in statistical thermodynamics is used to study salt effects on the lower consolute boundary of the aqueous non-ionic surfactant C8E5. The C8E5 micelles are modeled as hard spheres interacting via a temperature-dependent Yukawa attraction and the salt ions are modeled as positively and negatively charged hard spheres interacting via a Coulombic potential. The excess thermodynamic properties due to the Coulombic and Yukawa potentials are evaluated using the analytical solutions to the

8978549

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The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution

Ornstein-Zernike equation obtained for the mean spherical approximation closure. The Yukawa parameters for the micelle-micelle attractions are determined by fitting the theoretical phase diagram for a pure Yukawa fluid to the experimental lower consolute boundary for a salt-free C8E5 micelle-water solution. Ion-solvent interactions are indirectly accounted for by using previously determined adjusted values for the cation size and the dielectric constant of the medium. We evaluate theoretical coexistence cur

8978549

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The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution

ves for the C8E5 micelle-salt-water mixtures in the temperature-micelle volume fraction and temperature-salt molarity planes. We calculate the changes in the lower critical solution temperature (LCST) for the C8E5 micelle-salt-water mixture as a function of salt concentration for the salts NaF; NaCl; NaBr; NaI; and Na2SO4 and compare the trends seen with experiments. When ion-solvent interactions are indirectly accounted for; the theory correctly predicts the salting-out trends exhibited by NaF; NaCl; and N

8978549

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The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution

aBr. For the 1:2 salt (Na2SO4); charge effects resulting from the higher charge on the ions play a more important role in salting-out than ion-solvent interactions do. The theory; however; cannot predict the salting-in phenomena exhibited by NaI; thus indicating that salting-in is the result of variations in the intermicellar attraction as a function of the salt type and salt concentration. The theoretical results also indicate that excluded-volume forces resulting from the different sizes of the salt ions

8978549

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The Effects of Salts on the Lower Consolute Boundary of a Nonionic Micellar Solution

cannot alone account for the salting-in and salting-out phenomena seen in aqueous nonionic micellar solutions.

8978549

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Adsorption of Nonionic Surfactants on Kaolins

Adsorption of nonionic surfactant on kaolins of different origins was studied. The shape of the isotherm differs only slightly according to the origin of the kaolin; but the amount adsorbed is quite different. The relation between the morphology of the kaolin particles and the shape of the isotherm is not clear. Fluorescence studies show two different solubilization sites for adsorbed pyrene molecules. However; these two environments could not be correlated to the basal and lateral surfaces of the mineral p

8978550

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Adsorption of Nonionic Surfactants on Kaolins

articles.

8978550

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Mechanism of Particle Flocculation by Magnetic Seeding

Magnetic seeding flocculation of micrometer-sized particles in liquid suspensions is investigated. Primary forces acting on individual particles; including gravity and magnetic attraction; as well as van der Waals; electrostatic; magnetic dipole; and hydrodynamic interparticle forces; are examined and quantified. A mathematical statement of the overall relative velocity is developed from the net force acting on a particle. From this; the equation of relative motion for two particles in cylindrical coordinat

8978551

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Mechanism of Particle Flocculation by Magnetic Seeding

es is derived. A computer model is then used to solve this equation repeatedly to find the particle trajectory borderline between collision and noncollision; thus determining the collision efficiency and collision frequency. The effects of a variety of parameters on flocculation performance are then explored. It is found that some factors have unexpected and complex influences on the collision efficiency and collision frequency; particularly the particle size ratio and the direction of the magnetic field.

8978551

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Comparison of Solubilization of Hydrocarbons in (PEO-PPO) Diblock versus (PEO-PPO-PEO) Triblock Copolymer Micelles

The solubilization of hydrocarbons by micelles formed of diblock and symmetric triblock copolymers in water are compared in the framework of a mean-field theory of solubilization. The block copolymers contain poly(ethylene oxide) as the hydrophilic block and poly(propylene oxide) as the hydrophobic block and are designated as EXPYEX or EWPZ (where E and P denote ethylene and propylene oxides and the subscripts denote the number of segments). In the presence of a variety of aromatic and aliphatic hydrocarbon

8978552

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Comparison of Solubilization of Hydrocarbons in (PEO-PPO) Diblock versus (PEO-PPO-PEO) Triblock Copolymer Micelles

solubilizates; the core radius; corona thickness; and aggregation number of the micelle and also the volume fraction of the hydrocarbon solubilized in the core are predicted. The calculations show that for identical molecular weights and block compositions; the diblock (E200P64) copolymer micelles have a much larger core radius; corona thickness; aggregation number; and volume fraction of the hydrocarbon solubilized in the core compared with the symmetric triblock (E100P64E100) copolymer micelles. In contr

8978552

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Comparison of Solubilization of Hydrocarbons in (PEO-PPO) Diblock versus (PEO-PPO-PEO) Triblock Copolymer Micelles

ast; the diblock copolymer (E100P32); having the same block composition but half the molecular weight of the symmetric triblock copolymer (E100P64E100); gives rise to micelles having the same core radius; corona thickness; and volume fraction of the hydrocarbon solubilized as the micelles formed of the triblock copolymer; and an aggregation number twice that of the triblock copolymer micelle.

8978552

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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode

An experimental investigation was performed on electrosprays of low electric conductivity liquids (heptane with different amounts of an antistatic additive) that were operated in the cone-jet mode. The effects of liquid flow rate; applied voltage; and liquid electric conductivity on droplet size and spray monodispersity were systematically investigated. The droplet size was found to be dominantly controlled by the liquid flow rate and secondarily by the applied voltage. It showed no dependence on capillary

8978553

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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode

size. For a given liquid; stable and monodisperse electrosprays could be established only within certain ranges of liquid flow rates and applied voltages; that defined a cone-jet domain. This domain was affected by the electric conductivity of the liquid. As the liquid electric conductivity increased; the domain shifted toward smaller flow rates which implies that smaller droplets were generated in the spray. An increase in the capillary diameter caused a narrowing of this domain. Outside the cone-jet domai

8978553

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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode

n; electrosprays were unstable and polydisperse with different instability patterns that depended on the applied voltage and the liquid flow rate. Experiments also showed that the droplet size and the spray monodispersity were independent of the electrode configuration; as long as the electrospray was operated at the onset voltage condition; that is defined as the minimum voltage at which the cone-jet mode was established. By using dimensional analysis the controlling variables were combined into a few dime

8978553

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Monodisperse Electrosprays of Low Electric Conductivity Liquids in the Cone-Jet Mode

nsionless groups and an empirical fit was derived and was shown to correlate well all the experimental data.

8978553

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-0.043976348, 0.04864783, 0.034633387, -0.05181584, -0.044701234, 0.03957334, 0.024713203, 0.047117516, 0.042016473 ]

Contact Angle Studies of Ethyl Xanthate Coated Galena Particles

The wettability of ethyl xanthate coated galena particles has been determined from measurements of the equilibrium capillary pressure across a packed bed. Both the advancing liquid powder contact angle; thetap; and the specific wettable surface area; Awet; of galena particles have been obtained. The influence of particle size and ethyl xanthate surface coverage on the powder contact angle have been investigated and compared with floatability. Ethyl xanthate at a surface coverage of less than ten percent of

8978554

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0.03427158, 0.038932938, 0.028577305, 0.03114635, 0.042402472, 0.02987507, -0.02036696, 0.04510394, -0.0340597, -0.04791135, 0.014566746, -0.029689675, -0.003125229, 0.0030209443, -0.04409751, -0.028789185, 0.024405919, 0.002547525, -0.29069927, 0.054002896, 0.009693507, 0.043647267, -0.0035522995, -0.049315054, 0.07378718, -0.01930756, 0.025809623, 0.010395359, -0.047672983, 0.043488357, -0.037105475, 0.05524769, -0.02181039, -0.038191356, 0.014765383, -0.05249325, -0.007190675, -0.01199108, 0.025875837, -0.02961022, 0.17533064, 0.008514925, -0.029742645, -0.017665489, -0.0025690442, 0.052069493, -0.02860379, -0.004366713, -0.040442582, -0.026710114, 0.038827, -0.041369557, -0.01427541, 0.084063366, 0.0013333538, -0.026590932, 0.03003398, 0.00012880396, 0.01819519, -0.018076006, -0.036204983, -0.028047606, 0.013427891, -0.046295766, 0.052890528, -0.03911833, 0.019466469, -0.041793317, -0.04791135, -0.0026931926, -0.0021419737, -0.035225037, -0.00711122, 0.016327998, -0.044229936, -0.009428657, 0.0053367256, 0.039753973, 0.024551587, -0.06690109, -0.03639038, 0.023743795, 0.06886098 ]

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-0.007117872, 0.016328068, -0.044283096, -0.009428698, 0.0053235064, 0.039674688, 0.02453845, -0.066954345, -0.03636405, 0.02375714, 0.068861276 ]

Contact Angle Studies of Ethyl Xanthate Coated Galena Particles

an equivalent monolayer significantly increases both thetap and particle floatability.

8978554

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Optimization of Long-Term Stability of Magnetic Fluids from Magnetite and Synthetic Polyelectrolytes

Nanometer-sized suspensions of magnetite (Fe3O4) stabilized with polymeric surfactants; principally poly(methacrylic acid) (PMAA); were prepared by precipitation or sonication and studied by a variety of techniques. The long-term stability of the ferrofluids made with PMAA was optimal at pH 7 (close to the measured isoelectric point of the magnetite; 5.9) and improved at all pH values with increasing surfactant concentration. With extended times of sonication the molecular weight and polydispersity of the P

8978555

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Optimization of Long-Term Stability of Magnetic Fluids from Magnetite and Synthetic Polyelectrolytes

MAA decreased; although magnetite in the ferrofluid was not oxidized (X-ray). Particle diameters of 9-38 nm were measured by saturation magnetization; electron microscopy; and dynamic light scattering. Centrifugation at 8;000 rpm removed the magnetite from the suspensions together with roughly one molecule of PMAA for each magnetite particle in the fluid; with the average number increasing with higher concentrations and average molecular weights of the polymer.

8978555

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Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles

Microviscosity; micellar aggregation number (N); and critical micelle concentration (cmc) were determined in solutions of sodium N-dodecanoyl-glycinate (Lau-Gly); -valinate (Lau-Val); -leucinate (Lau-Leu); and -phenylalaninate (Lau-Phe) as a function of NaCl using fluorescent probes (auramine; pyrene). The microviscosity increased with increasing concentration of NaCl and reached a saturated value. In addition; two breakpoints were found on the curve of microviscosity vs NaCl concentration and by comparison

8978556

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0.054572757, 0.019037314, -0.05273086, -0.06999206, 0.029680843, 0.004746172, 0.029417714, 0.046678916, -0.0027003514, 0.012255188, 0.056309402, -0.006456504, -0.033206757, 0.015813995, 0.019734602, -0.016761256, -0.009005557, -0.013551094, -0.0822012, -0.021813314, 0.026431212, -0.26944312, 0.00471657, 0.008038562, 0.02702325, -0.016734943, -0.0016453725, 0.078464784, -0.050257456, -0.044494953, 0.021892253, 0.0021527163, -0.0058381534, 0.04317931, 0.049994327, 0.029943971, 0.032996256, 0.02965453, -0.01744539, 0.03444346, 0.02266848, 0.038364068, -0.06878167, 0.20502937, 0.009933083, -0.044337075, 0.015471929, 0.06436112, -0.030996483, 0.004841556, 0.02482613, -0.021260746, 0.026917998, 0.042389926, -0.041442666, 0.08088556, 0.078885786, -0.04062697, -0.01843212, 0.028786208, 0.033706702, 0.06572939, -0.029286152, -0.07857003, -0.009130543, 0.07641238, -0.017063854, -0.023589429, -0.04920494, -0.0057033002, -0.0038022, -0.09314733, 0.016024498, 0.002047465, -0.032233186, -0.008827946, -0.005706589, -0.067413405, 0.07162345, 0.011689464, 0.017905863, -0.010051491, -0.01637972, -0.0020491097, 0.04625791, 0.04965226 ]

Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles

with the data of N and solution viscosity. The first and second breakpoints were explained; respectively; as the beginnings of micellar growth and intermicellar interaction. The value of N increased steeply above the first breakpoint and the solution viscosity began to increase at the second breakpoint. The NaCl concentrations at the first and second breakpoints increased in the order Lau-Phe < Lau-Leu < Lau-Val approximately Lau-Gly. The absolute value of the slope of the Corrin-Harkins plot of the cmc wa

8978556

[ -0.07404272, 0.011597454, -0.079951234, -0.012542283, -0.013354039, 0.00082215166, 0.039576393, 0.046709195, -0.00841697, 0.0012217914, 0.024525654, -0.07510732, 0.057594698, 0.028398126, 0.015662884, -0.00996729, 0.018856674, -0.028371511, -0.06004327, 0.017406162, 0.014052681, -0.03231052, 0.0031305805, -0.09714448, 0.07377657, -0.0071261465, -0.060149733, 0.021944007, -0.009288609, -0.24294104, 0.018750215, 0.04080068, 0.02291545, -0.055305816, -0.02171778, 0.035530925, 0.013520382, -0.03875133, -0.03462602, -0.0021924046, 0.041492667, 0.01137788, 0.008377048, 0.017871922, 0.021464938, -0.007625176, 0.0068666507, 0.006414197, 0.06424843, -0.011637376, 0.029702257, -0.035078473, 0.002202385, 0.03912394, -0.048013326, 0.010326591, -0.031485457, -0.012934853, -0.025324102, 0.02366067, 0.008935961, -0.015223738, -0.15064047, 0.072818436, 0.035797074, 0.063609675, -0.015103971, -0.015064048, 0.0033751053, 0.049290843, -0.045671213, 0.043914627, -0.0043082912, 0.01940228, 0.056210723, 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0.007532024, 0.02680123, 0.037101205, 0.058020536, 0.011843642, 0.010339899, 0.0091222655, 0.000278625, -0.0066271164, -0.03986916, -0.027945671, 0.010206824, 0.02444581, 0.09661218, -0.025310794, -0.025191028, -0.027054071, 0.021198789, 0.0022739128, -0.009049075, 0.035797074, 0.0032736359, 0.007824788, -0.047481027, 0.034226794, -0.016115338, 0.017246472, -0.010905466, -0.017419469, 0.013813146, 0.019176053, 0.032683127, 0.054507367, 0.043808166, 0.07010371, -0.034759093, -0.005123373, 0.017446084, 0.0059351283, 0.05583811, -0.08319826, -0.058180228, -0.002475188, 0.028770734, -0.00970114, -0.021039099, -0.033588037, 0.0019528702, -0.0032054351, 0.026787922, 0.05668979, 0.057541467, -0.0037560314, -0.0077116746, 0.055199355, 0.039736085, 0.030181326, -0.031405613, 0.0048871655, -0.008962576, -0.060362652, -0.027040765, -0.04069422, -0.06089495, -0.028078746, 0.05700917, 0.08016416, -0.02831828, 0.066750236, -0.014026065, 0.071913525, -0.025537021, -0.08138844, -0.29659674, -0.043062948, 0.030447476, -0.0285312, 0.12647413, -0.10347883, 0.06052234, 0.023500979, 0.033588037, -0.07925925, 0.063077375, 0.017659003, -0.031378996, -0.011544224, -0.027599677, -0.011364574, 0.0427968, 0.016873863, 0.038831174, 0.07100862, -0.0007256726, 0.027027456, -0.013420576, 0.06541949, 0.06712284, 0.015183815, 0.10566125, -0.010972003, -0.061640166, -0.016128644, -0.008383702, -0.0015677854, -0.049690064, -0.05791408, -0.034439713, 0.010180209, -0.0058552837, -0.031192692, 0.003742724, -0.006064876, -0.055518735, 0.009820907, 5.198228e-7, -0.074255645, -0.040481303, -0.0041253134, -0.005123373, 0.01883006, -0.008210705, -0.037207667, -0.00529637, 0.022928758, -0.012336018, -0.050940968, 0.022955373, -0.0066504045, -0.0068666507, -0.0486787, -0.0058386493, 0.028903808, -0.021983929, 0.036595523, 0.07984477, -0.039203785, -0.030926544, -0.002525091, 0.03587692, -0.005918494, -0.0063842554, 0.039203785, -0.02574994, 0.08287888, -0.046017207, 0.019907964, 0.019295821, 0.02569671, -0.039895773, -0.06275799, -0.028131977, 0.012422516, -0.012449131, -0.026668156, 0.05738178, 0.004451346, 0.021265326, 0.026841152, -0.0043448866, -0.05748824, -0.0007730804, -0.007352373, 0.014744668, -0.007784866, -0.03129915, -0.035051856, -0.028504586, 0.018696984, -0.2953192, 0.024658728, 0.008317164, 0.06653731, 0.014119218, 0.051420037, 0.041093446, -0.03848518, -0.055891342, 0.063077375, -0.045857515, -0.0063776015, 0.026548387, 0.0068932655, 0.048971463, 0.008709734, 0.024352657, -0.05176603, -0.0026465217, 0.023926819, 0.041279748, -0.024778496, 0.17320994, 0.044367082, -0.029755486, 0.026495159, 0.039949004, -0.015915725, -0.022356538, -0.010965349, -0.008656505, 0.06398228, 0.034812324, -0.034067106, 0.05248463, 0.08628559, -0.046815652, -0.016754096, 0.0025300814, 0.049556993, 0.06398228, 0.0076717525, -0.097570315, -0.022649301, 0.12423847, -0.04599059, -0.027107302, -0.03550431, 0.022103695, -0.00061754946, -0.02596286, -0.003117273, 0.007838096, -0.0010687556, 0.03172499, -0.0025932917, -0.028930424, 0.017525928, 0.0019961195, -0.0008150821, 0.05770116, -0.02029388, -0.02821182, 0.00089825375, 0.07697036 ]

[ -0.07398999, 0.01157757, -0.07995177, -0.012509098, -0.013360782, 0.00085750537, 0.039550044, 0.04673612, -0.008403719, 0.0011660742, 0.024499202, -0.07510782, 0.057595085, 0.028345086, 0.01564968, -0.009914126, 0.018843494, -0.028371701, -0.060096905, 0.017379662, 0.014012852, -0.032337353, 0.0031256112, -0.097145125, 0.073777065, -0.007179424, -0.060203366, 0.021970768, -0.009308632, -0.24294266, 0.018763648, 0.040854186, 0.022955528, -0.055252954, -0.021704618, 0.035477933, 0.013467243, -0.03875159, -0.03462625, -0.0021325352, 0.041546177, 0.011391264, 0.008403719, 0.017898656, 0.021465082, -0.007658496, 0.0068467353, 0.0064308746, 0.06419563, -0.011637454, 0.029675841, -0.035078708, 0.002222361, 0.03909759, -0.048013646, 0.010359929, -0.031538896, -0.012875057, -0.025350885, 0.023674134, 0.008909406, -0.015197224, -0.15064149, 0.072872154, 0.0357707, 0.0636101, -0.015064148, -0.0150508415, 0.003390099, 0.04929117, -0.045698132, 0.043941535, -0.0042617433, 0.01940241, 0.0562111, 0.0014979313, -0.07409645, 0.04391492, -0.0053895586, 0.0020842953, 0.03545132, -0.052165605, -0.0051832916, -0.079259776, -0.025111351, -0.011291457, 0.0076851114, 0.020427093, 0.041546177, -0.05919199, 0.025803342, -0.06142766, -0.01668767, 0.0019645274, -0.012083257, 0.054614194, 0.0069066193, -0.03984281, 0.014318926, 0.3862384, -0.05413512, -0.013826546, -0.071328476, -0.0036762112, 0.00967459, 0.027160713, 0.026934486, 0.008663217, 0.06930573, -0.029276613, 0.0431697, 0.0111583825, -0.016261829, -0.05594495, -0.066857144, 0.0063044527, 0.09698544, -0.0794727, -0.014651614, 0.012063296, -0.028025704, -0.024805278, 0.014931073, -0.033135805, -0.014358848, 0.028957233, -0.012722019, 0.0124159455, 0.04745473, -0.017925272, 0.012735327, -0.027333712, -0.0007402326, -0.02408667, 0.023101911, -0.024339512, 0.01825796, -0.013959622, 0.0070796176, 0.034227025, -0.035211783, -0.03593039, -0.035983622, -0.07532074, 0.008643255, 0.039496813, 0.0076451884, -0.019801637, 0.019868175, 0.0003245795, 0.007512113, 0.026774794, 0.037101455, 0.058020927, 0.011830414, 0.010359929, 0.009109019, 0.00031439093, -0.006627161, -0.039816193, -0.027919244, 0.010246815, 0.024432665, 0.09666605, -0.025284348, -0.025257733, -0.027054252, 0.021185622, 0.002243986, -0.009062443, 0.03582393, 0.0033052631, 0.007784918, -0.047534574, 0.03425364, -0.01608883, 0.017246587, -0.010885578, -0.017432893, 0.013826546, 0.01918949, 0.032656733, 0.054507732, 0.04386169, 0.070157416, -0.034759324, -0.0051832916, 0.017419586, 0.005931841, 0.055838488, -0.08330528, -0.058180615, -0.002536752, 0.028744312, -0.009687898, -0.021052547, -0.033561647, 0.0019794984, -0.0032137737, 0.026814718, 0.056796633, 0.057488624, -0.0037494027, -0.0076984186, 0.055199724, 0.039762966, 0.030208142, -0.031379208, 0.004953736, -0.008962636, -0.060363054, -0.027080867, -0.040667877, -0.060895357, -0.028078934, 0.05700955, 0.08011146, -0.028291855, 0.06680391, -0.014026159, 0.07186078, -0.025510577, -0.08138899, -0.2965987, -0.04308985, 0.030447679, -0.028504776, 0.12647498, -0.103532754, 0.060469516, 0.023461213, 0.033614878, -0.07920655, 0.06307779, 0.017672429, -0.031325977, -0.01152434, -0.027573247, -0.011377957, 0.042876933, 0.016860668, 0.038831435, 0.07106233, -0.0007477181, 0.027080867, -0.013473896, 0.065313466, 0.067123294, 0.015157302, 0.10566196, -0.011005346, -0.06169381, -0.016128752, -0.008330528, -0.0015727862, -0.049717013, -0.057914466, -0.03441333, 0.010173623, -0.0058453423, -0.031219516, 0.0037194607, -0.0060981857, -0.05557234, 0.009860896, -0.0000036972642, -0.07425614, -0.04050819, -0.0041319947, -0.0050834846, 0.018816879, -0.008237375, -0.037207916, -0.0053596166, 0.022875682, -0.0123361, -0.050941307, 0.022915604, -0.006623834, -0.006860043, -0.048732255, -0.0058653033, 0.028930617, -0.021970768, 0.03654254, 0.07979208, -0.039177433, -0.030953366, -0.0025134638, 0.035903774, -0.0059185335, -0.006410913, 0.039230663, -0.025803342, 0.08287943, -0.046017513, 0.019881483, 0.019269336, 0.025723498, -0.03989604, -0.062758416, -0.02815878, 0.0124226, -0.0124159455, -0.026668334, 0.057435393, 0.004487972, 0.021225546, 0.026814718, -0.0043382617, -0.057488624, -0.0007485498, -0.007325807, 0.014744768, -0.007811533, -0.031325977, -0.03499886, -0.028504776, 0.018723726, -0.2953212, 0.02468551, 0.008330528, 0.06659099, 0.014159235, 0.051446997, 0.04114695, -0.03843221, -0.05589172, 0.063024566, -0.045857824, -0.0063776444, 0.026575182, 0.0068866583, 0.04897179, 0.008696485, 0.02440605, -0.05173976, -0.0026531932, 0.023993516, 0.04125341, -0.024791969, 0.17331755, 0.044393994, -0.0297823, 0.026495336, 0.03989604, -0.015942447, -0.022356687, -0.010945462, -0.008636601, 0.06398271, 0.034839172, -0.034120563, 0.052484985, 0.086286165, -0.04678935, -0.01679413, 0.0024868487, 0.04963717, 0.063929476, 0.0076451884, -0.09767743, -0.022596223, 0.1242393, -0.046017513, -0.027094176, -0.03550455, 0.022090536, -0.0006321087, -0.025976341, -0.0031588802, 0.007844802, -0.0010729213, 0.03175182, -0.0025933092, -0.028930617, 0.017539354, 0.001989479, -0.00078306627, 0.057701543, -0.020320632, -0.02821201, 0.0009182211, 0.07702411 ]

Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles

s smaller for Lau-Leu and -Phe than for Lau-Gly and -Val. Larger absolute values of the slope (1.2 approximately 2); which suggested the contribution of a salting out effect on cmc; were observed at high NaCl concentration for Lau-Gly and -Val. The micellar growth and intermicellar interaction occurred at lower NaCl concentration with increased size of the amino acid residue when the amino acid of the amino acid surfactant was larger than valine; that is; the hydrophobicity of the amino acid residue was the

8978556

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Effect of NaCl on Aggregation Number, Microviscosity, and Cmc of N-Dodecanoyl Amino Acid Surfactant Micelles

dominant factor rather than steric hindrance.

8978556

[ -0.04345734, 0.03816874, 0.056198064, -0.005866207, 0.019765478, -0.03288014, 0.007485507, -0.032212388, -0.06917918, -0.03782151, -0.030476231, -0.07446778, -0.049386986, 0.05040197, -0.033788282, 0.02122118, 0.015024435, 0.03280001, -0.06255507, -0.03504366, 0.04989448, 0.007011403, -0.011091371, -0.07142282, 0.015064499, 0.009361892, -0.019097725, -0.069659956, -0.026389584, -0.18194924, 0.050882753, -0.038783073, 0.0021368084, -0.058869075, -0.027858641, -0.0061700344, -0.03274659, 0.05748015, -0.04770425, -0.023010757, 0.02796548, 0.0075656376, 0.016066128, -0.0150778545, 0.008273455, -0.032212388, 0.031838447, -0.0034789913, 0.066347905, 0.02610913, 0.062448226, -0.0036292356, 0.014837463, -0.033734865, -0.026870366, 0.005552363, 0.06848471, 0.0123934895, 0.07291859, 0.012346746, 0.046502296, 0.039450828, -0.14968343, 0.004867917, 0.10315443, 0.04842542, -0.028633233, -0.060311418, 0.029114015, -0.0055590407, 0.03819545, 0.023304567, 0.06410425, 0.06511924, -0.017321503, 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Zeta Potential Measurements on Three Clays from Turkey and Effects of Clays on Coal Flotation

There is a growing trend of characterizing coal and coal wastes in order to study the effect of clays present in them during coal washing. Coarse wastes from the Zonguldak Coal Washery; Turkey; were characterized and found to contain kaolinite; illite; and chlorite. These three clays; obtained in almost pure form from various locations in Turkey; have been subjected to X-ray diffraction (XRD) analysis to assess their purity and zeta potential measurements in order to evaluate their properties in terms of th

8978557

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Zeta Potential Measurements on Three Clays from Turkey and Effects of Clays on Coal Flotation

eir surface charge and point of zero charge (pzc) values. It was found from XRD data that these clays were almost pure and their electrokinetic potential should therefore be representative of their colloidal behavior. All three clay minerals were negatively charged over the range from pH 2.5 to 11. Chlorite and illite have pzc at pH 3 and pH 2.5; respectively; whereas kaolinite has no pzc. The effect of these clays in Zonguldak coal; wastes; and black waters on coal flotation was studied by floating artific

8978557

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-0.012478917, 0.052065145, -0.03378131, -0.0013425947, 0.043573376, -0.0041496875, 0.017301975, -0.05248973, -0.026855212, 0.06750955, 0.009460359 ]

Zeta Potential Measurements on Three Clays from Turkey and Effects of Clays on Coal Flotation

ial mixtures of Zonguldak clean coal (4.5% ash) and individual clay. The flotation tests on coal/individual clay revealed that each clay influences coal flotation differently according to its type and amount. Illite had the worst effect on coal floated; followed by chlorite and kaolinite. The loss of yield in coal was found to be 18% for kaolinite; 20% for chlorite; and 28% for illite; indicating the worst effect of illite and least for kaolinite during coal flotation.

8978557

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The Conductivity Confined Temperature Dependence of Water-Free Electrorheological Fluids

The shear stresses and the current densities of four sorts of water-free ER fluids; two oxidized polyacrylonitriles-based and two aluminosilicates-based; were investigated at elevated and reduced temperatures in order to elucidate the operating mechanism. The complicated relationships among the mechanical properties; the current density; and temperature were especially addressed. The Wagner model was introduced to interpret our observations; instead of the commonly used conductivity model. It is found that

8978558

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The Conductivity Confined Temperature Dependence of Water-Free Electrorheological Fluids

the conductivity of the dispersed particles determines the temperature dependence of the shear stress and the current density of an ER fluid. Our findings have direct implication for the design of industrially required ER fluids and would be significant for ER applications.

8978558

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Surface Tension of Aqueous Solutions of Electrolytes: Relationship with Ion Hydration, Oxygen Solubility, and Bubble Coalescence

The surface tension of aqueous solutions of simple inorganic electrolytes (36 in total) have been measured by the maximum bubble pressure method as a function of electrolyte concentration up to 1 M. In most cases the surface tension increased; however in a minority of cases; certain combinations of cations and anions had a negligible effect or decreased surface tension. Results were analysed in terms of surface tension/electrolyte concentration gradients (d(Deltagamma)/dc) and this parameter was found to co

8978559

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Surface Tension of Aqueous Solutions of Electrolytes: Relationship with Ion Hydration, Oxygen Solubility, and Bubble Coalescence

rrelate with the entropies of ion hydration; Jones-Dole viscosity coefficients and dissolved oxygen gradients. Calculation of Gibbs surface deficiencies for selected electrolytes were carried out using the raw surface tension data. Discussion of the surface tension/electrolyte concentration gradients was extended to the mechanism of inhibition of bubble coalescence by electrolytes. The Gibbs-Marangoni effect did not provide a satisfactory explanation for the inhibition of coalescence for all electrolytes an

8978559

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Surface Tension of Aqueous Solutions of Electrolytes: Relationship with Ion Hydration, Oxygen Solubility, and Bubble Coalescence

d from the present study we suggest that dissolved gas (microbubble) gradients between macroscopic bubbles plays an important role in the coalescence process.

8978559

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Anomalous Adsorption of Copper(II) on Goethite

The adsorption of copper(II) onto goethite is qualitatively different from that of other metal-mineral systems. At pH 5.0 the adsorption isotherms are sigmoid rather than hyperbolic; and the corresponding graphs of C/N versus C (where C is concentration and N adsorption density) have distinct minima. At pH 5.5 the isotherms have the more usual shape. The experimental data can be fitted by a model in which monomeric CuOH+ and dimeric Cu2(OH)2+2 compete for surface sites; the dimer adsorbing more strongly to

8978560

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Anomalous Adsorption of Copper(II) on Goethite

the surface. As the concentration increases the proportion of the dimeric species increases; which leads to enhanced adsorption. At pH 5.5 adsorption of the monomer is sufficiently strong that normal behavior is observed at low concentrations; before there is sufficient dimer to compete effectively for sites. Data are presented for adsorption of Cu(II) to goethite at pH 5.0 and pH 5.5; at temperatures between 25 and 70°C. Adsorption is endothermic for both monomer and dimer. Enthalpies of adsorption ran

8978560

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Anomalous Adsorption of Copper(II) on Goethite

ge from 50 to 91 kJ mol-1; and entropies from 240 to 470 J K-1 mol-1.

8978560

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Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles

The interface polarity of benzyl-n-hexadecyldimethylammonium chloride (BHDC) cationic reversed micelles in benzene was studied and compared with those of the anionic systems of sodium 1;4-bis-2-ethylhexylsulfosuccinate (AOT) in benzene and hexane. The nonionic reversed micelles of the poly(oxyethylene)n dodecyl ethers type surfactants Brij 30 in benzene; cyclohexane; and decane and C12E5 in hexane; heptane; and decane were also investigated. 1-Methyl-8-oxyquinolinium betaine (QB) was used as optical probe.

8978561

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0.038073745, -0.091865525, 0.039879195, -0.009093625, 0.012857191, 0.044552125, 0.06733265, -0.0036440876, 0.03302911, 0.045746908 ]

Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles

The influence of surfactant concentration and W = [H2O]/[surfactant] were analyzed as a function of the absorption bands shifts in the visible; B1; and in the UV; B2; and the absorbances ratio of these bands. At W = 0 the polarity sensed in the micelle interfaces of AOT-hexane and AOT-benzene is entirely similar while for BHDC-benzene is quite smaller. The detected interaction between the QB and BHDC may favor the entrance of QB into the oil side of the micelle interface thus sensing a less polar environmen

8978561

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Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles

t. At W >/= 10 once the polar heads of the surfactants are completed hydrated; the anionic as well as the cationic surfactants show the same behavior. The polarity of Brij 30 and C12E5 in the aliphatic hydrocarbons is comparable. However at W = 0 their micropolarity is higher than that of AOT-hexane; showing that the formation of hydrogen bond between QB and the free OH groups of these surfactants is the major factor affecting the microenvironment. In all the studied systems even at the maximum possible W;

8978561

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Micropolarity of Reversed Micelles: Comparison between Anionic, Cationic, and Nonionic Reversed Micelles

the polarity sensed by QB never reaches the value of pure water; that is; never reaches the bulk water phase prevailing in the micellar core.

8978561

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Micromechanics: A New Approach to Studying the Strength and Breakup of Flocs

Micromechanical techniques were developed to pull apart single floc particles 6 to 40 μm in size in order to measure floc strengths and fractal dimensions. Flocs were formed by aggregating aqueous precipitated calcium carbonate sols with two water-soluble polymers. The tensile strengths ranged from 20 to 200 nN and showed no correlation with floc sizes when plotted on logarithmic scales. Flocs created by the two flocculant systems were found to have fractal dimensions of 1.8 and 2.4 based on analysis of

8978562

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Micromechanics: A New Approach to Studying the Strength and Breakup of Flocs

fragment sizes. The compact flocs favored breakup by surface erosion; whereas flocs characterized by the lower fractal dimension tended to undergo large scale fragmentation. Comparison of the two polymeric flocculants revealed that both the fractal dimension and the tendency for ruptured fragments to reflocculate were sensitive to the polymer used.

8978562

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-0.07557861, 0.053188838, -0.03765791, -0.027198838, 0.09786326, -0.031929072, 0.024557792, -0.011221163, 0.039497443, 0.0014560248, 0.0012802834, 0.040863954, -0.007864012, 0.023874536, -0.015097327, 0.00018179779, -0.03311163, -0.021351745, 0.021667093, -0.017423024, -0.3124056, 0.029931862, -0.050376978, 0.023782559, -0.022954768, 0.08020373, 0.029563954, 0.021430582, -0.07279303, -0.038104653, 0.009499884, 0.04278233, 0.019131163, -0.006438372, -0.023572326, 0.0000922847, 0.046540234, -0.019328257, 0.0095524425, -0.07006, 0.038341165, 0.09470977, 0.15536186, -0.034399305, 0.009953198, -0.0062379944, -0.024951978, 0.06653861, -0.052190233, 0.000042549513, 0.030457443, 0.009887501, 0.072109774, -0.011681047, -0.013047558, 0.05176977, -0.020497676, 0.018290233, 0.011556221, -0.0068259886, -0.0013607631, -0.038367443, -0.026265932, 0.030851629, 0.09528791, 0.05918047, 0.007988838, 0.00081670424, -0.010859826, 0.00410282, 0.045489073, -0.049325816, 0.004996308, 0.039129537, 0.023440931, -0.0010897602, -0.008429012, 0.057866514, 0.036685582, -0.0774707, -0.05886512, -0.06438372, 0.06963954, -0.011924128, 0.0334007 ]

Characterization of Silylated Silicas by Inverse Gas Chromatography: Modelization of the Poly(dimethylsiloxane) Monomer Unit/Surface Interactions Using Poly(dimethylsiloxane) Oligomers as Probes

Inverse gas chromatography (IGC) at infinite dilution was used to characterize the fumed silica surface. The silica was modified by chemical treatment with either dimethyldichlorosilane or trimethylchlorosilane. To observe the silica and poly(dimethylsiloxane) (PDMS) interactions; we used apolar (alkanes) and polar probes (chloroform; benzene; tetrahydrofuran; etc.); but also model molecules of PDMS such as linear and cyclic oligomers of PDMS with two to five monomer units. It is shown that PDMS oligomers a

8978563

[ -0.075964145, -0.0051218853, -0.040471833, -0.031148478, -0.017335612, -0.0039200466, 0.047225967, 0.061290458, -0.01791832, -0.031280912, -0.014753148, -0.095776275, 0.028897101, 0.0005198035, 0.03959777, -0.0025923958, 0.051861156, -0.018951306, -0.082373954, 0.028393852, 0.06303859, -0.040471833, -0.016421817, -0.037055034, 0.09365733, 0.02558625, 0.017825617, 0.0483649, -0.080784746, -0.2163442, -0.022964057, -0.07940743, 0.009753765, 0.010362961, 0.018289136, 0.062085062, 0.030433334, -0.059171513, 0.011071483, 0.019136714, 0.02807601, 0.03941236, -0.033240937, 0.014501524, 0.0026983428, -0.0023656024, -0.031492807, 0.00044944792, 0.079036616, 0.029426835, 0.026076255, 0.027890602, 0.003953155, 0.088783756, -0.011104591, -0.035863128, -0.0036982195, -0.039306413, 0.023970556, 0.04719948, -0.0024003664, 0.030433334, -0.12840801, 0.1272426, 0.030618742, 0.04158428, 0.04264375, -0.040206965, 0.06558132, 0.056522835, -0.032340385, 0.07320952, -0.026354367, 0.008972404, 0.02418245, -0.02301703, -0.010621208, -0.017971294, 0.037319902, 0.038220454, -0.0044497824, 0.012879207, 0.03708152, -0.033850133, -0.01962672, 0.021215929, -0.008621454, -0.004290862, 0.043835655, 0.048921123, 0.0053569553, -0.08014906, -0.06017801, 0.042458344, -0.043650247, 0.0014898826, -0.07162031, -0.035624746, 0.03313499, 0.3981496, -0.0035260555, 0.010389448, 0.016170193, -0.038935598, -0.048258953, -0.0021950935, 0.024076503, 0.027016537, 0.0010917528, 0.042749695, -0.0028324323, 0.026314637, -0.008786996, -0.07379223, -0.015799377, -0.0063270344, 0.03567772, -0.059754223, 0.014594227, 0.05090763, -0.023917582, 0.010568234, 0.009363084, -0.024659213, 0.021255659, 0.020010779, 0.035783667, 0.058217987, 0.03716098, -0.0078069847, 0.006721026, 0.019282391, -0.06383319, -0.024513535, -0.0028522974, 0.02464597, 0.008687671, -0.025533276, 0.06770027, 0.0017878591, -0.010290123, 0.0005417379, -0.08523453, -0.10705965, -0.017746156, 0.05149034, -0.011131078, 0.04770273, -0.05048384, -0.0758582, 0.016130462, 0.078718774, 0.0022795203, -0.002110667, 0.028393852, -0.011316486, -0.038220454, 0.007442791, 0.012276633, -0.02955927, -0.061502352, -0.015825864, -0.0030741245, 0.113257565, -0.0024003664, -0.01519018, -0.045107022, -0.053556312, 0.012952046, 0.030565768, 0.0016372154, 0.01966645, -0.026010038, -0.07320952, -0.011005266, 0.010958914, -0.012647447, -0.011806492, -0.012051495, -0.033108503, -0.023573253, 0.013455295, -0.03146632, 0.034167975, 0.030936584, -0.050536815, -0.021043764, 0.031360373, -0.048232466, 0.01378638, -0.071302466, 0.013170562, -0.07426899, 0.02865872, -0.0692365, 0.0039399117, -0.039068032, 0.013627459, -0.0634094, -0.034883115, 0.06383319, -0.014210169, -0.013627459, 0.042908616, 0.037717205, 0.04272321, 0.003982953, 0.076387934, 0.08417506, 0.068124056, -0.031519294, 0.025400842, -0.07209707, -0.056416888, -0.0025957066, 0.0019318811, 0.034115, -0.015176937, 0.08099664, -0.03305553, 0.033505805, -0.025030028, -0.06589916, -0.30915394, -0.008349964, 0.01436909, 0.0075686034, 0.09106162, -0.04248483, -0.026513288, 0.01515045, 0.023904338, -0.037690718, 0.0987428, 0.018527517, -0.02815547, -0.009084973, 0.007853337, 0.018606978, 0.024050016, -0.04065724, -0.0041451845, 0.006078721, 0.035969075, 0.035624746, 0.003006252, 0.06987218, 0.08131448, -0.011501893, 0.11368135, -0.021215929, -0.034009054, 0.01677939, 0.020672949, 0.020434568, -0.023427576, -0.04057778, -0.04870923, -0.025652466, 0.00014205616, 0.0054629026, 0.017825617, -0.023838121, 0.0032744308, 0.052973602, -0.00041613248, -0.03525393, -0.024328128, 0.006668052, 0.0025725306, -0.0058469614, -0.07220302, -0.0065058204, 0.08104961, -0.036392864, -0.004909991, -0.027334379, 0.023348115, -0.093869224, 0.011753518, -0.012958667, -0.047835164, 0.02702978, -0.020884844, 0.010760263, 0.036048535, -0.005522498, -0.06076072, 0.025109489, 0.017653452, 0.0019136714, 0.01090594, -0.005267563, 0.0051417504, 0.06902461, 0.017176691, 0.01697804, 0.055463362, 0.017666696, -0.004131941, -0.020156456, -0.022884596, -0.006098586, 0.061290458, -0.01896455, 0.027784655, -0.031174965, 0.037293416, 0.060389906, 0.010819858, -0.026513288, 0.0118793305, 0.031784162, -0.023944069, -0.023454063, -0.07151436, -0.01970618, 0.009349841, 0.01958699, -0.27397949, 0.03599556, 0.055251468, 0.04820598, -0.061290458, -0.00017413002, 0.011329729, 0.007926175, -0.025334625, 0.018805629, -0.018037511, 0.020487541, 0.056522835, 0.057794202, -0.0327112, 0.026301393, -0.010925805, -0.0028837505, -0.019454556, -0.04084265, 0.021176198, -0.01207136, 0.15245803, -0.033664726, -0.007760633, 0.059383407, -0.021215929, 0.022129722, -0.06351535, -0.009806738, 0.07601712, 0.014978286, 0.016527764, 0.0075487383, 0.033108503, 0.028870614, 0.012455419, -0.023083247, -0.03453879, -0.021984044, 0.03313499, -0.055251468, -0.032525793, -0.059966117, 0.01179987, -0.061979115, -0.0011985278, -0.0065687266, 0.027201945, -0.05040438, -0.01144892, 0.030168466, 0.0229773, -0.016580738, 0.023944069, -0.010568234, -0.0037511932, -0.017507775, -0.057423387, -0.000679552, 0.053450365, 0.017693182, -0.04142536, -0.018911576, 0.05172872 ]

[ -0.07591207, -0.0050755935, -0.040392853, -0.031148849, -0.017375547, -0.0039300257, 0.047173552, 0.061291188, -0.017958265, -0.031281285, -0.01474008, -0.09588336, 0.028897444, 0.0005380195, 0.03957175, -0.0025626284, 0.05188826, -0.018925045, -0.08237493, 0.028394189, 0.06309231, -0.040472314, -0.016408768, -0.037055474, 0.09371141, 0.025546823, 0.017786099, 0.048365474, -0.08083868, -0.21655867, -0.022951085, -0.0793554, 0.009780368, 0.010363084, 0.018249623, 0.0620858, 0.030433696, -0.059172217, 0.011071615, 0.019110454, 0.028129317, 0.039386343, -0.03324133, 0.014501696, 0.002653678, -0.002378874, -0.03149318, 0.00048587302, 0.079037555, 0.029453672, 0.026063323, 0.02791742, 0.0039664456, 0.08883779, -0.011144454, -0.03591653, -0.00368502, -0.03930688, 0.02397084, 0.04720004, -0.0023705969, 0.030433696, -0.12840953, 0.1272441, 0.030566132, 0.04158477, 0.042697232, -0.04023393, 0.06552912, 0.056523506, -0.032314282, 0.073157415, -0.026367923, 0.008959267, 0.024169493, -0.02300406, -0.01060809, -0.017997995, 0.03729386, 0.038247395, -0.0044001723, 0.0128793605, 0.037134938, -0.033850536, -0.019587222, 0.021189693, -0.00867453, -0.0042379387, 0.043756716, 0.048921704, 0.005333843, -0.080150016, -0.060178727, 0.042458847, -0.04359779, 0.001425338, -0.07156819, -0.035651658, 0.033188358, 0.39815432, -0.0035260974, 0.0104028145, 0.016157141, -0.038909573, -0.048259526, -0.0022663039, 0.024103276, 0.027069833, 0.0010975598, 0.042750206, -0.0028804739, 0.026341436, -0.008727505, -0.07389905, -0.015852539, -0.006294001, 0.03570463, -0.059754934, 0.014607645, 0.05088175, -0.023931108, 0.0105551155, 0.0094360355, -0.024646262, 0.021242667, 0.019997772, 0.03583707, 0.05821868, 0.03718791, -0.0078070774, 0.0067277276, 0.01928262, -0.06383395, -0.02452707, -0.0028341215, 0.024646262, 0.0086480435, -0.02553358, 0.06770107, 0.0017779476, -0.010277001, 0.0005748532, -0.085235536, -0.107060924, -0.017746368, 0.051385004, -0.011084858, 0.047703296, -0.05051093, -0.0758591, 0.016143898, 0.078719705, 0.0022530602, -0.002114003, 0.028447162, -0.011356351, -0.038141448, 0.0074561234, 0.012303266, -0.029533135, -0.061503083, -0.015852539, -0.0030774719, 0.113258906, -0.002382185, -0.015190361, -0.045160532, -0.05355695, 0.012892604, 0.030539645, 0.0016926923, 0.01965344, -0.026023591, -0.07326336, -0.011071615, 0.010919314, -0.012700572, -0.011852984, -0.012084747, -0.033082407, -0.02360002, 0.013521673, -0.03149318, 0.034194868, 0.030883977, -0.050590392, -0.021057257, 0.031360745, -0.048286013, 0.013760056, -0.071303315, 0.0132303145, -0.07432285, 0.028659059, -0.06918435, 0.0039664456, -0.03912147, 0.013601134, -0.06346313, -0.03491002, 0.06383395, -0.014263312, -0.013627621, 0.04288264, 0.037691165, 0.04272372, 0.004026042, 0.07638884, 0.08412308, 0.068177834, -0.031519666, 0.025414389, -0.07209793, -0.056470532, -0.002549385, 0.0018623753, 0.03416838, -0.015177118, 0.0809976, -0.033002947, 0.033479713, -0.025043568, -0.06584697, -0.3091576, -0.0082970895, 0.014382504, 0.0075951805, 0.0910627, -0.042458847, -0.026460629, 0.01515063, 0.023851648, -0.037691165, 0.098690994, 0.018435033, -0.028129317, -0.009058594, 0.007840186, 0.018580712, 0.023997327, -0.04068421, -0.0040922593, 0.0061317673, 0.036022477, 0.03562517, 0.003041052, 0.06997896, 0.081209496, -0.011535139, 0.1136827, -0.021269154, -0.033956483, 0.016792832, 0.020606976, 0.020461297, -0.023454342, -0.040631235, -0.048709806, -0.025705745, 0.00013409102, 0.0054033715, 0.017852316, -0.023785431, 0.0033886954, 0.05297423, -0.00047304333, -0.03525435, -0.024288686, 0.0066284006, 0.002617258, -0.005837098, -0.072203875, -0.0065224525, 0.081050575, -0.036419783, -0.004886873, -0.02736119, 0.023348393, -0.09387034, 0.01168744, -0.012972065, -0.047862217, 0.02699037, -0.020898335, 0.010773635, 0.036101937, -0.0055358075, -0.060655497, 0.025096543, 0.01768015, 0.0019186605, 0.010952422, -0.005214651, 0.0051682987, 0.06902543, 0.017137164, 0.016991485, 0.05541105, 0.017666906, -0.0041187466, -0.020169938, -0.022911355, -0.0060986583, 0.061291188, -0.018991262, 0.027811471, -0.031175336, 0.037346832, 0.060390625, 0.010872961, -0.026487116, 0.011879471, 0.03175805, -0.023944354, -0.023401367, -0.07151521, -0.019732902, 0.009356574, 0.01957398, -0.27377084, 0.036022477, 0.055252124, 0.048206553, -0.06134416, -0.00019772218, 0.011316621, 0.007939513, -0.025334926, 0.018792609, -0.017997995, 0.020514272, 0.056523506, 0.057741914, -0.032658614, 0.026288463, -0.010886204, -0.0028092898, -0.019401813, -0.04086962, 0.02117645, -0.012084747, 0.15245984, -0.033638638, -0.0077209943, 0.05933114, -0.02121618, 0.022116741, -0.06356908, -0.009780368, 0.07601802, 0.0150049515, 0.01652796, 0.007575315, 0.033108894, 0.02884447, 0.012501919, -0.023083521, -0.0345392, -0.021971062, 0.03313538, -0.05519915, -0.032552667, -0.059913855, 0.011833119, -0.061979853, -0.0012001975, -0.0065721157, 0.027202267, -0.050352007, -0.011415947, 0.030142337, 0.022924598, -0.016607422, 0.023878135, -0.010548494, -0.0037611704, -0.01749474, -0.05742407, -0.0006729383, 0.05342451, 0.017746368, -0.041399363, -0.019017749, 0.05178231 ]

Characterization of Silylated Silicas by Inverse Gas Chromatography: Modelization of the Poly(dimethylsiloxane) Monomer Unit/Surface Interactions Using Poly(dimethylsiloxane) Oligomers as Probes

re very appropriate to discriminate the silylated silicas.

8978563

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Measurement of Interaction Forces between Silica and alpha-Alumina by Atomic Force Microscopy

Interaction forces between a silica sphere and an alpha-alumina substrate at various pH values were measured by atomic force microscopy (AFM). As expected; at pH values of 10.8 and 10.2 when the surfaces are similarly charged; a repulsive force was observed. On the other hand; at pH values of 5.5; 6.4; and 8.6 when the surfaces are oppositely charged; attractive forces were observed. Experimental force vs separation distance curves were found to be in good agreement with theoretical predictions based on ele

8978564

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Measurement of Interaction Forces between Silica and alpha-Alumina by Atomic Force Microscopy

ctrostatic and van der Waals interactions. Interestingly; when the force/radius values at a particular separation distance were plotted against pH; the transition from an attractive to a repulsive force occurred at pH 9.3; which is very close to the point of zero charge (pzc) of alpha-alumina as determined from electrophoresis experiments. These results suggest that AFM force measurements can be used to estimate the pzc of materials. This method may be of particular significance for soluble salt minerals wh

8978564

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Measurement of Interaction Forces between Silica and alpha-Alumina by Atomic Force Microscopy

ere conventional electrophoretic measurements are not possible at high ionic strengths. Finally; results from transmittance studies further confirmed the interaction between silica and alpha alumina particles in suspensions at various pH values as would be expected based on the results from atomic force microscopy measurements.

8978564

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0.015923068, 0.032832168, 0.018001728, -0.008161405, 0.018468093, 0.013604563, 0.034111343, 0.061933406, -0.0048002386, -0.02151946, 0.04458459, 0.050021086 ]

Apparent Dipole Moments of Aerosol OT Reversed Micelles in Cyclohexane Determined at a Frequency of 1 MHz and at a Temperature of 298.15 K

Precise determinations of dielectric constants were carried out for Aerosol OT reversed micelles in cyclohexane at a frequency of 1 MHz and at a temperature of 298.15 K for molalities of AOT from 0 to 0.04 mol kg-1. The ratio of the amount of water; r; to that of AOT was varied from 0 to 25 and the apparent dipole moments for the mixed solute (AOT + r·H2O) were calculated. Discontinuous change in the limiting dipole moment with increasing r was found and was related to the characteristic of water to

8978565

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0.029245142, 0.0075638574, -0.0068526687, 0.035439797, 0.024725439, 0.015659444, 0.03496124, -0.042272523, -0.02682577, 0.03009591, 0.048945732 ]

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0.01298796, -0.013120897, -0.029166412, 0.016337976, 0.0026869923, -0.010442214, 0.036291845, 0.014304038, 0.027996566, -0.026547551, -0.022984834, -0.00822881, -0.0243275, -0.010681501, 0.062374115, -0.03217079, -0.007617299, 0.03445731, 0.0053739846, 0.008321866, 0.032436665, 0.016989369, 0.0037554747, 0.009697766, 0.33074763, -0.07077574, 0.052802637, 0.026840013, -0.058970924, -0.010654913, 0.012535973, -0.040599007, -0.045304984, 0.016324682, 0.0015445636, 0.058545522, -0.020831253, -0.0048920875, -0.076731324, -0.04325775, -0.05891775, -0.031027533, -0.024460437, -0.08284643, -0.01717548, 0.01753441, 0.038046613, 0.013280422, -0.010847672, 0.0036125672, 0.00892673, -0.054504234, 0.08295278, 0.06497968, -0.029325936, -0.033925563, -0.018052867, -0.018159216, -0.04027996, -0.017986398, 0.027385054, 0.029485462, -0.068276525, 0.0022433146, 0.03137317, -0.02081796, -0.011632001, -0.034324374, -0.10241479, -0.00249091, 0.11262436, -0.004616243, 0.04626213, -0.0241148, -0.014915549, 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0.032729127, -0.036212083, 0.093587756, -0.04772444, 0.032117616, 0.005639859, 0.012369802, -0.078539275, 0.117303744, 0.011977638, 0.049133573, -0.041954968, -0.028820775, -0.0040180255, 0.011293012, -0.0217884, 0.015846109, 0.052829225, -0.01681655, -0.048468888, -0.029485462, -0.047671266, 0.021509232, 0.032436665, 0.07492338, -0.025590403, -0.013466534, -0.031745393, 0.06779795, 0.05112763, -0.001914295, -0.029325936, -0.036265258, -0.044135135, 0.027517991, -0.05663123, -0.046501417, -0.011326246, 0.011685176, -0.020312797, -0.0151681295, -0.03323429, -0.022373324, -0.03799344, 0.01857132, -0.0031157145, 0.006819676, 0.0027916804, 0.060991567, -0.0081424005, 0.041662507, -0.004031319, -0.0033915592, 0.004267283, -0.012449564, 0.023955276, 0.0085810935, -0.024806073, -0.019661406, 0.0030691866, -0.052722875, 0.03974821, 0.010016815, -0.02371599, 0.020312797, -0.032117616, -0.015274479, -0.0429387, 0.026029095, 0.11517675, -0.037408516, 0.008129107, 0.010502036, -0.0023712665, -0.02013998, -0.018518146, -0.07476386, -0.021562407, 0.022944953, 0.009338835, 0.10922117, 0.031027533, -0.015553648, 0.03326088, 0.0052875755, -0.02354317, 0.0039781444, -0.0061716074, -0.0590241, 0.054982807, -0.0037222404, -0.0053407503, -0.010176339, -0.0049718497, -0.29586494, -0.02483266, 0.043816086, 0.07311544, 0.03209103, 0.031851742, 0.056897104, -0.0059755254, -0.014928843, 0.110284664, -0.032516427, 0.04575697, 0.00097293383, 0.03105412, -0.017800285, -0.025749927, 0.08561153, -0.07226464, -0.0327823, -0.08598375, 0.0071387254, -0.027198942, 0.16314048, 0.018770726, -0.05663123, 0.05083517, 0.043204576, 0.034218024, -0.086568676, -0.03323429, -0.059449498, 0.029591812, 0.023529876, 0.029698161, 0.010521976, 0.10018144, -0.04285894, 0.0075109494, 0.012509386, -0.016045514, -0.043098226, 0.0028830746, -0.04285894, -0.0015470561, 0.032941826, -0.09465126, -0.039322812, -0.029644987, 0.058598697, 0.028342202, -0.082208335, 0.022732254, 0.079868644, 0.04833595, 0.029246174, 0.0076040053, -0.0069393194, 0.035467632, 0.02472631, 0.015659997, 0.034935884, -0.042220842, -0.026800131, 0.030150147, 0.04897405 ]

Apparent Dipole Moments of Aerosol OT Reversed Micelles in Cyclohexane Determined at a Frequency of 1 MHz and at a Temperature of 298.15 K

bind to the head group of AOT. The process of forming W/O microemulsion and the molecular interactions in the micellar core are discussed in terms of the hydration of AOT.

8978565

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Decylammonium Chloride and Cesium Perfluorooctanoate Surface Free Energy and Their Critical Micelle Concentration

Measurements of the surface tension of decylamine and perfluoroheptane and interfacial tension of water-perfluoroheptane were carried out. Measurements of the contact angle were also made for water; glycerol; formamide; diiodomethane; bromoform; and benzene on DACl and CsPFO layers formed on Teflon and on DACl and CsPFO pellets; as well as of zeta potential for surfactants adsorbed on latex. From the results obtained and the literature data the surface free energy of DACl and CsPFO for both tails and heads

8978566

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Decylammonium Chloride and Cesium Perfluorooctanoate Surface Free Energy and Their Critical Micelle Concentration

parts of their molecules; and their free energy of interaction through water were determined. It was shown that the free energy of interaction between -CH2- groups through water; determined from interfacial tension; is in agreement with that obtained from the relationship between logCMC and the number of carbon atoms in the chain of molecules of surfactants having the same head. It was also shown that there is agreement between the total free energy of interaction between molecules of surfactants through wa

8978566

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Decylammonium Chloride and Cesium Perfluorooctanoate Surface Free Energy and Their Critical Micelle Concentration

ter and their critical micelle concentration (CMC).

8978566

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-0.002800994, 0.052483525, -0.0066463705, -0.021337131, -0.013867813, 0.01714638, 0.0027844692, -0.0061836694, -0.003843724, 0.015559977, -0.020729009, 0.061446704 ]

Numerical Simulation of Bubble Motion in Water

This paper presents the results of numerical simulations for bubble motion in water. The motion is axisymmetric and steady in the bubble's frame of reference. It is assumed that the liquid is quiescent except for the motion created by the bubble. The bubble Reynolds numbers range up to roughly 600. The results for clean interfaces are compared with Duineveld's experiments. The insoluble surfactant model is used to model the behavior of bubbles in contaminated water. Calculations of wake volumes are presente

8978567

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Numerical Simulation of Bubble Motion in Water

d.

8978567

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Analysis of Initial Protein Surface Coverage on Fouled Ultrafiltration Membranes

Internal surface coverage of protein in membranes during the initial phase of ultrafiltration was analyzed. Bovine serum albumin (BSA); in solutions of pH 5 and 7 with 0.05 and 0.15 M NaCl; were ultrafiltered with 100;000-MWCO polysulfone membranes. Mass uptake of the membranes was determined using electron paramagnetic resonance spectroscopy for separate membranes for fractions of an hour for up to 4 h. The resulting data were compared with models for surface coverage. The results showed a significant amou

8978569

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Analysis of Initial Protein Surface Coverage on Fouled Ultrafiltration Membranes

nt of protein loading exists in a very short time of exposure during ultrafiltration. The amount of material found in this period was not a function of solution properties; however; solution properties did affect the resistance per mass for adsorbed species when the pH was near the isoelectric point of BSA. The modeling comparison implied that the entrained solute from pH 7 appeared to behave as though it was lodged in the ultrathin skin area of the membrane. Solute in the membrane at pH 5 and low ionic str

8978569

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Analysis of Initial Protein Surface Coverage on Fouled Ultrafiltration Membranes

ength appeared to be lodged and adsorbed throughout the membrane substructure.

8978569

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-0.005599031, -0.06431436, -0.009555768, -0.06526795, 0.060023203, -0.026581326, 0.04479225 ]

Formation Mechanism of Monodispersed alpha-Fe2O3 Particles in Dilute FeCl3 Solutions

Some ambiguity is still involved in the interpretation of the growth mechanism of monodispersed hematite (alpha-Fe2O3) particles in dilute FeCl3 solutions. Namely; there are two entirely different proposals on this issue; viz. aggregation of preformed primary particles of alpha-Fe2O3 itself and reprecipitation of the ionic species through dissolution of the preformed beta-FeOOH particles. In order to resolve this problem; the formation process was followed in detail through TEM; Electron Diffraction; XRD; F

8978568

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Formation Mechanism of Monodispersed alpha-Fe2O3 Particles in Dilute FeCl3 Solutions

T-IR; and ICP spectrometry along with quantitative analyses on seed effects. As a result; it has been concluded that the nuclei of the hematite particles are initially generated with the formation of beta-FeOOH particles and that they are grown by deposition of the solute originally present in the solution phase and indirectly furnished from the beta-FeOOH by dissolution. As the concentration of the solute is lowered by the growth of the hematite particles; they continue to grow with the solute provided mai

8978568

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Formation Mechanism of Monodispersed alpha-Fe2O3 Particles in Dilute FeCl3 Solutions

nly from the beta-FeOOH in a steady-state of the dissolution of beta-FeOOH and growth of alpha-Fe2O3. The basic formation mechanism is common to the ellipsoidal particles grown in the presence of phosphate ions and spherical particles in their absence.

8978568

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Tl+/Na+ Competitive Binding at the Surface of Dodecylsulfate Micelles in Water-Urea Mixtures

The effect of urea on the competition between Tl+ and Na+ ions to bind with the surface of dodecylsulfate micelles in aqueous solution has been studied by fluorescence techniques; employing methods based on fluorescence quenching data (FQD) and critical micelle concentration measurements (CMCM). The results obtained are interpreted in terms of selectivity coefficients K (Tl+/Na+) defined within the framework of the pseudophase ion-exchange formalism. It is found that the ion specificity observed in the abse

8978570

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Tl+/Na+ Competitive Binding at the Surface of Dodecylsulfate Micelles in Water-Urea Mixtures

nce of urea [K(Tl+/Na+) = 3.8 +/- 0.3 (from FQD); K(Tl+/Na+) = 2.5 +/- 0.3 (from CMCM] is progressively lost in the presence of increasing concentrations of urea. Typically; values of K (Tl+/Na+) = 1.4 +/- 0.2 (from FQD) and K (Tl+/Na+) = 1.2 +/- 0.2 (from CMCM) in a water-urea mixture at 8 M urea; were obtained. The results are discussed in terms of urea association to the micellar interface and changes in the characteristics of the external medium.

8978570

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0.032762628, 0.0397566, -0.026858974, -0.00814412, -0.0012482109, -0.035687864, -0.007273197, -0.021766406, 0.07669434, 0.024000222 ]

Effects of Monovalent, Exchangeable Cations and Electrolytes on the Infrared Vibrations of Smectite Layers and Interlayer Water

Infrared spectroscopy was used to investigate how nuSi-O; the frequency of Si-O stretching; in layers of Li- and Na-montmorillonite and nu2; the frequency of H-O-H bending; in the interlayer water were affected by increasing the concentration; C; of LiCl and NaCl; respectively. Oriented gels of Li- and Na-montmorillonite equilibrated with solutions having various values of C were obtained by using a miniature pressure membrane apparatus. One part of each gel was used for the gravimetric determination of mw/

8978572

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-0.0013399008, 0.026660418, 0.05783136, -0.0053931638, -0.019612724, -0.03627213, -0.025331425, 0.01089372, -0.015491501, -0.017760187, -0.008269294, -0.052381143, -0.07721587, -0.0028543158, 0.10073503, -0.060730983, -0.043682277, -0.05326714, 0.026794659, 0.0010806463, 0.041346468, 0.02891568, -0.03071452, -0.015316987, -0.032379117, -0.0019951684, 0.04475621, -0.02139814, -0.039601326, 0.034849167, 0.008235733, 0.010021149, 0.06352321, 0.020189963, 0.03852739, 0.01953218, 0.07286644, -0.025197182, 0.04754844, 0.023572857, 0.016887616, -0.08199488, 0.038285755, -0.0686244, 0.098855644, -0.056274153, -0.037748788, -0.026445631, -0.04881031, 0.011390415, 0.030821914, 0.056596335, 0.048112255, 0.047736377, 0.022995617, 0.12747599, -0.003225159, -0.073242314, 0.0034802181, 0.027492717, -0.056918517, -0.003456726, 0.045991234, -0.008329703, 0.045212634, -0.041776042, -0.020216811, -0.021022264, -0.009054609, -0.044031303, 0.04266204, 0.027707504, -0.039467085, -0.004745447, -0.30349383, 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0.014001418, -0.016995009, -0.0066651045, -0.09413034, 0.018673033, 0.008987487, -0.022284135, 0.054018892, -0.012450925, -0.003768838, 0.018646184, 0.05128036, -0.0073363134, 0.02358628, -0.052703325, 0.0045642206, 0.016807072, 0.012437501, -0.036352675, 0.0056918515, 0.032862388, -0.2566703, 0.011195765, 0.0039030798, 0.008504217, -0.046608746, -0.002100884, 0.016015045, 0.013021453, -0.059173778, -0.013357057, -0.017035281, -0.026230844, 0.08231706, 0.033130873, -0.059979226, 0.018042095, 0.06733568, -0.05353562, 0.013410754, 0.047763225, 0.026566448, 0.031788453, 0.11566272, -0.01747828, -0.015115624, 0.0800618, -0.041910283, 0.07061118, -0.006856399, 0.02939895, 0.024660215, 0.09928522, 0.025841543, -0.07624933, -0.0022351258, 0.05490489, -0.0025690522, 0.001058832, -0.008551202, 0.016525164, -0.040299382, 0.037023883, -0.008041083, -0.031761605, 0.06781895, -0.046742987, 0.031224638, -0.03318457, 0.027707504, -0.06078468, 0.022351258, 0.025009245, 0.05686482, 0.002647919, 0.045373723, -0.02490185, 0.011739444, -0.009195562, 0.03594995, 0.018592486, -0.012471061, -0.04993794, -0.10175527, 0.10089612, 0.0063496362 ]

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Effects of Monovalent, Exchangeable Cations and Electrolytes on the Infrared Vibrations of Smectite Layers and Interlayer Water

mc; the water content. The other part was transferred to an FTIR spectrometer where the spectrum of the gel was measured by attenuated total reflectance. Thus; the dependence of both nuSi-O and nu2 on mw/mc was determined in the same samples. The results showed that increasing C had little or no effect on the relation between nuSi-O and mw/mc; or on the relation between nu2 and mw/mc. The vibrational coupling of Si-O stretching in the montmorillonite layers and H-O-H bending in the interlayer water was demo

8978572

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Effects of Monovalent, Exchangeable Cations and Electrolytes on the Infrared Vibrations of Smectite Layers and Interlayer Water

nstrated. It was essentially independent of the species of exchangeable cation and C. Thus neither the species of exchangeable cation nor C had any specific effect on the structure of the clay layers or the structure of the interlayer water.

8978572

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Self-Association of Phenothiazine Drugs: Influence of the Counterion on the Mode of Association

The association characteristics of the phenothiazine drug trimeprazine tartrate in water and aqueous electrolyte solution have been examined using static and dynamic light scattering techniques and compared with those reported for the structurally related drug promethazine hydrochloride; to identify differences in association pattern arising from differences in the counterions of the two drugs. The association of trimeprazine tartrate was micellar in water and in the presence of added electrolyte. A progres

8978571

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0.053061377, 0.0038852333, 0.02121652, -0.031215724, -0.05525665, 0.07190861, 0.030921236 ]

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Self-Association of Phenothiazine Drugs: Influence of the Counterion on the Mode of Association

sive increase of aggregation number and micellar radius was observed with increase of sodium chloride concentration over the range 0.05 to 0.60 M NaCl. This behavior is in contrast to that of promethazine hydrochloride which exhibits continuous association above the critical concentration in electrolyte of concentrations >/=0.2 M NaCl. Moreover; static light scattering curves for trimeprazine tartrate showed a single discontinuity corresponding to the onset of micellization; whereas the association behavior

8978571

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-0.0006497741, 0.0124930795, 0.006809231, -0.07523982, 0.011602152, 0.091852605, -0.025414877, 0.038906064, 0.016224258, -0.03587825, 0.054018334, -0.029956596, 0.035637096, -0.0103829885, -0.06157447, -0.016438615, 0.012513176, -0.054634616, -0.0020615256, 0.03242172, -0.009123633, -0.27395013, -0.0061460594, 0.013732339, -0.020658799, -0.009659529, 0.043541566, -0.07695469, 0.005151302, 0.004833114, -0.00043541566, -0.0025840243, -0.034458123, 0.06575446, 0.008554243, -0.032394923, -0.03531556, 0.023780392, 0.021556424, 0.0010182027, -0.0011446407, -0.010831801, -0.054098718, 0.11264538, -0.0002545507, 0.003824959, -0.003814911, -0.03649453, 0.06602241, 0.046381813, 0.07272111, 0.10498206, 0.0039656316, -0.027545063, -0.027236924, 0.013919903, -0.04118362, 0.019680787, 0.062485494, -0.023458855, -0.008246102, -0.061145753, 0.0082862945, 0.056269098, -0.070952654, 0.060556266, -0.043541566, 0.0018655886, -0.028000575, 0.02509334, 0.013404103, -0.0027029263, 0.021864563, 0.022212896, -0.0047259345, -0.03748594, -0.0070939255, 0.017738163, -0.0072948867, 0.027679037, -0.0072078034, 0.02792019, -0.018756365, -0.023083728, -0.0068929647, 0.04831104 ]

Self-Association of Phenothiazine Drugs: Influence of the Counterion on the Mode of Association

of promethazine hydrochloride (and other phenothiazine drugs with chloride counterions); in water and dilute electrolyte (0.05-0.1 M NaCl); is complex; with discontinuities in solution properties at several critical concentrations. The results of this study highlight the influence of the counterion on the association characteristics of this class of amphiphile.

8978571

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0.04379159, 0.033303685, -0.023486065, -0.05635604, 0.021054659, 0.050783522, 0.0009947406, -0.015035287, 0.008634776, 0.029834004, -0.00807621, -0.069025636, 0.03606366, -0.029203154, -0.058353737, -0.001950053, 0.023827774, -0.034696817, -0.036142517, 0.0056809466, -0.043239594, -0.3078554, 0.0049219537, 0.0018071259, 0.048391543, -0.019924384, 0.0038442495, -0.009995049, 0.08905516, 0.02072609, 0.020068953, -0.03693108, 0.013471302, 0.020068953, 0.011407892, 0.038245354, 0.022710644, 0.07312617, -0.049074966, 0.010139619, -0.03148999, -0.004823383, 0.025102621, 0.1544534, -0.062349126, 0.038429353, 0.010290761, -0.014943288, 0.01000162, 0.025523188, 0.01701984, 0.038166497, -0.032147124, 0.022066649, -0.025404904, 0.05159837, 0.0042352458, -0.01096104, 0.029781433, 0.004034819, 0.023604348, -0.04034819, -0.02817802, 0.080433525, -0.019083248, 0.05414806, 0.0006037443, -0.060036004, -0.08427121, 0.02678489, 0.00653851, -0.01481186, -0.004070962, 0.0054148063, 0.039664768, 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Adsorption of Glycosidic Surfactants at the Mercury Electrode

The adsorption of glycosidic surfactants from aqueous electrolyte solutions on a mercury electrode was studied by means of differential capacitive measurements (tensammetric method). The adsorption behavior of the mono- and disaccharidic surfactants studied is discussed in relation to their micellar properties; in particular their respective critical micellar concentration (CMC). With monosaccharidic surfactants; a broad and bell-shaped peak is observed on the tensammetric curves and it suggests the formati

8978573

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Adsorption of Glycosidic Surfactants at the Mercury Electrode

on of a monolayer called hemimicelle at the mercury electrode. For disaccharidic compounds; the split capacity peak observed at concentrations above the CMC suggests the formation of a multilayer of micelles throughout the electrical double layer.

8978573

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-0.010723426, 0.031669185, -0.035330515, 0.0053116037, -0.029985504, -0.08503911, 0.08792541, -0.016422542 ]

Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle

The proton affinity of individual surface groups has been calculated with a redefined version of the multi site complexation (MUSIC) model. In the new approach the proton affinity of an oxygen originates from the undersaturation of the oxygen valence. The factors valence and coordination number; which are the basis of Pauling's definition of bond valence; in combination with the number of coordinating (Me and H) ions; are dominant in determining the proton affinity. The neutralization of an oxygen by Me ion

8978574

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Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle

(s) is calculated on the basis of the actual bond valence; which accounts for structural details; resulting from an asymmetrical distribution of charge in the coordination environment. An important role in the new version of the MUSIC model is given to the H bonds. The model shows that the proton affinity is determined not only by the number of donating H bonds but also by the number of accepting H bonds. The proton affinity of surface groups and of solution complexes can be understood in one theoretical fr

8978574

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0.05447457, 0.005179995, -0.04398848, -0.03894454, -0.05158094, -0.042342562, 0.037776466, 0.041121397 ]

Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle

amework; on the basis of a different number of donating and accepting H bonds. The MUSIC model predicts the variation in proton affinity constants for surface groups in particular those with the same number of coordinating Me ions but with a different structural position. The model is able to predict on the basis of the proton affinity of the individual groups the correct PZC of Me hydroxides; oxohydroxides; and oxides; and explains previous exceptions. The model can also be applied in general to other mine

8978574

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Intrinsic Proton Affinity of Reactive Surface Groups of Metal (Hydr)oxides: The Bond Valence Principle

rals.

8978574

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Coarsening Due to Thermally Induced Marangoni Convection

The growth of closely packed droplets in a decomposing butoxyethanol/water mixture is studied at reduced gravity during scaled times t* = t(D/xi2) on the order of t* = 10(6) (t; time; D; diffusion coefficient; xi; correlation length). Thermally induced Marangoni convection at the surfaces of the droplets causes an enhancement of the coarsening process.

8978575

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Biochemical modulation: its pharmacological basis and clinical applications. Proceedings of a meeting. Singapore, October 19, 1995.

nan

8978576

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A comparative, randomized trial of UFT and 5-fluorouracil in combination with cyclophosphamide and doxorubicin in the treatment of advanced breast cancer patients at The Philippines General Hospital.

A comparative; randomized trial was conducted to determine the efficacy of oral UFT (Tegafur and Uracil) versus 5-fluorouracil (5-FU) in combination with cyclophosphamide and doxorubicin in patients with metastatic breast cancer. Of 62 evaluable patients; 31 received UFT (350 mg/m2/day orally x 14 days); doxorubicin (50 mg/m2 intravenously [I.V.] day 1) and cyclophosphamide (500 mg/m2 I.V. day 1). The other 31 patients received 5-FU (500 mg/m2 I.V. days 1 and 8); doxorubicin (50 mg/m2 I.V. day 1); and cyclo

8978577

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-0.01917734, 0.02490112, 0.03198898, 0.016890502, 0.022587536, -0.033085592, 0.1042049, -0.007796645 ]

A comparative, randomized trial of UFT and 5-fluorouracil in combination with cyclophosphamide and doxorubicin in the treatment of advanced breast cancer patients at The Philippines General Hospital.

phosphamide (500 mg/m2 I.V. day 1). Regimens were repeated for a total of six cycles. The two groups were comparable in terms of age; gender; performance status; menopausal status; and number and sites of metastases. No statistical difference in overall response rates was seen (UFT arm; 48.4% vs. 5-FU arm; 35 %; p = 0.30). Median response duration was 16 weeks (range; 4-30) for both arms. The toxicity profile (alopecia; anemia; leukopenia; thrombocytopenia; diarrhea) was similar in both groups and both regi

8978577

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0.02922358, -0.031276695, 0.07641859, -0.025637293, 0.024264105, 0.014198501, -0.06345996, 0.06932601, 0.017278176 ]

A comparative, randomized trial of UFT and 5-fluorouracil in combination with cyclophosphamide and doxorubicin in the treatment of advanced breast cancer patients at The Philippines General Hospital.

mens were well tolerated. Anemia and stomatitis were significantly more common in the 5-FU arm (p = 0.02). Thus; oral UFT has response rates and duration of response that are comparable to 5-FU in a combination regimen for advanced breast cancer.

8978577

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Mechanism-based improvement in the therapeutic selectivity of 5-FU prodrug alone and under conditions of metabolic modulation.

To compare the antitumor activity of Tegafur (150 mg/kg/day) with continuous intravenous infusion of 5-fluorouracil (5-FU) (12.5 mg/kg/day) and with oral UFT (60 mg/kg/day) with and without low- or high-dose leucovorin (50 or 200 mg/kg/day); rats with advanced colon cancer were treated with Tegafur or UFT 3 times daily for 28 days and 5-FU by continuous intravenous infusion for 28 days. UFT alone had a complete remission (CR) rate of 38%; whereas Tegafur and 5-FU produced no CRs. When high-dose leucovorin w

8978578

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Mechanism-based improvement in the therapeutic selectivity of 5-FU prodrug alone and under conditions of metabolic modulation.

as added; the CR rate for UFT increased to 75%; Tegafur plus high-dose leucovorin resulted in only a partial remission rate of 50%; with no CRs; low-dose leucovorin was not as effective as the high dose. Hence; UFT clearly offers significant therapeutic advantages over Tegafur and protracted infusion of 5-FU. High-dose leucovorin is essential for significant modulation of drug action in this tumor.

8978578

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Clinical application of biochemical modulation in cancer chemotherapy: biochemical modulation for 5-FU.

The addition of Uracil to Tegafur; a prodrug of 5-fluorouracil (5-FU); has been shown to enhance the antineoplastic effect of 5-FU while reducing the side effects attributed to 5-FU catabolism. Studies of 5-FU levels have shown that the 5-FU concentration in the tumor tissues of patients with head and neck cancer was 16.9 times greater than that in serum and approximately 2-6 times greater than in normal tissue. Similar observations have been made in tumor tissues of patients with breast cancer. The clinica

8978579

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Clinical application of biochemical modulation in cancer chemotherapy: biochemical modulation for 5-FU.

l efficacy of UFT; the combination of Uracil and Tegafur in a molar ratio of 4:1; has been studied in a variety of tumor types. An overall response rate of about 23% was obtained; with responses exceeding 30% in patients with head and neck; breast; and bladder cancer. Side effects are predominantly that of gastrointestinal toxicity. Hematologic toxicity is minimal and hepatotoxicity is rare. The UFT combination produces a good clinical effect in a variety of tumor types and is well tolerated.

8978579

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Phase II study of UFT plus leucovorin in colorectal cancer.

The activity and toxicity of UFT (Tegafur and Uracil) in a 4:1 molar concentration; plus leucovorin (LV); were evaluated in the treatment of 45 patients with advanced; bidimensionally measurable metastatic colorectal carcinoma. Initially 350 and later 300 mg/m2/day; plus 150 mg LV; as administered in divided doses every 8 h for 28 days. After two courses of treatment; responses were evaluated. The overall response rate was 42.2%; with responses observed in liver (n = 18); lung (n = 6); and bone (n = 1). Fiv

8978580

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Phase II study of UFT plus leucovorin in colorectal cancer.

e of the 7 patients who received 350 mg/m2 UFT experienced prolonged grade 3 diarrhea; resulting in a dose reduction to 300 mg/m2; 9 patients in the 300-mg/m2 group experienced grade 3 diarrhea; vomiting; abdominal cramping; and fatigue. Minor toxic effects included oral mucositis and rash. The oral regimen of 300 mg/m2/day UFT; plus 150 mg/day LV; administered for 28 days appears to have significant activity against metastatic colorectal carcinoma. The treatment is well tolerated; neutropenia did not occur

8978580

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Phase II study of UFT plus leucovorin in colorectal cancer.

; and oral mucositis was not significant; even though both are characteristic of intravenous schedules of 5-fluorouracil plus LV. The results of this trial constitutes the basis of phase III clinical trials comparing this oral schedule with intravenous 5-FU and LV to compare clinical efficacy; impact on well-being; and cost. In addition; the current National Surgical Adjuvant Breast and Bowel Project (NSABP) adjuvant colon clinical trial (CO-6) will compare this 28-day schedule of UFT plus oral leucovorin w

8978580

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Phase II study of UFT plus leucovorin in colorectal cancer.

ith a weekly regimen of intravenous 5-fluorouracil plus leucovorin in the postoperative adjuvant therapy of Dukes' B and C colon cancer patients.

8978580

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0.022444457, -0.0403713, -0.052070096, -0.016764795, -0.04324377, -0.04507171, -0.0046220697, -0.008800212, 0.029038088 ]

UFT modulated with leucovorin in advanced colorectal cancer: Oncopaz experience.

A phase II trial of UFT (Tegafur and Uracil) modulated by leucovorin was undertaken by the Oncopaz Cooperative Group to assess the efficacy and toxicity of this combination in patients with advanced colorectal cancer. A total of 75 patients were given 500 mg/m2 intravenous leucovorin and 195 mg/m2 of oral UFT on day 1; followed by oral leucovorin 15 mg/12 h and 195 mg/m2/12 h of oral UFT on days 2-14. An overall response rate of 39% was obtained; with seven complete responses (9%); and 22 partial responses

8978581

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UFT modulated with leucovorin in advanced colorectal cancer: Oncopaz experience.

(29%). The primary toxicity was gastrointestinal; with grade 1-2 diarrhea occurring in 8.5% of courses; and grade 3-4 in 3.5%. Hematologic toxicity was minimal; and there were no deaths due to toxicity. This regimen was active and well tolerated in patients with advanced colorectal cancer; including those 70 years of age or older.

8978581

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Experience of Oncopaz Cooperative Group with oral fluoropyrimidines in tumors of the stomach, lung, head and neck, and breast.

The Oncopaz Cooperative Group designed a chemotherapy regimen to modulate UFT (Tegafur and Uracil) with leucovorin. The regimen consisted of a high intravenous dose of leucovorin; followed by oral UFT and oral leucovorin twice daily for 14 days. Based on the promising results obtained with this regimen in patients with advanced colorectal cancer; the Oncopaz group performed several phase II trials using this combination with other drugs to treat advanced gastric; lung; head and neck; and breast cancers. Whe

8978582

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Experience of Oncopaz Cooperative Group with oral fluoropyrimidines in tumors of the stomach, lung, head and neck, and breast.

n combined with etoposide in gastric cancer; the regimen was shown to be active and well tolerated. However; when used with cisplatin to treat non-small cell lung cancer; a low response rate and high toxicity precluded its recommendation for further study. The addition of carboplatin in the treatment of head and neck cancer demonstrated moderate activity with low toxicity. In an ongoing trial of advanced breast cancer; preliminary results indicate that the combination of idarubicin; UFT; and leucovorin is a

8978582

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Experience of Oncopaz Cooperative Group with oral fluoropyrimidines in tumors of the stomach, lung, head and neck, and breast.

ctive; with moderate; primarily hematologic toxicity. Trials of new combinations are warranted to take advantage of the pharmacokinetic properties and oral bioavailability of UFT and leucovorin.

8978582

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Comparison of two different doses of ondansetron plus dexamethasone in the prophylaxis of cisplatin-induced emesis.

This study was conducted to evaluate the efficacy of two different doses of ondansetron (8 mg vs. 24 mg) plus dexamethasone in the prevention of cisplatin (CDDP)-induced emesis and nausea (acute and delayed). The persistence of the anti-emetic efficacy during the second cycle of chemotherapy was also assessed. Eighty patients receiving high-dose CDDP (>80 mg/m2) were randomized to have either ondansetron 8 mg plus dexamethasone 20 mg (8 mg group) or ondansetron 24 mg plus dexamethasone 20 mg (24 mg group);

8978584

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