Moussab/ORKG-training-evaluation-set huggingface dataset:
Research field: Planetary Sciences
Title: Raman spectroscopy for mineral identification and quantification for in situ planetary surface analysis: A point count method
Abstract: Quantification of mineral proportions in rocks and soils by Raman spectroscopy on a planetary surface is best done by taking many narrow-beam spectra from different locations on the rock or soil, with each spectrum yielding peaks from only one or two minerals. The proportion of each mineral in the rock or soil can then be determined from the fraction of the spectra that contain its peaks, in analogy with the standard petrographic technique of point counting. The method can also be used for nondestructive laboratory characterization of rock samples. Although Raman peaks for different minerals seldom overlap each other, it is impractical to obtain proportions of constituent minerals by Raman spectroscopy through analysis of peak intensities in a spectrum obtained by broad-beam sensing of a representative area of the target material. That is because the Raman signal strength produced by a mineral in a rock or soil is not related in a simple way through the Raman scattering cross section of that mineral to its proportion in the rock, and the signal-to-noise ratio of a Raman spectrum is poor when a sample is stimulated by a low-power laser beam of broad diameter. Results obtained by the Raman point-count method are demonstrated for a lunar thin section (14161,7062) and a rock fragment (15273,7039). Major minerals (plagioclase and pyroxene), minor minerals (cristobalite and K-feldspar), and accessory minerals (whitlockite, apatite, and baddeleyite) were easily identified. Identification of the rock types, KREEP basalt or melt rock, from the 100-location spectra was straightforward.
Extracted statement — Samples: 152,737,039
Research field: Planetary Sciences
Title: Raman spectroscopy as a method for mineral identification on lunar robotic exploration missions
Abstract: fiber bundle that carried the laser beam and returned the scattered radiation could be placed against surfaces at any desired angle by a deployment mechanism; otherwise, the instrument would need no moving parts. A modem micro-Raman spectrometer with its beam broadened (to .expand the spot to 50-gm diameter) and set for low resolution (7 cm ' in the 100-1400 cm ' region relative to 514.5-nm excitation), was used to simulate the spectra anticipated from a rover instrument. We present spectra for lunar mineral grains, <1 mm soil fines, breccia fragments, and glasses. From frequencies of olivine peaks, we derived sufficiently precise forsteritc contents to correlate the analyzed grains to known rock types and we obtained appropriate forsteritc contents from weak signals above background in soil fines and breccias. Peak positions of pyroxenes were sufficiently well determined to distinguish among orthorhombic, monoclinic, and triclinic (pyroxenoid) structures; additional information can be obtained from pyroxene spectra, but requires further laboratory calibration. Plagioclase provided sharp peaks in soil fines and most breccias even when the glass content was high.
Extracted statement — Raman Stokes-shift range (cm-1): 100-1400
Research field: Plasma and Beam Physics
Title: Cold Atmospheric Pressure Plasma VUV Interactions With Surfaces: Effect of Local Gas Environment and Source Design
Abstract: This study uses photoresist materials in combination with several optical filters as a diagnostic to examine the relative importance of VUV-induced surface modifications for different cold atmospheric pressure plasma (CAPP) sources. The argon fed kHz-driven ring-APPJ showed the largest ratio of VUV surface modification relative to the total modification introduced, whereas the MHz APPJ showed the largest overall surface modification. The MHz APPJ shows increased total thickness reduction and reduced VUV effect as oxygen is added to the feed gas, a condition that is often used for practical applications. We examine the influence of noble gas flow from the APPJ on the local environment. The local environment has a decisive impact on polymer modification from VUV emission as O2 readily absorbs VUV photons.
Extracted statement — VUV: FILTERS
Research field: Plasma and Beam Physics
Title: Etching materials with an atmospheric-pressure plasma jet
Abstract: A plasma jet has been developed for etching materials at atmospheric pressure and between 100 and C. Gas mixtures containing helium, oxygen and carbon tetrafluoride were passed between an outer, grounded electrode and a centre electrode, which was driven by 13.56 MHz radio frequency power at 50 to 500 W. At a flow rate of , a stable, arc-free discharge was produced. This discharge extended out through a nozzle at the end of the electrodes, forming a plasma jet. Materials placed 0.5 cm downstream from the nozzle were etched at the following maximum rates: for Kapton ( and He only), for silicon dioxide, for tantalum and for tungsten. Optical emission spectroscopy was used to identify the electronically excited species inside the plasma and outside in the jet effluent.
Extracted statement — Unit_frequency: MHz
Research field: Plasma and Beam Physics
Title: RF Capillary Jet - a Tool for Localized Surface Treatment
Abstract: The UV/VUV spectrum of a non‐thermal capillary plasma jet operating with Ar at ambient atmosphere and the temperature load of a substrate exposed to the jet have been measured. The VUV radiation is assigned to N, H, and O atomic lines along with an Ar*2 excimer continuum. The absolute radiance (115‐200 nm) of the source has been determined. Maximum values of 880 μW/mm2sr are obtained. Substrate temperatures range between 35 °C for low powers and high gas flow conditions and 95 °C for high powers and reduced gas flow. The plasma source (13.56, 27.12 or 40.78 MHz) can be operated in Ar and in N2. The further addition of a low percentage of silicon containing reactive admixtures has been demonstrated for thin film deposition. Several further applications related to surface modification have been successfully applied. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)
Extracted statement — Unit_frequency: MHz
Research field: Plasma and Beam Physics
Title: Vacuum UV Radiation of a Plasma Jet Operated With Rare Gases at Atmospheric Pressure
Abstract: The vacuum ultraviolet (VUV) emissions from 115 to 200 nm from the effluent of an RF (1.2 MHz) capillary jet fed with pure argon and binary mixtures of argon and xenon or krypton (up to 20%) are analyzed. The feed gas mixture is emanating into air at normal pressure. The Ar2 excimer second continuum, observed in the region of 120-135 nm, prevails in the pure Ar discharge. It decreases when small amounts (as low as 0.5%) of Xe or Kr are added. In that case, the resonant emission of Xe at 147 nm (or 124 nm for Kr, respectively) becomes dominant. The Xe2 second continuum at 172 nm appears for higher admixtures of Xe (10%). Furthermore, several N I emission lines, the O I resonance line, and H I line appear due to ambient air. Two absorption bands (120.6 and 124.6 nm) are present in the spectra. Their origin could be unequivocally associated to O2 and O3. The radiance is determined end-on at varying axial distance in absolute units for various mixtures of Ar/Xe and Ar/Kr and compared to pure Ar. Integration over the entire VUV wavelength region provides the integrated spectral distribution. Maximum values of 2.2 mW middotmm-2middotsr-1 are attained in pure Ar and at a distance of 4 mm from the outlet nozzle of the discharge. By adding diminutive admixtures of Kr or Xe, the intensity and spectral distribution is effectively changed.
Extracted statement — Unit_frequency: MHz
Research field: Plasma and Beam Physics
Title: Generation of atomic oxygen in the effluent of an atmospheric pressure plasma jet
Abstract: The planar 13.56 MHz RF-excited low temperature atmospheric pressure plasma jet (APPJ) investigated in this study is operated with helium feed gas and a small molecular oxygen admixture. The effluent leaving the discharge through the jet's nozzle contains very few charged particles and a high reactive oxygen species' density. As its main reactive radical, essential for numerous applications, the ground state atomic oxygen density in the APPJ's effluent is measured spatially resolved with two-photon absorption laser induced fluorescence spectroscopy. The atomic oxygen density at the nozzle reaches a value of ~1016 cm−3. Even at several centimetres distance still 1% of this initial atomic oxygen density can be detected. Optical emission spectroscopy (OES) reveals the presence of short living excited oxygen atoms up to 10 cm distance from the jet's nozzle. The measured high ground state atomic oxygen density and the unaccounted for presence of excited atomic oxygen require further investigations on a possible energy transfer from the APPJ's discharge region into the effluent: energetic vacuum ultraviolet radiation, measured by OES down to 110 nm, reaches far into the effluent where it is presumed to be responsible for the generation of atomic oxygen.
Extracted statement — Unit_frequency: MHz
Research field: Plasma and Beam Physics
Title: Cold Atmospheric Pressure Plasma VUV Interactions With Surfaces: Effect of Local Gas Environment and Source Design
Abstract: This study uses photoresist materials in combination with several optical filters as a diagnostic to examine the relative importance of VUV-induced surface modifications for different cold atmospheric pressure plasma (CAPP) sources. The argon fed kHz-driven ring-APPJ showed the largest ratio of VUV surface modification relative to the total modification introduced, whereas the MHz APPJ showed the largest overall surface modification. The MHz APPJ shows increased total thickness reduction and reduced VUV effect as oxygen is added to the feed gas, a condition that is often used for practical applications. We examine the influence of noble gas flow from the APPJ on the local environment. The local environment has a decisive impact on polymer modification from VUV emission as O2 readily absorbs VUV photons.
Extracted statement — Unit_frequency: MHz
Research field: Plasma and Beam Physics
Title: Absolute ozone densities in a radio-frequency driven atmospheric pressure plasma using two-beam UV-LED absorption spectroscopy and numerical simulations
Abstract: The efficient generation of reactive oxygen species (ROS) in cold atmospheric pressure plasma jets (APPJs) is an increasingly important topic, e.g. for the treatment of temperature sensitive biological samples in the field of plasma medicine. A 13.56 MHz radio-frequency (rf) driven APPJ device operated with helium feed gas and small admixtures of oxygen (up to 1%), generating a homogeneous glow-mode plasma at low gas temperatures, was investigated. Absolute densities of ozone, one of the most prominent ROS, were measured across the 11 mm wide discharge channel by means of broadband absorption spectroscopy using the Hartley band centered at λ = 255 nm. A two-beam setup with a reference beam in MachZehnder configuration is employed for improved signal-to-noise ratio allowing highsensitivity measurements in the investigated single-pass weak-absorbance regime. The results are correlated to gas temperature measurements, deduced from the rotational temperature of the N2 (C Π u → B Π g , υ = 0 → 2) optical emission from introduced air impurities. The observed opposing trends of both quantities as a function of rf power input and oxygen admixture are analysed and explained in terms of a zerodimensional plasma-chemical kinetics simulation. It is found that the gas temperature as well as the densities of O and O2(b Σ g ) influence the absolute O3 densities when the rf power is varied. ‡ Current address: KROHNE Innovation GmbH, Ludwig-Krone-Str.5, 47058 Duisburg, Germany Page 1 of 26 AUTHOR SUBMITTED MANUSCRIPT PSST-101801.R1 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 A cc e d M an us cr ip t
Extracted statement — Unit_frequency: MHz
Research field: Plasma and Beam Physics
Title: 2D spatially resolved O atom density profiles in an atmospheric pressure plasma jet: from the active plasma volume to the effluent
Abstract: Two-dimensional spatially resolved absolute atomic oxygen densities are measured within an atmospheric pressure micro plasma jet and in its effluent. The plasma is operated in helium with an admixture of 0.5% of oxygen at 13.56 MHz and with a power of 1 W. Absolute atomic oxygen densities are obtained using two photon absorption laser induced fluorescence spectroscopy. The results are interpreted based on measurements of the electron dynamics by phase resolved optical emission spectroscopy in combination with a simple model that balances the production of atomic oxygen with its losses due to chemical reactions and diffusion. Within the discharge, the atomic oxygen density builds up with a rise time of 600 µs along the gas flow and reaches a plateau of 8 × 1015 cm−3. In the effluent, the density decays exponentially with a decay time of 180 µs (corresponding to a decay length of 3 mm at a gas flow of 1.0 slm). It is found that both, the species formation behavior and the maximum distance between the jet nozzle and substrates for possible oxygen treatments of surfaces can be controlled by adjusting the gas flow.
Extracted statement — Unit_frequency: MHz
Research field: Plasma and Beam Physics
Title: Comparison of electron heating and energy loss mechanisms in an RF plasma jet operated in argon and helium
Abstract: The µ-APPJ is a well-investigated atmospheric pressure RF plasma jet. Up to now, it has mainly been operated using helium as feed gas due to stability restrictions. However, the COST-Jet design including precise electrical probes now offers the stability and reproducibility to create equi-operational plasmas in helium as well as in argon. In this publication, we compare fundamental plasma parameters and physical processes inside the COST reference microplasma jet, a capacitively coupled RF atmospheric pressure plasma jet, under operation in argon and in helium. Differences already observable by the naked eye are reflected in differences in the power-voltage characteristic for both gases. Using an electrical model and a power balance, we calculated the electron density and temperature at 0.6 W to be 9e17 m-3, 1.2 eV and 7.8e16 m-3, 1.7 eV for argon and helium, respectively. In case of helium, a considerable part of the discharge power is dissipated in elastic electron-atom collisions, while for argon most of the input power is used for ionization. Phase-resolved emission spectroscopy reveals differently pronounced heating mechanisms. Whereas bulk heating is more prominent in argon compared to helium, the opposite trend is observed for sheath heating. This also explains the different behavior observed in the power-voltage characteristics.
Extracted statement — Plasma_discharge: COST-Jet
Research field: Polymer Chemistry
Title: Biocatalytic Degradation Efficiency of Postconsumer Polyethylene Terephthalate Packaging Determined by Their Polymer Microstructures
Abstract: Polyethylene terephthalate (PET) is the most important mass‐produced thermoplastic polyester used as a packaging material. Recently, thermophilic polyester hydrolases such as TfCut2 from Thermobifida fusca have emerged as promising biocatalysts for an eco‐friendly PET recycling process. In this study, postconsumer PET food packaging containers are treated with TfCut2 and show weight losses of more than 50% after 96 h of incubation at 70 °C. Differential scanning calorimetry analysis indicates that the high linear degradation rates observed in the first 72 h of incubation is due to the high hydrolysis susceptibility of the mobile amorphous fraction (MAF) of PET. The physical aging process of PET occurring at 70 °C is shown to gradually convert MAF to polymer microstructures with limited accessibility to enzymatic hydrolysis. Analysis of the chain‐length distribution of degraded PET by nuclear magnetic resonance spectroscopy reveals that MAF is rapidly hydrolyzed via a combinatorial exo‐ and endo‐type degradation mechanism whereas the remaining PET microstructures are slowly degraded only by endo‐type chain scission causing no detectable weight loss. Hence, efficient thermostable biocatalysts are required to overcome the competitive physical aging process for the complete degradation of postconsumer PET materials close to the glass transition temperature of PET.
Extracted statement — Enzyme: TfCut2
Research field: Science
Title: Annotated facial landmarks in the wild: A large-scale, real- world database for facial landmark localization
Abstract: Face alignment is a crucial step in face recognition tasks. Especially, using landmark localization for geometric face normalization has shown to be very effective, clearly improving the recognition results. However, no adequate databases exist that provide a sufficient number of annotated facial landmarks. The databases are either limited to frontal views, provide only a small number of annotated images or have been acquired under controlled conditions. Hence, we introduce a novel database overcoming these limitations: Annotated Facial Landmarks in the Wild (AFLW). AFLW provides a large-scale collection of images gathered from Flickr, exhibiting a large variety in face appearance (e.g., pose, expression, ethnicity, age, gender) as well as general imaging and environmental conditions. In total 25,993 faces in 21,997 real-world images are annotated with up to 21 landmarks per image. Due to the comprehensive set of annotations AFLW is well suited to train and test algorithms for multi-view face detection, facial landmark localization and face pose estimation. Further, we offer a rich set of tools that ease the integration of other face databases and associated annotations into our joint framework.
Extracted statement — Databases: AFLW
Research field: Science
Title: The importance of diagnostic cytogenetics on outcome in AML: analysis of 1,612 patients entered into the MRC AML 10 trial
Abstract: Abstract Cytogenetics is considered one of the most valuable prognostic determinants in acute myeloid leukemia (AML). However, many studies on which this assertion is based were limited by relatively small sample sizes or varying treatment approach, leading to conflicting data regarding the prognostic implications of specific cytogenetic abnormalities. The Medical Research Council (MRC) AML 10 trial, which included children and adults up to 55 years of age, not only affords the opportunity to determine the independent prognostic significance of pretreatment cytogenetics in the context of large patient groups receiving comparable therapy, but also to address their impact on the outcome of subsequent transplantation procedures performed in first complete remission (CR). On the basis of response to induction treatment, relapse risk, and overall survival, three prognostic groups could be defined by cytogenetic abnormalities detected at presentation in comparison with the outcome of patients with normal karyotype. AML associated with t(8;21), t(15;17) or inv(16) predicted a relatively favorable outcome. Whereas in patients lacking these favorable changes, the presence of a complex karyotype, −5, del(5q), −7, or abnormalities of 3q defined a group with relatively poor prognosis. The remaining group of patients including those with 11q23 abnormalities, +8, +21, +22, del(9q), del(7q) or other miscellaneous structural or numerical defects not encompassed by the favorable or adverse risk groups were found to have an intermediate prognosis. The presence of additional cytogenetic abnormalities did not modify the outcome of patients with favorable cytogenetics. Subgroup analysis demonstrated that the three cytogenetically defined prognostic groups retained their predictive value in the context of secondary as well as de novo AML, within the pediatric age group and furthermore were found to be a key determinant of outcome from autologous or allogeneic bone marrow transplantation (BMT) in first CR. This study highlights the importance of diagnostic cytogenetics as an independent prognostic factor in AML, providing the framework for a stratified treatment approach of this disease, which has been adopted in the current MRC AML 12 trial.
Extracted statement — Disease: AML
Research field: Science
Title: Applications of Artificial Neural Network for the Prediction of Flow Boiling Curves
Abstract: An artificial neural network (ANN) was applied successfully to predict flow boiling curves. The databases used in the analysis are from the 1960's, including 1,305 data points which cover these parameter ranges: pressure P=100–1,000 kPa, mass flow rate G=40–500 kg/m2-s, inlet subcooling ΔTsub =0–35°C, wall superheat ΔTw = 10–300°C and heat flux Q=20–8,000kW/m2. The proposed methodology allows us to achieve accurate results, thus it is suitable for the processing of the boiling curve data. The effects of the main parameters on flow boiling curves were analyzed using the ANN. The heat flux increases with increasing inlet subcooling for all heat transfer modes. Mass flow rate has no significant effects on nucleate boiling curves. The transition boiling and film boiling heat fluxes will increase with an increase in the mass flow rate. Pressure plays a predominant role and improves heat transfer in all boiling regions except the film boiling region. There are slight differences between the steady and the transient boiling curves in all boiling regions except the nucleate region. The transient boiling curve lies below the corresponding steady boiling curve.
Extracted statement — Types: ANN
Research field: Science
Title: Using artificial neural network to predict the pressure drop in a rotating packed bed
Abstract: Although rotating beds are good equipments for intensified separations and multiphase reactions, but the fundamentals of its hydrodynamics are still unknown. In the wide range of operating conditions, the pressure drop across an irrigated bed is significantly lower than dry bed. In this regard, an approach based on artificial intelligence, that is, artificial neural network (ANN) has been proposed for prediction of the pressure drop across the rotating packed beds (RPB). The experimental data sets used as input data (280 data points) were divided into training and testing subsets. The training data set has been used to develop the ANN model while the testing data set was used to validate the performance of the trained ANN model. The results of the predicted pressure drop values with the experimental values show a good agreement between the prediction and experimental results regarding to some statistical parameters, for example (AARD% = 4.70, MSE = 2.0 × 10−5 and R2 = 0.9994). The designed ANN model can estimate the pressure drop in the countercurrent flow rotating packed bed with unexpected phenomena for higher pressure drop in dry bed than in wet bed. Also, the designed ANN model has been able to predict the pressure drop in a wet bed with the good accuracy with experimental.
Extracted statement — Types: ANN
Research field: Science
Title: APTEEN: a hybrid protocol for efficient routing and comprehensive information retrieval in wireless
Abstract: Wireless sensor networks with thousands of tiny sensor nodes, are expected to find wide applicability and increasing deployment in coming years, as they enable reliable monitoring and analysis of the environment. In this paper, we propose a hybrid routing protocol (APTEEN) which allows for comprehensive information retrieval. The nodes in such a network not only react to time-critical situations, but also give an overall picture of the network at periodic intervals in a very energy efficient manner. Such a network enables the user to request past, present and future data from the network in the form of historical, one-time and persistent queries respectively. We evaluated the performance of these protocols and observe that these protocols are observed to outperform existing protocols in terms of energy consumption and longevity of the network.
Extracted statement — Protocol: APTEEN