Moussab/ORKG-training-evaluation-set huggingface dataset:
Research field: Engineering
Title: Photoluminescence based H2 and O2 gas sensing by ZnO nanowires
Abstract: Gas sensing properties of ZnO nanowires prepared via thermal chemical vapor deposition method were investigated by analyzing change in their photoluminescence (PL) spectra. The as-synthesized nanowires show two different PL peaks positioned at 380 nm and 520 nm. The 380 nm emission is ascribed to near band edge emission, and the green peak (520 nm) appears due to the oxygen vacancy defects. The intensity of the green PL signal enhances upon hydrogen gas exposure, whereas it gets quenched upon oxygen gas loading. The ZnO nanowires' sensing response values were observed as about 54% for H2 gas and 9% for O2 gas at room temperature for 50 sccm H2/O2 gas flow rate. The sensor response was also analyzed as a function of sample temperature ranging from 300 K to 400 K. A conclusion was derived from the observations that the H2/O2 gases affect the adsorbed oxygen species on the surface of ZnO nanowires. The adsorbed species result in the band bending and hence changes the depletion region which causes variation i...
Extracted statement — Target gas: Hydrogen
Research field: Engineering
Title: Sensitivity amplification of fiber-optic in-line Mach–Zehnder Interferometer sensors with modified Vernier-effect
Abstract: In this paper, a novel sensitivity amplification method for fiber-optic in-line Mach-Zehnder interferometer (MZI) sensors has been proposed and demonstrated. The sensitivity magnification is achieved through a modified Vernier-effect. Two cascaded in-line MZIs based on offset splicing of single mode fiber (SMF) have been used to verify the effect of sensitivity amplification. Vernier-effect is generated due to the small free spectral range (FSR) difference between the cascaded in-line MZIs. Frequency component corresponding to the envelope of the superimposed spectrum is extracted to take Inverse Fast Fourier Transform (IFFT). Thus we can obtain the envelope precisely from the messy superimposed spectrum. Experimental results show that a maximum sensitivity amplification factor of nearly 9 is realized. The proposed sensitivity amplification method is universal for the vast majority of in-line MZIs.
Extracted statement — keywords: Interferometer
Research field: Engineering
Title: Vernier effect of two cascaded in-fiber Mach–Zehnder interferometers based on a spherical-shaped structure
Abstract: The Vernier effect of two cascaded in-fiber Mach-Zehnder interferometers (MZIs) based on a spherical-shaped structure has been investigated. The envelope based on the Vernier effect is actually formed by a frequency component of the superimposed spectrum, and the frequency value is determined by the subtraction between the optical path differences of two cascaded MZIs. A method based on band-pass filtering is put forward to extract the envelope efficiently; strain and curvature measurements are carried out to verify the validity of the method. The results show that the strain and curvature sensitivities are enhanced to -8.47 pm/με and -33.70 nm/m-1 with magnification factors of 5.4 and -5.4, respectively. The detection limit of the sensors with the Vernier effect is also discussed.
Extracted statement — keywords: interferometers
Research field: Engineering
Title: High-Sensitivity Fiber-Optic Strain Sensor Based on the Vernier Effect and Separated Fabry–Perot Interferometers
Abstract: A high-sensitivity fiber-optic strain sensor, based on the Vernier effect and separated Fabry–Perot interferometers (FPIs), is proposed and experimentally demonstrated. One air-cavity FPI is used as a sensing FPI (SFPI) and another is used as a matched FPI (MFPI) to generate the Vernier effect. The two FPIs are connected by a fiber link but separated by a long section of single-mode fiber (SMF). The SFPI is fabricated by splicing a section of microfiber between two SMFs with a large lateral offset, and the MFPI is formed by a section of hollow-core fiber sandwiched between two SMFs. By using the Vernier effect, the strain sensitivity of the proposed sensor reaches $\text{1.15 nm/}\mu \varepsilon $, which is the highest strain sensitivity of an FPI-based sensor reported so far. Owing to the separated structure of the proposed sensor, the MFPI can be isolated from the SFPI and the detection environment. Therefore, the MFPI is not affected by external physical quantities (such as strain and temperature) and thus has a very low temperature cross-sensitivity. The experimental results show that a low-temperature cross-sensitivity of $\text{0.056 } \mu \varepsilon /^ {\circ }{\text{C}}$ can be obtained with the proposed sensor. With its advantages of simple fabrication, high strain sensitivity, and low-temperature cross-sensitivity, the proposed sensor has great application prospects in several fields.
Extracted statement — keywords: interferometers
Research field: Engineering
Title: Highly Robust Flexible Vertical-Channel Thin-Film Transistors Using Atomic-Layer-Deposited Oxide Channels and Zeocoat Spacers on Ultrathin Polyimide Substrates
Abstract: Mechanically flexible vertical-channel-structured thin-film transistors (VTFTs) with a channel length of 200 nm were fabricated on 1.2 μm thick colorless polyimide (CPI) substrates. All layers comp...
Extracted statement — keywords: Layers
Research field: Engineering
Title: Natural Biowaste-Cocoon-Derived Granular Activated Carbon-Coated ZnO Nanorods: A Simple Route To Synthesizing a Core–Shell Structure and Its Highly Enhanced UV and Hydrogen Sensing Properties
Abstract: Granular activated carbon (GAC) materials were prepared via simple gas activation of silkworm cocoons and were coated on ZnO nanorods (ZNRs) by the facile hydrothermal method. The present combination of GAC and ZNRs shows a core-shell structure (where the GAC is coated on the surface of ZNRs) and is exposed by systematic material analysis. The as-prepared samples were then fabricated as dual-functional sensors and, most fascinatingly, the as-fabricated core-shell structure exhibits better UV and H2 sensing properties than those of as-fabricated ZNRs and GAC. Thus, the present core-shell structure-based H2 sensor exhibits fast responses of 11% (10 ppm) and 23.2% (200 ppm) with ultrafast response and recovery. However, the UV sensor offers an ultrahigh photoresponsivity of 57.9 A W-1, which is superior to that of as-grown ZNRs (0.6 A W-1). Besides this, switching photoresponse of GAC/ZNR core-shell structures exhibits a higher switching ratio (between dark and photocurrent) of 1585, with ultrafast response and recovery, than that of as-grown ZNRs (40). Because of the fast adsorption ability of GAC, it was observed that the finest distribution of GAC on ZNRs results in rapid electron transportation between the conduction bands of GAC and ZNRs while sensing H2 and UV. Furthermore, the present core-shell structure-based UV and H2 sensors also well-retained excellent sensitivity, repeatability, and long-term stability. Thus, the salient feature of this combination is that it provides a dual-functional sensor with biowaste cocoon and ZnO, which is ecological and inexpensive.
Extracted statement — ZnO form: Nanorods
Research field: Engineering
Title: Probing the highly efficient room temperature ammonia gas sensing properties of a luminescent ZnO nanowire array prepared via an AAO-assisted template route
Abstract: Here, we report the facile synthesis of a highly ordered luminescent ZnO nanowire array using a low temperature anodic aluminium oxide (AAO) template route which can be economically produced in large scale quantity. The as-synthesized nanowires have diameters ranging from 60 to 70 nm and length ∼11 μm. The photoluminescence spectrum reveals that the AAO/ZnO assembly has a strong green emission peak at 490 nm upon excitation at a wavelength of 406 nm. Furthermore, the ZnO nanowire array-based gas sensor has been fabricated by a simple micromechanical technique and its NH3 gas sensing properties have been explored thoroughly. The fabricated gas sensor exhibits excellent sensitivity and fast response to NH3 gas at room temperature. Moreover, for 50 ppm NH3 concentration, the observed value of sensitivity is around 68%, while the response and recovery times are 28 and 29 seconds, respectively. The present synthesis technique to produce a highly ordered ZnO nanowire array and a fabricated gas sensor has great potential to push the low cost gas sensing nanotechnology.
Extracted statement — ZnO form: Nanowires
Research field: Engineering
Title: Photoluminescence based H2 and O2 gas sensing by ZnO nanowires
Abstract: Gas sensing properties of ZnO nanowires prepared via thermal chemical vapor deposition method were investigated by analyzing change in their photoluminescence (PL) spectra. The as-synthesized nanowires show two different PL peaks positioned at 380 nm and 520 nm. The 380 nm emission is ascribed to near band edge emission, and the green peak (520 nm) appears due to the oxygen vacancy defects. The intensity of the green PL signal enhances upon hydrogen gas exposure, whereas it gets quenched upon oxygen gas loading. The ZnO nanowires' sensing response values were observed as about 54% for H2 gas and 9% for O2 gas at room temperature for 50 sccm H2/O2 gas flow rate. The sensor response was also analyzed as a function of sample temperature ranging from 300 K to 400 K. A conclusion was derived from the observations that the H2/O2 gases affect the adsorbed oxygen species on the surface of ZnO nanowires. The adsorbed species result in the band bending and hence changes the depletion region which causes variation i...
Extracted statement — ZnO form: Nanowires
Research field: Engineering
Title: A Highly Sensitive Nonenzymatic Glucose Biosensor Based on the Regulatory Effect of Glucose on Electrochemical Behaviors of Colloidal Silver Nanoparticles on MoS2
Abstract: A novel and highly sensitive nonenzymatic glucose biosensor was developed by nucleating colloidal silver nanoparticles (AgNPs) on MoS2. The facile fabrication method, high reproducibility (97.5%) and stability indicates a promising capability for large-scale manufacturing. Additionally, the excellent sensitivity (9044.6 μA·mM−1·cm−2), low detection limit (0.03 μM), appropriate linear range of 0.1–1000 μM, and high selectivity suggests that this biosensor has a great potential to be applied for noninvasive glucose detection in human body fluids, such as sweat and saliva.
Extracted statement — keywords: nonenzymatic
Research field: Engineering
Title: Role of ALD Al2O3 Surface Passivation on the Performance of p-Type Cu2O Thin Film Transistors
Abstract: High-performance p-type oxide thin film transistors (TFTs) have great potential for many semiconductor applications. However, these devices typically suffer from low hole mobility and high off-state currents. We fabricated p-type TFTs with a phase-pure polycrystalline Cu2O semiconductor channel grown by atomic layer deposition (ALD). The TFT switching characteristics were improved by applying a thin ALD Al2O3 passivation layer on the Cu2O channel, followed by vacuum annealing at 300 °C. Detailed characterization by transmission electron microscopy-energy dispersive X-ray analysis and X-ray photoelectron spectroscopy shows that the surface of Cu2O is reduced following Al2O3 deposition and indicates the formation of a 1-2 nm thick CuAlO2 interfacial layer. This, together with field-effect passivation caused by the high negative fixed charge of the ALD Al2O3, leads to an improvement in the TFT performance by reducing the density of deep trap states as well as by reducing the accumulation of electrons in the semiconducting layer in the device off-state.
Extracted statement — keywords: Passivation
Research field: Engineering
Title: Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
Abstract: Two organolead halide perovskite nanocrystals, CH(3)NH(3)PbBr(3) and CH(3)NH(3)PbI(3), were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells. When self-assembled on mesoporous TiO(2) films, the nanocrystalline perovskites exhibit strong band-gap absorptions as semiconductors. The CH(3)NH(3)PbI(3)-based photocell with spectral sensitivity of up to 800 nm yielded a solar energy conversion efficiency of 3.8%. The CH(3)NH(3)PbBr(3)-based cell showed a high photovoltage of 0.96 V with an external quantum conversion efficiency of 65%.
Extracted statement — keywords: Perovskites
Research field: Engineering
Title: Highly Efficient and Stable Sn-Rich Perovskite Solar Cells by Introducing Bromine
Abstract: Compositional engineering of recently arising methylammonium (MA) lead (Pb) halide based perovskites is an essential approach for finding better perovskite compositions to resolve still remaining issues of toxic Pb, long-term instability, etc. In this work, we carried out crystallographic, morphological, optical, and photovoltaic characterization of compositional MASn0.6Pb0.4I3-xBrx by gradually introducing bromine (Br) into parental Pb-Sn binary perovskite (MASn0.6Pb0.4I3) to elucidate its function in Sn-rich (Sn:Pb = 6:4) perovskites. We found significant advances in crystallinity and dense coverage of the perovskite films by inserting the Br into Sn-rich perovskite lattice. Furthermore, light-intensity-dependent open circuit voltage (Voc) measurement revealed much suppressed trap-assisted recombination for a proper Br-added (x = 0.4) device. These contributed to attaining the unprecedented power conversion efficiency of 12.1% and Voc of 0.78 V, which are, to the best of our knowledge, the highest performance in the Sn-rich (≥60%) perovskite solar cells reported so far. In addition, impressive enhancement of photocurrent-output stability and little hysteresis were found, which paves the way for the development of environmentally benign (Pb reduction), stable monolithic tandem cells using the developed low band gap (1.24-1.26 eV) MASn0.6Pb0.4I3-xBrx with suggested composition (x = 0.2-0.4).
Extracted statement — keywords: Perovskites
Research field: Engineering
Title: Fabrication of Efficient Low-Bandgap Perovskite Solar Cells by Combining Formamidinium Tin Iodide with Methylammonium Lead Iodide
Abstract: Mixed tin (Sn)-lead (Pb) perovskites with high Sn content exhibit low bandgaps suitable for fabricating the bottom cell of perovskite-based tandem solar cells. In this work, we report on the fabrication of efficient mixed Sn-Pb perovskite solar cells using precursors combining formamidinium tin iodide (FASnI3) and methylammonium lead iodide (MAPbI3). The best-performing cell fabricated using a (FASnI3)0.6(MAPbI3)0.4 absorber with an absorption edge of ∼1.2 eV achieved a power conversion efficiency (PCE) of 15.08 (15.00)% with an open-circuit voltage of 0.795 (0.799) V, a short-circuit current density of 26.86(26.82) mA/cm(2), and a fill factor of 70.6(70.0)% when measured under forward (reverse) voltage scan. The average PCE of 50 cells we have fabricated is 14.39 ± 0.33%, indicating good reproducibility.
Extracted statement — keywords: Perovskites
Research field: Engineering
Title: Solar Blind Photodetectors Enabled by Nanotextured β-Ga2O3 Films Grown via Oxidation of GaAs Substrates
Abstract: A simple and inexpensive method for growing Ga<sub>2</sub>O<sub>3</sub> using GaAs wafers is demonstrated. Si-doped GaAs wafers are heated to 1050 °C in a horizontal tube furnace in both argon and air ambients in order to convert their surfaces to β-Ga<sub>2</sub>O<sub>3</sub>. The β-Ga<sub>2</sub>O<sub>3</sub> films are characterized using scanning electron micrograph, energy-dispersive X-ray spectroscopy, and X-ray diffraction. They are also used to fabricate solar blind photodetectors. The devices, which had nanotextured surfaces, exhibited a high sensitivity to ultraviolet (UV) illumination due in part to large surface areas. Furthermore, the films have coherent interfaces with the substrate, which leads to a robust device with high resistance to thermo-mechanical stress. The photoconductance of the β-Ga<sub>2</sub>O<sub>3</sub> films is found to increase by more than three orders of magnitude under 270 nm ultraviolet illumination with respect to the dark current. The fabricated device shows a responsivity of ∼292 mA/W at this wavelength.
Extracted statement — keywords: photodetector
Research field: Engineering
Title: Thermal annealing effect on β-Ga2O3 thin film solar blind photodetector heteroepitaxially grown on sapphire substrate
Abstract: This paper presents the effect of thermal annealing on β‐Ga2O3 thin film solar‐blind (SB) photodetector (PD) synthesized on c‐plane sapphire substrates by a low pressure chemical vapor deposition (LPCVD). The thin films were synthesized using high purity gallium (Ga) and oxygen (O2) as source precursors. The annealing was performed ex situ the under the oxygen atmosphere, which helped to reduce oxygen or oxygen‐related vacancies in the thin film. Metal/semiconductor/metal (MSM) type photodetectors were fabricated using both the as‐grown and annealed films. The PDs fabricated on the annealed films had lower dark current, higher photoresponse and improved rejection ratio (R250/R370 and R250/R405) compared to the ones fabricated on the as‐grown films. These improved PD performances are due to the significant reduction of the photo‐generated carriers trapped by oxygen or oxygen‐related vacancies.
Extracted statement — keywords: photodetector
Research field: Engineering
Title: Solar blind deep ultraviolet β-Ga2O3 photodetectors grown on sapphire by the Mist-CVD method
Abstract: In this report, we demonstrate high spectral responsivity (SR) solar blind deep ultraviolet (UV) β-Ga2O3 metal-semiconductor-metal (MSM) photodetectors grown by the mist chemical-vapor deposition (Mist-CVD) method. The β-Ga2O3 thin film was grown on c-plane sapphire substrates, and the fabricated MSM PDs with Al contacts in an interdigitated geometry were found to exhibit peak SR>150A/W for the incident light wavelength of 254 nm at a bias of 20 V. The devices exhibited very low dark current, about 14 pA at 20 V, and showed sharp transients with a photo-to-dark current ratio>105. The corresponding external quantum efficiency is over 7 × 104%. The excellent deep UV β-Ga2O3 photodetectors will enable significant advancements for the next-generation photodetection applications.
Extracted statement — keywords: Photodetectors
Research field: Engineering
Title: Efficiently Improving the Stability of Inverted Perovskite Solar Cells by Employing Polyethylenimine-Modified Carbon Nanotubes as Electrodes
Abstract: Inverted perovskite solar cells (PSCs) have been becoming more and more attractive, owing to their easy-fabrication and suppressed hysteresis, while the ion diffusion between metallic electrode and perovskite layer limit the long-term stability of devices. In this work, we employed a novel polyethylenimine (PEI) modified cross-stacked superaligned carbon nanotube (CSCNT) film in the inverted planar PSCs configurated FTO/NiO x/methylammonium lead tri-iodide (MAPbI3)/6, 6-phenyl C61-butyric acid methyl ester (PCBM)/CSCNT:PEI. By modifying CSCNT with a certain concentration of PEI (0.5 wt %), suitable energy level alignment and promoted interfacial charge transfer have been achieved, leading to a significant enhancement in the photovoltaic performance. As a result, a champion power conversion efficiency (PCE) of ∼11% was obtained with a Voc of 0.95 V, a Jsc of 18.7 mA cm-2, a FF of 0.61 as well as negligible hysteresis. Moreover, CSCNT:PEI based inverted PSCs show superior durability in comparison to the standard silver based devices, remaining over 85% of the initial PCE after 500 h aging under various conditions, including long-term air exposure, thermal, and humid treatment. This work opens up a new avenue of facile modified carbon electrodes for highly stable and hysteresis suppressed PSCs.
Extracted statement — keywords: Polyethylenimine
Research field: Engineering
Title: RF MEMS Switches With Enhanced Power-Handling Capabilities
Abstract: This paper reports on the experimental and theoretical characterization of RF microelectromechanical systems (MEMS) switches for high-power applications. First, we investigate the problem of self-actuation due to high RF power and we demonstrate switches that do not self-actuate or catastrophically fail with a measured RF power of up to 5.5 W. Second, the problem of switch stiction to the down state as a function of the applied RF power is also theoretically and experimentally studied. Finally, a novel switch design with a top electrode is introduced and its advantages related to RF power-handling capabilities are presented. By applying this technology, we demonstrate hot-switching measurements with a maximum power of 0.8 W. Our results, backed by theory and measurements, illustrate that careful design can significantly improve the power-handling capabilities of RF MEMS switches.
Extracted statement — keywords: Self-actuation
Research field: Engineering
Title: Sensitivity-enhanced temperature sensor by hybrid cascaded configuration of a Sagnac loop and a F-P cavity
Abstract: A hybrid cascaded configuration consisting of a fiber Sagnac interferometer (FSI) and a Fabry-Perot interferometer (FPI) was proposed and experimentally demonstrated to enhance the temperature intensity by the Vernier-effect. The FSI, which consists of a certain length of Panda fiber, is for temperature sensing, while the FPI acts as a filter due to its temperature insensitivity. The two interferometers have almost the same free spectral range, with the spectral envelope of the cascaded sensor shifting much more than the single FSI. Experimental results show that the temperature sensitivity is enhanced from −1.4 nm/°C (single FSI) to −29.0 (cascaded configuration). The enhancement factor is 20.7, which is basically consistent with theoretical analysis (19.9).
Extracted statement — keywords: Sensitivity
Research field: Engineering
Title: Ultra-Sensitive Strain Sensor Based on Femtosecond Laser Inscribed In-Fiber Reflection Mirrors and Vernier Effect
Abstract: One of the efficient techniques to enhance the sensitivity of optical fiber sensor is to utilize Vernier effect. However, the complex system structure, precisely controlled device fabrication, or expensive materials required for implementing the technique creates the difficulties for practical applications. Here, we propose a highly sensitive optical fiber strain sensor based on two cascaded Fabry–Perot interferometers and Vernier effect. Of the two interferometers, one is for sensing and the other for referencing, and they are formed by two pairs of in-fiber reflection mirrors fabricated by femtosecond laser pulse illumination to induce refractive-index-modified area in the fiber core. A relatively large distance between the two Fabry–Perot interferometers needs to be used to ensure the independent operation of the two interferometers. The fabrication of the device is simple, and the cavity's length can be precisely controlled by a computer-controlled three-dimensional micromachining platform. Moreover, as the device is based on the inner structure inside the optical fiber, good robustness of the device can be guaranteed. The experimental results obtained show that the strain sensitivity of the device is ∼28.11 pm/μϵ, while the temperature sensitivity achieved is ∼278.48 pm/°C.
Extracted statement — keywords: Sensitivity