Moussab/ORKG-training-evaluation-set huggingface dataset:
Research field: Planetary Sciences
Title: Silica polymorphs in lunar granite: Implications for granite petrogenesis on the Moon
Abstract: Abstract Granitic lunar samples largely consist of granophyric intergrowths of silica and K-feldspar. The identification of the silica polymorph present in the granophyre can clarify the petrogenesis of the lunar granites. The presence of tridymite or cristobalite would indicate rapid crystallization at high temperature. Quartz would indicate crystallization at low temperature or perhaps intrusive, slow crystallization, allowing for the orderly transformation from high-temperature silica polymorphs (tridymite or cristobalite). We identify the silica polymorphs present in four granitic lunar samples from the Apollo 12 regolith using laser Raman spectroscopy. Typically, lunar silica occurs with a hackle fracture pattern. We did an initial density calculation on the hackle fracture pattern of quartz and determined that the volume of quartz and fracture space is consistent with a molar volume contraction from tridymite or cristobalite, both of which are less dense than quartz. Moreover, we analyzed the silica in the granitic fragments from Apollo 12 by electron-probe microanalysis and found it contains up to 0.7 wt% TiO2, consistent with initial formation as the high-temperature silica polymorphs, which have more open crystal structures that can more readily accommodate cations other than Si. The silica in Apollo 12 granitic samples crystallized rapidly as tridymite or cristobalite, consistent with extrusive volcanism. The silica then inverted to quartz at a later time, causing it to contract and fracture. A hackle fracture pattern is common in silica occurring in extrusive lunar lithologies (e.g., mare basalt). The extrusive nature of these granitic samples makes them excellent candidates to be similar to the rocks that compose positive relief silicic features such as the Gruithuisen Domes.
Extracted statement — Relavance: Tridymite
Research field: Plasma and Beam Physics
Title: 2D spatially resolved O atom density profiles in an atmospheric pressure plasma jet: from the active plasma volume to the effluent
Abstract: Two-dimensional spatially resolved absolute atomic oxygen densities are measured within an atmospheric pressure micro plasma jet and in its effluent. The plasma is operated in helium with an admixture of 0.5% of oxygen at 13.56 MHz and with a power of 1 W. Absolute atomic oxygen densities are obtained using two photon absorption laser induced fluorescence spectroscopy. The results are interpreted based on measurements of the electron dynamics by phase resolved optical emission spectroscopy in combination with a simple model that balances the production of atomic oxygen with its losses due to chemical reactions and diffusion. Within the discharge, the atomic oxygen density builds up with a rise time of 600 µs along the gas flow and reaches a plateau of 8 × 1015 cm−3. In the effluent, the density decays exponentially with a decay time of 180 µs (corresponding to a decay length of 3 mm at a gas flow of 1.0 slm). It is found that both, the species formation behavior and the maximum distance between the jet nozzle and substrates for possible oxygen treatments of surfaces can be controlled by adjusting the gas flow.
Extracted statement — Unit_gas_flow_rate: slm
Research field: Plasma and Beam Physics
Title: Stark Broadening of Hydrogen Lines in a Plasma
Abstract: The frequency distributions of hydrogen lines broadened by the local fields of both ions and electrons in a plasma are calculated in the classical path approximation. The electron collisions are treated by an impact theory which takes into account the Stark splitting caused by the quasistatic ion fields. The ion field-strength distribution function used includes the effect of electron shielding and ion-ion correlations. The various approximations that were employed are examined for self-consistency and an accuracy of about 10% in the resulting line profiles is expected. Good agreement with experimental H/sub beta / profiles is obtained while there are deviations of factors of two with the usual Holtsmark theory. Asymptotic distributions for the line wings are given for astrophysical applications. Also here the electron effects are generally as important as the ion effects for all values of the electron density and in some cases the electron broadening is larger than the ion broadening. (auth)
Extracted statement — Comparison  to: Experiment
Research field: Plasma and Beam Physics
Title: Stark Broadening of Neutral Helium Lines in a Plasma
Abstract: The frequency distributions of spectral lines of nonhydrogenic atoms broadened by local fields of both electrons and ions in a plasma are calculated in the classical path approximation. The electron collisions are treated by an impact theory which takes into account deviations from adiabaticity. For the ion effects, the adiabatic approximation can be used to describe the time-dependent wave functions. The various approximations employed were examined for self-consistency, and an accuracy of about 20% in the resulting line profiles is expected. Good agreement with Wulff's experimental helium line profiles was obtained while there are large deviations from the adiabatic theory, especially for the line shifts. Asymptotic distributions for the line wings are given for astrophysical applications. Here the ion effects can be as important as the electron effects and lead to large asymmetries, but near the line core electrons usually dominate. Numerical results are tabulated for 24 neutral helium lines with principal quantum numbers up to five.
Extracted statement — Comparison  to: Experiment
Research field: Polymer Chemistry
Title: Current Technologies in Depolymerization Process and the Road Ahead
Abstract: Although plastic is considered an indispensable commodity, plastic pollution is a major concern around the world due to its rapid accumulation rate, complexity, and lack of management. Some political policies, such as the Chinese import ban on plastic waste, force us to think about a long-term solution to eliminate plastic wastes. Converting waste plastics into liquid and gaseous fuels is considered a promising technique to eliminate the harm to the environment and decrease the dependence on fossil fuels, and recycling waste plastic by converting it into monomers is another effective solution to the plastic pollution problem. This paper presents the critical situation of plastic pollution, various methods of plastic depolymerization based on different kinds of polymers defined in the Society of the Plastics Industry (SPI) Resin Identification Coding System, and the opportunities and challenges in the future.
Extracted statement — Method: depolymerization
Research field: Polymer Chemistry
Title: Hydrolysis and Solvolysis as Benign Routes for the End-of-Life Management of Thermoset Polymer Waste
Abstract: The production of thermoset polymers is increasing globally owing to their advantageous properties, particularly when applied as composite materials. Though these materials are traditionally used in more durable, longer-lasting applications, ultimately, they become waste at the end of their usable lifetimes. Current recycling practices are not applicable to traditional thermoset waste, owing to their network structures and lack of processability. Recently, researchers have been developing thermoset polymers with the right functionalities to be chemically degraded under relatively benign conditions postuse, providing a route to future management of thermoset waste. This review presents thermosets containing hydrolytically or solvolytically cleavable bonds, such as esters and acetals. Hydrolysis and solvolysis mechanisms are discussed, and various factors that influence the degradation rates are examined. Degradable thermosets with impressive mechanical, thermal, and adhesion behavior are discussed, illustrating that the design of material end of life need not limit material performance. Expected final online publication date for the Annual Review of Chemical and Biomolecular Engineering, Volume 11 is June 8, 2020. Please see http://www.annualreviews.org/page/journal/pubdates for revised estimates.
Extracted statement — Method: solvolysis
Research field: Polymer Chemistry
Title: Biocatalytic Degradation Efficiency of Postconsumer Polyethylene Terephthalate Packaging Determined by Their Polymer Microstructures
Abstract: Polyethylene terephthalate (PET) is the most important mass‐produced thermoplastic polyester used as a packaging material. Recently, thermophilic polyester hydrolases such as TfCut2 from Thermobifida fusca have emerged as promising biocatalysts for an eco‐friendly PET recycling process. In this study, postconsumer PET food packaging containers are treated with TfCut2 and show weight losses of more than 50% after 96 h of incubation at 70 °C. Differential scanning calorimetry analysis indicates that the high linear degradation rates observed in the first 72 h of incubation is due to the high hydrolysis susceptibility of the mobile amorphous fraction (MAF) of PET. The physical aging process of PET occurring at 70 °C is shown to gradually convert MAF to polymer microstructures with limited accessibility to enzymatic hydrolysis. Analysis of the chain‐length distribution of degraded PET by nuclear magnetic resonance spectroscopy reveals that MAF is rapidly hydrolyzed via a combinatorial exo‐ and endo‐type degradation mechanism whereas the remaining PET microstructures are slowly degraded only by endo‐type chain scission causing no detectable weight loss. Hence, efficient thermostable biocatalysts are required to overcome the competitive physical aging process for the complete degradation of postconsumer PET materials close to the glass transition temperature of PET.
Extracted statement — Performed at temperature: temperature
Research field: Polymer Chemistry
Title: Biocatalytic Degradation Efficiency of Postconsumer Polyethylene Terephthalate Packaging Determined by Their Polymer Microstructures
Abstract: Polyethylene terephthalate (PET) is the most important mass‐produced thermoplastic polyester used as a packaging material. Recently, thermophilic polyester hydrolases such as TfCut2 from Thermobifida fusca have emerged as promising biocatalysts for an eco‐friendly PET recycling process. In this study, postconsumer PET food packaging containers are treated with TfCut2 and show weight losses of more than 50% after 96 h of incubation at 70 °C. Differential scanning calorimetry analysis indicates that the high linear degradation rates observed in the first 72 h of incubation is due to the high hydrolysis susceptibility of the mobile amorphous fraction (MAF) of PET. The physical aging process of PET occurring at 70 °C is shown to gradually convert MAF to polymer microstructures with limited accessibility to enzymatic hydrolysis. Analysis of the chain‐length distribution of degraded PET by nuclear magnetic resonance spectroscopy reveals that MAF is rapidly hydrolyzed via a combinatorial exo‐ and endo‐type degradation mechanism whereas the remaining PET microstructures are slowly degraded only by endo‐type chain scission causing no detectable weight loss. Hence, efficient thermostable biocatalysts are required to overcome the competitive physical aging process for the complete degradation of postconsumer PET materials close to the glass transition temperature of PET.
Extracted statement — Enzyme: fusca
Research field: Science
Title: Undifferentiated embryonal sarcoma of the liver mimicking acute appendicitis. Case report and review of the literature
Abstract: Abstract Background Undifferentiated embryonal sarcoma (UES) of liver is a rare malignant neoplasm, which affects mostly the pediatric population accounting for 13% of pediatric hepatic malignancies, a few cases has been reported in adults. Case presentation We report a case of undifferentiated embryonal sarcoma of the liver in a 20-year-old Caucasian male. The patient was referred to us for further investigation after a laparotomy in a district hospital for spontaneous abdominal hemorrhage, which was due to a liver mass. After a through evaluation with computed tomography scan and magnetic resonance imaging of the liver and taking into consideration the previous history of the patient, it was decided to surgically explore the patient. Resection of I–IV and VIII hepatic lobe. Patient developed disseminated intravascular coagulation one day after the surgery and died the next day. Conclusion It is a rare, highly malignant hepatic neoplasm, affecting almost exclusively the pediatric population. The prognosis is poor but recent evidence has shown that long-term survival is possible after complete surgical resection with or without postoperative chemotherapy.
Extracted statement — Sex: Male
Research field: Science
Title: DNA methylation and embryogenic compe- tence in leaves and callus of napiergrass (Pennisetum purpureum Schum
Abstract: Quantitative and qualitative levels of DNA methylation were evaluated in leaves and callus of Pennisetum purpureum Schum. The level of methylation did not change during leaf differentiation or aging and similar levels of methylation were found in embryogenic and nonembryogenic callus.
Extracted statement — Comparison: none
Research field: Science
Title: RIGHT HEPATOLOBECTOMY FOR PRIMARY MESENCHYMOMA OF THE LIVER*
Abstract: SUMMARYA case report of a large primary malignant mesenchymoma of the liver is presented. This tumor was successfully removed with normal liver tissue surrounding the tumor by right hepatolobectomy. The pathologic characteristics and clinical behavior of tumors falling into this general category are
Extracted statement — Laboratory fi ndings: Normal
Research field: Science
Title: Hepatic sarcomas in adults: a review of 25 cases.
Abstract: Twenty-five patients with an apparently primary sarcoma of the liver are reviewed. Presenting complaints were non-specific, but hepatomegaly and abnormal liver function tests were usual. Use of the contraceptive pill (four of 11 women) was identified as a possible risk factor; one patient had previously been exposed to vinyl chloride monomer. Detailed investigation showed that the primary tumour was extrahepatic in nine of the 25 patients. Distinguishing features of the 15 patients with confirmed primary hepatic sarcoma included a lower incidence of multiple hepatic lesions and a shorter time from first symptoms to diagnosis, but the most valuable discriminator was histology. Angiosarcomas and undifferentiated tumours were all of hepatic origin, epithelioid haemangioendotheliomas (EHAE) occurred as primary and secondary lesions and all other differentiated tumours arose outside the liver. The retroperitoneum was the most common site of an occult primary tumour and its careful examination therefore crucial: computed tomography scanning was found least fallible in this respect in the present series. Where resection (or transplantation), the best treatment, was not possible, results of therapy were disappointing, prognosis being considerably worse for patients with primary hepatic tumours. Patients with EHAE had a better overall prognosis regardless of primary site.
Extracted statement — Laboratory fi ndings: Normal
Research field: Science
Title: Undifferentiated Sarcoma of the Liver in a 21-year-old Woman: Case Report
Abstract: A successful surgical case of malignant undifferentiated (embryonal) sarcoma of the liver (USL), a rare tumor normally found in children, is reported. The patient was a 21-year-old woman, complaining of epigastric pain and abdominal fullness. Chemical analyses of the blood and urine and complete blood counts revealed no significant changes, and serum alpha-fetoprotein levels were within normal limits. A physical examination demonstrated a film, slightly tender lesion at the liver's edge palpable 10 cm below the xiphoid process. CT scan and ultrasonography showed an oval mass, confined to the left lobe of the liver, which proved to be hypovascular on angiography. At laparotomy, a large, 18 x 15 x 13 cm tumor, found in the left hepatic lobe was resected. The lesion was dark red in color, encapsulated, smooth surfaced and of an elastic firm consistency. No metastasis was apparent. Histological examination resulted in a diagnosis of undifferentiated sarcoma of the liver. Three courses of adjuvant chemotherapy, including adriamycin, cis-diaminodichloroplatinum, vincristine and dacarbazine were administered following the surgery with no serious adverse effects. The patient remains well with no evidence of recurrence 12 months after her operation.
Extracted statement — Laboratory fi ndings: Normal
Research field: Science
Title: Undifferentiated (Embryonal) Sarcoma of the Liver
Abstract: A 10‐year‐old girl with undifferentiated (embryonal) sarcoma of the liver reported here had abdominal pain, nausea, vomiting and weakness when she was 8 years old. Chemical analyses of the blood and urine were normal. Serum alpha‐fetoprotein was within normal limits. She died of cachexia 1 year and 8 months after the onset of symptoms. Autopsy showed a huge tumor mass in the liver and a few metastatic nodules in the lungs, which were consistent histologically with undifferenitated sarcoma of the liver. To our knowledge, this is the second case report of hepatic undifferentiated sarcoma of children in Japan, the feature being compatible with the description of Stocker and Ishaka.
Extracted statement — Laboratory fi ndings: Normal
Research field: Science
Title: Real Exchange Rate Volatility and U.S. Bilateral Trade: A VAR Approach
Abstract: This paper uses VAR models to investigate the impact of real exchange rate volatility on U.S. bilateral imports from the United Kingdom, France, Germany, Japan and Canada. The VAR systems include U.S. and foreign macro variables, and are estimated separately for each country. The major results suggest that the effect of volatility on imports is weak, although permanent shocks to volatility do have a negative impact on this measure of trade, and those effects are relatively more important over the flexible rate period. Copyright 1989 by MIT Press.
Extracted statement — Nominal or real exchange rate used: Real
Research field: Science
Title: The Effect of Real Exchange Rate Uncertainty on Exports: Empirical Evidence
Abstract: Unless very specific assumptions are made, theory alone cannot determine the sign of the relation between real exchange rate uncertainty and exports. On the one hand, convexity of the profit function with respect to prices implies that an increase in price uncertainty raises the expected returns in the export sector. On the other, potential asymmetries in the cost of adjusting factors of production (for example, investment irreversibility) and risk aversion tend to make the uncertainty-exports relation negative. This article examines these issues using a simple risk-aversion model. Export equations allowing for uncertainty are then estimated for six developing countries. Contrary to the ambiguity of the theory, the empirical relation is strongly negative. Estimates indicate that a 5 percent increase in the annual standard deviation of the real exchange rate can reduce exports by 2 to 30 percent in the short run. These effects are substantially magnified in the long run.
Extracted statement — Nominal or real exchange rate used: Real
Research field: Science
Title: Estimating the impact of exchange rate volatility on exports: evidence from Asian countries
Abstract: The paper examines the impact of exchange rate volatility on the exports of five Asian countries. The countries are Turkey, South Korea, Malaysia, Indonesia and Pakistan. The impact of a volatility term on exports is examined by using an Engle-Granger residual-based cointegrating technique. The results indicate that the exchange rate volatility reduced real exports for these countries. This might mean that producers in these countries are risk-averse. The producers will prefer to sell in domestic markets rather than foreign markets if the exchange rate volatility increases.
Extracted statement — Nominal or real exchange rate used: Real
Research field: Science
Title: Exchange Rate Uncertainty in Turkey and its Impact on Export Volume
Abstract: This paper investigates the impact of real exchange rate volatility on Turkey’s exports to its most important trading partners using quarterly data for the period 1982 to 2001. Cointegration and error correction modeling approaches are applied, and estimates of the cointegrating relations are obtained using Johansen’s multivariate procedure. Estimates of the short-run dynamics are obtained through the error correction technique. Our results indicate that exchange rate volatility has a significant positive effect on export volume in the long run. This result may indicate that firms operating in a small economy, like Turkey, have little option for dealing with increased exchange rate risk.
Extracted statement — Nominal or real exchange rate used: Real
Research field: Science
Title: On the Relationship Between CO 2 Emissions and Economic Growth: The Mauritian Experience
Abstract: This paper analyses the relationship between GDP and carbon dioxide emissions for Mauritius and vice-versa in a historical perspective. Using rigorous econometrics analysis, our results suggest that the carbon dioxide emission trajectory is closely related to the GDP time path. We show that emissions elasticity on income has been increasing over time. By estimating the EKC for the period 1975-2009, we were unable to prove the existence of a reasonable turning point and thus no EKC “U” shape was obtained. Our results suggest that Mauritius could not curb its carbon dioxide emissions in the last three decades. Thus, as hypothesized, the cost of degradation associated with GDP grows over time and it suggests that the economic and human activities are having increasingly negative environmental impacts on the country as cpmpared to their economic prosperity.
Extracted statement — Type of data: time
Research field: Science
Title: Hepatic sarcomas in adults: a review of 25 cases.
Abstract: Twenty-five patients with an apparently primary sarcoma of the liver are reviewed. Presenting complaints were non-specific, but hepatomegaly and abnormal liver function tests were usual. Use of the contraceptive pill (four of 11 women) was identified as a possible risk factor; one patient had previously been exposed to vinyl chloride monomer. Detailed investigation showed that the primary tumour was extrahepatic in nine of the 25 patients. Distinguishing features of the 15 patients with confirmed primary hepatic sarcoma included a lower incidence of multiple hepatic lesions and a shorter time from first symptoms to diagnosis, but the most valuable discriminator was histology. Angiosarcomas and undifferentiated tumours were all of hepatic origin, epithelioid haemangioendotheliomas (EHAE) occurred as primary and secondary lesions and all other differentiated tumours arose outside the liver. The retroperitoneum was the most common site of an occult primary tumour and its careful examination therefore crucial: computed tomography scanning was found least fallible in this respect in the present series. Where resection (or transplantation), the best treatment, was not possible, results of therapy were disappointing, prognosis being considerably worse for patients with primary hepatic tumours. Patients with EHAE had a better overall prognosis regardless of primary site.
Extracted statement — Symptoms and signs: hepatomegaly