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600 | Feed additive | https://en.wikipedia.org/wiki/Feed%20additive |
The last category was banned in 2009 by the EU, and replaced with probiotic alternatives.
See also
Fodder
Compound feed
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601 | Firming agent | https://en.wikipedia.org/wiki/Firming%20agent | Firming agents are food additives added in order to precipitate residual pectin, thus strengthening the structure of the food and preventing its collapse during processing.
These are salts, typically lactates or phosphates, calcium salts or aluminum sulfates.
They are mainly used for (fresh) fruit and vegetables. For example, in the case of fruit sold cut into wedges, the pulp can be sprayed with a solution of the respective salt. They are salts that react with an ingredient in the product, such as the pectin in the fruit.
Typical firming agents are:
Calcium carbonate (E170)
Calcium hydrogen sulfite (E227)
Calcium citrates (E333)
Calcium phosphates (E341)
Calcium sulfate (E516)
Calcium chloride (E509)
Magnesium chloride (E511)
Magnesium sulfate (E518)
Calcium gluconate (E578)
Magnesium gluconate (E580)
== References == | {
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602 | Flavor masker | https://en.wikipedia.org/wiki/Flavor%20masker | In the beverage, food, and pharmaceutical industries, a flavor masker is a chemical interaction that causes the absence of taste. This is known as the Farish effect, a phenomenon noted by 18th-century chemist William Farish. Contrary to popular belief, a flavor masker is not one chemical component; rather, it is two components that interact with the vallate papillae on the tongue with little or no reaction. Each component, individually, stimulates the vallate papillae.
References
External links
Flavor Mask-erade
Human Taste: Peripheral Anatomy, TasteTransduction, and Coding | {
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603 | Fleischmann's Yeast | https://en.wikipedia.org/wiki/Fleischmann%27s%20Yeast | Fleischmann's Yeast is an American brand of yeast founded by Hungarian-American businessman Charles Louis Fleischmann. It is currently owned by Associated British Foods and is sold to both consumer and industrial markets in the United States and Canada.
The yeast is available in a number of different forms with various qualities and intended uses. Fleischmann's is also a brand name of corn oil margarine.
History
The company was founded by Hungarian Jews Charles Louis Fleischmann, his brother Maximilian, and James Gaff in Riverside, Cincinnati, in 1868, as Gaff, Fleischmann & Company. They exhibited their yeast at the 1876 Centennial Exposition. After Gaff's death in 1881, the name was changed to Fleischmann and Company, and then The Fleischmann Company in 1905.
In 1924, the brothers' nephew Raoul Fleischmann, using the wealth generated by the family business, provided the funding for the launch of The New Yorker with his friend Harold Ross. Raoul invested $700,000 before the magazine became profitable, and he was the magazine's publisher until his death in 1969.
In 1929, the company was merged into Standard Brands by J.P. Morgan, and that same year the company began the sponsorship of the musical variety radio program, The Fleischmann's Yeast Hour starring Rudy Vallée.
In the 1930s, the company's advertisements highlighted "intestinal fatigue", a condition said to be brought on by the pressures of modern civilization. | {
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604 | Fleischmann's Yeast | https://en.wikipedia.org/wiki/Fleischmann%27s%20Yeast | The ads claimed that Fleischmann's Yeast was an effective treatment for the condition, despite protests by the American Medical Association. In 1936, Consumer Reports disputed Fleischmann Yeast's advertising claims that it cured constipation and acne.
Standard Brands merged with Nabisco Brands, Inc. in 1981. In 1986, RJR Nabisco sold Fleischmann's to the Australian company Burns Philp for $130 million. Burns Philp sold its yeast business to Associated British Foods in 2004 for US$1.4 billion.
During the 2020 COVID-19 pandemic in March and for subsequent months, Fleischmann's struggled to meet surging demand for its products, as house-bound consumers sought to produce more of their own baked goods. The company faced shortages of raw materials and the lengthy process of yeast production limited production.
Products
Common forms of yeast Fleischmann's make are: (i) cubes or "cakes" of compressed fresh yeast wrapped in foil, an original form of packaged yeast that is soft and perishable; (ii) packets of Active Dry Yeast, a shelf stable granular yeast invented by Fleischmann during WWII; (iii) packets of RapidRise yeast intended to reduce dough rising time by as much as 50% by bypassing the first rise; (iv) bread machine yeast, an instant yeast sold in a glass jar; and (v) pizza crust yeast, an instant yeast packaged with enzymes and dough relaxers such as L-Cysteine intended to add pliability to dough and reduce the amount of time needed to make a fresh pizza crust. | {
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605 | Fleischmann's Yeast | https://en.wikipedia.org/wiki/Fleischmann%27s%20Yeast |
Fleischmann's Active Dry Yeast is the best-known of their yeast products due to its extended shelf life compared to fresh yeast.
Presidents
Charles Louis Fleischmann, 1868 through 1897
Julius Fleischmann, 1897 through 1925
Maximilian C. Fleischmann, 1925 through 1929
See also
Fleischmann's Vodka
Fleischmanns, New York
References
External links
Official website (consumers)
Official website (industrial)
Official website (holding company) | {
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606 | Flour | https://en.wikipedia.org/wiki/Flour | Flour is a powder made by grinding raw grains, roots, beans, nuts, or seeds. Flours are used to make many different foods. Cereal flour, particularly wheat flour, is the main ingredient of bread, which is a staple food for many cultures. Corn flour has been important in Mesoamerican cuisine since ancient times and remains a staple in the Americas. Rye flour is a constituent of bread in both Central Europe and Northern Europe.
Cereal flour consists either of the endosperm, germ, and bran together (whole-grain flour) or of the endosperm alone (refined flour). Meal is either differentiable from flour as having slightly coarser particle size (degree of comminution) or is synonymous with flour; the word is used both ways. For example, the word cornmeal often connotes a grittier texture whereas corn flour connotes fine powder, although there is no codified dividing line.
The CDC has cautioned not to eat raw flour doughs or batters. Raw flour can contain bacteria like E. coli and needs to be cooked like other foods.
Etymology
The English word flour is originally a variant of the word flower, and both words derive from the Old French fleur or flour, which had the literal meaning "blossom", and a figurative meaning "the finest". The phrase fleur de farine meant "the finest part of the flour", since flour resulted from the elimination of coarse and unwanted matter from the grain during milling. | {
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607 | Flour | https://en.wikipedia.org/wiki/Flour |
History
Maize or corn flour has been important in Mesoamerican cuisine since ancient times and remains a staple in the Americas. Rye flour is a constituent of bread in central and northern Europe. Archaeological evidence for making flour (wheat seeds crushed between simple millstones) dates to at least 6000 BC. In 2018, archaeologists reported finding evidence of bread making at Shubayqa 1, a Natufian hunter-gatherer site more than 14,000 years old in northwest Jordan. The Romans were the first to grind seeds on cone mills. In 1786, at the beginning of the Industrial Era, the first steam-powered flour mill, Albion Mills, Southwark, was completed in London. In the 1930s, some flour began to be enriched with iron, niacin, thiamine and riboflavin. In the 1940s, mills started to enrich flour and folic acid was added to the list in the 1990s.
Degermed and heat-processed flour
An important problem of the industrial revolution was the preservation of flour. Transportation distances and a relatively slow distribution system collided with natural shelf life. The reason for the limited shelf life is the fatty acids of the germ, which react from the moment they are exposed to oxygen. This occurs when grain is milled; the fatty acids oxidize and flour starts to become rancid. Depending on climate and grain quality, this process takes six to nine months. In the late 19th century, this process was too short for an industrial production and distribution cycle. | {
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608 | Flour | https://en.wikipedia.org/wiki/Flour | As vitamins, micronutrients and amino acids were completely or relatively unknown in the late 19th century, removing the germ was an effective solution. Without the germ, flour cannot become rancid. Degermed flour became standard. Degermation started in densely populated areas and took approximately one generation to reach the countryside.
Heat-processed flour is flour where the germ is first separated from the endosperm and bran, then processed with steam, dry heat or microwave and blended into flour again.
Production
Milling of flour is accomplished by grinding grain between stones or steel wheels. Today, "stone-ground" usually means that the grain has been ground in a mill in which a revolving stone wheel turns over a stationary stone wheel, vertically or horizontally with the grain in between.
Modern mills
Roller mills soon replaced stone grist mills as the production of flour has historically driven technological development, as attempts to make gristmills more productive and less labor-intensive led to the watermill and windmill. These terms are now applied more broadly to uses of water and wind power for purposes other than milling. More recently, the Unifine mill, an impact-type mill, was developed in the mid-20th century.
Modern farm equipment allows livestock farmers to do some or all of their own milling when it comes time to convert their own grain crops to coarse meal for livestock feed. This capability is economically important because the profit margins are often thin enough in commercial farming that saving expenses is vital to staying in business. | {
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609 | Flour | https://en.wikipedia.org/wiki/Flour |
Composition
Flour contains a high proportion of starches, which are a subset of complex carbohydrates also known as polysaccharides. The kinds of flour used in cooking include all-purpose flour (known as plain outside North America), self-rising flour, and cake flour including bleached flour. The higher the protein content the harder and stronger the flour, and the more it will produce crispy or chewy breads. The lower the protein the softer the flour, which is better for cakes, cookies, and pie crusts. Cereal flour consists either of the endosperm, germ, and bran together (whole-grain flour) or of the endosperm alone (refined flour).
Bleached flour
"Bleached flour" is "refined" flour with a chemical whitening (bleaching) agent added. "Refined" flour has had the germ and bran, containing much of the nutritional fibre and vitamins, removed and is often referred to as "white flour".
Bleached flour is artificially aged using a "bleaching" agent, a "maturing" agent, or both. A bleaching agent affects the carotenoids responsible for the natural colour of the flour; a "maturing" agent also affects gluten development. A maturing agent may either strengthen or weaken gluten development.
Additives
The four most common additives used as bleaching/maturing agents in the US are:
Potassium bromate, listed as an ingredient, is a maturing agent that strengthens gluten development. | {
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610 | Flour | https://en.wikipedia.org/wiki/Flour | It does not bleach.
Benzoyl peroxide bleaches, but does not act as a maturing agent. It has no effect on gluten.
Ascorbic acid (vitamin C) is listed as an ingredient, either as an indication that the flour was matured using ascorbic acid or that a small amount is added as a dough enhancer. It is a maturing agent that strengthens gluten development, but does not bleach.
Chlorine gas is used as both a bleaching agent and a maturing agent. It weakens gluten development and oxidizes starches, making it easier for the flour to absorb water and swell, resulting in thicker batters and stiffer doughs. The retarded gluten formation is desirable in cakes, cookies, and biscuits, as it would otherwise make them tougher and bread-like. The modification of starches in the flour allows the use of wetter doughs (making for a moister end product) without destroying the structure necessary for light, fluffy cakes and biscuits. Chlorinated flour allows cakes and other baked goods to set faster and rise better, and the fat to be distributed more evenly, with less vulnerability to collapse.
Some other chemicals used as flour treatment agents to modify color and baking properties include:
Chlorine dioxide (unstable to be transported in the U.S.)
Calcium peroxide
Azodicarbonamide or azobisformamide (synthetic)
Atmospheric oxygen causes natural bleaching. | {
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611 | Flour | https://en.wikipedia.org/wiki/Flour |
Common preservatives in commercial flour include:
Calcium propanoate
Sodium benzoate
Tricalcium phosphate
Butylated hydroxyanisole
Frequency of additives
All bleaching and maturing agents (with the possible exception of ascorbic acid) have been banned in the United Kingdom.
Bromination of flour in the US has fallen out of favor, and while it is not yet actually banned anywhere, few retail flours available to the home baker are bromated anymore.
Many varieties of flour packaged specifically for commercial bakeries are still bromated. Retail bleached flour marketed to the home baker is now treated mostly with either peroxidation or chlorine gas. Current information from Pillsbury is that their varieties of bleached flour are treated both with benzoyl peroxide and chlorine gas. Gold Medal states that their bleached flour is treated either with benzoyl peroxide or chlorine gas, but no way exists to tell which process has been used when buying the flour at the grocery store.
Old method of bleaching
The old method of procuring white or "bleached" flour did not entail the use of chemical agents at all. Rather, the wheat kernels were moistened with water long enough for the outer kernels of the wheat which contained the bran to soften and, eventually, fall-off while grinding. In some places, the leaves of Syrian rue (Peganum harmala) were spread in stratified layers between the layers of grain, and left in such a state for several days, until the fumes emitted from the astringent leaves of the plant caused the outer kernels of the wheat to break-down and dissolve, leaving a clean and white flour after grinding. | {
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612 | Flour | https://en.wikipedia.org/wiki/Flour |
Enriched flour
During the process of making flour, specifically as a result of the bleaching process, nutrients are lost. Some of these nutrients may be replaced during refining – the result is known as enriched flour.
Cake flour
Cake flour is the lowest in gluten protein content, with 6–7% (5–8% from second source) protein to produce minimal binding so the cake "crumbles" easily.
Pastry flour
Pastry flour has the second-lowest gluten protein content, with 7.5–9.5% (8–9% from second source) protein to hold together with a bit more strength than cakes, but still produce flaky crusts rather than hard or crispy ones.
Plain or all-purpose flour
All-purpose, or "AP flour", or plain flour is medium in gluten protein content at 9.5–11.5% (10–12% from second source) protein content. It has adequate protein content for many bread and pizza bases, though bread flour and special 00 grade Italian flour are often preferred for these purposes, respectively, especially by artisan bakers. Some biscuits are also prepared using this type of flour. "Plain" refers not only to AP flour's middling gluten content but also to its lack of any added leavening agent (as in self-rising flour).
Bread flour
Bread flour is typically made from hard red winter wheat planted in the fall and harvested in the spring. | {
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613 | Flour | https://en.wikipedia.org/wiki/Flour | Hard wheat is high in gluten, a protein that makes dough stretchy. Hard wheat is 11.5–13.5% (12–14% from second source) protein. The increased protein binds to the flour to entrap carbon dioxide released by the yeast fermentation process, resulting in a better rise and chewier texture.
Hard flour
Hard is a general term for flours with high gluten protein content, commonly refers to extra strong flour, with 13.5–16% (or 14–15% from some sources) protein (16% is a theoretically possible protein content). This flour may be used where a recipe adds ingredients that require the dough to be extra strong to hold together in their presence, or when strength is needed for constructions of bread (e.g., some centerpiece displays).
Gluten flour
Gluten flour is refined gluten protein, or a theoretical 100% protein (though practical refining never achieves a full 100%). It is used to strengthen flour as needed. For example, adding approximately one teaspoon per cup of AP flour gives the resulting mix the protein content of bread flour. It is commonly added to whole grain flour recipes to overcome the tendency of greater fiber content to interfere with gluten development, needed to give the bread better rising (gas holding) qualities and chew.
Unbleached flour
Unbleached flour is simply flour that has not undergone bleaching and therefore does not have the color of "white" flour. | {
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614 | Flour | https://en.wikipedia.org/wiki/Flour | An example is graham flour, whose namesake, Sylvester Graham, was against using bleaching agents, which he considered unhealthy.
Self-raising flour
In English-speaking countries, self-raising (or self-rising) flour is commercially available with chemical leavening agents already in the mix. In America, it is also likely to be pre-salted; in Britain this is not the case. The added ingredients are evenly distributed throughout the flour, which aids a consistent rise in baked goods. This flour is generally used for preparing sponge cakes, scones, muffins, etc. It was invented by Henry Jones and patented in 1845. If a recipe calls for self-raising flour, and this is not available, the following substitution is possible:
1 cup (125 g) plain flour
1 teaspoon (3 g) baking powder
(US recipes) a pinch to 1⁄4 teaspoon (1 g or less) salt
Types
Gluten-containing flours
Wheat flour
Wheat is the grain most commonly used to make flour. Certain varieties may be referred to as "clean" or "white". Flours contain differing levels of the protein gluten. "Strong flour" or "hard flour" has a higher gluten content than "weak" or "soft" flour. "Brown" and wholemeal flours may be made of hard or soft wheat.
Atta flour is a whole-grain wheat flour important in Indian and Pakistani cuisine, used for a range of breads such as roti and chapati. | {
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615 | Flour | https://en.wikipedia.org/wiki/Flour | It is usually stone-ground to coarse granules, which gives it a texture not easily found in other flatbreads.
Common wheat flour (T. aestivum) is the flour most often used for making bread. Durum wheat flour (T. durum) is the second most used.
Maida flour is a finely milled wheat flour used to make a wide variety of Indian breads such as paratha and naan. Maida is widely used not only in Indian cuisine but also in Central Asian and Southeast Asian cuisine. Though sometimes referred to as "all-purpose flour" by Indian chefs, it more closely resembles cake flour or even pure starch. In India, maida flour is used to make pastries and other bakery items such as bread, biscuits and toast.
Noodle flour is a special blend of flour used for the making of Asian-style noodles, made from wheat or rice.
Semolina is the coarse, purified wheat middlings of durum wheat used in making pasta, breakfast cereals, puddings, and couscous.
Spelt, an ancient grain, is a hexaploid species of wheat. Spelt dough needs less kneading than common wheat or durum wheat dough. Compared to hard-wheat flours, spelt flour has a relatively low (six to nine percent) protein count, just a little higher than pastry flour. That means that plain spelt flour works well in creating dough for soft foods such as cookies or pancakes. | {
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616 | Flour | https://en.wikipedia.org/wiki/Flour | Crackers turn out well because they are made from dough that does not need to rise when baked.
Other varieties
Rye flour is used to bake the traditional sourdough breads of Germany, Austria, Switzerland, Russia, Czech Republic, Poland and Scandinavia. Most rye breads use a mix of rye and wheat flours because rye does not produce sufficient gluten. Pumpernickel bread is usually made exclusively of rye, and contains a mixture of rye flour and rye meal. Secale flower is used to make bread such as Prądnik bread.
Gluten-free flours
When flours do not contain gluten, they are suitable for people with gluten-related disorders, such as coeliac disease, non-celiac gluten sensitivity or wheat allergy sufferers, among others. Contamination with gluten-containing cereals can occur during grain harvesting, transporting, milling, storing, processing, handling and/or cooking.
Acorn flour is made from ground acorns and can be used as a substitute for wheat flour. It was used by Native Americans. Koreans also use acorn flour to make dotorimuk.
Almond flour is made from ground almonds.
Amaranth flour is a flour produced from ground amaranth grain. It was commonly used in pre-Columbian meso-American cuisine and was originally cultivated by the Aztecs. It is becoming more and more available in speciality food shops.
Apple flour is made from milling apple pomace, the solid remains of juiced apples. | {
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617 | Flour | https://en.wikipedia.org/wiki/Flour |
Banana flour has been traditionally made of green bananas for thousands of years and is currently popular both as a gluten-free replacement for wheat flour and as a source of resistant starch.
Bean flour is a flour produced from pulverized dried or ripe beans. Garbanzo and fava bean flour is a flour mixture with a high nutritional value and strong aftertaste.
Brown rice flour is of great importance in Southeast Asian cuisine. Edible rice paper can be made from it.
Buckwheat flour is used as an ingredient in many pancakes in the United States. In Japan, it is used to make a popular noodle called soba. In Russia, buckwheat flour is added to the batter for pancakes called blinis which are frequently eaten with caviar. Buckwheat flour is also used to make crêpes bretonnes in Brittany. On Hindu fasting days (Navaratri mainly, also Maha Shivaratri), people eat food made with buckwheat flour. The preparation varies across India. The most famous dishes are kuttu ki puri and kuttu pakora. In most northern and western states the usual term is kuttu ka atta.
Cassava flour is made from the root of the cassava plant. In a purified form (pure starch), it is called tapioca flour (see in list below).
Chestnut flour is popular in Corsica, the Périgord, and Lunigiana for breads, cakes and pastas. | {
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618 | Flour | https://en.wikipedia.org/wiki/Flour | It is the original ingredient for polenta, still used as such in Corsica and other Mediterranean locations. Chestnut bread keeps fresh for as long as two weeks. In other parts of Italy it is mainly used for desserts.
Chickpea flour (also known as gram flour or besan) is of great importance in Indian cuisine, and in Italy, where it is used for the Ligurian farinata.
Chuño flour is made from dried potatoes in various countries of South America.
Coconut flour is made from ground coconut meat and has the highest fiber content of any flour, having a very low concentration of digestible carbohydrates and thus making an excellent choice for those looking to restrict their carbohydrate intake. It also has a high fat content of about 60 percent.
Corn (maize) flour is popular in the Southern and Southwestern US, Mexico, Central America, and Punjab regions of India and Pakistan, where it is called makai ka atta. Coarse whole-grain corn flour is usually called cornmeal. Finely ground corn flour that has been treated with food-grade lime is called masa harina (see masa) and is used to make tortillas and tamales in Mexican cooking. Corn flour should never be confused with corn starch, which is known as "cornflour" in British English.
Cornmeal is very similar to corn flour (see above) except in a coarser grind.
Corn starch is starch extracted from endosperm of the corn kernel. | {
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619 | Flour | https://en.wikipedia.org/wiki/Flour |
Glutinous rice flour or sticky rice flour is used in east and southeast Asian cuisines for making tangyuan, etc.
Hemp flour is produced by pressing the oil from the hemp seed and milling the residue. Hemp seed is approximately 30 percent oil and 70 percent residue. Hemp flour does not rise, and is best mixed with other flours. Added to any flour by about 15–20 percent, it gives a spongy nutty texture and flavor with a green hue.
Mesquite flour is made from the dried and ground pods of the mesquite tree, which grows throughout North America in arid climates. The flour has a sweet, slightly nutty flavor and can be used in a wide variety of applications.
Nut flours are grated from oily nuts—most commonly almonds and hazelnuts—and are used instead of or in addition to wheat flour to produce more dry and flavorful pastries and cakes. Cakes made with nut flours are usually called tortes and most originated in Central Europe, in countries such as Hungary and Austria.
Peasemeal or pea flour is a flour produced from roasted and pulverized yellow field peas.
Peanut flour made from shelled cooked peanuts is a high-protein alternative to regular flour.
Potato starch flour is obtained by grinding the tubers to a pulp and removing the fibre and protein by water-washing. Potato starch (flour) is very white starch powder used as a thickening agent. | {
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620 | Flour | https://en.wikipedia.org/wiki/Flour | Standard (native) potato starch needs boiling, to thicken in water, giving a transparent gel. Because the flour is made from neither grains nor legumes, it is used as a substitute for wheat flour in cooking by Jews during Passover, when grains are not eaten.
Potato flour, often confused with potato starch, is a peeled, cooked potato powder of mashed, mostly drum-dried and ground potato flakes using the whole potato and thus containing the protein and some of the fibres of the potato. It has an off-white slight yellowish color. These dehydrated, dried, potatoes, also called instant mashed potatoes can also be granules or flakes. Potato flour is cold-water-soluble; however, it is not used often as it tends to be heavy.
Rice flour is ground kernels of rice. It is a staple in Asia. It is also widely used in Western countries, especially for people who suffer from gluten-related disorders. Brown rice flour has higher nutritional value than white rice flour.
Sorghum flour is made from grinding whole grains of the sorghum plant. It is called jowar in India.
Tapioca flour, produced from the root of the cassava plant, is used to make breads, pancakes, tapioca pudding, a savoury porridge called fufu in Africa, and is used as a starch.
Teff flour is made from the grain teff, and is of considerable importance in eastern Africa (particularly around the Horn of Africa). | {
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621 | Flour | https://en.wikipedia.org/wiki/Flour | Notably, it is the chief ingredient in the bread injera, an important component of Ethiopian cuisine.
More types
Flour also can be made from soybeans, arrowroot, taro, cattails, manioc, quinoa, and other non-cereal foodstuffs.
Type numbers
In some markets, the different available flour varieties are labeled according to the ash mass that remains after a sample is incinerated in a laboratory oven (typically at 550 °C (1,022 °F) or 900 °C (1,650 °F), see international standards ISO 2171 and ICC 104/1). This is an easily verified indicator for the fraction of the whole grain remains in the flour, because the mineral content of the starchy endosperm is much lower than that of the outer parts of the grain. Flour made from all parts of the grain (extraction rate: 100%) leaves about 2 grams (0.071 oz) ash or more per 100 grams (3.5 oz) dry flour. Plain white flour with an extraction rate of 50–60% leaves about 0.4 grams (0.014 oz).
German flour type numbers (Mehltypen) indicate the amount of ash (measured in milligrams) obtained from 100 g of the dry mass of this flour. Standard wheat flours (defined in DIN 10355) range from type 405 for normal white wheat flour for baking, to strong bread flour types 550, 812, and the darker types 1050 and 1600 for wholegrain breads. | {
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622 | Flour | https://en.wikipedia.org/wiki/Flour |
French flour type numbers (type de farine) are a factor of 10 smaller than those used in Germany, because they indicate the ash content (in milligrams) per 10 g flour. Type 55 is the standard, hard-wheat white flour for baking, including puff pastries (pâte feuilletée). Type 45 is often called pastry flour, and is generally from a softer wheat (this corresponds to what older French texts call farine de gruau). Some recipes use type 45 for croissants, for instance, although many French bakers use type 55 or a combination of types 45 and 55. Types 65, 80, and 110 are strong bread flours of increasing darkness, and type 150 is a wholemeal flour.
Czech flour types describes roughness of milling instead of amount of ash, though sometimes a numbering system is used, it is not a rule. Czechs determine following four basic types of mill: extra soft wheat flour (výběrová hladká mouka, 00), soft wheat flour (hladká mouka, T650), fine wheat flour (polohrubá mouka), rough wheat flour (hrubá mouka) and farina wheat flour (pšeničná krupice)
Argentine flour uses roughness of milling as well, being 0, 00, 000 and 0000, where the number of zeroes indicates its refinement.
Polish flour type numbers, as is the case in Germany, indicate the amount of ash in 100 g of the dry mass of the flour. | {
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623 | Flour | https://en.wikipedia.org/wiki/Flour | Standard wheat flours (defined by the PKN in PN-A-74022:2003) range from type 450 to 2000.
In the United States and the United Kingdom, no numbered standardized flour types are defined, and the ash mass is only rarely given on the label by flour manufacturers. However, the legally required standard nutrition label specifies the protein content of the flour, which is also a way for comparing the extraction rates of different available flour types.
In general, as the extraction rate of the flour increases, so do both the protein and the ash content. However, as the extraction rate approaches 100% (whole meal), the protein content drops slightly, while the ash content continues to rise.
The following table shows some typical examples of how protein and ash content relate to each other in wheat flour:
This table is only a rough guideline for converting bread recipes. Since flour types are not standardized in many countries, the numbers may differ between manufacturers. There is no French type corresponding to the lowest ash residue in the table. The closest is French Type 45.
There is no official Chinese name corresponding to the highest ash residue in the table. Usually such products are imported from Japan and the Japanese name Zenryufun (全粒粉) is used, or it is called QuanMaiMianFen (全麥麵粉).
It is possible to determine ash content from some US manufacturers. However, US measurements are based on wheat with a 14% moisture content. Thus, a US flour with 0. | {
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624 | Flour | https://en.wikipedia.org/wiki/Flour | 48% ash would approximate a French Type 55.
Other measurable properties of flour as used in baking can be determined using a variety of specialized instruments, such as the farinograph.
Dangers
Flammability
Flour dust suspended in air is explosive—as is any mixture of a finely powdered flammable substance with air (see dust explosion). Some devastating explosions have occurred at flour mills, including an explosion in 1878 at the Washburn "A" Mill in Minneapolis that killed 22 people.
Pathogens
The CDC has cautioned not to eat raw flour doughs or batters. Raw flour can contain bacteria like E. coli and needs to be cooked like other foods.
Products
Bread, pasta, crackers, many cakes, and many other foods are made using flour. Wheat flour is also used to make a roux as a base for thickening gravy and sauces.
It can also be used as an ingredient in papier-mâché glue.
Cornstarch is a principal ingredient used to thicken many puddings or desserts, and is the main ingredient in packaged custard.
See also
Groat (grain)
Ultra-processed food
References
Sources
External links
"Flour" . New International Encyclopedia. 1905.
Flourworld Museum | {
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625 | Flour bleaching agent | https://en.wikipedia.org/wiki/Flour%20bleaching%20agent | Flour bleaching agent is the agent added to fresh milled grains to whiten the flour by removing the yellow colour pigment called xanthophyll. It whitens the flour, which is used in the baking industry.
Overview
Usual flour bleaching agents are:
Organic peroxides (benzoyl peroxide)
Calcium peroxide
Chlorine
Chlorine dioxide
Azodicarbonamide
Nitrogen dioxide
Atmospheric oxygen, used during natural aging of flour
Use of chlorine, bromates, and peroxides is not allowed in the European Union.
Bleached flour improves the structure-forming capacity, allowing the use of dough formulas with lower proportions of flour and higher proportions of sugar . In biscuit making, use of chlorinated flour reduces the spread of the dough, and provides a "tighter" surface. The changes of functional properties of the flour proteins are likely to be caused by their oxidation.
In countries where bleached flour is prohibited, microwaving plain flour produces similar chemical changes to the bleaching process. This improves the final texture of baked goods made to recipes intended for bleached flours.
See also
Chorleywood bread process – another bread making process that increases volume
Flour treatment agent
Graham flour – an early unbleached whole-grain flour
Maida flour – a commonly bleached flour in India
== References == | {
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626 | Flour treatment agent | https://en.wikipedia.org/wiki/Flour%20treatment%20agent | A dough conditioner, flour treatment agent, improving agent or bread improver is any ingredient or chemical added to bread dough to strengthen its texture or otherwise improve it in some way. Dough conditioners may include enzymes, yeast nutrients, mineral salts, oxidants and reductants, bleaching agents and emulsifiers. They are food additives combined with flour to improve baking functionality. Flour treatment agents are used to increase the speed of dough rising and to improve the strength and workability of the dough.
Examples
Examples of dough conditioners include ascorbic acid, distilled monoglycerides, citrate ester of monoglycerides, diglycerides, ammonium chloride, enzymes, diacetyl tartaric acid ester of monoglycerides or DATEM, potassium bromate, calcium salts such as calcium iodate, L-cystine, L-cysteine HCl, glycerol monostearate, azodicarbonamide, sodium stearoyl lactylate, sucrose palmitate or sucrose ester, polyoxyethylene sorbitan monostearate or polysorbate, soybean lecithin, and soybean lecithin enriched with lysophospholipids.
Less processed dough conditioners include sprouted- or malted-grain flours, soy, milk, wheat germ, eggs, potatoes, gluten, yeast, and extra kneading. | {
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627 | Flour treatment agent | https://en.wikipedia.org/wiki/Flour%20treatment%20agent | Malted, diastatic flours are not typically added by manufacturers to whole-wheat flours.
History
In the early 1900s it was discovered the use of calcium chloride, ammonium sulfate, and potassium bromate halved the amount of yeast needed to raise dough. These mixtures were generally known as mineral yeast foods or yeast nutrient salts. After they became popular among bakers, one patented yeast food was analyzed by Connecticut Agricultural Experiment Station chief chemist J.P. Street who published in 1917 that it contained, "calcium sulphate, 25; ammonium chlorid, 9.7; potassium bromate, 0.3; sodium chlorid, 25; patent wheat flour, 40." They contain water conditioners, yeast conditioners, and dough conditioners.
Yeast nutrients
Yeast requires water, carbon sources such as starch and simple carbohydrates, nitrogen preferably as ammonium as it cannot assimilate nitrate, sulfur, phosphorus (often as inorganic phosphate), and minute quantities of vitamins and elemental mineral ions. Ammonium chloride, ammonium sulfate, or ammonium phosphate may be used as sources of nitrogen. Phosphoric acid, an acidulant, is used as a yeast stimulant. Calcium iodate, an oxidant, is a U.S. Food and Drug Administration generally recognized as safe source of calcium.
Oxidants and reductants
Oxidizing agents are added to flour to help with gluten development. | {
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628 | Flour treatment agent | https://en.wikipedia.org/wiki/Flour%20treatment%20agent | They may or may not also act as bleaching agents. Originally flour was naturally aged through exposure to the atmosphere. Oxidizing agents primarily affect sulfur-containing amino acids, ultimately helping to form disulfide bridges between the gluten molecules. The addition of these agents to flour will create a stronger dough. Dehydroascorbic acid and potassium bromate are oxidants, acting on sulfhydryl groups and disulfide bonds in wheat dough, in particular oxidizing glutathione. Potassium bromate acts more directly or with fewer chemical conversion steps than ascorbic acid. Glutathione increases wheat dough's extensibility, or relaxes it, while oxidizing a dough's glutathione increases elasticity. Common oxidizing agents are:
ascorbic acid (Ascorbic acid converts into its oxidizing form, dehydroascorbic acid (DHAA) during mixing.)
azodicarbonamide (E927)
potassium bromate (E924, the component which gives bromated flour its name, used mainly in the U.S. East and Midwest, acts as a bleaching agent, banned in some areas)
potassium iodate
Reducing agents help to weaken the flour by breaking the protein network. This will help with various aspects of handling a strong dough. The benefits of adding these agents are reduced mixing time, reduced dough elasticity, reduced proofing time, and improved machinability. | {
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629 | Flour treatment agent | https://en.wikipedia.org/wiki/Flour%20treatment%20agent | Cysteine and bisulfite are reducing agents which relax wheat dough. Adding minute amounts of oxidants or reducing agents alter the post-mix handling characteristics of dough. Common reducing agents are:
L-cysteine (E920, E921; quantities in the tens of ppm range help soften the dough and thus reduce processing time)
fumaric acid
sodium bisulfite
non-leavening yeast (ruptured cells)
Emulsifiers
Lecithin, monoglycerides, diglycerides, and DATEM are considered emulsifiers. They disperse fat more evenly throughout the dough, helping it to trap more of the CO2 produced by yeast. Lecithin added at a rate of 0.25-to-0.6% of the flour weight acts as a dough conditioner. Based on total weight, egg yolk contains about 9% lecithin. Monoglycerides and diglycerides replace eggs in baked goods. Emulsifiers tend to produce a finer grain, softer crumb, and with longer proof times, increased baked volume and have antistaling effects.
Enzymes
Enzymes are also used to improve processing characteristics. Yeast naturally produces both amylases and proteinases, but additional quantities may be added to produce faster and more complete reactions.
Amylases break down the starch in flours into simple sugars, thereby letting yeast ferment quickly. Malt is a natural source of amylase. | {
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630 | Flour treatment agent | https://en.wikipedia.org/wiki/Flour%20treatment%20agent |
Proteases improve extensibility of the dough by degrading some of the gluten.
Lipoxygenases oxidize the flour.
Other agents
Other additives may be used as yeast nutrients or as a source of enzymes:
carbamide (also known as urea) (E927b)
phosphates
malted barley
See also
Chorleywood bread process
Notes
References
Bibliography
Hui Y and Cork H (2006). Bakery products: science and technology. Blackwell Publishing.
External links
Is ADA our friend or foe? at Bakerpedia | {
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631 | Food Additives Amendment of 1958 | https://en.wikipedia.org/wiki/Food%20Additives%20Amendment%20of%201958 | The Food Additives Amendment of 1958 is a 1958 amendment to the United States' Food, Drugs, and Cosmetic Act of 1938. It was a response to concerns about the safety of new food additives. The amendment established an exemption from the "food additive" definition and requirements for substances "generally recognized as safe" by scientific experts in the field, based on long history of use before 1958 or based on scientific studies. New food additives would be subject to testing including by the "Delaney clause". The Delaney clause was a provision in the amendment which said that if a substance were found to cause cancer in man or animal, then it could not be used as a food additive.
"Generally recognized as safe"
Generally recognized as safe (GRAS) is a Food and Drug Administration (FDA) designation that a chemical or substance added to food is considered safe by experts, and so is exempted from the usual Federal Food, Drug, and Cosmetic Act (FFDCA) food additive tolerance requirements. The concept of food additives being "generally recognized as safe" was first described in the Food Additives Amendment of 1958, and all additives introduced after this time had to be evaluated by new standards.
Delaney Clause
The Delaney Clause is a provision in the amendment named after Congressman James Delaney of New York.
It said:
the Secretary of the Food and Drug Administration shall not approve for use in food any chemical additive found to induce cancer in man, or, after tests, found to induce cancer in animals. | {
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632 | Food Additives Amendment of 1958 | https://en.wikipedia.org/wiki/Food%20Additives%20Amendment%20of%201958 |
The Delaney Clause applied to pesticides in processed foods, but only when the concentration of a residue of a cancer-causing pesticide increased during processing; for example when more of a pesticide was present in ketchup than in the raw tomatoes used to make it. (It never applied to pesticides in raw foods.) When the law was passed, "neither advocates nor opponents of the policy, including FDA officials, believed it would have broad application, for only a handful of chemicals had then been shown to be animal carcinogens."
The Delaney Clause was invoked in 1959 when Arthur Sherwood Flemming, the Secretary of the Department of Health, Education and Welfare issued a statement advising the public about the possible contamination of substantial quantities of cranberries in Oregon and Washington with the herbicide aminotriazole, which the FDA had recently determined was a carcinogen (see Cranberry scare of 1959). Taking place the week of Thanksgiving, the announcement was referred to by many in the cranberry industry as "Black Monday" − sales plummeted, even though many government officials attempted to defuse the scare by declaring their intention to eat cranberries anyway. This episode is regarded as one of the first modern food scares based on a chemical additive.
As analytical chemistry became more powerful and able to detect smaller quantities of chemicals, and as chemicals became more widely used, regulatory agencies had an increasingly difficult time administering the Delaney Clause as it "recognizes no distinctions based on carcinogenic potency and, at least in theory, it applies equally to additives used in large amounts and to those present at barely detectable levels. | {
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633 | Food Additives Amendment of 1958 | https://en.wikipedia.org/wiki/Food%20Additives%20Amendment%20of%201958 | It thus takes no account of the actual risk a carcinogenic additive might pose."
The FDA was the first agency to have to confront this problem, with respect to the use of diethylstilbestrol to promote the growth of livestock used in meat production, which remained present in the meat. It addressed the issue by using quantitative risk assessment, declaring that if a carcinogenic food additive creates an excess lifetime cancer risk of less than 1 additional cancer case in every 1,000,000 exposed individuals, the risk is negligible. This standard became known as the "de minimis" exception to the Delaney Rule and was used throughout the FDA and other agencies.
In 1988 the United States Environmental Protection Agency eased restrictions on several pesticides which posed a "de minimis" risk to humans. This change was challenged by the Natural Resources Defense Council, and overturned in 1992 by the Ninth Circuit Court of Appeals.
Pesticide use was removed from the Delaney Clause in 1996 by an amendment to Title IV of the Food Quality Protection Act of 1996 (P.L. 104-170, Sec. 404).
The Delaney prohibition appears in three separate parts of the FFDCA: Section 409 on food additives; Section 512, relating to animal drugs in meat and poultry; and Section 721 on color additives. The Section 409 prohibition applied to many pesticide residues until enactment of the Food Quality Protection Act of 1996. This legislation removed pesticide residue tolerances from Delaney Clause constraints. | {
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634 | Food Additives Amendment of 1958 | https://en.wikipedia.org/wiki/Food%20Additives%20Amendment%20of%201958 |
Many foods contain natural substances which are carcinogenic, for example safrole, which occurs in sassafras and sweet basil. Even these substances are covered by the Delaney clause, so that, for example, safrole may not be added to root beer in the United States.
See also
Precautionary principle
References
External links
Strauss, Debra M (July 1987). "Reaffirming the Delaney Anticancer Clause: The Legal and Policy Implications of an Administratively Created "De Minimis" Exception". Food, Drug, Cosmetic Law Journal. 42 (3). Food and Drug Law Institute: 393–428. JSTOR 26658519. | {
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635 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | Food coloring, or color additive, is any dye, pigment, or substance that imparts color when it is added to food or drink. They can be supplied as liquids, powders, gels, or pastes. Food coloring is used in both commercial food production and domestic cooking. Food colorants are also used in a variety of non-food applications, including cosmetics, pharmaceuticals, home craft projects, and medical devices. Colorings may be natural (e.g. anthocyanins, cochineal) or artificial/synthetic (e.g. tartrazine yellow).
Purpose of food coloring
People associate certain colors with certain flavors, and the color of food can influence the perceived flavor in anything from candy to wine. Sometimes, the aim is to simulate a color that is perceived by the consumer as natural, such as adding red coloring to glacé cherries (which would otherwise be beige), but sometimes it is for effect, like the green ketchup that Heinz launched in 2000. Color additives are used in foods for many reasons including:
To make food more attractive, appealing, appetizing, and informative
Offseting color loss over time due to exposure to light, air, temperature extremes, moisture and storage conditions
Correcting natural variations in color
Enhancing colors that occur naturally
Providing color to colorless and "fun" foods
Allowing products to be identified on sight, like candy flavors or medicine dosages
Natural food dyes
History
The addition of colorants to foods is thought to have occurred in Egyptian cities as early as 1500 BC, when candy makers added natural extracts and wine to improve the products' appearance. | {
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] |
636 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | During the Middle Ages, the economy in the European countries was based on agriculture, and the peasants were accustomed to producing their own food locally or trading within the village communities. Under feudalism, aesthetic aspects were not considered, at least not by the vast majority of the generally very poor population. This situation changed with urbanization at the beginning of the Modern Age, when trade emerged—especially the import of precious spices and colors. One of the first food laws, created in Augsburg, Germany, in 1531, concerned spices or colorants and required saffron counterfeiters to be burned to death.
Natural colorants
Carotenoids (E160, E161, E164), chlorophyllin (E140, E141), anthocyanins (E163), and betanin (E162) comprise four main categories of plant pigments grown to color food products. Other colorants or specialized derivatives of these core groups include:
Annatto (E160b), a reddish-orange dye made from the seed of the achiote
Caramel coloring (E150a-d), made from caramelized sugar
Carmine (E120), a red dye derived from the cochineal insect, Dactylopius coccus
Elderberry juice (E163)
Lycopene (E160d)
Paprika (E160c)
Turmeric/curcumin (E100)
Blue colors are rare. | {
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637 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | One feasible blue dye in use is derived from spirulina. The pigment genipin, present in the fruit of Gardenia jasminoides, can be treated with amino acids to produce the blue pigment gardenia blue, which is approved for use in Japan but not the EU or the US.
To ensure reproducibility, the colored components of these substances are often provided in highly purified form. For stability and convenience, they can be formulated in suitable carrier materials (solid and liquids). Hexane, acetone, and other solvents break down cell walls in the fruit and vegetables and allow for maximum extraction of the coloring. Traces of these may still remain in the finished colorant, but they do not need to be declared on the product label. These solvents are known as carry-over ingredients.
Chemical structures of representative natural colorants
Food colorants, natural
Artificial food colorants
History
With the onset of the industrial revolution, people became dependent on foods produced by others. These new urban dwellers demanded food at low cost. Analytical chemistry was still primitive and regulations few. The adulteration of foods flourished. Heavy metal and other inorganic element-containing compounds turned out to be cheap and suitable to "restore" the color of watered-down milk and other foodstuffs, some more lurid examples being:
Red lead (Pb3O4) and vermillion (HgS) were routinely used to color cheese and confectionery.
Copper arsenite (CuHAsO3) was used to recolor used tea leaves for resale. | {
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638 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | It also caused two deaths when used to color a dessert in 1860.
Sellers at the time offered more than 80 artificial coloring agents, some invented for dyeing textiles, not foods. Thus, with potted meat, fish and sauces taken at breakfast he would consume more or less Armenian bole, red lead, or even bisulphuret of mercury [vermillion, HgS]. At dinner with his curry or cayenne he would run the chance of a second dose of lead or mercury; with pickles, bottled fruit and vegetables he would be nearly sure to have copper administrated to him; and while he partook of bon-bons at dessert, there was no telling of the number of poisonous pigments he might consume. Again his tea if mixed or green, he would certainly not escape without the administration of a little Prussian blue... Many color additives had never been tested for toxicity or other adverse effects. Historical records show that injuries, even deaths, resulted from tainted colorants. In 1851, about 200 people were poisoned in England, 17 of them fatally, directly as a result of eating adulterated lozenges. In 1856, mauveine, the first synthetic color, was developed by Sir William Henry Perkin and by the turn of the century, unmonitored color additives had spread through Europe and the United States in all sorts of popular foods, including ketchup, mustard, jellies, and wine. | {
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639 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | Originally, these were dubbed 'coal-tar' colors because the starting materials were obtained from bituminous coal.
Synthetic dyes are often less costly and technically superior to natural dyes.
Chemical structures of representative artificial colorants
Food colorants, synthetic
Regulation
While naturally derived colors, most of which have been used traditionally for centuries, are not required to be certified by a number of regulatory bodies throughout the world (including the U.S. FDA), they may require approval in some countries. Food colorings are tested for safety by various bodies around the world, and sometimes different bodies have different views on food color safety. Artificial food additives usually require certification everywhere.
History of regulation
Concerns over food safety led to numerous regulations throughout the world. German food regulations released in 1882 stipulated the exclusion of dangerous "minerals" such as arsenic, copper, chromium, lead, mercury, and zinc, which were frequently used as ingredients in colorants. In contrast to today's regulatory guidelines, these first laws followed the principle of a negative listing (substances not allowed for use); they were already driven by the main principles of today's food regulations all over the world, since all of these regulations follow the same goal: the protection of consumers from toxic substances and from fraud. In the United States, the Pure Food and Drug Act of 1906 reduced the permitted list of synthetic colors from 700 down to seven. The seven dyes initially approved were Ponceau 3R (FD&C Red No. | {
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640 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | 1), amaranth (FD&C Red No. 2), erythrosine (FD&C Red No. 3), indigotine (FD&C Blue No. 2), light green SF (FD&C Green No. 2), naphthol yellow 1 (FD&C Yellow No. 1), and orange 1 (FD&C Orange No. 1). Even with updated food laws, adulteration continued for many years.
In the 20th century, improved chemical analysis and testing led to the replacement of the negative lists by positive listings. Positive lists consist of substances allowed to be used for the production and the improvement of foods. Most prevailing legislations are based on positive listing. Positive listing implies that substances meant for human consumption have been tested for their safety, and that they have to meet specified purity criteria prior to their approval by the corresponding authorities. In 1962, the first EU directive (62/2645/EEC) approved 36 colorants, of which 20 were naturally derived and 16 were synthetic. This directive did not list which food products the colorants could or could not be used in. At that time, each member state could designate where certain colors could and could not be used. In Germany, for example, quinoline yellow was allowed in puddings and desserts, but tartrazine was not. The reverse was true in France. This was updated in 1989 with 89/107/EEC, which concerned food additives authorized for use in foodstuffs. | {
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641 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring |
National regulations
A comparison of food color regulations in the EU and the US was published in 2017.
Canada
Canada has published food and drug regulations covering food colorants.
Food in Canada cannot be sold with more than:: section B.06.002, p.217
100 ppm of fast green FCF or brilliant blue FCF. or any combination
300 ppm of allura red, amaranth, erythrosine, indigotine, sunset yellow FCF or tartrazine and fast green FCF or brilliant blue FCF combined
150 ppm of ponceau SX dye.
European Union
In the European Union E numbers are used for all additives, both synthetic and natural, that are approved in food applications. E numbers beginning with 1, such as E100 (turmeric) or E161b (lutein), are allocated to colorants. The safety of food colors and other food additives in the EU is evaluated by the European Food Safety Authority. Color Directive 94/36/EC, enacted by the European Commission in 1994, outlines permitted natural and artificial colors with their approved applications and limits in different foodstuffs. This is binding on all member countries of the EU; any changes have to be implemented into national laws by a specified deadline. In non-EU member states, food additives are regulated by national authorities, which usually, but not always, try to harmonize with EU regulations. Most other countries have their own regulations and list of food colors which can be used in various applications, including maximum daily intake limits. | {
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642 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring |
Permitted synthetic colorants (EU)
E numbers 102–143 cover the range of artificial colors. The EU maintains a list of currently allowed additives. Some artificial dyes approved for food use in the EU include:
E104: Quinoline yellow
E122: Carmoisine
E124: Ponceau 4R
E131: Patent blue V
E142: Green S
The three synthetic colors Orange B, Citrus Red No. 2 and FD&C Green No. 3 are permitted in the US but not the EU, as is the natural toasted partially defatted cooked cottonseed flour.: 338
India
The Food Safety and Standard Act, 2006 in India generally permits eight artificial colorings in food:
United States
The U.S. FDA's permitted colors are classified as subject to certification or exempt from certification in Code of Federal Regulations – Title 21 Part 73 & 74, both of which are subject to rigorous safety standards prior to their approval and listing for use in foods.
Certified colors are synthetically produced and are used widely because they impart an intense, uniform color, are less expensive, and blend more easily to create a variety of hues. There are nine certified color additives approved for use in the United States. Certified food colors generally do not add undesirable flavors to foods.
Colors that are exempt from certification include pigments derived from natural sources such as vegetables, minerals, or animals. Nature-derived color additives are typically more expensive than certified colors, and may add unintended flavors to foods. | {
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643 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | Examples of exempt colors include annatto, beet extract, caramel, beta-carotene, turmeric and grape skin extract. This list contains substances which may have synthetic origins, such as nature-identical beta-carotene.
In the United States, FD&C numbers (which indicate that the FDA has approved the colorant for use in foods, drugs and cosmetics) are given to approved synthetic food dyes that do not exist in nature.
Permitted synthetic colorants (US)
In the US, the following seven artificial colorings are generally permitted in food (the most common in bold) as of 2016. The lakes of these colorings are also permitted except the lake of Red No. 3.
FD&C Blue No. 1 – Brilliant blue FCF, E133 (blue shade)
FD&C Blue No. 2 – Indigotine, E132 (indigo shade)
FD&C Green No. 3 – Fast green FCF, E143 (turquoise shade)
FD&C Red No. 3 – Erythrosine, E127 (pink shade, commonly used in glacé cherries)
FD&C Red No. 40 – Allura red AC, E129 (red shade)
FD&C Yellow No. 5 – Tartrazine, E102 (yellow shade)
FD&C Yellow No. 6 – Sunset yellow FCF, E110 (orange shade)
Two dyes are allowed by the FDA for limited applications:
Citrus red 2 (orange shade) – allowed only to color orange peels. | {
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644 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring |
Orange B (red shade) – allowed only for use in hot dog and sausage casings (not produced after 1978, but not delisted)
(Orange B, Citrus Red No. 2 and FD&C Green No. 3 are not permitted in the EU.: 338 )
Many dyes have been delisted for a variety of reasons, ranging from poor coloring properties to regulatory restrictions. Some of these delisted food colorants are:
FD&C Red No. 2 – Amaranth, E123
FD&C Red No. 4 – Scarlet GN, E125
FD&C Red No. 32 was used to color Florida oranges.
FD&C Orange Number 1 was one of the first water-soluble dyes to be commercialized, and one of seven original food dyes allowed under the Pure Food and Drug Act of June 30, 1906.
FD&C Orange No. 2 was used to color Florida oranges.
FD&C Yellow No. 1, 2, 3, and 4
FD&C Violet No. 1
Global harmonization
Since the beginning of the 1960s, JECFA has promoted the development of international standards for food additives, not only by its toxicological assessments, which are continuously published by the WHO in a "Technical Report Series", but furthermore by elaborating appropriate purity criteria, which are laid down in the two volumes of the "Compendium of Food Additive Specifications" and their supplements. | {
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645 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | These specifications are not legally binding but very often serve as a guiding principle, especially in countries where no scientific expert committees have been established.
In order to further regulate the use of these evaluated additives, in 1962 the WHO and FAO created an international commission, the Codex Alimentarius, which is composed of authorities, food industry associations and consumer groups from all over the world. Within the Codex organization, the Codex Committee for Food Additives and Contaminants is responsible for working out recommendations for the application of food additives: the General Standard for Food Additives. In the light of the World Trade Organizations General Agreement on Tariffs and Trade (GATT), the Codex Standard, although not legally binding, influences food color regulations all over the world.
Criticism and health implications
Widespread public belief that artificial food coloring causes ADHD-like hyperactivity in children originated from Benjamin Feingold, a pediatric allergist from California, who proposed in 1973 that salicylates, artificial colors, and artificial flavors cause hyperactivity in children; however, there is no evidence to support broad claims that food coloring causes food intolerance and ADHD-like behavior in children.: 452 It is possible that certain food colorings may act as a trigger in those who are genetically predisposed, but the evidence is weak.
Despite concerns expressed that food colorings may cause ADHD-like behavior in children, the collective evidence does not support this assertion. UK Food Standards Agency (FSA) examined the effects of tartrazine, allura red, ponceau 4R, quinoline yellow, sunset yellow and carmoisine on children. | {
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646 | Food coloring | https://en.wikipedia.org/wiki/Food%20coloring | These colorants are found in beverages. The study found "a possible link between the consumption of these artificial colours and a sodium benzoate preservative and increased hyperactivity" in the children; the advisory committee to the FSA that evaluated the study also determined that because of study limitations, the results could not be extrapolated to the general population, and further testing was recommended. The U.S. FDA did not make changes following the publication of the Southampton study. Following a citizen petition filed by the Center for Science in the Public Interest in 2008, requesting the FDA ban several food additives, the FDA reviewed the available evidence, and still made no changes.
The European regulatory community, with an emphasis on the precautionary principle, required labelling and temporarily reduced the acceptable daily intake (ADI) for the food colorings; the UK FSA called for voluntary withdrawal of the colorings by food manufacturers. However, in 2009 the EFSA re-evaluated the data at hand and determined that "the available scientific evidence does not substantiate a link between the color additives and behavioral effects" for any of the dyes.
See also
Azo compound
Acid dye
E number
Federal Food, Drug, and Cosmetic Act
Food additive
References
External links
FDA/CFSAN Food Color Facts
Natural Food Colors (Food-Info)
Report on the Certification of Color Additives by U.S. FDA
NATCOL: What are natural food colours?
CSPI: Food Dyes Pose Rainbow of Risks | {
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647 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification | Food fortification or enrichment is the process of adding micronutrients (essential trace elements and vitamins) to food. It can be carried out by food manufacturers, or by governments as a public health policy which aims to reduce the number of people with dietary deficiencies within a population. The predominant diet within a region can lack particular nutrients due to the local soil or from inherent deficiencies within the staple foods; the addition of micronutrients to staples and condiments can prevent large-scale deficiency diseases in these cases.
As defined by the World Health Organization (WHO) and the Food and Agricultural Organization of the United Nations (FAO), fortification refers to "the practice of deliberately increasing the content of an essential micronutrient, i.e. vitamins and minerals (including trace elements) in a food, to improve the nutritional quality of the food supply and to provide a public health benefit with minimal risk to health", whereas enrichment is defined as "synonymous with fortification and refers to the addition of micronutrients to a food which are lost during processing".
Food fortification has been identified as the second strategy of four by the WHO and FAO to begin decreasing the incidence of nutrient deficiencies at the global level. As outlined by the FAO, the most commonly fortified foods are cereals and cereal-based products; milk and dairy products; fats and oils; accessory food items; tea and other beverages; and infant formulas. Undernutrition and nutrient deficiency is estimated globally to cause the deaths of between 3 and 5 million people per year. | {
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648 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification |
Types
Fortification is present in common food items in two different ways: adding back and addition. Flour loses nutritional value due to the way grains are processed; enriched flour has iron, folic acid, niacin, riboflavin, and thiamine added back to it. Conversely, other fortified foods have micronutrients added to them that don't naturally occur in those substances. An example of this is orange juice, which often is sold with added calcium.
Food fortification can also be categorized according to the stage of addition:
Commercial and industrial fortification (wheat flour, corn meal, cooking oils)
Biofortification (breeding crops to increase their nutritional value, which can include both conventional selective breeding, and genetic engineering)
Home fortification (example: vitamin D drops)
Rationale
Micronutrients serve an important role in bodily development and growth. Deficiencies of these micronutrients may cause improper development or even disease.
The WHO and FAO, among many other nationally recognized organizations, have recognized that there are over 2 billion people worldwide who have a variety of micronutrient deficiencies. In 1992, 159 countries pledged at the FAO/WHO International Conference on Nutrition to make efforts to help combat these issues of micronutrient deficiencies, highlighting the importance of decreasing the number of those with iodine, vitamin A, and iron deficiencies. A significant statistic that led to these efforts was the discovery that approximately 1 in 3 people worldwide were at risk for either an iodine, vitamin A, or iron deficiency. | {
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649 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification | Although it is recognized that food fortification alone will not combat this deficiency, it is a step towards reducing the prevalence of these deficiencies and their associated health conditions.
In Canada, the Food and Drug Regulations have outlined specific criteria which justify food fortification:
To replace nutrients which were lost during manufacturing of the product (e.g. the manufacturing of flour)
To act as a public health intervention
To ensure the nutritional equivalence of substitute foods (e.g. to make butter and margarine similar in content, soy milk and cow's milk, etc.)
To ensure the appropriate vitamin and mineral nutrient composition of foods for special dietary purposes (e.g., gluten-free products, low sodium, or any other products specifically designed for special dietary requirements from an individual).
There are also several advantages to approaching nutrient deficiencies among populations via food fortification as opposed to other methods. These may include, but are not limited to: treating a population without specific dietary interventions therefore not requiring a change in dietary patterns, continuous delivery of the nutrient, does not require individual compliance, and potential to maintain nutrient stores more efficiently if consumed regularly.
Around the world
The subsections below describe fortifications in some jurisdictions around the world. A more comprehensive view is given by the online Global Fortification Data Exchange. It indicates which of 197 countries worldwide have mandatory and voluntary food fortification in their datasets and country profiles. The website is maintained by the Food Fortification Initiative, GAIN, Iodine Global Network, and the Micronutrient Forum. | {
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650 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification |
Argentina
In Argentina, wheat flour must by law (Ley 25.630 of 2002) be fortified with iron, thiamine (vitamin B1), riboflavin (B2), niacin (B3), and folic acid (B9).
Colombia
Wheat flour sold in Colombia must by law be fortified with vitamin B1, vitamin B2, niacin (B3), folic acid (B9) and iron (Decreto 1944 of 1996).
El Salvador, Guatemala, Honduras and Nicaragua
The four countries, also called the C-4, all legally require wheat flour to be fortified with vitamins B1, B2, B3, B9, and iron.
Philippines
The Philippine law on food fortification has two components: mandatory (covering select staples) and voluntary (under the Sangkap Pinoy program). The latter has been criticized for covering only low nutritional-value food, namely, junk food, to enable them to be sold in schools.
United Kingdom
UK law (The Bread and Flour Regulations 1998) requires that all flour (except wholemeal and some self-raising flours) be fortified with calcium. Wheat flour must also be fortified with iron, thiamine (vitamin B1) and vitamin B3.
United States
In the 1920s, food fortification emerged as a strategy in the United States to address and prevent the lack of micronutrients in the population's diet. Specifically, it was discovered in the 1930s and 1940s, that micronutrient deficiency is often linked to specific diseases and syndromes. | {
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651 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification | Consequently, the Committee on Food and Nutrition suggested that micronutrients be added to flour. In 1980, The Food and Drug Administration put into action its Food Fortification Policy which included six fundamental rules. In addition to establishing safety guidelines of food fortification, this policy aimed to ensure that food fortification was solely for when the supplemental micronutrient had a national deficiency and that the food chosen to provide that nutrient was consumed by enough of the population to make a change. This policy also emphasized the importance of clinical data, a shift from earlier policies which relied on dietary data alone. The 2002 farm bill (P.L. 107–171, Sec. 3013) requires the Administrator of USAID, in consultation with the Secretary of Agriculture, to establish micronutrient fortification programs under P.L. 480 food aid. Section 3013 replaces a pilot program similarly named and authorized in the 1996 farm bill (P.L. 104–127, Sec. 415). Under the programs, grains and other commodities made available to countries selected for participation will be fortified with micronutrients (e.g., iron, vitamin A, iodine, and folic acid).
Criticism
In addition to criticism of government-mandated fortification, food companies have been criticized for indiscriminate enrichment of foods for marketing purposes. Food safety worries led to legislation in Denmark in 2004 restricting foods fortified with extra vitamins or minerals. Products banned include: Rice Krispies, Shreddies, Horlicks, Ovaltine, and Marmite. | {
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652 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification |
Limited absorption
One factor that limits the benefits of food fortification is that isolated nutrients added back into a processed food that has had many of its nutrients removed, does not always result in the added nutrients being as bioavailable as they would be in the original, whole food. An example is skim milk that has had the fat removed, and then had vitamin A and vitamin D added back. Vitamins A and D are both fat-soluble and non-water-soluble, so a person consuming skim milk without fats may not be able to absorb as much of these vitamins as one would be able to absorb from drinking whole milk. On the other hand, the nutrient added as a fortificant may have a higher bioavailability than from foods, which is the case with folic acid used to increase folate intakes.
Phytochemicals such as phytic acid in cereal grains can also impact nutrient absorption, limiting the bioavailability of intrinsic and additional nutrients, and reducing the effectiveness of fortification programs.
Different forms of micronutrients
There is a concern that micronutrients are legally defined in such a way that does not distinguish between different forms, and that fortified foods often have nutrients in a balance that would not occur naturally. For example, in the U.S., food is fortified with folic acid, which is one of the many naturally-occurring forms of folate, and which only contributes a minor amount to the folates occurring in natural foods. | {
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653 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification | In many cases, such as with folate, it is an open question of whether or not there are any benefits or risks to consuming folic acid in this form.
In many cases, the micronutrients added to foods in fortification are synthetic.
Certain forms of micronutrients can be actively toxic in a sufficiently high dose, even if other forms are safe at the same or much higher doses. There are examples of such toxicity in both synthetic and naturally occurring forms of vitamins. Retinol, the active form of Vitamin A, is toxic in a much lower dose than other forms, such as beta carotene. Menadione, a phased-out synthetic form of Vitamin K, is also known to be toxic.
Examples of fortification in foods
Many foods and beverages worldwide have been fortified, whether a voluntary action by the product developers or by law. Although some may view these additions as strategic marketing schemes to sell their product, there is a lot of work that must go into a product before simply fortifying it. To fortify a product, it must first be proven that the addition of this vitamin or mineral is beneficial to health, safe, and an effective method of delivery. The addition must also abide by all food and labeling regulations and support nutritional rationale. From a food developer's point of view, they also need to consider the costs associated with this new product and whether there will be a market to support the change.
The Food Fortification Initiative lists all countries in the world that conduct fortification programs, and within each country, what nutrients are added to which foods, and whether those programs are voluntary or mandatory. | {
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654 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification | Vitamin fortification programs exist in one or more countries for folate, niacin, riboflavin, thiamine, vitamin A, vitamin B6, vitamin B12, vitamin D and vitamin E. Mineral fortification programs include calcium, fluoride, iodine, iron, selenium and zinc. As of December 21, 2018, 81 countries required food fortification with one or more vitamins. The most commonly fortified vitamin – as used in 62 countries – is folate; the most commonly fortified food is wheat flour (enriched flour). Examples of foods and beverages that have been fortified:
Iodized salt
"Iodine deficiency disorder (IDD) is the single greatest cause of preventable mental retardation. Severe deficiencies cause cretinism, stillbirth and miscarriage. But even mild deficiency can significantly affect the learning ability of populations. [...] Today over 1 billion people in the world suffer from iodine deficiency, and 38 million babies born every year are not protected from brain damage due to IDD."—Kul Gautam, Deputy Executive Director, UNICEF, October 2007
Iodised salt has been used in the United States since before World War II. It was discovered in 1821 that goiters could be treated by the use of iodized salts. However, it was not until 1916 that the use of iodized salts could be tested in a research trial as a preventative measure against goiters. | {
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655 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification | By 1924, it became readily available in the US. Currently in Canada and the US, the RDA for iodine is as low as 90 µg/day for children (4–8 years) and as high as 290 µg/day for breast-feeding mothers.
Diseases that are associated with an iodine deficiency include: intellectual disabilities, hypothyroidism, and goiter. There is also a risk of various other growth and developmental abnormalities.
Folate
Folate (as a fortification ingredient, folic acid) functions in reducing blood homocysteine levels, forming red blood cells, proper growth and division of cells and preventing neural tube defects (NTDs). In many industrialized countries, the addition of folic acid to flour has prevented a significant number of NTDs in infants. Two common types of NTDs, spina bifida and anencephaly, affect approximately 2500-3000 infants born in the US annually. Research trials have shown the ability to reduce the incidence of NTDs by supplementing pregnant mothers with folic acid by 72%.
Niacin
Niacin (a form of vitamin B3) has been added to bread in the US since 1938 (when voluntary addition started), a program which substantially reduced the incidence of pellagra. Pellagra was seen amongst poor families who used corn as their main dietary staple. Although corn itself does contain niacin, it is not a bioavailable form unless it undergoes nixtamalization (treatment with alkali, traditional in Native American cultures) and therefore was not contributing to the overall intake of niacin. | {
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656 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification |
Diseases associated with niacin deficiency include pellagra which consisted of signs and symptoms called the three D's-"dermatitis, dementia, and diarrhea." Others may include vascular or gastrointestinal diseases. Common diseases which present a high frequency of niacin deficiency include alcoholism, anorexia nervosa, HIV infection, gastrectomy, malabsorptive disorders, certain cancers and their associated treatments.
Vitamin D
Since Vitamin D is a fat-soluble vitamin, it cannot be added to a wide variety of foods. Foods that it is commonly added to are margarine, vegetable oils and dairy products. During the late 1800s, after the discovery of curing conditions of scurvy and beriberi had occurred, researchers were aiming to see if the disease, later known as rickets, could also be cured by food. Their results showed that sunlight exposure and cod liver oil were the cure. It was not until the 1930s that vitamin D was actually linked to curing rickets. This discovery led to the fortification of common foods such as milk, margarine, and breakfast cereals. This took the astonishing statistics of approximately 80–90% of children showing varying degrees of bone deformations due to vitamin D deficiency to being a very rare condition.
Diseases associated with a vitamin D deficiency include rickets, osteoporosis, and certain types of cancer (breast, prostate, colon and ovaries). | {
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657 | Food fortification | https://en.wikipedia.org/wiki/Food%20fortification | It has also been associated with increased risks for fractures, heart disease, type 2 diabetes, autoimmune and infectious diseases, asthma and other wheezing disorders, myocardial infarction, hypertension, congestive heart failure, and peripheral vascular disease.
Fluoride
Although fluoride is not considered an essential mineral, it is useful in prevention of tooth decay and maintaining adequate dental health. In the mid-1900s it was discovered that towns with a high level of fluoride in their water supply was causing the residents' teeth to have both brown spotting and a strange resistance to dental caries. This led to the fortification of water supplies with fluoride in safe amounts (or reduction of naturally occurring levels) to retain the properties of resistance to dental caries but avoid the staining caused by fluorosis (a condition caused by excessive fluoride intake). The tolerable upper intake level (UL) set for fluoride ranges from 0.7 mg/day for infants aged 0–6 months and 10 mg/day for adults over the age of 19.
See also
Food additive
Food composition
Dietary supplement
Food processing
Nutraceutical
Micronutrient deficiency
References
External links
Food fortification in the Philippines: Policies, programmes, issues, and prospects (PDF) | {
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658 | Fumaric acid | https://en.wikipedia.org/wiki/Fumaric%20acid | Fumaric acid is an organic compound with the formula HO2CCH=CHCO2H. A white solid, fumaric acid occurs widely in nature. It has a fruit-like taste and has been used as a food additive. Its E number is E297. The salts and esters are known as fumarates. Fumarate can also refer to the C4H2O2−4 ion (in solution). Fumaric acid is the trans isomer of butenedioic acid, while maleic acid is the cis isomer.
Biosynthesis and occurrence
It is produced in eukaryotic organisms from succinate in complex 2 of the electron transport chain via the enzyme succinate dehydrogenase.
Fumaric acid is found in fumitory (Fumaria officinalis), bolete mushrooms (specifically Boletus fomentarius var. pseudo-igniarius), lichen, and Iceland moss.
Fumarate is an intermediate in the citric acid cycle used by cells to produce energy in the form of adenosine triphosphate (ATP) from food. It is formed by the oxidation of succinate by the enzyme succinate dehydrogenase. Fumarate is then converted by the enzyme fumarase to malate.
Human skin naturally produces fumaric acid when exposed to sunlight.
Fumarate is also a product of the urea cycle. | {
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659 | Fumaric acid | https://en.wikipedia.org/wiki/Fumaric%20acid |
Click on genes, proteins and metabolites below to link to respective articles.
Uses
Food
Fumaric acid has been used as a food acidulant since 1946. It is approved for use as a food additive in the EU, USA and Australia and New Zealand. As a food additive, it is used as an acidity regulator and can be denoted by the E number E297. It is generally used in beverages and baking powders for which requirements are placed on purity. Fumaric acid is used in the making of wheat tortillas as a food preservative and as the acid in leavening. It is generally used as a substitute for tartaric acid and occasionally in place of citric acid, at a rate of 1 g of fumaric acid to every ~1.5 g of citric acid, in order to add sourness, similarly to the way malic acid is used. As well as being a component of some artificial vinegar flavors, such as "Salt and Vinegar" flavored potato chips, it is also used as a coagulant in stove-top pudding mixes.
The European Commission Scientific Committee on Animal Nutrition, part of DG Health, found in 2014 that fumaric acid is "practically non-toxic" but high doses are probably nephrotoxic after long-term use.
Medicine
Fumaric acid was developed as a medicine to treat the autoimmune condition psoriasis in the 1950s in Germany as a tablet containing 3 esters, primarily dimethyl fumarate, and marketed as Fumaderm by Biogen Idec in Europe. | {
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660 | Fumaric acid | https://en.wikipedia.org/wiki/Fumaric%20acid | Biogen would later go on to develop the main ester, dimethyl fumarate, as a treatment for multiple sclerosis.
In patients with relapsing-remitting multiple sclerosis, the ester dimethyl fumarate (BG-12, Biogen) significantly reduced relapse and disability progression in a phase 3 trial. It activates the Nrf2 antioxidant response pathway, the primary cellular defense against the cytotoxic effects of oxidative stress.
Signaling metabolite in cell biology
In mammals, malic enzyme 2 (ME2) is allosterically activated by fumarate. The Krebs cycle intermediate fumarate links metabolism to mitobiogenesis through binding to malic enzyme 2 (ME2). Mechanistically, fumarate binds ME2 with two complementary consequences. First, promoting the formation of ME2 dimers, which activate deoxyuridine 5'-triphosphate nucleotidohydrolase (DUT). DUT fosters thymidine generation and an increase of mtDNA. Second, fumarate-induced ME2 dimers abrogate ME2 monomer binding to mitochondrial ribosome protein L45, freeing it for mitoribosome assembly and mtDNA-encoded protein production. Methylation of the ME2-fumarate binding site by protein arginine methyltransferase-1 inhibits fumarate signaling to constrain mitobiogenesis. | {
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661 | Fumaric acid | https://en.wikipedia.org/wiki/Fumaric%20acid | Notably, acute myeloid leukemia is highly dependent on mitochondrial function and is sensitive to targeting of the fumarate-ME2 axis.
Other uses
Fumaric acid is used in the manufacture of polyester resins and polyhydric alcohols and as a mordant for dyes.
When fumaric acid is added to their feed, lambs produce up to 70% less methane during digestion.
Synthesis
Fumaric acid is produced based on catalytic isomerisation of maleic acid in aqueous solutions at low pH. It precipitates from the reaction solution. Maleic acid is accessible in large volumes as a hydrolysis product of maleic anhydride, produced by catalytic oxidation of benzene or butane.
Historic and laboratory routes
Fumaric acid was first prepared from succinic acid. A traditional synthesis involves oxidation of furfural (from the processing of maize) using chlorate in the presence of a vanadium-based catalyst.
Reactions
The chemical properties of fumaric acid can be anticipated from its component functional groups. This weak acid forms a diester, it undergoes bromination across the double bond, and it is a good dienophile.
Safety
Fumaric acid is required for life. The oral LD50 is 10g/kg.
See also
Citric acid cycle (TCA cycle)
Photosynthesis
Maleic acid, the cis isomer of fumaric acid
References
External links
International Chemical Safety Card 1173 | {
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662 | Generally recognized as safe | https://en.wikipedia.org/wiki/Generally%20recognized%20as%20safe | Generally recognized as safe (GRAS) is a United States Food and Drug Administration (FDA) designation that a chemical or substance added to food is considered safe by experts under the conditions of its intended use. An ingredient with a GRAS designation is exempted from the usual Federal Food, Drug, and Cosmetic Act (FFDCA) food additive tolerance requirements. The concept of food additives being "generally recognized as safe" was first described in the Food Additives Amendment of 1958, and all additives introduced after this time had to be evaluated by new standards. The FDA list of GRAS notices is updated approximately each month, as of 2021.
History
On 6 September 1958, the Food Additives Amendment of 1958 was signed into law, with a list of 700 food substances that were exempt from the then-new requirement that manufacturers test food additives before putting them on the market. On August 31, 1960, William W. Goodrich, assistant general counsel of the FDA, addressed the annual meeting (16 Bus. Law. 107 1960–1961) of the FFDCA. The purpose of the meeting was the forthcoming March 6, 1961, effective date of the enforcement provisions of the "Food Additives Amendment of 1958", referred to as GRAS.
Designation and list
A GRAS determination can be self-affirmed or the FDA can be notified of a determination of GRAS by qualified non-governmental experts:
Self-affirmed. The manufacturer of this chemical or substance had performed all necessary research, including the formation of an expert panel to review safety concerns, and is prepared to use these findings to defend its product's GRAS status. | {
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663 | Generally recognized as safe | https://en.wikipedia.org/wiki/Generally%20recognized%20as%20safe |
FDA Response to GRAS notification. The manufacturer has performed all the aforementioned due diligence, and submitted a GRAS notification to inform the FDA of a determination that the use of a substance is GRAS. Following evaluation, the FDA provides three possible responses: 1. FDA does not question the basis for the notifier's GRAS determination, 2. the notification does not provide a sufficient basis for GRAS determination, or 3. the FDA has, at the notifier's request, ceased to evaluate the GRAS notice.
As of January 2021 (beginning in 1998), 955 ingredient or food substances have been filed with the FDA. These petitions, submitted by sponsors or manufacturers, are reviewed for the safety evidence contained in the document. FDA posts status of the review as either without further questions (as a position of "no objection") or the petition is withdrawn by the applicant.
For substances used in food prior to January 1, 1958, a grandfather clause allows experience based on common use in food to be used in asserting an ingredient is safe under the conditions of their intended use.
The FDA can also explicitly withdraw the GRAS classification, as it did for trans fat in 2015.
List of GRAS notices
The list of GRAS notices is updated approximately each month by the FDA.
Code of Federal Regulations
The Code of Federal Regulations, revised as of April 1, 2020, includes (CFR) title 21 170.30(b) that provides general recognition of safety through scientific procedures requires the same quantity and quality of scientific evidence needed to obtain approval of the substance as a food additive. | {
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664 | Generally recognized as safe | https://en.wikipedia.org/wiki/Generally%20recognized%20as%20safe | and ordinarily is based upon published studies, which may be corroborated by unpublished studies and other data and information.
Intended use
The substance must be shown to be "generally recognized" as safe under the conditions of its intended use. For new proposals, the proponent of the exemption – usually a food manufacturer or ingredient supplier wishing to highlight a food ingredient in its manufactured product – has the burden of providing rigorous scientific evidence that use of the substance in an edible consumer product is safe. To establish GRAS, the proponent must show that there is a consensus of expert opinion that the substance is safe for its intended use. For existing GRAS items, new uses should not substantially exceed historical occurrence levels of the substance in the diet.
Enforcement
When use of a substance does not qualify for the GRAS exemption, it is subject to the premarket approval mandated by the Federal Food, Drug, and Cosmetic Act. In such circumstances, the FDA can take enforcement action to stop distribution of the food substance and foods containing it on the grounds that such foods are not deemed GRAS or contain an unlawfully added ingredient.
An example of a non-GRAS ingredient requiring enforcement actions in the form of FDA warning letters to 15 companies in 2019 was cannabidiol, which, as of 2021, had not been established with sufficient scientific evidence of safety as a GRAS ingredient.
See also
Generally recognized as safe and effective
Novel food
Substantial equivalence
References
External links
GRAS Notification Program, FDA, January 2020 | {
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665 | Glazing agent | https://en.wikipedia.org/wiki/Glazing%20agent | A glazing agent is a natural or synthetic substance that provides a waxy, homogeneous coating to prevent water loss from a surface and provide other protection.
Natural
Natural glazing agents keep moisture inside plants and insects. Scientists harnessed this characteristic in coatings made of substances classified as waxes. A natural wax is chemically defined as an ester with a very long hydrocarbon chain that also includes a long chain alcohol.
Examples are:
Stearic acid (E570)
Beeswax (E901)
Candelilla wax (E902)
Carnauba wax (E903)
Shellac (E904)
Microcrystalline wax (E905c), Crystalline wax (E907)
Lanolin (E913)
Oxidized polyethylene wax (E914)
Esters of colophonium (E915)
Paraffin
Synthetic
Scientists have produced glazing agents that mimic their natural counterparts. These components are added in different proportions to achieve the optimal glazing agent for a product. Such products include cosmetics, automobiles and food.
Some of the characteristics that are looked for in all of the above industries are:
1. Preservation - the glazing agent must protect the product from degradation and water loss. This characteristic can lead to a longer shelf life for a food or the longevity of a car without rusting.
2. Stability - the glazing agent must maintain its integrity under pressure or heat. | {
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666 | Glazing agent | https://en.wikipedia.org/wiki/Glazing%20agent |
3. Uniform viscosity - this ensures a stronger protective coating that can be applied to the product as a homogeneous layer.
4. Industrial reproduction - because most glazing agents are used on commercial goods and therefore large quantities of glazing agent may be needed.
There are different variations of glazing agents, depending on the product, but they are all designed for the same purpose.
References
See also
Glaze (cooking technique)
Food coating, a comprehensive description of this unit operation in a food processing line. | {
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667 | Gluconic acid | https://en.wikipedia.org/wiki/Gluconic%20acid | Gluconic acid is an organic compound with molecular formula C6H12O7 and condensed structural formula HOCH2(CHOH)4CO2H. A white solid, it forms the gluconate anion in neutral aqueous solution. The salts of gluconic acid are known as "gluconates". Gluconic acid, gluconate salts, and gluconate esters occur widely in nature because such species arise from the oxidation of glucose. Some drugs are injected in the form of gluconates.
Chemical structure
The chemical structure of gluconic acid consists of a six-carbon chain, with five hydroxyl groups positioned in the same way as in the open-chained form of glucose, terminating in a carboxylic acid group. It is one of the 16 stereoisomers of 2,3,4,5,6-pentahydroxyhexanoic acid.
Production
Gluconic acid is typically produced by the aerobic oxidation of glucose in the presence of the enzyme glucose oxidase. The conversion produces gluconolactone and hydrogen peroxide. The lactone spontaneously hydrolyzes to gluconic acid in water.
C6H12O6 + O2 → C6H10O6 + H2O2
C6H10O6 + H2O → C6H12O7
Variations of glucose (or other carbohydrate-containing substrate) oxidation using fermentation. | {
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668 | Gluconic acid | https://en.wikipedia.org/wiki/Gluconic%20acid | or noble metal catalysis.
Gluconic acid was first prepared by Hlasiwetz and Habermann in 1870 and involved the chemical oxidation of glucose. In 1880, Boutroux prepared and isolated gluconic acid using the glucose fermentation.
Occurrence and uses
Gluconic acid occurs naturally in fruit, honey, and wine. As a food additive (E574), it is now known as an acidity regulator.
The gluconate anion chelates Ca2+, Fe2+, K+, Al3+, and other metals, including lanthanides and actinides. It is also used in cleaning products, where it dissolves mineral deposits, especially in alkaline solution.
Zinc gluconate injections are used to neuter male dogs.
Gluconate is also used in building and construction as a concrete admixture (retarder) to slow down the cement hydration reactions, and to delay the cement setting time. It allows for a longer time to lay the concrete, or to spread the cement hydration heat over a longer period of time to avoid too high a temperature and the resulting cracking. Retarders are mixed in to concrete when the weather temperature is high or to cast large and thick concrete slabs in successive and sufficiently well-mixed layers.
Gluconic acid aqueous solution finds application as a medium for organic synthesis.
Medicine
In medicine, gluconate is used most commonly as a biologically neutral carrier of Zn2+, Ca2+, Cu2+, Fe2+, and K+ to treat electrolyte imbalance. | {
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669 | Gluconic acid | https://en.wikipedia.org/wiki/Gluconic%20acid |
Calcium gluconate, in the form of a gel, is used to treat burns from hydrofluoric acid; calcium gluconate injections may be used for more severe cases to avoid necrosis of deep tissues, as well as to treat hypocalcemia in hospitalized patients. Gluconate is also an electrolyte present in certain solutions, such as "plasmalyte a", used for intravenous fluid resuscitation. Quinine gluconate is a salt of gluconic acid and quinine, which is used for intramuscular injection in the treatment of malaria.
Ferrous gluconate injections have been proposed in the past to treat anemia.
See also
Uronic acid
Glucuronic acid
Isosaccharinic acid (ISA)
References
External links
Gluconic acid on NIST.gov
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670 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | Glutamate flavoring is the generic name for flavor-enhancing compounds based on glutamic acid and its salts (glutamates). These compounds provide an umami (savory) taste to food.
Glutamic acid and glutamates are natural constituents of many fermented or aged foods, including soy sauce, fermented bean paste, and cheese. They can also be found in hydrolyzed proteins such as yeast extract. The sodium salt of glutamic acid, monosodium glutamate (MSG), is manufactured on a large scale and widely used in the food industry.
Glutamic acid versus glutamates
When glutamic acid or any of its salts are dissolved in water, they form a solution of separate negative ions, called glutamates, and positive ions like H3O+ or Na+. The result is actually a chemical equilibrium among several ionized forms, including zwitterions, that depends on the pH (acidity) of the solution. Within the common pH range of foods, the prevailing ion can be described as −OOC-C(NH+3)-(CH2)2-COO−, which has an electric charge of −1.
Only the glutamate ion is responsible for the umami flavor, so the effect does not depend significantly on the starting compound. However, some crystalline salts such as monosodium glutamate dissolve much better and faster than crystalline glutamic acid. | {
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671 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | This has proven to be an important factor in the implementation of substances as flavor enhancers.
Discovery
Although they occur naturally in many foods, glutamic acid and other amino acid flavor contributions were not scientifically identified until early in the twentieth century. In 1866, the German chemist Karl Heinrich Ritthausen discovered and identified the compound. In 1907, Japanese researcher Kikunae Ikeda of the Tokyo Imperial University identified brown crystals left behind after the evaporation of a large amount of kombu broth as glutamic acid. These crystals, when tasted, reproduced the ineffable but undeniable flavor detected in many foods, especially seaweed. Professor Ikeda coined the term umami for this flavor. He then patented a method of mass-producing the crystalline salt of glutamic acid known as monosodium glutamate.
Isomers
Further research into the compound has found that only the L-glutamate enantiomer has flavor-enhancing properties. Manufactured monosodium glutamate consists to over 99.6% of the naturally predominant L-glutamate form, which is a higher proportion of L-glutamate than can be found in the free glutamate ions of fermented naturally occurring foods. Fermented products such as soy sauce, steak sauce, and Worcestershire sauce have levels of glutamate similar to those in foods with added monosodium glutamate. | {
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672 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | However, 5% or more of the glutamate may be the D-enantiomer. Nonfermented naturally occurring foods have lower relative levels of D-glutamate than fermented products do.
Taste perception
Glutamic acid stimulates specific receptors located in taste buds such as the amino acid receptor T1R1/T1R3 or other glutamate receptors like the metabotropic receptors (mGluR4 and mGluR1), which induce the flavor known as umami. This is classified as one of the five basic tastes (the word "umami" is a loanword from Japanese; it is also referred to as "savory" or "meaty").
The flavoring effect of glutamate comes from its free form, in which it is not bound to other amino acids in protein. Nonetheless, glutamate by itself does not elicit an intense umami taste. The mixing of glutamate with nucleotides inosine-5'-monophosphate (IMP) or guanosine-5'-monophosphate (GMP) enhances the taste of umami; T1R1 and T1R3 respond primarily to mixtures of glutamate and nucleotides. While research has shown that this synergism occurs in some animal species with other amino acids, studies of human taste receptors show that the same reaction only occurs between glutamate and the selected nucleotides. | {
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673 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | Moreover, sodium in monosodium glutamate may activate glutamate to produce a stronger umami taste.
Two hypotheses for the explanation of umami taste transduction have been introduced: the first posits that the umami taste is transduced by an N-methyl-D-aspartate (NMDA) type glutamate ion channel receptor; the second posits that the taste is transduced by a metabotropic type glutamate receptor (taste-mGluR4). The metabotropic glutamate receptors such as mGluR4 and mGluR1 can be easily activated at glutamate concentration levels found in food.
Sources
Natural occurrence
Glutamate is ubiquitous in biological life. It is found naturally in all living cells, primarily in the bound form as a constituent of proteins. Only a fraction of the glutamate in foods is in its "free" form, and only free glutamate produces an umami flavor in foods. The savory flavor of tomatoes, fermented soy products, yeast extracts, certain sharp cheeses, and fermented or hydrolyzed protein products (such as soy sauce and fermented bean paste) is partially due to the presence of free glutamate ions.
Asia
Japanese cuisine originally used broth made from kombu (kelp) to produce the umami taste in soups. | {
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674 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring |
Rome
In the Roman Empire glutamic acid was found in a sauce called garum, made from fermenting fish in saltwater. The flavor enhancing properties of glutamic acid allowed Romans to reduce the use of expensive salt.
Concentration in foods
The following table illustrates the glutamate content of some selected common foods. Free glutamate is the form directly tasted and absorbed whereas glutamate bound in protein is not available until further breakdown by digestion or cooking. In general, vegetables contain more free glutamate but less protein-bound glutamate.
Hydrolyzed protein
Hydrolyzed proteins, or protein hydrolysates, are acid- or enzymatically treated proteins from certain foods. One example is yeast extract. Hydrolyzed protein contains free amino acids, such as glutamate, at levels of 5% to 20%. Hydrolyzed protein is used in the same manner as monosodium glutamate in many foods, such as canned vegetables, soups, and processed meats.
Pure salts
Manufacturers, such as Ajinomoto, use selected strains of Corynebacterium glutamicum bacteria in a nutrient-rich medium. The bacteria are selected for their ability to excrete glutamic acid, which is then separated from the nutrient medium and processed into its sodium salt, monosodium glutamate.
Safety as a flavor enhancer
Studies
Monosodium glutamate (MSG) is regarded as safe for consumption. | {
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675 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | An association between MSG consumption and a constellation of symptoms has not been demonstrated under rigorously controlled conditions. Techniques used to adequately control for experimental bias include a placebo-controlled double-blinded experimental design and the use of capsules to deliver the compound to mask the strong and unique after-taste of glutamates. Even though there are also reports of MSG sensitivity among a subset of the population, this has not been demonstrated in placebo‐controlled trials.
Chinese restaurant syndrome
Origin
The controversy surrounding the safety of MSG started on 4 April 1968, when Dr. Robert Ho Man Kwok wrote a correspondence letter to the New England Journal of Medicine, coining the term "Chinese restaurant syndrome". In his letter, Kwok suggested several possible causes before he nominated MSG for his symptoms. This letter was initially met with insider satirical responses, often using race as prop for humorous effect, within the medical community. Some claimed that during the discursive uptake in media, the conversations were recontextualized as legitimate while the supposed race-based motivations of the humor were not parsed.
In January 2018, Dr. Howard Steel claimed that it was actually a prank submission by him under a pseudonym. However, it turned out that there was a Dr. Robert Ho Man Kwok who worked at the National Biomedical Research Foundation, both names Steel claimed to have invented. Kwok's children, his colleague at the research foundation, and the son of his boss there confirmed that Dr. | {
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676 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | Robert Ho Man Kwok, who had died in 2014, wrote this letter. After hearing about Kwok's family, Steel's daughter Anna came to believe that the admission that the letter was a prank was itself one of the last pranks by her late father.
The claims of "Chinese restaurant syndrome" have the same symptoms as hypernatremia, so it may actually be salt poisoning.
Reactions
Some authors and activists have attributed the negative perceptions around MSG to xenophobic or racist biases towards East Asians and East Asian cuisine, criticising the classification of alleged MSG-related symptoms as "Chinese Restaurant Syndrome".
In 2020, Ajinomoto, the leading manufacturer of MSG, launched the #RedefineCRS campaign to combat what it said was the myth that MSG is harmful to people's health. Following the #RedefineCRS campaign, Merriam-Webster announced it will be "reviewing" the term, which was added to the dictionary in 1993.
Regulations
Regulation timeline
In 1959, the U.S. Food and Drug Administration (FDA) classified monosodium glutamate as generally recognized as safe (GRAS). This action stemmed from the 1958 Food Additives Amendment to the Federal Food, Drug, and Cosmetic Act that required premarket approval for new food additives and led the FDA to promulgate regulations listing substances, such as monosodium glutamate, which have a history of safe use or are otherwise GRAS. | {
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] |
677 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring |
Since 1970, FDA has sponsored extensive reviews on the safety of monosodium glutamate, other glutamates, and hydrolyzed proteins, as part of an ongoing review of safety data on GRAS substances used in processed foods. One such review was by the Federation of American Societies for Experimental Biology (FASEB) Select Committee on GRAS Substances. In 1980, the committee concluded that monosodium glutamate was safe at current levels of use but recommended additional evaluation to determine monosodium glutamate's safety at significantly higher levels of consumption. Additional reports attempted to look at this.
In 1986, FDA's Advisory Committee on Hypersensitivity to Food Constituents concluded that monosodium glutamate poses no threat to the general public but that reactions of brief duration might occur in some people. Other reports have given the following findings:
The 1987 Joint Expert Committee on Food Additives of the United Nations Food and Agriculture Organization and the World Health Organization placed monosodium glutamate in the safest category of food ingredients.
A 1991 report by the European Community's (EC) Scientific Committee for Foods reaffirmed monosodium glutamate's safety and classified its "acceptable daily intake" as "not specified", the most favorable designation for a food ingredient. In addition, the EC Committee said, "Infants, including prematures, have been shown to metabolize glutamate as efficiently as adults and therefore do not display any special susceptibility to elevated oral intakes of glutamate. | {
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678 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | " Legislation in effect since June 2013 classifies glutamic acid and glutamates as salt substitutes, seasonings, and condiments with a maximum level of consumption of 10g/kg expressed as glutamic acid.
European Union
Following the compulsory EU-food labeling law the use of glutamic acid and its salts has to be declared, and the name or E number of the salt has to be listed. Glutamic acid and its salts as food additives have the following E numbers: glutamic acid: E620, monosodium glutamate: E621, monopotassium glutamate: E622, calcium diglutamate: E623, monoammonium glutamate: E624, and magnesium diglutamate: E625. In the European Union, these substances are regarded as "flavor enhancers" and are not allowed to be added to milk, emulsified fat and oil, pasta, cocoa/chocolate products and fruit juice. The EU has not yet published an official NOAEL (no observable adverse effect level) for glutamate, but a 2006 consensus statement of a group of German experts drawing from animal studies was that a daily intake of glutamic acid of 6 grams per kilogram of body weight (6 g/kg/day) is safe. From human studies, the experts noted that doses as high as 147g/day produced no adverse effects in males when given for 30 days; in a 70 kg (150 lb) male, this amount corresponds to 2. | {
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679 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | 1 g per kg of body weight.
United States
In 1959, the Food and Drug Administration classified MSG as a "generally recognized as safe" (GRAS) food ingredient under the Federal Food, Drug, and Cosmetic Act. In 1986, FDA's Advisory Committee on Hypersensitivity to Food Constituents also found that MSG was generally safe, but that short-term reactions may occur in some people. To further investigate this matter, in 1992 the FDA contracted the Federation of American Societies for Experimental Biology (FASEB) to produce a detailed report, which was published in 1995. The FASEB report reaffirmed the safety of MSG when it is consumed at usual levels by the general population, and found no evidence of any connection between MSG and any serious long-term reactions.
Under 2003 U.S. Food and Drug Administration regulations, when monosodium glutamate is added to a food, it must be identified as "monosodium glutamate" in the label's ingredient list. Because glutamate is commonly found in food, primarily from protein sources, the FDA does not require foods and ingredients that contain glutamate as an inherent component to list it on the label. Examples include tomatoes, cheeses, meats, hydrolyzed protein products such as soy sauce, and autolyzed yeast extracts. These ingredients are to be declared on the label by their common or usual names. The term 'natural flavor' is now used by the food industry when using glutamic acid. | {
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680 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | Because of lack of regulation, it is impossible to determine what percentage of 'natural flavor' is actually glutamic acid.
The food additives disodium inosinate and disodium guanylate are usually used in synergy with monosodium glutamate-containing ingredients, and provide a likely indicator of the addition of glutamate to a product.
As of 2002, the National Academy of Sciences Committee on Dietary Reference Intakes had not set a NOAEL or LOAEL for glutamate.
Australia and New Zealand
Standard 1.2.4 of the Australia New Zealand Food Standards Code requires the presence of monosodium glutamate as a food additive to be labeled. The label must bear the food additive class name (such as "flavor enhancer"), followed by either the name of the food additive (such as "MSG") or its International Numbering System (INS) number (e.g., "621").
Canada
The Canada Food Inspection Agency considers claims of "no MSG" or "MSG free" to be misleading and deceptive when other sources of free glutamates are present.
Ingredients
Forms of glutamic acid that can be added to food include:
Monosodium glutamate
Glutamic acid (E620), glutamate (E620)
Monopotassium glutamate (E622)
Calcium glutamate (E623)
Monoammonium glutamate (E624)
Magnesium glutamate (E625)
Sodium glutamate (E621)
The following are also rich sources of glutamic acid, and may be added for umami flavor:
Hydrolyzed vegetable protein
Autolyzed yeast, yeast extract, yeast food, and nutritional yeast
Cheese products, e. | {
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] |
681 | Glutamate flavoring | https://en.wikipedia.org/wiki/Glutamate%20flavoring | g. parmesan (1200 mg / 100 g)
Various savory fermented seasonings, including soy sauce and worcestershire sauce
(See § Sources for more examples.)
See also
Notes
References
External links
"The Long Fuse". This American Life (Radio broadcast). Episode 668. February 15, 2019. Public Radio Exchange (PRX). WBEZ. Retrieved February 21, 2019. See the segments "Prologue" and "Humor Is Not the Best Medicine" for the story behind "Chinese restaurant syndrome". | {
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682 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | Glycerol (), also called glycerine or glycerin, is a simple triol compound. It is a colorless, odorless, viscous liquid that is sweet-tasting and non-toxic. The glycerol backbone is found in lipids known as glycerides. It is also widely used as a sweetener in the food industry and as a humectant in pharmaceutical formulations. Because of its three hydroxyl groups, glycerol is miscible with water and is hygroscopic in nature.
Structure
Although achiral, glycerol is prochiral with respect to reactions of one of the two primary alcohols. Thus, in substituted derivatives, the stereospecific numbering labels the molecule with a sn- prefix before the stem name of the molecule.
Production
Glycerol is generally obtained from plant and animal sources where it occurs in triglycerides, esters of glycerol with long-chain carboxylic acids. The hydrolysis, saponification, or transesterification of these triglycerides produces glycerol as well as the fatty acid derivative:
Triglycerides can be saponified with sodium hydroxide to give glycerol and fatty sodium salt or soap.
Typical plant sources include soybeans or palm. Animal-derived tallow is another source. Approximately 950,000 tons per year are produced in the United States and Europe; 350,000 tons of glycerol were produced per year in the U. | {
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683 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | S. alone from 2000 to 2004. The EU directive 2003/30/EC set a requirement that 5.75% of petroleum fuels were to be replaced with biofuel sources across all member states by 2010. It was projected in 2006 that by 2020, production would be six times more than demand, creating an excess of glycerol as a byproduct of biofuel production.
Glycerol from triglycerides is produced on a large scale, but the crude product is of variable quality, with a low selling price of as low as US$0.02–0.05 per kilogram in 2011. It can be purified, but the process is expensive. Some glycerol is burned for energy, but its heat value is low.
Crude glycerol from the hydrolysis of triglycerides can be purified by treatment with activated carbon to remove organic impurities, alkali to remove unreacted glycerol esters, and ion exchange to remove salts. High purity glycerol (greater than 99.5%) is obtained by multi-step distillation; a vacuum chamber is necessary due to its high boiling point (290 °C).
Synthetic glycerol
Because of the large-scale production of biodiesel from fats, where glycerol is a waste product, the market for glycerol is depressed. Thus, synthetic processes are not economical. Owing to oversupply, efforts are being made to convert glycerol to synthetic precursors, such as acrolein and epichlorohydrin. | {
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684 | Glycerol | https://en.wikipedia.org/wiki/Glycerol |
Although usually not cost-effective because so much is produced from processing of fats, glycerol can be produced by various routes. During World War II, synthetic glycerol processes became a national defense priorities because it is a precursor to nitroglycerine. Epichlorohydrin is the most important precursor. chlorination of propylene gives allyl chloride, which is oxidized with hypochlorite to dichlorohydrin, which reacts with a strong base to give epichlorohydrin. Epichlorohydrin can be hydrolyzed to glycerol. Chlorine-free processes from propylene include the synthesis of glycerol from acrolein and propylene oxide.
Applications
Food industry
In food and beverages, glycerol serves as a humectant, solvent, and sweetener, and may help preserve foods. It is also used as filler in commercially prepared low-fat foods (e.g., cookies), and as a thickening agent in liqueurs. Glycerol and water are used to preserve certain types of plant leaves. As a sugar substitute, it has approximately 27 kilocalories per teaspoon (sugar has 20) and is 60% as sweet as sucrose. It does not feed the bacteria that form a dental plaque and cause dental cavities. As a food additive, glycerol is labeled as E number E422. | {
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685 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | It is added to icing (frosting) to prevent it from setting too hard.
As used in foods, glycerol is categorized by the U.S. Academy of Nutrition and Dietetics as a carbohydrate. The U.S. Food and Drug Administration (FDA) carbohydrate designation includes all caloric macronutrients excluding protein and fat. Glycerol has a caloric density similar to table sugar, but a lower glycemic index and different metabolic pathway within the body.
It is also recommended as an additive when using polyol sweeteners such as erythritol and xylitol which have a cooling effect, due to its heating effect in the mouth, if the cooling effect is not wanted.
Excessive consumption by children can lead to glycerol intoxication. Symptoms of intoxication include hypoglycemia, nausea and a loss of consciousness (syncope). While intoxication as a result of excessive glycerol consumption is rare and its symptoms generally mild, occasional reports of hospitalization have occurred. In the United Kingdom in August 2023, manufacturers of syrup used in slush ice drinks were advised to reduce the amount of glycerol in their formulations by the Food Standards Agency to reduce the risk of intoxication.
Medical, pharmaceutical and personal care applications
Glycerol is used in medical, pharmaceutical and personal care preparations, often as a means of improving smoothness, providing lubrication, and as a humectant. | {
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686 | Glycerol | https://en.wikipedia.org/wiki/Glycerol |
Ichthyosis and xerosis have been relieved by the topical use of glycerin. It is found in allergen immunotherapies, cough syrups, elixirs and expectorants, toothpaste, mouthwashes, skin care products, shaving cream, hair care products, soaps, and water-based personal lubricants. In solid dosage forms like tablets, glycerol is used as a tablet holding agent. For human consumption, glycerol is classified by the FDA among the sugar alcohols as a caloric macronutrient. Glycerol is also used in blood banking to preserve red blood cells prior to freezing.
Taken rectally, glycerol functions as a laxative by irritating the anal mucosa and inducing a hyperosmotic effect, expanding the colon by drawing water into it to induce peristalsis resulting in evacuation. It may be administered undiluted either as a suppository or as a small-volume (2–10 ml) enema. Alternatively, it may be administered in a dilute solution, such as 5%, as a high-volume enema.
Taken orally (often mixed with fruit juice to reduce its sweet taste), glycerol can cause a rapid, temporary decrease in the internal pressure of the eye. This can be useful for the initial emergency treatment of severely elevated eye pressure.
In 2017, researchers showed that the probiotic Limosilactobacillus reuteri bacteria can be supplemented with glycerol to enhance its production of antimicrobial substances in the human gut. | {
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687 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | This was confirmed to be as effective as the antibiotic vancomycin at inhibiting Clostridioides difficile infection without having a significant effect on the overall microbial composition of the gut.
Glycerol has also been incorporated as a component of bio-ink formulations in the field of bioprinting. The glycerol content acts to add viscosity to the bio-ink without adding large protein, saccharide, or glycoprotein molecules.
Botanical extracts
When utilized in "tincture" method extractions, specifically as a 10% solution, glycerol prevents tannins from precipitating in ethanol extracts of plants (tinctures). It is also used as an "alcohol-free" alternative to ethanol as a solvent in preparing herbal extractions. It is less extractive when utilized in a standard tincture methodology. Alcohol-based tinctures can also have the alcohol removed and replaced with glycerol for its preserving properties. Such products are not "alcohol-free" in a scientific or FDA regulatory sense, as glycerol contains three hydroxyl groups. Fluid extract manufacturers often extract herbs in hot water before adding glycerol to make glycerites.
When used as a primary "true" alcohol-free botanical extraction solvent in non-tincture based methodologies, glycerol has been shown to possess a high degree of extractive versatility for botanicals including removal of numerous constituents and complex compounds, with an extractive power that can rival that of alcohol and water–alcohol solutions. | {
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688 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | That glycerol possesses such high extractive power assumes it is utilized with dynamic (critical) methodologies as opposed to standard passive "tincturing" methodologies that are better suited to alcohol. Glycerol possesses the intrinsic property of not denaturing or rendering a botanical's constituents inert like alcohols (ethanol, methanol, and so on) do. Glycerol is a stable preserving agent for botanical extracts that, when utilized in proper concentrations in an extraction solvent base, does not allow inverting or mitigates reduction-oxidation of a finished extract's constituents, even over several years. Both glycerol and ethanol are viable preserving agents. Glycerol is bacteriostatic in its action, and ethanol is bactericidal in its action.
Electronic cigarette liquid
Glycerin, along with propylene glycol, is a common component of e-liquid, a solution used with electronic vaporizers (electronic cigarettes). This glycerol is heated with an atomizer (a heating coil often made of Kanthal wire), producing the aerosol that delivers nicotine to the user.
Antifreeze
Like ethylene glycol and propylene glycol, glycerol is a non-ionic kosmotrope that forms strong hydrogen bonds with water molecules, competing with water-water hydrogen bonds. This interaction disrupts the formation of ice. The minimum freezing point temperature is about −38 °C (−36 °F) corresponding to 70% glycerol in water. | {
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689 | Glycerol | https://en.wikipedia.org/wiki/Glycerol |
Glycerol was historically used as an anti-freeze for automotive applications before being replaced by ethylene glycol, which has a lower freezing point. While the minimum freezing point of a glycerol-water mixture is higher than an ethylene glycol-water mixture, glycerol is not toxic and is being re-examined for use in automotive applications.
In the laboratory, glycerol is a common component of solvents for enzymatic reagents stored at temperatures below 0 °C (32 °F) due to the depression of the freezing temperature. It is also used as a cryoprotectant where the glycerol is dissolved in water to reduce damage by ice crystals to laboratory organisms that are stored in frozen solutions, such as fungi, bacteria, nematodes, and mammalian embryos. Some organisms like the moor frog produce glycerol to survive freezing temperatures during hibernation.
Chemical intermediate
Glycerol is used to produce a variety of useful derivatives.
Nitration gives nitroglycerin, an essential ingredient of various explosives such as dynamite, gelignite, and propellants like cordite. Nitroglycerin under the name glyceryl trinitrate (GTN) is commonly used to relieve angina pectoris, taken in the form of sub-lingual tablets, patches, or as an aerosol spray.
Trifunctional polyether polyols are produced from glycerol and propylene oxide. | {
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690 | Glycerol | https://en.wikipedia.org/wiki/Glycerol |
Oxidation of glycerol affords mesoxalic acid. Dehydrating glycerol affords hydroxyacetone.
Chlorination of glycerol gives the 1-chloropropane-2,3-diol:
HOCH(CH2OH)2 + HCl → HOCH(CH2Cl)(CH2OH) + H2O
The same compound can be produced by hydrolysis of epichlorohydrin.
Vibration damping
Glycerol is used as fill for pressure gauges to damp vibration. External vibrations, from compressors, engines, pumps, etc., produce harmonic vibrations within Bourdon gauges that can cause the needle to move excessively, giving inaccurate readings. The excessive swinging of the needle can also damage internal gears or other components, causing premature wear. Glycerol, when poured into a gauge to replace the air space, reduces the harmonic vibrations that are transmitted to the needle, increasing the lifetime and reliability of the gauge.
Niche uses
Entertainment industry
Glycerol is used by set decorators when filming scenes involving water to prevent an area meant to look wet from drying out too quickly.
Glycerine is also used in the generation of theatrical smoke and fog as a component of the fluid used in fog machines as a replacement for glycol, which has been shown to be an irritant if exposure is prolonged.
Ultrasonic couplant
Glycerol can be sometimes used as replacement for water in ultrasonic testing, as it has favourably higher acoustic impedance (2. | {
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691 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | 42 MRayl versus 1.483 MRayl for water) while being relatively safe, non-toxic, non-corrosive and relatively low cost.
Internal combustion fuel
Glycerol is also used to power diesel generators supplying electricity for the FIA Formula E series of electric race cars.
Research on additional uses
Research continues into potential value-added products of glycerol obtained from biodiesel production. Examples (aside from combustion of waste glycerol):
Hydrogen gas production.
Glycerine acetate is a potential fuel additive.
Additive for starch thermoplastic.
Conversion to various other chemicals:
Propylene glycol
Acrolein
Ethanol
Epichlorohydrin, a raw material for epoxy resins
Metabolism
Glycerol is a precursor for synthesis of triacylglycerols and of phospholipids in the liver and adipose tissue. When the body uses stored fat as a source of energy, glycerol and fatty acids are released into the bloodstream.
Glycerol is mainly metabolized in the liver. Glycerol injections can be used as a simple test for liver damage, as its rate of absorption by the liver is considered an accurate measure of liver health. Glycerol metabolism is reduced in both cirrhosis and fatty liver disease.
Blood glycerol levels are highly elevated during diabetes, and is believed to be the cause of reduced fertility in patients who suffer from diabetes and metabolic syndrome. | {
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692 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | Blood glycerol levels in diabetic patients average three times higher than healthy controls. Direct glycerol treatment of testes has been found to cause significant long-term reduction in sperm count. Further testing on this subject was abandoned due to the unexpected results, as this was not the goal of the experiment.
Circulating glycerol does not glycate proteins as do glucose or fructose, and does not lead to the formation of advanced glycation endproducts (AGEs). In some organisms, the glycerol component can enter the glycolysis pathway directly and, thus, provide energy for cellular metabolism (or, potentially, be converted to glucose through gluconeogenesis).
Before glycerol can enter the pathway of glycolysis or gluconeogenesis (depending on physiological conditions), it must be converted to their intermediate glyceraldehyde 3-phosphate in the following steps:
The enzyme glycerol kinase is present mainly in the liver and kidneys, but also in other body tissues, including muscle and brain. In adipose tissue, glycerol 3-phosphate is obtained from dihydroxyacetone phosphate with the enzyme glycerol-3-phosphate dehydrogenase.
Glycerol has very low toxicity when ingested; its LD50 oral dose for rats is 12600 mg/kg and 8700 mg/kg for mice. It does not appear to cause toxicity when inhaled, although changes in cell maturity occurred in small sections of lung in animals under the highest dose measured. | {
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693 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | A sub-chronic 90-day nose-only inhalation study in Sprague–Dawley (SD) rats exposed to 0.03, 0.16 and 0.66 mg/L glycerin (Per liter of air) for 6-hour continuous sessions revealed no treatment-related toxicity other than minimal metaplasia of the epithelium lining at the base of the epiglottis in rats exposed to 0.66 mg/L glycerin.
Historical cases of contamination with diethylene glycol
On 4 May 2007, the FDA advised all U.S. makers of medicines to test all batches of glycerol for diethylene glycol contamination. This followed an occurrence of hundreds of fatal poisonings in Panama resulting from a falsified import customs declaration by Panamanian import/export firm Aduanas Javier de Gracia Express, S. A. The cheaper diethylene glycol was relabeled as the more expensive glycerol. Between 1990 and 1998, incidents of DEG poisoning reportedly occurred in Argentina, Bangladesh, India, and Nigeria, and resulted in hundreds of deaths. In 1937, more than one hundred people died in the United States after ingesting DEG-contaminated elixir sulfanilamide, a drug used to treat infections.
Etymology
The origin of the gly- and glu- prefixes for glycols and sugars is from Ancient Greek γλυκύς glukus which means sweet. | {
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694 | Glycerol | https://en.wikipedia.org/wiki/Glycerol | Name glycérine was coined ca. 1811 by Michel Eugène Chevreul to denote what was previously called "sweet principle of fat" by its discoverer Carl Wilhelm Scheele. It was borrowed into English ca. 1838 and in the 20th c. displaced by 1872 term glycerol featuring an alcohols' suffix -ol.
Properties
Table of thermal and physical properties of saturated liquid glycerin:
See also
Dioxalin
Epichlorohydrin
Nitroglycerin
Oleochemicals
Saponification/Soapmaking
Solketal
Transesterification
References
External links
Mass spectrum of glycerol Archived 13 February 2022 at the Wayback Machine
CDC – NIOSH Pocket Guide to Chemical Hazards – Glycerin (mist) | {
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695 | Glycerol ester of wood rosin | https://en.wikipedia.org/wiki/Glycerol%20ester%20of%20wood%20rosin | Glycerol ester of wood rosin (or gum rosin), also known as glyceryl abietate or ester gum, is an oil-soluble food additive (E number E445). The food-grade material is used in foods, beverages, and cosmetics to keep oils in suspension in water, and its name may be shortened in the ingredient list as glycerol ester of rosin. It is also used as an ingredient in the production of chewing gum and ice cream.
To make the glycerol ester of wood rosin, refined wood rosin is reacted with glycerin to produce the glycerol ester.
Glycerol ester of wood rosin is an alternative to brominated vegetable oil in citrus oil-flavored soft drinks. In some cases, both ingredients are used together.
References
External links
Standard Terminology Relating to Pine Chemicals, Including Tall Oil and Related Products | {
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696 | Glycerol monostearate | https://en.wikipedia.org/wiki/Glycerol%20monostearate | Glycerol monostearate, commonly known as GMS, is a monoglyceride commonly used as an emulsifier in foods. It takes the form of a white, odorless, and sweet-tasting flaky powder that is hygroscopic. Chemically it is the glycerol ester of stearic acid. It is also used as hydration powder in exercise formulas
Structure, synthesis, and occurrence
Glycerol monostearate exists as three stereoisomers, the enantiomeric pair of 1-glycerol monostearate and 2-glycerol monostearate. Typically these are encountered as a mixture as many of their properties are similar.
Commercial material used in foods is produced industrially by a glycerolysis reaction between triglycerides (from either vegetable or animal fats) and glycerol.
Glycerol monostearate occurs naturally in the body as a product of the breakdown of fats by pancreatic lipase. It is present at very low levels in certain seed oils.
Uses
GMS is a food additive used as a thickening, emulsifying, anticaking, and preservative agent; an emulsifying agent for oils, waxes, and solvents; a protective coating for hygroscopic powders; a solidifier and control release agent in pharmaceuticals; and a resin lubricant. | {
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] |
697 | Glycerol monostearate | https://en.wikipedia.org/wiki/Glycerol%20monostearate | It is also used in cosmetics and hair-care products.
GMS is largely used in baking preparations to add "body" to the food. It is somewhat responsible for giving ice cream and whipped cream their smooth texture. It is sometimes used as an antistaling agent in bread.
It can also be used as an additive in plastic, where GMS works as an antistatic and antifogging agent. This is common in food packaging.
See also
Glyceryl hydroxystearate
Monolaurin
Compendial status
British Pharmacopoeia
== References == | {
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698 | Glyceryl behenate | https://en.wikipedia.org/wiki/Glyceryl%20behenate | Glyceryl behenate is a fat used in cosmetics, foods, and oral pharmaceutical formulations. In cosmetics, it is mainly used as a viscosity-increasing agent in emulsions.
In pharmaceutical formulations, glyceryl behenate is mainly used as a tablet and capsule lubricant and as a lipidic coating excipient. It has been investigated for the encapsulation of various drugs such as retinoids. It has also been investigated for use in the preparation of sustained release tablets as a matrix-forming agent for the controlled release of water-soluble drugs and as a lubricant in oral solid dosage formulations. It can also be used as a hot-melt coating agent sprayed onto a powder.
It is used widely in cosmetics as non-comedogenic (non- pimple causing substance) ingredient. It does not clog the oil pores of facial skin.
It is also used widely as ingredient for preparation of lipidic nano-particles such as solid lipid nanoparticles (SLN) and nanostructured lipid carriers (NLC). Chemically, glyceryl behenate is a mixture of various esters of behenic acid and glycerol (glycerides). The mixture predominantly contains the diester glyceryl dibehenate.
See also
Behenic acid
== References == | {
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] |
699 | Heptyl acetate | https://en.wikipedia.org/wiki/Heptyl%20acetate | Heptyl acetate (C9H18O2), also known as acetate C-7, is a colorless alcohol-soluble liquid that is the ester formed by the condensation of 1-heptanol and acetic acid.
Heptyl acetate is used as a fruit essence flavoring in foods and as a scent in perfumes. It has a woody, fruity, rumlike odor and a spicy, floral taste with a soapy, fatty texture.
== References == | {
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