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Amylase
https://en.wikipedia.org/wiki/Amylase
This imparts flavour and causes the bread to rise. While amylases are found naturally in yeast cells, it takes time for the yeast to produce enough of these enzymes to break down significant quantities of starch in the bread. This is the reason for long fermented doughs such as sourdough. Modern breadmaking techniques have included amylases (often in the form of malted barley) into bread improver, thereby making the process faster and more practical for commercial use. α-Amylase is often listed as an ingredient on commercially package-milled flour. Bakers with long exposure to amylase-enriched flour are at risk of developing dermatitis or asthma. Molecular biology In molecular biology, the presence of amylase can serve as an additional method of selecting for successful integration of a reporter construct in addition to antibiotic resistance. As reporter genes are flanked by homologous regions of the structural gene for amylase, successful integration will disrupt the amylase gene and prevent starch degradation, which is easily detectable through iodine staining. Medical uses Amylase also has medical applications in the use of pancreatic enzyme replacement therapy (PERT). It is one of the components in Sollpura (liprotamase) to help in the breakdown of saccharides into simple sugars. Other uses An inhibitor of alpha-amylase, called phaseolamin, has been tested as a potential diet aid. When used as a food additive, amylase has E number E1100, and may be derived from pig pancreas or mold fungi.
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Amylase
https://en.wikipedia.org/wiki/Amylase
Bacilliary amylase is also used in clothing and dishwasher detergents to dissolve starches from fabrics and dishes. Factory workers who work with amylase for any of the above uses are at increased risk of occupational asthma. Five to nine percent of bakers have a positive skin test, and a fourth to a third of bakers with breathing problems are hypersensitive to amylase. Hyperamylasemia Blood serum amylase may be measured for purposes of medical diagnosis. A higher than normal concentration may reflect any of several medical conditions, including acute inflammation of the pancreas (which may be measured concurrently with the more specific lipase), perforated peptic ulcer, torsion of an ovarian cyst, strangulation, ileus, mesenteric ischemia, macroamylasemia and mumps. Amylase may be measured in other body fluids, including urine and peritoneal fluid. A January 2007 study from Washington University in St. Louis suggests that saliva tests of the enzyme could be used to indicate sleep deficits, as the enzyme increases its activity in correlation with the length of time a subject has been deprived of sleep. History In 1831, Erhard Friedrich Leuchs (1800–1837) described the hydrolysis of starch by saliva, due to the presence of an enzyme in saliva, "ptyalin", an amylase. it was named after the Ancient Greek name for saliva: πτύαλον - ptyalon.
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Amylase
https://en.wikipedia.org/wiki/Amylase
The modern history of enzymes began in 1833, when French chemists Anselme Payen and Jean-François Persoz isolated an amylase complex from germinating barley and named it "diastase". It is from this term that all subsequent enzyme names tend to end in the suffix -ase. In 1862, Russian biochemist Aleksandr Yakovlevich Danilevsky (1838–1923) separated pancreatic amylase from trypsin. Evolution Salivary amylase Saccharides are a food source rich in energy. Large polymers such as starch are partially hydrolyzed in the mouth by the enzyme amylase before being cleaved further into sugars. Many mammals have seen great expansions in the copy number of the amylase gene. These duplications allow for the pancreatic amylase AMY2 to re-target to the salivary glands, allowing animals to detect starch by taste and to digest starch more efficiently and in higher quantities. This has happened independently in mice, rats, dogs, pigs, and most importantly, humans after the agricultural revolution. Following the agricultural revolution 12,000 years ago, human diet began to shift more to plant and animal domestication in place of hunting and gathering. Starch has become a staple of the human diet. Despite the obvious benefits, early humans did not possess salivary amylase, a trend that is also seen in evolutionary relatives of the human, such as chimpanzees and bonobos, who possess either one or no copies of the gene responsible for producing salivary amylase.
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Amylase
https://en.wikipedia.org/wiki/Amylase
Like in other mammals, the pancreatic alpha-amylase AMY2 was duplicated multiple times. One event allowed it to evolve salivary specificity, leading to the production of amylase in the saliva (named in humans as AMY1). The 1p21.1 region of human chromosome 1 contains many copies of these genes, variously named AMY1A, AMY1B, AMY1C, AMY2A, AMY2B, and so on. However, not all humans possess the same number of copies of the AMY1 gene. Populations known to rely more on saccharides have a higher number of AMY1 copies than human populations that, by comparison, consume little starch. The number of AMY1 gene copies in humans can range from six copies in agricultural groups such as European-American and Japanese (two high starch populations) to only two to three copies in hunter-gatherer societies such as the Biaka, Datog, and Yakuts. The correlation that exists between starch consumption and number of AMY1 copies specific to population suggest that more AMY1 copies in high starch populations has been selected for by natural selection and considered the favorable phenotype for those individuals. Therefore, it is most likely that the benefit of an individual possessing more copies of AMY1 in a high starch population increases fitness and produces healthier, fitter offspring. This fact is especially apparent when comparing geographically close populations with different eating habits that possess a different number of copies of the AMY1 gene.
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Amylase
https://en.wikipedia.org/wiki/Amylase
Such is the case for some Asian populations that have been shown to possess few AMY1 copies relative to some agricultural populations in Asia. This offers strong evidence that natural selection has acted on this gene as opposed to the possibility that the gene has spread through genetic drift. Variations of amylase copy number in dogs mirrors that of human populations, suggesting they acquired the extra copies as they followed humans around. Unlike humans whose amylase levels depend on starch content in diet, wild animals eating a broad range of foods tend to have more copies of amylase. This may have to do with mainly detection of starch as opposed to digestion. == References ==
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Anticaking agent
https://en.wikipedia.org/wiki/Anticaking%20agent
An anticaking agent is an additive placed in powdered or granulated materials, such as table salt or confectioneries, to prevent the formation of lumps (caking) and for easing packaging, transport, flowability, and consumption. Caking mechanisms depend on the nature of the material. Crystalline solids often cake by formation of liquid bridge and subsequent fusion of microcrystals. Amorphous materials can cake by glass transitions and changes in viscosity. Polymorphic phase transitions can also induce caking. Some anticaking agents function by absorbing excess moisture or by coating particles and making them water-repellent. Calcium silicate (CaSiO3), a commonly used anti-caking agent, added to e.g. table salt, absorbs both water and oil. Anticaking agents are also used in non-food items such as road salt, fertilisers, cosmetics, and detergents. Some studies suggest that anticaking agents may have a negative effect on the nutritional content of food; one such study indicated that most anti-caking agents result in the additional degradation of vitamin C added to food. Examples An anticaking agent in salt is denoted in the ingredients, for example, as "anti-caking agent (554)", which is sodium aluminosilicate. This product is present in many commercial table salts as well as dried milk, egg mixes, sugar products, flours and spices.
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406
Anticaking agent
https://en.wikipedia.org/wiki/Anticaking%20agent
In Europe, sodium ferrocyanide (535) and potassium ferrocyanide (536) are more common anticaking agents in table salt. "Natural" anticaking agents used in more expensive table salt include calcium carbonate and magnesium carbonate. Diatomaceous earth, mostly consisting of silicon dioxide (SiO2), may also be used as an anticaking agent in animal foods, typically mixed at 2% rate of a product dry weight. List of anticaking agents The most widely used anticaking agents include the stearates of calcium and magnesium, silica and various silicates, talc, as well as flour and starch. Ferrocyanides are used for table salt. The following anticaking agents are listed in order by their number in the Codex Alimentarius by the Food and Agriculture Organization of the UN. 341 tricalcium phosphate 460(ii) powdered cellulose 470b magnesium stearate 500 sodium bicarbonate 535 sodium ferrocyanide 536 potassium ferrocyanide 538 calcium ferrocyanide 542 calcium phosphate 550 sodium silicate 551 silicon dioxide 552 calcium silicate 553a magnesium trisilicate 553b talcum powder 554 sodium aluminosilicate 555 potassium aluminium silicate 556 calcium aluminosilicate 558 bentonite 559 aluminium silicate 570 stearic acid 900 polydimethylsiloxane == References ==
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407
Aspartame-acesulfame salt
https://en.wikipedia.org/wiki/Aspartame-acesulfame%20salt
Aspartame-acesulfame salt is an artificial sweetener marketed under the name Twinsweet. It is produced by soaking a 2:1 mixture of aspartame and acesulfame potassium in an acidic solution and allowing it to crystallize; moisture and potassium are removed during this process. It is approximately 350 times as sweet as sucrose. It has been given the E number E962. History Aspartame-acesulfame salt was invented in 1995 by sweetener expert Dr John Fry while working for The Holland Sweetener Company (HSC), a subsidiary of DSM. HSC marketed it with the name Twinsweet. It was approved for use as an artificial sweetener in the European Parliament and Council Directive 94/35 EC as amended by Directive 2003/115/EC in 2003. In North America, it falls under the same regulations as aspartame and acesulfame-K. It is also approved for use in China, Russia, Hong Kong, Australia, and New Zealand. In December 2006, HSC ceased all of its aspartame operations, citing a glut in the market driving prices below profitable values. The rights to aspartame-acesulfame are now owned by The NutraSweet Company Inc., who has continued to market the sweetener successfully in the United States and European Union. References External links Media related to Aspartame-acesulfame salt at Wikimedia Commons Holland Sweetener Company
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408
Aversive agent
https://en.wikipedia.org/wiki/Aversive%20agent
Aversive agents are unpleasantly flavored substances added to poisonous household goods to discourage children and animals from consuming them. Aversive agents are not intended to be harmful, only unpleasant. For example, to prevent children from consuming poisonous anti-freeze, which has a sweet flavor due to the ethylene glycol, an aversive agent is added, which gives the anti-freeze an unpleasant taste. There are two primary classes of aversive agents: bitterants, chemicals producing a bitter flavor, and pungent agents, chemicals producing an unpleasantly pungent flavor. See also Denaturation (food) Adulterant Denatonium == References ==
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409
Azodicarbonamide
https://en.wikipedia.org/wiki/Azodicarbonamide
Azodicarbonamide, ADCA, ADA, or azo(bis)formamide, is a chemical compound with the molecular formula C2H4O2N4. It is a yellow to orange-red, odorless, crystalline powder. It is sometimes called a 'yoga mat' chemical because of its widespread use in foamed plastics. It was first described by John Bryden in 1959. Synthesis It is prepared in two steps via treatment of urea with hydrazine to form biurea, as described in this idealized equation: 2 O=C(NH2)2 + H2N−NH2 → H2N−C(=O)−NH−NH−C(=O)−NH2 + 2 NH3 Oxidation with chlorine or chromic acid yields azodicarbonamide: H2N−C(=O)−NH−NH−C(=O)−NH2 + Cl2 → H2N−C(=O)−N=N−C(=O)−NH2 + 2 HCl Applications Blowing agent The principal use of azodicarbonamide is in the production of foamed plastics as a blowing agent. The thermal decomposition of azodicarbonamide produces nitrogen, carbon monoxide, carbon dioxide, and ammonia gases, which are trapped in the polymer as bubbles to form a foamed article. Azodicarbonamide is used in plastics, synthetic leather, and other industries and can be pure or modified.
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410
Azodicarbonamide
https://en.wikipedia.org/wiki/Azodicarbonamide
Modification affects the reaction temperatures. Pure azodicarbonamide generally reacts around 200 °C. In the plastic, leather, and other industries, modified azodicarbonamide (average decomposition temperature 170 °C) contains additives that accelerate the reaction or react at lower temperatures. An example of the use of azodicarbonamide as a blowing agent is found in the manufacture of vinyl (PVC) and EVA-PE foams, where it forms bubbles upon breaking down into gas at high temperature. Vinyl foam is springy and does not slip on smooth surfaces. It is useful for carpet underlay and floor mats. Commercial yoga mats made of vinyl foam have been available since the 1980s; the first mats were cut from carpet underlay. Food additive As a food additive, azodicarbonamide is used as a flour bleaching agent and a dough conditioner. It reacts with moist flour as an oxidizing agent. The main reaction product is biurea, which is stable during baking. Secondary reaction products include semicarbazide and ethyl carbamate. It is known by the E number E927. Many restaurants in the US fast food industry removed the additive in response to negative publicity. Safety and regulation Occupational (inhalation) In a 1999 report, the World Health Organization has linked exposure to azodicarbonamide at workplaces where it is manufactured or handled in raw form to "respiratory issues, allergies and asthma".
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411
Azodicarbonamide
https://en.wikipedia.org/wiki/Azodicarbonamide
The available data are restricted to these occupational environments. Exposure of the general public to azodicarbonamide could not be evaluated because of the lack of available data. The WHO concluded, "The level of risk is uncertain; hence, exposure levels should be reduced as much as possible". In the UK, the Health and Safety Executive has identified azodicarbonamide as a respiratory sensitizer (a possible cause of asthma) in workplace settings and determined that containers of it should be labeled with "May cause sensitisation by inhalation." Azodicarbonamide was added to the REACH Regulation candidate Substances of Very High Concern list in 2012, for its respiratory sensitizing properties. Food (ingestion) In some jurisdictions, the use of azodicarbonamide as a flour bleaching agent has been phased out. For example, it is no longer authorized for use in Australia and the European Union as a food additive. Azodicarbonamide as a blowing agent in plastics has been banned in the European Union since August 2005 for the manufacture of plastic articles that are intended to come into direct contact with food. In the United States, azodicarbonamide has a generally recognized as safe (GRAS) status and is allowed to be added to flour at levels up to 45 ppm. However, use in products intended for human consumption is in decline under pressure of the public opinion. In 2014, amid public discomfort with the dual uses of azodicarbonamide, the sandwich franchise Subway and hamburger franchise Wendy's announced that they would no longer use it as a dough conditioner.
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412
Azodicarbonamide
https://en.wikipedia.org/wiki/Azodicarbonamide
As of February 2014, the Center for Science in the Public Interest stated azodicarbonamide "has been poorly tested" and advocates for reducing the amount of azodicarbonamide that is allowed to be used in food. The ban on ADA in food is mostly motivated by the weak carcinogenic property of semicarbazide, a side product of ADA use. The EU banned ADA in food containers despite an EFSA report considering such exposure "not a concern" due to low levels produced. The FDA's review maintains that ADA is safe at amounts allowed. As of February, 2021, in contrast to direct competitors like Wendy's that have phased out the ingredient, A&W continues to use azodicarbonamide in an unspecified quantity ("under 2 %") in their standard hamburger buns. References External links International Chemical Safety Card
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413
Bambermycin
https://en.wikipedia.org/wiki/Bambermycin
Bambermycin (flavomycin) is a complex of antibiotics obtained from Streptomyces bambergiensis and Streptomyces ghanaensis used as a food additive for beef cattle, dairy cattle, poultry and swine. The complex consists mainly of moenomycins A and C. Bambermycin is a performance-enhancing antibiotic intended and available solely for use in animal nutrition. Its mechanism of action is to inhibit the synthesis of the bacterial wall. Bambermycin is predominantly effective against Gram-positive pathogenic bacteria. However, it does not have significant action against Lactobacillus, Bifidobacterium, and other protective bacteria. Bambermycin has no precautions or warnings to humans on its label pertaining to mixing and handling and is non-hazardous when used according to label directions. Bambermycin has no withdrawal requirement. Bambermycin is not absorbed by the intestine and no measurable residues are found in edible tissues even when fed at up to 50 times the normal recommended dosage. Synonyms include flavomycin, flavofosfolipol, flavophospholipol, moenomycin, and the brand name Gainpro. == References ==
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Beta-glucan
https://en.wikipedia.org/wiki/Beta-glucan
Beta-glucans, β-glucans comprise a group of β-D-glucose polysaccharides (glucans) naturally occurring in the cell walls of cereals, bacteria, and fungi, with significantly differing physicochemical properties dependent on source. Typically, β-glucans form a linear backbone with 1–3 β-glycosidic bonds but vary with respect to molecular mass, solubility, viscosity, branching structure, and gelation properties, causing diverse physiological effects in animals. At dietary intake levels of at least 3 g per day, oat fiber β-glucan decreases blood levels of LDL cholesterol and so may reduce the risk of cardiovascular diseases. β-glucans are natural gums and are used as texturing agents in various nutraceutical and cosmetic products, and as soluble fiber supplements. History Cereal and fungal products have been used for centuries for medicinal and cosmetic purposes; however, the specific role of β-glucan was not explored until the 20th century. β-glucans were first discovered in lichens, and shortly thereafter in barley. A particular interest in oat β-glucan arose after a cholesterol lowering effect from oat bran reported in 1981. In 1997, the FDA approved of a claim that intake of at least 3.0 g of β-glucan from oats per day decreased absorption of dietary cholesterol and reduced the risk of coronary heart disease.
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415
Beta-glucan
https://en.wikipedia.org/wiki/Beta-glucan
The approved health claim was later amended to include these sources of β-glucan: rolled oats (oatmeal), oat bran, whole oat flour, oatrim (the soluble fraction of alpha-amylase hydrolyzed oat bran or whole oat flour), whole grain barley and barley beta-fiber. An example of an allowed label claim: "Soluble fiber from foods such as oatmeal, as part of a diet low in saturated fat and cholesterol, may reduce the risk of heart disease. A serving of oatmeal supplies 0.75 grams of the 3.0 g of β-glucan soluble fiber necessary per day to have this effect." The claim language is in the Federal Register 21 CFR 101.81 Health Claims: "Soluble fiber from certain foods and risk of coronary heart disease (CHD)". Structure Glucans are arranged in six-sided D-glucose rings connected linearly at varying carbon positions depending on the source, although most commonly β-glucans include a 1-3 glycosidic link in their backbone. Although technically β-glucans are chains of D-glucose polysaccharides linked by β-type glycosidic bonds, by convention not all β-D-glucose polysaccharides are categorized as β-glucans. Cellulose is not conventionally considered a β-glucan, as it is insoluble and does not exhibit the same physicochemical properties as other cereal or yeast β-glucans.
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416
Beta-glucan
https://en.wikipedia.org/wiki/Beta-glucan
Some β-glucan molecules have branching glucose side-chains attached to other positions on the main D-glucose chain, which branch off the β-glucan backbone. In addition, these side-chains can be attached to other types of molecules, like proteins, as in polysaccharide-K. The most common forms of β-glucans are those comprising D-glucose units with β-1,3 links. Yeast and fungal β-glucans contain 1-6 side branches, while cereal β-glucans contain both β-1,3 and β-1,4 backbone bonds. The frequency, location, and length of the side-chains may play a role in immunomodulation. Differences in molecular weight, shape, and structure of β-glucans dictate the differences in biological activity. In general, β-1,3 linkages are created by 1,3-Beta-glucan synthase, and β-1,4 linkages are created by cellulose synthase. The process leading to β-1,6 linkages is poorly understood: although genes important in the process have been identified, not much is known about what each of them do. β-glucan types β-glucans form a natural component of the cell walls of bacteria, fungi, yeast, and cereals such as oat and barley. Each type of beta-glucan comprises a different molecular backbone, level of branching, and molecular weight which affects its solubility and physiological impact.
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Beta-glucan
https://en.wikipedia.org/wiki/Beta-glucan
One of the most common sources of β(1,3)D-glucan for supplement use is derived from the cell wall of baker's yeast (Saccharomyces cerevisiae). β-glucans found in the cell walls of yeast contain a 1,3 glucose backbone with elongated 1,6 glucose branches. Other sources include seaweed, and various mushrooms, such as lingzhi, shiitake, chaga, and maitake, which are under preliminary research for their potential immune effects. Fermentable fiber In the diet, β-glucans are a source of soluble, fermentable fiber – also called prebiotic fiber – which provides a substrate for microbiota within the large intestine, increasing fecal bulk and producing short-chain fatty acids as byproducts with wide-ranging physiological activities. This fermentation impacts the expression of many genes within the large intestine, which further affects digestive function and cholesterol and glucose metabolism, as well as the immune system and other systemic functions. Cereal Cereal β-glucans from oat, barley, wheat, and rye have been studied for their effects on cholesterol levels in people with normal cholesterol levels and in those with hypercholesterolemia. Intake of oat β-glucan at daily amounts of at least 3 grams lowers total and low-density lipoprotein cholesterol levels by 5 to 10% in people with normal or elevated blood cholesterol levels.
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418
Beta-glucan
https://en.wikipedia.org/wiki/Beta-glucan
Oats and barley differ in the ratio of trimer and tetramer 1-4 linkages. Barley has more 1-4 linkages with a degree of polymerization higher than 4. However, the majority of barley blocks remain trimers and tetramers. In oats, β-glucan is found mainly in the endosperm of the oat kernel, especially in the outer layers of that endosperm. β-glucan absorption Enterocytes facilitate the transportation of β(1,3)-glucans and similar compounds across the intestinal cell wall into the lymph, where they begin to interact with macrophages to activate immune function. Radiolabeled studies have verified that both small and large fragments of β-glucans are found in the serum, which indicates that they are absorbed from the intestinal tract. M cells within the Peyer's patches physically transport the insoluble whole glucan particles into the gut-associated lymphoid tissue. (1,3)-β-D-glucan medical application An assay to detect the presence of (1,3)-β-D-glucan in blood is marketed as a means of identifying invasive or disseminated fungal infections. This test should be interpreted within the broader clinical context, however, as a positive test does not render a diagnosis, and a negative test does not rule out infection. False positives may occur because of fungal contaminants in the antibiotics amoxicillin-clavulanate, and piperacillin/tazobactam.
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Beta-glucan
https://en.wikipedia.org/wiki/Beta-glucan
False positives can also occur with contamination of clinical specimens with the bacteria Streptococcus pneumoniae, Pseudomonas aeruginosa, and Alcaligenes faecalis, which also produce (1→3)β-D-glucan. This test can aid in the detection of Aspergillus, Candida, and Pneumocystis jirovecii. This test cannot be used to detect Mucor or Rhizopus, the fungi responsible for mucormycosis, as they do not produce (1,3)-beta-D-glucan. See also Prebiotic (nutrition) Resistant starch Xylooligosaccharides Zymosan References External links beta-Glucans at the U.S. National Library of Medicine Medical Subject Headings (MeSH)
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Biosprint
https://en.wikipedia.org/wiki/Biosprint
Biosprint is a microbiological feed additive produced and worldwide distributed by the Italian biotech company prosol S.p.A. This zoo-technical additive contains cells of the yeast Saccharomyces cerevisiae selected under the unique code MUCL™ 39885 and deposited in the Belgian collections of micro-organisms/Mycothèque de l’Université Catholique de Louvain Biosprint has gained the EU authorization as feed additive for beef cattle, piglets, sows, dairy cows and horses. According to several tests, the influence of Biosprint on the diet consists of the improvement of the digestive efficiency and of the better assimilation of nutrients. References 1. ^ EFSA (European Food safety Authority), 2004. Opinion of the Scientific Panel on Additives and Products or Substances used in Animal Feed on a request from the Commission on the safety of “Biosprint BCCM™/MUCL39885” for dairy cows. The EFSA Journal 26, 1–6. https://efsa.onlinelibrary.wiley.com/doi/abs/10.2903/j.efsa.2004.26 2. ^ EFSA JournalEFSA (European Food safety Authority), Scientific Opinion on the safetyand efficacy of Biosprint®(Saccharomyces cerevisiae) as a feed additive for horses - EFSA Panel on Additives and Products or Substances used in Animal Feed (FEEDAP), Parma, Italy http://www.
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Biosprint
https://en.wikipedia.org/wiki/Biosprint
bezpecna-krmiva.cz/soubory/biosprint.pdf 3. ^ EFSA Journal (2009); 1(9), SCIENTIFIC OPINION on the safety and the efficacy of Biosprint® (Saccharomyces cerevisiae) as a feed additive for sows. Scientific Opinion of the Panel on Additives and Products or Substances used in Animal Feed (Question No EFSA-Q-2008-302) Adopted on 3 February 2009 https://www.efsa.europa.eu/en/efsajournal/pub/3174 4. ^ All about feed, Biosprint gets EU authorization for sows: http://www.allaboutfeed.net/Home/General/2009/10/Biosprint-gets-EU-authorization-for-sows-AAF003693W/ 5. ^ EFSA Journal(2013);11(4), SCIENTIFIC OPINION on the efficacy of Biosprint®(Saccharomyces cerevisiae) as a feed additive for cattle fattening, EFSA Panel on Additives and Products or Substances used in Animal Feed (FEEDAP), European Food Safety Authority (EFSA), Parma, Italy http://www.efsa.europa.eu/en/efsajournal/pub/3174 External links http://www.
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Biosprint
https://en.wikipedia.org/wiki/Biosprint
biosprint.bio
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Bitterant
https://en.wikipedia.org/wiki/Bitterant
A bitterant (or bittering agent) is a chemical that is added to a product to make it smell or taste bitter. Bitterants are commonly used as aversive agents to discourage the inhalation or ingestion of toxic substances. Examples of use The addition of a bitterant to ethanol denatures the product. Bitterants are used in antifreeze to prevent pet and child poisonings. It is required by law in some places (France, Oregon, etc.). Gas dusters often use a bitterant to discourage inhalant abuse, although this can cause problems for legitimate users. The bitterant not only leaves a bitter flavor in the air, but also leaves a bitter residue on objects, like screens and keyboards, that may transfer to hands and cause problems (such as when eating). Game cartridges for the Nintendo Switch are coated with denatonium as a safety feature to deter small children from ingesting them. Some button cell batteries manufactured by Duracell are coated with a bitterant to discourage accidental ingestion by children. Examples of bitterants Denatonium is used in a variety of applications as an aversive agent. Sucrose octaacetate Quercetin Brucine Quassin Bitterness scales The threshold for stimulation of bitter taste by quinine averages a concentration of 8 μM (8 micromolar). The taste thresholds of other bitter substances are rated relative to quinine, which is thus given a reference index of 1.
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424
Bitterant
https://en.wikipedia.org/wiki/Bitterant
For example, Brucine has an index of 11, is thus perceived as intensely more bitter than quinine, and is detected at a much lower solution threshold. The most bitter substance known is the synthetic chemical denatonium, which has an index of 1,000. It is used as an aversive agent (a bitterant) that is added to toxic substances to prevent accidental ingestion. This was discovered in 1958 during research on lignocaine, a local anesthetic, by MacFarlan Smith of Gorgie, Edinburgh, Scotland. Brewery Beer bitterness scales attempt to rate the perceived relative bitterness of beer. The bitterness of beer is provided by compounds such as isohumulones from hops used during brewing. The International Bittering Units scale, or simply IBU scale, is measured through the use of a spectrophotometer and solvent extraction a calculation is performed on this absorbance to give a result in IBU. This technique was adopted at the same time as another method based on measuring the concentration (in milligrams per litre; parts per million w/v) of IAA isomerized α acids in a beer, causing some confusion among small-scale brewers. The American Society of Brewing Chemists, in the introduction to its methods on measuring bitterness, points out some differences between the results of the two methods: While the results of the IAA methods are practically identical to those obtained by the [I]BU method for beer brewed with fresh hops, the IAAs of beer brewed with old or poorly stored hops, and with certain special hop extracts, can be significantly lower than the [I]BU figure.
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Bitterant
https://en.wikipedia.org/wiki/Bitterant
The European Bitterness Units scale, often abbreviated as EBU, is a bitterness scale in which lower values are generally "less bitter" and higher values "more bitter". The scale and method are defined by the European Brewery Convention, and the numerical value should be the same as of the International Bitterness Units scale (IBU), defined in co-operation with the American Society of Brewing Chemists. However, the exact process of determining EBU and IBU values differs slightly, which may in theory result with slightly smaller values for EBU than IBU. IBU cannot be determined by perceived bitterness. For example, the bittering effect of hops is less noticeable in beers with a high quantity of malt, so a higher bitterness is needed in heavier beers to balance the flavour and achieve the same perceived bitterness as compared to a lighter beer. For example, an Imperial Stout may have an IBU of 50, but will taste less bitter than an English Bitter with an IBU of 30, because the latter beer uses much less malt than the former. After around 100 IBU, hop utilization is so poor that the number ceases to be meaningful in regard to taste, although continued hop additions will increase bitterness. Light lagers without much bitterness will generally have 8–20 IBU, while an India Pale Ale may have 60–100 IBU or more. See also Denaturation (food), the deliberate addition of an unpleasantly flavored or poisonous substances to food in order to prevent the consumption of the food for various reasons.
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Bitterant
https://en.wikipedia.org/wiki/Bitterant
Adulterant, a substance added to food for deceptive or malicious reasons, for example to cheaply replace legitimate ingredients. References Sources Crouch, Andy (2006). The Good Beer Guide to New England. UPNE. ISBN 978-1-58465-469-8. Rabin, Dan; Forget, Carl (1998). The Dictionary of Beer and Brewing. Taylor & Francis. ISBN 978-1-57958-078-0.
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Bittering agent
https://en.wikipedia.org/wiki/Bittering%20agent
A bittering agent is a flavoring agent added to a food or beverage to impart a bitter taste, possibly in addition to other effects. While many substances are bitter to a greater or lesser degree, a few substances are used specifically for their bitterness, especially to balance other flavors, such as sweetness. Notable beverage examples include caffeine, found naturally in tea and coffee and added to many soft drinks, hops in beer, and quinine in tonic water. Food examples include bitter melon, which may be mixed into a stir fry or soup for its bitter flavor. Potent bittering agents may also be added to dangerous products as aversive agents to make them foul tasting, so as to prevent accidental poisoning. Examples including anti-freeze, household cleaning products and pesticides such as slug pellets. In general dangerous products with bright colours, which may be appealing to children, often contain agents such as denatonium. However, the efficacy of using bittering agents for this purpose is not conclusive. Beer Prior to the introduction of hops, many other bitter herbs and flowers were used as bittering agents in beer, in a mixture called gruit, which could include dandelion, burdock root, marigold, horehound (the German name for horehound means "mountain hops"), ground ivy, and heather. Also bog myrtle. More recently, some Chinese and Okinawan beer uses bitter melon as a bittering agent.
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Bittering agent
https://en.wikipedia.org/wiki/Bittering%20agent
Other substances Various other substances are used, including: Aloin Gesho, used in Tej, Ethiopian honey wine Other uses Other prominent uses of bittering agents include: Bitters – used as digestifs or flavorings Dandelion and burdock – traditional British soft drink == References ==
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Blue raspberry flavor
https://en.wikipedia.org/wiki/Blue%20raspberry%20flavor
Blue raspberry is a manufactured flavoring and food coloring for candy, snack foods, syrups, and soft drinks. The color does not derive from any species of raspberry, however the flavor is intended to mimic that of a blackcap raspberry. Its flavor was developed using "mostly esters of the banana, cherry, and pineapple variety," and sugar is commonly added to create taste appeal for the blue raspberry flavoring. Food products labeled as blue raspberry flavor are commonly dyed with a bright blue synthetic food coloring, such as brilliant blue FCF (also called Blue #1) having European food coloring number E133. The blue color was used to differentiate raspberry-flavored foods from cherry-, watermelon-, and strawberry-flavored foods, each of which is red. Blue raspberry flavor and color were first used in the United States in 1958 to add interest to snow cones. Regulatory agencies, such as the US Food and Drug Administration, provide guidelines on artificial flavors and colors for manufacturers out of concern for consumer safety, and have approved the use of blue raspberry as a safe ingredient since 1969. References External links Media related to Blue raspberry at Wikimedia Commons
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Borax
https://en.wikipedia.org/wiki/Borax
Borax (also referred to as sodium borate, tincal () and tincar ()) is a salt (ionic compound), a hydrated or anhydrous borate of sodium, with the chemical formula Na2H20B4O17 (also written as Na2B4O7·10H2O). It is a colorless crystalline solid that dissolves in water to make a basic solution. It is commonly available in powder or granular form and has many industrial and household uses, including as a pesticide, as a metal soldering flux, as a component of glass, enamel, and pottery glazes, for tanning of skins and hides, for artificial aging of wood, as a preservative against wood fungus, and as a pharmaceutic alkalizer. In chemical laboratories, it is used as a buffering agent. The terms tincal and tincar refer to native borax, historically mined from dry lake beds in various parts of Asia. History Borax was first discovered in dry lake beds in Tibet. Native tincal from Tibet, Persia, and other parts of Asia was traded via the Silk Road to the Arabian Peninsula in the 8th century AD. Borax first came into common use in the late 19th century when Francis Marion Smith's Pacific Coast Borax Company began to market and popularize a large variety of applications under the 20 Mule Team Borax trademark, named for the method by which borax was originally hauled out of the California and Nevada deserts.
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431
Borax
https://en.wikipedia.org/wiki/Borax
Etymology The English word borax is Latinized: the Middle English form was boras, from Old French boras, bourras. That may have been from Medieval Latin baurach (another English spelling), borac(-/um/em), borax, along with Spanish borrax (> borraj) and Italian borrace, in the 9th century, and from Arabic buraq (بورق) as mentioned for example in kitab al-tabikh of Ibn Sayyar al-Warraq. The words tincal and tincar were adopted into English in the 17th century from Malay tingkal and from Urdu/Persian Arabic تنکار‎ tinkār/tankār; thus the two forms in English. These all appear to be related to the Sanskrit टांकण ṭānkaṇa. Chemistry From the chemical perspective, borax contains the [B4O5(OH)4]2− ion. In this structure, there are two four-coordinate boron centers and two three-coordinate boron centers. It is a proton conductor at temperatures above 21 °C. Conductivity is maximum along the b-axis. Borax is also easily converted to boric acid and other borates, which have many applications. Its reaction with hydrochloric acid to form boric acid is: Na2B4O7·10H2O + 2 HCl → 4 H3BO3 + 2 NaCl + 5 H2O Borax is sufficiently stable to find use as a primary standard for acid-base titrimetry.
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432
Borax
https://en.wikipedia.org/wiki/Borax
: p.316  Molten borax dissolves many metal oxides to form glasses. This property is important for its uses in metallurgy and for the borax bead test of qualitative chemical analysis. Borax is soluble in a variety of solvents; however, it is notably insoluble in ethanol. The term borax properly refers to the so-called "decahydrate" Na2B4O7·10H2O, but that name is not consistent with its structure. It is actually octahydrate. The anion is not tetraborate [B4O7]2− but tetrahydroxy tetraborate [B4O5(OH)4]2−, so the more correct formula should be Na2B4O5(OH)4·8H2O. However, the term may be applied also to the related compounds. Borax "pentahydrate" has the formula Na2B4O7·5H2O, which is actually a trihydrate Na2B4O5(OH)4·3H2O. It is a colorless solid with a density of 1.880 kg/m3 that crystallizes from water solutions above 60.8 °C in the rhombohedral crystal system. It occurs naturally as the mineral tinkhanite. It can be obtained by heating the decahydrate above 61 °C.
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433
Borax
https://en.wikipedia.org/wiki/Borax
Borax "dihydrate" has the formula Na2B4O7·2H2O, which is actually anhydrous, with the correct formula Na2B4O5(OH)4. It can be obtained by heating the "decahydrate" or "pentahydrate" to above 116-120 °C. Anhydrous borax is sodium tetraborate proper, with formula Na2B4O7. It can be obtained by heating any hydrate to 300 °C. It has one amorphous (glassy) form and three crystalline forms – α, β, and γ, with melting points of 1015, 993 and 936 K respectively. α-Na2B4O7 is the stable form. Natural sources Borax occurs naturally in evaporite deposits produced by the repeated evaporation of seasonal lakes. The most commercially important deposits are found in: Turkey; Boron, California; and Searles Lake, California. Also, borax has been found at many other locations in the Southwestern United States, the Atacama desert in Chile, newly discovered deposits in Bolivia, and in Tibet and Romania. Borax can also be produced synthetically from other boron compounds. Naturally occurring borax (known by the trade name Rasorite–46 in the United States and many other countries) is refined by a process of recrystallization.
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434
Borax
https://en.wikipedia.org/wiki/Borax
Uses Borax is used in pest control solutions because it is toxic to ants. Because it is slow-acting, worker ants will carry the borax to their nests and poison the rest of the colony. Borax is used in various household laundry and cleaning products, including the 20 Mule Team Borax laundry booster, Boraxo powdered hand soap, and some tooth bleaching formulas. Borate ions (commonly supplied as boric acid) are used in biochemical and chemical laboratories to make buffers, e.g. for polyacrylamide gel electrophoresis of DNA and RNA, such as TBE buffer (borate buffered tris-hydroxymethylaminomethonium) or the newer SB buffer or BBS buffer (borate buffered saline) in coating procedures. Borate buffers (usually at pH 8) are also used as preferential equilibration solutions in dimethyl pimelimidate (DMP) based crosslinking reactions. Borax as a source of borate has been used to take advantage of the co-complexing ability of borate with other agents in water to form complex ions with various substances. Borate and a suitable polymer bed are used to chromatograph non-glycated hemoglobin differentially from glycated hemoglobin (chiefly HbA1c), which is an indicator of long-term hyperglycemia in diabetes mellitus.
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435
Borax
https://en.wikipedia.org/wiki/Borax
Borax alone does not have a high affinity for hardness cations, although it has been used for water-softening. Its chemical equation for water-softening is given below: Ca2+(aq) + Na2B4O7(aq) → CaB4O7(s)↓ + 2 Na+(aq) Mg2+(aq) + Na2B4O7(aq) → MgB4O7(s)↓ + 2 Na+(aq) The sodium ions introduced do not make water "hard". This method is suitable for removing both temporary and permanent types of hardness. A mixture of borax and ammonium chloride is used as a flux when welding iron and steel. It lowers the melting point of the unwanted iron oxide (scale), allowing it to run off. Borax is also mixed with water as a flux when soldering jewelry metals such as gold or silver, where it allows the molten solder to wet the metal and flow evenly into the joint. Borax is also a good flux for "pre-tinning" tungsten with zinc, making the tungsten soft-solderable. Borax is often used as a flux for forge welding. In artisanal gold mining, borax is sometimes used as part of a process known as the borax method (as a flux) meant to eliminate the need for toxic mercury in the gold extraction process, although it cannot directly replace mercury.
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436
Borax
https://en.wikipedia.org/wiki/Borax
Borax was reportedly used by gold miners in parts of the Philippines in the 1900s. There is evidence that, in addition to reducing the environmental impact, this method achieves better gold recovery for suitable ores and is less expensive. This borax method is used in northern Luzon in the Philippines, but miners have been reluctant to adopt it elsewhere for reasons that are not well understood. The method has also been promoted in Bolivia and Tanzania. A rubbery polymer sometimes called Slime, Flubber, 'gluep' or 'glurch' (or erroneously called Silly Putty, which is based on silicone polymers), can be made by cross-linking polyvinyl alcohol with borax. Making flubber from polyvinyl acetate-based glues, such as Elmer's Glue, and borax is a common elementary science demonstration. Borax, given the E number E285, is used as a food additive but this use is banned in some countries, such as Australia, China, Thailand and the United States. As a consequence, certain foods, such as caviar, produced for sale in the United States contain higher levels of salt to assist preservation. In addition to its use as a preservative, borax imparts a firm, rubbery texture to food. In China, borax (Chinese: 硼砂; pinyin: péng shā or Chinese: 月石; pinyin: yuè shí) has been found in foods including wheat and rice noodles named lamian (Chinese: 拉面; pinyin: lāmiàn), shahe fen (Chinese: 沙河粉; pinyin: shāhéfěn), char kway teow (Chinese: 粿條; pinyin: guǒ tiáo), and chee cheong fun (Chinese: 肠粉; pinyin: chángfěn) In Indonesia, it is a common, but forbidden, additive to such foods as noodles, bakso (meatballs), and steamed rice.
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437
Borax
https://en.wikipedia.org/wiki/Borax
When consumed with boric acid, numerous studies have demonstrated a negative association between borax and various types of cancers. Boric acid and borax are low in toxicity for acute oral exposures, at approximately the same acute toxicity as salt. The average dose for asymptomatic ingestion cases, which accounts for 88% of all ingestions, is around 0.9 grams. However, the range of reported asymptomatic doses is wide, from 0.01 to 88.8 g. Other uses include: Ingredient in enamel glazes Component of glass, pottery, and ceramics Used as an additive in ceramic slips and glazes to improve fit on wet, greenware, and bisque Fire retardant Anti-fungal compound for cellulose insulation Mothproofing 10% solution for wool Pulverized for the prevention of stubborn pests (e.g. German cockroaches) in closets, pipe and cable inlets, wall panelling gaps, and inaccessible locations where ordinary pesticides are undesirable Precursor for sodium perborate monohydrate that is used in detergents, as well as for boric acid and other borates Tackifier ingredient in casein, starch and dextrin-based adhesives Precursor for boric acid, a tackifier ingredient in polyvinyl acetate, polyvinyl alcohol-based adhesives To make indelible ink for dip pens by dissolving shellac into heated borax Curing agent for snake skins Curing agent for salmon eggs, for use in sport fishing for salmon Swimming pool buffering agent to control pH Neutron absorber, are used in nuclear reactors and spent fuel pools to control reactivity and to shut down a nuclear chain reaction As a micronutrient fertilizer to correct boron-deficient soils Preservative in taxidermy To color fires with a green tint Traditionally used to coat dry-cured meats such as hams to improve the appearance and discourage flies Used by blacksmiths in forge welding Used as a flux for melting metals and alloys in casting to draw out impurities and prevent oxidation Used as a woodworm treatment (diluted in water) In particle physics as an additive to nuclear emulsion, to extend the latent image lifetime of charged particle tracks.
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438
Borax
https://en.wikipedia.org/wiki/Borax
The first observation of the pion, which was awarded the 1950 Nobel Prize, used this type of emulsion. Toxicity According to one study, borax is not acutely toxic. Its LD50 (median lethal dose) score is tested at 2.66 g/kg in rats, meaning that a significant dose of the chemical is needed to cause severe symptoms or death. The lethal dose is not necessarily the same for humans. On pesticide information websites it is listed as a non-lethal compound and of no hazardous concerns. Borax has been in use as an insecticide in the United States with various restrictions since 1946. All restrictions were removed in February 1986 due to the low toxicity of borax, as reported in two EPA documents relating to boric acid and borax. EPA has determined that, because they are of low toxicity and occur naturally, boric acid and its sodium salts should be exempted from the requirement of a tolerance (maximum residue limit) for all raw agricultural commodities. Although it cited inconclusive data, a re-evaluation in 2006 by the EPA still found that "There were no signs of toxicity observed during the study and no evidence of cytotoxicity to the target organ." In the reevaluation, a study of toxicity due to overexposure was checked and the findings were that "The residential handler inhalation risks due to boric acid and its sodium salts as active ingredients are not a risk concern and do not exceed the level of concern.
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439
Borax
https://en.wikipedia.org/wiki/Borax
.." but that there could be some risk of irritation to children inhaling it if used as a powder for cleaning rugs. Overexposure to borax dust can cause respiratory irritation, while no skin irritation is known to exist due to external borax exposure. Ingestion may cause gastrointestinal distress including nausea, persistent vomiting, abdominal pain, and diarrhea. Effects on the vascular system and human brain include headaches and lethargy but are less frequent. In severe cases, a "beefy" red rash affecting the palms, soles, buttocks and scrotum has occurred. The Indonesian Directorate of Consumer Protection warns of the risk of liver cancer with high consumption of borax over a period of 5–10 years. Borax was added to the Substance of Very High Concern (SVHC) candidate list on December 16, 2010. The SVHC candidate list is part of the EU Regulations on the Registration, Evaluation, Authorisation and Restriction of Chemicals 2006 (REACH), and the addition was based on the revised classification of borax as toxic for reproduction category 1B under the CLP Regulations. Substances and mixtures imported into the EU which contain borax are now required to be labelled with the warnings "May damage fertility" and "May damage the unborn child". It was proposed for addition to REACH Annex XIV by the ECHA on July 1, 2015. If this recommendation is approved, all imports and uses of borax in the EU will have to be authorized by the ECHA.
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440
Borax
https://en.wikipedia.org/wiki/Borax
A review of the boron toxicity (as boric acid and borates) published in 2012 in the Journal of Toxicology and Environmental Health concluded: "It clearly appears that human B [boron] exposures, even in the highest exposed cohorts, are too low to reach the blood (and target tissue) concentrations that would be required to exert adverse effects on reproductive functions." A draft risk assessment released by Health Canada in July 2016 has found that overexposure to boric acid has the potential to cause developmental and reproductive health effects. Since people are already exposed to boric acid naturally through their diets and water, Health Canada advised that exposure from other sources should be reduced as much as possible, especially for children and pregnant women. The concern is not with any one product, but rather multiple exposures from a variety of sources. With this in mind, the department also announced that certain pesticides that contain boric acid, which are commonly used in homes, will have their registrations cancelled and be phased out of the marketplace. As well, new, more protective label directions are being introduced for other boric acid pesticides that continue to be registered in Canada (for example, enclosed bait stations and spot treatments using gel formulations). Footnotes See also Borax bead test John Veatch List of cleaning agents Sodium borohydride Ulexite References External links International Chemical Safety Card 0567 International Chemical Safety Card 1229 (fused borax) National Pollutant Inventory – Boron and compounds NIOSH Pocket Guide to Chemical Hazards Sodium Borate in sefsc.
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441
Borax
https://en.wikipedia.org/wiki/Borax
noaa.gov
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442
Bornyl acetate
https://en.wikipedia.org/wiki/Bornyl%20acetate
Bornyl acetate is a chemical compound. Its molecular formula is C12H20O2 and its molecular weight is 196.29 g/mol. It is the acetate ester of borneol. It is used as a food additive, flavouring agent, and odour agent. It is a component of the essential oil from pine needles (from the family Pinaceae) and primarily responsible for its odor. == References ==
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443
N-Butyl lactate
https://en.wikipedia.org/wiki/N-Butyl%20lactate
n-Butyl lactate is an industrial chemical and food additive. Uses In an industrial context, n-butyl lactate is used as a solvent and as a chemical feedstock. It is used as a dairy-related flavoring agent. Metabolism It is metabolized to lactic acid, which is in turn metabolized to n-butanol, n-butyraldehyde, and n-butyric acid. Safety n-Butyl lactate reacts with strong acids, strong bases, and oxidizers. It is also flammable. Exposure to dangerous amounts can occur through inhalation, ingestion, skin contact, or eye contact and causes irritation of the affected area, drowsiness, headache, central nervous system depression, nausea, and vomiting. It is approved as a food additive by the US Food and Drug Administration. == References ==
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444
Butyl oleate
https://en.wikipedia.org/wiki/Butyl%20oleate
Butyl oleate is a fatty acid ester and an organic chemical found in liquid form. It has the formula C22H42O2 and the CAS Registry Number 142-77-8. It is REACH registered and produced or imported into the European Union with the EC number of 205-559-6. Synthesis and reactions It is formed by the condensation of oleic acid and butanol often using an enzyme as catalyst or other biobased catalysts. Ionic liquids may also be used as the catalyst. It undergoes the Bouveault–Blanc reduction with oleyl alcohol and butanol as the products. Alternative names It is also known as Butyl cis-9-octadecenoate, Oleic acid butyl ester, butyl 9-octadecenoate and 1-butyl oleate. The IUPAC name is butyl (Z)-octadec-9-enoate. Uses It has approval for use as a food additive in Europe and also the US by the FDA. Various other uses include as a lubricant and lubricant additive, paints and coatings additive, and as a plasticizer especially for PVC. Similar to other fatty acid esters, it has found use in biodiesel and as a fuel additive. See also Ethyl oleate Oleate == References ==
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445
Tert-Butylhydroquinone
https://en.wikipedia.org/wiki/Tert-Butylhydroquinone
tert-Butylhydroquinone (TBHQ, tertiary butylhydroquinone) is a synthetic aromatic organic compound which is a type of phenol. It is a derivative of hydroquinone, substituted with a tert-butyl group. Applications Food preservative In foods, TBHQ is used as a preservative for unsaturated vegetable oils and many edible animal fats. It does not cause discoloration even in the presence of iron, and does not change flavor or odor of the material to which it is added. It can be combined with other preservatives such as butylated hydroxyanisole (BHA). As a food additive, its E number is E319. It is added to a wide range of foods. Its primary advantage is extending storage life. Other In perfumery, it is used as a fixative to lower the evaporation rate and improve stability. It is used industrially as a stabilizer to inhibit autopolymerization of organic peroxides. It is used as an antioxidant in biodiesel. It is also added to varnishes, lacquers, resins, and oil-field additives. Safety and regulation The European Food Safety Authority (EFSA) and the United States Food and Drug Administration (FDA) have evaluated TBHQ and determined that it is safe to consume at the concentration allowed in foods.
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446
Tert-Butylhydroquinone
https://en.wikipedia.org/wiki/Tert-Butylhydroquinone
The FDA and European Union both set an upper limit of 0.02% (200mg/kg) of the oil or fat content in foods. At very high doses, it has some negative health effects on lab animals, such as producing precursors to stomach tumors and damage to DNA. A number of studies have shown that prolonged exposure to very high doses of TBHQ may be carcinogenic, especially for stomach tumors. Other studies, however, have shown opposite effects including inhibition against HCA-induced carcinogenesis (by depression of metabolic activation) for TBHQ and other phenolic antioxidants (TBHQ was one of several, and not the most potent). The EFSA considers TBHQ to be noncarcinogenic. A 1986 review of scientific literature concerning the toxicity of TBHQ determined that a wide margin of safety exists between the levels of intake by humans and the doses that produce adverse effects in animal studies. In addition, TBHQ has been identified by high-throughput screening as having potential immunotoxic effects. There have been reports of vision disturbances in individuals exposed to this chemical. == References ==
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Calcium bisulfite
https://en.wikipedia.org/wiki/Calcium%20bisulfite
Calcium bisulfite (calcium bisulphite or calcium hydrogen sulfite) is an inorganic compound which is the salt of a calcium cation and a bisulfite anion. It may be prepared by treating lime with an excess of sulfur dioxide and water. As a food additive it is used as a preservative under the E number E227. Calcium bisulfite is an acid salt and behaves like an acid in aqueous solution. It is used in the sulfite process for producing paper from wood chips. Synthesis Calcium bisulfite can be prepared by treating lime (chemical formula Ca(OH)2) with an excess of sulfur dioxide and water. Upon synthesis of calcium bisulfite solution, it will have a green to yellow opaque appearance as an aqueous solution. Chemical reactions When calcium bisulfite reacts with the surrounding air, a crystalline precipitate will form composed of calcium sulfite dihydrate. When calcium bisulfite is digested as a food additive, different reactions in metabolic pathways can result. One common pathway results in a reaction that will yield 6%-8% sulfur dioxide. This can go to sulfite when absorbed by the lungs, and the sulfite will be converted to sulfate in the liver by an enzyme called sulfite oxidase. Sulfite can be harmful for people susceptible to asthma, leading to asthma attacks. Sulfite can also cause uticaria and angioedema in otherwise healthy individuals.
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Calcium bisulfite
https://en.wikipedia.org/wiki/Calcium%20bisulfite
A process known as wet limestone scrubbing is a means by which sulfur dioxide is removed from the waste emmitted during the combustion of fossil fuels. A step in this process is the oxidation of calcium bisulfite to produce sulfate. When this reaction occurs in an aqeous solution, gyspum results. The rate of this reaction can be increased in the presence of Magnesium (II) Sulfate as a catalyst. Other catalysts for the oxidation of calcium bisulfite include manganese, iron, cobalt, nickel, lead, and zinc. Application Economical Calcium bisulfite is one of the chemicals used in an overall mild bisulfite treatment meant to increase the sugar yield effieciency in processing timber excess to biofuel and jet fuel. The use of the Mild Bisulfite methodology both increases the yield and also saves cost in shipping wood to ethanol plants for processing. Calcium bisulfite is often used as a food preservative. One such case is to brine cherries. However, research is showing that some microorganisms can cause cherries to rot since they produce the enzyme polygalacturonase that can work even in the presence of calcium bisulfite. Three species of fungi that are especially capable of rotting brined cherries are Aspergillus niger, Cytospora leucostoma, and Penicillium expansum. Medicinal A calcium bisulfite liquor solution is used in the process of converting dihydroquercetin in tree bark pulp and then converting dihydroquercetin to a usable form: quercetin.
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449
Calcium bisulfite
https://en.wikipedia.org/wiki/Calcium%20bisulfite
Calcium bisulfite is not the optimum bisulfite compound for this reaction since the calcium ions can be removed from the calcium bisulfite solution during the reaction, thereby inhibiting the mechanism. However, calcium bisulfites, like other bisuflites such as ammonium bisulfite, have a catalytic capacity in this reaction since they are not used up and can be reused. See also Pulp (paper) Potassium bisulfite Sodium bisulfite == References ==
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Calcium caseinate
https://en.wikipedia.org/wiki/Calcium%20caseinate
Calcium caseinate is one of several milk proteins derived from casein in skim and 1% milk. Calcium caseinate has a papery, sweet and overall bland flavor, and is primarily used in meal preparation and fat breakdown. Caseinates are produced by adding an alkali to another derivative of casein, acid casein. The type of caseinate is determined by the cation added alongside the acid casein. Other cations used to form caseinates besides calcium include ammonium, potassium, and sodium. Calcium caseinate contains about 17% glutamic acid. This provides many health benefits such as treating low blood sugar, improving memory and focus, boosting the immune system and treating intellectual disorders. Calcium caseinate is also soluble and does not clot in the stomach. Calcium caseinate is mostly composed of 3.5% moisture, 1.0% fat, 90.9% protein, 0.1% lactose, 4.5% ash, although this may vary slightly by manufacturer. Calcium caseinate is semi-soluble in water, contrary to acid casein and rennet casein which are not soluble in water. Sodium caseinate is more water soluble than calcium caseinate, due to its polarity. Physical properties Caseins are found in milk which is held together by colloidal calcium phosphate. Calcium caseinate is generally stable at a pH above 5.7, and appears as a milky liquid. This is unlike ammonium, potassium, and sodium caseinates, which are practically clear.
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Calcium caseinate
https://en.wikipedia.org/wiki/Calcium%20caseinate
At a neutral or acidic pH, casein is relatively insoluble in water, and is easily separated from other milk proteins, sugars, and minerals. Casein can be resuspended by alternating the pH levels with NaOH or Ca(OH)2, resulting in aqueous solutions of sodium caseinate or calcium caseinate. Most caseinates are capable of withstanding temperatures of up to 140°C (284°F), however calcium caseinate is influenced by heat with temperatures as low as 50°C (122°F). Calcium is a divalent cation, allowing it to form bonds with several caseinate anions. The binding of a calcium ion is able to reduce the electrostatic repulsion and induces a net attraction between caseins. This leads to the formation of several covalent bonds between caseinate anions, which can ultimately cause the cross-linked caseinate to form pockets of hydrophobic regions. Calcium caseinate forms visco-elastic suspensions which increase remarkably when increasing concentration (50–300 g L−1) and decreasing temperature(10–50 °C). Application in food Several foods, baked goods, creamers, and toppings all contain a variety of caseinates. Calcium caseinate's nutritional benefits include improving the structure configuration of foods; emulsifying and stabilizing fat; and enhancing foaming and foam stability. Sodium caseinate acts as a greater food additive for stabilizing processed foods, however companies could opt to use calcium caseinate to increase calcium content and decrease sodium levels in their products.
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Calcium caseinate
https://en.wikipedia.org/wiki/Calcium%20caseinate
There are two Calcium Caseinate forms, spray-dried (Scaca) or roller-dried (Rcaca) which are used for multiple applications. Scaca can be found in dry milk powder, instant soups, medications, and instant coffee. It plays an important role in the conversion of fruit and vegetable juices into instant powders, instant coffees and teas, drying of eggs and dairy products such as ice cream mixes. Rcaca is mostly used in meat products and processed cheese. At high temperatures, Scaca can decrease while there is no impact on Rcaca. Some mechanical properties such as Fibrous calcium caseinate gel shows that its structure is more anisotropic than plant-based meat analogue candidates. Its formation is strongly influenced because of its solvent isotope effect. 30% of Scaca mixed with H2O gives more anisotropic fibers. On the other hand, Rcaca results in a homogeneous gel meaning that there is no effect. This demonstrates that both Scaca and Rcaca make a significant impact in the field of food science, given that these methods are commonly used for the industrial production of food biopolymers. Calcium caseinate role in the body Muscle mass Caseinate, being a protein, plays an important role for muscle hypertrophy, which is the enlargement of muscle mass. Caseinate in particular has demonstrated to be more effective with this process compared to other types of proteins, such as soy- and whey-derived proteins.
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453
Calcium caseinate
https://en.wikipedia.org/wiki/Calcium%20caseinate
Consumption of caseinate leads to higher muscle weight and less fat weight gain compared to the other two proteins. Blood pressure and insulin regulation In addition to the impact caseinate has on the body's muscle mass, it also has shown to help lower serum TAG for those who are hypertensive. Calcium caseinate supplementation has shown improvement in several cardiometabolic risk factors, such as blood pressure, arterial reactivity, lipid levels and blood vessel function. Furthermore, Calcium caseinate can help lower central systolic blood pressure by improving endothelial function. This leads to better control of vascular relaxation and contraction, as well as blood clotting regulation, immune function and platelet adhesion. Calcium caseinate has also significantly lower insulin compared to whey protein and maltodextrin which reflected in reduced plasma nonesterified fatty acids and was also able to induce lower postprandial TAG concentrations. == References ==
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454
Calcium inosinate
https://en.wikipedia.org/wiki/Calcium%20inosinate
Calcium inosinate is a calcium salt of the nucleoside inosine. Under the E number E633, it is a food additive used as a flavor enhancer.
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455
Calcium peroxide
https://en.wikipedia.org/wiki/Calcium%20peroxide
Calcium peroxide or calcium dioxide is the inorganic compound with the formula CaO2. It is the peroxide (O22−) salt of Ca2+. Commercial samples can be yellowish, but the pure compound is white. It is almost insoluble in water. Structure and stability As a solid, it is relatively stable against decomposition. In contact with water however it hydrolyzes with release of oxygen. Upon treatment with an acid, it forms hydrogen peroxide. Preparation Calcium peroxide is produced by combining calcium salts and hydrogen peroxide: Ca(OH)2 + H2O2 → CaO2 + 2 H2O The octahydrate precipitates upon the reaction of calcium hydroxide with dilute hydrogen peroxide. Upon heating it dehydrates. Applications It is mainly used as an oxidant to enhance the extraction of precious metals from their ores. In its second main application, it is used as a food additive under the E number E930 it is used as flour bleaching agent and improving agent. In agriculture it is used in the presowing treatments of rice seed. Also, calcium peroxide has found use in aquaculture to oxygenate and disinfect water. In the ecological restoration industry it is used in the treatment of soils. Calcium peroxide is used in a similar manner to magnesium peroxide for environmental restoration programs. It is used to restore soil and groundwater contaminated with petroleum by the process of enhanced in-situ bioremediation.
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456
Calcium peroxide
https://en.wikipedia.org/wiki/Calcium%20peroxide
It is a minor component of some dentifrices. It is also used for curing polythioether polymers by oxidising terminal thiol groups to disulphide bridges. == References ==
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457
Calcium stearate
https://en.wikipedia.org/wiki/Calcium%20stearate
Calcium stearate is a carboxylate salt of calcium, classified as a calcium soap. The salt is a component of some lubricants, surfactants, as well as many foodstuffs. It is a white waxy powder. Production and occurrence Calcium stearate is produced by heating stearic acid and calcium oxide: 2 C17H35COOH + CaO → (C17H35COO)2Ca + H2O It is also the main component of soap scum, a white solid that forms when soap is mixed with hard water. Unlike soaps containing sodium and potassium, calcium stearate is insoluble in water and does not lather well. Commercially it is sold as a 50% dispersion in water or as a spray dried powder. As a food additive it is known by the generic E number E470. Applications Calcium stearate is a waxy material with low solubility in water, unlike traditional sodium and potassium soaps. It is also easy and cheap to produce, and exhibits low toxicity. These attributes are the basis of many of its applications. Related applications exist for the magnesium stearate. Calcium stearate is used as a flow agent and surface conditioner in some candies such as Smarties, jawbreakers and Sprees. It is a waterproofing agent for fabrics. A lubricant in pencils and crayons. A lubricant in the dry drawing method of wire production The concrete industry uses calcium stearate for efflorescence control of cementitious products used in the production of concrete masonry units i.
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458
Calcium stearate
https://en.wikipedia.org/wiki/Calcium%20stearate
e. paver and block, as well as waterproofing. In paper production, calcium stearate is used as a lubricant to provide good gloss, preventing dusting and fold cracking in paper and paperboard making. In plastics, it can act as an acid scavenger or neutralizer at concentrations up to 1000ppm, a lubricant and a release agent. It may be used in plastic colorant concentrates to improve pigment wetting. In rigid PVC, it can accelerate fusion, improve flow, and reduce die swell. Applications in the personal care and pharmaceutical industry include tablet mold release, anti-tack agent, and gelling agent. Calcium stearate is a component in some types of defoamers. Anticaking agent for drugs etc. == References ==
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459
Calcium stearoyl-2-lactylate
https://en.wikipedia.org/wiki/Calcium%20stearoyl-2-lactylate
Calcium stearoyl-2-lactylate (calcium stearoyl lactylate or CSL) or E482 is a versatile, FDA approved food additive. It is one type of a commercially available lactylate. CSL is non-toxic, biodegradable, and typically manufactured using biorenewable feedstocks. Because CSL is a safe and highly effective food additive, it is used in a wide variety of products from baked goods and desserts to packaging. As described by the Food Chemicals Codex 7th edition, CSL is a cream-colored powder. CSL is currently manufactured by the esterification of stearic acid and lactic acid with partial neutralization using food-grade hydrated lime (calcium hydroxide). Commercial grade CSL is a mixture of calcium salts of stearoyl lactic acid, with minor proportions of other salts of related acids. The HLB for CSL is 5.1. It is slightly soluble in hot water. The pH of a 2% aqueous suspension is approximately 4.7. Food labeling requirements To be labeled as CSL for sale within the United States, the product must conform to the specifications detailed in 21 CFR 172.844. In the EU, the product must conform to the specifications detailed in Regulation (EC) No 96/77. Tests for these specifications can be found in the Food Chemical Codex. Acceptance criteria for these two regions are as follows: To be labeled as CSL for sale in other regions, the product must conform to the specifications detailed in that region's codex.
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Calcium stearoyl-2-lactylate
https://en.wikipedia.org/wiki/Calcium%20stearoyl-2-lactylate
Food applications and maximum use levels CSL finds widespread application in baked goods, cereals, pastas, instant rice, desserts, icings, fillings, puddings, toppings, sugar confectionaries, powdered beverage mixes, creamers, cream liqueurs, dehydrated potatoes, snack dips, sauces, gravies, chewing gum, dietetic foods, minced and diced canned meats, and mostarda di frutta. In the United States, approved uses and use levels are described in 21 CFR 172.844, 21 CFR 176.170 and 21 CFR 177.120. while the corresponding regulations in the EU are listed in Regulation (EC) No 95/2. The largest application of CSL is in yeast leavened bakery products. Although CSL was introduced to the market first, most applications use SSL. The main reason for the preference of SSL over CSL is that CSL has less crumb softening effects than SSL. However, CSL is still preferred in some applications, such as lean hearth bread-type formulations. In these applications, CSL is preferred because CSL performs better than SSL as a dough strengthener, while the finished product does not require a soft crumb or a perfectly symmetrical loaf shape. == References ==
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461
Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
Calcium sulfate (or calcium sulphate) is the inorganic compound with the formula CaSO4 and related hydrates. In the form of γ-anhydrite (the anhydrous form), it is used as a desiccant. One particular hydrate is better known as plaster of Paris, and another occurs naturally as the mineral gypsum. It has many uses in industry. All forms are white solids that are poorly soluble in water. Calcium sulfate causes permanent hardness in water. Hydration states and crystallographic structures The compound exists in three levels of hydration corresponding to different crystallographic structures and to minerals: CaSO4 (anhydrite): anhydrous state. The structure is related to that of zirconium orthosilicate (zircon): Ca2+ is 8-coordinate, SO2−4 is tetrahedral, O is 3-coordinate. CaSO4·2H2O (gypsum and selenite (mineral)): dihydrate. CaSO4·1/2H2O (bassanite): hemihydrate, also known as plaster of Paris. Specific hemihydrates are sometimes distinguished: α-hemihydrate and β-hemihydrate. Uses The main use of calcium sulfate is to produce plaster of Paris and stucco. These applications exploit the fact that calcium sulfate which has been powdered and calcined forms a moldable paste upon hydration and hardens as crystalline calcium sulfate dihydrate.
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462
Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
It is also convenient that calcium sulfate is poorly soluble in water and does not readily dissolve in contact with water after its solidification. Hydration and dehydration reactions With judicious heating, gypsum converts to the partially dehydrated mineral called bassanite or plaster of Paris. This material has the formula CaSO4·(nH2O), where 0.5 ≤ n ≤ 0.8. Temperatures between 100 and 150 °C (212–302 °F) are required to drive off the water within its structure. The details of the temperature and time depend on ambient humidity. Temperatures as high as 170 °C (338 °F) are used in industrial calcination, but at these temperatures γ-anhydrite begins to form. The heat energy delivered to the gypsum at this time (the heat of hydration) tends to go into driving off water (as water vapor) rather than increasing the temperature of the mineral, which rises slowly until the water is gone, then increases more rapidly. The equation for the partial dehydration is: CaSO4 · 2 H2O → CaSO4 · 1/2 H2O + 1+1/2 H2O↑ The endothermic property of this reaction is relevant to the performance of drywall, conferring fire resistance to residential and other structures. In a fire, the structure behind a sheet of drywall will remain relatively cool as water is lost from the gypsum, thus preventing (or substantially retarding) damage to the framing (through combustion of wood members or loss of strength of steel at high temperatures) and consequent structural collapse.
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463
Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
But at higher temperatures, calcium sulfate will release oxygen and act as an oxidizing agent. This property is used in aluminothermy. In contrast to most minerals, which when rehydrated simply form liquid or semi-liquid pastes, or remain powdery, calcined gypsum has an unusual property: when mixed with water at normal (ambient) temperatures, it quickly reverts chemically to the preferred dihydrate form, while physically "setting" to form a rigid and relatively strong gypsum crystal lattice: CaSO4 · 1/2 H2O + 1+1/2 H2O → CaSO4 · 2 H2O This reaction is exothermic and is responsible for the ease with which gypsum can be cast into various shapes including sheets (for drywall), sticks (for blackboard chalk), and molds (to immobilize broken bones, or for metal casting). Mixed with polymers, it has been used as a bone repair cement. Small amounts of calcined gypsum are added to earth to create strong structures directly from cast earth, an alternative to adobe (which loses its strength when wet). The conditions of dehydration can be changed to adjust the porosity of the hemihydrate, resulting in the so-called α- and β-hemihydrates (which are more or less chemically identical). On heating to 180 °C (356 °F), the nearly water-free form, called γ-anhydrite (CaSO4·nH2O where n = 0 to 0.
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464
Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
05) is produced. γ-Anhydrite reacts slowly with water to return to the dihydrate state, a property exploited in some commercial desiccants. On heating above 250 °C, the completely anhydrous form called β-anhydrite or "natural" anhydrite is formed. Natural anhydrite does not react with water, even over geological timescales, unless very finely ground. The variable composition of the hemihydrate and γ-anhydrite, and their easy inter-conversion, is due to their nearly identical crystal structures containing "channels" that can accommodate variable amounts of water, or other small molecules such as methanol. Food industry The calcium sulfate hydrates are used as a coagulant in products such as tofu. For the FDA, it is permitted in cheese and related cheese products; cereal flours; bakery products; frozen desserts; artificial sweeteners for jelly & preserves; condiment vegetables; and condiment tomatoes and some candies. It is known in the E number series as E516, and the UN's FAO knows it as a firming agent, a flour treatment agent, a sequestrant, and a leavening agent. Dentistry Calcium sulfate has a long history of use in dentistry. It has been used in bone regeneration as a graft material and graft binder (or extender) and as a barrier in guided bone tissue regeneration.
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465
Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
It is a biocompatible material and is completely resorbed following implantation. It does not evoke a significant host response and creates a calcium-rich milieu in the area of implantation. Other uses When sold at the anhydrous state as a desiccant with a color-indicating agent under the name Drierite, it appears blue (anhydrous) or pink (hydrated) due to impregnation with cobalt(II) chloride, which functions as a moisture indicator. Up to the 1970s, commercial quantities of sulfuric acid were produced at many locations from anhydrous calcium sulfate. Upon being mixed with shale or marl, and roasted at 1400°C, the sulfate liberates sulfur dioxide gas, a precursor in sulfuric acid production. The reaction also produces calcium silicate, a mineral phase essential in cement clinker production. 2 CaSO4 + 2 SiO2 + C → 2 CaSiO3 + 2 SO2 + CO2 The plants made sulfuric acid by the “Anhydrite Process”, in which cement clinker itself was a by-product. In this process, anhydrite (calcium sulfate) replaces limestone in a cement rawmix, and under reducing conditions, sulfur dioxide is evolved instead of carbon dioxide. The sulfur dioxide is converted to sulfuric acid by the Contact Process using a vanadium pentoxide catalyst. CaSO4 + 2 C → CaS + 2CO2 3 CaSO4 + CaS + 2 SiO2 → 2 Ca2SiO4 (belite) + 4 SO2 3 CaSO4 + CaS → 4 CaO + 4 SO2 Ca2SiO4 + CaO → Ca3OSiO4 (alite) 2 SO2 + O2 → 2 SO3 (in the presence of the catalyst vanadium pentoxide) SO3 + H2O → H2SO4 Because of its use in an expanding niche market, the plant at Whitehaven, Cumbria continued to expand in a manner not shared by the other Anhydrite Process plants.
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Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
The anhydrite mine opened on 11/1/1955, and the acid plant started on 14/11/1955. For a while in the early 1970s, it became the largest sulfuric acid plant in the UK, making about 13% of national production, and it was by far the largest Anhydrite Process plant ever built. Production and occurrence The main sources of calcium sulfate are naturally occurring gypsum and anhydrite, which occur at many locations worldwide as evaporites. These may be extracted by open-cast quarrying or by deep mining. World production of natural gypsum is around 127 million tonnes per annum. In addition to natural sources, calcium sulfate is produced as a by-product in a number of processes: In flue-gas desulfurization, exhaust gases from fossil-fuel power stations and other processes (e.g. cement manufacture) are scrubbed to reduce their sulfur dioxide content, by injecting finely ground limestone: SO2 + 0.5 O2 + CaCO3 → CaSO4 + CO2 Related sulfur-trapping methods use lime and some produces an impure calcium sulfite, which oxidizes on storage to calcium sulfate. In the production of phosphoric acid from phosphate rock, calcium phosphate is treated with sulfuric acid and calcium sulfate precipitates. The product, called phosphogypsum is often contaminated with impurities making its use uneconomic. In the production of hydrogen fluoride, calcium fluoride is treated with sulfuric acid, precipitating calcium sulfate.
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467
Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
In the refining of zinc, solutions of zinc sulfate are treated with hydrated lime to co-precipitate heavy metals such as barium. Calcium sulfate can also be recovered and re-used from scrap drywall at construction sites. These precipitation processes tend to concentrate radioactive elements in the calcium sulfate product. This issue is particular with the phosphate by-product, since phosphate ores naturally contain uranium and its decay products such as radium-226, lead-210 and polonium-210. Extraction of uranium from phosphorus ores can be economical on its own depending on prices on the uranium market or the separation of uranium can be mandated by environmental legislation and its sale is used to recover part of the cost of the process. Calcium sulfate is also a common component of fouling deposits in industrial heat exchangers, because its solubility decreases with increasing temperature (see the specific section on the retrograde solubility). Retrograde solubility The dissolution of the different crystalline phases of calcium sulfate in water is exothermic and releases heat (decrease in Enthalpy: ΔH < 0). As an immediate consequence, to proceed, the dissolution reaction needs to evacuate this heat that can be considered as a product of reaction. If the system is cooled, the dissolution equilibrium will evolve towards the right according to the Le Chatelier principle and calcium sulfate will dissolve more easily. Thus the solubility of calcium sulfate increases as the temperature decreases and vice versa. If the temperature of the system is raised, the reaction heat cannot dissipate and the equilibrium will regress towards the left according to Le Chatelier principle.
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Calcium sulfate
https://en.wikipedia.org/wiki/Calcium%20sulfate
The solubility of calcium sulfate decreases as temperature increases. This counter-intuitive solubility behaviour is called retrograde solubility. It is less common than for most of the salts whose dissolution reaction is endothermic (i.e., the reaction consumes heat: increase in Enthalpy: ΔH > 0) and whose solubility increases with temperature. Another calcium compound, calcium hydroxide (Ca(OH)2, portlandite) also exhibits a retrograde solubility for the same thermodynamic reason: because its dissolution reaction is also exothermic and releases heat. So, to dissolve the maximum amount of calcium sulfate or calcium hydroxide in water, it is necessary to cool the solution down close to its freezing point instead of increasing its temperature. The retrograde solubility of calcium sulfate is also responsible for its precipitation in the hottest zone of heating systems and for its contribution to the formation of scale in boilers along with the precipitation of calcium carbonate whose solubility also decreases when CO2 degasses from hot water or can escape out of the system. On planet Mars 2011 findings by the Opportunity rover on the planet Mars show a form of calcium sulfate in a vein on the surface. Images suggest the mineral is gypsum. See also Calcium sulfate (data page) Alabaster Anhydrite Bathybius haeckelii Chalk (calcium carbonate) Gypsum Gypsum plaster Phosphogypsum Selenite (mineral) Flue-gas desulfurization References External links International Chemical Safety Card 1215 NIOSH Pocket Guide to Chemical Hazards
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Candelilla wax
https://en.wikipedia.org/wiki/Candelilla%20wax
Candelilla wax is a wax derived from the leaves of the small candelilla shrub native to northern Mexico and the southwestern United States, Euphorbia antisyphilitica, from the family Euphorbiaceae. It is yellowish-brown, hard, brittle, aromatic, and opaque to translucent. Composition and production With a melting point of 68.5–72.5 °C (155–162 °F), candelilla wax consists of mainly hydrocarbons (about 50%, chains with 29–33 carbons), esters of higher molecular weight (20–29%), free acids (7–9%), and resins (12–14%, mainly triterpenoid esters). The high hydrocarbon content distinguishes this wax from carnauba wax. It is insoluble in water, but soluble in many organic solvents such as acetone, chloroform, benzene, and turpentine. The wax is obtained by boiling the leaves and stems with dilute sulfuric acid, and the resulting "cerote" is skimmed from the surface and further processed. In this way, about 900 tons are produced annually. Uses It is mostly used mixed with other waxes to harden them without raising their melting point. As a food additive, candelilla wax has the E number E 902 and is used as a glazing agent. It also finds use in the cosmetic industry, as a component of lip balms and lotion bars.
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Candelilla wax
https://en.wikipedia.org/wiki/Candelilla%20wax
One of its major uses is as a binder for chewing gums. Candelilla wax can be used as a substitute for carnauba wax and beeswax. It is also used for making varnish. References External links Candelilla wax data sheet - from the UN Food and Agriculture Organization Candelilla Institute Wax, Men, and Money: Candelilla Wax Camps along the Rio Grande
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471
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
Carboxymethyl cellulose (CMC) or cellulose gum is a cellulose derivative with carboxymethyl groups (-CH2-COOH) bound to some of the hydroxyl groups of the glucopyranose monomers that make up the cellulose backbone. It is often used in its sodium salt form, sodium carboxymethyl cellulose. It used to be marketed under the name Tylose, a registered trademark of SE Tylose. Preparation Carboxymethyl cellulose is synthesized by the alkali-catalyzed reaction of cellulose with chloroacetic acid. The polar (organic acid) carboxyl groups render the cellulose soluble and chemically reactive. Fabrics made of cellulose—e.g., cotton or viscose rayon—may also be converted into CMC. Following the initial reaction, the resultant mixture produces approximately 60% CMC and 40% salts (sodium chloride and sodium glycolate). This product, called technical CMC, is used in detergents. An additional purification process is used to remove salts to produce pure CMC, which is used for food and pharmaceutical applications. An intermediate "semi-purified" grade is also produced, which is typically used in paper applications such as the restoration of archival documents. Structure and properties Structure CMC is a derivative of the regenerated cellulose [C6H10O5]n with hydroxy-acetic acid (hydroxy ethanoic acid) CH2(OH)COOH or sodium monochloroacetate ClCH2COONa.
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472
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
The CMC backbone consists of D-glucose residues linked by -1,4-linkage. It has carboxymethyl groups (-CH2-COOH) bound to some of the hydroxyl groups of the glucopyranose monomers that make up the cellulose backbone. It is often used as its sodium salt, sodium carboxymethyl cellulose. Properties CMC is a white or lightly yellow powder with no odor, no flavor, and no poisonous properties. It is hygroscopic and dissolves well in either hot or cold water, forming a viscous solution. It is not soluble in organic solvents like methanol, ethanol, acetone, chloroform, benzol, etc. The functional properties of CMC depend on the degree of substitution of the cellulose structure (i.e., how many of the hydroxyl groups have been converted to carboxymethylene (oxy) groups in the substitution reaction), as well as the chain length of the cellulose backbone structure and the degree of clustering of the carboxymethyl substituents. It is commonly used as a viscosity modifier or thickener, and to stabilize emulsions in various products, both food and non-food related. It is used primarily because it has a high viscosity, is nontoxic, and is generally considered to be hypoallergenic.
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473
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
Uses Introduction Carboxymethyl cellulose (CMC) is used in a large variety of applications ranging from food production to medical treatments. It is commonly used as a viscosity modifier or thickener and to stabilize emulsions in both food and non-food products. It is used primarily because it has high viscosity, is nontoxic, and is generally considered to be hypoallergenic, as the major source fiber is either softwood pulp or cotton linter. Non-food products include products such as toothpaste, laxatives, diet pills, water-based paints, detergents, textile sizing, reusable heat packs, various paper products, filtration materials, synthetic membranes, wound healing applications, and also in leather crafting to help burnish edges. Food science CMC is registered as E466 or E469 (when it is enzymatically hydrolyzed). CMC used for a viscosity modifier or thickener and to stabilize emulsions in various products, including ice cream, mayonnaise, and beverages. CMC is also used extensively in gluten-free and reduced-fat food products. Marshmallows: CMC not only prevents dehydration and shrinkage of the product but also contributes to a more airy structure. When combined with gelatin, it can significantly increase the viscosity of the gelatin.
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474
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
A high molecular weight CMC (DS around 1.0) should be selected. Ice cream: CMC has a lower viscosity at higher temperatures, and its viscosity increases upon cooling, which is conducive to the improvement of the expansion rate of the product and facilitates operation. It is advisable to use CMC at a concentration less than 0.4% (viscosity: 250~260 mPa·s or DS around 0.6). Fruit juice beverages, soups, sauces, and instant soluble drinks: Due to its good rheological properties (pseudoplasticity), CMC delivers a refreshing taste, and its excellent suspension stability ensures uniform flavor and texture throughout the product. For acidic fruit juices, a CMC with good uniformity in degree of substitution is required. If it is further blended with a certain proportion of other water-soluble gums (such as xanthan gum), the effect can be even better. A high viscosity CMC (DS0.6~0.8) should be selected. Instant noodles: The addition of 0.1% CMC helps to control moisture content, reduce oil absorption, and enhance the glossiness of the noodles. Dehydrated vegetables, tofu skin, and dried tofu sticks, and other dehydrated foods: They rehydrate well and easily, and have a good appearance. It is advisable to use high viscosity CMC (with a degree of substitution around 0.
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Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
6). Noodles, bread, and frozen foods: CMC can prevent starch retrogradation and dehydration, and control the viscosity of pastes. The effect is further improved when used in combination with konjac flour, xanthan gum, certain emulsifiers, and phosphates. A medium viscosity CMC (DS0.5 to 0.8) should be selected. Orange juice, pulpy orange, coconut juice, and fruit tea: Because it provides excellent suspension and support, it is even better when combined with xanthan gum or agar. A medium viscosity CMC (DS around 0.6) should be selected. Soy sauce: The addition of salt-tolerant CMC to adjust its viscosity can make the soy sauce have a delicate and smooth taste. Vegetarian burgers: CMC is used to enhance the texture, stability, and shelf life of vegetarian burgers, making them more palatable and easier to handle during cooking and consumption. Food fraud Shrimp and prawns: CMC injections have been used to fraudulently increase the weight and visual appeal. Detergent uses Detergent Grade Carboxymethyl Cellulose (CMC) is a cornerstone ingredient in modern cleaning products. CMC is used for its thickening and stabilizing properties, enhancing the texture and efficiency of detergents. It plays an important role in improving soil suspension and preventing redeposition, making it essential for high-performance laundry and dishwashing detergents.
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476
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
With a tailored viscosity range, CMC ensures detergents maintain optimal consistency, crucial for both liquid and powder formulas. Its compatibility with diverse detergent ingredients, including surfactants and builders, allows for versatile applications. Laundry Detergents: 5% CMC incorporated to improve soil suspension and fabric care. Blend with surfactants, builders, and fragrance. This formulation ensures efficient cleaning and fabric protection, making laundry detergents more effective. Dishwashing Liquids: 3% CMC used for enhanced grease removal and suds stability. Combine with cleaning agents and scents. This mix results in a powerful dishwashing liquid that cuts through grease and leaves dishes spotless. Powdered Detergents: 4% CMC added to prevent caking and ensure smooth texture. Mix with cleaning agents, brighteners, and fragrance. This formulation keeps powdered detergents free-flowing and effective. Hand Washes: 2% CMC blended for a luxurious, moisturizing feel. Include cleansing agents and essential oils. This composition creates hand washes that clean effectively while being gentle on the skin. Surface Cleaners: 1.5% CMC incorporated to enhance cleaning power and leave a streak-free finish. Mix with disinfectants and fragrances. This formula is ideal for multi-surface cleaners that effectively clean and freshen surfaces. Car Wash Solutions: 2% CMC used to remove tough dirt and grime. Combine with cleaning agents and wax for shine.
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477
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
This formulation results in a car wash solution that cleans effectively without damaging the vehicle’s finish. Fabric Softeners: 3% CMC added to fabric softeners for improved texture and fabric conditioning. Blend with softening agents and scents. This formula makes fabrics feel soft and smell fresh. Toilet Bowl Cleaners: 2% CMC incorporated for enhanced cling to bowl surfaces. Mix with disinfectants and cleaning agents. This formula ensures a thorough clean and lasting freshness in toilet bowl cleaners. Textile uses Textile Grade Carboxymethyl Cellulose (CMC) is an essential component in the textile industry, widely used for its diverse applications. Primarily, it’s employed as a thickening agent in textile printing, constituting about 2-3% of printing pastes, to achieve sharp, clear designs. In dyeing processes, CMC, at a concentration of 1-2%, aids in uniform dye dispersion and fixation, ensuring vibrant and consistent colors. It’s also used in fabric finishing, at about 0.5-1%, to enhance fabric hand feel and texture. Additionally, CMC serves as a binding agent in non-woven fabrics, contributing to the strength and stability of the material. In sizing applications, about 1-3% of CMC is used to protect yarns during weaving, reducing breakages. The product’s role in fabric softening and conditioning is pivotal, improving the overall quality and wearability of textiles.
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478
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
Textile Printing: Mix 3% CMC to create thickened printing pastes, ensuring precise and vibrant prints on fabrics. Blend with dyes and water to achieve desired consistency. This application results in sharp, clear textile designs that are visually appealing. Fabric Dyeing: Use 2% CMC for even dye distribution and improved color fixation in fabric dyeing. Combine with fabric dyes and water, ensuring uniform application. This leads to consistently colored fabrics with long-lasting hues. Fabric Finishing: Incorporate 1% CMC in finishing solutions to enhance fabric feel and appearance. Mix with finishing agents and apply to textiles. This application gives fabrics a soft, luxurious texture and improves wear resistance. Yarn Sizing: Apply 3% CMC in sizing mixtures to protect yarn during weaving. Blend with starches and size mixtures, enhancing yarn strength and reducing breakages in the loom. This ensures smoother weaving and higher-quality textiles. Non-Woven Fabric Production: Use 2% CMC as a binder in non-woven fabrics for increased strength and stability. Combine with fibrous materials, creating durable and cohesive non-woven textiles used in various applications. Fabric Softening: Add 1.5% CMC to softening solutions for a softer fabric hand feel. Mix with softeners and apply to textiles, resulting in comfortable and pleasant-to-touch fabrics, ideal for clothing and home textiles. Textile Coatings: Incorporate 2.5% CMC in coating formulations to improve fabric coating uniformity.
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479
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
Blend with coating materials, enhancing the protective properties of coated fabrics used in specialty applications. Printing Thickener Replacement: Use CMC as an eco-friendly alternative to synthetic thickeners in printing pastes. Mix 3% CMC to achieve the desired viscosity, providing a sustainable and effective solution for textile printing. Cosmetics uses Cosmetics Grade Carboxymethyl Cellulose (CMC) is a versatile ingredient used in over 50% of cosmetic products for its exceptional properties. As a thickening agent, it’s crucial in formulations where viscosity needs to be precisely controlled, commonly found in 30-40% of skincare products. In hair care, about 25% of shampoos and conditioners utilize CMC for its conditioning and detangling effects. It’s also a staple in makeup, contributing to the texture and stability of around 20% of foundations and mascaras. In toothpaste, making up approximately 15% of the market, CMC enhances texture and consistency. Its moisture retention properties are vital in 35% of moisturizers and lotions, ensuring skin hydration. Moreover, CMC serves as a film-forming agent in approximately 10% of sunscreens, improving application and wear. These diverse applications underscore CMC’s critical role in enhancing the quality and performance of cosmetic products. Cleansing Lotion: Formulate with 1.5% CMC (FH9), 5% Beta-Cyclodextrin Hydrate, 15% Liquid Paraffin, and 5% Glycerin.
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480
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
Add suitable preservatives and fragrances. Mix with distilled water to make up to 100%. This emulsion serves as an excellent and stable cosmetic product. Almond Cream: Use 1.3% CMC (FH9), 9.9% Almond Oil, 0.2% Bitter Almond Oil, 0.8% Geranium Oil, and 90% Ethanol. Include appropriate amounts of preservatives and fragrances. Mix well, then dilute with 100% distilled water. This almond cream offers excellent skin protection and anti-wrinkle benefits. Lipstick: CMC aids in pigment suspension and dispersion, binding other ingredients for even distribution. For more information, contact Carboxymethyl Cellulose suppliers. Dosage: 0.5%-1.0%, using grade FH9. Royal Jelly Face Mask: Royal Jelly, a precious natural nourisher, stimulates gland activity and disease resistance, offering special skin protection. Adding CMC to the face mask ensures uniform distribution of ingredients and enhances skin hydration. It also has excellent film-forming properties. Formula: 2% CMC (FH9), 1% Sodium Alginate, 5% Polyethylene Glycol, 1% Carbomer 940, 1.5% Polyoxyethylene Lauryl Ether, 10% Ethanol, 0.5% Triethanolamine, 5% Glycerin, 0.
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481
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
5% Royal Jelly, and 73.5% Refined Water, with a suitable amount of preservative. Shampoo: CMC combined with Fatty Acid Ethanolamine or 2,2'-Iminodiethanol forms a thin film around hair, providing a sleek effect. Typical Formula: 2.5% CMC (FH9), 10% Propylene Glycol (plasticizer), 44.6% Water, Triethanolamine, 20% Sodium Lauryl Sulfate (cleansing agent), Sorbitol, 3% Polyoxethylene (adjusting agent), 2% Sodium Stearate (brightener), 0.8% Dye, Fragrances, and a suitable amount of preservative. Anti-Aging Serum: A formula comprising 0.7% CMC (FH9) for a smooth, gel-like texture. It includes 10% Hyaluronic Acid for deep hydration, 2% Vitamin C for skin brightening, and 5% Collagen for elasticity. The base is a mixture of 70% water and 10% Glycerin, enhanced with natural antioxidants and preservatives. Sunscreen Lotion: Formulated with 2% CMC (FH9) for consistency and stability. It contains 10% Zinc Oxide and 5% Titanium Dioxide for broad-spectrum UV protection. Additional ingredients include 5% Aloe Vera for soothing and 3% Vitamin E for skin repair.
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482
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
The base is 70% water, with added emollients and preservatives. Hand Cream: This cream uses 1.5% CMC (FH9) for a rich texture. Key ingredients include 5% Shea Butter for moisturizing, 2% Glycerin for hydration, and 0.5% Allantoin for skin repair. The formula is enhanced with 80% water, essential oils for fragrance, and preservatives to maintain shelf life. Hair Styling Gel: A formulation with 1.2% CMC (FH9) for strong hold and flexibility. It includes 5% Vegetable Glycerin for moisture, 2% Pro-Vitamin B5 for hair strength, and 0.5% Argan Oil for shine. The base consists of 85% water, along with natural fragrances and preservatives for a lasting effect. CMC is used to achieve tartrate or cold stability in wine, an innovation that may save megawatts of electricity used to chill wine in warm climates. It is more stable than metatartaric acid and is very effective in inhibiting tartrate precipitation. It is reported that KHT crystals, in presence of CMC, grow slower and change their morphology. Their shape becomes flatter because they lose 2 of the 7 faces, changing their dimensions. CMC molecules, negatively charged at wine pH, interact with the electropositive surface of the crystals, where potassium ions are accumulated.
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483
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
The slower growth of the crystals and the modification of their shape are caused by the competition between CMC molecules and bitartrate ions for binding to the KHT crystals. Specific culinary uses CMC powder is widely used in the ice cream industry, to make ice creams without churning or extremely low temperatures, thereby eliminating the need for conventional churners or salt ice mixes. CMC is used in baking breads and cakes. The use of CMC gives the loaf an improved quality at a reduced cost, by reducing the need of fat. CMC is also used as an emulsifier in biscuits. By dispersing fat uniformly in the dough, it improves the release of the dough from the moulds and cutters, achieving well-shaped biscuits without any distorted edges. It can also help to reduce the amount of egg yolk or fat used in making the biscuits. Use of CMC in candy preparation ensures smooth dispersion in flavor oils, and improves texture and quality. CMC is used in chewing gums, margarines and peanut butter as an emulsifier. Medical applications CMC is also used in numerous medical applications. Some examples include: Device for epistaxis (nose bleeding). A poly-vinyl chloride (PVC) balloon is covered by CMC knitted fabric reinforced by nylon. The device is soaked in water to form a gel, which is inserted into the nose of the balloon and inflated. The combination of the inflated balloon and the therapeutic effect of the CMC stops the bleeding.
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484
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
Fabric used as a dressing following ear nose and throat surgical procedures. Water is added to form a gel, and this gel is inserted into the sinus cavity following surgery. In ophthalmology, CMC is used as a lubricating agent in artificial tears solutions for the treatment of dry eyes. In veterinary medicine, CMC is used in abdominal surgeries in large animals, particularly horses, to prevent the formation of bowel adhesions. Research applications Insoluble CMC (water-insoluble) can be used in the purification of proteins, particularly in the form of charged filtration membranes or as granules in cation-exchange resins for ion-exchange chromatography. Its low solubility is a result of a lower DS value (the number of carboxymethyl groups per anhydroglucose unit in the cellulose chain) compared to soluble CMC. Insoluble CMC offers physical properties similar to insoluble cellulose, while the negatively charged carboxylate groups allow it to bind to positively charged proteins. Insoluble CMC can also be chemically cross-linked to enhance the mechanical strength of the material. Moreover, CMC has been used extensively to characterize enzyme activity from endoglucanases (part of the cellulase complex); it is a highly specific substrate for endo-acting cellulases, as its structure has been engineered to decrystallize cellulose and create amorphous sites that are ideal for endoglucanase action.
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485
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
CMC is desirable because the catalysis product (glucose) is easily measured using a reducing sugar assay, such as 3,5-dinitrosalicylic acid. Using CMC in enzyme assays is especially important in screening for cellulase enzymes that are needed for more efficient cellulosic ethanol conversion. CMC was misused in early work with cellulase enzymes, as many had associated whole cellulase activity with CMC hydrolysis. As the mechanism of cellulose depolymerization became better understood, it became clear that exo-cellulases are dominant in the degradation of crystalline (e.g. Avicel) and not soluble (e.g. CMC) cellulose. Other uses In laundry detergents, it is used as a soil suspension polymer designed to deposit onto cotton and other cellulosic fabrics, creating a negatively charged barrier to soils in the wash solution. CMC is also used as a thickening agent, for example, in the oil-drilling industry as an ingredient of drilling mud, where it acts as a viscosity modifier and water retention agent. CMC is sometimes used as an electrode binder in advanced battery applications (i.e. lithium ion batteries), especially with graphite anodes. CMC's water solubility allows for less toxic and costly processing than with non-water-soluble binders, like the traditional polyvinylidene fluoride (PVDF), which requires toxic n-methylpyrrolidone (NMP) for processing.
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486
Carboxymethyl cellulose
https://en.wikipedia.org/wiki/Carboxymethyl%20cellulose
CMC is often used in conjunction with styrene-butadiene rubber (SBR) for electrodes requiring extra flexibility, e.g. for use with silicon-containing anodes. CMC is also used in ice packs to form a eutectic mixture resulting in a lower freezing point, and therefore more cooling capacity than ice. Aqueous solutions of CMC have also been used to disperse carbon nanotubes, where the long CMC molecules are thought to wrap around the nanotubes, allowing them to be dispersed in water. In conservation-restoration, it is used as an adhesive or fixative (commercial name Walocel, Klucel). Adverse reactions Effects on inflammation, microbiota-related metabolic syndrome, and colitis are a subject of research. Carboxymethyl cellulose is suggested as a possible cause of inflammation of the gut, through alteration of the human gastrointestinal microbiota, and has been suggested as a triggering factor in inflammatory bowel diseases such as ulcerative colitis and Crohn's disease. While thought to be uncommon, case reports of severe reactions to carboxymethyl cellulose exist. Skin testing is believed to be a useful diagnostic tool for this purpose. Carboxymethyl cellulose was the active ingredient in an eye drop brand Ezricare Artificial Tears which was recalled due to potential bacterial contamination. See also Croscarmellose sodium Hydroxypropyl cellulose Methyl cellulose References External links CMC chemical structure and properties MC and CMC: commercial preparations and various uses, including paper conservation; bibliography
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Carnauba wax
https://en.wikipedia.org/wiki/Carnauba%20wax
Carnauba (; Portuguese: carnaúba [kaʁnaˈubɐ]), also called Brazil wax and palm wax, is a wax of the leaves of the carnauba palm Copernicia prunifera (synonym: Copernicia cerifera), a plant native to and grown only in the northeastern Brazilian states of Ceará, Piauí, Paraíba, Pernambuco, Rio Grande do Norte, Maranhão and Bahia. It is known as the "Queen of Waxes". In its pure state, it is usually available in the form of hard yellow-brown flakes. It is obtained by collecting and drying the leaves, beating them to loosen the wax, then refining and bleaching it. As a food additive, its E number is E903. Composition Carnauba consists mostly of aliphatic esters (40 wt%), diesters of 4-hydroxycinnamic acid (21.0 wt%), ω-hydroxycarboxylic acids (13.0 wt%), and fatty alcohols (12 wt%). The compounds are predominantly derived from acids and alcohols in the C26-C30 range. It is distinctive for its high content of diesters and its methoxycinnamic acid. It is sold in grades of T1, T3 and T4 according to its purity level, which is accomplished by filtration, centrifugation and bleaching.
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Carnauba wax
https://en.wikipedia.org/wiki/Carnauba%20wax
Properties Because it creates a glossy finish, carnauba wax is used in automobile waxes, shoe polishes, dental floss, food products (such as sweets), polishes for musical instruments, and floor and furniture waxes and polishes, especially when mixed with beeswax and turpentine. It is commonly used for paper coatings in the United States. In its purest form, it was often used on speedboat hulls in the early 1960s to enhance speed and handling in saltwater. It is also used in some surfboard waxes, possibly in combination with coconut oil. Because of its hypoallergenic and emollient properties as well as its gloss, carnauba wax is used as a thickener in cosmetics such as lipstick, eyeliner, mascara, eye shadow, foundation, deodorant, and skincare and sun care preparations. It is also used to make cutler's resin. It is the finish of choice for most briar tobacco smoking pipes, as it produces a high gloss when buffed that dulls with time, rather than flaking off like most other finishes. Because it is too brittle to be used alone, carnauba wax is often combined with other waxes (principally beeswax) to treat and waterproof leather products, where it provides a high-gloss finish and increases leather's hardness and durability. It is also used in the pharmaceutical industry as a coating to make tablets easier to swallow.
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489
Carnauba wax
https://en.wikipedia.org/wiki/Carnauba%20wax
A very small amount (less than 1/100 of 1% by weight, e.g. 30 grams per 300 kg) is sprinkled onto a batch of tablets after they have been sprayed and dried; they are then tumbled for a few minutes to coat them. In 1890, Charles Tainter patented the use of carnauba wax on phonograph cylinders as a replacement for the usual paraffin/beeswax mixture. Carnauba wax may be used as a mold release agent for manufacturing fibre-reinforced plastics. An aerosol mold release agent is formed by dissolving it in a solvent. Unlike silicone or PTFE, carnauba is suitable for use with liquid epoxy, epoxy molding compounds (EMC), and some other plastic types, generally enhancing their properties. It is not very soluble in chlorinated or aromatic hydrocarbons. It is used in melt/castable explosives to produce an insensitive explosive formula such as Composition B, which is a blend of RDX and TNT. Production and export In 2006, Brazil produced 22,409 tons of carnauba wax, of which 14% was solid and 86% was in powder form. There are 20 to 25 exporters of carnauba wax in Brazil who, after buying it from middlemen or directly from farmers, refine the wax before shipping it to the rest of the world. The four largest exporters are Pontes, Brasil Ceras, Foncepi, and Carnauba do Brasil, who together account for around €25 million of the export market.
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490
Carnauba wax
https://en.wikipedia.org/wiki/Carnauba%20wax
According to the German television program Markencheck, conditions for many carnauba production workers are quite poor; one Brazilian Labor Ministry official found conditions "that could be described as slavery." According to the Brazilian Ministry of Development, Industry and Foreign Trade, the major destinations for exported carnauba wax are: United States (25%) Japan (15–25%) Germany (10–15%) Netherlands (5%) Italy (5%) Other countries (18%) The Initiative for Responsible Carnauba (IRC) was founded in 2018 as part of the Private Business Action for Biodiversity project, in association with the Union for Ethical BioTrade (UEBT). Its aim is to foster responsible production that respects workers’ rights and preserves biodiversity. In an established working group with 20 local manufacturers and international distributors and brands, the IRC has set social, traceability and biodiversity standards and helped local producers implement them, with the UEBT's support. In collaboration with the local NGO Associação Caatinga, the Initiative has created a manual of good practices for the sector and 12 short learning videos, available on YouTube and sharable via WhatsApp, to inform field workers of their rights and about good biodiversity practices. Technical characteristics INCI name: Copernicia cerifera (carnauba) wax Melting point: 82–86 °C (180–187 °F) (among the highest of natural waxes; higher than beeswax, 62–64 °C (144–147 °F)) Relative density: ~0.
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491
Carnauba wax
https://en.wikipedia.org/wiki/Carnauba%20wax
97 Among the hardest of natural waxes Practically insoluble in water or ethyl alcohol Soluble by heating in ethyl acetate or xylene References External links Botanical description - from the Mildred E. Mathias Botanical Garden Carnauba wax data sheet - from the UN Food and Agriculture Organization Carnauba Wax Background Paper - published report from field work Associacao Caatinga Good Practices Manual for the Carnauba supply chain Archived 2019-12-05 at the Wayback Machine - Associacao Caatinga/BMU-IKI/GIZ (2019) Initiative for Responsible Carnauba - IRC Private Business Action for Biodiversity - BMU-IKI/GIZ Union for Ethical BioTrade - UEBT
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492
Chicory
https://en.wikipedia.org/wiki/Chicory
Common chicory (Cichorium intybus) is a somewhat woody, perennial herbaceous plant of the family Asteraceae, usually with bright blue flowers, rarely white or pink. Native to the Old World, it has been introduced to the Americas and Australia. Many varieties are cultivated for salad leaves, chicons (blanched buds), or roots (var. sativum), which are baked, ground, and used as a coffee substitute and food additive. In the 21st century, inulin, an extract from chicory root, has been used in food manufacturing as a sweetener and source of dietary fiber. Chicory is also grown as a forage crop for livestock. Description When flowering, chicory has a tough, grooved, and more or less hairy stem. It can grow to 1.5 metres (5 feet) tall. The leaves are stalked, lanceolate and unlobed; they range from 7.5–32 centimetres (3–12+1⁄2 inches) in length (smallest near the top) and 2–8 cm (3⁄4–3+1⁄4 in) wide. The flower heads are 3–5 cm (1+1⁄4–2 in) wide, and usually light blue or lavender; it has also rarely been described as white or pink. Of the two rows of involucral bracts, the inner is longer and erect, the outer is shorter and spreading. It flowers from March until October.
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493
Chicory
https://en.wikipedia.org/wiki/Chicory
The seed has small scales at the tip. Chemistry Substances which contribute to the plant's bitterness are primarily the two sesquiterpene lactones, lactucin and lactucopicrin. Other components are aesculetin, aesculin, cichoriin, umbelliferone, scopoletin, 6,7-dihydrocoumarin, and further sesquiterpene lactones and their glycosides. Around 1970, it was discovered that the root contains up to 20% inulin, a polysaccharide similar to starch. Names Common chicory is also known as blue daisy, blue dandelion, blue sailors, blue weed, bunk, coffeeweed, cornflower, hendibeh, horseweed, ragged sailors, succory, wild bachelor's buttons, and wild endive. ("Cornflower" is also commonly applied to Centaurea cyanus.) Common names for varieties of var. foliosum include endive, radicchio, radichetta, Belgian endive, French endive, red endive, sugarloaf, and witloof (or witlof). Distribution and habitat Chicory is native to western Asia, North Africa, and Europe. It lives as a wild plant on roadsides in Europe. The plant was brought to North America by early European colonists. It is also common in China, and Australia, where it has become widely naturalized.
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494
Chicory
https://en.wikipedia.org/wiki/Chicory
It is more common in areas with abundant rain. Ecology Chicory is both a cultivated crop and a weedy plant with a cosmopolitan distribution. Analysis of introduced weedy populations in North America has revealed that naturalized weedy chicory is partially descended from domesticated cultivars. Chicory grows in roadsides, waste places, and other disturbed areas, and can survive in lawns due to its ability to resprout from its low basal rosette of leaves. It typically does not enter undisturbed natural areas. It most prefers limestone soils, but tolerates an array of conditions. Bees, butterflies, and flies feed upon it. Uses Culinary The entire plant is edible. Raw chicory leaves are 92% water, 5% carbohydrates, 2% protein, and contain negligible fat (table). In a 100-gram (3½ oz) reference amount, raw chicory leaves provide 23 calories (96 J) and significant amounts (more than 20% of the Daily Value) of vitamin K, vitamin A, vitamin C, some B vitamins, and manganese. Vitamin E and calcium are present in moderate amounts. Raw endive is 94% water and has low nutrient content. Root chicory Root chicory (Cichorium intybus var. sativum) has long been cultivated in Europe as a coffee substitute. The roots are baked, roasted, ground, and used as an additive, especially in the Mediterranean region (where the plant is native).
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Chicory
https://en.wikipedia.org/wiki/Chicory
As a coffee additive, it is also mixed in Indian filter coffee and in parts of Southeast Asia, South Africa, and the southern United States, particularly in New Orleans. In France, a mixture of 60% chicory and 40% coffee is sold under the trade name Ricoré. It has been more widely used during economic crises such as the Great Depression in the 1930s and during World War II in Continental Europe. Chicory, with sugar beet and rye, was used as an ingredient of the East German Mischkaffee (mixed coffee), introduced during the "East German coffee crisis" of 1976–1979. It is also added to coffee in Spanish, Greek, Turkish, Syrian, Lebanese and Palestinian cuisines. Some beer brewers use roasted chicory to add flavor to stouts (commonly expected to have a coffee-like flavor). Others have added it to strong blond Belgian-style ales, to augment the hops, making a witloofbier, from the Dutch name for the plant. The roots can also be cooked like parsnips. Leaf chicory Wild While edible raw, wild chicory leaves usually have a bitter taste, especially the older leaves. The flavor is appreciated in certain cuisines, such as in the Ligurian and Apulian regions of Italy and also in the southern part of India. In Ligurian cuisine, wild chicory leaves are an ingredient of preboggion and in the Apulian region, wild chicory leaves are combined with fava bean puree in the traditional local dish fave e cicorie selvatiche.
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496
Chicory
https://en.wikipedia.org/wiki/Chicory
In Albania, the leaves are used as a spinach substitute, mainly served simmered and marinated in olive oil, or as ingredient for fillings of byrek. In Greece a variety of wild chicory found in Crete and known as stamnagathi (spiny chicory) is used as a salad served with olive oil and lemon juice. By cooking and discarding the water, the bitterness is reduced, after which the chicory leaves may be sautéed with garlic, anchovies, and other ingredients. In this form, the resulting greens might be combined with pasta or accompany meat dishes. Cultivated Chicory may be cultivated for its leaves, usually eaten raw as salad leaves. Cultivated chicory is generally divided into three types, of which there are many varieties: Radicchio usually has variegated red or red and green leaves. Some only refer to the white-veined red-leaved type as radicchio, also known as red endive and red chicory. It has a bitter and spicy taste, which mellows when it is grilled or roasted. It can also be used to add color and zest to salads. It is largely used in Italy in different varieties, the most famous being the ones from Treviso (known as radicchio rosso di Treviso), from Verona (radicchio di Verona), and Chioggia (radicchio di Chioggia), which are classified as an IGP.
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497
Chicory
https://en.wikipedia.org/wiki/Chicory
It is also common in Greece, where it is known as radiki and mainly boiled in salads, and is used in pies. Belgian endive is known in Dutch as witloof or witlof ("white leaf"), indivia in Italy, endivias in Spain, chicory in the UK, as witlof in Australia, endive in France and Canada, and chicon in parts of northern France, in Wallonia and (in French) in Luxembourg. It has a small head of cream-colored, bitter leaves. The harvested root is allowed to sprout indoors in the absence of sunlight, which prevents the leaves from turning green and opening up (etiolation). It is often sold wrapped in blue paper to protect it from light, so as to preserve its pale color and delicate flavor. The smooth, creamy white leaves may be served stuffed, baked, boiled, cut, or cooked in a milk sauce, or simply cut raw. The tender leaves are slightly bitter; the whiter the leaf, the less bitter the taste. The harder inner part of the stem at the bottom of the head can be cut out before cooking to prevent bitterness. Belgium exports chicon/witloof to over 40 countries. The technique for growing these blanched endives was accidentally discovered in the 1850s at the Botanical Garden of Brussels in Saint-Josse-ten-Noode, Belgium. Today France is the largest producer of endive.
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498
Chicory
https://en.wikipedia.org/wiki/Chicory
Catalogna chicory (Cichorium intybus var. foliosum), also known as puntarelle, includes a whole subfamily (some varieties from Belgian endive and some from radicchio) of chicory and is used throughout Italy. Although leaf chicory is often called "endive", true endive (Cichorium endivia) is a different species in the same genus, distinct from Belgian endive. Chicory root and inulin Inulin is mainly found in the plant family Asteraceae as a storage carbohydrate (for example Jerusalem artichoke, dahlia, yacon, etc.). It is used as a sweetener in the food industry, with 10% of the sweetening power of sucrose and is sometimes added to yogurts as a 'prebiotic'. Fresh chicory root may contain 13–23% inulin as a percentage of its total carbohydrate content. Traditional use Chicory root contains essential oils similar to those found in plants in the related genus Tanacetum. In alternative medicine, chicory has been listed as one of the 38 plants used to prepare Bach flower remedies. Forage Chicory is highly digestible for ruminants and has a low fiber concentration. Chicory roots were once considered an "excellent substitute for oats" for horses due to their protein and fat content. Chicory contains a low quantity of reduced tannins that may increase protein utilization efficiency in ruminants.
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499
Chicory
https://en.wikipedia.org/wiki/Chicory
Some tannins reduce intestinal parasites. Dietary chicory may be toxic to internal parasites, with studies of ingesting chicory by farm animals having lower worm burdens, leading to its use as a forage supplement. Although chicory might have originated in France, Italy and India, much development of chicory for use with livestock has been undertaken in New Zealand. Forage varieties 'Puna' ('Grasslands Puna'): Developed in New Zealand, Grasslands Puna is well adapted to different climates, being grown from Alberta, Canada, New Mexico, Florida to Australia. It is resistant to bolting, which leads to high nutrient levels in the leaves in spring. It also is able to quickly come back after grazing. 'Forage Feast': A variety from France used for human consumption and also for wildlife plots, where animals such as deer might graze. It is resistant to bolting. It is very cold-hardy, and being lower in tannins than other forage varieties, is suitable for human consumption. 'Choice': has been bred for high winter and early-spring growth activity, and lower amounts of lactucin and lactone, which are believed to taint milk. It is also use for seeding deer wildlife plots. 'Oasis': was bred for increased lactone rates for the forage industry, and for higher resistance to fungal diseases such as Sclerotinia (mainly s. minor and S. sclerotiorum.
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