id
int64
0
283k
text
stringlengths
23
10.4k
100
We will look at this in more detail a little later.In everyday experience, light doesn't seem to have many special properties but it does: A huge spectrum: The light we can see (visible EM radiation) is only a small part of all of the EM radiation (electromagnetic spectrum) that exists
101
Nature's speed limit: Nothing moves faster than the speed of light
102
Wave nature: All EM radiation has the ability to behave like a wave which we call wave-like behaviour
103
Particle nature: All EM radiation has the ability to behave like a particle which we call particle-like behaviour
104
No medium required: EM radiation can propagate without a medium through which to move even though they are waves
105
We will discuss this in the following sections and in even more detail in Grades 11 and 12.
106
Diagrams of compounds are very useful because they help us to picture how the atoms are arranged in the compound and they help us to see the shape of the compound
107
There are three types of diagrams that are commonly used: Wireframe or stick models In this model, the bonds between atoms are shown as “sticks”
108
Ball and stick models This is a 3-dimensional molecular model that uses “balls” to represent atoms and “sticks” to represent the bonds between them
109
The centres of the atoms (the balls) are connected by straight lines which represent the bonds between them
110
Table 12.1 shows examples of the different types of models for all the types of compounds.Covalent molecularCovalent networkIonic networkMetallic networkName of compoundglucosegraphitesilver chloridezincFormula or Stick modelBall-and-stick modelSpace-filling model Table 12.1: Different representations for compounds CanvasMol (www.alteredqualia.com/canvasmol) is a website that allows you to view several compounds
111
You do not need to know these compounds, this is simply to allow you to see one way of representing compounds.
112
The synthesis (forming) of water () from hydrogen gas () and oxygen gas () is another example of chemical change
113
A simplified diagram of this reaction is shown in Figure 13.3
114
The chemical bonds between in and between in are broken and new bonds between and (to form ) are formed
115
A chemical change has taken place.Video: VPbhyA mixture of hydrogen and oxygen gas is used as a fuel to get rockets into space.There are some important things to remember about chemical changes: Arrangement of particles During a chemical change, the particles themselves are changed in some way
116
In the example of hydrogen peroxide that was used earlier, the molecules were split up into their component atoms
117
The number of particles will change because each molecule breaks down into two water molecules () and one oxygen molecule ()
118
Energy changes The energy changes that take place during a chemical reaction are much greater than those that take place during a physical change in matter
119
During a chemical reaction, energy is used up in order to break bonds and then energy is released when the new product is formed
120
Reversibility Chemical changes are far more difficult to reverse than physical changes
121
When hydrogen peroxide decomposes into water and oxygen, it is almost impossible to get back to hydrogen peroxide
122
Mass conservation Mass is conserved during a chemical change, but the number of molecules may change
123
In the example of the decomposition of hydrogen peroxide, for every two molecules of hydrogen peroxide that decomposes, three molecules are formed (two water and one oxygen)
124
Table 13.1 highlights these concepts for the decomposition of hydrogen peroxide.Moleculestwo moleculesthree moleculesEnergy changesenergy taken in when bonds are brokenenergy given off when bonds are formedMass is conservedAtoms are conserved oxygen atoms, hydrogen atoms oxygen atoms, hydrogen atoms Table 13.1: Important concepts in chemical change Exercise 13.1See solutions For each of the following say whether a chemical or a physical change occurs
125
Melting candle wax.Mixing sodium chloride () and silver nitrate () to form silver chloride ().Mixing hydrochloric acid () and magnesium ribbon () to form magnesium chloride ().Dissolving salt in water.Tearing a piece of magnesium ribbon
126
As we have already mentioned, a number of changes can occur when elements are combined with one another
127
One way of representing chemical changes is through balanced chemical equations
128
A chemical equation describes a chemical reaction by using symbols for the elements involved
129
For example, if we look at the reaction between iron and sulfur to form iron sulfide , we could represent these changes in a sentence, in a word equation or using chemical symbols: Sentence: Iron reacts with sulfur to form iron sulfide
130
A chemical formula shows each element by its symbol and also shows how many atoms of each element are found in that compound
131
The number of atoms (if greater than one) is shown as a subscript.The following exercise serves as revision
132
Magnetism is an interaction that allows certain kinds of objects, which are called 'magnetic' objects, to exert forces on each other without physically touching
133
A magnetic object is surrounded by a magnetic 'field' that gets weaker as one moves further away from the object
134
A second object can feel a magnetic force from the first object because it feels the magnetic field of the first object
135
The further away the objects are the weaker the magnetic force will be.Video: VPfkkHumans have known about magnetism for many thousands of years
136
For example, lodestone is a magnetised form of the iron oxide mineral magnetite
137
It is referred to in old European and Asian historical records; from around BCE in Europe and around BCE in Asia.Magnetic objects stuck to a magnetThe root of the English word magnet is from the Greek word magnes, probably from Magnesia in Asia Minor, once an important source of lodestone.
138
Electrostatics is the study of electric charge which is at rest or static (not moving)
139
In this chapter we will look at some of the basic principles of electrostatics as well as the principle of conservation of charge.Video: VPfmg
140
When you measure the potential difference across (or between) the terminals of a battery that is not in a complete circuit you are measuring the emf of the battery
141
This is the maximum amount of work per coulomb of charge the battery can do to drive charge from one terminal, through the circuit, to the other terminal.The volt is named after the Italian physicist Alessandro Volta (1745–1827).Electrical potential difference is also called voltage.When you measure the potential difference across (or between) the terminals of a battery that is in a complete circuit you are measuring the terminal potential difference of the battery
142
Although this is measured in volts it is not identical to the emf
143
The difference will be the work done to drive charge through the battery.BatteriesOne lead of the voltmeter is connected to one end of the battery and the other lead is connected to the opposite end
144
The voltmeter may also be used to measure the voltage across a resistor or any other component of a circuit but must be connected in parallel.
145
Many reactions in chemistry and all biological reactions (reactions in living systems) take place in water
146
In this chapter we will look at some of these reactions in detail
147
Almost all the reactions that occur in aqueous solutions involve ions
148
We will look at three main types of reactions that occur in aqueous solutions, namely precipitation reactions, acid-base reactions and redox reactions
149
Before we can learn about the types of reactions, we need to first look at ions in aqueous solutions and electrical conductivity.Video: VPbls
150
Sometimes it is important to know exactly how many particles (eg atoms or molecules) are in a sample of a substance, or what quantity of a substance is needed for a chemical reaction to take place.The amount of substance is so important in chemistry that it is given its own name, which is the mole.Mole The mole (abbreviation “mol”) is the SI (Standard International) unit for “amount of substance”
151
The mole is a counting unit just like hours or days
152
We can easily count one second or one minute or one hour
153
If we want bigger units of time, we refer to days, months and years
154
We call this number Avogadro's number.Avogadro's number The number of particles in a mole, equal to
155
If we had this number of cold drink cans, then we could cover the surface of the earth to a depth of over
156
If you could count atoms at a rate of 10 million per second, then it would take you 2 billion years to count the atoms in one mole!The original hypothesis that was proposed by Amadeo Avogadro was that “equal volumes of gases, at the same temperature and pressure, contain the same number of molecules”
157
His ideas were not accepted by the scientific community and it was only four years after his death, that his original hypothesis was accepted and that it became known as “Avogadro's Law”
158
In honour of his contribution to science, the number of particles in one mole was named Avogadro's number.We use Avogadro's number and the mole in chemistry to help us quantify what happens in chemical reaction
159
If we measure of carbon we have one mole or carbon atoms
160
You will remember that when the mass, in grams, of an element is equal to its relative atomic mass, the sample contains one mole of that element
161
This mass is called the molar mass of that element.You may sometimes see the molar mass written as
162
We will use in this book, but you should be aware of the alternate notation.It is worth remembering the following: On the periodic table, the relative atomic mass that is shown can be interpreted in two ways
163
The mass (in grams) of a single, average atom of that element relative to the mass of an atom of carbon
164
The average atomic mass of all the isotopes of that element
165
ElementRelative atomic mass (u)Molar mass ()Mass of one mole of the element (g)MagnesiumLithiumOxygenNitrogenIron Table 19.1: The relationship between relative atomic mass, molar mass and the mass of one mole for a number of elements
166
Calculate the number of moles of iron (Fe) in an sample
167
If we look at the periodic table, we see that the molar mass of iron is
168
This means that 1 mole of iron will have a mass of .If 1 mole of iron has a mass of , then: the number of moles of iron in must be:There are 2 moles of iron in the sample
169
You need to imagine that the horizontal line is like a division sign and that the vertical line is like a multiplication sign
170
So, for example, if you want to calculate , then the remaining two letters in the triangle are and and is above with a division sign between them
171
Your calculation will then be Remember that when you use the equation , the mass is always in grams (g) and molar mass is in grams per mol ()
172
Always write the units next to any number you use in a formula or sum
173
Calculate the number of moles of copper there are in a sample that with a mass of
174
Calculate the number of atoms there are in a sample of aluminium that with a mass of
175
However, you need to remember that all your calculations will apply to the whole compound
176
So, when you calculate the molar mass of a covalent compound, you will need to add the molar mass of each atom in that compound
177
The number of moles will also apply to the whole molecule
178
For example, if you have one mole of nitric acid () the molar mass is and there are molecules of nitric acid
179
This is the mass of all the atoms in one formula unit of the compound
180
For example, one mole of sodium chloride () has a formula mass of and there are molecules of sodium chloride in one formula unit.In a balanced chemical equation, the number that is written in front of the element or compound, shows the mole ratio in which the reactants combine to form a product
181
If there are no numbers in front of the element symbol, this means the number is '1'.Video: VPezceg In this reaction, 1 mole of nitrogen molecules reacts with 3 moles of hydrogen molecules to produce 2 moles of ammonia molecules
182
Scalars are physical quantities which have only a number value or a size (magnitude)
183
A scalar tells you how much of something there is.Scalar A scalar is a physical quantity that has only a magnitude (size)
184
For example, a person buys a tub of margarine which is labelled with a mass of
185
The mass of the tub of margarine is a scalar quantity
186
It only needs one number to describe it, in this case, .Vectors are different because they are physical quantities which have a size and a direction
187
A vector tells you how much of something there is and which direction it is in.Vector A vector is a physical quantity that has both a magnitude and a direction
188
For example, a car is travelling east along a freeway at
189
The car is moving at (this is the magnitude) and we know where it is going – east (this is the direction)
190
Your weight is proportional to your mass (magnitude) and is always in the direction towards the centre of the earth
191
This chapter is about how things move along a straight line or, more scientifically, how things move in one dimension
192
This is useful for learning how to describe the movement (motion) of cars along a straight road or of trains along straight railway tracks
193
There are three features of motion that we use to describe exactly how an object moves
194
They are:The jerk is the name we give to how fast the acceleration is changing.Traffic often moves along a straight line
195
The word energy comes from the Greek word energeia (ένέργεια), meaning activity or operation
196
Energy is closely linked to mass and cannot be created or destroyed
197
In this chapter we will consider gravitational potential and kinetic energy.Video: VPgjm
198
As far as we know, the Earth we live on is the only planet that is able to support life
199
Amongst other factors, the Earth is just the right distance from the sun to have temperatures that are suitable for life to exist