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Born in San Nicolás de los Arroyos, Buenos Aires Province, Franco started his career at Club Atlético Independiente, moving at the age of 20 to Spain with CP Mérida where he did not appear in La Liga, barred by Carlos Navarro Montoya and suffering team relegation. In the following year he joined RCD Mallorca, spending his first season with their reserves and again dropping down a tier, now in Segunda División.
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
1
Born in San Nicolás de los Arroyos, Buenos Aires Province, Franco started his career at Club Atlético Independiente, moving at the age of 20 to Spain with CP Mérida where he did not appear in La Liga, barred by Carlos Navarro Montoya and suffering team relegation. In the following year he joined RCD Mallorca, spending his first season with their reserves and again dropping down a tier, now in Segunda División.
With the Argentina under-20 team, Franco won the 1997 FIFA World Youth Championship in Malaysia. On 6 May 2006, two years after making his debut for the senior side, he was selected by coach José Pekerman – also the manager of the under-20s – to the squad for the 2006 FIFA World Cup.
0
Born in San Nicolás de los Arroyos, Buenos Aires Province, Franco started his career at Club Atlético Independiente, moving at the age of 20 to Spain with CP Mérida where he did not appear in La Liga, barred by Carlos Navarro Montoya and suffering team relegation. In the following year he joined RCD Mallorca, spending his first season with their reserves and again dropping down a tier, now in Segunda División.
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
1
Born in San Nicolás de los Arroyos, Buenos Aires Province, Franco started his career at Club Atlético Independiente, moving at the age of 20 to Spain with CP Mérida where he did not appear in La Liga, barred by Carlos Navarro Montoya and suffering team relegation. In the following year he joined RCD Mallorca, spending his first season with their reserves and again dropping down a tier, now in Segunda División.
With the Argentina under-20 team, Franco won the 1997 FIFA World Youth Championship in Malaysia. On 6 May 2006, two years after making his debut for the senior side, he was selected by coach José Pekerman – also the manager of the under-20s – to the squad for the 2006 FIFA World Cup.
0
Franco would be however promoted to the Balearic Islands club's first team, going on to establish himself as the starter after replacing compatriot Carlos Roa in the pecking order. In the 2000–01 campaign he appeared in 27 matches as Mallorca finished in a best-ever third position, and helped win the Copa del Rey two years after.
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
1
Franco would be however promoted to the Balearic Islands club's first team, going on to establish himself as the starter after replacing compatriot Carlos Roa in the pecking order. In the 2000–01 campaign he appeared in 27 matches as Mallorca finished in a best-ever third position, and helped win the Copa del Rey two years after.
With the Argentina under-20 team, Franco won the 1997 FIFA World Youth Championship in Malaysia. On 6 May 2006, two years after making his debut for the senior side, he was selected by coach José Pekerman – also the manager of the under-20s – to the squad for the 2006 FIFA World Cup.
0
Franco would be however promoted to the Balearic Islands club's first team, going on to establish himself as the starter after replacing compatriot Carlos Roa in the pecking order. In the 2000–01 campaign he appeared in 27 matches as Mallorca finished in a best-ever third position, and helped win the Copa del Rey two years after.
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
1
Franco would be however promoted to the Balearic Islands club's first team, going on to establish himself as the starter after replacing compatriot Carlos Roa in the pecking order. In the 2000–01 campaign he appeared in 27 matches as Mallorca finished in a best-ever third position, and helped win the Copa del Rey two years after.
With the Argentina under-20 team, Franco won the 1997 FIFA World Youth Championship in Malaysia. On 6 May 2006, two years after making his debut for the senior side, he was selected by coach José Pekerman – also the manager of the under-20s – to the squad for the 2006 FIFA World Cup.
0
Franco would be however promoted to the Balearic Islands club's first team, going on to establish himself as the starter after replacing compatriot Carlos Roa in the pecking order. In the 2000–01 campaign he appeared in 27 matches as Mallorca finished in a best-ever third position, and helped win the Copa del Rey two years after.
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
1
Franco would be however promoted to the Balearic Islands club's first team, going on to establish himself as the starter after replacing compatriot Carlos Roa in the pecking order. In the 2000–01 campaign he appeared in 27 matches as Mallorca finished in a best-ever third position, and helped win the Copa del Rey two years after.
After starting out at Independiente in 1995, he went on to spend the vast majority of his career in Spain, playing 328 La Liga matches over 14 seasons in representation of Mallorca, Atlético Madrid and Zaragoza.
0
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
1
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
Leonardo "Leo" Neoren Franco (born 20 May 1977) is an Argentine former professional footballer who played as a goalkeeper, and is a manager.
0
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
1
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
After starting out at Independiente in 1995, he went on to spend the vast majority of his career in Spain, playing 328 La Liga matches over 14 seasons in representation of Mallorca, Atlético Madrid and Zaragoza.
0
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
Franco would be however promoted to the Balearic Islands club's first team, going on to establish himself as the starter after replacing compatriot Carlos Roa in the pecking order. In the 2000–01 campaign he appeared in 27 matches as Mallorca finished in a best-ever third position, and helped win the Copa del Rey two years after.
1
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
On 30 June 2006, Franco replaced the injured Roberto Abbondanzieri in the quarter-final clash against hosts Germany, failing to save one single penalty shootout attempt.
0
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
1
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
Leo Franco:5035268
0
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
1
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
On 30 June 2006, Franco replaced the injured Roberto Abbondanzieri in the quarter-final clash against hosts Germany, failing to save one single penalty shootout attempt.
0
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
1
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
On 30 June 2006, Franco replaced the injured Roberto Abbondanzieri in the quarter-final clash against hosts Germany, failing to save one single penalty shootout attempt.
0
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
Born in San Nicolás de los Arroyos, Buenos Aires Province, Franco started his career at Club Atlético Independiente, moving at the age of 20 to Spain with CP Mérida where he did not appear in La Liga, barred by Carlos Navarro Montoya and suffering team relegation. In the following year he joined RCD Mallorca, spending his first season with their reserves and again dropping down a tier, now in Segunda División.
1
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
Leo Franco:5035268
0
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
1
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
Leo Franco:5035268
0
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
1
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
With the Argentina under-20 team, Franco won the 1997 FIFA World Youth Championship in Malaysia. On 6 May 2006, two years after making his debut for the senior side, he was selected by coach José Pekerman – also the manager of the under-20s – to the squad for the 2006 FIFA World Cup.
0
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
On 1 July 2009, aged 32, after not seeing his contract renewed, Franco left the Vicente Calderón Stadium – as Coupet– and signed with Galatasaray S.K. from Turkey. His first Süper Lig appearance took place on 9 August, in a 3–2 away victory over Gaziantepspor.
1
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
After starting out at Independiente in 1995, he went on to spend the vast majority of his career in Spain, playing 328 La Liga matches over 14 seasons in representation of Mallorca, Atlético Madrid and Zaragoza.
0
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
1
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
With the Argentina under-20 team, Franco won the 1997 FIFA World Youth Championship in Malaysia. On 6 May 2006, two years after making his debut for the senior side, he was selected by coach José Pekerman – also the manager of the under-20s – to the squad for the 2006 FIFA World Cup.
0
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
1
Franco left Aragon in the summer of 2014, and subsequently moved to San Lorenzo de Almagro. On 24 July 2015, after appearing rarely, he moved to SD Huesca, newly promoted to the Spanish second tier.
An Argentine international for two years, Franco appeared for the nation at the 2006 World Cup.
0
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
Franco was signed by Atlético Madrid in June 2004, being first choice from the beginning. Until the end of 2007–08 he saved seven penalties, including two against Sevilla FC on 23 March 2006 (0–1 home loss) and two more at Real Betis on 2 December (1–0 win). Precisely during that season, he was challenged by newly signed Christian Abbiati (loaned by A.C. Milan), but regained his starting status in 2008–09, relegating veteran Grégory Coupet to the bench.
1
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
After starting out at Independiente in 1995, he went on to spend the vast majority of his career in Spain, playing 328 La Liga matches over 14 seasons in representation of Mallorca, Atlético Madrid and Zaragoza.
0
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
Franco returned to Spain after only one year, joining Real Zaragoza on a two-year deal. He made his competitive debut on 29 August 2010, in a 0–0 draw at Deportivo de La Coruña.
1
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
Leonardo "Leo" Neoren Franco (born 20 May 1977) is an Argentine former professional footballer who played as a goalkeeper, and is a manager.
0
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
Born in San Nicolás de los Arroyos, Buenos Aires Province, Franco started his career at Club Atlético Independiente, moving at the age of 20 to Spain with CP Mérida where he did not appear in La Liga, barred by Carlos Navarro Montoya and suffering team relegation. In the following year he joined RCD Mallorca, spending his first season with their reserves and again dropping down a tier, now in Segunda División.
1
On 19 August 2016, Franco announced his retirement at the age of 39 and was immediately named director of external relations at his last club. On 29 May 2018, he replaced the departing Rubi as first-team manager in view of their first-ever season in the top flight, being dismissed on 9 October due to poor results.
With the Argentina under-20 team, Franco won the 1997 FIFA World Youth Championship in Malaysia. On 6 May 2006, two years after making his debut for the senior side, he was selected by coach José Pekerman – also the manager of the under-20s – to the squad for the 2006 FIFA World Cup.
0
Lignin is highly heterogeneous polymer derived from a handful of precursor lignols that crosslink in diverse ways. The lignols that crosslink are of three main types, all derived from phenylpropane: coniferyl alcohol (4-hydroxy-3-methoxyphenylpropane) (its radical is sometimes called guaiacyl), sinapyl alcohol (3,5-dimethoxy-4-hydroxyphenylpropane) (its radical is sometimes called syringyl), and paracoumaryl alcohol (4-hydroxyphenylpropane) (its radical is sometimes called 4-hydroxyphenyl).
Lignin's molecular masses exceed 10,000 u. It is hydrophobic as it is rich in aromatic subunits. The degree of polymerisation is difficult to measure, since the material is heterogeneous. Different types of lignin have been described depending on the means of isolation.
1
Lignin is highly heterogeneous polymer derived from a handful of precursor lignols that crosslink in diverse ways. The lignols that crosslink are of three main types, all derived from phenylpropane: coniferyl alcohol (4-hydroxy-3-methoxyphenylpropane) (its radical is sometimes called guaiacyl), sinapyl alcohol (3,5-dimethoxy-4-hydroxyphenylpropane) (its radical is sometimes called syringyl), and paracoumaryl alcohol (4-hydroxyphenylpropane) (its radical is sometimes called 4-hydroxyphenyl).
It is covalently linked to hemicellulose and therefore cross-links different plant polysaccharides, conferring mechanical strength to the cell wall and by extension the plant as a whole. Its most commonly noted function is the support through strengthening of wood (mainly composed of xylem cells and lignified sclerenchyma fibres) in vascular plants.
0
The relative amounts of the precursor "monomers" vary according to the plant source. Broadly speaking:
Lignin's molecular masses exceed 10,000 u. It is hydrophobic as it is rich in aromatic subunits. The degree of polymerisation is difficult to measure, since the material is heterogeneous. Different types of lignin have been described depending on the means of isolation.
1
The relative amounts of the precursor "monomers" vary according to the plant source. Broadly speaking:
Thermochemolysis (chemical break down of a substance under vacuum and at high temperature) with tetramethylammonium hydroxide (TMAH) or cupric oxide has also been used to characterize lignins. The ratio of syringyl lignol (S) to vanillyl lignol (V) and cinnamyl lignol (C) to vanillyl lignol (V) is variable based on plant type and can therefore be used to trace plant sources in aquatic systems (woody vs. non-woody and angiosperm vs. gymnosperm). Ratios of carboxylic acid (Ad) to aldehyde (Al) forms of the lignols (Ad/Al) reveal diagenetic information, with higher ratios indicating a more highly degraded material. Increases in the (Ad/Al) value indicate an oxidative cleavage reaction has occurred on the alkyl lignin side chain which has been shown to be a step in the decay of wood by many white-rot and some soft rot fungi.
0
Lignin's molecular masses exceed 10,000 u. It is hydrophobic as it is rich in aromatic subunits. The degree of polymerisation is difficult to measure, since the material is heterogeneous. Different types of lignin have been described depending on the means of isolation.
The relative amounts of the precursor "monomers" vary according to the plant source. Broadly speaking:
1
Lignin's molecular masses exceed 10,000 u. It is hydrophobic as it is rich in aromatic subunits. The degree of polymerisation is difficult to measure, since the material is heterogeneous. Different types of lignin have been described depending on the means of isolation.
The conventional method for lignin quantitation in the pulp industry is the Klason lignin and acid-soluble lignin test, which is standardized procedures. The cellulose is digested thermally in the presence of acid. The residue is termed Klason lignin. Acid-soluble lignin (ASL) is quantified by the intensity of its Ultraviolet spectroscopy. The carbohydrate composition may be also analyzed from the Klason liquors, although there may be sugar breakdown products (furfural and 5-hydroxymethylfurfural). or NREL
0
Many grasses have mostly G, while some palms have mainly S. All lignins contain small amounts of incomplete or modified monolignols, and other monomers are prominent in non-woody plants.
Lignin is highly heterogeneous polymer derived from a handful of precursor lignols that crosslink in diverse ways. The lignols that crosslink are of three main types, all derived from phenylpropane: coniferyl alcohol (4-hydroxy-3-methoxyphenylpropane) (its radical is sometimes called guaiacyl), sinapyl alcohol (3,5-dimethoxy-4-hydroxyphenylpropane) (its radical is sometimes called syringyl), and paracoumaryl alcohol (4-hydroxyphenylpropane) (its radical is sometimes called 4-hydroxyphenyl).
1
Many grasses have mostly G, while some palms have mainly S. All lignins contain small amounts of incomplete or modified monolignols, and other monomers are prominent in non-woody plants.
The polymerisation step, that is a radical-radical coupling, is catalysed by oxidative enzymes. Both peroxidase and laccase enzymes are present in the plant cell walls, and it is not known whether one or both of these groups participates in the polymerisation. Low molecular weight oxidants might also be involved. The oxidative enzyme catalyses the formation of monolignol radicals. These radicals are often said to undergo uncatalyzed coupling to form the lignin polymer. An alternative theory invokes an unspecified biological control.
0
Lignin fills the spaces in the cell wall between cellulose, hemicellulose, and pectin components, especially in vascular and support tissues: xylem tracheids, vessel elements and sclereid cells.
Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall. Thus, lignin makes it possible for the plant's vascular tissue to conduct water efficiently. Lignin is present in all vascular plants, but not in bryophytes, supporting the idea that the original function of lignin was restricted to water transport.
1
Lignin fills the spaces in the cell wall between cellulose, hemicellulose, and pectin components, especially in vascular and support tissues: xylem tracheids, vessel elements and sclereid cells.
Lignin is present in red algae, which suggest that the common ancestor of plants and red algae also synthesised lignin. This finding also suggests that the original function of lignin was structural as it plays this role in the red alga "Calliarthron", where it supports joints between calcified segments.
0
Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall. Thus, lignin makes it possible for the plant's vascular tissue to conduct water efficiently. Lignin is present in all vascular plants, but not in bryophytes, supporting the idea that the original function of lignin was restricted to water transport.
Lignin fills the spaces in the cell wall between cellulose, hemicellulose, and pectin components, especially in vascular and support tissues: xylem tracheids, vessel elements and sclereid cells.
1
Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall. Thus, lignin makes it possible for the plant's vascular tissue to conduct water efficiently. Lignin is present in all vascular plants, but not in bryophytes, supporting the idea that the original function of lignin was restricted to water transport.
Well-studied ligninolytic enzymes are found in "Phanerochaete chrysosporium" and other white rot fungi. Some white rot fungi, such as "C. subvermispora", can degrade the lignin in lignocellulose, but others lack this ability. Most fungal lignin degradation involves secreted peroxidases. Many fungal laccases are also secreted, which facilitate degradation of phenolic lignin-derived compounds, although several intracellular fungal laccases have also been described. An important aspect of fungal lignin degradation is the activity of accessory enzymes to produce the H2O2 required for the function of lignin peroxidase and other heme peroxidases.
0
It is covalently linked to hemicellulose and therefore cross-links different plant polysaccharides, conferring mechanical strength to the cell wall and by extension the plant as a whole. Its most commonly noted function is the support through strengthening of wood (mainly composed of xylem cells and lignified sclerenchyma fibres) in vascular plants.
Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall. Thus, lignin makes it possible for the plant's vascular tissue to conduct water efficiently. Lignin is present in all vascular plants, but not in bryophytes, supporting the idea that the original function of lignin was restricted to water transport.
1
It is covalently linked to hemicellulose and therefore cross-links different plant polysaccharides, conferring mechanical strength to the cell wall and by extension the plant as a whole. Its most commonly noted function is the support through strengthening of wood (mainly composed of xylem cells and lignified sclerenchyma fibres) in vascular plants.
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
0
Finally, in terms of its other functions, lignin confers disease resistance.
Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall. Thus, lignin makes it possible for the plant's vascular tissue to conduct water efficiently. Lignin is present in all vascular plants, but not in bryophytes, supporting the idea that the original function of lignin was restricted to water transport.
1
Finally, in terms of its other functions, lignin confers disease resistance.
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily. Chemically, lignins are polymers made by cross-linking phenolic precursors.
0
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
Given that it is the most prevalent biopolymer after cellulose, lignin has been investigated as a feedstock for biofuel production and can become a crucial plant extract in the development of a new class of biofuels.
1
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
The polymerisation step, that is a radical-radical coupling, is catalysed by oxidative enzymes. Both peroxidase and laccase enzymes are present in the plant cell walls, and it is not known whether one or both of these groups participates in the polymerisation. Low molecular weight oxidants might also be involved. The oxidative enzyme catalyses the formation of monolignol radicals. These radicals are often said to undergo uncatalyzed coupling to form the lignin polymer. An alternative theory invokes an unspecified biological control.
0
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
Mechanical, or high-yield pulp, which is used to make newsprint, still contains most of the lignin originally present in the wood. This lignin is responsible for newsprint's yellowing with age. High quality paper requires the removal of lignin from the pulp. These delignification processes are core technologies of the papermaking industry as well as the source of significant environmental concerns.
1
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall. Thus, lignin makes it possible for the plant's vascular tissue to conduct water efficiently. Lignin is present in all vascular plants, but not in bryophytes, supporting the idea that the original function of lignin was restricted to water transport.
0
Mechanical, or high-yield pulp, which is used to make newsprint, still contains most of the lignin originally present in the wood. This lignin is responsible for newsprint's yellowing with age. High quality paper requires the removal of lignin from the pulp. These delignification processes are core technologies of the papermaking industry as well as the source of significant environmental concerns.
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
1
Mechanical, or high-yield pulp, which is used to make newsprint, still contains most of the lignin originally present in the wood. This lignin is responsible for newsprint's yellowing with age. High quality paper requires the removal of lignin from the pulp. These delignification processes are core technologies of the papermaking industry as well as the source of significant environmental concerns.
Lignin is present in red algae, which suggest that the common ancestor of plants and red algae also synthesised lignin. This finding also suggests that the original function of lignin was structural as it plays this role in the red alga "Calliarthron", where it supports joints between calcified segments.
0
Mechanical, or high-yield pulp, which is used to make newsprint, still contains most of the lignin originally present in the wood. This lignin is responsible for newsprint's yellowing with age. High quality paper requires the removal of lignin from the pulp. These delignification processes are core technologies of the papermaking industry as well as the source of significant environmental concerns.
Lignin removed by the kraft process is usually burned for its fuel value, providing energy to power the mill. Two commercial processes exist to remove lignin from black liquor for higher value uses: LignoBoost (Sweden) and LignoForce (Canada). Higher quality lignin presents the potential to become a renewable source of aromatic compounds for the chemical industry, with an addressable market of more than $130bn.
1
Mechanical, or high-yield pulp, which is used to make newsprint, still contains most of the lignin originally present in the wood. This lignin is responsible for newsprint's yellowing with age. High quality paper requires the removal of lignin from the pulp. These delignification processes are core technologies of the papermaking industry as well as the source of significant environmental concerns.
The polymerisation step, that is a radical-radical coupling, is catalysed by oxidative enzymes. Both peroxidase and laccase enzymes are present in the plant cell walls, and it is not known whether one or both of these groups participates in the polymerisation. Low molecular weight oxidants might also be involved. The oxidative enzyme catalyses the formation of monolignol radicals. These radicals are often said to undergo uncatalyzed coupling to form the lignin polymer. An alternative theory invokes an unspecified biological control.
0
In sulfite pulping, lignin is removed from wood pulp as lignosulfonates, for which many applications have been proposed. They are used as dispersants, humectants, emulsion stabilizers, and sequestrants (water treatment). Lignosulfonate was also the first family of water reducers or superplasticizers to be added in the 1930s as admixture to fresh concrete in order to decrease the water-to-cement ("w/c") ratio, the main parameter controlling the concrete porosity, and thus its mechanical strength, its diffusivity and its hydraulic conductivity, all parameters essential for its durability. It has application in environmentally sustainable dust suppression agent for roads. Also, can be used in making of biodegradable plastic along with cellulose as an alternative to hydrocarbon made plastics if lignin extraction is achieved through a more environmentally viable process than generic plastic manufacturing.
Lignin removed by the kraft process is usually burned for its fuel value, providing energy to power the mill. Two commercial processes exist to remove lignin from black liquor for higher value uses: LignoBoost (Sweden) and LignoForce (Canada). Higher quality lignin presents the potential to become a renewable source of aromatic compounds for the chemical industry, with an addressable market of more than $130bn.
1
In sulfite pulping, lignin is removed from wood pulp as lignosulfonates, for which many applications have been proposed. They are used as dispersants, humectants, emulsion stabilizers, and sequestrants (water treatment). Lignosulfonate was also the first family of water reducers or superplasticizers to be added in the 1930s as admixture to fresh concrete in order to decrease the water-to-cement ("w/c") ratio, the main parameter controlling the concrete porosity, and thus its mechanical strength, its diffusivity and its hydraulic conductivity, all parameters essential for its durability. It has application in environmentally sustainable dust suppression agent for roads. Also, can be used in making of biodegradable plastic along with cellulose as an alternative to hydrocarbon made plastics if lignin extraction is achieved through a more environmentally viable process than generic plastic manufacturing.
Lignin is present in red algae, which suggest that the common ancestor of plants and red algae also synthesised lignin. This finding also suggests that the original function of lignin was structural as it plays this role in the red alga "Calliarthron", where it supports joints between calcified segments.
0
In sulfite pulping, lignin is removed from wood pulp as lignosulfonates, for which many applications have been proposed. They are used as dispersants, humectants, emulsion stabilizers, and sequestrants (water treatment). Lignosulfonate was also the first family of water reducers or superplasticizers to be added in the 1930s as admixture to fresh concrete in order to decrease the water-to-cement ("w/c") ratio, the main parameter controlling the concrete porosity, and thus its mechanical strength, its diffusivity and its hydraulic conductivity, all parameters essential for its durability. It has application in environmentally sustainable dust suppression agent for roads. Also, can be used in making of biodegradable plastic along with cellulose as an alternative to hydrocarbon made plastics if lignin extraction is achieved through a more environmentally viable process than generic plastic manufacturing.
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
1
In sulfite pulping, lignin is removed from wood pulp as lignosulfonates, for which many applications have been proposed. They are used as dispersants, humectants, emulsion stabilizers, and sequestrants (water treatment). Lignosulfonate was also the first family of water reducers or superplasticizers to be added in the 1930s as admixture to fresh concrete in order to decrease the water-to-cement ("w/c") ratio, the main parameter controlling the concrete porosity, and thus its mechanical strength, its diffusivity and its hydraulic conductivity, all parameters essential for its durability. It has application in environmentally sustainable dust suppression agent for roads. Also, can be used in making of biodegradable plastic along with cellulose as an alternative to hydrocarbon made plastics if lignin extraction is achieved through a more environmentally viable process than generic plastic manufacturing.
Lignin plays a crucial part in conducting water and aqueous nutrients in plant stems. The polysaccharide components of plant cell walls are highly hydrophilic and thus permeable to water, whereas lignin is more hydrophobic. The crosslinking of polysaccharides by lignin is an obstacle for water absorption to the cell wall. Thus, lignin makes it possible for the plant's vascular tissue to conduct water efficiently. Lignin is present in all vascular plants, but not in bryophytes, supporting the idea that the original function of lignin was restricted to water transport.
0
Lignin removed by the kraft process is usually burned for its fuel value, providing energy to power the mill. Two commercial processes exist to remove lignin from black liquor for higher value uses: LignoBoost (Sweden) and LignoForce (Canada). Higher quality lignin presents the potential to become a renewable source of aromatic compounds for the chemical industry, with an addressable market of more than $130bn.
In sulfite pulping, lignin is removed from wood pulp as lignosulfonates, for which many applications have been proposed. They are used as dispersants, humectants, emulsion stabilizers, and sequestrants (water treatment). Lignosulfonate was also the first family of water reducers or superplasticizers to be added in the 1930s as admixture to fresh concrete in order to decrease the water-to-cement ("w/c") ratio, the main parameter controlling the concrete porosity, and thus its mechanical strength, its diffusivity and its hydraulic conductivity, all parameters essential for its durability. It has application in environmentally sustainable dust suppression agent for roads. Also, can be used in making of biodegradable plastic along with cellulose as an alternative to hydrocarbon made plastics if lignin extraction is achieved through a more environmentally viable process than generic plastic manufacturing.
1
Lignin removed by the kraft process is usually burned for its fuel value, providing energy to power the mill. Two commercial processes exist to remove lignin from black liquor for higher value uses: LignoBoost (Sweden) and LignoForce (Canada). Higher quality lignin presents the potential to become a renewable source of aromatic compounds for the chemical industry, with an addressable market of more than $130bn.
Lignin biosynthesis begins in the cytosol with the synthesis of glycosylated monolignols from the amino acid phenylalanine. These first reactions are shared with the phenylpropanoid pathway. The attached glucose renders them water-soluble and less toxic. Once transported through the cell membrane to the apoplast, the glucose is removed, and the polymerisation commences. Much about its anabolism is not understood even after more than a century of study.
0
Lignin removed by the kraft process is usually burned for its fuel value, providing energy to power the mill. Two commercial processes exist to remove lignin from black liquor for higher value uses: LignoBoost (Sweden) and LignoForce (Canada). Higher quality lignin presents the potential to become a renewable source of aromatic compounds for the chemical industry, with an addressable market of more than $130bn.
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
1
Lignin removed by the kraft process is usually burned for its fuel value, providing energy to power the mill. Two commercial processes exist to remove lignin from black liquor for higher value uses: LignoBoost (Sweden) and LignoForce (Canada). Higher quality lignin presents the potential to become a renewable source of aromatic compounds for the chemical industry, with an addressable market of more than $130bn.
Finally, in terms of its other functions, lignin confers disease resistance.
0
Given that it is the most prevalent biopolymer after cellulose, lignin has been investigated as a feedstock for biofuel production and can become a crucial plant extract in the development of a new class of biofuels.
In sulfite pulping, lignin is removed from wood pulp as lignosulfonates, for which many applications have been proposed. They are used as dispersants, humectants, emulsion stabilizers, and sequestrants (water treatment). Lignosulfonate was also the first family of water reducers or superplasticizers to be added in the 1930s as admixture to fresh concrete in order to decrease the water-to-cement ("w/c") ratio, the main parameter controlling the concrete porosity, and thus its mechanical strength, its diffusivity and its hydraulic conductivity, all parameters essential for its durability. It has application in environmentally sustainable dust suppression agent for roads. Also, can be used in making of biodegradable plastic along with cellulose as an alternative to hydrocarbon made plastics if lignin extraction is achieved through a more environmentally viable process than generic plastic manufacturing.
1
Given that it is the most prevalent biopolymer after cellulose, lignin has been investigated as a feedstock for biofuel production and can become a crucial plant extract in the development of a new class of biofuels.
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily. Chemically, lignins are polymers made by cross-linking phenolic precursors.
0
Given that it is the most prevalent biopolymer after cellulose, lignin has been investigated as a feedstock for biofuel production and can become a crucial plant extract in the development of a new class of biofuels.
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
1
Given that it is the most prevalent biopolymer after cellulose, lignin has been investigated as a feedstock for biofuel production and can become a crucial plant extract in the development of a new class of biofuels.
Well-studied ligninolytic enzymes are found in "Phanerochaete chrysosporium" and other white rot fungi. Some white rot fungi, such as "C. subvermispora", can degrade the lignin in lignocellulose, but others lack this ability. Most fungal lignin degradation involves secreted peroxidases. Many fungal laccases are also secreted, which facilitate degradation of phenolic lignin-derived compounds, although several intracellular fungal laccases have also been described. An important aspect of fungal lignin degradation is the activity of accessory enzymes to produce the H2O2 required for the function of lignin peroxidase and other heme peroxidases.
0
The conventional method for lignin quantitation in the pulp industry is the Klason lignin and acid-soluble lignin test, which is standardized procedures. The cellulose is digested thermally in the presence of acid. The residue is termed Klason lignin. Acid-soluble lignin (ASL) is quantified by the intensity of its Ultraviolet spectroscopy. The carbohydrate composition may be also analyzed from the Klason liquors, although there may be sugar breakdown products (furfural and 5-hydroxymethylfurfural). or NREL
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
1
The conventional method for lignin quantitation in the pulp industry is the Klason lignin and acid-soluble lignin test, which is standardized procedures. The cellulose is digested thermally in the presence of acid. The residue is termed Klason lignin. Acid-soluble lignin (ASL) is quantified by the intensity of its Ultraviolet spectroscopy. The carbohydrate composition may be also analyzed from the Klason liquors, although there may be sugar breakdown products (furfural and 5-hydroxymethylfurfural). or NREL
The polymerisation step, that is a radical-radical coupling, is catalysed by oxidative enzymes. Both peroxidase and laccase enzymes are present in the plant cell walls, and it is not known whether one or both of these groups participates in the polymerisation. Low molecular weight oxidants might also be involved. The oxidative enzyme catalyses the formation of monolignol radicals. These radicals are often said to undergo uncatalyzed coupling to form the lignin polymer. An alternative theory invokes an unspecified biological control.
0
The conventional method for lignin quantitation in the pulp industry is the Klason lignin and acid-soluble lignin test, which is standardized procedures. The cellulose is digested thermally in the presence of acid. The residue is termed Klason lignin. Acid-soluble lignin (ASL) is quantified by the intensity of its Ultraviolet spectroscopy. The carbohydrate composition may be also analyzed from the Klason liquors, although there may be sugar breakdown products (furfural and 5-hydroxymethylfurfural). or NREL
Thermochemolysis (chemical break down of a substance under vacuum and at high temperature) with tetramethylammonium hydroxide (TMAH) or cupric oxide has also been used to characterize lignins. The ratio of syringyl lignol (S) to vanillyl lignol (V) and cinnamyl lignol (C) to vanillyl lignol (V) is variable based on plant type and can therefore be used to trace plant sources in aquatic systems (woody vs. non-woody and angiosperm vs. gymnosperm). Ratios of carboxylic acid (Ad) to aldehyde (Al) forms of the lignols (Ad/Al) reveal diagenetic information, with higher ratios indicating a more highly degraded material. Increases in the (Ad/Al) value indicate an oxidative cleavage reaction has occurred on the alkyl lignin side chain which has been shown to be a step in the decay of wood by many white-rot and some soft rot fungi.
1
The conventional method for lignin quantitation in the pulp industry is the Klason lignin and acid-soluble lignin test, which is standardized procedures. The cellulose is digested thermally in the presence of acid. The residue is termed Klason lignin. Acid-soluble lignin (ASL) is quantified by the intensity of its Ultraviolet spectroscopy. The carbohydrate composition may be also analyzed from the Klason liquors, although there may be sugar breakdown products (furfural and 5-hydroxymethylfurfural). or NREL
Bacterial degradation of lignin is particularly relevant in aquatic systems such as lakes, rivers, and streams, where inputs of terrestrial material (e.g. leaf litter) can enter waterways and leach dissolved organic carbon rich in lignin, cellulose, and hemicellulose. In the environment, lignin can be degraded either biotically via bacteria or abiotically via photochemical alteration, and oftentimes the latter assists in the former. In addition to the presence or absence of light, several of environmental factors affect the biodegradability of lignin, including bacterial community composition, mineral associations, and redox state.
0
A solution of hydrochloric acid and phloroglucinol is used for the detection of lignin (Wiesner test). A brilliant red color develops, owing to the presence of coniferaldehyde groups in the lignin.
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
1
A solution of hydrochloric acid and phloroglucinol is used for the detection of lignin (Wiesner test). A brilliant red color develops, owing to the presence of coniferaldehyde groups in the lignin.
Finally, in terms of its other functions, lignin confers disease resistance.
0
A solution of hydrochloric acid and phloroglucinol is used for the detection of lignin (Wiesner test). A brilliant red color develops, owing to the presence of coniferaldehyde groups in the lignin.
The conventional method for lignin quantitation in the pulp industry is the Klason lignin and acid-soluble lignin test, which is standardized procedures. The cellulose is digested thermally in the presence of acid. The residue is termed Klason lignin. Acid-soluble lignin (ASL) is quantified by the intensity of its Ultraviolet spectroscopy. The carbohydrate composition may be also analyzed from the Klason liquors, although there may be sugar breakdown products (furfural and 5-hydroxymethylfurfural). or NREL
1
A solution of hydrochloric acid and phloroglucinol is used for the detection of lignin (Wiesner test). A brilliant red color develops, owing to the presence of coniferaldehyde groups in the lignin.
Mechanical, or high-yield pulp, which is used to make newsprint, still contains most of the lignin originally present in the wood. This lignin is responsible for newsprint's yellowing with age. High quality paper requires the removal of lignin from the pulp. These delignification processes are core technologies of the papermaking industry as well as the source of significant environmental concerns.
0
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
Lignin and its models have been well examined by 1H and 13C NMR spectroscopy. Owing to the structural complexity of lignins, the spectra are poorly resolved and quantitation is challenging.
1
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
Lignin biosynthesis begins in the cytosol with the synthesis of glycosylated monolignols from the amino acid phenylalanine. These first reactions are shared with the phenylpropanoid pathway. The attached glucose renders them water-soluble and less toxic. Once transported through the cell membrane to the apoplast, the glucose is removed, and the polymerisation commences. Much about its anabolism is not understood even after more than a century of study.
0
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
Thermochemolysis (chemical break down of a substance under vacuum and at high temperature) with tetramethylammonium hydroxide (TMAH) or cupric oxide has also been used to characterize lignins. The ratio of syringyl lignol (S) to vanillyl lignol (V) and cinnamyl lignol (C) to vanillyl lignol (V) is variable based on plant type and can therefore be used to trace plant sources in aquatic systems (woody vs. non-woody and angiosperm vs. gymnosperm). Ratios of carboxylic acid (Ad) to aldehyde (Al) forms of the lignols (Ad/Al) reveal diagenetic information, with higher ratios indicating a more highly degraded material. Increases in the (Ad/Al) value indicate an oxidative cleavage reaction has occurred on the alkyl lignin side chain which has been shown to be a step in the decay of wood by many white-rot and some soft rot fungi.
1
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
0
Thermochemolysis (chemical break down of a substance under vacuum and at high temperature) with tetramethylammonium hydroxide (TMAH) or cupric oxide has also been used to characterize lignins. The ratio of syringyl lignol (S) to vanillyl lignol (V) and cinnamyl lignol (C) to vanillyl lignol (V) is variable based on plant type and can therefore be used to trace plant sources in aquatic systems (woody vs. non-woody and angiosperm vs. gymnosperm). Ratios of carboxylic acid (Ad) to aldehyde (Al) forms of the lignols (Ad/Al) reveal diagenetic information, with higher ratios indicating a more highly degraded material. Increases in the (Ad/Al) value indicate an oxidative cleavage reaction has occurred on the alkyl lignin side chain which has been shown to be a step in the decay of wood by many white-rot and some soft rot fungi.
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
1
Thermochemolysis (chemical break down of a substance under vacuum and at high temperature) with tetramethylammonium hydroxide (TMAH) or cupric oxide has also been used to characterize lignins. The ratio of syringyl lignol (S) to vanillyl lignol (V) and cinnamyl lignol (C) to vanillyl lignol (V) is variable based on plant type and can therefore be used to trace plant sources in aquatic systems (woody vs. non-woody and angiosperm vs. gymnosperm). Ratios of carboxylic acid (Ad) to aldehyde (Al) forms of the lignols (Ad/Al) reveal diagenetic information, with higher ratios indicating a more highly degraded material. Increases in the (Ad/Al) value indicate an oxidative cleavage reaction has occurred on the alkyl lignin side chain which has been shown to be a step in the decay of wood by many white-rot and some soft rot fungi.
Well-studied ligninolytic enzymes are found in "Phanerochaete chrysosporium" and other white rot fungi. Some white rot fungi, such as "C. subvermispora", can degrade the lignin in lignocellulose, but others lack this ability. Most fungal lignin degradation involves secreted peroxidases. Many fungal laccases are also secreted, which facilitate degradation of phenolic lignin-derived compounds, although several intracellular fungal laccases have also been described. An important aspect of fungal lignin degradation is the activity of accessory enzymes to produce the H2O2 required for the function of lignin peroxidase and other heme peroxidases.
0
Thermochemolysis (chemical break down of a substance under vacuum and at high temperature) with tetramethylammonium hydroxide (TMAH) or cupric oxide has also been used to characterize lignins. The ratio of syringyl lignol (S) to vanillyl lignol (V) and cinnamyl lignol (C) to vanillyl lignol (V) is variable based on plant type and can therefore be used to trace plant sources in aquatic systems (woody vs. non-woody and angiosperm vs. gymnosperm). Ratios of carboxylic acid (Ad) to aldehyde (Al) forms of the lignols (Ad/Al) reveal diagenetic information, with higher ratios indicating a more highly degraded material. Increases in the (Ad/Al) value indicate an oxidative cleavage reaction has occurred on the alkyl lignin side chain which has been shown to be a step in the decay of wood by many white-rot and some soft rot fungi.
Lignin and its models have been well examined by 1H and 13C NMR spectroscopy. Owing to the structural complexity of lignins, the spectra are poorly resolved and quantitation is challenging.
1
Thermochemolysis (chemical break down of a substance under vacuum and at high temperature) with tetramethylammonium hydroxide (TMAH) or cupric oxide has also been used to characterize lignins. The ratio of syringyl lignol (S) to vanillyl lignol (V) and cinnamyl lignol (C) to vanillyl lignol (V) is variable based on plant type and can therefore be used to trace plant sources in aquatic systems (woody vs. non-woody and angiosperm vs. gymnosperm). Ratios of carboxylic acid (Ad) to aldehyde (Al) forms of the lignols (Ad/Al) reveal diagenetic information, with higher ratios indicating a more highly degraded material. Increases in the (Ad/Al) value indicate an oxidative cleavage reaction has occurred on the alkyl lignin side chain which has been shown to be a step in the decay of wood by many white-rot and some soft rot fungi.
Global commercial production of lignin is a consequence of papermaking. In 1988, more than 220 million tons of paper were produced worldwide. Much of this paper was delignified; lignin comprises about 1/3 of the mass of lignocellulose, the precursor to paper. It can thus be seen that lignin is handled on a very large scale. Lignin is an impediment to papermaking as it is colored, it yellows in air, and its presence weakens the paper. Once separated from the cellulose, it is burned as fuel. Only a fraction is used in a wide range of low volume applications where the form but not the quality is important.
0
Lignin and its models have been well examined by 1H and 13C NMR spectroscopy. Owing to the structural complexity of lignins, the spectra are poorly resolved and quantitation is challenging.
A solution of hydrochloric acid and phloroglucinol is used for the detection of lignin (Wiesner test). A brilliant red color develops, owing to the presence of coniferaldehyde groups in the lignin.
1
Lignin and its models have been well examined by 1H and 13C NMR spectroscopy. Owing to the structural complexity of lignins, the spectra are poorly resolved and quantitation is challenging.
Many grasses have mostly G, while some palms have mainly S. All lignins contain small amounts of incomplete or modified monolignols, and other monomers are prominent in non-woody plants.
0
Lignin and its models have been well examined by 1H and 13C NMR spectroscopy. Owing to the structural complexity of lignins, the spectra are poorly resolved and quantitation is challenging.
Thioglycolysis is an analytical technique for lignin quantitation. Lignin structure can also be studied by computational simulation.
1
Lignin and its models have been well examined by 1H and 13C NMR spectroscopy. Owing to the structural complexity of lignins, the spectra are poorly resolved and quantitation is challenging.
Lignin is a class of complex organic polymers that form key structural materials in the support tissues of most plants. Lignins are particularly important in the formation of cell walls, especially in wood and bark, because they lend rigidity and do not rot easily. Chemically, lignins are polymers made by cross-linking phenolic precursors.
0
Susie Bright:502973
She is one of the early writers/activists referred to as a sex-positive feminist. Her papers are part of the Human Sexuality Collection at Cornell University Library along with the archives of On Our Backs.
1
Susie Bright:502973
She was born with the name Susannah Bright and is the daughter of linguist William Bright and Elizabeth Bright. Her stepmother is Lise Menn, and her stepbrothers are Joseph Menn and Stephen Menn. Bright previously lived with her former partner Honey Lee Cottrell in the 1980s. Since 1993, she has lived with her partner Jon Bailiff. She has one daughter with partner Jon Bailiff, named Aretha.
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Susannah Bright, also known as Susie Sexpert (born March 25, 1958), is an American feminist, author, journalist, critic, editor, publisher, producer, and performer, often on the subject of sexual politics and sexuality.
Susie Bright:502973
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Susannah Bright, also known as Susie Sexpert (born March 25, 1958), is an American feminist, author, journalist, critic, editor, publisher, producer, and performer, often on the subject of sexual politics and sexuality.
The donation included papers and documents from her early activist days in "The Red Tide," Teamsters for a Democratic Union, and International Socialists, her early stage and film work, a complete archive of "On Our Backs" magazine and Fatale Videos, her reviews and research as a critic for "Penthouse Forum," and the X-Rated Critics Association, all of her nonfiction manuscripts and anthology research for "Best American Erotica," costumes, VHS tapes, books, writings— as well as many other artist files from the early lesbian feminist and erotic literary fiction publishing era.
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