Zero-Cost Estimation of Zero-Point Energies. 
An additive, linear, atom-type-based (ATB) scheme is developed allowing no-cost estimation of zero-point vibrational energies (ZPVE) of neutral, closed-shell molecules in their ground electronic states.  The atom types employed correspond to those defined within the MM2 molecular mechanics force field approach.  The reference training set of 156 molecules cover chained and branched alkanes, alkenes, cycloalkanes and cycloalkenes, alkynes, alcohols, aldehydes, carboxylic acids, amines, amides, ethers, esters, ketones, benzene derivatives, heterocycles, nucleobases, all the natural amino acids, some dipeptides and sugars, as well as further simple molecules and ones containing several structural units, including several vitamins.  A weighted linear least-squares fit of atom-type-based ZPVE increments results in recommended values for the following atoms, with the number of atom types defined in parentheses: H(8), D(1), B(1), C(6), N(7), O(3), F(1), Si(1), P(2), S(3), and Cl(1).  The average accuracy of the ATB ZPVEs is considerably better than 1 kcal mol(-1), that is, better than chemical accuracy.  The proposed ATB scheme could be extended to many more atoms and atom types, following a careful validation procedure; deviation from the MM2 atom types seems to be necessary, especially for third-row elements.