Evidence of a reentrant peierls distortion in liquid GeTe
The local atomic order of semiconducting liquid GeTe is studied using first-principles molecular-dynamics simulations.  Our work points out a high degree of alternating chemical order in the liquid and demonstrates the presence of a Peierls distortion close above the melting temperature.  This distortion, absent in the high temperature crystalline structure of NaCl type, is a remnant of the atomic arrangement in the A7 low temperature crystalline phase.  It disappears slowly with temperature, as the liquid evolves from a semiconducting to a metallic state.