CHEMICAL HYGIENE PLAN AND HAZARDOUS MATERIALS SAFETY MANUAL FOR LABORATORIES This is the Chemical Hygiene Plan specific to the following areas: Laboratory name or room number(s): Chmielewski Lab Building: Wetherill building, rooms 441, 441A, 463, and 475 Supervisor: Dr. Jean Chmielewski Department: Chemistry Telephone numbers 911 for Emergency and urgent consultation 48221 Police business line 46919 Fire Dept business line 46371 Radiological and Environmental Management Revised on: Print one full copy and professor sign cover page. That copy must be kept easily accessible to all staff, and all staff aware of, and able to quickly locate it. Signature signifies that information included is this group’s CHP and that supervisor has verified accuracy of cover page, SOPs, page (i) and Appendices J & K. All laboratory chemical use areas must maintain a work-area specific Chemical Hygiene Plan which conforms to the requirements of the OSHA Laboraotry Standard 29 CFR 19190.1450. This document was modified from a Chemistry-specific template <http://www.chem.purdue.edu/chemsafety/CHP/2013CHM-CHPtemplate.docx>, which was modified from the REM-provided template made available to the University. The REM model CHP was version 2010A; updates are to be found at www.purdue.edu/rem
Eyes: Get medical aid immediately. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Skin: Immediately flush skin with plenty of water and soap. Ingestion: Move person to fresh air and rinse mouth with water Get medical aid immediately Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Standard Operating Procedure for Carbon tetrachloride Storage and Handling: in a cooled dry well ventilated area Avoid contact with eyes, be very cautious when handling. Wear appropriate clothing that covers skin and appropriate PPE such as gloves, protection eye wear. Compound should be handled in the hood. Health effects: Skin irritation, rash, absorption may occur, digestive disorders, headache, drowsiness, dizziness, loss of coordination, lung congestion, effects on the brain, convulsions, coma Eyes may cause eye irritation Inhalation irritation, digestive disorders, headache, drowsiness, dizziness, loss of coordination, lung congestion, effects on the convulsions, coma. Ingestion irritation, digestive disorders, headache, drowsiness, dizziness, loss of coordination, lung congestion, effects on the brain, convulsions, coma. Long term exposure may cause cancer , liver and kidney damage
INJURY AND ILLNESS GENERAL Employees and students must notify their immediate supervisor or instructor of all illnesses and injuries related to exposure to hazardous chemicals. Employees and students should report to the if medical attention is required. Students should be accompanied by a friend, teaching assistant or instructor. If transportation is necessary, the University Police (see page) should be called to get transportation for the victim. Do not move a seriously injured person unless he/she is in further danger. Do not transport injured person(s) in personal or department vehicles. Call 911 for ambulance transportation. In cases of serious injury or illness, it is imperative that appropriate actions be followed immediately. When in doubt as to what should be done, telephone the University Police at (see cover page) for assistance. Give emergency and medical personnel the following information: your name, location and nature of the emergency the name of the chemical involved the amount involved area of the body affected symptoms The supervisor or instructor must ensure the appropriate injury report forms are completed. Contact your Business Office for additional information. If you have any questions regarding injury and illness procedures, contact your supervisor, instructor, or the University Police. MINOR FIRST-AID First Aid Kits. First aid kits are not recommended except for remote operations where emergency care is not readily available. If a department desires a first aid kit, it must be maintained with essential supplies at all times. See the General Stores Catalog for a list of essential supplies. First aid kit supplies can be purchased from General Stores. First aid kits must be readily accessible. If the kit is not visible, the area where it is stored must be clearly marked. Do not dispense or administer any medications, including aspirin. Do not put any ointments or creams on wounds or Use cool water. The MSDS contains special first aid information. giving first aid, call the ambulance (see cover page) to transport the victim to a medical facility for evaluation. Student and employee first aid cases are treated at the ( campus). Visitor first aid cases are treated at the nearest off-campus hospital. For specific aid information, contact your supervisor, instructor, or the University Police.
If storage or use of any particular material occurs in more than one room, give separate information for each room. Attach separate pages if necessary but preserve exact spelling and CAS numbers as they appear here. Reportable Materials (continued) CAS # Regulated Material/Substance Builduing/Room Max. lbs. on hand* Max. lbs. used** 3,3'-dichlorobenzidine (and SEE DEFINITION (7) 60-11-7 4-dimethylaminoazobenzene 75-21-8 ethylene aka oxirane 151-56-4 ethyleneimine, aka aziridine 50-00-0 formaldehyde and formaldehyde solutions, aka formalin lead SEE DEFINITION (8) 75-09-2 methylene chloride, aka dichloromethane 101-77-9 methylenedianiline 134-32-7 alpha-naphthylamine 91-59-8 beta-naphthylamine 92-93-3 4-nitrobiphenyl, aka 4-phenyl-nitrobenzene 62-75-9 N-nitrosodimethylamine 57-57-8 beta-propiolactone 75-01-4 vinyl chloride, aka chloroethene *Max. lbs. on hand = estimate maximum potential for weight in pounds present in room at any time. **Max. lbs. used = estimate maximum potential for weight in pounds used in room in a work day. Return to REM-IH Section, REM, CIVL Returned by (name):