Section 9—Physical and chemical properties Shape and aspect ratio Crystallinity Dustiness Surface area Degree of aggregation or agglomeration, and dispersibility Redox potential Biodurability or biopersistence Surface coating or chemistry Section 10—Stability and reactivity Reactivity Chemical stability ☐ Conditions to Incompatible materials Hazardous decomposition products Section 11—Toxicological information Information on possible routes of exposure Early onset symptoms related to exposure Exposure levels and health effects Interactive effects ☐ When specific chemical data is not available Mixtures of chemicals Other information Section 12—Ecological information Ecotoxicity Persistence and degradability Bioaccumulative potential Mobility in soil adverse effects Section 13—Disposal considerations Disposal methods
P210 Keep away from heat/ sparks/ open flames/ hot surfaces—No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P240 Ground/bond container and receiving equipment. —if the explosive is electrostatically sensitive. P250 Do not subject to grinding/shock/…/friction. Manufacturer/ supplier or the competent authority to specify applicable rough handling. P280 Wear face protection. Manufacturer/supplier or competent authority to specify type of equipment. P370 + P380 In case of fire: Evacuate area. P372 Explosion risk in case of fire. —except if explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P373 DO NOT fight fire when fire reaches explosives. P374 fire with normal precautions from a reasonable distance. —if explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P401 Store ... …in accordance with local/ regional/ national/ international Regulations (to be specified). P501 Dispose of contents/container to... … in accordance with regional/ national/ international Regulations (to be specified). Explosives Hazard category Signal word Hazard statement Symbol* Division 1.5 Danger H205 May mass explode in fire Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/ sparks/ open flames/ hot surfaces—No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P240 Ground/ Bond container and receiving equipment. —if electrostatically sensitive material is for reloading. P241 Use explosion-proof electrical/ ventilating/ lighting/ ... / equipment. ... Manufacturer/ supplier or the competent authority to specify other equipment. —if dust clouds can P280 Wear protective gloves/ eye protection/face protection Manufacturer/ supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ...Manufacturer/supplier or the competent authority to specify appropriate media. —if water increases risk. Self-reactive substances and mixtures Hazard category Signal word Hazard statement Symbol Type A Danger H240 Heating may cause an explosion Exploding bomb Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/ sparks/ open flames/hot surfaces—No smoking. Manufacturer/ supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from clothing/ …/ combustible materials. ... Manufacturer/supplier or the competent authority to specify incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/ eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/ supplier or the competent authority to specify appropriate media. —if water increases risk. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. P403 + P235 Store in a well-ventilated place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ... Manufacturer/ supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/ container to... … in accordance with local/ regional/ national/ international Regulations (to be specified). Self-reactive substances and mixtures Hazard category Signal word Hazard statement Symbol Type B Danger H241 Heating may cause a fire or explosion Exploding bomb and Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/ sparks/ open flames/hot surfaces—No smoking. Manufacturer/ supplier or the competent authority to specify applicable ignition source(s). P220 Keep/ away from clothing/ .../ combustible materials. ... Manufacturer/ supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/ eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/ supplier or the competent authority to specify appropriate media. —if water increases risk. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. P403 + P235 Store in a well-ventilated place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ... Manufacturer/ supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/container to... …in accordance with local/ regional/ national/ international Regulations (to be specified). Self-reactive substances and mixtures Hazard category Signal word Hazard statement Symbol Type C Type D Type E Type F Danger Danger Danger Danger H242 Heating may cause a fire H242 Heating may a fire H242 Heating may cause a fire H242 Heating may cause a fire Flame Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/ sparks/ open flames/ hot surfaces—No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition sources(s). P222 Do not contact with air. P280 Wear protective gloves/ eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P302 + P334 IF ON SKIN: Immerse in cool water/ wrap with wet bandages P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/ supplier or the competent authority to specify appropriate media. —if water increases risk. P422 Store contents under… ... Manufacturer/ supplier or the competent authority to specify appropriate liquid or gas. Pyrophoric solids Hazard category Signal word Hazard statement Symbol 1 Danger H250 Catches fire spontaneously if exposed to air Flame Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/ sparks/ open flames/ hot surfaces—No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition sources(s). P222 Do not allow contact with air. P280 Wear protective gloves/ eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P335 + P334 Brush off loose particles from skin. Immerse in cool water/ wrap in wet bandages P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/ supplier or the competent authority to specify appropriate media. —if water increases risk. P422 Store contents under… ... Manufacturer/ supplier or the competent authority to specify appropriate liquid or inert gas.
Self-heating substances and mixtures Hazard category Signal word Hazard statement Symbol 1 2 Danger Warning H251 Self-heating; may catch fire H252 Self-heating in large quantities; may catch fire Flame Precautionary statements Prevention Response Storage Disposal P235 + P410 Keep cool. Protect from sunlight. P280 Wear protective gloves/ eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P407 Maintain air gap between stacks/ pallets. P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify mass and temperature. P420 Store away from other materials. Substances and mixtures which, in contact with water, emit flammable gases Hazard category Signal word Hazard statement Symbol 1 2 Danger Danger H260 In contact with water releases flammable gases, which may ignite spontaneously H261 In contact with water releases flammable gases Flame Precautionary statements Prevention Response Storage Disposal
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232 Handle inert gas. Protect from moisture. P280 Wear protective gloves/ eye protection/ face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P335 + P334 Brush off loose particles from skin and immerse in cool water/ wrap in wet bandages. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate —if water increases risk. P402 + P404 in a dry place. Store in a closed container. P501 Dispose of contents/ container to... …in accordance with local/regional/national/ international Regulations (to be specified). Substances and mixtures which, in contact with water, emit flammable gases Hazard category Signal word Hazard statement Symbol 3 Danger H261 In contact with releases flammable gases Flame Precautionary statements Prevention Response Storage Disposal P231 + P232 Handle under inert gas. Protect from moisture. P280 Wear protective gloves/ eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction. ...Manufacturer/ supplier or the competent authority to specify appropriate —if water increases risk. P402 + P404 in a dry place. Store in a closed container. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Oxidising liquids Hazard category Signal word Hazard statement Symbol
1 Danger H271 May cause fire or explosion; strong oxidiser Flame over circle Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat. P220 Keep/ away from clothing and other combustible materials. P221 Take any precaution to avoid mixing with combustibles/... ... Manufacturer/ supplier or the competent authority to specify incompatible materials. P280 Wear protective gloves / eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P283 Wear fire/ flame resistant/ retardant clothing. P306 + P360 IF ON CLOTHING: immediately contaminated clothing and skin with plenty of water before removing clothes. P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/ supplier or the competent authority to specify appropriate media. —if water increases risk. P501 Dispose of contents/ container to... …in accordance with local/ regional/ national/ international Regulations (to be specified). Oxidising liquids Hazard category Signal word Hazard statement Symbol 2 3 Danger Warning H272 May intensify fire; oxidiser H272 May intensify fire; oxidiser Flame over circle Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat. P220 Keep/ Store away from clothing and other combustible materials. P221 Take any precaution to avoid mixing with combustibles/... ... Manufacturer/ supplier or the competent authority to specify other incompatible materials. P280 Wear protective gloves / eye protection/ face protection. Manufacturer/ supplier or the competent authority to specify type of equipment. P283 Wear fire/ flame resistant/ retardant clothing. P306 + P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. P371 + P380 + P375 In case of fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/ supplier or the competent authority to specify appropriate media. —if water increases risk. P501 Dispose of contents/ container to... …in accordance with local/ regional/ national/ international Regulations (to be specified). Oxidising solids Hazard category Signal word Hazard statement Symbol 2 3 Danger Warning H272 May intensify fire; oxidiser H272 May intensify fire; oxidiser Flame over circle Precautionary statements Prevention Response Storage Disposal
Acute toxicity—oral Hazard category Signal word Hazard statement Symbol 1 2 Danger Danger H300 Fatal if swallowed H300 Fatal if swallowed and crossbones Precautionary statements Prevention Response Storage Disposal P264 Wash…thoroughly handling. … Manufacturer/ supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. —if immediate administration of antidote is required. P330 mouth. P405 Store locked up. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). toxicity—oral Hazard category Signal word Hazard statement Symbol 3 Danger H301 Toxic if swallowed Skull and crossbones Precautionary statements Prevention Response Storage Disposal
P264 Wash…thoroughly after handling. … Manufacturer/ supplier or the competent authority to specify of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental aid instruction. —if immediate administration of antidote is required. P330 Rinse mouth. P405 Store locked up. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Acute toxicity—oral Hazard category Signal word Hazard statement Symbol 4 Warning H302 Harmful if swallowed Exclamation mark Precautionary statements Prevention Response Storage Disposal P264 Wash…thoroughly after handling. … Manufacturer/ supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). toxicity—dermal Hazard category Signal word Hazard statement Symbol 1 2 Danger Danger H310 Fatal in contact with skin H310 in contact with skin Skull and crossbones
Precautionary statements Prevention Response Storage Disposal P262 Do not get in eyes, on skin, or on clothing. P264 Wash…thoroughly after handling. … Manufacturer/ supplier or the competent authority to specify of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/ protective clothing. Manufacturer/ supplier or the competent authority to specify type of equipment. P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water. P310 Immediately call a POISON CENTRE or doctor/ physician. P322 Specific measures (see ... on this label) ... Reference to supplemental first aid instruction. —if immediate measures such as specific cleansing agent is advised. P361 Remove/ Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P405 locked up. P501 Dispose of contents/ container to... ... in accordance with regional/ national/ international Regulations (to be specified). Acute toxicity—dermal Hazard category Signal word Hazard statement Symbol 3 Danger H311 Toxic in contact with skin and crossbones Precautionary statements Prevention Response Storage Disposal
P280 Wear protective gloves/ protective clothing. Manufacturer/ supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTRE or doctor/ physician if you feel unwell. P322 Specific measures (see ... on this label) ... Reference to supplemental first aid instruction. —if measures such as specific cleansing is advised. P361 Remove/ Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Acute toxicity—dermal Hazard category Signal word Hazard statement Symbol 4 Warning H312 Harmful in contact with skin Exclamation mark Precautionary statements Prevention Response Storage Disposal
P280 Wear protective gloves/ protective clothing. Manufacturer/ supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTRE or doctor/ physician if you feel unwell. P322 Specific measures (see ... on this label) ... Reference to supplemental aid instruction. —if measures such as specific cleansing agent is advised. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Acute toxicity—inhalation Hazard category Signal word Hazard statement Symbol 1 2 Danger Danger H330 Fatal if inhaled H330 Fatal if inhaled Skull and crossbones Precautionary statements Prevention Response Storage Disposal P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P284 Wear respiratory protection. Manufacturer/ supplier or the competent authority to specify equipment. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 Immediately call a POISON CENTER or doctor/ physician. P320 Specific treatment is urgent (see ... on this label) ... Reference to supplemental first aid instruction. —if immediate administration of antidote is required. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. —if product is volatile as to generate hazardous atmosphere. P405 Store locked up. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified).
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Manufacturer/ supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. Skin corrosion/irritation Hazard category Signal word Hazard statement Symbol 1A to 1C Danger H314 Causes severe skin burns and eye damage Corrosion Precautionary statements Prevention Response Storage Disposal
P264 Wash…thoroughly after handling. … Manufacturer/ supplier or the competent authority to specify of the body to be washed after handling. P280 Wear protective gloves. Manufacturer/ supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. —Manufacturer/ supplier or the competent authority may specify a cleansing agent if appropriate. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before Serious eye damage/irritation Hazard category Signal word Hazard statement Symbol 1 Danger H318 Causes serious eye damage Corrosion Precautionary statements Prevention Response Storage Disposal P280 Wear eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P305 + P351 + P338 IF IN EYES: cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a POISON CENTER or doctor/physician.
P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P285 In case of inadequate ventilation wear respiratory protection. Manufacturer/supplier or the competent authority to specify equipment P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/ physician. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Sensitisation—skin Hazard category Signal word Hazard statement Symbol 1, 1A, 1B Warning H317 May cause an allergic skin reaction Exclamation mark Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Manufacturer/ supplier or the competent authority to specify applicable conditions. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Manufacturer/ supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/ attention. P321 Specific treatment (see ... on this ... Reference to supplemental first aid instruction. —Manufacturer/ supplier or the competent authority may specify a cleansing agent if appropriate. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified).
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Manufacturer/ supplier or the competent authority to specify applicable conditions. P264 Wash …thoroughly after handling. … Manufacturer/ supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P307 + P311 IF exposed: Call a POISON CENTER or doctor/ physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. —if immediate measures are required. P405 locked up. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Specific target organ toxicity (single exposure) Hazard category Signal word Hazard statement Symbol 2 Warning H371 May cause damage to organs <...> <<...>> <...> (or all organs affected, if known) <<...>> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Health hazard Precautionary statements Prevention Response Storage Disposal
P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Manufacturer/ supplier or the competent authority to specify applicable conditions. P264 Wash…thoroughly after handling. … Manufacturer/ supplier or the competent authority to specify of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P307 + P311 IF exposed: Call a POISON CENTER or doctor/ physician. P405 Store locked up. P501 Dispose of contents/ container to... ... in accordance with regional/ national/ international Regulations (to be specified). Specific target organ toxicity (single exposure) Hazard category Signal word Hazard statement Symbol 3 Warning H335 May cause respiratory irritation; or H336 May cause drowsiness or dizziness Exclamation mark Precautionary statements Prevention Response Storage Disposal P261 breathing dust/ fume/ gas/ mist/ vapours/ spray. Manufacturer/ supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/ physician if you feel unwell. P403 + P233 Store in a well-ventilated place. Keep container tightly closed. —if product is volatile so as to generate hazardous atmosphere. P405 Store locked up. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Specific target toxicity (repeated exposure) Hazard category Signal word Hazard statement Symbol
1 Danger H372 Causes damage to organs <...> through prolonged or repeated exposure <<...>> <...> (state all organs affected, if known) <<...>> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Health hazard Precautionary statements Prevention Response Storage Disposal P260 Do not breathe dust/ fume/ gas/ mist/ vapours/ Manufacturer/supplier or the competent authority to specify applicable conditions. P264 Wash … thoroughly after handling. …Manufacturer/ supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P314 Get medical advice/attention if you feel unwell. P501 Dispose of contents/ container to... ... in accordance with local/ regional/ national/ international Regulations (to be specified). Specific target organ toxicity (repeated exposure) Hazard category Signal word Hazard statement Symbol 2 Warning H373 May cause damage to organs <...> through prolonged or repeated exposure <<...>> <...> (state all organs affected, if known) <<...>> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Health hazard Precautionary statements Prevention Response Storage Disposal