APPENDIX D Shock-Sensitive Materials The following are examples of materials which can be shock-sensitive: acetylides aluminum ophorite explosive amatol ammonal ammonium nitrate ammonium perchlorate ammonium picrate ammonium salt lattice tetryl calcium nitrate copper acetylide cyanuric triazide cyclotrimethylenetrinitramine dinitroethyleneurea dinitroglycerine dinitrophenol dinitrophenolates dinitrophenyl hydrazine dinitrotoluene dipicryl sulfone dipicrylamine erythritol tetranitrate fulminate of mercury fulminate of silver fulminating gold fulminating mercury fulminating platinum gelatinized nitrocellulose guanyl nitrosamino guanyltetrazene guanyl nitrosamino guanylidene hydrazine guanylidene heavy metal azides hexanite hexanitrodiphenylamine hexanitrostilbene hexogen hydrazine mixtures hydrazinium nitrate hydrazoic acid lead azide lead mannite lead mononitroresorcinate lead picrate lead salts lead styphnate magnesium ophorite mannitol hexanitrate mercury oxalate mercury tartrate nitrated carbohydrate nitrated glucoside nitrated polyhydric alcohol nitrogen trichloride nitrogen tri-iodide nitroglycerin nitroglycide nitroglycol nitroguanidine nitroparaffins nitronium perchlorate nitrotoluene nitrourea organic amine nitrates organic nitramines organic peroxides (t-butyl peroxide) picramic acid picramide picric acid picryl chloride picryl fluoride polynitro aliphatic compounds potassium nitroaminotetrazole silver acetylide silver azide silver styphnate silver tetrazene sodatol sodium amatol sodium sodium/potassium nitrate explosive mixtures sodium picramate syphnic acid tetrazene tetranitrocarbazole tetrytol trimonite trinitroanisole trinitrobenzene trinitrobenzoic acid trinitrocresol trinitronaphthalene trinitrophenetol trinitrotoluene tritonal urea nitrate
APPENDIX F Laboratory Safety/Supply Checklist The presence/availability of items marked *** is required in all areas of laboratory use of hazardous chemicals. Supervisors must determine which of the others are required. ___ Fire extinguisher ___ Safety shower and eyewash ___ Fire blanket ___ Splash-proof goggles ___ Fire alarm ___ Specialty goggles U.V., IR, etc.) ___ Dust pan and broom*** ___ Face shield (8" minimum) ___ Safety cans for chemical storage ___ Gloves appropriate for material(s) being used (see Table 1)*** ___ Acid/corrosive storage cabinet ___ Lab coat*** ___ Bottle carrier(s) (rubber, polyethylene) ___ Dust ___ Hazard Assessments documented and posted ___ Other PPE (list) ___ Flammable storage cabinets ___ Respirators with appropriate cartridges* ___ control trays ___ Hearing protection (i.e., ear ___ ___ ___ ___ ___ ___ Spill clean-up media for: Acid Base Solvent Oil Mercury Radioactivity ___ ___ ___ Emergency procedures for: spill or explosion*** ___ ___ ___ Biosafety supplies: a. Sharps containers b. Autoclave bags c. Biohazard warning labels ___ Laboratory hoods (fan operational, adequate face velocity, no broken glass, clean and orderly) ___ Chemical Hygiene Plan*** ___ Standard Operating Procedures*** ___ Material Safety Data Sheets ___ Labeled Containers*** * Cartridge respirators may only be worn by employees enrolled in the Purdue Respiratory Protection Program. Contact the REM Industrial Hygiene Section for more information.