Methacrylates If the name of a family or sub-family is not sufficient to characterise the chemical elements of important functional groups, the generic name should be a combination of the corresponding different family or sub-family names. Examples: Name Family Sub-family Generic Name Lead hexafluorosilicate 009: Fluorine compounds Inorganic fluorides 082: Lead compounds Inorganic lead fluoride Chlorobenzene 602: Halogenated hydrocarbons Halogenated aromatic hydrocarbons 017: Chlorine compounds Chlorinated aromatic hydrocarbon 2,3,6-Trichlorophenylacetic acid 607: Organic acids and derivatives Halogenated aromatic acids 017: Chlorine compounds Chlorinated aromatic acid 1-Chloro-1-nitropropane 610: Chloronitrated compounds 601: Hydrocarbons Aliphatic hydrocarbons Chlorinated aliphatic hydrocarbon Tetrapropyl dithiopyrophosphate 015: Phosphorus compounds Phosphoric esters 016: Sulphur compounds Thiophosphoric ester In the case of certain elements, notably metals, the name of the family or sub-family may be indicated by the 'organic' or 'inorganic'. Examples: Name Family Sub-family Generic Name Dimercury dichloride 080: Mercury compounds Inorganic mercury compound Barium acetate 056: Barium compounds Organic barium compound Ethyl nitrite 007: Nitrogen compounds Nitrites Organic nitrite Sodium hydrosulphite 016: Sulphur compounds Inorganic sulphur compound C.3. Division of substances into families and sub-families Family No Families Sub-families 001 Hydrogen compounds Hydrides 003 Lithium compounds 004 Beryllium compounds 005 Boron compounds Boranes Borates
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P230 Keep wetted with... …Manufacturer/supplier or the competent authority to specify appropriate material. - if drying out increases explosion hazard, except as needed for manufacturing or operating processes (e.g. nitrocellulose). P240 Ground/bond container and receiving equipment. - if the explosive is electrostatically sensitive. P250 Do not subject to grinding/shock/…/friction. …Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 +P380 In case of fire: evacuate area. P372 Explosion risk in case of fire. P373 DO NOT fight fire when fire reaches explosives. P401 Store ... …in accordance with Regulations (to be specified). P501 Dispose of contents/container to... …in accordance with Regulations (to be specified). EXPLOSIVES Symbol Exploding bomb Hazard category Signal word Hazard statement Division 1.4 Warning H204 Fire or projection hazard Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P240 Ground/bond container and receiving equipment. - if the explosive is electrostatically sensitive. P250 Do not subject to Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear face protection. Manufacturer/supplier or competent authority to specify type of equipment. P370+P380 In case of fire: Evacuate area. P372 Explosion risk in case of fire. - except if explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P373 DO NOT fight fire when fire reaches explosives. P374 Fight fire with normal precautions from a reasonable distance. - If explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P401 Store ... …in accordance with local/regional/ national/international Regulations (to be specified). P501 Dispose of contents/container to... … in accordance with Regulations (to be specified). EXPLOSIVES Symbol* Hazard category Signal word Hazard statement Division 1.5 Danger H205 May mass explode in fire Precautionary statements Prevention Response Storage Disposal
OXIDISING GASES Symbol Flame over circle Hazard category Signal word Hazard statement 1 Danger H270 May cause or intensify fire; oxidiser Precautionary statements Prevention Response Storage Disposal P220 Keep/Store away from materials. …Manufacturer/supplier or the competent authority to specify other incompatible materials. P244 Keep reduction valves free from grease and oil. P370 + P376 In case of fire: Stop leak if safe to do so. P403 in well-ventilated place. GASES UNDER PRESSURE Symbol Gas cylinder Hazard category Signal word Hazard statement Compressed gas Warning H280 Contains gas under pressure; may explode if heated Liquefied gas Warning H280 Contains gas under pressure; may explode if heated Dissolved gas Warning H280 Contains gas under pressure; may explode if heated Precautionary statements Prevention Response Storage Disposal P410 + P403 Protect from sunlight. in a place. GASES UNDER PRESSURE Symbol Gas cylinder Hazard category Signal word Hazard statement Refrigerated liquefied gas Warning H281 Contains refrigerated gas; may cause cryogenic ventilated
or injury Precautionary statements Prevention Response Storage Disposal P282 Wear cold insulating gloves/face shield/eye protection. P336 Thaw frosted parts with lukewarm water. Do not rub affected area. P315 Get immediate medical advice/attention P403 Store in well-ventilated place. FLAMMABLE LIQUIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H224 Extremely flammable liquid and vapour 2 Danger H225 Highly flammable liquid and vapour 3 Warning H226 Flammable liquid and vapour Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P233 Keep container tightly closed. P240 Ground/Bond container and receiving equipment - if electrostatically sensitive material is for reloading. - if product is volatile so as to generate hazardous atmosphere. P241 Use explosion-proof electrical/ventilating/ lighting/.../equipment. ... Manufacturer/supplier or P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P370 + P378 In case of fire: Use ... for extinction. or the competent authority to specify appropriate media. - if water increases risk. P403 + P235 Store in a place. Keep cool. P501 Dispose of contents/container to... … in accordance with Regulations (to be specified).
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P240 Ground/Bond container and receiving equipment. - if electrostatically sensitive material is for reloading. P241 Use explosion-proof electrical/ventilating/ lighting/... /equipment. ... Manufacturer/supplier or the competent authority to specify other equipment. - if dust clouds can occur. P280 Wear protective gloves/eye protection/face protection Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ...Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. SELF-REACTIVE SUBSTANCES AND MIXTURES Symbol Exploding bomb Hazard category Signal word Hazard statement Type A Danger H240 Heating may cause an explosion Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from materials. ... Manufacturer/supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. P403 + P235 Store in a place. Keep cool. P411 at temperatures not exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/container to... … in accordance with Regulations (to be specified). SELF-REACTIVE SUBSTANCES AND MIXTURES Symbol Exploding bomb and flame Hazard category Signal word Hazard statement Type B Danger H241 Heating may cause a fire or explosion Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from materials. ... Manufacturer/supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. P403 + P235 in a place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/container to... …in accordance with Regulations (to be specified). SELF-REACTIVE SUBSTANCES AND MIXTURES Symbol Flame Hazard category Signal word Hazard statement Type C Danger H242 Heating may a fire Type D Danger H242 Heating may cause a fire Type E Warning H242 Heating may cause a fire Type F Warning H242 Heating may cause a fire Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from materials. …Manufacturer/supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P403 + P235 Store in a place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ...Manufacturer/supplier or the competent authority to specify temperature. P420 away from other materials. P501 Dispose of contents/container to... …in accordance with Regulations (to be specified). Note: Hazard category Type G: There are no label elements allocated to this hazard category PYROPHORIC LIQUIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H250 Catches fire spontaneously if exposed to air Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition sources(s). P222 Do not contact with air. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P334 IF ON SKIN: Immerse in cool water/wrap with wet bandages P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate - if water increases risk. P422 Store contents under... ... Manufacturer/supplier or the competent authority to specify appropriate liquid or inert gas. PYROPHORIC SOLIDS Symbol Hazard category Signal word Hazard statement 1 Danger H250 Catches fire spontaneously if exposed to air Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P222 Do not allow contact with air. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P335 + P334 off loose particles from skin. Immerse in cool water/wrap in wet bandages. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P422 Store contents under... …Manufacturer/supplier or the competent authority to specify appropriate liquid or inert gas.
P210 Keep away from heat. P220 Keep away from clothing and other combustible materials. P221 Take any precaution to avoid mixing with combustibles/... …Manufacturer/supplier or the competent authority to specify other incompatible materials. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P283 Wear fire/flame resistant/retardant clothing. P306 + P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P501 Dispose of contents/container to... …in accordance with local/regional/ national/international Regulations (to be specified). OXIDISING SOLIDS Symbol Flame over circle Hazard category Signal word Hazard statement 2 Danger H272 May intensify fire; oxidiser 3 Warning H272 May intensify fire; oxidiser Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces.- No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from materials. ... Manufacturer/supplier or the competent authority to specify incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P411 + P235 Store at temperatures not exceeding …°C/…°F. Keep cool. ... Manufacturer/supplier or the competent authority to specify temperature. P410 Protect from sunlight. P420 Store away from other materials. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified). ORGANIC PEROXIDES Symbol Exploding bomb and Hazard category Signal word Hazard statement Type B Danger H241 Heating may cause a fire or explosion Precautionary statements Prevention Response Storage Disposal
P330 Rinse mouth. ACUTE TOXICITY – ORAL Symbol Exclamation mark Hazard category Signal word Hazard statement 4 Warning H302 Harmful if swallowed Precautionary statements Prevention Response Storage Disposal P264 … thoroughly after handling. or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, or smoke when using this product. P301 + P312 IF SWALLOWED: Call a or doctor/physician if you feel unwell. P330 Rinse mouth. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). TOXICITY - DERMAL Symbol Skull and crossbones Hazard category Signal word Hazard statement 1 Danger H310 Fatal in contact with skin 2 Danger H310 Fatal in contact with skin Precautionary statements Prevention Response Storage Disposal
P262 Do not get in eyes, on skin, or on clothing. P264 … thoroughly after handling. or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water. P310 Immediately call a POISON CENTRE or doctor/physician. P322 Specific measures (see ... on this ... Reference to supplemental first aid instruction. - if immediate measures such as specific cleansing agent is advised. P361 Remove/Take off immediately all contaminated clothing. P363 contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). TOXICITY - DERMAL Symbol Skull and crossbones Hazard category Signal word Hazard statement 3 Danger H311 Toxic in contact with skin Precautionary statements Prevention Response Storage Disposal
P280 Wear protective gloves/protective clothing Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a or doctor/physician if you feel unwell. P322 Specific measures (see ... on this label) ... Reference to supplemental first aid instruction. - if measures such as specific cleansing agent is advised. P363 contaminated clothing before reuse. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). ACUTE TOXICITY - INHALATION Symbol Skull and crossbones Hazard category Signal word Hazard statement 1 Danger H330 Fatal if inhaled 2 Danger H330 Fatal if inhaled Precautionary statements Prevention Response Storage Disposal P260 Do not breathe dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P284 Wear respiratory protection. Manufacturer/supplier or the competent authority to specify equipment. P304 + P340 IF INHALED: Remove victim to air and keep at rest in a position comfortable for breathing. P310 Immediately call a or doctor/physician. P320 Specific treatment is urgent (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate P403 + P233 in a place. Keep container tightly closed. - if product is volatile as to generate hazardous atmosphere. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
ACUTE TOXICITY - INHALATION Symbol Exclamation mark Hazard category Signal word Hazard statement 4 Warning H332 Harmful if inhaled Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a or doctor/physician if you feel unwell. SKIN CORROSION/IRRITATION Symbol Corrosion Hazard category Signal word Hazard statement 1A to 1C Danger H314 Causes severe skin burns and eye damage Precautionary statements Prevention Response Storage Disposal P260 Do not breathe dusts or mists. - if inhalable particles of dusts or mists may occur during use. P264 …thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P280 Wear protective gloves/protective clothing/eye protection/face protection. Manufacturer/supplier or the competent authority P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. skin with water/shower. P363 contaminated clothing before reuse. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 Immediately call a or doctor/physician. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
SENSITISATION – RESPIRATORY Symbol Health hazard Hazard category Signal word Hazard statement 1, 1A, 1B Danger H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P285 In case of inadequate ventilation wear respiratory protection. Manufacturer/supplier or the competent authority to specify equipment P304 + P341 IF INHALED: If breathing is difficult, remove victim to air and keep at rest in a position comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a or doctor/physician. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified). SENSITISATION – SKIN Symbol Exclamation mark Hazard category Signal word Hazard statement 1, 1A, 1B Warning H317 May an allergic skin reaction Precautionary statements Prevention Response Storage Disposal
P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - Manufacturer/supplier or the competent authority may specify a cleansing agent if appropriate. P363 contaminated clothing before P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified). GERM CELL MUTAGENICITY Symbol Health hazard Hazard category Signal word Hazard statement 1A, 1B Danger H340 May cause genetic defects <...> 2 Warning H341 Suspected of causing genetic defects <...> <...> route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Precautionary statements Prevention Response Storage Disposal P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P308 + P313 IF exposed or concerned: Get medical advice/attention. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified).
P260 Do not breathe dust/fume/gas/mist/ Manufacturer/supplier or the competent authority to specify applicable conditions. P264 …thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P307 + P311 IF exposed: Call a or doctor/physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate measures are required. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified). SPECIFIC TARGET ORGAN TOXICITY (Single Exposure) Symbol Health hazard Hazard category Signal word Hazard statement 2 Warning H371 May cause damage to organs <...> <<...>> <...> (or state all organs affected, if known) <<...>> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Precautionary statements Prevention Response Storage Disposal