P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P230 Keep wetted with... …Manufacturer/supplier or the competent authority to specify appropriate material. - if drying out increases explosion hazard, except as needed for manufacturing or operating processes (e.g. nitrocellulose). P240 Ground/bond container and receiving equipment. - if the explosive is electrostatically sensitive. P250 Do not subject to grinding/shock/…/friction. …Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 +P380 In case of fire: evacuate area. P372 Explosion risk in case of fire. P373 DO NOT fire when fire reaches explosives. P401 Store ... …in accordance with Regulations (to be specified). P501 Dispose of contents/container to... …in accordance with local/ Regulations (to be specified). EXPLOSIVES Symbol Exploding bomb Hazard category Signal word Hazard statement Division 1.4 Warning H204 Fire or projection hazard Precautionary statements Prevention Response Storage Disposal
Liquefied gas Warning H280 Contains gas under pressure; may explode if heated Dissolved gas Warning H280 Contains gas under pressure; may explode if heated Precautionary statements Prevention Response Storage Disposal P410 + P403 Protect from sunlight. Store in a place. UNDER PRESSURE Symbol Gas cylinder Hazard category Signal word Hazard statement Refrigerated liquefied gas Warning H281 Contains refrigerated gas; may cause cryogenic burns or injury Precautionary statements Prevention Response Storage Disposal P282 Wear cold insulating gloves/face shield/eye protection. P336 Thaw frosted parts with lukewarm water. Do not rub affected area. P315 Get immediate medical advice/attention P403 in well-ventilated place. FLAMMABLE LIQUIDS Symbol Hazard category Signal word Hazard statement 1 Danger H224 Extremely flammable liquid and vapour 2 Danger H225 Highly flammable liquid and vapour 3 Warning H226 Flammable liquid and vapour
P210 Keep away from flames and hot surfaces. – No smoking. P280 Wear protective gloves/eye protection/face protection Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/supplier or the competent authority to specify appropriate media. if water increases risk. P403 + P235 Store in a place. Keep cool. P501 Dispose of contents/container to... in accordance with national/international Regulations (to be specified). FLAMMABLE SOLIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H228 Flammable solid 2 Warning H228 Flammable solid Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 away from materials. ... Manufacturer/supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. P403 + P235 Store in a place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/container to... … in accordance with Regulations (to be specified). SELF-REACTIVE SUBSTANCES AND MIXTURES Symbol Exploding bomb and flame Hazard category Signal word Hazard statement Type B Danger H241 Heating may a fire or explosion Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from materials. …Manufacturer/supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P403 + P235 Store in a place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ...Manufacturer/supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/container to... …in accordance with Regulations (to be specified). Note: Hazard category Type G: There are no label elements allocated to this hazard category PYROPHORIC LIQUIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H250 Catches fire spontaneously if exposed to air Precautionary statements Prevention Response Storage Disposal
P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition sources(s). P222 Do not allow contact with air. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P334 IF ON SKIN: Immerse in cool water/wrap with wet bandages P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P422 Store contents under . ... Manufacturer/supplier or the competent authority to specify appropriate liquid or inert gas. PYROPHORIC SOLIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H250 Catches fire spontaneously if exposed to air Precautionary statements Prevention Response Storage Disposal
P235 + P410 Keep cool. Protect from sunlight. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P407 Maintain air gap between stacks/pallets. P413 bulk masses greater than … kg/…lbs at temperatures not exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify mass and temperature. P420 away from other materials. SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES Symbol Flame Hazard category Signal word Hazard statement 1 Danger H260 In contact with water releases flammable gases, which may ignite spontaneously 2 Danger H261 In contact with water releases flammable gases Precautionary statements Prevention Response Storage Disposal P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232 Handle under inert gas. Protect from moisture. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent P335 + P334 Brush off loose particles from skin and immerse in cool water/wrap in wet bandages. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P402 + P404 Store in a dry place. Store in a closed container. P501 Dispose of contents/container to... …in accordance with local/regional/national/ international Regulations (to be specified).
authority to specify type of equipment. SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES Symbol Flame Hazard category Signal word Hazard statement 3 Warning H261 In contact with water releases flammable gases Precautionary statements Prevention Response Storage Disposal P231 + P232 Handle under inert gas. Protect from moisture. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction. ...Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P402 + P404 in a dry place. Store in a closed container. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified).
OXIDISING LIQUIDS Symbol Flame over circle Hazard category Signal word Hazard statement 1 Danger H271 May cause fire or explosion; strong oxidiser Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat. P220 away from clothing and other combustible materials. P221 Take any precaution to avoid mixing with combustibles/... ... Manufacturer/supplier or the competent authority to specify other incompatible materials. P280 Wear protective gloves /eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P283 Wear fire/flame resistant/retardant clothing. P306 + P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P501 Dispose of contents/container to... …in accordance with local/regional/ national/international Regulations (to be specified). OXIDISING LIQUIDS Symbol Flame over circle Hazard category Signal word Hazard statement 2 Danger H272 May intensify fire; oxidiser 3 Warning H272 May intensify fire; oxidiser
P210 Keep away from heat. P220 Keep away from clothing and other combustible materials. P221 Take any precaution to mixing with combustibles/... …Manufacturer/supplier or the competent authority to specify other incompatible materials. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P283 Wear fire/flame resistant/retardant clothing. P306 + P360 IF ON CLOTHING: immediately contaminated clothing and skin with plenty of water before removing clothes. P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P501 Dispose of contents/container to... …in accordance with local/regional/ national/international Regulations (to be specified). OXIDISING SOLIDS Symbol Flame over circle Hazard category Signal word Hazard statement 2 Danger H272 May intensify fire; oxidiser 3 Warning H272 May intensify fire; oxidiser Precautionary statements Prevention Response Storage Disposal
P234 Keep only in original container. P390 Absorb spillage to prevent material damage. P406 Store in corrosive resistant/... container with a resistant inner liner. ... Manufacturer/supplier or the competent authority to specify other compatible materials. ACUTE TOXICITY - ORAL Symbol Skull and crossbones Hazard category Signal word Hazard statement 1 Danger H300 Fatal if swallowed 2 Danger H300 Fatal if swallowed Precautionary statements Prevention Response Storage Disposal P264 Wash …thoroughly handling. … Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate administration of antidote is required. P330 mouth. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). ACUTE TOXICITY – ORAL Symbol and crossbones Hazard category Signal word Hazard statement 3 Danger H301 Toxic if swallowed Precautionary statements Prevention Response Storage Disposal
P264 Wash … thoroughly after handling. … Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate administration of antidote is required. P330 Rinse mouth. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). ACUTE TOXICITY – ORAL Symbol Exclamation mark Hazard category Signal word Hazard statement 4 Warning H302 Harmful if swallowed Precautionary statements Prevention Response Storage Disposal P264 Wash … thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). ACUTE TOXICITY - DERMAL Symbol Skull and crossbones Hazard category Signal word Hazard statement
P280 Wear protective gloves/protective clothing. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTRE or doctor/physician if you feel unwell. P322 Specific measures (see ... on this label) ... Reference to supplemental first aid instruction. - if measures such as specific cleansing agent is advised. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). ACUTE TOXICITY – DERMAL Symbol Exclamation mark Hazard category Signal word Hazard statement 4 Warning H312 Harmful in contact with skin Precautionary statements Prevention Response Storage Disposal
P260 Do not breathe dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P284 Wear respiratory protection. Manufacturer/supplier or the competent authority to specify equipment. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 Immediately call a POISON CENTER or doctor/physician. P320 Specific treatment is urgent (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate administration of antidote is required. P403 + P233 Store in a place. Keep container tightly closed. - if product is volatile as to generate hazardous atmosphere. P405 locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified). ACUTE TOXICITY - INHALATION Symbol Skull and crossbones Hazard category Signal word Hazard statement 3 Danger H331 Toxic if inhaled Precautionary statements Prevention Response Storage Disposal P261 breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P311 Call a POISON CENTER or doctor/physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate specific measures are required. P403 + P233 in a place. Keep container tightly closed. - if product is volatile so as to generate hazardous atmosphere. P405 Store locked up. P501 Dispose of content/container to… … in accordance with Regulations (to be specified).
ACUTE TOXICITY - INHALATION Symbol Exclamation mark Hazard category Signal word Hazard statement 4 Warning H332 Harmful if inhaled Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P304 + P340 IF INHALED: Remove victim to air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. SKIN CORROSION/IRRITATION Symbol Corrosion Hazard category Signal word Hazard statement 1A to 1C Danger H314 Causes severe skin burns and eye damage Precautionary statements Prevention Response Storage Disposal P260 Do not breathe or mists. - if inhalable particles of dusts or mists may occur during use. P264 Wash …thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303 + P361 + P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. skin with water/shower. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
P260 Do not breathe dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P264 Wash … thoroughly handling. … Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, or smoke when using this product. P309 + P311 IF exposed or if you feel unwell: Call a POISON CENTER or doctor/physician. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified). SPECIFIC TARGET ORGAN TOXICITY (Single Exposure) Symbol Exclamation mark Hazard category Signal word Hazard statement 3 Warning H335 May cause respiratory irritation; or H336 May cause drowsiness or dizziness Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P403 + P233 Store in a place. Keep container tightly closed. - if product is volatile so as to generate hazardous atmosphere. P405 locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
SPECIFIC TARGET TOXICITY (Repeated Exposure) Symbol Health hazard Hazard category Signal word Hazard statement 1 Danger H372 Causes damage to organs <...> through prolonged or repeated exposure <<...>> <...> (state all organs affected, if known) <<...>> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Precautionary statements Prevention Response Storage Disposal P260 Do not breathe dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P264 Wash … thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P314 Get medical advice/attention if you feel unwell. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified). SPECIFIC TARGET ORGAN TOXICITY (Repeated Exposure) Symbol Health hazard Hazard category Signal word Hazard statement 2 Warning H373 May cause damage to organs <...> through prolonged or repeated exposure <<...>>
Fire protection General AS/NZS 1221:1997 Fire hose reels AS 1603 part 1-17 Automatic fire detection and alarm systems AS 1670 part 1-6 Fire detection, warning, control and intercom systems – System design, installation and commissioning AS 1851 Set:2005 Maintenance of fire protection equipment AS 2118 part 1-9 Automatic fire sprinkler installations AS 2419 part 1-3 Fire hydrant installations AS 2441:2005 Installation of fire hose AS 2941:2008 Fixed fire protection installations – Pump set systems Fire prevention AS/NZS 1020:1995 Control of undesirable static electricity AS/NZS 1768:2007 Lightning protection AS 2359.12:1996 Powered industrial trucks – Hazardous areas Fire Extinguishers AS/NZS 1841 Set: 2007 Portable fire extinguishers AS/NZS 1850:2009 Portable fire extinguishers – Classification, rating and performance testing AS 2444:2001 Portable fire extinguishers and fire blankets – Selection and location AS 4265:1995 Wheeled fire extinguishers Industry or particular situation AS 2243 part 1-10 Safety in laboratories AS 2507:1998 The storage and handling of agricultural and veterinary chemicals AS/NZS 2865:2009 Safe working in a confined space AS/NZS 2982: 2010 Laboratory design and construction AS 3846:2005 The handling and transport of dangerous cargoes in port areas AS 4041:2006 Pressure piping AS/NZS 4114.1 2003 Spray painting booths – design, construction and testing Personal protective equipment (PPE) AS/NZS 1336:1997 Recommended practices for occupational eye protection AS/NZS 1337 part 1-6 Eye protectors for industrial applications AS/NZS 1715:2009 Selection, use and maintenance of respiratory protective devices AS/NZS 1716:2003 Respiratory protective devices AS/NZS 2161 Set: 2008 Occupational protective gloves AS/NZS 2210.1:2010 Safety, protective and occupational footwear - to selection, care and use