EXPLOSIVES Symbol Exploding bomb Hazard category Signal word Hazard statement Unstable Explosive Danger H200 Unstable Explosive Precautionary statements Prevention Response Storage Disposal P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P281 Use personal protective equipment as required. P372 Explosion risk in case of fire. P373 DO NOT fight fire when fire reaches explosives. P380 Evacuate area. P401 Store ... …in accordance with local/regional/ national/international Regulations (to be specified). P501 Dispose of contents/container to... …in accordance with local/regional/ national/international Regulations (to be specified).
Symbol Exploding bomb Hazard category Signal word Hazard statement Division 1.4 Warning H204 Fire or projection hazard Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P240 Ground/bond container and receiving equipment. - if the explosive is electrostatically sensitive. P250 Do not subject to Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear face protection. Manufacturer/supplier or competent authority to specify type of equipment. P370+P380 In case of fire: Evacuate area. P372 Explosion risk in case of fire. - except if explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P373 DO NOT fight fire when fire reaches explosives. P374 Fight fire with normal precautions from a reasonable distance. - If explosives are 1.4S AMMUNITION AND COMPONENTS THEREOF. P401 Store ... …in accordance with local/regional/ national/international Regulations (to be specified). P501 Dispose of contents/container to... … in accordance with Regulations (to be specified).
EXPLOSIVES Symbol* Hazard category Signal word Hazard statement Division 1.5 Danger H205 May mass explode in fire Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P230 Keep wetted with... …Manufacturer/supplier or the competent authority to specify appropriate material. - if drying out increases explosion hazard, except as needed for manufacturing or operating processes (e.g. nitrocellulose). P240 Ground/bond container and receiving equipment - if the explosive is electrostatically sensitive. P250 Do not subject to …Manufacturer/supplier or the competent authority to specify applicable rough handling. P280 Wear face protection. Manufacturer/supplier or competent authority to specify type of equipment. P370 + P380 In case of fire: Evacuate area. P372 Explosion risk in case of fire. P373 DO NOT fight fire when fire reaches explosives. P401 Store ... …in accordance with local/regional/ national/international Regulations (to be specified). P501 Dispose of contents/container to... … in accordance with local/regional/ national/international Regulations (to be specified). *Note: This symbol is according to the ADG Code for the transport of dangerous goods
FLAMMABLE SOLIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H228 Flammable solid 2 Warning H228 Flammable solid Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P240 Ground/Bond container and receiving equipment. - if electrostatically sensitive material is for reloading. P241 Use explosion-proof electrical/ventilating/ lighting/... /equipment. ... Manufacturer/supplier or the competent authority to specify other equipment. - if dust clouds can occur. P280 Wear protective gloves/eye protection/face protection Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ...Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk.
SELF-REACTIVE SUBSTANCES AND MIXTURES Symbol Exploding bomb and flame Hazard category Signal word Hazard statement Type B Danger H241 Heating may cause a fire or explosion Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from materials. ... Manufacturer/supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P370 + P380 + P375 In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion. P403 + P235 Store in a place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/container to... …in accordance with Regulations (to be specified).
SELF-REACTIVE SUBSTANCES AND MIXTURES Symbol Flame Hazard category Signal word Hazard statement Type C Danger H242 Heating may cause a fire Type D Danger H242 Heating may cause a fire Type E Warning H242 Heating may cause a fire Type F Warning H242 Heating may cause a fire Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep/Store away from materials. …Manufacturer/supplier or the competent authority to specify other incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P403 + P235 Store in a place. Keep cool. P411 Store at temperatures not exceeding …°C/…°F. ...Manufacturer/supplier or the competent authority to specify temperature. P420 Store away from other materials. P501 Dispose of contents/container to... …in accordance with Regulations (to be specified). Note: Hazard category Type G: There are no label elements allocated to this hazard category
PYROPHORIC LIQUIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H250 Catches fire spontaneously if exposed to air Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition sources(s). P222 Do not allow contact with air. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P334 IF ON SKIN: Immerse in cool water/wrap with wet bandages P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P422 Store contents under... ... Manufacturer/supplier or the competent authority to specify appropriate liquid or inert gas. PYROPHORIC SOLIDS Symbol Flame Hazard category Signal word Hazard statement 1 Danger H250 Catches fire spontaneously if exposed to air Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or P335 + P334 Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages. P422 Store contents under... …Manufacturer/supplier or the competent authority to specify
the competent authority to specify applicable ignition source(s). P222 Do not allow contact with air. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. appropriate liquid or inert gas. SELF-HEATING SUBSTANCES AND MIXTURES Symbol Flame Hazard category Signal word Hazard statement 1 Danger H251 Self-heating; may catch fire 2 Warning H252 Self-heating in large quantities; may catch fire Precautionary statements Prevention Response Storage Disposal P235 + P410 Keep cool. Protect from sunlight. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P407 Maintain air gap between stacks/pallets. P413 Store bulk masses greater than … kg/…lbs at temperatures not exceeding …°C/…°F. ... Manufacturer/supplier or the competent authority to specify mass and temperature. P420 Store away from other materials.
SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES Symbol Flame Hazard category Signal word Hazard statement 1 Danger H260 In contact with water releases flammable gases, which may ignite spontaneously 2 Danger H261 In contact with water releases flammable gases Precautionary statements Prevention Response Storage Disposal P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. P231 + P232 Handle under inert gas. Protect from moisture. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P335 + P334 Brush off loose particles from skin and immerse in cool water/wrap in wet bandages. P370 + P378 In case of fire: Use ... for extinction ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P402 + P404 Store in a dry place. Store in a closed container. P501 Dispose of contents/container to... …in accordance with local/regional/national/ international Regulations (to be specified). SUBSTANCES AND MIXTURES WHICH, IN CONTACT WITH WATER, EMIT FLAMMABLE GASES Symbol Flame Hazard category Signal word Hazard statement 3 Warning H261 In contact with water releases flammable gases Precautionary statements Prevention Response Storage Disposal
P231 + P232 Handle under inert gas. Protect from moisture. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P370 + P378 In case of fire: Use ... for extinction. ...Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P402 + P404 Store in a dry place. Store in a closed container. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). OXIDISING LIQUIDS Symbol Flame over circle Hazard category Signal word Hazard statement 1 Danger H271 May cause fire or explosion; strong oxidiser Precautionary statements Prevention Response Storage Disposal
OXIDISING SOLIDS Symbol Flame over circle Hazard category Signal word Hazard statement 1 Danger H271 May cause fire or explosion; strong oxidiser Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat. P220 Keep away from clothing and other combustible materials. P221 Take any precaution to avoid mixing with combustibles/... …Manufacturer/supplier or the competent authority to specify other incompatible materials. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P283 Wear fire/flame resistant/retardant clothing. P306 + P360 IF ON CLOTHING: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes. P371 + P380 + P375 In case of major fire and large quantities: Evacuate area. Fight fire remotely due to the risk of explosion. P370 + P378 In case of fire: Use ... for extinction. ... Manufacturer/supplier or the competent authority to specify appropriate media. - if water increases risk. P501 Dispose of contents/container to... …in accordance with local/regional/ national/international Regulations (to be specified).
ORGANIC PEROXIDES Symbol Exploding bomb and flame Hazard category Signal word Hazard statement Type B Danger H241 Heating may cause a fire or explosion Precautionary statements Prevention Response Storage Disposal P210 Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Manufacturer/supplier or the competent authority to specify applicable ignition source(s). P220 Keep /Store away from materials. ... Manufacturer/supplier or the competent authority to specify incompatible materials. P234 Keep only in original container. P280 Wear protective gloves/eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P411 + P235 Store at temperatures not exceeding …°C/…°F. Keep cool. Manufacturer/supplier or the competent authority to specify temperature. P410 Protect from sunlight. P420 Store away from other materials. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
Rinse mouth. ACUTE TOXICITY – ORAL Symbol Skull and crossbones Hazard category Signal word Hazard statement 3 Danger H301 Toxic if swallowed Precautionary statements Prevention Response Storage Disposal P264 Wash … thoroughly after handling. … Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate administration of antidote is required. P330 Rinse mouth. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified).
ACUTE TOXICITY – ORAL Symbol Exclamation mark Hazard category Signal word Hazard statement 4 Warning H302 Harmful if swallowed Precautionary statements Prevention Response Storage Disposal P264 Wash … thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. P330 Rinse mouth. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified).
ACUTE TOXICITY - DERMAL Symbol Skull and crossbones Hazard category Signal word Hazard statement 1 Danger H310 Fatal in contact with skin 2 Danger H310 Fatal in contact with skin Precautionary statements Prevention Response Storage Disposal P262 Do not get in eyes, on skin, or on clothing. P264 Wash … thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P280 Wear protective gloves/protective clothing. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P350 IF ON SKIN: Gently wash with plenty of soap and water. P310 Immediately call a POISON CENTRE or doctor/physician. P322 Specific measures (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate measures such as specific cleansing agent is advised. P361 Remove/Take off immediately all contaminated clothing. P363 Wash contaminated clothing before reuse. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified).
ACUTE TOXICITY – DERMAL Symbol Exclamation mark Hazard category Signal word Hazard statement 4 Warning H312 Harmful in contact with skin Precautionary statements Prevention Response Storage Disposal P280 Wear protective gloves/protective clothing Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P312 Call a POISON CENTER or doctor/physician if you feel unwell. P322 Specific measures (see ... on this label) ... Reference to supplemental first aid instruction. - if measures such as specific cleansing agent is advised. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified).
ACUTE TOXICITY - INHALATION Symbol Skull and crossbones Hazard category Signal word Hazard statement 1 Danger H330 Fatal if inhaled 2 Danger H330 Fatal if inhaled Precautionary statements Prevention Response Storage Disposal P260 Do not breathe dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P271 Use only outdoors or in a well-ventilated area. P284 Wear respiratory protection. Manufacturer/supplier or the competent authority to specify equipment. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P310 Immediately call a POISON CENTER or doctor/physician. P320 Specific treatment is urgent (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate administration of antidote is required. P403 + P233 Store in a place. Keep container tightly closed. - if product is volatile as to generate hazardous atmosphere. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with local/regional/national/international Regulations (to be specified). ACUTE TOXICITY - INHALATION Symbol Skull and crossbones Hazard category Signal word Hazard statement 3 Danger H331 Toxic if inhaled Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. P304 + P340 IF INHALED: Remove victim to fresh air and keep at rest in a P403 + P233 Store in a place. Keep container tightly P501 Dispose of contents/container to…
SKIN CORROSION/IRRITATION Symbol Exclamation mark Hazard category Signal word Hazard statement 2 Warning H315 Causes skin irritation Precautionary statements Prevention Response Storage Disposal P264 Wash … thoroughly after handling. … Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P280 Wear protective gloves. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - Manufacturer/supplier or the competent authority may specify a cleansing agent if appropriate. P332 + P313 If skin irritation occurs: Get medical advice/attention. P362 Take off contaminated clothing and wash before reuse.
P264 Wash … thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P280 Wear eye protection/face protection. Manufacturer/supplier or the competent authority to specify type of equipment. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical advice/attention. SENSITISATION – RESPIRATORY Symbol Health hazard Hazard category Signal word Hazard statement 1, 1A, 1B Danger H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P285 In case of inadequate ventilation wear respiratory protection. Manufacturer/supplier or the competent authority to specify equipment P304 + P341 IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. P342 + P311 If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
SENSITISATION – SKIN Symbol Exclamation mark Hazard category Signal word Hazard statement 1, 1A, 1B Warning H317 May cause an allergic skin reaction Precautionary statements Prevention Response Storage Disposal P261 Avoid breathing dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P272 Contaminated work clothing should not be allowed out of the workplace. P280 Wear protective gloves. Manufacturer/supplier or the competent authority to specify type of equipment. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P333 + P313 If skin irritation or rash occurs: Get medical advice/attention. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - Manufacturer/supplier or the competent authority may specify a cleansing agent if appropriate. P363 Wash contaminated clothing before reuse. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
SPECIFIC TARGET ORGAN TOXICITY (Single Exposure) Symbol Health hazard Hazard category Signal word Hazard statement 1 Danger H370 Causes damage to organs <...> <<...>> <...> (or state all organs affected if known) <<...>> (state route of exposure if it is conclusively proven that no other routes of exposure cause the hazard) Precautionary statements Prevention Response Storage Disposal P260 Do not breathe dust/fume/gas/mist/ vapours/spray. Manufacturer/supplier or the competent authority to specify applicable conditions. P264 Wash …thoroughly after handling. …Manufacturer/supplier or the competent authority to specify parts of the body to be washed after handling. P270 Do not eat, drink or smoke when using this product. P307 + P311 IF exposed: Call a POISON CENTER or doctor/physician. P321 Specific treatment (see ... on this label) ... Reference to supplemental first aid instruction. - if immediate measures are required. P405 Store locked up. P501 Dispose of contents/container to... ... in accordance with Regulations (to be specified).
precedence rules described in Appendix E, the exclamation mark hazard pictogram and ‘Warning’ signal word have been omitted and duplicate precautionary statements have not been included. Read label before use. Keep out of reach of children Flammosol FLAMMABLE LIQUID, TOXIC N.O.S. (aliphatic hydrocarbons, toxicole) UN 1992 Contains: Aliphatic hydrocarbons 95% Toxicole 5% 4 L DANGER Highly flammable liquid and vapour Toxic if swallowed Causes skin irritation IF ON SKIN (or hair): Take off contaminated clothing and wash before re-use. In case of fire: Use powder for extinction. Rinse skin using plenty of soap and water. Keep away from sparks and open flames. – No smoking. If skin irritation occurs: Get medical advice/attention. Keep container tightly closed. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Ground/bond container and receiving equipment. Rinse mouth. Use explosion-proof electrical equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Store locked up in a well-ventilated place. Keep cool. Wear protective gloves and eye and face protection. Wash hands thoroughly after handling. Dispose of contents/container in accordance with Jurisdictional regulations. Do not eat, drink or smoke when using this product. Refer to the Safety Data Sheet before use. Madeup Chemical Company, 999 Chemical Street, Chemical Town, My State. Telephone: 1300 000 000 www.madeup-chemical-company.com.au