TemperatureModulated Micromechanical Thermal Analysis with Microstring Resonators Detects Multiple Coherent Features of Small Molecule Glass Transition Micromechanical Thermal Analysis utilizes microstring resonators to analyze a minimum amount of sample to obtain both the thermal and mechanical responses of the sample during a heating ramp. We introduce a modulated setup by superimposing a sinusoidal heating on the linear heating and implementing a postmeasurement data deconvolution process. This setup is utilized to take a closer look at the glass transition as an important fundamental feature of amorphous matter with relations to the processing and physical stability of small molecule drugs. With an additionally developed image and qualitative mode shape analysis, we are able to separate distinct features of the glass transition process and explain a previously observed twofold change in resonance frequency. The results from this setup indicate the detection of initial relaxation to viscous flow onset as well as differences in mode responsivity and possible changes in the primary resonance mode of the string resonators. The modulated setup is helpful to distinguish these processes during the glass transition with varying responses in the frequency and quality factor domain and offers a more robust way to detect the glass transition compared to previously developed methods. Furthermore, practical and theoretical considerations are discussed when performing measurements on string resonators (and comparable emerging analytical techniques) for physicochemical characterization.

Thermal Stability of Type II Modifications by IR Femtosecond Laser in Silicabased Glasses Femtosecond (fs) laser written fiber Bragg gratings (FBGs) are excellent candidates for ultrahigh temperature (u003e800 oC) monitoring. More specifically, Type II modifications in silicate glass fibers, characterized by the formation of selforganized birefringent nanostructures, are known to exhibit remarkable thermal stability around 1000 oC for several hours. However, to date there is no clear understanding on how both laser writing parameters and glass composition impact the overall thermal stability of these fiberbased sensors. In this context, this work investigates thermal stability of Type II modifications in various conventional glass systems (including pure silica glasses with various Cl and OH contents, GeO2SiO2 binary glasses, TiO2 and B2O3doped commercial glasses) and with varying laser parameters (writing speed, pulse energy). In order to monitor thermal stability, isochronal annealing experiments (xcex94txe2x81x93 30 min, xcex94Txe2x81x93 50 oC) up to 1400 oC were performed on the irradiated samples, along with quantitative retardance measurements. Among the findings to highlight, it was established that ppm levels of Cl and OH can drastically reduce thermal stability (by about 200 oC in this study). Moreover, GeO2 doping up to 17 mole% only has a limited impact on thermal stability. Finally, the relationships between glass viscosity, dopantsimpurities, and thermal stability, are discussed.