Diphosphorus
Diphosphorus is an inorganic chemical with the chemical formula . Unlike nitrogen, its lighter pnictogen neighbor which forms a stable N molecule with a nitrogen to nitrogen triple bond, phosphorus prefers a tetrahedral form P because P-P pi-bonds are high in energy. Diphosphorus is, therefore, very reactive with a bond-dissociation energy (117 kcal/mol or 490 kJ/mol) half that of dinitrogen. The bond distance has been measured at 1.8934 Å. Synthesis. Diphosphorus has been generated by heating white phosphorus at 1100 kelvins (827 °C). Nevertheless, some advancements have been obtained in generating the diatomic molecule  in homogeneous solution under normal conditions with the use of some transition metal complexes (based on, for example, tungsten and niobium). Methods for dissociation of bonds in P molecules via photoexcitation were also proposed. The molecule attracted attention in 2006, when a new method for its synthesis at milder temperatures emerged. This method is a variation on nitrogen expulsion in azides with formation of a nitrene. The synthesis of the diphosphorus precursor consists of reacting a terminal niobium phosphide with a chloroiminophosphane: Heating this compound at 50 °C in 1,3-cyclohexadiene serving as a solvent and as a trapping  reagent expels diphosphorus, which is reactive, as the end products are a double Diels–Alder adduct and the niobium imido compound: The same imido compound also forms when the thermolysis is performed in toluene, but in this case the fate of the diphosphorus is unknown. P has been suggested to form as an intermediate in the photolysis of P, and in the presence of 2,3-dimethyl-1,3-butadiene the diphosphane resulting from Diels–Alder addition is again formed. To date, no direct evidence of P formation via P photolysis exists. The generation of diphosphorus from a diphosphorus bisanthracene adduct has been  reported. The synthesis of a stabilized HP cation has been reported.