Dithiin
Dithiin is a class of heterocyclic compounds, with the parent members having the formula (CH)S. Two isomers of this parent are recognized, 1,2- and 1,4-dithiins. Planar dithiins are 8π e systems and thus antiaromatic. Akin to the behavior of cyclooctatetraene adopts nonplanar structures. Vinyldithiin, a common component of garlic, is a misnomer for 3-vinyl-4"H"-1,2-dithiin. 1,3-dithiins are unknown. 1,4-Dithiins. 1,4-Dithiins have been more extensively studied. They are usually prepared by condensation of the equivalent of α-mercaptocarbonyls. For example, the acetal HSCHCH(OEt) converts upon heating to the parent 1,4-dithiin. They are nonplanar and  can be oxidized to their radical cations. Photolysis leads to dimerization via a [2+2] cycloaddition. Thianthrene is dibenzo-1,4-dithiin. 1,2-Dithiins. 1,2-Dithiins are isomers of but-2-ene-dithials. They tend to be unstable with respect to loss of sulfur and formation of the thiophene derivative: They are often claret-colored. Some occur as flower pigments in plants of the family Asteraceae.