6-j symbol
Wigner's 6-"j" symbols were introduced by Eugene Paul Wigner in 1940 and published in 1965. They are defined as a sum over products of four Wigner 3-j symbols, The summation is over all six allowed by the selection rules of the 3-"j" symbols. They are closely related to the Racah W-coefficients, which are used for recoupling 3 angular momenta, although Wigner 6-"j" symbols have higher symmetry and therefore provide a more efficient means of storing the recoupling coefficients. Their relationship is given by: Symmetry relations. The 6-"j" symbol is invariant under any permutation of  the columns: The 6-"j" symbol is also invariant if upper and lower arguments are interchanged in any two columns: These equations reflect the 24 symmetry operations of the automorphism group that leave the associated tetrahedral Yutsis graph with 6 edges invariant: mirror operations that exchange two vertices and a swap an adjacent pair of edges. The 6-"j" symbol is zero unless "j", "j", and "j" satisfy triangle conditions, i.e., In combination with the symmetry relation for interchanging upper and lower arguments this shows that triangle conditions must also be satisfied for the triads ("j", "j", "j"), ("j", "j", "j"), and  ("j", "j", "j"). Furthermore, the sum of each of the elements of a triad must be an integer. Therefore, the members of each triad are either all integers or contain one integer and two half-integers. Special case. When "j" = 0 the expression for the 6-"j" symbol is: The "triangular delta" is equal to 1 when the triad ("j", "j", "j") satisfies the triangle conditions, and zero otherwise. The symmetry relations can be used to find the expression when another "j" is equal to zero. Orthogonality relation. The 6-"j" symbols satisfy this orthogonality relation: Asymptotics. A remarkable formula for  the asymptotic behavior of the 6-"j" symbol was first conjectured by Ponzano and Regge and later proven by Roberts. The asymptotic formula applies when all six quantum numbers "j", ..., "j" are taken to be large and associates to the 6-"j" symbol the geometry of a tetrahedron. If the 6-"j" symbol is determined by the quantum numbers "j", ..., "j" the associated tetrahedron has edge lengths "J" = "j"+1/2 (i=1...,6) and the asymptotic formula is given by, The notation is as follows: Each θ is the external dihedral angle about the edge "J" of the associated tetrahedron and the amplitude factor  is expressed in terms of the volume, "V", of this tetrahedron. Mathematical interpretation. In representation theory, 6-"j" symbols are matrix coefficients of the associator isomorphism in a tensor category. For example, if we are given three representations "V", "V", "V" of a group (or quantum group), one has a natural isomorphism of tensor product representations, induced by coassociativity of the corresponding bialgebra. One of the axioms defining a monoidal category is that associators satisfy a pentagon identity, which is equivalent to the Biedenharn-Elliot identity for 6-"j" symbols. When a monoidal category is semisimple, we can restrict our attention to  irreducible objects, and define multiplicity spaces so that tensor products are decomposed as: where the sum is over all isomorphism classes of irreducible objects. Then: The associativity isomorphism induces a vector space isomorphism and the 6j symbols are defined as the component maps: When the multiplicity spaces have canonical basis elements and dimension at most one (as in the case of "SU"(2) in the traditional setting), these component maps can be interpreted as numbers, and the 6-"j" symbols become ordinary matrix coefficients. In abstract terms, the 6-"j" symbols are precisely the information that is lost when passing from a semisimple  monoidal category to its Grothendieck ring, since one can reconstruct a monoidal structure using the associator. For the case of representations of a finite group, it is well-known that the character table alone (which determines the underlying abelian category and the Grothendieck ring structure) does not determine a group up to isomorphism, while the symmetric monoidal category structure does, by Tannaka-Krein duality. In particular, the two nonabelian groups of order 8 have equivalent abelian categories of representations and isomorphic Grothdendieck rings, but the 6-"j" symbols of their representation categories are distinct, meaning their representation categories are inequivalent as  monoidal categories. Thus, the 6-"j" symbols give an intermediate level of information, that in fact uniquely determines the groups in many cases, such as when the group is odd order or simple.