Sulfur hexafluoride
Sulfur hexafluoride (SF) or sulphur hexafluoride (British spelling) is an extremely potent and persistent greenhouse gas that is primarily utilized as an electrical insulator and arc suppressant. It is inorganic, colorless, odorless, non-flammable, and non-toxic. has an octahedral geometry, consisting of six fluorine atoms attached to a central sulfur atom. It is a hypervalent molecule. Typical for a nonpolar gas, is poorly soluble in water but quite soluble in nonpolar organic solvents. It has a density of 6.12 g/L at sea level conditions, considerably higher than the density of air (1.225 g/L). It is  generally transported as a liquefied compressed gas. The concentration of in Earth's troposphere reached 10.63 parts per trillion (ppt) in 2021, rising at 0.36 ppt/year. The increase over the prior 40 years was driven in large part by the expanding electric power sector, including fugitive emissions from banks of gas contained in its medium- and high-voltage switchgear. Uses in magnesium, aluminium, and electronics manufacturing also hastened atmospheric growth. Synthesis and reactions. Sulfur hexafluoride on Earth exists primarily as a man-made industrial gas and has also been found to occur naturally. Alternatively, utilizing bromine, sulfur hexafluoride can  be synthesized from SF and CoF at lower temperatures (e.g. 100 °C), as follows: There is virtually no reaction chemistry for . A main contribution to the inertness of SF is the steric hindrance of the sulfur atom, whereas its heavier group 16 counterparts, such as SeF are more reactive than SF as a result of less steric hindrance (See hydrolysis example). It does not react with molten sodium below its boiling point, but reacts exothermically with lithium. Applications. The electrical power industry used about 80% of the sulfur hexafluoride produced in 2000, mostly as a gaseous dielectric medium. Other  main uses as of 2015 included a silicon etchant for semiconductor manufacturing, and an inert gas for the casting of magnesium. Dielectric medium. is used in the electrical industry as a gaseous dielectric medium for high-voltage sulfur hexafluoride circuit breakers, switchgear, and other electrical equipment, often replacing oil-filled circuit breakers (OCBs) that can contain harmful polychlorinated biphenyls (PCBs). gas under pressure is used as an insulator in gas insulated switchgear (GIS) because it has a much higher dielectric strength than air or dry nitrogen. The high dielectric strength is a result of the gas's high electronegativity and  density. This property makes it possible to significantly reduce the size of electrical gear. This makes GIS more suitable for certain purposes such as indoor placement, as opposed to air-insulated electrical gear, which takes up considerably more room. Gas-insulated electrical gear is also more resistant to the effects of pollution and climate, as well as being more reliable in long-term operation because of its controlled operating environment. Exposure to an arc chemically breaks down though most of the decomposition products tend to quickly re-form , a process termed "self-healing". Arcing or corona can produce disulfur decafluoride  (), a highly toxic gas, with toxicity similar to phosgene. was considered a potential chemical warfare agent in World War II because it does not produce lacrimation or skin irritation, thus providing little warning of exposure. Alternatives to as a dielectric gas include several fluoroketones. Compact GIS technology that combines vacuum switching with clean air insulation has been introduced for a subset of applications up to 420 kV. Medical use. is used to provide a tamponade or plug of a retinal hole in retinal detachment repair operations in the form of a gas bubble. It is inert in the vitreous chamber  and initially doubles its volume in 36 hours before being absorbed in the blood in 10–14 days. Tracer compound. Sulfur hexafluoride was the tracer gas used in the first roadway air dispersion model calibration; this research program was sponsored by the U.S. Environmental Protection Agency and conducted in Sunnyvale, California on U.S. Highway 101. Gaseous is used as a tracer gas in short-term experiments of ventilation efficiency in buildings and indoor enclosures, and for determining infiltration rates. Two major factors recommend its use: its concentration can be measured with satisfactory accuracy at very low concentrations, and the Earth's  atmosphere has a negligible concentration of . Sulfur hexafluoride was used as a non-toxic test gas in an experiment at St John's Wood tube station in London, United Kingdom on 25 March 2007. The gas was released throughout the station, and monitored as it drifted around. The purpose of the experiment, which had been announced earlier in March by the Secretary of State for Transport Douglas Alexander, was to investigate how toxic gas might spread throughout London Underground stations and buildings during a terrorist attack. Sulfur hexafluoride is also routinely used as a tracer gas in laboratory fume hood  containment testing. The gas is used in the final stage of ASHRAE 110 fume hood qualification. A plume of gas is generated inside of the fume hood and a battery of tests are performed while a gas analyzer arranged outside of the hood samples for SF to verify the containment properties of the fume hood. It has been used successfully as a tracer in oceanography to study diapycnal mixing and air-sea gas exchange. Greenhouse gas. According to the Intergovernmental Panel on Climate Change, is the most potent greenhouse gas that has been evaluated, with a global warming potential of  23,900 times that of when compared over a 100-year period. Sulfur hexafluoride is inert in the troposphere and stratosphere and is extremely long-lived, with an estimated atmospheric lifetime of 800–3,200 years. Measurements of SF show that its global average mixing ratio has increased from a steady base of about 54 parts per quadrillion prior to industrialization, to over 10 parts per trillion (ppt) as of April 2020, and is increasing by about 0.35 ppt (3.5 percent) per year. Average global SF concentrations increased by about seven percent per year during the 1980s and 1990s, mostly as the result  of its use in magnesium production, and by electrical utilities and electronics manufacturers. Given the small amounts of SF released compared to carbon dioxide, its overall individual contribution to global warming is estimated to be less than 0.2 percent, however the collective contribution of it and similar man-made halogenated gases has reached about 10 percent as of 2020. Alternatives are being tested. In Europe, falls under the F-Gas directive which ban or control its use for several applications. Since 1 January 2006, is banned as a tracer gas and in all applications except high-voltage switchgear. It was  reported in 2013 that a three-year effort by the United States Department of Energy to identify and fix leaks at its laboratories in the United States such as the Princeton Plasma Physics Laboratory, where the gas is used as a high voltage insulator, had been productive, cutting annual leaks by . This was done by comparing purchases with inventory, assuming the difference was leaked, then locating and fixing the leaks. Physiological effects and precautions. Sulfur hexafluoride is a nontoxic gas, but by displacing oxygen in the lungs, it also carries the risk of asphyxia if too much is inhaled. Since  it is more dense than air, a substantial quantity of gas, when released, will settle in low-lying areas and present a significant risk of asphyxiation if the area is entered. That is particularly relevant to its use as an insulator in electrical equipment since workers may be in trenches or pits below equipment containing . As with all gases, the density of affects the resonance frequencies of the vocal tract, thus changing drastically the vocal sound qualities, or timbre, of those who inhale it. It does not affect the vibrations of the vocal folds. The density of sulfur hexafluoride is  relatively high at room temperature and pressure due to the gas's large molar mass. Unlike helium, which has a molar mass of about 4 g/mol and pitches the voice up, has a molar mass of about 146 g/mol, and the speed of sound through the gas is about 134 m/s at room temperature, pitching the voice down. For comparison, the molar mass of air, which is about 80% nitrogen and 20% oxygen, is approximately 30 g/mol which leads to a speed of sound of 343 m/s. Sulfur hexafluoride has an anesthetic potency slightly lower  than nitrous oxide; it is classified as a mild anesthetic.