Assertion: sulfur | /r/HasProperty | 4 n
Facets:
Source sentences:
text: An important S–N compound is the cage tetrasulfur tetranitride (S 4 N 4 ).
text: S 4 N 4 adopts an unusual “extreme cradle” structure, with D 2d point group symmetry.
text: S 4 N 4 has been shown to co-crystallize with benzene and the C 60 molecule.
text: S 4 N 4 is stable to air.
text: This endothermic enthalpy of formation originates in the difference in energy of S 4 N 4 compared to its highly stable decomposition products:
text: Because one of its decomposition products is a gas, S 4 N 4 can be used as an explosive.
text: S 4 N 4 is thermochromic, changing from pale yellow below −30 °C to orange at room temperature to deep red above 100 °C.
text: 2 Cl 2 → S 4 N 4 + 8 (CH 3 ) 3 SiCl +
text: S 4 N 4 serves as a Lewis base by binding through nitrogen to strongly Lewis acidic compounds such as SbCl 5 and SO 3 .
text: S 4 N 4
text: S 4 N 4 + HBF 4 → [S 4 N 4 H+][BF −
text: 2 S 4 N 4 + 6 OH− +
text: S 4 N 4 + 6 OH− +
text: S 4 N 4 reacts with metal complexes.
text: S 4 N 4 reacts with Vaska's complex ([Ir(Cl)(CO)(PPh 3 ) 2 ] in an oxidative addition reaction to form a six coordinate iridium complex where the S 4 N 4 binds through two sulfur atoms and one nitrogen atom.
text: S 4 N 4 as a precursor to other S-N compounds [ edit ]
text: [S 4 N 5 ]−
text: S 4 N 4 + NMe 4 N 3 → NMe 4 [S 3 N 3 ] + ⅛ S 8 + 2 N 2
text: S 4 N 4 + NMe 4 N 3 → NMe 4 [S 3 N 3 ] + ⅛ S 8 + 2 N 2
text: 2 S 4 N 4 + PPN(N 3 ) → PPN[NS 4 ] + ½ S 8 + 5 N 2
text: S 4 N 4 reacts with electron-poor alkynes.
text: Chlorination of S 4 N 4 gives thiazyl chloride.
text: S 4 N 4 is shock-sensitive.