Assertion: reduction | /r/CapableOf | use phms
Facets:
value: as the hydrosilane
type: OTHER
Source sentences:
text: C147, 5.0 mol %) able to promote the reduction using (EtO) 2 MeSiH or PHMS as the hydrosilane at 40–65 °C leading to the corresponding alcohols in 50–93% ee ( On the other hand, chiral pincer iron complexes have been developed for asymmetric hydrosilylation of ketones.
text: In 2008, Gade reported a [Fe(tetraphenyl-carbpi)(OAc)] complex (, 5.0 mol %) able to promote the reduction using (EtO)MeSiH or PHMS as the hydrosilane at 40–65 °C leading to the corresponding alcohols in 50–93% ee ( Scheme 72 ).