Assertion: hydrogen peroxide's effect | /r/HasProperty | equal
Facets:
value: substantially
type: DEGREE
Source sentences:
text: This larger charge separation is reflected in a lower activation energy and in a higher reactivity for hydrogen abstraction from benzylic alcohols than from aromatic aldehydes, even if the enthalpic effects are substantially equal.
text: The higher reactivity of aliphatic aldehydes compared to aromatic aldehydes is exclusively due to the polar effect because the enthalpic effects are substantially equal (Table 5): alkyls are electron-releasing groups and so increase the contribution of polar forms to the transition states, while aryl groups are electron-withdrawing and decrease the charge separation in the transition state (eq 16).