  Mastery of order-disorder processes in highly non-equilibrium nanostructured
oxides has significant implications for the development of emerging energy
technologies. However, we are presently limited in our ability to quantify and
harness these processes at high spatial, chemical, and temporal resolution,
particularly in extreme environments. Here we describe the percolation of
disorder at the model oxide interface LaMnO$_3$ / SrTiO$_3$, which we visualize
during in situ ion irradiation in the transmission electron microscope. We
observe the formation of a network of disorder during the initial stages of ion
irradiation and track the global progression of the system to full disorder. We
couple these measurements with detailed structural and chemical probes,
examining possible underlying defect mechanisms responsible for this unique
percolative behavior.
