Plastic

[[File:Various plastic products.JPG|thumb|right|165px|Plastic containers]]
{{enviro}}
{{cquote|'''Mr. McGuire''': I just want to say one word to you. Just one word.<BR>
'''Benjamin''': Yes, sir.<BR>
'''Mr. McGuire''': Are you listening?<BR>
'''Benjamin''': Yes, I am.<BR>
'''Mr. McGuire''': Plastics.<BR>
'''Benjamin''': Exactly how do you mean?
'''Mr. McGuire''': There's a great future in plastics. Think about it. Will you think about it? |||''The Graduate'' (1967)<ref>[https://www.imdb.com/title/tt0061722/quotes/?ref_=tt_trv_qu  The Graduate (1967)] ''IMDb''.</ref>}}
'''Plastics''' are polymers of hydrocarbons, with many practical applications in modern society. The first synthetic plastic was produced in 1855 by Alexander Parkes<ref>{{wpa|Celluloid}}</ref> with commercial production not coming until 1889 for the film industry<ref>{{wpa||Nitrocellulose}}</ref> and widespread plastic consumer goods beginning to appear in the early 20<sup>th</sup> century.<ref>{{wpa|Bakelite}}</ref> Most plastics are hard-wearing and durable.<ref>{{wpa|Plastic}}</ref> However, '''plastic pollution''' is a major issue among environmentalists. Plastic is present in a huge variety of products, and much plastic finds its way into the oceans and even into drinking water and the food chain. This leads many people to see {{wpl|plastic pollution}} as an environmental catastrophe requiring urgent action.

There is a movement by people to live plastic-free lives.<ref name=fote>[https://friendsoftheearth.uk/plastics/living-without-plastic Living Without Plastic], Friends of the Earth, accessed 11 Jan 2019</ref> While reducing unnecessary waste is sensible, if taken literally, this can be carried to extremes. Many claims of plastic-free living don't really exclude all plastic, merely calling for reductions — this may be considered sensible or deceptive, depending on your point of view. There are also claims by people or places to be "plastic free", which should be taken with a pinch of salt (preferably packaged in waterproof plastic). Campaigning group Surfers Against Sewage say of their Plastic-Free Communities campaign: "It's not about removing all plastic from our lives. It’s about kicking our addiction to avoidable single-use plastic".<ref name=sas>[https://www.sas.org.uk/plastic-free-communities/ Plastic-Free Communities], Surfers Against Sewage, accessed 11 Jan 2019</ref> Most people will want to balance a desire to save plastic with a desire to avoid other environmental impacts and to avoid debt and bankruptcy. But it isn't always clear where the lines should be drawn.

==Dangers of plastic waste==
===Statistics and types of pollution===
Since plastic became widely used, 8.3 billion metric tonnes has been made and 6.3 billion tons of this has been discarded as waste. About 12% of plastic waste is burned, but the vast majority ends up in landfills, where it can linger for hundreds of years before it decays.<ref>[https://news.nationalgeographic.com/2017/07/plastic-produced-recycling-waste-ocean-trash-debris-environment/ Planet or Plastic: A whopping 91% of plastic isn't recycled], National Geographic, July 2017</ref>

As well as concern about the amount of plastic going to landfills, there is special concern about plastic waste in the oceans, which, rather than sitting in a landfill, drifts around… a lot. 8 million metric tonnes (18 billion lb) of plastic enters the ocean per year.<ref name=natgeo>[https://www.nationalgeographic.com/environment/2018/07/ocean-plastic-pollution-solutions/ A running list of action on plastic pollution], National Geographic, July 2018</ref>

Some of this exists in the form of incredibly huge ocean gyres as big as a country.<ref>{{wpa|Great Pacific garbage patch}}</ref> A study of the Great Pacific Garbage Patch, between Hawaii and California, found that it contained 79,000 metric tonnes, of which 46% was fishing nets and much of the rest other fishing waste; 20% of the debris came from the 2011 Japanese tsunami.<ref name=natgeofishinggear>[https://news.nationalgeographic.com/2018/03/great-pacific-garbage-patch-plastics-environment/ The Great Pacific Garbage Patch Isn’t What You Think it Is], National Geographic, March 2018</ref>

Rubbish enters the marine environment in various ways: discarded directly into sea or into rivers which empty into the sea; from sewers (failure to process/filter); lines, floats, and nets from fishing boats; tsunamis sweeping debris out to sea;<ref name=natgeofishinggear/> lost cargoes that accidentally fall off boats or are scattered by shipwrecks; from landfills which have been scattered or leached out; etc.

In popular environmental arguments, it is common to confuse marine pollution (stuff floating in the sea) and beach pollution (a mix of things beachgoers have dropped and stuff washed up from the sea). Because of the difficulty in measuring pollution, only a small region will generally be studied. Because of this, it is necessary to be careful when extrapolating from an individual study to larger policy recommendations. These conflicting figures are [[Policy-based evidence making|often used for political purposes]]: for instance, if you want to ban plastic bags, go to a beach in the middle of summer and count the plastic, most of which will have been dropped by recent visitors; if you want to foreground pollution from ships, go into the middle of the ocean in winter.

===Effects on humans===
It is suggested that ingesting food containing minute plastic products may be bad for you. A study in Vienna announced in 2018 found evidence of microplastics in human stools, suggesting that plastic was being consumed in food.<ref>[https://www.theguardian.com/environment/2018/oct/22/microplastics-found-in-human-stools-for-the-first-time Microplastics found in human stools for the first time], The Guardian, 22 Oct 2018</ref> Plastic fibres have also been found in drinking water from taps.<ref>[https://www.theguardian.com/environment/2017/sep/06/plastic-fibres-found-tap-water-around-world-study-reveals Plastic fibres found in tap water around the world, study reveals], The Guardian, 6 Sep 2017</ref>

Although there is evidence from lab studies that consuming plastic can damage some animals, there is as yet no evidence of harm in humans.<ref name=natgeoplasticharmingus/>

===Effects on animals===
There is evidence that plastic causes damage to individual organisms, although there is not evidence that it causes population-level damage.<ref name=natgeoplasticharmingus>[https://www.nationalgeographic.com/magazine/2018/06/plastic-planet-health-pollution-waste-microplastics/ We Know Plastic Is Harming Marine Life. What About Us?], National Geographic, June 2018</ref>

==Specific plastics==
Some plastics are singled out by activists as especially evil.

===Drinking straws===
[[File:Single Use Plastic Straw.jpg|thumb|right|165px|Single use plastic straw on a beach]]
These are a particularly obvious thing because nobody needs to drink through straws. Except disabled people who can't lift a glass to their mouth.<ref>[https://www.theguardian.com/commentisfree/2018/jul/09/disabled-person-plastic-straws-baby-wipes I rely on plastic straws and baby wipes. I’m disabled – I have no choice], Penny Pepper, ''The Guardian'', 9 July 2018</ref> The simplest solution is for bars and restaurants to only give them out if you ask for one. Since many are used for stirring mixed drinks, you can also substitute for a wooden or other recyclable drink stirrer, or a spoon which can be washed and reused.

There are dire warnings of environmental damage from drinking straws.<ref>[https://www.greenmatters.com/renewables/2018/07/18/aowRJ/why-are-straws-bad Plastic Straws], Green Matters, 18 July 2018</ref> However, this may be taking things out of proportion. There has been wild exaggeration of the amount of plastic straws in the ocean, with a claim that Americans use 500 million plastic straws a day. This statistic has been debunked as something made up by a 9 year old kid.<ref>[https://www.bloomberg.com/opinion/articles/2018-06-07/plastic-straws-aren-t-the-problem Plastic Straws Aren't The Problem], Adam Minter, Bloomberg, 7 June 2018</ref>

As well as environmental issues, there are separate concerns that straws cause gas (indigestion), wrinkles, and tooth decay.<ref>[https://www.washingtonpost.com/lifestyle/wellness/plastic-straws-arent-just-bad-for-the-environment--they-can-be-bad-for-your-body/2018/07/02/d682fdfe-7964-11e8-aeee-4d04c8ac6158_story.html?utm_term=.5bbe4fe8fb29 Plastic straws aren’t just bad for the environment — they can be bad for your body], Washington Post, 2 July 2018</ref>

===Microplastics===
[[File:Microplastic.jpg|thumb|left|165px|Microplastics]]
Tiny plastic particles, with uses such as as abrasives, are particularly damaging to the environment because they are typically passed through drains and into oceans; as yet, sewage plants do not filter them out.<ref>{{wpa|Microplastics}}</ref>
{{clear}}

===Liquid soap===
[[File:Dr. Bronner's Magic Soap.jpg|thumb|right|165px|[[Dr. Bronner's Soap]]]]
Liquid soap and handwash and shampoo are a new ''bete noire'', because they are often packaged in plastic bottles, and people don't often recycle the plastic. In contrast, bar soap can be packaged in paper or card (although it isn't always). While reducing the use of plastic bottles is good, this can also be done by taking plastic bottles to stores that will refill them with liquid soap. Bar soap can be harsher than liquid detergents due to its higher pH, requiring the use of moisturiser, which itself probably comes in a plastic tub or bottle, so beware.

The hostility to liquid soap may reflect a wider but less rational [[Chemophobia|hostility to "artificial chemicals"]] in such products.<ref>[https://www.salon.com/2009/08/13/shampoo/ Shampoo], Salon, 2009</ref><ref>[https://articles.mercola.com/sites/articles/archive/2010/07/13/sodium-lauryl-sulfate.aspx Deadly and Dangerous Shampoos, Toothpastes, and Detergents: Could 16,000 Studies Be Wrong About SLS?], [[Joseph Mercola]]</ref>

===Pre-packaged vegetables===
Another thing which attracts the ire of anti-plastic warriors is vegetables that are wrapped in plastic.<ref>[https://delishably.com/food-industry/Pre-Wrapped-Produce-Fruits-and-Vegetables-Are-Getting-a-Bad-Wrap Pre-Packaged Produce: Fresh Foods Get a "Bad Wrap" for Sustainability], Delishably, 12 Dec 2018</ref> Again, a laudable thing, but it ignores a few facts. Firstly, even loose veg probably arrives at your store wrapped in plastic — it's just that the staff take it out of a bag before putting it on display. Second, you often get people ranting about fruit and veg that is peeled and chopped and placed in a plastic bag, but this is useful for the elderly and other people whose motor skills don't let them chop onions, etc. Due to the high price of pre-chopped vs unprepared, it's unlikely that many people buy them except for a good reason.

===Fast fashion===
Today, a lot of stores manufacture cheap clothes which last for a short period of time before they (a) go out of style and (b) fall apart. These clothes are only one-step up from the futuristic dream of wear-once-and-throw-away paper clothes. They can be considered very wasteful, whether made from natural products (cotton uses a lot of water to grow and cloth manufacture produces a lot of pollution) or artificial fibres (i.e. plastic).<ref>[https://sustainability.uq.edu.au/projects/recycling-and-waste-minimisation/fast-fashion-quick-cause-environmental-havoc Fast fashion quick to cause environmental havoc], University of Queensland, Australia, accessed 11 Jan 2019</ref>

==Difficulties with reducing plastic==
Many people are attempting to reduce their plastic usage, and some are even living what the media call "plastic free" lives.<ref name=fote/><ref name=sas/> There are a number of problems. Such definitions generally mean reducing or entirely cutting the use of single-use plastics such as bags, straws, and packaging. They tend to ignore other forms of plastic found everywhere in modern life. To live a truly plastic-free life would be almost impossible.

===Hidden plastics===
Many industries use huge amounts of single-use packaging: hospitality, food service, bars, healthcare, beauty. Plastic offers convenient and hygienic packaging for many products in these industries. But this is often unseen by people, and therefore attracts much less interest than retail food packaging.

Another industry which uses plastics is distribution and wholesale. Some advocates of plastics don't realise that the loose vegetables in the supermarket often arrive in plastic packets that are opened by staff. Your local grocer may do better — with paper sacks or reusable wooden crates — but it's far from guaranteed.

A particular problem is plastic nets, floats, and lines used in commercial sea fishing. This is frequently lost and forms a substantial part of marine plastic pollution.<ref name=natgeofishinggear/>

Other apparently benign products also contain plastic. Examples include tea-bags and moist baby wipes. Such plastic use may not be obvious until it is noticed by environmental campaigners and becomes the next hot topic.

===Domestic plastics===
Plastic is inescapable in the home: consumer electronics; wiring insulation; pipes; pharmaceutical packaging. There are uses in construction, and most vehicles and many bicycles have plastic parts.

Much clothing is made from plastic, especially sportswear, waterproofs, and shoes; but even jeans and cotton underwear probably contains a little elastane.<ref>{{wpa|Synthetic fiber}}</ref> If you are a vegan (avoiding leather, wool, and other animal products), your alternatives are limited even further. Cotton is environmentally unfriendly, requiring lots of water and being grown by many unpleasant regimes, sometimes using [[Slavery|slaves]].<ref>[https://www.worldwildlife.org/industries/cotton Cotton], World Wildlife Fund, accessed 11 Jan 2019</ref><ref>[https://www.antislavery.org/take-action/campaigns/end-uzbek-cotton-crimes/ End Cotton Crimes campaign], Anti-slavery International, accessed 11 Jan 2019</ref> That being said, the mere act of machine washing polyester clothing releases potentially hundreds of thousands of microplastic fibers into wastewater systems.<ref>https://www.vox.com/the-goods/2018/9/19/17800654/clothes-plastic-pollution-polyester-washing-machine More than ever, our clothes are made of plastic. Just washing them can pollute the oceans, ''Vox''</ref>

===Myth of single-use===
Many so-called single use items can be re-used, e.g. plastic bags, tubs, bottles. This makes a nonsense of a rigid division in many cases, although a few things such as potato crisp/chip bags and other forms of plastic wrap are unlikely to be ever reused.

Conversely, things like fishing nets are not single use, but are lost so frequently that they must be considered nearly as predictable a form of waste as a single-use bottle. And if you only wear clothes once, e.g. an outfit for a special occasion, then it is essentially single-use.

Other products such as gag gifts, novelties, and unwanted promotional items are essentially no-use plastics, and so they are even worse. Yet for some reason there is less interest in banning novelty items than plastic bags, which at least have a practical use.

This is important because when people, organisations, or places declare they are plastic free, they nearly always mean they avoid certain types of "single-use" plastic, rather than the abolition of all plastics.<ref name=sas/>

===Advantages of packaging===
Effective food packaging will reduce wastage and hence have an environmental benefit. Of course, there are alternatives, but many have downsides: refrigeration (uses lots of energy), irradiation (requires large-scale equipment and [[Radiophobia|scares people]]), waxing (may affect food taste), food additives (most are benign, but some people have allergies to certain ones; may be expensive; may alter taste; not suitable for all products, e.g. raw fruit and veg).

Alternatives to plastic packaging (e.g. plastic-free shops) often require a certain mass of people to be economic, particularly with perishable goods such as food. Hence they will tend to concentrate in areas with well-off, middle-class, liberal consumers who are able to afford what may well be higher-priced and less convenient goods. In contrast, packaged products will often be cheaper and more accessible to the poor. (Although this is not necessarily so — cardboard is good for packaging many frozen foods while fresh products may need plastic.)

===Cost of replacement===
People are trying to replace cheap plastic vessels with more expensive non-plastic items such as glass jars and metal vessels. If you buy a plastic bottle of water every day, then replacing that with a durable alternative will doubtless have environmental benefits.

===Shifting the blame===
While the goal of reducing one's personal plastic use is admirable, the effect one or even a thousand consumers can have is minimal. Similar to the way oil companies use propaganda to convince the public that the consumer is to blame for energy use when the vast majority is used by large entities,<ref>https://www.vox.com/22429551/climate-change-crisis-exxonmobil-harvard-study</ref> the vast majority of plastics enter the consumer economy via large corporations, and the consumer has effectively zero choice in the matter.

==Alternative solutions==
===Clearing ocean plastic===
Instead of banning plastic, we could try and clear all the plastic in the seas, by gathering it up with booms or filtering from sea water.<ref>[https://www.theoceancleanup.com/ The Ocean Cleanup]</ref><ref>[https://www.bbc.co.uk/news/science-environment-45438736 Giant plastic catcher heads for Pacific Ocean clean-up], BBC, 7 Sep 2018</ref> Unfortunately, destructive microplastics are not so easily cleaned up. While methods are being researched to portentially remove microplastics from the environment,<ref>https://www.theguardian.com/science/2021/apr/28/scientists-find-way-to-remove-polluting-microplastics-with-bacteria Scientists find way to remove polluting microplastics with bacteria, ''The Guardian''</ref><ref>https://www.frontiersin.org/articles/10.3389/fmars.2020.00128/full Passive and Active Removal of Marine Microplastics by a Mushroom Coral (Danafungia scruposa), ''Frontiers in Marine Science''</ref> at the moment the only viable method we have is to reduce the amount of plastics that enter the environment in the first place.

===Penalise littering===
"But if plastic waste is caused by littering, why not just punish litterers?"

Actually, while some environmentalists may blame inconsiderate individuals and foreground things like discarded plastic bags, much plastic waste is caused by products that are accidentally lost (whether from boats or in tsunamis and storms), as well as microplastics that pass through sewage.<ref name=natgeofishinggear/>

===Biodegradable plastic===
This seems a good alternative, and many people call for using biodegradable products (wood, paper, etc) instead of plastic. This can commonly be seen in the form of cellophane plastic wrap (just make sure the wrap you are buying is ''actually' cellophane, and not polypropylene labeled as cellophane<ref>https://www.beeco.green/facts/is-cellophane-recyclable/</ref>).

===Using Less===
The simplest method of reducing plastic pollution is to simply use less of it when possible.

===Reduce, reuse, or recycle?===
{{main|Waste hierarchy}}

The waste hierarchy is based on the principle that you should reduce use where possible, and if not re-use, and when reuse is impossible, recycle. Hence, recycling should not be a first option but can be a way of disposing of waste. Recycling plastic requires energy for processing, and also requires products to be transported to recycling stations. Many plastics cannot be reused: it often isn't a case of melting down and reusing, and waste is often recycled to lower-grade plastic if it can be recycled at all.

So one way of reducing plastic waste is to improve recycling schemes. This can involve clear labelling and restrictions on the types of plastic used to prefer more recyclable ones. An alternative is to have deposit schemes to collect and refill plastic bottles. Again, there are pros and cons. Some schemes may involve complex infrastructure, lots of small transactions to take account of, and involve economies of scale that benefit large businesses over small. Standardisation helps recycling and reuse, but stifles innovation and may antagonise libertarians.

Whether reusing or recycling, there is a question of whether the producer or the state should be responsible for collecting and processing. Putting the responsibility on the producer reduces state and personal spending. However, there is the question of how to get back to the producer. Schemes that require consumers to transport their plastic waste will benefit middle-class people with cars. The alternative is a centralised state scheme such as curbside collections of waste for recycling mixed waste.

Mixed waste recycling schemes are complicated by the different values of different products: often they are subsidised by high-value waste (particularly [[aluminium]] but also easily-reused plastic), and if you remove that, you render schemes uneconomic as a whole and will end up with large amounts of discarded of low-value waste. On the other hand, mixed waste schemes still have to deal with the low value waste, which may involve shipping it overseas.

The reality of plastic recycling is that it is difficult, over-promoted, and rarely utilizable. In 2024, the State of [[California]] sued ExxonMobil for lying about plastics being recyclable, that it tried to convince the public through false advertising "that plastic recycling could solve the plastic waste and pollution crisis."<ref>[https://www.washingtonpost.com/climate-solutions/2024/09/23/california-sues-exxonmobil-plastics-recycling/ California accuses ExxonMobil of lying about plastics being recyclable: The state alleges the oil company deceived "the public to convince us that plastic recycling could solve the plastic waste and pollution crisis."] by Allyson Chiu (September 23, 2024) ''The Washington Post''.</ref> ExxonMobil is a major manufacturer of plastic precursor materials.

===Burning?===
Waste can be burned for power generation and heating. However, it causes air pollution and carbon dioxide, and burning plastic is much less efficient than burning gas, so it isn't ideal either.<ref>[https://www.bbc.co.uk/news/science-environment-43120041 Should we burn or bury waste plastic?], BBC, 20 Feb 2018</ref>

==References==
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[[Category:Chemistry]]

Categories: Chemistry