Lilith , Adam 's first wife from the garden of Eden steals Mary Wardwell 's identity and plans to train Sabrina as her replacement .
Michelle Gomez as Lilith / Madam Satan : The first wife of Adam from the Garden of Eden , who steals the identity of Mary Wardwell , Sabrina 's favorite teacher and mentor at Baxter High ; a cunning manipulator , she intends to groom Sabrina to take her place as Satan 's foot soldier so that she herself can rise to be his queen . *
Chilling Adventures of Sabrina -LRB-TV series-RRB-