Calibration transfer of near-IR partial least squares property models of fuels using virtual standards
Partial least squares (PLS) models of 10 important jet and diesel fuel properties were built using spectra from a master near-IR dispersive instrument and then subsequently transferred to a secondary dispersive instrument via a novel calibration transfer method using virtual standards and a slope-bias correction. Implementation of the transfer requires that only seven spectra of neat solvents be acquired on the master and secondary instruments. The spectra of the neat solvents are then used to digitally replicate spectra from the calibration set to generate virtual standards. Comparison of PLS predictions for the master and secondary instrument virtual standards provides a simple but effective slope-bias correction for transfer. The transferred fuel properties include American Petroleum Institute gravity, % aromatics, cetane index, flashpoint, hydrogen content, % saturates, and distillation temperatures at 10%, 20%, 50%, and 90% volume recovered. Transfer error was lower than using either the pure solvents with a slope-bias correction or than using a piecewise direct standardization calibration transfer using fuel spectra. Transfer error was higher than when using actual fuels to transfer the calibration. The use of virtual standards eliminates the need to maintain either complex fuel standards or the master instrument for future instrument calibration transfers. Copyright (C) 2011 John Wiley & Sons, Ltd.
calibration transfer pls diesel fuel near ir spectroscopy jet fuel