Stereoselective propagation in free radical polymerization of acrylamides: A DFT study
Stereoselective propagation of acylamides is modeled in radical polymerization. Temperature and solvent effect is shown on stereoselective propagation. Stereospecifity is directed by interplay between steric effects and H-bondings.
stereoselective radical polymerization dft acrylate pro-racemo pro-meso