PATENT DOCUMENT

Publication Number: US-10090876-B1
Application Number: US-201615170631-A
Country: US
Kind Code: B1

Title: Electronic devices with masking layers

Abstract:
An electronic device may have transparent structures. The transparent structures may include a transparent member such as a transparent button member, a transparent member that serves as a display cover layer, a transparent member that covers a sensor such as a touch sensor, or other transparent member. The transparent member may have an inner surface that is covered with an opaque masking layer that is free of materials that discolor upon light exposure and that is formed from a layer of polymer and light-scattering inclusions such as solid particles, hollow microspheres, porous particles, and voids. A protective layer such as an inorganic layer may be formed over the polymer layer. A fingerprint sensor, touch sensor, or other structures may be attached to the opaque masking layer using a layer of adhesive.

Claims:
What is claimed is: 
     
       1. An electronic device, comprising:
 a display having a pixel array; 
 a housing; 
 a transparent member in the housing, wherein the transparent member has an inner surface; 
 opaque masking structures on the inner surface that contain light-scattering inclusions and that are free of materials that discolor on exposure to light, wherein the opaque masking structures do not overlap the pixel array; and 
 a fingerprint sensor mounted under the opaque masking structures. 
 
     
     
       2. The electronic device defined in  claim 1  wherein the opaque masking structures include a light-scattering layer and wherein the light-scattering inclusions are formed in the light-scattering layer. 
     
     
       3. The electronic device defined in  claim 2  wherein the light-scattering layer is a white layer that is free of titanium dioxide. 
     
     
       4. The electronic device defined in  claim 3  wherein the opaque masking structures include a protective layer on the white layer. 
     
     
       5. The electronic device defined in  claim 4  wherein the white layer comprises a polymer layer having inclusions that are selected from the group consisting of: solid particles, porous particles, voids, and hollow microstructures. 
     
     
       6. The electronic device defined in  claim 4  wherein the white layer comprises:
 a polymer layer; and 
 solid light-scattering particles in the polymer layer. 
 
     
     
       7. The electronic device defined in  claim 4  wherein the white layer comprises:
 a polymer layer; and 
 porous light-scattering particles in the polymer layer. 
 
     
     
       8. The electronic device defined in  claim 4  wherein the white layer comprises:
 a polymer layer; and 
 light-scattering voids in the polymer layer. 
 
     
     
       9. The electronic device defined in  claim 4  wherein the white layer comprises:
 a polymer layer; and 
 light-scattering hollow microspheres in the polymer. 
 
     
     
       10. The electronic device defined in  claim 4  wherein the transparent member comprises a button member. 
     
     
       11. The electronic device defined in  claim 4  further comprising adhesive that attaches the fingerprint sensor to the opaque masking structures. 
     
     
       12. The electronic device defined in claim  11  wherein the protective layer comprises an inorganic layer. 
     
     
       13. The electronic device defined in  claim 3  wherein the fingerprint sensor comprises a capacitive sensor attached to the white layer. 
     
     
       14. Apparatus, comprising:
 a transparent member having an inner surface; 
 a light-blocking white layer on the inner surface of the transparent member, wherein the light-blocking white layer is free of titanium dioxide and is formed from a polymer layer containing light-scattering inclusions selected from the group consisting of: solid particles, porous particles, voids, and hollow microspheres; and 
 a capacitive sensor configured to make capacitive measurements through the transparent member. 
 
     
     
       15. The apparatus defined in  claim 14  further comprising an inorganic protective layer on the light-blocking white layer, wherein the light-blocking white layer is interposed between the inorganic protective layer and the transparent member. 
     
     
       16. The apparatus defined in  claim 15  wherein the capacitive sensor is attached to the protective layer with adhesive and wherein the light-scattering inclusions comprise solid particles with a different index of refraction than the polymer layer. 
     
     
       17. An electronic device, comprising:
 a display having an active area and an inactive area; 
 a transparent button member in the inactive area, wherein the transparent button member has an inner surface; 
 a polymer layer on the inner surface of the transparent button member that contains light-scattering inclusions and that is free of titanium dioxide; and 
 a touch sensor that is attached to the polymer layer. 
 
     
     
       18. The electronic device defined in  claim 17  further comprising an inorganic protective layer on the polymer layer and a layer of adhesive with which the touch sensor is attached to the protective layer.

Description:
This application claims the benefit of provisional patent application No. 62/275,555 filed on Jan. 6, 2016, which is hereby incorporated by reference herein in its entirety. 
    
    
     FIELD 
     This relates generally to electronic devices and, more particularly, to masking layers for coating transparent structures in electronic devices. 
     BACKGROUND 
     Electronic devices sometimes contain transparent structures. For example, the display in a cellular telephone may be covered with a layer of glass. Cosmetic coatings such as layers of black and white ink are sometimes formed on the inner surfaces of the glass layer. In some devices, transparent button members may be coated with layers such as ink layers. 
     If care is not taken, the masking material that is used to coat a transparent structure in an electronic device may be prone to discoloration. For example, white ink layers that contain titanium oxide particles may acquire a bluish tint upon exposure to ultraviolet light. 
     SUMMARY 
     An electronic device may have transparent structures. The transparent structures may include a transparent member such as a transparent button member, a transparent member that serves as a display cover layer, a transparent member that covers a sensor such as a touch sensor, or other transparent members. 
     A transparent member in an electronic device may have an inner surface that is covered with a masking layer such as a layer of white ink or other white layer. The masking layer may be formed from a layer of polymer having light-scattering inclusions. The light-scattering inclusions may be formed from solid particles, porous particles, voids, hollow microspheres, or other structures that have an index of refraction that differs from that of the layer of polymer. 
     To prevent undesired color changes in the masking layer, the masking layer may be free of structures that discolor upon exposure to light. A protective layer such as an inorganic layer may be formed over the polymer layer to help prevent scratches. A fingerprint sensor, touch sensor, or other structures may be attached to the opaque masking layer using a layer of adhesive. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a perspective view of an illustrative electronic device in accordance with an embodiment. 
         FIG. 2  is a cross-sectional side view of a portion of an illustrative electronic device with a button member in accordance with an embodiment. 
         FIG. 3  is a cross-sectional side view of an illustrative masking layer with solid light-scattering particles in accordance with an embodiment. 
         FIG. 4  is a cross-sectional side view of an illustrative masking layer with porous light-scattering particles formed from solid material containing cavities in accordance with an embodiment. 
         FIG. 5  is a cross-sectional side view of an illustrative masking layer with light-scattering voids in accordance with an embodiment. 
         FIG. 6  is a cross-sectional side view of an illustrative masking layer with light-scattering hollow microspheres in accordance with an embodiment. 
         FIG. 7  is a cross-sectional side view of an illustrative electronic device with an opaque layer that is used to hide a touch sensor from view in accordance with an embodiment. 
     
    
    
     DETAILED DESCRIPTION 
     Electronic devices may be provided with opaque layers of material such as layers of polymer with light-scattering inclusions (e.g., ink). The opaque layers of material, which may sometimes be referred to as opaque masking layers, masking layers, or masking structures may be white, black, gray, or may have other suitable colors. Configurations in which the opaque layers are white layers may sometimes be described herein as an example. This is, however, merely illustrative. Masking layer coatings for electronic devices may have any suitable appearance. 
       FIG. 1  is a perspective view of an illustrative electronic device of the type that may include an opaque masking layer. Electronic device  10  may be a computing device such as a laptop computer, a computer monitor containing an embedded computer, a tablet computer, a cellular telephone, a media player, or other handheld or portable electronic device, a smaller device such as a wrist-watch device, a pendant device, a headphone or earpiece device, a device embedded in eyeglasses or other equipment worn on a user&#39;s head, or other wearable or miniature device, a television, a computer display that does not contain an embedded computer, a gaming device, a navigation device, an embedded system such as a system in which electronic equipment with a display is mounted in a kiosk or automobile, equipment that implements the functionality of two or more of these devices, an accessory (e.g., earbuds, a remote control, a wireless trackpad, etc.), or other electronic equipment. In the illustrative configuration of  FIG. 1 , device  10  is a portable device such as a cellular telephone, media player, tablet computer, or other portable computing device. Other configurations may be used for device  10  if desired. The example of  FIG. 1  is merely illustrative. 
     In the example of  FIG. 1 , device  10  includes display  14 . Display  14  has been mounted in housing  12 . Housing  12 , which may sometimes be referred to as an enclosure or case, may be formed of plastic, glass, ceramics, fiber composites, metal (e.g., stainless steel, aluminum, etc.), other suitable materials, or a combination of any two or more of these materials. Housing  12  may be formed using a unibody configuration in which some or all of housing  12  is machined or molded as a single structure or may be formed using multiple structures (e.g., an internal frame structure, one or more structures that form exterior housing surfaces, etc.). Openings may be formed in housing  12  to form communications ports, holes for buttons, and other structures. 
     Display  14  may be a touch screen display that incorporates a layer of conductive capacitive touch sensor electrodes or other touch sensor components (e.g., resistive touch sensor components, acoustic touch sensor components, force-based touch sensor components, light-based touch sensor components, etc.) or may be a display that is not touch-sensitive. Capacitive touch sensor electrodes may be formed from an array of indium tin oxide pads or other transparent conductive structures. 
     Display  14  may include an array of pixels formed from liquid crystal display (LCD) components, an array of electrophoretic pixels, an array of plasma display pixels, an array of organic light-emitting diode pixels or other light-emitting diode pixels, an array of electrowetting pixels, or pixels based on other display technologies. 
     Display  14  may be protected using a display cover layer such as a layer of transparent glass, clear plastic, transparent ceramic, sapphire or other transparent crystalline material, or other transparent layer(s). The display cover layer may have a planar shape, a convex curved profile, a concave curved profile, a shape with planar and curved portions, a layout that includes a planar main area surrounded on one or more edges with a portion that is bent out of the plane of the planar main area, or other suitable shape. An opening may be formed in the display cover layer to accommodate ports such as speaker port  18 . 
     One or more additional openings may also be formed in the display cover layer. For example, an opening may be formed in the display cover layer to accommodate a button such as button  16 . Button  16  may be formed from a transparent button member that moves within the opening in the display cover layer. The button member may be circular, may be square, or may have other suitable shapes and may be formed from the same material as the display cover layer or other suitable materials. With one illustrative arrangement, which may sometimes be described herein as an example, button  16  may have a button member formed from a transparent layer such as a layer of sapphire. An opaque masking layer may be formed on the underside of the button member and on portions of the display cover layer for display  14  (e.g., on the inner surface of the display cover layer in inactive area IA of display  14 ). Other configurations may be used for display  14 , if desired (e.g., button  16  may be formed from an integral region of the display cover layer, etc.). 
       FIG. 2  is a cross-sectional side view of a portion of device  10  of  FIG. 1  in the vicinity of button  16  taken along line  20  of  FIG. 1  and viewed in direction  22 . As shown in  FIG. 2 , opaque masking structures (layer)  24  may be formed on the underside of button member  26  in button  16  and on the underside of display cover layer  36  (e.g., in the portions of display cover layer  36  shown by opaque masking structures  24 ′ of  FIG. 2  and inactive area IA of  FIG. 1 ). Button member  26  may be transparent. Opaque masking layer  24  may block visible light. For example, opaque masking layer  24  may be a white layer that blocks internal components under member  26  from view. Layer  24  may be opaque or transparent at infrared wavelengths. Configurations for device  10  in which layer  24  is formed under a transparent member such as button member  26  may sometimes be described herein as an example. In general, masking layer  24  may be formed on the surface of any suitable structure in device  10 . 
     Button member  26  may be formed from a transparent structure such as a layer of sapphire, glass, or plastic (as examples). During operation, a user may press against button member  26 , causing button member  26  to move in the −Z direction (e.g., to actuate a tactile switch or other device under button member  26 ). To provide button  16  with the ability to gather user fingerprints, button  16  may have a sensor such as fingerprint sensor  34 . Fingerprint sensor  34  may, for example, be a capacitive sensor (i.e., a capacitive touch sensor) that has an array of capacitive touch sensor electrodes. Sensor  34  may be formed from a semiconductor die (e.g., a silicon integrated circuit) and may be coupled to control circuitry within device  10  using a flexible printed circuit cable or other signal path. Sensor  34  may be mounted to the inner surface of opaque masking structures  24  using adhesive  32 . Adhesive  32  may be a rigid adhesive such as a cured liquid adhesive (e.g., epoxy, a silicone-epoxy hybrid with a high cross-link density, etc.), may be a layer of pressure sensitive adhesive, or may be other suitable adhesive. If desired, button  16  may be formed from an integral portion of the display cover layer for display  14  and/or may have a strain gauge or other sensor for detecting when a user has pressed on button  16 . The use of a configuration for button  16  with a movable button member and an associated tactile switch is merely illustrative. 
     Opaque masking structures  24  may include layers such as layers  28  and  30 . Layers  28  and  30  may be formed as coating layers on the inner surface of button member  26  (and the inner surface of display cover layer  36  and/or other transparent structures in device  10 ). Layer  28  may be a light-scattering layer such as a layer of white ink, other white layer, or other opaque masking layer. Layer  30  may be a protective layer such as a layer of silicon oxide, a layer of silicon nitride, an oxynitride layer, other inorganic layers, or other protective structures on the underside of layer  28 . Protective layer  30  may help prevent layer  28  from becoming scratched during assembly. If desired, protective layer  30  may be deposited using physical vapor deposition techniques (e.g., sputtering). The thickness of physical vapor deposition inorganic layer  30  may be less than 1 micron, less than 0.5 microns, less than 0.2 microns, less than 0.1 microns, more than 0.01 microns, or other suitable thickness. Layer  28  may be 0.5 to 50 microns thick, less than 25 microns thick, less than 10 microns thick, less than 5 microns thick, more than 1 micron thick, or other suitable thickness. Layer  28  preferably has a thickness that is sufficient to allow layer  28  to block internal components in device  10  from view by a user. 
     Layer  28  may be free of materials that discolor during exposure to light. Some white inks contain titanium dioxide particles. When exposed to light at wavelengths below the band gap of titania (e.g., ultraviolet wavelengths of less than 415 nm), surface defects may be induced in the titanium dioxide particles. This can create Ti 3+  ions and oxygen defect sights, leading to an undesired bluish appearance for the white ink. Although the presence of atmospheric oxygen at the surface of the titanium dioxide particles may help remove the bluish appearance, atmospheric oxygen may be prevented from reaching the titanium dioxide particles in some situations due to the presence of intervening layers of material (e.g., adhesive with limited oxygen permeability). Oxygen permeable adhesives may not always exhibit desired physical properties (i.e., these adhesives may be soft and not structurally sufficient for desired applications) and may therefore not be suitable for use in attaching structures to a white ink layer containing titanium dioxide particles. 
     To help avoid undesired discoloration, layer  28  may be free of materials that discolor under light exposure such as titanium dioxide. Layer  28  may be formed from a polymer matrix (binder) with light-scattering inclusions such as particles, bubbles, or other light-scattering features. These light-scattering inclusions may have dimensions of less than 50 microns, less than 25 microns, less than 10 microns, 2-15 microns, more than 1 micron, less than 5 microns, or other suitable sizes. To ensure that layer  28  has a desired appearance (e.g., a suitably white appearance when layer  28  is a white layer), layer  28  may include light-scattering features that are able to scatter light efficiently even in the absence of particles of titanium dioxide or in arrangements in which the density of particles of titanium dioxide is small. By using these light-scattering structures in layer  28 , it is not necessary for adhesive layers in device  10  such as adhesive layer  32  to be formed from oxygen permeable materials (i.e., adhesive  32  may be a strong and rigid adhesive that is impermeable to oxygen). 
     With one illustrative arrangement, layer  28  has light-scattering inclusions formed from solid particles such as particles  40  of  FIG. 3 . Particles  40  and other light-scattering inclusions for layer  28  may be embedded within a layer of polymer such as polymer layer  42 . Polymer layer  42  may be formed from a resin such as polyester, epoxy, acrylic, urethane, other polymer, or other binder material that forms a supporting matrix for particles  40 . The index of refraction of layer  42  may be about 1.5-1.6 (as an example). Particles  40  may have an index of refraction that is lower than layer  42  or higher than layer  42 . Incoming light (i.e., light that enters layer  28  from the exterior of device  10  after passing through button member  26  or other transparent member in device  10 ), may be scattered from particles  42  due to the mismatch between the index of refraction of particles  40  and the index of refraction of layer  42 . Particles  40  may be formed from a transparent material (e.g., a dielectric) such as aluminum oxide, zinc oxide, tantalum oxide, other metal oxides, nitrides, other inorganic materials, organic materials, or other materials. The index of refraction of particles  40  preferably differs from the index of refraction of layer  42  by 0.1 or more, 0.2 or more, or 0.3 or more (as examples). 
     If desired, particles  40  may include voids such as voids  44  of  FIG. 4  (i.e., particles  40  may be open-cell or closed-cell porous materials). Voids  44  in porous particles such as porous particles  40  of  FIG. 4  may contain vacuum or may be bubbles that are filled with air, an inert gas such as nitrogen, or one or more other gasses, etc. Voids (pores)  44  may be less than 5 microns in diameter, 1-4 microns in diameter, more than 0.5 microns in diameter, or other suitable size. If desired, a mixture of particles  40  may be used in polymer  42 , some of which are solid as described in connection with  FIG. 3  and some of which are porous as described in connection with  FIG. 4 . 
       FIG. 5  shows how polymer layer  42  may contain void  46  that serve as light-scattering features. Voids  46  may contain vacuum or may be bubbles that are filled with air, an inert gas such as nitrogen, or one or more other gasses, etc. Voids  46  may be less than 5 microns in diameter, 1-4 microns in diameter, more than 0.5 microns in diameter, or other suitable size. With one suitable arrangement, bubbles such as voids  46  of  FIG. 5  may be incorporated into polymer  42  by omitting chemical additives that prevent the formation of foam (sometimes referred to as defoamers or anti-foaming agents). Polymer  42  that is free of defoamer material may be foamed to form voids  46  of  FIG. 5  by introducing gas bubbles into polymer  42  while polymer  42  is a liquid and then curing polymer  42  before the bubbles coalesce. Polymer  42  may be cured by application of heat, light (e.g., visible light and/or ultraviolet light), at room temperature (e.g., when using a two-part adhesive), using a curing catalyst, etc. 
     In the example of  FIG. 6 , hollow microstructures such as hollow microspheres  48  have been incorporated into polymer  42  to form layer  28 . Each microsphere  48  may have a shell surrounding a void. Shells  50  may be formed from inorganic materials (oxides, nitrides, glass, etc.) or organic materials (e.g., polymer). Voids  52  may contain vacuum or a gas (nitrogen, air, etc.). The dimensions (diameters) of microspheres  48  may be less than 10 microns, 2-10 microns, less than 1 micron, more than 0.5 microns, more than 3 microns, or other suitable size. 
     If desired, other light-scattering inclusions may be incorporated into polymer layer  42  to form layer  28 . Structures of the type shown in  FIGS. 3, 4, 5, and 6  and, if desired, other light-scattering features may be incorporated into layer  42  in any suitable combination. If desired, the light-scattering features may be free of titanium dioxide and other materials that discolor under exposure to light such as ultraviolet light and/or may include minimal amounts of such materials. 
     In addition to forming layers such as layer  28  between button member  26  and fingerprint sensor  34 , layers such as layer  28  of  FIGS. 4, 5, 6, and 7  may be incorporated under other transparent conductive structures (e.g., in regions  24 ′ of  FIG. 2 ). In the example of  FIG. 7 , device  10  is a trackpad or other device that includes a touch sensor such as touch sensor  60 . Touch sensor  60  may be formed from an array of capacitive touch sensor electrodes (electrodes  62 ) supported by a substrate (substrate  64 ). Substrate  64  may be a dielectric material such as a molded plastic support structure or a printed circuit (e.g., a printed circuit with a substrate formed from rigid printed circuit board material such as fiberglass-filled epoxy or a printed circuit formed from a flexible substrate such as a layer of polyimide or other flexible sheet of polymer). 
     Touch sensor  60  may be mounted within the interior of device  10 . For example, touch sensor  60  may be mounted to the underside of a protective outer member such as member  66 . Planar member  66  may be a layer of transparent material such as a layer of clear plastic or glass. To help hide internal components in device  10  from view by a user (e.g., to help block touch sensor  60  from view from the exterior of device  10 ), an opaque masking layer may be formed on the inner surface of planar member  66 . As an example, opaque masking layer structures  24  may be formed on the underside of planar member  66  and may be interposed between touch sensor  60  and member  66 . Structures  24  may include an opaque layer with light-scattering features such as layer  28  and an optional protective layer such as layer  30 . Optional adhesive layer  70  may be used to attach touch sensor  60  to structures  24 . 
     The foregoing is merely illustrative and various modifications can be made by those skilled in the art without departing from the scope and spirit of the described embodiments. The foregoing embodiments may be implemented individually or in any combination.

Metadata:
Filing Date: 20160601
Publication Date: 20181002
Grant Date: 20181002
Priority Date: 20160106
Inventors: MATSUYUKI, NAOTO
WILSON, JAMES R.
ROGERS, MATTHEW S.
Assignee: APPLE INC
CPC Classifications: [{"code": "H04B1/3888", "inventive": true, "first": true, "tree": "[]"}, {"code": "C03C17/34", "inventive": true, "first": true, "tree": "[]"}, {"code": "C03C17/34", "inventive": true, "first": true, "tree": "[]"}, {"code": "C03C2217/425", "inventive": false, "first": false, "tree": "[]"}, {"code": "C03C2217/445", "inventive": false, "first": false, "tree": "[]"}, {"code": "C03C2217/475", "inventive": false, "first": false, "tree": "[]"}, {"code": "C03C2217/445", "inventive": false, "first": false, "tree": "[]"}, {"code": "C03C2217/425", "inventive": false, "first": false, "tree": "[]"}, {"code": "C03C2217/475", "inventive": false, "first": false, "tree": "[]"}]
Family ID: 63638655