PATENT DOCUMENT

Publication Number: US-11066322-B2
Application Number: US-201815986778-A
Country: US
Kind Code: B2

Title: Selectively heat-treated glass-ceramic for an electronic device

Abstract:
The embodiments disclosed herein are directed to forming selectively heat-treated glass-ceramic parts for use in an electronic device. In various embodiments, glass-ceramic parts, such as a cover sheet, may have multiple different regions having different objectives for material properties such as optical properties, strength, fracture toughness, hardness, and the like. Different regions may be selectively heat treated to achieve desired results.

Claims:
What is claimed is: 
     
       1. An electronic device comprising:
 a display; 
 a housing; 
 a cover sheet affixed to the housing and covering the display, the cover sheet comprising:
 a first region having an optical haze and a first median crystal size; 
 a second region positioned over the display having a second median crystal size that is smaller than a crystal size that causes scattering of light; and 
 a third region positioned between the first region and the second region, the third region defining a transition between the first region and the second region and including crystals that range in size from the first median crystal size to the second median crystal size, the transition having a gradient of crystal sizes between the first region and the second region, the gradient defining a uniform profile extending from a top surface of the cover sheet to a bottom surface of the cover sheet. 
 
 
     
     
       2. The electronic device of  claim 1 , further comprising:
 a processor configured to provide information for presentation on the display; 
 a mask at least partially surrounding a periphery of the display; wherein:
 the cover sheet is positioned adjacent to the display; 
 the first region is adjacent to the mask such that the mask conceals the optical haze; and 
 the second region is adjacent to the display such that the information presented on the display is free of haze induced by the cover sheet. 
 
 
     
     
       3. The electronic device of  claim 2 , wherein the mask is formed from an opaque ink. 
     
     
       4. The electronic device of  claim 1 , wherein a strength of the first region is greater than a strength of the second region. 
     
     
       5. The electronic device of  claim 1 , further comprising at least one camera positioned adjacent to the second region of the display such that images captured by the at least one camera are free of haze induced by the cover sheet. 
     
     
       6. The electronic device of  claim 1 , wherein the cover sheet comprises an opening for at least one of a button or a speaker.

Description:
CROSS-REFERENCE TO RELATED APPLICATION(S) 
     This application is a non-provisional patent application of and claims the benefit of U.S. Provisional Patent Application No. 62/593,564, filed Dec. 1, 2017 and titled “Selectively Heat-Treated Glass-Ceramic for an Electronic Device,” the disclosure of which is hereby incorporated herein by reference in its entirety. 
    
    
     FIELD 
     Embodiments described herein relate to electronic device components and, in particular, selectively heat-treated glass-ceramic parts for use in electronic devices. 
     BACKGROUND 
     Many traditional electronic devices include parts formed of glass-ceramic materials, such as cover sheets and the like. Many traditional glass-ceramic parts include consistent material properties throughout. This leads to many portions of a glass-ceramic part having material properties that are not well-suited for the glass part&#39;s function and/or position on the device. In many cases, it is advantageous to have different material properties at different locations on a device. 
     SUMMARY 
     Certain embodiments described herein generally reference a method for forming a glass-ceramic part having first and second regions with differently-sized ceramic crystals. The method includes heating the first region of a glass part to a first temperature that is at or above a crystallization temperature of the glass part. The method further includes maintaining the second region of the glass part at or below a second temperature that is below the first temperature, thereby converting the glass part to a glass-ceramic part with the first region having a first median crystal size and the second region having a second median crystal size that is less than the first median crystal size. 
     Other embodiments described generally reference a method for forming a glass-ceramic part having first and second regions with different crystal densities. The method includes heating a first region of a glass part to a first temperature that is at or above a nucleation temperature of the glass part. The method further includes maintaining a second region of the glass part at or below a second temperature that is below the first temperature. The method further includes subsequently heating the first region of the glass part to a third temperature at or above a crystallization temperature of the glass part, thereby converting the glass part to a glass-ceramic part with the first region having a first crystal density and the second region having a second crystal density that is less than the first crystal density. 
     Still further embodiments described herein relate to, include, or take the form of an electronic device that includes a display, a housing, and a cover sheet affixed to the housing and positioned adjacent to the display. The cover sheet includes an optically hazed first region having a first median crystal size and an optically transparent second region having a second median crystal size that is smaller than a size that causes scattering of light. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       Reference will now be made to representative embodiments illustrated in the accompanying figures. It should be understood that the following descriptions are not intended to limit this disclosure to one preferred embodiment. To the contrary, the disclosure provided herein is intended to cover alternatives, modifications, and equivalents as may be included within the spirit and scope of the described embodiments, and as defined by the appended claims. 
         FIG. 1  illustrates an example electronic device that may incorporate selectively heat-treated glass-ceramics, according to one or more embodiments presented herein. 
         FIGS. 2A and 2B  illustrate example selective heat treatment patterns for a glass-ceramic cover sheet of an electronic device. 
         FIG. 3  is a simplified flow chart depicting an example process for manufacturing a selectively heat-treated glass-ceramic part as described herein. 
         FIG. 4  is a chart illustrating an example heat treatment temperature profile over time for the example process described with respect to  FIG. 3 . 
         FIG. 5A-5B  illustrate cross-sections of example glass-ceramic parts having a first region and a second region, with a border separating the regions. 
         FIG. 6  shows a glass part undergoing selective heat treatment to form a glass-ceramic part using a laser. 
         FIG. 7  shows a glass part undergoing selective heat treatment to form a glass-ceramic part using heat sinks. 
         FIG. 8  shows a glass part undergoing selective heat treatment to form a glass-ceramic part using a conductive coating to inductively heat a portion of the glass part. 
         FIG. 9  shows a glass part undergoing selective heat treatment to form a glass-ceramic part using a low-emissivity coating to shield a portion of the glass part. 
         FIG. 10  shows a glass part undergoing selective heat treatment to form a glass-ceramic part using a gas and/or fluid cooling device. 
         FIGS. 11A and 11B  illustrate cross-sections of a selectively heat-treated glass-ceramic part, showing a laser for performing additional heat treatment along a border between regions of the selectively heat-treated glass-ceramic part. 
         FIG. 12  is a simplified flow chart depicting an example process for forming a selectively heat-treated glass-ceramic part as described herein. 
         FIG. 13  is an illustrative block diagram of an electronic device that may incorporate a glass-ceramic part as described herein. 
     
    
    
     The use of the same or similar reference numerals in different figures indicates similar, related, or identical items. 
     Additionally, it should be understood that the proportions and dimensions (either relative or absolute) of the various features and elements (and collections and groupings thereof) and the boundaries, separations, and positional relationships presented therebetween, are provided in the accompanying figures merely to facilitate an understanding of the various embodiments described herein and, accordingly, may not necessarily be presented or illustrated to scale, and are not intended to indicate any preference or requirement for an illustrated embodiment to the exclusion of embodiments described with reference thereto. 
     DETAILED DESCRIPTION 
     Reference will now be made in detail to representative embodiments illustrated in the accompanying drawings. It should be understood that the following descriptions are not intended to limit the embodiments to one preferred embodiment. To the contrary, it is intended to cover alternatives, modifications, and equivalents as can be included within the spirit and scope of the described embodiments as defined by the claims. 
     The embodiments disclosed herein are directed to selectively heat treating glass to form glass-ceramic parts for use in an electronic device. In various embodiments, glass-ceramic parts, such as a cover sheet (e.g., a cover glass), may have multiple different regions having different objectives for material properties such as optical properties, strength, fracture toughness, hardness, and the like. 
     For example, in a region of a glass-ceramic part (e.g., a cover sheet, input surface, housing, or the like) that is adjacent to a display of the electronic device, it may be desirable for the glass-ceramic part to be transparent (e.g., allowing light to pass through the material without being scattered) such that information presented on the display is unaffected by visual defects, distortion, or other artifacts induced by the glass part. Similarly, in a region of the glass-ceramic part that is adjacent to a camera of the electronic device, it may be desirable for the glass-ceramic part to be transparent to avoid distortion of images captured by the camera. Likewise, in a region of the glass-ceramic part that is adjacent to a sensor of the electronic device, it may be desirable for the glass-ceramic part to be transparent to avoid adversely impacting sensor performance. 
     In other regions of the glass-ceramic part, such as regions near or along the edges of the electronic device that may be subjected to impact forces, it may be less important that the glass-ceramic part be transparent, and instead be more desirable for the glass-ceramic part to have different material properties such as increased strength, fracture toughness, and/or hardness. Accordingly, the glass-ceramic part may be manufactured or otherwise processed to achieve different material properties within different regions of the part. 
     To form a glass-ceramic part having varying material properties, a glass part having a randomly arranged atomic structure may be selectively heat treated to create an ordered crystalline structure in one or more regions of the part. Based on the selective heat treatment, the presence of a crystalline structure and the characteristics (e.g., crystal size and density) of the crystalline structure may vary across the part, which results in varying material properties across the part. In one embodiment, one or more regions of the glass-ceramic part still includes one or more regions of glass (e.g., having a randomly arranged atomic structure) after the selective heat treatment along with one or more regions of glass-ceramic (e.g., having an ordered crystalline structure). In another embodiment, the glass-ceramic part does not include regions of glass after the selective heat treatment. 
     Heat treatment and the resulting change in the atomic structure (e.g., crystal growth) may result in one or more regions of a glass-ceramic part having different material properties than the glass from which it was formed. The material properties that may change include optical properties (e.g., transparency), Young&#39;s modulus (e.g., stiffness), strength (e.g., ability to withstand stress without fracture), fracture toughness (e.g., ability of a cracked glass part to withstand stress without fracture), and/or hardness (e.g., ability to resist abrasion). Heat treatment may affect the transparency a glass-ceramic part, for example by inducing an optical haze. In one embodiment, haze in the glass-ceramic part is caused by crystal growth in the glass-ceramic in which the crystals are of a sufficient size and/or density to scatter light. 
     Detailed embodiments of these general considerations will now be disclosed in relation to the accompanying figures. 
       FIG. 1  illustrates an example electronic device  100  that may incorporate selectively heat-treated glass-ceramics, according to one or more embodiments presented herein. The electronic device  100  includes a device housing  104  and cover sheet  102  affixed to the device housing. The cover sheet  102  may be formed of a selectively heat-treated glass-ceramic material. The electronic device  100  may additionally include a camera  110 , a display  111 , one or more buttons  112 , and/or an output device (such as a speaker)  113 . 
     The cover sheet  102  may be disposed at any of several locations on (or in) the device housing  104 . For example, the cover sheet  102  may be positioned at least partially over the display  111  of the electronic device  100  as depicted in  FIG. 1 . The cover sheet  102  may define one or more exterior surfaces of the electronic device  100 . In the embodiment of  FIG. 1 , the cover sheet  102  defines a top surface  103  of the electronic device  100 . The cover sheet  102  may include one or more openings, such as an opening to allow inputs at the button  112 , an opening adjacent the speaker  113 , and so on. Alternatively or additionally, the cover sheet  102  may be positioned on a different surface or portion of an electronic device  100 , such as a sidewall, a top surface, a bottom surface, and the like. 
     The electronic device  100  can also include one or more internal components (not shown) typical of a computing or electronic device, such as, for example, one or more processors, memory components, network interfaces, and so on. Furthermore, although the electronic device  100  is illustrated as a cellular phone, It should be appreciated that any number of electronic devices may incorporate a selectively heat-treated glass-ceramic part, including (but not limited to): a computer, a laptop computer, a tablet computer, a phone, a wearable device, a health monitoring device, a home or building automation device, a home or building appliance, a craft or vehicle entertainment, control, and/or information system, a navigation device, a personal digital assistant, a media player, a watch, another wearable device, a touch-sensitive device, a keypad, a keyboard, and so on. 
     The device housing  104  provides a device structure, defines an internal volume of the electronic device  100 , and houses device components. In various embodiments, the device housing  104  may be constructed from any suitable material, including metals (e.g., aluminum, titanium, and the like), polymers, ceramics (e.g., glass, sapphire), and the like. In one embodiment, the device housing  104  is constructed from multiple materials. The device housing  104  can form an outer surface or partial outer surface and protective case for the internal components of the electronic device  100 . 
     The display  111  can be implemented with any suitable technology, including, but not limited to liquid crystal display (LCD) technology, light emitting diode (LED) technology, organic light-emitting display (OLED) technology, organic electroluminescence (OEL) technology, or another type of display technology. The display  111  provides a graphical output, for example associated with an operating system, user interface, and/or applications of the electronic device  100 . In one embodiment, the display  111  includes one or more sensors and is configured as a touch-sensitive (e.g., single-touch, multi-touch) and/or force-sensitive display to receive inputs from a user. In various embodiments, a graphical output of the display  111  is responsive to inputs provided at the display and/or the buttons  112 . 
     As discussed above, in various embodiments, it may be desirable to have different material properties of the cover sheet  102  in different regions of the cover sheet. For example, different properties may be appropriate in different regions of the cover sheet  102  based on the position of the regions with respect to other device components. Accordingly, the cover sheet  102  may be manufactured or otherwise processed to achieve different material properties within different regions of the cover sheet. 
     One method for achieving different material properties within different regions of the cover sheet is to selectively heat treat the cover sheet  102 . As discussed above, heat treatment may change the material properties of the cover sheet, such as Young&#39;s modulus, strength, fracture toughness, and/or hardness. However, heat treatment may also effect the transparency part of the cover sheet, for example by inducing an optical haze. In one embodiment, haze in the glass is caused by crystal growth in the cover sheet in which the crystals are of a sufficient size and/or density within the cover sheet to scatter light. 
       FIGS. 2A and 2B  illustrate example selective heat treatment patterns for a glass-ceramic cover sheet of an electronic device. In various embodiments, the selective heat treatment patterns result in different material properties in different regions of the cover sheet. 
       FIG. 2A  illustrates an example selective heat treatment pattern for the cover sheet  102  in which the region  204  of the cover sheet that is not adjacent to the camera or the display is selectively heat treated, for example to increase the strength, fracture toughness, and/or hardness of the region. Similarly,  FIG. 2B  illustrates an example selective heat treatment pattern for the cover sheet  102  in which the selectively heat-treated region  204  corresponds to areas of the cover sheet near the edges and corners of the device. These areas may be more likely to suffer damage than areas farther from the edges of the device and so may be treated to increase their strength and/or toughness (e.g., resistance to impact). 
     Regions  204  and  206  are adjacent to the display and the camera, and so may have sufficient transparency to avoid distortion of information and images. Further, regions  204  and  206  and/or farther from the edges of the electronic device, so they may be less susceptible to damage. In one embodiment, these regions are not heat treated to maximize the optical performance of the glass. In other embodiments, regions  204  and  206  may be heat treated, but not to a degree that induces an optical haze that affects the transparency of the glass. 
     In various embodiments, the electronic device  100  may have multiple different regions having different objectives for material properties such as optical properties, strength, fracture toughness, hardness, and the like. Different regions may be selectively heat treated to achieve desired results. 
       FIG. 3  is a simplified flow chart depicting an example process for manufacturing a selectively heat-treated glass-ceramic part (e.g., the cover sheet of  FIGS. 1 and 2 ) as described herein. In the process  300  shown in  FIG. 3 , elemental constituents are formed into a glass and subsequently heat treated to form a glass-ceramic.  FIG. 4  is a chart illustrating an example heat treatment temperature profile over time for the example process described with respect to  FIG. 3 . 
     Referring now to  FIG. 3 , the process  300  includes operation  302  in which elemental constituents are heated to a temperature at or above their melting point using a heat source (e.g., a furnace, kiln, laser, or the like). The elemental constituents may be a glass-ceramic system, such as an LAS system (Li 2 O×Al 2 O 3 ×nSiO 2 ), an MAS system (MgO×Al 2 O 3 ×nSiO 2 ), a ZAS system (ZnO×Al 2 O 3 ×nSiO 2 ), or a different combination of materials. The elemental constituents may include nucleating agents such as silver, gold, platinum, palladium, zirconium oxide and/or titanium oxide. In one embodiment, the melting point may be at or above 1600 degrees Celsius. Turning to the example of  FIG. 4 , the heating to the temperature at or above the melting point is shown by the temperature increase between position  401  and position  402 . 
     Returning to  FIG. 3 , at operation  304 , the melted elemental constituents are solidified (e.g., cooled) to form a glass part. In one embodiment, the glass part has a randomly arranged atomic structure. The glass part may be formed without any ceramic particles therein, but instead with components or elements that may precipitate to form nucleates that may be grown into ceramic particles. In other embodiments, the glass part is formed with ceramic particles, for example based on thermal conditions during the cooling process. In the example of  FIG. 4 , the glass cooling process is shown as the temperature decreases between positions  402  and  404 . In one embodiment, solidification begins between 1200 degrees Celsius and 1300 degrees Celsius. Cooling may continue at this stage to room temperature. Following operation  304 , the glass part may be inspected and/or formed into an appropriate shape. This may involve cutting, polishing, and other processes to achieve the appropriate shape for the eventual use of the glass part. 
     Returning to  FIG. 3 , after the glass part is formed, the glass part may be heat treated to form a glass-ceramic. At operation  306 , at least a portion of the glass part is heated to a temperature at or above a nucleation temperature of the material to create nucleation sites. In the example of  FIG. 4 , the nucleation operation  306  is shown as the temperature increases between positions  405  and  406 , and temperature being maintained between positions  406  and  407 . As used herein, “nucleation temperature” generally refers to a temperature at which substantial nucleation occurs in the glass part. Nucleation is the process by which nucleation sites self-organize in the glass part. Nucleation sites are sites where crystal growth may occur under the right temperature conditions. In one embodiment, the elemental constituents include one or more nucleating agents to enhance the nucleation process, such as silver, gold, platinum, palladium, zirconium oxide and/or titanium oxide. In one embodiment, the nucleation temperature is between 700 and 800 degrees Celsius. In another embodiment, the nucleation temperature is between 600 and 900 degrees Celsius. In still another embodiment, the nucleation temperature is between 500 and 1000 degrees Celsius. 
     As discussed above, different regions of the glass part may be heated to different temperatures and/or at different rates during operation  306  to achieve different nucleation rates and/or densities in different regions of the part. This results in different atomic structures within the different regions of the glass-ceramic part that is formed.  FIG. 5A  illustrates a cross-section of an example glass part  500  having a first region  501  and a second region  502 , with a border  505  separating the regions. In one embodiment, during a nucleation operation such as operation  306 , the first region  501  of the glass part  500  may be heated to a temperature at or above a nucleation temperature of the glass part  500  and maintained for a period of time, while the second region  502  may be maintained at a different temperature below the nucleation temperature of the glass part  500 . As shown in  FIG. 5A , this may result in a higher density of nucleation sites  510  in the first region  501  than in the second region  502 . In one embodiment, no nucleation sites  510  are formed in the second region  502 . In another embodiment shown in FIG.  5 A, nucleation sites  510  are formed in the second region  502 , but at a lesser density than the nucleation sites  510  in the first region  501 . In still another embodiment, the entire glass part is heated uniformly during operation  306 , so nucleation is substantially consistent across the entire glass part. Selective nucleation is discussed in more detail below with respect to  FIG. 12 . 
     Returning to  FIG. 3 , during operation  308 , at least a portion of the glass part is heated to a temperature at or above a crystallization temperature of the glass part to induce crystal growth that results in the conversion of the glass to a glass-ceramic. In the example of  FIG. 4 , the crystallization operation  308  is shown as the temperature increases between position  407  and  408  and the temperature being maintained between positions  408  and  409 . As used herein, “crystallization temperature” generally refers to a temperature at which substantial crystal growth occurs. Crystal growth is the arrangement of atoms, molecules, or ions into an orderly repeating pattern extending in all three spatial dimensions, which results in a glass-ceramic. In one embodiment, the crystallization temperature is between 750 and 850 degrees Celsius. In another embodiment, the crystallization temperature is between 650 and 950 degrees Celsius. In still another embodiment, the crystallization temperature is between 550 and 1050 degrees Celsius. 
     As discussed above, different regions of the glass part may be heated to different temperatures and/or at different rates during operation  308  to achieve differing crystal growth rates and/or densities in different regions of the glass-ceramic part that is formed as a result of the heat treatment.  FIG. 5B  illustrates a cross-section of an example glass-ceramic part  550  that has undergone a conversion from a glass to a glass-ceramic. The glass-ceramic part  550  has a first region  551  and a second region  552 , and a border  555  separating the regions. In one embodiment, during a crystallization operation such as operation  308 , the first region  551  may be heated to a temperature at or above a crystallization temperature of the material and maintained for a period of time, while a second region  552  may be maintained at a different temperature below the crystallization temperature of the material. This may result in a higher rate of crystal growth of crystals  560  in the first region  551  than in the second region  552 . As shown in  FIG. 5B , the first region thus has a larger average crystal size than the second region. In one embodiment, no crystal growth occurs in the second region. In another embodiment, crystal growth occurs in the second region, but at a lower rate than the crystal growth in the first region. In still another embodiment, both regions  551  and  552  are heated uniformly during operation  306 , so crystal growth is substantially consistent across the entire part. Selective crystal growth is discussed in more detail below with respect to  FIG. 12 . 
     In the embodiments of  FIGS. 5A and 5B , the nucleation sites and crystals are shown with circular cross-sections for illustrative purposes. In practice, the nucleation sites and crystals may take a variety of shapes and have varying cross-sections according to their structure. 
     Returning to  FIG. 3 , at operation  310 , the glass-ceramic part is cooled after the crystallization operation  308 . In the example of  FIG. 4 , the cooling operation is shown as the temperature decrease from position  409  to position  410 . Optionally, the glass-ceramic part may undergo additional finishing and/or pressing operations. 
     In the operations of  FIG. 3 , changes to the timing of the various steps will result in different material properties. For example, the longer a region of a glass-ceramic part that is maintained at or above its crystallization temperature, the more crystal growth will occur. Similarly, rates of change of the temperatures and the temperature values themselves will affect the properties as well. Thus, adjusting the time at temperature, rate of change, and/or temperature values for each of the steps will result in different outcomes and material properties. 
     After the heat treatment of the glass-ceramic part (e.g., the nucleation and crystallization operations), at least a portion of the glass-ceramic part may have a polycrystalline structure, in which a number of single crystals or crystallites are held together by layers of amorphous solid. The polycrystalline structure of the glass-ceramic part may result in the glass-ceramic part having different material properties than an untreated glass part, such as hardness, modulus, density, optical properties, chemical resistivity, and viscosity at elevated temperatures. 
       FIGS. 6-11B  illustrate glass parts undergoing selective heat treatment to form a glass-ceramic part using a variety of methods. In various embodiments, the heat treatment may include nucleation and/or crystallization operations as described above. In general, the methods described with respect to  FIGS. 6-11B  are directed to heating and/or cooling one or more regions of a glass part differently than one or more other regions of the glass part. The methods described with respect to  FIGS. 6-10  are applicable to applying or removing heat during nucleation operations, crystallization operations, and other heat treatment operations. 
       FIG. 6  shows a glass part  600  undergoing selective heat treatment to form a glass-ceramic part using a laser  610 . In various embodiments, a laser is used to heat a first region  601  of the glass part  600 , while not applying heat (or applying less heat) to a second region  602 . In one embodiment, the laser beam  611  is a focused beam capable of delivering energy to a beam spot. In another embodiment, the laser beam  611  is a broad beam configured to deliver energy to a wide area. In this embodiment, a mask may be applied to the second region  602  to shield the second region from at least a portion of the energy transmitted by the laser beam  611 . 
     In various embodiments, the laser  610  may be configured to deposit energy at a particular depth (e.g., a certain distance from the top surface or bottom surface of the glass part  600  with respect to  FIG. 6 ). Depositing energy at a particular depth allows the laser to heat the first region  601  of the glass part  600  more uniformly throughout its thickness than heat applied to an exterior surface. Accordingly, a border between the regions  601 ,  602  may be more finely controlled and substantially perpendicular to the top and bottom surfaces as shown in  FIG. 6 . 
     In one embodiment, the laser  610  is used in conjunction with one or more heat sources (e.g., a furnace, a conductive coating, and the like) and/or temperature regulation mechanisms (e.g., a heat sink, a low-emissivity coating, a gas or liquid cooling device, and the like). In one embodiment, the laser  610  is used in conjunction with a furnace. The entire glass part  600  may be placed in a furnace to achieve a temperature that is near, but below, a significant temperature (e.g., the nucleation temperature, the crystallization temperature, and so on). Then, the laser  610  may be used to heat the first region  601  to a higher temperature (e.g., a temperature at or above the nucleation temperature or the crystallization temperature), while the second region  602  is maintained at the lower temperature. 
     In various embodiments, the laser  610  may be any suitable type of laser for applying energy to the glass part  600 . Examples include gas lasers, chemical lasers, solid state lasers, fiber lasers, photonic crystal lasers, semiconductor lasers, and so on. 
       FIG. 7  shows a glass part  700  undergoing selective heat treatment to form a glass-ceramic part using heat sinks  710 . In various embodiments, one or more heat sinks  710  are disposed adjacent to a first region  701  of the glass part  700 . The heat sinks  710  may be used to remove heat from the first region  701  of the glass part  700  while the glass part  700  is heated, for example in a furnace. The heat sinks  710  allow the first region  701  to be maintained at a lower temperature than a second region  702  that is not adjacent to the heat sinks  710 . In one embodiment, the heat sinks  710  are straight fin heat sinks as shown in  FIG. 7 . In other embodiments, the heat sinks may take many forms, such as pin fin heat sinks, flared fin heat sinks, or another type of heat sink. The heat sinks  710  may contact the glass part  700  or there may be a gap between the heat sinks  710  and the glass part  700 . 
     In various embodiments, the heat sink  710  transfers heat from the glass part  700  to a fluid medium. In one embodiment, the fluid medium is air. In another embodiment, the fluid medium is another gas or liquid such as a coolant. The heat sink  710  may be formed of any suitable material for conducting heat, such as copper, aluminum, or the like. The heat sink  710  may be used alone or in combination with other heating and/or temperature regulation operations such as those described herein. 
       FIG. 8  shows a glass part  800  undergoing selective heat treatment to form a glass-ceramic part using a conductive coating  810  to inductively heat a portion of the glass part. In various embodiments, the conductive coating  810  is disposed adjacent to a first region  801  of the glass part  800 . The conductive coating  810  may be applied to one or more surfaces of the glass part  800 . An electrical current may then be applied to the conductive coating  810 , which results in inductive heating of the first region  801  of the glass part  800 , while the second region  802  is not heated (or heated less). The conductive coating  810  may be formed of any suitable conductive material, such as copper. The conductive coating  810  may be used alone or in combination with other heating and/or temperature regulation operations such as those described herein. 
       FIG. 9  shows a glass part  900  undergoing selective heat treatment to form a glass-ceramic part using a low-emissivity coating  910  to shield a portion of the glass part. In various embodiments, the low-emissivity coating  910  is disposed adjacent to a first region  901  of the glass part  900 . The low-emissivity coating  910  may be applied to one or more surface of the glass part  800 . In various embodiments, heat is applied to the glass part  900 , for example using one or more of a furnace, laser, conductive coating(s), or the like. The low-emissivity coating  910  shields the first region  901  and allows less heat energy into the first region  901 , and thus results in a lower temperature of the first region than the second region  902 . The low-emissivity coating  910  may be any suitable material for blocking heat energy, such as silver. In one embodiment, the low-emissivity coating  910  is a layer of silver with a thickness between 1 and 5 nanometers. The low-emissivity coating  910  may be used alone or in combination with other heating and/or temperature regulation operations such as those described herein. 
       FIG. 10  shows a glass part  1000  undergoing selective heat treatment to form a glass-ceramic part using a gas and/or fluid cooling device  1010 . In various embodiments, heat is applied to the glass part  1000 , for example using one or more of a furnace, laser, conductive coating(s), or the like. The cooling device  1010  regulates the temperature of a first region  1001  of the glass part  1000  while the glass part  1000  is heated such that a second region  1002  experiences higher temperatures and/or higher rates of temperature increases compared to the first region  1001 . Regulating the temperature may include cooling the first region  1001 , maintaining the temperature of the first region  1001 , and/or reducing a rate of temperature increase of the first region  1001 . The cooling device  1010  may be any suitable device for applying a coolant, such as a gas or liquid. The cooling device  1010  may be used alone or in combination with other heating and/or temperature regulation operations such as those described herein. 
     Selectively heat-treated glass-ceramic parts with multiple regions include borders between the regions that d have different material properties. Based on how heat is applied and/or removed from the different regions, the borders may include a gradient or transition zone in which the material properties gradually change from those consistent with the first region to those consistent with the second region. In one embodiment, this gradient exists in a direction perpendicular to the interface of the two regions (e.g., left-to-right or right-to-left with respect to  FIGS. 6-10 . For example, if a first region has a first median crystal size and a second region has a second median crystal size, the border may include a portion of the glass part where the median crystal size transitions from the first median crystal size to the second median crystal size. This is a result of temperature gradients that occur during heating. 
     Similarly, a glass-ceramic part that is heated from the surface (e.g., a top or bottom surface) during selective heat treatment may have different material properties at different distances from the surface of the glass-ceramic part because of different heating that occurs at different distances from the surface. Along a border between regions, this may result in a border that differs in its lateral position (e.g., left-to-right or right-to-left with respect to  FIGS. 7-10 ) through the thickness (e.g., upward-to-downward with respect to  FIGS. 7-10 ) of the glass-ceramic part. This is shown, for example, in  FIGS. 7-10 , where the border deviates toward each of the regions that were heated to a higher temperature in a middle part along the thickness of the glass-ceramic part. 
     In response to the issues described above, further processing may be used to mitigate the effects of the temperature gradients on the border.  FIGS. 11A and 11B  illustrate cross-sections of a selectively heat-treated glass-ceramic part showing a laser for performing additional heat treatment along a border between regions of the selectively heat-treated glass-ceramic part.  FIG. 11A  illustrates an actual border  1105   a  and a desired border  1105   b  between differently treated regions  1101  and  1102  of a glass-ceramic part  1100 . In the example of  FIG. 11A , region  1101  was treated at a higher temperature than region  1102 , and the interior of the glass-ceramic part did not reach as high of a temperature for as long as the exterior portions, resulting in an actual border  1105   a  that deviates from the desired border  1105   b . The actual border  1105   a  is similar to the borders of  FIGS. 7-10 , and differs in its lateral position through the thickness of the glass-ceramic part  1100 , as indicated by its curved shape in cross-section. 
     In  FIG. 11A , a laser  1110  with a focused beam  1111  similar to the laser and beam described with respect to  FIG. 6  is used to deposit energy into the part of the region  1102  that is between the actual border  1105   a  and the desired border  1105   b . The energy may be deposited at particular “depths” within the glass-ceramic part  1100  (e.g., different distances from the surfaces). In particular, the laser  1110  may deposit more energy at positions that are in the interior of the glass-ceramic part  1100  (e.g., not close to the top or bottom surface) to target the area between the actual border  1105   a  and the desired border  1105   b  for additional heat treatment. The additional heat treatment may result in the area between the actual border  1105   a  and the desired border  1105   b  transitioning from having material properties consistent with the region  1102  to having material properties consistent with the region  1101 . This effectively moves the actual border  1105   a  to be substantially the same as the desired border  1105   b , as shown in  FIG. 11B . 
       FIG. 12  is a simplified flow chart depicting an example process  1200  for forming a selectively heat-treated glass-ceramic part as described herein. As discussed throughout this application, nucleation and/or crystal growth within different regions of a glass part may be controlled to achieve desired material properties in each region of the resulting glass-ceramic part. For example, as discussed above, a first region may be designed for an area of an electronic device that is more susceptible to damage and/or that is not adjacent to a display, camera, or other sensor. In such a situation, it may be desirable to increase properties such as hardness, strength, and/or fracture toughness within the first region, while transparency may be less important. Conversely, a second region may be designed for an area of an electronic device that is adjacent to a display, camera and/or another sensor. Thus, transparency may be a very important property for the second region. 
     Crystal growth in the glass part results in conversion to a glass-ceramic having different material properties than the glass part, such as increased hardness, strength, fracture toughness, and the like. Depending on their size and/or density, crystals may also contribute to scattering of light, thereby creating a haze within the glass-ceramic part. This haze may distort graphics transmitted through the glass-ceramic part (e.g., by a display), images collected through the glass-ceramic part (e.g., by a camera), or other data collected by sensors adjacent to the glass-ceramic part, such as fingerprint sensors and the like. As a result, in a situation similar to the one discussed above, it may be appropriate to induce crystal growth in the first region, while limiting or prohibiting crystal growth in the second region. This may be achieved by creating conditions in which different nucleation, crystal growth, or both occur in the different regions. This may include heating and/or maintaining the different regions at different temperatures. It may also include adjusting rates of temperature changes and the times the regions of the part are maintained at certain temperatures. 
     At operation  1202 , a first region of a glass part is heated to a first temperature at or above the nucleation temperature of the glass part. Heat is applied to the glass part, for example using one or more of a furnace, laser, conductive coating(s), or the like. The first region may be maintained at the first temperature for a period of time while nucleation occurs in the first region. During nucleation, nucleation sites are formed within the first region. The nucleation sites have an associated density (e.g., nucleation sites per volume). 
     At operation  1204 , while the first region is at the first temperature, a second region of the glass part is maintained below the first temperature. The temperature may be maintained by a heat sink, a low-emissivity coating, a cooling device, or the like, or the positioning of a heat source such as a laser, furnace, or conductive coating. In one embodiment, the second region is maintained below the nucleation temperature of the glass part such that nucleation does not occur. In another embodiment, the temperature of the second region exceeds the nucleation temperature, so nucleation occurs, but at a slower rate and/or lesser density than nucleation in the first region. As a result, the first region may have a higher density of nucleation sites than the second region. 
     At operation  1206 , the first region of the glass part is heated to a second temperature that is at or above the crystallization temperature of the glass part. The first region may be maintained at the second temperature for a period of time while crystallization occurs in the first region. During crystallization, crystals form and grow at nucleation sites within the first region, thereby converting the glass part to a glass-ceramic part. The crystals have an associated crystal density (e.g., crystals per volume). Each crystal also has an associated size, and a median or other average crystal size of a portion of the glass-ceramic part, such as the first region, may be determined. In one embodiment, nucleation occurs during the crystallization process as well, and crystal growth may occur at the new nucleation sites, thereby increasing the crystal density of the first region. As discussed above, crystal growth results in conversion of the glass part to a glass-ceramic part having different material properties than the glass part, such as increased hardness, strength, fracture toughness, elastic modulus, and the like. Depending on their size and/or density, crystals may also contribute to scattering of light, thereby creating a haze within the glass-ceramic part. 
     At operation  1208 , the second region is maintained below the second temperature. As discussed above, the temperature may be maintained by a heat sink, a low-emissivity coating, a cooling device, or the like, or the positioning of a heat source such as a laser, furnace, or conductive coating. In one embodiment, the second region is maintained below the crystallization temperature of the glass part such that crystal growth does not occur (e.g., the crystal density is zero). In another embodiment, the temperature of the second region exceeds the crystallization temperature, so crystal growth may occur, but at a slower rate and/or lesser density than crystal growth in the first region. As a result, the first region may have a higher density of and larger median size of crystals than the second region. 
     In various embodiments, the glass-ceramic part may undergo further processing for preparation and installation in an electronic device. Further processing may include polishing, finishing, and the like. In one embodiment, a mask is applied to the first region to mask the haze in the glass. For example, a mask may be applied to the first region around a periphery of a display of an electronic device (e.g., at least partially surrounding the display) to conceal the haze. The mask may be formed from an ink (e.g., an opaque ink) applied to the glass. In another embodiment, the mask is a translucent or opaque film or other covering. 
     In various embodiments, the steps of method  1200  are performed in a different order or with more or fewer steps. In one embodiment, selective heating occurs at either the nucleation phase or the crystallization phase. For example, the first and second regions may be heated to the first temperature in operation  1202 , operation  1204  would be eliminated from the process, and different rates of crystal growth would occur during operations  1206  and  1208 . Alternatively, different nucleation may occur during operations  1202  and  1204 , and then the first and second regions may be heated to the second temperature in operation  1206 , and operation  1208  would be eliminated. 
       FIG. 13  is an illustrative block diagram  1300  of an electronic device that may incorporate a glass-ceramic part as described herein (e.g., electronic device  100 ). The electronic device can include a display  1310 , one or more processing devices  1302 , memory  1304 , one or more audio input/output (I/O) devices  1306 , one or more input/output (I/O) devices  1308 , one or more haptic output devices  1314 , a power source  1312 , and a network communication interface  1316 . 
     The display  1310  may provide an image or graphical output (e.g., computer-generated image data) for the electronic device. The display may also provide an input surface for one or more input devices, such as, for example, a touch sensing device and/or a fingerprint sensor. The display  1310  may be substantially any size and may be positioned substantially anywhere on the electronic device. 
     The processing device  1302  can control some or all of the operations of the electronic device. The processing device  1302  can communicate, either directly or indirectly, with substantially all of the components of the electronic device. For example, a system bus or signal line or other communication mechanisms (e.g., electronic connectors) can provide communication between the processing device(s)  1302 , the memory  1304 , the I/O device(s)  1306 , 1308 , the display  1310 , the power source  1312 , the haptic output device(s)  1314 , and/or the network communication interface  1316 . The one or more processing devices  1302  can be implemented as any electronic device capable of processing, receiving, or transmitting data or instructions. For example, the processing device(s)  1302  can each be a microprocessor, a central processing unit, an application-specific integrated circuit, a field-programmable gate array, a digital signal processor, an analog circuit, a digital circuit, or combination of such devices. The processor may be a single-thread or multi-thread processor. The processor may be a single-core or multi-core processor. 
     Accordingly, as described herein, the phrase “processing device” or, more generally, “processor” refers to a hardware-implemented data processing unit or circuit physically structured to execute specific transformations of data including data operations represented as code and/or instructions included in a program that can be stored within and accessed from a memory. The term is meant to encompass a single processor or processing unit, multiple processors, multiple processing units, analog or digital circuits, or other suitably configured computing element or combination of elements. 
     The memory  1304  can store electronic data that can be used by the electronic device. For example, a memory can store electrical data or content such as, for example, audio and video files, documents and applications, device settings and user preferences, timing signals, signals received from the one or more sensors, one or more pattern recognition algorithms, data structures or databases, and so on. The memory  1304  can be configured as any type of memory. By way of example only, the memory can be implemented as random access memory, read-only memory, Flash memory, removable memory, or other types of storage elements, or combinations of such devices. 
     The one or more I/O devices  1306 ,  1308  can transmit and/or receive data to and from a user or another electronic device. The I/O device(s)  1306 ,  1308  can include a display, a touch or force sensing input surface such as a trackpad, one or more buttons, one or more microphones or speakers, one or more ports such as a microphone port, one or more accelerometers for tap sensing, one or more optical sensors for proximity sensing, and/or a keyboard. 
     The power source  1312  can be implemented with any device capable of providing energy to the electronic device. For example, the power source  1312  can be one or more batteries or rechargeable batteries, or a connection cable that connects the electronic device to another power source such as a wall outlet. 
     The haptic output devices  1314  can facilitate production of haptic outputs (e.g., tactile outputs), for example using a haptic actuator. For example, an input surface may provide feedback in response to a sensed touch, to confirm an input, and so on. 
     The network communication interface  1316  can facilitate transmission of data to or from other electronic devices. For example, a network communication interface can transmit electronic signals via a wireless and/or wired network connection. Examples of wireless and wired network connections include, but are not limited to, cellular, Wi-Fi, Bluetooth, IR, and Ethernet. 
     It should be noted that  FIG. 13  is for illustrative purposes only. In other examples, an electronic device may include fewer or more components than those shown in  FIG. 13 . Additionally or alternatively, the electronic device can be included in a system and one or more components shown in  FIG. 13  are separate from the electronic device but included in the system. For example, an electronic device may be operatively connected to, or in communication with a separate display. As another example, one or more applications can be stored in a memory separate from the wearable electronic device. The processing unit in the electronic device can be operatively connected to and in communication with the separate display and/or memory. 
     Although many embodiments reference a selectively heat-treated glass-ceramic part in a portable electronic device (such as a cell phone or tablet computer) it may be appreciated that a selectively heat-treated glass-ceramic part can be incorporated into various electronic devices, mechanical devices, electromechanical devices and so on, including but not limited to: portable electronic devices (e.g., battery-powered, wirelessly powered devices, tethered devices, and so on); stationary electronic devices; control devices (e.g., home automation devices, industrial automation devices, aeronautical or terrestrial vehicle control devices, and so on); personal computing devices (e.g., cellular devices, tablet devices, laptop devices, desktop devices, and so on); wearable devices (e.g., implanted devices, wrist-worn devices, eyeglass devices, and so on); accessory devices (e.g., protective covers such as keyboard covers for tablet computers, stylus input devices, charging devices, and so on); and so on. 
     One may appreciate that although many embodiments are disclosed above, that the operations and steps presented with respect to methods and techniques described herein are meant as exemplary and accordingly are not exhaustive. One may further appreciate that alternate step order or fewer or additional operations may be required or desired for particular embodiments. 
     Although the disclosure above is described in terms of various exemplary embodiments and implementations, it should be understood that the various features, aspects and functionality described in one or more of the individual embodiments are not limited in their applicability to the particular embodiment with which they are described, but instead can be applied, alone or in various combinations, to one or more of the some embodiments of the invention, whether or not such embodiments are described and whether or not such features are presented as being a part of a described embodiment. Thus, the breadth and scope of the present invention should not be limited by any of the above-described exemplary embodiments but is instead defined by the claims herein presented.

Metadata:
Filing Date: 20180522
Publication Date: 20210720
Grant Date: 20210720
Priority Date: 20171201
Inventors: JONES, CHRISTOPHER D.
ROGERS, MATTHEW S.
NGUYEN, Que Anh S.
Assignee: APPLE INC
CPC Classifications: [{"code": "H04M1/0266", "inventive": true, "first": false, "tree": "[]"}, {"code": "C03B32/02", "inventive": true, "first": true, "tree": "[]"}, {"code": "G06F2200/1634", "inventive": false, "first": false, "tree": "[]"}, {"code": "G06F1/1637", "inventive": true, "first": false, "tree": "[]"}, {"code": "G06F1/1626", "inventive": false, "first": false, "tree": "[]"}, {"code": "G06F1/1626", "inventive": false, "first": false, "tree": "[]"}, {"code": "C03B32/02", "inventive": true, "first": true, "tree": "[]"}, {"code": "H04M1/0266", "inventive": true, "first": false, "tree": "[]"}, {"code": "G06F2200/1634", "inventive": false, "first": false, "tree": "[]"}, {"code": "C03B32/02", "inventive": true, "first": true, "tree": "[]"}, {"code": "G06F1/1626", "inventive": false, "first": false, "tree": "[]"}, {"code": "G06F2200/1634", "inventive": false, "first": false, "tree": "[]"}, {"code": "H04M1/0266", "inventive": true, "first": false, "tree": "[]"}]
Family ID: 66658413