PATENT DOCUMENT

Publication Number: US-10845665-B1
Application Number: US-201615295142-A
Country: US
Kind Code: B1

Title: Devices with guest-host liquid crystal modulators

Abstract:
A window may be provided with a light modulator. The light modulator may be dynamically adjusted to control visible light transmission through the window. The window may also have layers that selectively block light with non-visible wavelengths. The light-blocking layers may block ultraviolet light, near infrared light such as light from solar radiation, and far infrared light such as heat produced due to the absorption of visible light by the light modulator. The light modulator may be a guest-host liquid crystal light modulator. The guest-host liquid crystal light modulator may have a layer of liquid crystal material with dye that is interposed between polymer substrate layers. The polymer substrate layers may be thermoplastic layers that are moldable to conform to window shapes with compound curves.

Claims:
What is claimed is: 
     
       1. A system, comprising:
 structures that form an interior region that is separated from an exterior region; and 
 a window in the structures that is interposed between the interior region and the exterior region, wherein the window includes:
 a guest-host liquid crystal light modulator; and 
 a layer configured to block infrared light emitted by the guest-host liquid crystal light modulator, wherein the layer that is configured to block the infrared light comprises:
 a metal layer, 
 a metal oxide barrier layer that directly contacts the metal layer, and 
 a crystalline oxide seed layer that directly contacts the metal oxide barrier layer, wherein the metal oxide barrier layer is interposed between the crystalline oxide seed layer and the metal layer. 
 
 
 
     
     
       2. The system defined in  claim 1  wherein the layer that is configured to block the infrared light comprises at least two metal layers. 
     
     
       3. The system defined in  claim 1  wherein the metal layer comprises a silver layer. 
     
     
       4. The system defined in  claim 3  wherein the crystalline oxide seed layer comprises zinc oxide. 
     
     
       5. The system defined in  claim 1  wherein the window further comprises at least one glass layer and a polymer layer on the glass layer that is interposed between the layer that is configured to block the infrared light and the glass layer. 
     
     
       6. The system defined in  claim 1  wherein the guest-host liquid crystal light modulator comprises dichroic dye. 
     
     
       7. The system defined in  claim 6  wherein the dichroic dye comprises a mixture of azo dye and anthraquinone dye. 
     
     
       8. The system defined in  claim 1  wherein the window further comprises first and second glass layers, wherein the guest-host liquid crystal modulator is interposed between the first and second glass layers. 
     
     
       9. The system defined in  claim 8  further comprising an ultraviolet light blocking filter layer between the first glass layer and the guest-host liquid crystal modulator. 
     
     
       10. The system defined in  claim 1  wherein the light emitted by the guest-host liquid crystal light modulator comprises light with wavelengths from 8 microns to 10 microns, wherein the layer that is configured to block infrared light emitted by the liquid crystal light modulator is configured to block the light with the wavelengths from 8 microns to 10 microns and is configured to block near-infrared light with wavelengths from 700 nm to 2.5 microns. 
     
     
       11. The system defined in  claim 1  wherein the guest-host liquid crystal light modulator has pixelated transparent electrodes. 
     
     
       12. The system defined in  claim 1  wherein the guest-host liquid crystal light modulator has first and second polymer substrates and wherein the first and second polymer substrates comprise thermoplastic material that is configured to be molded to form a shape with compound curves. 
     
     
       13. The system defined in  claim 1  wherein the guest-host liquid crystal light modulator has a layer of liquid crystal molecules and dye molecules interposed between first and second transparent conductive electrodes and wherein the layer of liquid crystal molecules and dye molecules has a thickness that varies across the guest-host liquid crystal light modulator. 
     
     
       14. The system defined in  claim 1 , wherein the metal oxide barrier layer comprises titanium. 
     
     
       15. The system defined in  claim 14 , wherein the metal oxide barrier layer comprises titanium oxide, the metal layer comprises silver, and the crystalline oxide seed layer comprises zinc oxide. 
     
     
       16. A system, comprising:
 structures that form an interior region that is separated from an exterior region; and 
 a window in the structures that is interposed between the interior region and the exterior region, wherein the window includes:
 a guest-host liquid crystal light modulator; and 
 a layer configured to block infrared light emitted by the guest-host liquid crystal light modulator, wherein the guest-host liquid crystal light modulator has a layer of liquid crystal molecules and dye molecules interposed between first and second transparent conductive electrodes, wherein the guest-host liquid crystal light modulator has metal terminals that run along at least first and second edges of the transparent conductive electrodes, and wherein the metal terminals are configured to concurrently apply different voltages to the first and second edges that produce a voltage across the guest-host liquid crystal light modulator layer that varies linearly as a function of position along the first and second transparent conductive electrodes, the layer comprising:
 a metal layer, 
 a metal oxide barrier layer that directly contacts the metal layer, and 
 a crystalline oxide seed layer that directly contacts the metal oxide barrier layer, wherein the metal oxide barrier layer is interposed between the crystalline oxide seed layer and the metal layer. 
 
 
 
     
     
       17. The system defined in  claim 16 , wherein the metal layer comprises silver, the metal oxide barrier layer comprises titanium oxide, and the crystalline oxide seed layer comprises zinc oxide. 
     
     
       18. A system, comprising:
 structures that form an interior region that is separated from an exterior region; and 
 a window in the structures that is interposed between the interior region and the exterior region, wherein the window includes:
 a guest-host liquid crystal light modulator; and 
 a layer configured to block infrared light emitted by the guest-host liquid crystal light modulator, wherein the guest-host liquid crystal light modulator has a layer of liquid crystal molecules and dye molecules interposed between first and second transparent conductive electrodes, wherein the guest-host liquid crystal light modulator has respective first and second liquid crystal alignment layers on the first and second transparent conductive electrodes, and wherein the first liquid crystal alignment layer has different regions with different respective alignment directions that establish alignment directions for the liquid crystal molecules in the absence of an applied voltage, the layer comprising:
 a metal layer, 
 a metal oxide barrier layer that directly contacts the metal layer, and 
 a crystalline oxide seed layer that directly contacts the metal oxide barrier layer, wherein the metal oxide barrier layer is interposed between the crystalline oxide seed layer and the metal layer. 
 
 
 
     
     
       19. The system defined in  claim 18 , wherein the different respective alignment directions are varied in a stepwise fashion across a dimension of the guest-host liquid crystal light modulator.

Description:
This application claims the benefit of provisional patent application No. 62/289,810, filed on Feb. 1, 2016, which is hereby incorporated by reference herein in its entirety. 
    
    
     BACKGROUND 
     This relates generally to light modulators, and, more particularly, to devices with liquid crystal light modulators. 
     Mechanical shutters and electronic shutters have been used to control the transmission of light. For example, movable mechanical sunshades have been used to control the amount of light that passes through the windows of a building or vehicle. Electrochromic devices have also been used to control the amount of light that passes through windows. Electrochromic devices exhibit light transmission values that can be varied as a function of applied voltage. This allows electronic signals to be used to vary light transmission in place of the movement of mechanical systems. 
     It can be challenging to form a window light modulator with desired properties. If care it not taken, modulation speed will be too slow, light transmission in wavelength ranges of interest will be different than desired, and excessive haze or other optical defects will be present. 
     It would therefore be desirable to be able to provide improved light modulators. 
     SUMMARY 
     A window may be provided with a light modulator. The light modulator may be dynamically adjusted to control visible light transmission through the window. 
     The window may also have layers that selectively block light with non-visible wavelengths. The light-blocking layers may block ultraviolet light, near infrared light such as light from solar radiation, and far infrared light such as heat produced due to the absorption of visible light by the light modulator. The light-blocking layers may have multiple layers of crystalline metal on multiple respective crystalline oxide seed layers. Barrier layers may be formed between the metal layers and the oxide seed layers. 
     The light modulator may be a guest-host liquid crystal light modulator. The guest-host liquid crystal light modulator may have a layer of liquid crystal material with dye that is interposed between polymer substrate layers. The polymer substrate layers may be thermoplastic layers that are moldable to conform to window shapes with compound curves. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
         FIG. 1  is a schematic diagram of an illustrative system that includes a light modulator such as a liquid crystal light modulator in accordance with an embodiment. 
         FIG. 2  is a cross-sectional side view of an illustrative system with a window having a light modulator that serves as an interface between an interior portion of the system and the exterior environment surrounding the system in accordance with an embodiment. 
         FIG. 3  is a cross-sectional side view of an illustrative guest-host liquid crystal light modulator in accordance with an embodiment. 
         FIG. 4  is a graph in which light transmission has been plotted as a function of applied voltage to a light modulator in accordance with an embodiment. 
         FIG. 5  is a cross-sectional side view of illustrative equipment for fabricating a guest-host liquid crystal light modulator in accordance with an embodiment. 
         FIG. 6  is a top view showing edge sealant patterns that may be used when fabricating guest-host liquid crystal modulators using equipment of the type shown in  FIG. 5  in accordance with an embodiment. 
         FIG. 7  is a cross-sectional side view of a compression molding tool being used to shape a liquid crystal light modulator in accordance with an embodiment. 
         FIG. 8  is a cross-sectional side view of an illustrative three-metal-layer low-e layer for a window or other planar transparent layer with a liquid crystal modulator in accordance with an embodiment. 
         FIG. 9  is a cross-sectional side view of an illustrative two-metal-layer low-e layer for a window or other planar transparent layer with a liquid crystal modulator in accordance with an embodiment. 
         FIG. 10  is a graph in which light reflectivity for a window or other planar transparent layer with a low-e layer has been plotted as a function of wavelength in accordance of the present invention. 
         FIG. 11  is a cross-sectional side view of an illustrative system with a window having a light modulator and a low-e layer that serves as an interface between an interior portion of the system and the exterior environment surrounding the system in accordance with an embodiment. 
         FIG. 12  is a flow chart of illustrative steps involved in forming a window with a light modulator in accordance with an embodiment. 
         FIG. 13  is a diagram showing how a light modulator for a window may be provided with elongated terminals that allow light transmission gradients to be formed within the light modulator in accordance with an embodiment. 
         FIG. 14  is a graph of an illustrative control voltage that may be established across the light modulator of  FIG. 13  in accordance with an embodiment. 
         FIG. 15  is a graph showing how the light modulator of  FIG. 13  may exhibit a transmission gradient when controlled using a control voltage of the type shown in  FIG. 14  in accordance with an embodiment. 
         FIG. 16  is a diagram of an illustrative light modulator electrode arrangement with strip-shaped terminals that divide an electrode into multiple bands in accordance with an embodiment. 
         FIG. 17  is a diagram of another illustrative light modulator electrode arrangement in accordance with an embodiment. 
         FIG. 18  is a diagram of an illustrative pixelated electrode for a light modulator to control light transmission through a window in adjustable patterns in accordance with an embodiment. 
         FIG. 19  is a cross-sectional side view of an illustrative light modulator having a varying liquid crystal layer thickness in accordance with an embodiment. 
         FIG. 20  is a graph of illustrative light transmission characteristics associated with the light modulator of  FIG. 19  in on and off states in accordance with an embodiment. 
         FIG. 21  is a cross-sectional side view of an illustrative light modulator electrode showing how a liquid crystal alignment layer may be patterned in accordance with an embodiment. 
         FIG. 22  is a cross-sectional side view of an illustrative stacked light modulator having a pair of stacked light modulator cells in accordance with an embodiment. 
         FIG. 23  is a graph of illustrative light transmission characteristics for the cells and stacked light modulator of  FIG. 22  in accordance with an embodiment. 
     
    
    
     DETAILED DESCRIPTION 
     A light modulator may be used to control the amount of light passing through a window or other transparent structure. An illustrative system of the type that may be provided with a window having a light modulator is shown in  FIG. 1 . System  10  of  FIG. 1  may be an electronic device such as a computer or other equipment with a display, touch sensor, or other component that includes one or more transparent electrodes, may be an electronic device such as a computer or other electronic equipment having a camera or other component that senses light through structures having one or more transparent electrodes, may be an automobile, truck, airplane, or other vehicle that has windows through which it is desired to control light transmission, may be a building with windows through which it is desired to control light transmission, or may be other system that includes a window or other transparent structure through which light transmission is controlled. The use of light modulators to control the transmission of light through transparent structures such as windows (e.g., windows in building and vehicles) may sometimes be described herein as an example. This is, however, merely illustrative. Light modulators may be used in controlling light transmission through any suitable structures. 
     As shown in  FIG. 1 , system  10  may include control circuitry  12 . Control circuitry  12  may include storage and processing circuitry for supporting the operation of device  10 . The storage and processing circuitry may include storage such as hard disk drive storage, nonvolatile memory (e.g., flash memory or other electrically-programmable-read-only memory configured to form a solid state drive), volatile memory (e.g., static or dynamic random-access-memory), etc. Processing circuitry in control circuitry  12  may be used to control the operation of device  10 . The processing circuitry may be based on one or more microprocessors, microcontrollers, digital signal processors, baseband processors, power management units, audio chips, application specific integrated circuits, etc. 
     In some configurations, system  10  may include input-output devices  14  that allow data to be supplied to system  10  and that allow data to be provided from system  10  to external systems. Input-output devices  14  may include buttons, joysticks, scrolling wheels, touch pads, key pads, keyboards, microphones, speakers, tone generators, vibrators, cameras, sensors, light-emitting diodes and other status indicators, data ports, etc. A user can control the operation of this type of system by supplying commands through input-output devices  14  and may receive status information and other output from the system using the output resources of input-output devices  14 . If desired, input-output devices  14  may include one or more displays (e.g., organic light-emitting diode displays and other displays with arrays of light-emitting diodes, liquid crystal displays, electrophoretic displays, etc.). Displays may be touch screen displays that include a touch sensor for gathering touch input from a user or may be insensitive to touch. A touch sensor for a display may be based on an array of capacitive touch sensor electrodes, acoustic touch sensor structures, resistive touch components, force-based touch sensor structures, a light-based touch sensor, or other suitable touch sensor arrangements. 
     System  10  may include one or more light modulators. The light modulators may modulate the amount of light transmission through a window or other structure in response to control signals from control circuitry  12 . The light modulator may be any suitable electrically controlled light modulator. With one suitable arrangement, which is sometimes described herein as an example, system  10  may have a light modulator such as guest-host liquid crystal modulator  16 . Based on information from input-output devices  14  and/or other information, control circuitry  12  may apply signals to guest-host liquid crystal modulator  16  that direct modulator  16  to increase or decrease light transmission through modulator  16 . 
     Light modulator  16  may be incorporated into a window in system  10 . As shown in  FIG. 2 , for example, light modulator  16  may be incorporated into window  28  in structures  20 . Structures  20  may form walls in a building, the body of a vehicle, walls in a container, or other support structures for the window  28 . Window  28  in structures  20  separates interior  22  from exterior  24 . Examples of windows  28  that may include light modulators such as light modulator  16  include office building windows, windows in a home, vehicle windows such as a sunroof window in an automobile or truck, side and rear vehicle windows in an automobile or truck, or a strip-shaped part of a window such as an upper strip along the front window in an automobile or truck, window portions with other shapes on the front, rear, and/or side windows portions of side and rear windows. There may be one or more windows  28  with light modulators in system  10 . The arrangement of  FIG. 2  is merely illustrative. 
     Light modulator  16  may dynamically control the transmission of light from exterior  24  to interior  22  and from interior  22  to exterior  24 . For example, when it is desired to dim a room in a building, the visible light transmission of light modulator  16  may be decreased to decrease the amount of light  26  that is passing from exterior  24  to interior  22 . When it is desired to let more light pass into interior  22 , light modulator  16  may be adjusted to increase the visible light transmission of light modulator  16 . 
     Window  28  may contain one or more low-emissivity glass layers (sometimes referred to as low-e glass layers). The low-e glass of window  28  may exhibit low amounts of light transmission at infrared wavelengths. This type of infrared light blocking configuration may help avoid excessive heat transmission to interior  22 . For example, near-infrared light components of solar radiation in light  26  may be blocked by the low-e glass of window  28  rather than being passed into interior  22 . Visible light in light  26  that is blocked by modulator  16  may be emitted as far-infrared light (heat). The low-e glass of window  28  may also help block this far-infrared light. By blocking near-infrared and far-infrared light, low-e glass in window  28  may help reduce solar heat build up in the interior of a building, the interior of a vehicle, or the interior of a container or other structure. 
     A cross-sectional side view of an illustrative light modulator is shown in  FIG. 3 . Light modulator  16  of  FIG. 3  has transparent substrate layers  30  with conductive coatings that form electrodes  32 . The inner surfaces of electrodes  32  may be provided with a coating (rubbing layer) to help orient liquid crystal molecules in liquid crystal layer  38 . Liquid crystal layer  38  may be interposed between substrate layers  30 . Spacer structures such as spacer  33  may be used to ensure that layers  30  and electrodes  32  are separated from each other by a desired distance (i.e., spacers  33  may ensure that the separation between layers  30  and therefore the thickness of layer  38  has a value of about 5-15 microns or other suitable thickness). Spacers  33  may be formed from embossed features on substrate  30 , photolithographically formed structures on substrate  30 , microspheres, or other suitable spacer structures. 
     During operation, control signals may be applied to electrodes  32  from control circuitry  12  via terminals  40 . The control signals may control the transmission T of modulator  16 . For example, transmission T may be adjusted from a high level when the applied voltage V across terminals  40  is small to a low level when the applied voltage V across terminals  40  is high, as shown in the graph of  FIG. 4 . Voltage V may be, for example, an alternating current (AC) voltage. 
     Layers  30  may be formed from glass, plastic, ceramic, or other material. Layers  30  may, for example, be formed from transparent glass (e.g., glass that is transparent in visible wavelengths). If desired, layers  30  may be formed from plastic. For example, layers  30  may be plastic layers such as clear sheets of polycarbonate or other thermoplastic material. The thermoplastic sheets may be transparent at visible wavelengths. When formed from thermoplastic material, layers  30  may be molded into a desired shape under heat and pressure. For example, layers  30  may be molded into a shape having compound curves (e.g., in a configuration in which window  28  has glass layers with compound curves). The thickness of layers  30  may be about 100-300 microns, more than 150 microns, less than 250 microns, or other suitable thickness. 
     Liquid crystal modulator  16  may be a guest-host liquid crystal modulator. Liquid crystal layer  38  of guest-host liquid crystal modulator  16  may include liquid crystal molecules  34  (e.g., host molecules) and dye molecules  36  (e.g., guest molecules) that are rotated when molecules  34  are rotated by applied electric fields. Any suitable guest-host system may be used for liquid crystal layer  38  of modulator  16 . With one suitable arrangement, which may sometimes be described herein as an example, modulator  16  may contain a vertical alignment layer (e.g., a polyimide rubbing layer) on the inner surfaces of electrodes  32  to orient liquid crystal molecules  34  vertically in the absence of applied electric field to electrodes  40 . Dye molecules  36  may be associated with a dichroic dye having a concentration of about 1-2%, more than 0.5%, or less than 4%. Dye molecules  36  may include a mixture of two or more dyes. For example, the dye formed from molecules  36  may include a first dye such as an azo dye that exhibits a satisfactory contrast ratio (ratio between high and low light transmission) and a second dye such as an anthraquinone dye (a small molecule dye) that exhibits a satisfactory stability under exposure to light (e.g., ultraviolet light). The color of modulator  16  may be adjusted by selecting an appropriate mixture of dyes. For example, a black dye (e.g., a black azo dye) may be formed from 5-10 colored dyes that have a black appearance when combined. 
     Illustrative equipment for forming modulator  16  is shown in  FIG. 5 . In the example of  FIG. 5 , a continuous modulator layer  16  is being produced using a roll-based process. Other types of fabrication techniques may be used. The use of a roll-based process may help enhance production throughput. 
     With the illustrative arrangement of  FIG. 5 , lower and upper substrate portions  30  are attached to each other using rollers such as roller  60 . Before laminating substrates  30  to each other, the lower substrate  30  may be provided with spacers  33  using equipment  50  and  54 . Equipment  50  may include a rotating hollow drum with a central cylindrical photomask through which ultraviolet light exposes a layer of photoresist on the surface of substrate  30  so that subsequent development with photoresist development equipment  54  may form spacers  33 . If desired, spacers  33  may be formed by embossing techniques (e.g., using depressed portions on the drum of equipment  50  to create corresponding raised portions in substrate  30  that serve as spacers  33 ). Spacers  33  may also be formed by ink-jet printing, gravure printing, or other printing techniques (e.g., techniques in which liquid polymer is printed onto the surface of substrate  30  and cured by heat and/or application of ultraviolet light), by incorporating microspheres or other spacer structures, or by otherwise forming spacers  33 . 
     After forming spacers  33 , equipment  58  may deposit a ring of sealant  56  on the lower substrate among substrates  30 . Equipment  58  may be, for example, a printing drum, an ink-jet printer, a computer-controlled positioner that dispenses a bead of sealant from a needle dispenser, or other sealant deposition equipment. Roller  60  may press layers  30  together. Spacers  33  may maintain a desired distance between layers  30 . Sealant  56  may create a ring-shaped barrier that prevents outward lateral movement of liquid crystal material when liquid crystal material is introduced into the cavity formed between layers  30 . 
     The surfaces of layers  30  may be coated with a conductive material to form electrodes  32 . For example, layers  30  may be coated with silver nanowires before processing with equipment  50 ,  56 , and  60 . The silver nanowires may have a diameter of 25-100 nm, more than 30 nm, or less than 200 nm (as example). The lengths of the nanowires may be 0.1 to 100 microns, 1-20 microns, more than 3 microns, less than 15 microns, or other suitable length. Silver nanowire electrode structures may be highly conductive and flexible. The concentration of the silver nanowires in electrodes  32  may be sufficiently low to prevent undesired haze in modulator  16 . The thickness of the silver nanowire layer that forms electrodes  32  may be, as an example, less than 0.1 microns. The inner surfaces of electrodes  32  may be coated with a layer of dielectric that serves to orient liquid crystals  34  in the absence of an applied electric field. This inner dielectric coating layer, which may sometimes be referred to as a rubbing layer, may be formed from a polymer such as polyimide (as an example). 
     After processing using the roll-based equipment of  FIG. 5 , modulators  16  may be singulated from the resulting roll of flexible substrate  30  that exits drum  16  (i.e., modulators  16  may be singulated from a roll of substrate by forming cuts along cut lines such as cut line  62  of  FIG. 6 ). 
     Heated press structures such as compression mold  64  of  FIG. 7  may be moved towards each other in directions  66  when it is desired to mold the material of substrates  30  into a desired shape. In the example of  FIG. 7 , mold  64  has compound curvature, which causes the thermoplastic material of substrates  30  to be molded into a shape with a compound curvature (e.g., a shape with one or more surfaces of compound curvature). Other types of shapes may be used for mold  64 , if desired. 
     Window  28  may include multiple laminated layers of material (e.g., glass, plastic, modulator  16 , etc.). With one suitable arrangement, an inner layer of material in window  28  may be formed from a low-emissivity (“low-e”) layer. An illustrative low-e layer for window  28  is shown in  FIG. 8 . Low-e layer  68  may be formed on a glass substrate or other suitable substrate and may be incorporated into window  28  with one or more other layers such as the layers of modulator  16 ). 
     Low-e layer  68  has a stack with multiple layers such as layers  76  and may be formed on a substrate such as substrate  78  (e.g., a glass layer in window  28 ). Each layer  76  in the stack may include a seed layer such as seed layer  70  (e.g., a crystalline oxide layer such as a layer of zinc oxide), a metal layer on the seed layer such as layer  74  (e.g., a silver layer), and a protective layer on the metal layer such as layer  72 . Protective layer  72  may be formed from a material that helps prevent diffusion of silver from layer  74  into the zinc oxide of seed layer  70 . Layer  72  may be formed from titanium (e.g., as with LoĒ 3 -366® glass from Cardinal Glass Industries), or may be formed from a transparent oxide such as titanium oxide (TiO 2 ). The use of transparent oxide barrier layers in low-e layer  68  may help increase visible light transmission (e.g. to a value above 80%, above 85%, above 90%, or above 95%). 
     During fabrication, layers of material may be deposited on substrate  78  in sequence. Initially a crystalline seed layer such as layer  70  may be deposited. The seed layer may be formed from a crystalline oxide such as zinc oxide or other material that serves as a suitable base layer for subsequent crystalline silver deposition. The deposited seed layer  70  may have a thickness of about 11 nm (10-15 nm, less than 15 nm, more than 10 nm, etc.) and may be deposited using sputter deposition or other suitable deposition techniques. 
     Following deposition of seed layer  70 , metal layer  74  may be deposited on seed layer  70 . Metal layer  74  may be formed from silver or other suitable metal and may have a thickness of about 10-20 nm, more than 10 nm, less than 20 nm, etc. Sputter deposition techniques or other deposition techniques may be used when depositing layer  74 . 
     Silver has the potential of becoming damaged when exposed to oxygen. The risk of damage will be elevated when the deposited silver has a rough surface morphology. By forming a thin layer, layer  74  may be crystalline and may exhibit a smooth surface morphology suitable for supporting the growth of additional smooth crystalline layers of material for layer  68 . 
     After depositing the first silver layer  74 , a barrier film such as protective layer  72  of may be deposited. Protective layer  72  may be a crystalline layer of titanium oxide (e.g., titanium dioxide) that exhibits a close lattice match to zinc oxide layer  70  and silver layer  74  and that serves to protect silver layer  74  from damage during subsequent layer deposition steps (e.g., when sputter depositing additional seed layers). Layer  72  may be deposited using a technique such as atomic layer deposition that allows layer  72  to be accurately deposited to a thickness of about 2 nm (e.g., about 10-20 atomic layers) without damaging silver layer  74  (as an example). Layer  72  may, for example, have a thickness of less than 3 nm, less than 5 nm, more than 1 nm, 1-5 nm, 1-3 nm, or other suitable thickness. If desired, other deposition techniques may be used (e.g., sputtering) and/or other materials may be used to form protective layer  72  (e.g., titanium, ZnAlO, silicon oxide, silicon nitride, etc.). An advantage of using titanium oxide rather than materials such as titanium is that transmission for layer  68  may be enhanced (e.g., visible light transmission may be increased from about 70% to about 85-90%). 
     After depositing protective layer  72  in the first of layers  76  on substrate  78 , the formation of that layer is complete. Subsequent layers  76  may then be formed in the same way (and may, if desired, be covered with a zinc oxide layer or other suitable layer). 
     The thicknesses of the layers in film  68  may be selected to produce desired thin-film interference effects and visible light absorption effects (e.g., to create a visible pass band and low transmission in near infrared and far infrared wavelengths). 
     If desired, different numbers of metal layers  74  (e.g., three or more, four or more, five or more, fewer than five, etc.) may be used in film  68 . Barrier layer  72  also need not be formed from a separate layer of material. With the illustrative two-metal-layer configuration for low-e film  68  of  FIG. 9 , there are two metal layers  74 . Barrier layers  70 ′ may be formed by depositing an initial portion (e.g., 10-15 nm) of the zinc oxide of each layer  70  in the absence of gaseous oxygen. In this way, this initial portion (portion  70 ′) of each zinc oxide layer can serve as a barrier layer that prevents oxygen (e.g. oxygen that is present during the deposition of subsequent portions of each layer  70 ) from diffusing into underlying silver in layers  74 . The incorporation of gaseous oxygen into the upper portions of each zinc oxide layer may help ensure that visible light transmission is maximized. 
     Using a low-e layer such as one of the illustrative low-e layers  68  of  FIGS. 9 and 10  or other low-e layer, the low-e layer portion of window  28  may be characterized by a reflectivity spectrum of the type shown in  FIG. 10 . As shown in  FIG. 10 , layer  68  may have a reflectivity R that is low in the visible light portion of the spectrum (e.g., from 380 nm to about 700-780 nm), and that rises (starting at about 700 nm) to a high reflectivity value in near infrared wavelengths (e.g., NIR wavelengths of about 700 nm to 2.5 microns) and far infrared wavelengths (e.g. FIR wavelengths of about 8 microns to 10 microns). Solar radiation includes light in near infrared wavelengths, so the ability to reflect light (and therefore not transmit light) at near infrared wavelengths helps prevent solar radiation from heating interior  22 . Visible light that is blocked by absorption in modulator  16  may be converted to heat (e.g., far infrared light at 8-10 microns), so the ability to reflect (and not transmit) light at far infrared wavelengths may also help prevent heating of interior  22 . Visible light may be transmitted or blocked by modulator  16  depending on whether it is desired to allow visible light to illuminate and heat interior  22 . Ultraviolet light may be absorbed and/or reflected by layers such as layer  68 , UV-blocking coating layers in window  28 , and/or stand-alone UV-blocking filter layers (e.g., a filter layer placed between an outer glass layer in window  28  and modulator  16 ). 
       FIG. 11  is a cross-sectional side view of an illustrative window in system  10 . As shown in  FIG. 11 , window  28  may have one or more glass layers such as inner glass layer  80  and outer glass layer  84 . The edges of glass layers  80  and  82  and the intervening layers of material between layers  80  and  82  may be sealed using epoxy, silicone, or other sealant  110  (e.g., to prevent intrusion of oxygen that may degrade the materials of window  28 ). Glass layers  80  and  84  may have thicknesses of about 2-3 mm, less than 3 mm, more than 1 mm, or other suitable thickness. Layers such as interlayer  82  may be formed from polymer and may exhibit strong binding properties and high optical clarity. Layer  82  may be, for example, a layer of polyvinyl butyral or ethylene-vinyl acetate. There may be two or more glass layers, three or more glass layers, or other suitable number of glass layers such as layers  80  and  84  in window  28 . Interlayers  82  may be used to form a laminated glass structure from layers such as layers  80  and  84  that serves as safety glass for window  28 . 
     Guest-host liquid crystal light modulator  16  may be incorporated into the stack of layers that forms window  28 . For example, light modulator  16  may be sandwiched between outer glass layer  84  and inner glass layer  80 . Optional infrared (IR) and ultraviolet (UV) blocking layers such as layer  68  may be interposed between modulator  16  and inner glass layer  80  (and, if desired, may be interposed between outer glass layer  84  and modulator  16  (as indicated by optional blocking layer  68 ′, which may be a low-e layer and/or a UV blocking filter layer). The incorporation of UV-blocking structures in layer  68 ′ may help prevent degradation of substrates  30  and other structures in window  28 . Layers  68  of window  28  may be, for example a layer that includes low-e structures of the type shown in  FIGS. 8 and 9  and/or other low emissivity structures to reflect solar radiation and to reflect heat generated in modulator  16 . Low emissivity structures may also be used for optional layer  68 ′. 
     Illustrative steps in forming window  28  are shown in  FIG. 12 . 
     At step  90 , equipment of the type shown in  FIG. 5  may be used to form a roll of light modulator cells. 
     At step  92 , the roll of modulator cell structures that has been formed using the roll-based processing equipment of  FIG. 5  or other suitable processing equipment may be singulated to form individual modulator cells (see, e.g., modulator cells  16  of  FIG. 6 ). 
     Before filling the empty modulator cells produced during the singulation operations of step  92 , molding equipment of the type shown in  FIG. 7  (e.g., mold  64 ) may be used to shape substrates  30  and the other structures of modulators  16  into a desired shape (e.g., a shape with compound curves). If desired, a dummy glass substrate may serve as part of mold  64  and may help ensure that modulator  16  is shaped into a desired shape. When heated, the material of substrates  30  may shrink (e.g., heat shrink) onto the surface of the dummy glass substrate or other mold structure. 
     At step  96 , after forming light modulator structures  16  into a desired shape, liquid crystal material  38  (e.g., a liquid containing liquid crystal molecules  34  and dye molecules  36 ) may be introduced into the cavity formed between the opposing substrate layers  30  in the empty light modulator structures. Needle injection or other liquid crystal filling techniques may be used to fill each modulator  16  with liquid crystal material. After liquid crystal material  38  has been introduced into each modulator  16 , that modulator will be able to serve as a light modulator in window  28 . If desired, liquid crystal material  38  may be introduced into the cavity between substrate layers  30  before molding substrates  30  into a desired shape with mold  64 . The arrangement of  FIG. 12  in which substrates  30  are molded before being filled with material  38  is merely illustrative. 
     At step  28 , lamination techniques may be used to form window  28  from layers of glass, layers such as low-e layer  68 , and interlayer  82  (e.g., lamination at a temperature of about 140° C. when using a polyvinyl butyral layer as layer  82  to bind window layers together). 
     If desired, guest-host liquid crystal light modulator  16  in window  28  may be provided with terminals on electrodes  32 . The terminals may be provided along the edges of electrodes  32  or on other portions of electrodes  32  and may be supplied with different voltages to allow light transmission to be varied across the surface of light modulator  16 . As shown in  FIG. 13 , for example, light modulator  16  may be provide with strip-shaped terminals  32 B that run along the edges of electrodes  32  (parallel with dimension Y and into the page in the orientation of FIG.  13 ). Terminals  32 B may be formed from thick layers of transparent conductive material such as indium tin oxide and/or may be formed from metal. The sheet resistance of terminals  32 B may be less than the sheet resistance of electrodes  32 , so that there is minimal voltage drop along the lengths of terminals  32 B. The sheet resistance of electrodes  32  may be higher to allow voltages to drop gradually across the surface of light modulator  16 . 
     With the illustrative configuration of  FIG. 13 , a first control voltage V 1  may be applied to electrodes  32  along the left edge of electrodes  32  and a second control voltage V 2  may be applied to electrodes  32  along the right edge of electrodes  32 . Between the left-hand and right-hand terminals  32 B voltage V varies between voltage V 1  and voltage V 2  due to the resistance of electrodes  32 . If, for example, V 1  is less than V 2 , the voltage V across liquid crystal layer  38  may vary linearly as a function of position X across light modulator  16 , as shown in  FIG. 14 . This results in a gradient in light transmission T through modulator  16  of the type shown in  FIG. 15 . Voltages V 1  and/or V 2  may be varied in real time to create motion effects (e.g., window darkening effects that mimic a physical sunshade being raised or lowered in window  28  or other suitable motion in the light transmission through modulator  16 ). 
     If desired, terminals  32 B may be provided with other configurations. For example, a series of terminals  32 B may span electrode  32  at different positions X across modulator  16 , thereby allowing different sections of light modulator  16  to be provided with individually controllable gradients (see, e.g.,  FIG. 16  in which electrode  32  has been spanned by six different strip-shaped terminals  32 B). Each of terminals  32 B may be provided with an independently adjustable voltage or sets of two or more of terminals  32 B may be driven using shared control voltage signals. In the example of  FIG. 17 , terminals  32 B have been segmented along the edges of electrodes  32  to provide additional light transmission adjustability across the surface of modulator  16  in the X-Y plane. In general, electrodes  32  may be provided with any suitable number of terminals  32 B (e.g., two or more, three or more, four or more, 5-10, more than 10, fewer than 20, etc.). The examples of  FIGS. 13, 16, and 17  are merely illustrative. 
     In addition to or instead of adding terminals  32 B to electrode  32 , electrode  32  may be patterned to form individually adjustable electrode pixels  32 P, as shown by the pixelated electrode configuration of  FIG. 18 . Pixels  32 P may be relatively large (e.g., multiple centimeters in width or larger) to minimize control complexity or may be smaller (e.g., millimeter sized or less) to allow images or other information to be displayed with modulator  16 . 
       FIG. 19  shows how the thickness TH of liquid crystal layer  38  may be varied as a function of position X across light modulator  16 . This type of arrangement may result in a light transmission gradient for modulator  16  when modulator  16  is in its off state, as shown by light transmission curve TB of  FIG. 20 . When modulator  116  is turned on (i.e., when a drive voltage is applied to electrodes  32 ), light transmission for modulator  16  of  FIG. 19  may change to the transmission of curve TA (as an example). In general, light modulator  16  may have a normally dark or a normally light state, as determined by the alignment of the liquid crystals in layer  38  in the presence and absence of applied voltages on electrodes  32 . In the example of  FIGS. 19 and 20 , modulator  16  exhibits more light transmission (curve TA) when a voltage is applied than when the voltage is removed (light transmission curve TB). This is merely illustrative. In general, light modulator  16  may be normally on, may be normally off, or may have some regions that are normally on and some regions that are normally off. 
     Light modulator  16  may have polymer alignment layers (sometimes referred to as liquid crystal alignment layers) on the surfaces of electrodes  32  facing liquid crystal layer  38 . The alignment directions associated these alignment layers help establish desired alignment directions for the liquid crystals of layer  38  in the absence of applied voltages. Alignment layers may be configured by exposing the polymer of the alignment layers (e.g., polyimide) to polarized ultraviolet light with a controlled polarization orientation. This allows the liquid crystals of layer  38  to be arranged in any one of a variety of different possible configurations. Examples of liquid crystal configurations that may be used for light modulator  16  include an electrically controlled birefringence (EBC) mode, a vertical alignment mode, a super twisted nematic mode, and a reverse twisted nematic mode. 
     In the electrically controlled birefringence mode, the upper and lower alignment layers have alignment directions that are parallel to each other (in the X-Y plane). When no voltage is applied, the liquid crystals and dye molecules of layer  38  are horizontal (parallel to the surfaces of electrodes  32 ) and light is absorbed (the modulator is dark). When voltage is applied, the liquid crystals and dye molecules are oriented vertically across the thickness of layer  38  and the modulator is clear. 
     In the vertical alignment mode, the modulator is normally clear. The top and bottom alignment layers can be used to vertically align the liquid crystal molecules and dye molecules in the absence of applied voltage. When voltage is applied, the modulator becomes dark. 
     In the super twisted nematic arrangement, there is a 270° twist in the liquid crystal and dye molecules (as a function of distance across the thickness of layer  38 ). This forms a helical shape for the liquid crystal and dye molecules. In the absence of applied voltage, the super twisted nematic light modulator is dark. In the presence of applied voltage, the transmission of the super twisted nematic light modulator increases. 
     In the reverse twisted nematic arrangement applied voltage can be varied so that the liquid crystals and dye molecules are either aligned vertically (perpendicular to the surface normal of planar electrodes  32 ) and are transparent or are aligned horizontally and are opaque (and are twisting 90° when transitioning between lower and upper electrodes due to a perpendicular arrangement between the orientations of the upper and lower alignment layers). 
     The alignment layer(s) on electrode(s)  32  can be aligned differently in different regions of modulator  16  (e.g., by selective application of a polarized ultraviolet light source with various orientations to the alignment layers during fabrication) to create light transmission characteristics for modulator  16  that vary as a function of position. This type of arrangement is shown for the lower electrode  32  in a light modulator in the cross-sectional side view of  FIG. 21 . In the  FIG. 21  example, alignment layer  120  has been deposited on electrode  32  on substrate  30 . Photo-exposure has caused region A 1  of layer  120  to have a first alignment, region A 2  to have a second alignment (e.g., an alignment direction that is at a non-zero angle with respect to the alignment direction of area A 1 ), and region A 3  to have a third alignment (e.g., an alignment direction that differs from both that of region A 1  and that of region A 2 ). Three different alignments are present in alignment layer  120  of  FIG. 21 , but, in general, alignment layers on electrodes  32  may have any suitable number of potentially differently aligned alignment areas (e.g., 2-10, more than 5, more than 10, more than 20, fewer than 100, etc.). Alignment directions may be varied continuously and gradually across a single dimension such as dimension X (e.g., to create a smooth light transmission gradient for modulator  16  in the absence of applied voltage), and/or may be varied in a stepwise fashion (e.g., to create some areas that are normally dark and other areas that are clear or gray). Combinations of these arrangements may also be used. In general, any suitable pattern of alignment directions may be created in respective regions of alignment layers such as alignment layer  120  of  FIG. 21  (e.g., gradient patterns, stripe patterns, checkerboard patterns, patterns associated with text, logos, or other images, decorative trim patterns, a horizontal stripe along the upper edge of the front window of a vehicle that serves as a sunshade, etc.). Alignment layer patterning to create desired patterns of regions with different respective liquid crystal alignment directions may be used in combination with any desired pattern of electrode terminals  32 B and/or any desired variation in liquid crystal layer thickness TH (see, e.g.,  FIG. 19 ). These techniques may be used for modulators  16  in windows  28  with desired light blocking and transmission properties. In addition, modulators  16  may include stacked modulator cells. 
       FIG. 22  is a cross-sectional side view of an illustrative stacked light modulator. Stacked light modulator  16  of  FIG. 22  includes an upper light modulator cell (light modulator M 1 ) and a lower light modulator cell (light modulator M 2 ) that have been joined by optically clear adhesive layer  131 . During operation, the light transmission characteristic of modulator  16  is determined by the combined light transmission characteristics of modulators M 1  and M 2 . As shown in the example of  FIG. 23 , light modulator M 1  may have a transmission T 1 , light modulator M 2  may have a transmission T 2 , and light modulator  16  may have transmission T 3  that is equal to the product of T 1  and T 2 . By using multiple stacked modulators (e.g., two or more, three or more, four or more, etc.), desired light transmission patterns (gradients, etc.) may be produced by light modulator  16 . 
     The foregoing is merely illustrative and various modifications can be made to the described embodiments. The foregoing embodiments may be implemented individually or in any combination.

Metadata:
Filing Date: 20161017
Publication Date: 20201124
Grant Date: 20201124
Priority Date: 20160201
Inventors: BAYAT, Khadijeh
CHEN, CHENG
Kamei, Ibuki
CHANG, SHIH-WEI
YUEN, AVERY P.
GE, ZHIBING
Assignee: APPLE INC
CPC Classifications: [{"code": "G02F1/13725", "inventive": true, "first": false, "tree": "[]"}, {"code": "E06B2009/2464", "inventive": false, "first": false, "tree": "[]"}, {"code": "E06B9/24", "inventive": true, "first": true, "tree": "[]"}, {"code": "E06B2009/2417", "inventive": false, "first": false, "tree": "[]"}, {"code": "G02F1/13725", "inventive": true, "first": true, "tree": "[]"}, {"code": "E06B9/24", "inventive": true, "first": false, "tree": "[]"}, {"code": "E06B2009/2417", "inventive": false, "first": false, "tree": "[]"}, {"code": "E06B9/24", "inventive": true, "first": false, "tree": "[]"}, {"code": "G02F1/13725", "inventive": true, "first": true, "tree": "[]"}]
Family ID: 73462260