PATENT DOCUMENT

Publication Number: US-10071583-B2
Application Number: US-201113021641-A
Country: US
Kind Code: B2

Title: Marking of product housings

Abstract:
Techniques or processes for providing markings on products are disclosed. In one embodiment, the products have housings and the markings are to be provided on the housings. For example, a housing for a particular product can include an outer housing surface and the markings can be provided in the outer housing surface so as to be visible from the outside of the housing.

Claims:
What is claimed is: 
     
       1. A method for marking an article, comprising:
 providing a metal structure for the article; 
 adherently coupling material of a thin film adjacent to a surface of the metal structure, so as to provide a resulting structure having a lightness factor magnitude in a visible color space, and a tactilely smooth surface; and 
 selectively altering the thin film to increase the lightness factor magnitude of selected regions of the resulting structure by stippling with a laser, while maintaining adherent coupling of the material of the thin film, 
 wherein:
 the stippling within the selected region comprises creating an array of light alterations with adjacent pairs of light alterations having an unaltered region there between; 
 each of the light alterations formed by a single laser pulse having a spot size diameter between approximately 50 microns and approximately 100 microns; and 
 the selectively altering the thin film comprises microfracturing selected regions of the thin film that are near the surface of the metal structure while maintaining the tactilely smooth surface. 
 
 
     
     
       2. The method as recited in  claim 1 , wherein the selectively altering the thin film increases the lightness factor magnitude to be above fifty. 
     
     
       3. The method as recited in  claim 1 , wherein the selectively altering the thin film comprises white marking of the resulting structure. 
     
     
       4. The method as recited in  claim 1 , wherein the structure is visible through the thin film. 
     
     
       5. A method for marking an article, comprising:
 providing a metal structure for the article; 
 adherently coupling material of a thin film adjacent to a surface of the metal structure, so as to provide a resulting structure having a lightness factor magnitude in a visible color space and a smooth protective surface; and 
 altering the lightness factor magnitude, using a laser, of regions of the resulting structure that is visible through the thin film by stippling, comprising creating an array of light alterations with adjacent pairs of light alterations having an unaltered region there between, while maintaining adherent coupling of the material of the thin film, wherein: 
 each of the light alterations is formed by a single laser pulse having a spot size diameter between approximately 50 microns and approximately 100 microns; and 
 altering the lightness factor magnitude comprises microfracturing selected regions of the thin film that are near the surface of the metal structure while maintaining the smoothness of the protective surface. 
 
     
     
       6. A method for marking an article, comprising:
 providing an article comprising aluminum metal; 
 anodizing the article to create tactilely smooth anodized layer; and 
 marking the article that is visible through the anodized layer by stippling, by creating an array of light alterations with adjacent pairs of light alterations having an unaltered region there between, each of the light alterations formed by a single laser pulse with a spot size diameter between approximately 50 microns and approximately 100 microns within the anodized layer using a laser, wherein the forming the light alterations comprises fracturing selected regions of the anodized layer that are adjacent to the surface of the metal structure while maintaining the tactilely smooth anodized layer. 
 
     
     
       7. The method as recited in  claim 6 , wherein the light alterations provide a white or translucent appearance within the anodized layer above the aluminum metal. 
     
     
       8. The method as recited in  claim 7 , wherein the marking comprises inducing microfractures in the anodized layer to provide the light alterations.

Description:
CROSS-REFERENCE TO RELATED APPLICATIONS 
     This application is a continuation-in-part of U.S. application Ser. No. 12/895,384, filed Sep. 30, 2010 and entitled “SUB-SURFACE MARKING OF PRODUCT HOUSINGS,” which is hereby incorporated herein by reference, which in turn is a continuation-in-part of U.S. application Ser. No. 12/643,772, filed Dec. 21, 2009 and entitled “SUB-SURFACE MARKING OF PRODUCT HOUSINGS,” which is hereby incorporated herein by reference, which claims priority benefit of U.S. Provisional Application No. 61/252,623, filed Oct. 16, 2009 and entitled “SUB-SURFACE MARKING OF PRODUCT HOUSINGS,” which is hereby incorporated herein by reference. 
    
    
     BACKGROUND OF THE INVENTION 
     Field of the Invention 
     The present invention relates to marking products and, more particularly, marking housings of electronic devices. 
     Description of the Related Art 
     Consumer products, such as electronic devices, have been marked with different information for many years. For example, it is common for electronic devices to be marked with a serial number, model number, copyright information and the like. Conventionally, such marking is done with an ink printing or stamping process. Although conventional ink printing and stamping is useful for many situations, such techniques can be inadequate in the case of handheld electronic devices. The small form factor of handheld electronic devices, such as mobile phones, portable media players and Personal Digital Assistants (PDAs), requires that the marking be very small. In order for such small marking to be legible, the marking must be accurately and precisely formed. Unfortunately, however, conventional techniques are not able to offer sufficient accuracy and precision. Thus, there is a need for improved techniques to mark products. 
     SUMMARY 
     The invention pertains to techniques or processes for providing markings on products. In one embodiment, the products have housings and the markings are to be provided on the housings. For example, a housing for a particular product can include an outer housing surface and the markings can be provided on the outer housing surface so as to be visible from the outside of the housing. The markings provided on products can be textual and/or graphic. The markings can be formed with high resolution. The markings are also able to be light or dark (e.g., white or black), even on metal surfaces. 
     In general, the markings (also referred to as annotations or labeling) provided on products according to the invention can be textual and/or graphic. The markings can be used to provide a product (e.g., a product&#39;s housing) with certain information. The marking can, for example, be use to label the product with various information. When a marking includes text, the text can provide information concerning the product (e.g., electronic device). For example, the text can include one or more of: name of product, trademark or copyright information, design location, assembly location, model number, serial number, license number, agency approvals, standards compliance, electronic codes, memory of device, and the like). When a marking includes a graphic, the graphic can pertain to a logo, a certification mark, standards mark or an approval mark that is often associated with the product. The marking can be used for advertisements to be provided on products. The markings can also be used for customization (e.g., user customization) of a housing of a product. 
     The invention can be implemented in numerous ways, including as a method, system, device, or apparatus. Several embodiments of the invention are discussed below. 
     As a method for marking an article, one embodiment can, for example, include at least providing a metal structure for the article, adherently coupling material of a thin film adjacent to a surface of the metal structure, so as to provide a resulting structure having a lightness factor magnitude in a visible color space, and selectively altering the thin film for substantially increasing the lightness factor magnitude of selected regions of the resulting structure, while substantially maintaining adherent coupling of the material of the thin film. 
     As another method for marking an article, one embodiment can, for example, include at least: providing a metal structure for the article, adherently coupling material of a thin film adjacent to a surface of the metal structure, so as to provide a resulting structure having a lightness factor magnitude in a visible color space, and altering the lightness factor magnitude of selected regions of the resulting structure, while substantially maintaining adherent coupling of the material of the thin film. 
     As another method, one embodiment can, for example, include at least providing an article comprising aluminum metal, anodizing the article to create an anodized layer; and creating light scattering points within the anodized layer, the light scattering points providing a white or translucent appearance above the aluminum metal, which is disposed beneath the anodized layer. 
     As another embodiment, the electronic device housing can, for example, include at least a metal structure having a lightness factor magnitude in a visible color space; a substantially translucent thin film coupled adjacent to a surface of the metal structure, so as to provide a resulting structure; and textual or graphical marking indicia on the electronic device housing selected altered regions of the resulting structure having a lightness factor magnitude substantially different than that of the metal structure. 
     As an electronic device housing, one embodiment can, for example, include at least a metal structure, a thin film coupled adjacent to a surface of the metal structure, and selectively fractured regions of the thin film that are substantially smooth. 
     As another electronic device housing, one embodiment can, for example, include at least a housing structure including at least an outer portion and an inner portion, the outer portion being anodized and the inner portion being unanodized, and selectively altered surface regions formed within the outer portion of the housing structure. The altered surface regions provide marking of the electronic device housing. 
     Other aspects and advantages of the invention will become apparent from the following detailed description taken in conjunction with the accompanying drawings which illustrate, by way of example, the principles of the invention. 
    
    
     
       BRIEF DESCRIPTION OF THE DRAWINGS 
       The invention will be readily understood by the following detailed description in conjunction with the accompanying drawings, wherein like reference numerals designate like structural elements, and in which: 
         FIG. 1  is a diagram of a marking state machine according to one embodiment. 
         FIG. 2  is an illustration of a substrate having marking alterations according to one embodiment. 
         FIGS. 3A-3C  are flow diagrams of marking processes according to one embodiment. 
         FIGS. 4A-4D  are diagrams illustrating marking of a metal structure according to one embodiment. 
         FIG. 5  is a table illustrating exemplary laser operation parameters for dark or black marking of the metal structure according to one embodiment. 
         FIG. 6  is a diagram further illustrating exemplary laser operation parameters for dark or black marking of the metal structure according to one embodiment. 
         FIG. 7A  is a diagram of a top view of an exemplary two-hundred times magnification photomicrograph of light or white marking of an anodized thin film surface of the metal structure according to one embodiment. 
         FIG. 7B  is a diagram of a top view of an exemplary lightness halftone pattern for marking the anodized thin film surface of the metal structure according to another embodiment. 
         FIG. 7C  is a diagram of a top view of an exemplary one thousand times magnification scanning electron micrograph of a microfractured region of the anodized thin film surface of the metal structure, for effecting the light or white marking of the metal structure. 
         FIG. 7D  is a diagram of an exemplary anodized thin film surface topography as measured by an optical surface profiler. 
         FIGS. 8A-8C  are diagrams of various exemplary views representative of a two-hundred times magnification photomicrograph of dark or black marking the metal structure according to one embodiment. 
         FIG. 8D  is a diagram of a top view representative of an exemplary darkness halftone pattern for marking the metal structure according to another embodiment. 
         FIG. 9  is a diagram of a top view illustrating an exemplary lightness halftone pattern and a darkness halftone pattern for marking the metal structure according to another embodiment. 
         FIG. 10A  is a diagrammatic representation of an exemplary product housing. 
         FIG. 10B  illustrates the product housing having markings according to one exemplary embodiment. 
     
    
    
     DETAILED DESCRIPTION OF EMBODIMENTS OF THE INVENTION 
     The invention pertains to techniques or processes for providing markings on products. In one embodiment, the products have housings and the markings are to be provided on the housings. For example, a housing for a particular product can include an outer housing surface and the markings can be provided on an outer housing surface so as to be visible from the outside of the housing. The markings provided on products can be textual and/or graphic. The markings can be formed with high resolution. The markings are also able to be light or dark (e.g., white or black), even on metal surfaces. 
     In general, the markings (also referred to as annotations or labeling) provided on products can be textual and/or graphic. The markings can be used to provide a product (e.g., a product&#39;s housing) with certain information. The marking can, for example, be use to label the product with various information. When a marking includes text, the text can provide information concerning the product (e.g., electronic device). For example, the text can include one or more of: name of product, trademark or copyright information, design location, assembly location, model number, serial number, license number, agency approvals, standards compliance, electronic codes, memory of device, and the like). When a marking includes a graphic, the graphic can pertain to a logo, a certification mark, standards mark or an approval mark that is often associated with the product. The marking can be used for advertisements to be provided on products. The markings can also be used for customization (e.g., user customization) of a housing of a product. 
     Appearance of the housing, and in particular appearance of markings on the housing may be described using CIE 1976 L*a*b* (also known as CIELAB), which is a color space standard specified by the International Commission on Illumination (French Commission internationale de l&#39;éclairage). CIELAB describes colors visible to the human eye and was created to serve as a device independent model to be used as a reference. The three coordinates of the CIELAB standard represent: 1) the lightness factor magnitude of the color (L*=0 yields ultimate black and L*=100 indicates diffuse ultimate white, 2) its position between red/magenta and green (a*, negative values indicate green while positive values indicate magenta) and 3) its position between yellow and blue (b*, negative values indicate blue and positive values indicate yellow). As discussed in further detail subsequently herein, measurements in a format corresponding to the CIELAB standard may be made using a spectrophotometer, such as the COLOREYE™ XTH spectrophotometer, which was sold by GretagMacbeth™. Similar spectrophotometers are available from X-Rite™. 
     Exemplary embodiments of the invention are discussed below with reference to  FIGS. 1-10B . However, those skilled in the art will readily appreciate that the detailed description given herein with respect to these figures is for explanatory purposes as the invention extends beyond these limited embodiments. 
       FIG. 1  is a diagram of a marking state machine  100  according to one embodiment of the invention. The marking state machine  100  reflects three (3) basic states associated with marking an electronic device. Specifically, the marking can mark a housing of an electronic device, such as a portable electronic device. 
     The marking state machine  100  includes a substrate formation state  102 . At the substrate formation state  102 , a substrate can be obtained or produced. For example, the substrate can represent at least a portion of a housing surface of an electronic device. Next, the marking state machine  100  can transition to a protective surface state  104 . At the protective surface state  104 , a protective surface can be formed or applied to at least one surface of the substrate. The protective surface can be used to protect the surface of the substrate. For example, the protective surface can be a more durable surface than that of the surface of the substrate. Next, the marking state machine  100  can transition to a marking state  106 . At the marking state  106 , marking can be produced on the substrate (e.g., produced sub-surface to the protective surface) and/or produced in the protective surface. The marking can be provided with high resolution. Since the marking may be provided while maintaining smoothness of the protective surface, the marking has the advantage of not being perceptible of tactile detection on the surface. 
       FIG. 2  is an illustration of a substrate  200  and an adjacently coupled protective thin film  202 . The substrate  200  may comprise metal, and in particular may comprise aluminum. The substrate may be substantially gray, and is depicted in the figures using stippling (i.e., pattern of small dots). The protective thin film  202  may comprise an anodized layer  202 . 
     As shown in  FIG. 2 , marking alterations  203 ,  204  may include light or white alterations  203  (depicted with left to right hatching) that may be created by microfracturing of the thin film  202  while still maintaining a tactilely smooth surface of the thin film  202 ; and/or may include dark or black subsurface alterations  204  (depicted with cross hatching.) The sub-surface alterations  204  are provided below the thin film  202  and on a top surface  205  of the substrate  200 . Given that the thin film  202  is typically substantially translucent (e.g., clear), the sub-surface alterations  204  may be visible to a user through the thin film  202 . 
     Accordingly, the sub-surface alterations  204  can provide dark or black markings on the substrate  200 . Since the dark or black markings are provided by the sub-surface alterations  204 , the markings are protected by the thin film  202  provided on the substrate  200 . Further, the sub-surface alterations may be made visible while maintaining the tactilely smooth surface of the thin film  202 . 
     The substrate  200  can represent at least a portion of a housing of an electronic device. The marking being provided to the substrate  200  can provide text and/or graphics to an outer housing surface of an electronic device, such as a portable electronic device. The marking techniques are particularly useful for smaller scale portable electronic devices, such as electronic devices. Examples of handheld electronic devices include mobile telephones (e.g., cell phones), Personal Digital Assistants (PDAs), portable media players, remote controllers, pointing devices (e.g., computer mouse), game controllers, etc. 
       FIGS. 3A-3C  are flow diagrams of marking processes  300 A,  300 B,  300 C according to one embodiment. The marking processes  300 A,  300 B,  300 C can be performed on an electronic device that is to be marked. The marking processes  300 A,  300 B,  300 C are, for example, suitable for applying text or graphics to a housing (e.g., an outer housing surface) of an electronic device. The marking can be provided such that it is visible to users of the electronic device. However, the marking can be placed in various different positions, surfaces or structures of the electronic device. 
     The marking processes  300 A,  300 B,  300 C can provide a metal structure for an article to be marked. The metal structure can pertain to a metal housing for an electronic device, such as a portable electronic device, to be marked. The metal structure can be formed of one metal layer. The metal structure can also be formed of multiple layers of different materials, where at least one of the multiple layers is a metal layer. The metal layer can, for example, be or include aluminum, titanium, niobium or tantalum. 
     In accordance with the marking process  300 A shown in  FIG. 3A , the process may begin with providing  302 A the metal structure for an article to be marked. After the metal structure has been provided  302 A, material of a thin film may be adherently coupled  304 A adjacent to a surface of the metal structure, so as to provide a resulting structure having a lightness factor magnitude in a visible color space. In one embodiment, the surface of the metal structure may be anodized  304 A to adherently couple material of the thin film (e.g. anodized layer.) Typically, the surface of the metal structure to be anodized  304 A is an outer or exposed metal surface of the metal structure. For example, the outer or exposed surface can represent an exterior surface of the metal housing for the electronic device. 
     Given that the thin film (e.g., anodized layer) is typically substantially translucent (e.g., clear), the metal of the resulting structure may be gray and may be substantially visible through the thin film. Measuring lightness factor magnitude of the resulting structure using a spectrophotometer, in accordance with the CIELAB standard scale, the lightness factor magnitude may be about 68 (which may be referred to as “L*68”). 
     Thereafter, as shown in the process  300 A of  FIG. 3A , the thin film may be selectively altered  306 A for increasing substantially the lightness factor magnitude of selected regions of the resulting structure, while substantially maintaining adherent coupling of the material of the thin film. The selectively altering  306 A of the thin film may increase the lightness factor magnitude to be substantially above fifty. For example, in measurements of selected altered thin film regions using a spectrophotometer, in accordance with the CIELAB scale, the selected altered thin film regions showed an increased lightness factor magnitude, which was about 86.6 (which may be referred to as L*86.6). 
     Increasing substantially the lightness factor magnitude may provide a substantially lightened visible appearance, and may provide a substantially white visible appearance, of the selected regions of the resulting structure. In other words, selectively altering  306 A the thin film may provide a substantially lightened visible appearance, and may provide a substantially white visible appearance, of the thin film of selected regions of the resulting structure. Accordingly, selectively altering  306 A the thin film may cause substantially white marking of the resulting structure. 
     Selectively altering  306 A the thin film may be employed for marking the article by altered lightness characteristics of selected regions of the resulting structure, which may cause one or more light textual or graphical indicia to appear on the resulting structure. Further, as will be discussed in greater detail subsequently herein, selectively altering  306 A the thin film for increasing substantially the lightness factor magnitude of selected regions of the resulting structure may comprise lightness halftoning, wherein the selected regions of the thin film may be arranged in a lightness halftone pattern. 
     Selectively altering  306 A the thin film may comprises fracturing and, more particularly, may comprise microfracturing the thin film of selected regions of the resulting structure. For example, the thin film can pertain to an anodized layer selectively altering the thin film may comprise selectively altering an anodized layer discussed previously herein. Accordingly, selectively altering the thin film may comprises fracturing and, more particularly, may comprise microfracturing the anodized layer of selected regions of the resulting structure. 
     Selectively altering  306 A the thin film may comprise heating, and in particular may comprise laser heating of selected regions of the resulting structure. Selectively altering  306 A the thin film may comprise heating the metal surface of selected regions of the resulting structure. Selectively altering  306 A the thin film may comprise fracturing the thin film (e.g., anodized layer) adjacent to the surface of the metal structure, by heating the metal surface of selected regions of the resulting structure. 
     The material of the thin film may be substantially more brittle than metal of the metal structure. In other words, the metal of the metal structure may be substantially more ductile than the material of the thin film. Further, thermal expansion in response to heating of the metal of the metal structure may be substantially greater than thermal expansion in response heating of the thin film. Moreover, laser selection and operation may be controlled so that laser heating by electron-phonon coupling may predominate over other laser effects; and electron-phonon coupling of the metal of the metal structure may be substantially higher than electron-phonon coupling of the thin film, so that laser heating of the metal of the metal structure may be substantially greater than laser heating of the thin film. Accordingly, selectively heating of the metal surface of selected regions of the resulting structure may selectively alter  306 A the thin film by fracturing the thin film adjacent to the surface of the metal structure. In other words, the foregoing different responses to heating of the metal and the adherently coupled thin film may contribute to stresses in excess of fracture tolerance of the thin film, which may result in fracturing of the thin film. 
     For example, aluminum oxide of an anodized layer may be substantially more brittle than aluminum metal of the metal structure. In other words, the aluminum metal of the metal structure may be substantially more ductile than the aluminum oxide of the anodized layer. Further, thermal expansion in response to heating of the aluminum metal of the metal structure may be substantially greater than thermal expansion in response to heating of the aluminum oxide of the anodized layer. Moreover, in the case of laser heating by electron-phonon coupling, electron-phonon coupling of the aluminum metal of the metal structure may be substantially higher than electron-phonon coupling of the aluminum oxide of the anodized layer, so that laser heating of the aluminum metal of the metal structure may be substantially greater than laser heating of the aluminum oxide of the anodized layer. Accordingly, selectively heating the aluminum metal surface of selected regions of the resulting structure may selectively alter  306 A the anodized layer by fracturing (e.g., microfracturing) the anodized layer adjacent to the surface of the metal structure. In other words, the foregoing different responses to heating of the aluminum metal and the adherently coupled aluminum oxide of the anodized layer may contribute to stresses in excess of fracture tolerance of the anodized layer, which may result in fracturing of the anodized layer. 
     Substantially maintaining adherent coupling of the material of the thin film to the metal substrate may substantially avoid etching of the material of the thin film material. For example, substantially maintaining adherent coupling of the aluminum oxide material of an anodized layer may substantially avoid etching the aluminum oxide material of the anodized layer when being selectively altered  306 A. Accordingly, selectively altering  306 A the thin film may maintain a tactilely smooth surface of the thin film. In such case, the thin film may be selectively altered by microfracturing the thin film, while maintain the tactilely smooth surface of the thin film. Moreover, measurements by an optical surface profiler may show substantially no change in thin film surface topology due to selectively altering  306 A the thin film, while also substantially maintaining adherent coupling of the material of the thin film. In particular, microfracturing the thin film, while substantially maintaining adherent coupling of the material of the thin film, may show substantially no change in thin film surface topology in measurements by the optical surface profiler. In other words, the selectively altering  306 A of the thin film may induce micro-features therein (e.g., microfracturing) but can doe so without destruction of the thin layer. 
     Selectively altering  306 A the thin film may comprise directing a laser output through the thin film adjacent to a surface of the metal structure, and towards the surface of the metal structure. As will be discussed in greater detail subsequently herein the laser output may be controlled for substantially maintaining adherent coupling of the material of the thin film, so as to avoid various deleterious effects, while white marking select portions of the thin film via micro-fracturing. The laser output may be controlled so as to maintain the tactilely smooth surface of the thin film. The laser output may be controlled so as to substantially avoid laser etching of the thin film. The laser output may be controlled so as to substantially avoid ablation of the metal or thin film. 
     Accordingly, substantially maintaining adherent coupling  306 A of the material of the thin film may comprise substantially avoiding laser etching of the material of the thin film material. Substantially maintaining adherent coupling  306 A of the material of the thin film may also comprise substantially avoiding ablation of the material of the thin film. 
     Selectively altering  306 A the thin film may employ a suitably selected and operated laser for providing the laser output. For example, one specific suitable laser may be operated in substantially continuous wave (CW) mode at a selectively limited power of two (2) Watts and at an infrared wavelength (10.6 micron wavelength), such as the Alltec laser model CO2 LC100, which may be obtained from Alltec GmbH, An der Trave 27-31, 23923 Selmsdorf, Germany. Accompanying optics may be used to provide a laser output spot size within a range from approximately seventy (70) microns to approximately one-hundred (100) microns. For a spot of about 0.00005 square centimeters, selectively limits irradiance to approximately forty (40) Kilo-Watts per square centimeter, for selectively altering  306 A the thin film, while substantially maintaining adherent coupling of the material of the thin film. It should be understood that the foregoing are approximate exemplary laser operating parameters, and that various other laser operating parameters may be suitable for selectively altering  306 A the thin film, while substantially maintaining adherent coupling of the material of the thin film. Laser output spot size and/or irradiance may be selected for selectively altering  306 A the thin film, while substantially maintaining adherent coupling of the material of the thin film. The foregoing may substantially avoid etching or ablation of the material of the thin film material; may maintain a tactilely smooth surface of the thin film; and/or may substantially avoid changes in thin film surface topology. 
     Selectively altering  306 A the thin film may comprise directing the laser output towards the surface of the metal structure, while limiting power of the laser output, so as to substantially avoid ablation of the metal of the metal structure. The metal may be characterized by an ablation threshold irradiance, and the laser output may have an irradiance that is approximately less than the ablation threshold irradiance of the metal, for substantially avoiding ablation of the metal of the metal structure. Following the block  306 A of selectively altering the thin film, the marking process  300 A shown in  FIG. 3A  can end. 
     In accordance with the marking process  300 B shown in  FIG. 3B , the process may begin with providing  302 B the metal structure for an article to be marked, wherein the metal may comprise aluminum metal. After the metal structure has been provided  302 B, the article may be anodized for creating  304 B an anodized layer. After creating  304 B the anodized layer, light scattering points may be created  306 B within the anodized layer, for example, by microfracturing the anodized layer. The light scattering points may provide a white or translucent appearance above the aluminum metal, which is disposed beneath the anodized layer. Following the block  306 B of creating the light scattering points, the marking process  300 B shown in  FIG. 3B  can end. 
     In accordance with the marking process  300 C shown in  FIG. 3C , the process may begin with providing  302 C the metal structure for an article to be marked. After the metal structure is provided  302 C, material of a thin film may be adherently coupled  304 C adjacent to a surface of the metal structure, so as to provide a resulting structure having a lightness factor magnitude in a visible color space. The metal of the resulting structure may be gray and may be substantially visible through the thin film. Measuring lightness factor magnitude of the resulting structure using a spectrophotometer, in accordance with the CIELAB standard scale, the lightness factor magnitude may be about 68 (which may be referred to as “L*68”). The surface of the metal structure may be anodized  304 C to adherently couple material of the thin film (e.g. anodized layer). For example, after the metal structure has been provided  302 C, the surface of the metal structure can be anodized  304 C. 
     Thereafter, as shown in the process  300 C of  FIG. 3C , surface characteristics of selected regions of the surface of the metal structure may be selectively altered  306 C, for example may be selectively roughened, for decreasing substantially the lightness factor magnitude of selected regions of the resulting structure, while substantially maintaining adherent coupling of the material of the thin film. Such selective roughening may be ultrasmall scale roughening, for example the ultrasmall scale roughening may comprise nanoscale roughening. Selectively altering  306 C of the metal surface may decrease the lightness factor magnitude to be substantially below fifty. For example, in measurements of selected altered metal surface regions using a spectrophotometer, in accordance with the CIELAB standard scale, the selected altered metal surface regions showed a decreased lightness factor magnitude, which may range in magnitude from about twenty to about thirty (which may be referenced as about “L*20” to about “L*30”.) 
     Decreasing substantially the lightness factor magnitude may provide a substantially darkened visible appearance, and may provide a substantially black visible appearance, of the selected regions of the resulting structure. In other words, selectively altering  306 C the metal surface may provide a substantially darkened visible appearance, and may provide a substantially black visible appearance, of the metal surface of selected regions of the resulting structure. Accordingly, selectively altering  306 C the metal surface may cause substantially black marking of the resulting structure. 
     Selectively altering  306 C the metal surface may be employed for marking the article by altered darkness characteristics of selected regions of the resulting structure, which can be used to form one or more dark textual or graphical indicia to appear on the resulting structure. Further, as will be discussed in greater detail subsequently herein, selectively altering  306 C the metal surface for decreasing substantially the lightness factor magnitude of selected regions of the resulting structure may comprise darkness halftoning, wherein the selected regions of the metal surface may be arranged in a darkness halftone pattern. 
     Substantially maintaining adherent coupling of the material of the thin film may substantially avoid etching or ablation of the material of the thin film material. The thin film can be a layer of aluminum oxide material. For example, substantially maintaining adherent coupling of an aluminum oxide material of an anodized layer may substantially avoid etching or ablation the aluminum oxide material of the anodized layer. Accordingly, selectively altering  306 C the metal surface may substantially maintain a tactilely smooth surface of the thin film. In such case, the metal surface may be selectively altered beneath the thin film, while the thin film remains substantially in place, and while substantially maintaining the tactilely smooth surface of the thin film. 
     Selectively altering  306 C the metal surface may comprise directing a laser output through the thin film (e.g., anodized layer) adjacent to the surface of the metal structure, and towards the surface of the metal structure. Typically, the surface of the metal structure to be anodized is an outer or exposed metal surface of the metal structure. The outer or exposed surface with anodized layer typically represents an exterior surface of the metal housing for the electronic device. Thereafter, surface characteristics of selected portions of an inner unanodized surface of the metal structure may be altered  306 C. The inner unanodized surface may be part of the metal layer that was anodized, or may be part of another metal layer that was not anodized. 
     As will be discussed in greater detail subsequently herein, the laser output may be controlled for substantially maintaining adherent coupling of the material of the thin film, so as to avoid various deleterious effects, while black marking the metal surface. The laser output may be controlled so as to maintain substantially the tactilely smooth surface of the thin film. The laser output may be controlled so as to substantially avoid laser etching of the thin film. The laser output may be controlled for substantially avoiding ablation of the metal or thin film. 
     Accordingly, substantially maintaining adherent coupling  306 C of the material of the thin film may comprise substantially avoiding laser etching of the material of the thin film material. Substantially maintaining adherent coupling  306 C of the material of the thin film may also comprise substantially avoiding ablation of the material of the thin film. 
     Selectively altering  306 C the metal surface may employ a suitably selected and operated laser for providing the laser output. The surface characteristics can be altered  306 C using a laser, such as an infrared wavelength laser (e.g., picosecond pulsewidth infrared laser or nanosecond pulsewidth infrared laser). For example, one specific suitable laser is a six (6) Watt infrared wavelength picosecond pulsewidth laser at 1000 KHz with a scan speed of 50 mm/sec. While such picosecond pulsewidth laser may provide many advantages, it may be more expensive than an alternative nanosecond pulsewidth laser. Accordingly, an example of a suitable alternative laser is a ten (10) Watt infrared wavelength nanosecond pulsewidth lasers at 40 KHz with a scan speed of 20 mm/sec. Fluence of pulses of the laser may be selected so as to be approximately less than an ablation threshold fluence that characterizes the metal. Selection of the laser fluence may be for substantially avoiding ablation of the metal. Further, fluence of pulses of the laser may be selected so as to be greater than a damage fluence that characterizes the metal, so as to provide for altering surface characteristics of the selected portions of the inner unanodized surface of the metal structure. Accompanying optics may be used to provide a laser output spot size within a selected range, as discussed in greater detail subsequently herein. 
     Laser output spot size and/or irradiance may be selected for selectively altering  306 C the metal surface, while substantially maintaining adherent coupling of the material of the thin film. The foregoing may substantially avoid etching or ablation of the material of the thin film material; may substantially maintain a tactilely smooth surface of the thin film; and/or may substantially avoid changes in thin film surface topology. 
     Selectively altering  306 C the metal surface may comprise directing the laser output towards the surface of the metal structure, while limiting power of the laser output, so as to substantially avoid ablation of the metal of the metal structure. The metal may be characterized by an ablation threshold irradiance and/or ablation threshold fluence, and the laser output may have an irradiance and/or fluence that is approximately less than the ablation threshold irradiance and/or ablation threshold fluence of the metal, for substantially avoiding ablation of the metal of the metal structure. Following the block  306 C of selectively altering the metal surface, the marking process  300 C shown in  FIG. 3C  can end. 
     The process  300 B shown in  FIG. 3B  and the process  300 C shown in  FIG. 3C  can be considered embodiment of the process  300 A shown in  FIG. 3A . 
       FIGS. 4A-4D  are diagrams illustrating marking of a metal structure according to one embodiment.  FIG. 4A  illustrates a base metal structure  400 . As an example, the base metal structure  400  can be formed of aluminum, titanium, niobium or tantalum. In  FIGS. 4A-4D , the base metal structure may be substantially gray, and is depicted in the  FIGS. 4A-4D  using stippling.  FIG. 4B  illustrates the base metal structure  400  after an upper surface has been anodized to form an anodized surface  402 . The thickness of the anodized surface  402  can, for example, be about 5-20 microns. The anodized surface  402  can be considered a thin film, which represents a coating or layer. Aluminum oxide material of the anodized surface may be adherently (e.g., chemically bonded) coupled adjacent to an inner unanodized surface  406  of the metal structure  400 . 
     After the anodized surface  402  has been formed on the base metal structure  400 ,  FIG. 4C  illustrates light (e.g., white) alterations  403  (depicted with left to right hatching) that may be created by microfracturing of the anodized surface  402 , while substantially maintaining adherent coupling of the aluminum oxide material of the anodized surface  402  adjacent to the inner unanodized surface  406  of the metal structure  400 . The light alterations  403  are formed by suitably selected optical energy  407  produced by a suitably selected and operated laser  409  (as discussed in detail previously herein with respect to light or white marking). The altered surfaces  403  combine to provide marking of the metal structure  400 . For example, the light alterations  403  appear to be light, and thus when selectively formed can provide light or white marking. The light or white marking can also be provided in lightness halftone arranged in a suitably selected lightness halftone pattern. If the anodized surface is dyed or colored, the markings may appear in different colors. 
     The laser  407  may include a galvanometer mirror or other arrangement for raster scanning a spot of the optical energy over the anodized surface  402 , so as to form the light alterations into a rasterized depiction of the light (e.g., white) marking indicia. Suitable pitch between raster scan lines of the scanning spot for the light (e.g., white) marking may be selected. For example, pitch between raster scan lines may be about fifty (50) microns, and scan speed may be about two hundred (200) millimeters per second. 
     Alternatively or additionally, after the anodized surface  402  has been formed on the base metal structure  400 ,  FIG. 4D  illustrates altered surfaces  404  (depicted with cross hatching) being selectively formed on an inner unanodized surface  406 , while substantially maintaining adherent coupling of the aluminum oxide material of the anodized surface  402  adjacent to the inner unanodized surface  406  of the metal structure  400 . Such altered structures  404  are formed for dark (e.g., black) marking by suitably selected optical energy  408  produced by a suitably selected and operated laser  410  (as discussed in detail previously herein with respect to dark or black marking). The altered surfaces  404  combine to provide dark (e.g., black) marking of the metal structure  400 . For example, the altered surfaces  404  appear to be dark or black and thus when selectively formed can provide dark marking. The resulting dark marking is visible through the anodized surface  402  which can be substantially translucent. If the anodized surface  402  is primarily clear, the resulting marking can be appear as dark (e.g., black). The marking can also be provided in darkness halftone in a suitably selected darkness halftone pattern. If the anodized surface is dyed or colored, the dark markings may appear in different colors. 
     Fluence of the optical energy may be above the damage threshold fluence for the base metal structure, for forming the altered structures  404 . However, notwithstanding the foregoing, it should be understood that fluence of the optical energy that forms the altered structures  404  on the altered surfaces of the base metal structure may be selected to be approximately below the ablation threshold fluence for the base metal structure, so as to avoid deleterious effects, for example, predominant ablative stripping of the anodized surface or the base metal structure. Further, predominant fracturing of the anodized surface, or predominant delaminating of the anodized surface away from the base metal structure, may be substantially avoided by selectively limiting fluence of the optical energy that forms the altered structures. Fluence of the optical energy that forms the altered structures  404  on the altered surfaces of the base metal structure may be selected so that non-ablative laser-material interactions such as heating, surface melting, surface vaporization and/or plasma formation predominate over any ablation. In other words, by exercising due care in selection of the fluence of the optical energy that forms the altered structures on the altered surfaces of the base metal structure; ablation, which may be characterized by direct evaporation the metal, in an explosive boiling that forms a mixture of energetic gases comprising atoms, molecules, ions and electrons, may not predominate over non-ablative laser-material interactions, such as heating, surface melting, surface vaporization and/or plasma formation. 
     The laser  410  may include a galvanometer mirror or other arrangement for raster scanning a spot of the optical energy over the inner unanodized surface  406 , so as to form the altered structures into a rasterized depiction of the marking indicia. Suitable pitch between raster scan lines of the scanning spot for the black marking may be selected. For example, a suitable pitch may be a fine pitch of about thirteen (13) microns. The laser  410  may further include optics for contracting or expanding size of the spot of the optical energy, by focusing or defocusing the spot. Expanding size of the spot, by defocusing the spot may be used to select fluence of the optical energy. In particular, expanding size of the spot may select fluence of the optical energy below the ablation threshold fluence for the base metal structure. Spot size of the optical energy for the nanosecond class laser mentioned previously herein may be within a range from approximately fifty (50) microns to approximately one hundred (100) microns; and spot size may be about seventy (70) microns. 
       FIG. 5  is a table illustrating exemplary laser operation parameters for dark (e.g., black) marking of a metal structure according to one embodiment. In particular, the table of  FIG. 4D  shows examples of various suitable laser models which may be used for marking the metal structure. The FOBA DP20GS is a Diode Pumped Solid State Neodymium-Doped Yttrium Orthovanadate (DPSS YVO4) type laser, which is available from FOBA Technology and Services GmbH, having offices at 159 Swanson Road, Boxborough, Mass. The SPI 12W/SM AND SPI 20W/SM are fiber type lasers, which are available from SPI Lasers UK, having offices at 4000 Burton Drive, Santa Clara, Calif. The Lumera is a picosecond type laser, which is available from LUMERA LASER GmbH, having an office at Opelstr 10, 67661 Kaiserslautern, Germany. It should be understood that the table of  FIG. 5  shows approximate exemplary laser operating parameters, and that various other laser operating parameters may be selected to provide the fluence of the optical energy that forms the altered structures for dark or black marking of a base metal structure, wherein the fluence may be selected to be approximately below the ablation threshold fluence for the base metal structure. 
       FIG. 6  is a diagram further illustrating exemplary laser operation parameters for dark (e.g., black) marking a metal structure according to one embodiment. In the diagram of  FIG. 6 , irradiance of Laser Light Intensity in Watts per square centimeter is shown along a vertical axis, while Interaction Time of each pulse of the laser light (optical energy) with the metal structure is shown in fractions of a second along a horizontal axis. For illustrative reference purposes, diagonal lines of constant fuence of approximately ten (10) milli-Joules per square centimeter and of approximately one (1) Joule per square centimeter are shown in  FIG. 6 . For substantially avoiding ablation of the metal structure, excessively high laser light intensity may be avoided, so that a temperature “T” of the metal structure may not substantially exceed a critical temperature for ablation of the metal structure. For example, a stippled region of exemplary excessively high laser light intensity is shown in  FIG. 6 , along with a descriptive legend T&gt;T critical for ablation.  FIG. 6  further shows a cross hatched region of suggested approximate parameters for formation of the altered structures for the dark or black marking. 
       FIG. 7A  is a diagram of a top view of an exemplary two-hundred times magnification photomicrograph of light (e.g., white) marking of an anodized thin film surface  702  of a metal structure according to one embodiment. The anodized thin film surface  702  may be substantially clear or translucent, however, as shown in  FIG. 7A , slight curved island surface features of the anodized thin film surface  702  may be seen under the two-hundred times magnification. Further, the anodized thin film surface  702  may include light alterations  703  (depicted with left to right hatching) that may be created by microfracturing of the anodized thin film surface  702 , while substantially maintaining adherent coupling of the aluminum oxide material of the anodized thin film surface adjacent to the inner unanodized surface of the metal structure. As depicted using stippling in  FIG. 7A , the metal structure may appear gray and may be visible through an unaltered substantially clear or transparent remainder portion of the anodized thin film surface  702 . Light scattering points may be created by microfracturing the anodized thin film surface for the light alterations  703 , which may significantly obscure visibility of the metal structure through the anodized thin film surface. 
       FIG. 7B  is a diagram of a top view of an exemplary lightness halftone pattern  713  of light (e.g., white) alterations  713  (depicted with left to right hatching), which may be created by microfracturing of the anodized thin film surface  702 . As depicted using stippling in  FIG. 7B , the metal structure may appear gray and may be visible through the unaltered substantially clear or transparent remainder portion of the anodized thin film surface  702 . Size of the light alterations  713 , as well as spaced apart arrangement of the light alterations  713  in the lightness halftone pattern may be selected so as to provide a desired halftoning appearance. 
       FIG. 7C  is a diagram of a top view of an exemplary one thousand times magnification scanning electron micrograph of a microfractured region of an anodized thin film surface of a metal structure, for effecting the light or white marking of the metal structure. Scanning electron microscopy can reveal details and features smaller than wavelengths of visible light. For example, anodic pores having diameters on the order of ten nanometers and extending into the anodized thin film surface are shown in  FIG. 7C . The scanning electron micrograph reveals the structure of microfractures  716 , having dimensions on a scale of less than one micron, wherein the microfractures  716  may produce substantial scattering of light at visible wavelengths. One slight curved island surface features  718  of the anodized thin film surface  702  is shown under one thousand times magnification in the diagram depiction of the scanning electron micrograph of  FIG. 7C . 
       FIG. 7D  is a diagram of an exemplary anodized thin film surface topography of the anodized thin film  702  as measured by an optical surface profiler, which at low magnification (e.g., less than two-hundred times magnification) may show substantially no perceptible change in the thin film surface topology for regions of light marking alterations, relative to remainder unaltered regions, without light marking alterations. Measurements, for example, can be made using ADE Phase Shift MicroXAM Optical interferometric profiler. Depictions of slight curved island surface features are shown in  FIG. 7D  for the anodized thin film surface topography of the anodized thin film  702 . Typically, height magnitude of the slight curved island surface features may be less than about a couple of microns. 
     As mentioned previously herein, and as presently shown in  FIG. 7D , substantially maintaining adherent coupling of the material of the anodized thin film  702  may substantially avoid etching of the material of the thin film material. More particularly, substantially maintaining adherent coupling of the aluminum oxide material of the anodized thin film  702  may substantially avoid etching the aluminum oxide material of the anodized thin film  702 . Moreover, measurements by the optical surface profiler may show substantially no change in the anodized thin film surface topology due to selectively altering the thin film, while substantially maintaining adherent coupling of the material of the thin film. In particular, microfracturing the anodized thin film, while substantially maintaining adherent coupling of the material of the thin film, may show substantially no change in thin film surface topology in measurements by the optical surface profiler. 
       FIGS. 8A-8C  are diagrams of various exemplary views representative of a two-hundred times magnification photomicrograph of dark (e.g., black) marking the metal structure according to one embodiment. Base metal structure  800  may appear gray, and is depicted in  FIGS. 8A-8C  using stippling. In  FIG. 8A , the anodized thin film surface  802  is shown exploded away from the inner unanodized surface  806  of the base metal structure  800  in isometric view, so as to show clearly altered structures  804  (which are particularly highlighted using cross hatching). The altered structures  804  may correspond to selected roughened regions. The selected roughened regions may comprise ultrasmall scale roughening in selected regions of the inner unanodized surface  806  of the base metal structure  800 . For example, the ultrasmall scale roughening may comprise nanoscale roughening. The anodized thin film surface  802 , the altered structures  804  and the inner unanodized surface  806  of the base metal structure  400  are shown in a collapsed isometric view in  FIG. 8B , and in a top view in  FIG. 8C . 
     The anodized thin film surface  802  may appear substantially optically transparent as shown in  FIGS. 8A through 8C ; however, slight curved island surface features of the anodized thin film surface  802  may be seen under the two-hundred times magnification. Further,  FIGS. 8A through 8C  show a stepped plateau feature of the anodized thin film surface  802 , which may be due to elevation by the altered structures  804 , or may be due to an increase in volume contributed by the altered structures  804 . A thickness of the stepped plateau feature may be slight, and may be about two to four microns. Accordingly, notwithstanding the slight stepped plateau feature of about two to four microns, selectively altering the unanodized metal surface  806  to produce the altered structures  804 , substantially maintains adherent coupling of the material of the anodized thin film surface  802 . The foregoing may substantially avoid etching or ablation of the material of the thin film material; may substantially maintain a tactilely smooth surface of the thin film; and/or may substantially avoid changes in thin film surface topology. 
       FIG. 8D  is a diagram of a top view of an exemplary darkness halftone pattern  814  (depicted with cross hatching) for marking the metal structure according to another embodiment. As depicted using stippling in  FIG. 8D , a metal structure may appear gray and may be visible through the unaltered substantially clear or transparent remainder portion of the anodized thin film surface  802 . Size of the dark (e.g., black) alterations  814 , as well as spaced apart arrangement of the dark alterations  814  in the darkness halftone pattern may be selected so as to provide a desired halftoning appearance. 
       FIG. 9  is a diagram of a top view illustrating an exemplary lightness halftone pattern  913  (depicted with left to right hatching) and a darkness halftone pattern  914  (depicted with cross hatching) for marking the metal structure according to another embodiment. As depicted using stippling in  FIG. 9 , a metal structure may appear gray and may be visible through the unaltered substantially clear or transparent remainder portion of an anodized thin film surface  902 . To provide a desired halftoning appearance, suitable selections may be made for sizes of the alterations  913 ,  914  as well as spaced apart arrangements of the alterations  913 .  914  in the respective lightness and darkness halftone patterns. 
       FIG. 10A  is a diagrammatic representation of an exemplary product housing  1000 . The housing  1000  may be formed using aluminum or another suitable metal. The housing  1000  may be a housing that is to be a part of an overall assembly. For example, the housing  1000  can be a bottom of a cell phone assembly or portable media player, or can be a portion of a housing for a personal computer or any other device having a metal housing. 
       FIG. 10B  illustrates the product housing  1000  having markings  1002  according to one exemplary embodiment. The markings  1002  can be light or white markings in accordance with the light or white markings discussed previously herein. Alternatively or additionally, the markings  1002  can be dark or black markings produced on a sub-surface of the product housing  1000  in accordance with the dark or black markings discussed previously herein. In this example, the labeling includes a logo graphic  1004 , serial number  1006 , model number  1008 , and certification/approval marks  1010  and  1012 . Besides light (e.g., white) or dark (e.g., black) colors for marking, other colors or shades can be provided by halftoning and/or dyes. 
     The marking processes described herein are, for example, suitable for applying text or graphics to a housing surface (e.g., an outer housing surface) of a device, such as an electronic device. The marking processes are, in one embodiment, particularly well-suited for applying text and/or graphics to an outer housing surface of a portable electronic device. Examples of portable electronic devices include mobile telephones (e.g., cell phones), Personal Digital Assistants (PDAs), portable media players, portable computers, remote controllers, pointing devices (e.g., computer mouse), game controllers, etc. The portable electronic device can further be a hand-held electronic device. The term hand-held generally means that the electronic device has a form factor that is small enough to be comfortably held in one hand. A hand-held electronic device may be directed at one-handed operation or two-handed operation. In one-handed operation, a single hand is used to both support the device as well as to perform operations with the user interface during use. In two-handed operation, one hand is used to support the device while the other hand performs operations with a user interface during use or alternatively both hands support the device as well as perform operations during use. In some cases, the hand-held electronic device is sized for placement into a pocket of the user. By being pocket-sized, the user does not have to directly carry the device and therefore the device can be taken almost anywhere the user travels (e.g., the user is not limited by carrying a large, bulky and often heavy device). 
     This application is also references: (i) U.S. Provisional Patent Application No. 61/121,491, filed Dec. 10, 2008, and entitled “Techniques for Marking Product Housings,” which is hereby incorporated herein by reference; (ii) U.S. patent application Ser. No. 12/358,647, filed Jan. 23, 2009, and entitled “Method and Apparatus for Forming a Layered Metal Structure with an Anodized Surface,” which is hereby incorporated herein by reference; (iii) U.S. patent application Ser. No. 12/475,597, filed May 31, 2009, and entitled “Techniques for Marking Product Housings,” which is hereby incorporated herein by reference; (iv) U.S. application Ser. No. 12/643,772, filed Dec. 21, 2009 and entitled “SUB-SURFACE MARKING OF PRODUCT HOUSINGS,” which is hereby incorporated herein by reference; and (v) U.S. application Ser. No. 12/895,384, filed Sep. 30, 2010 and entitled “SUB-SURFACE MARKING OF PRODUCT HOUSINGS,” which is hereby incorporated herein by reference. 
     The various aspects, features, embodiments or implementations of the invention described above can be used alone or in various combinations. 
     Different aspects, embodiments or implementations may, but need not, yield one or more of the following advantages. One advantage of the invention is that durable, high precision markings can be provided to product housings. As an example, the markings being provided on a product housing that not only have high resolution and durability but also provide a smooth and high quality appearance. Another advantage is that the marking techniques are effective for surfaces that are flat or curved. 
     The many features and advantages of the present invention are apparent from the written description. Further, since numerous modifications and changes will readily occur to those skilled in the art, the invention should not be limited to the exact construction and operation as illustrated and described. Hence, all suitable modifications and equivalents may be resorted to as falling within the scope of the invention.

Metadata:
Filing Date: 20110204
Publication Date: 20180911
Grant Date: 20180911
Priority Date: 20091016
Inventors: NASHNER, MICHAEL
Assignee: APPLE INC
CPC Classifications: [{"code": "Y10T156/1041", "inventive": false, "first": false, "tree": "[]"}, {"code": "B41M5/262", "inventive": true, "first": true, "tree": "[]"}, {"code": "Y10T428/13", "inventive": false, "first": false, "tree": "[]"}, {"code": "C25D11/18", "inventive": true, "first": false, "tree": "[]"}, {"code": "C25D11/04", "inventive": true, "first": false, "tree": "[]"}, {"code": "C25D11/04", "inventive": true, "first": false, "tree": "[]"}, {"code": "C25D11/18", "inventive": true, "first": false, "tree": "[]"}, {"code": "Y10T156/1041", "inventive": false, "first": false, "tree": "[]"}, {"code": "Y10T428/13", "inventive": false, "first": false, "tree": "[]"}, {"code": "Y10T156/1041", "inventive": false, "first": false, "tree": "[]"}, {"code": "Y10T428/13", "inventive": false, "first": false, "tree": "[]"}, {"code": "C25D11/04", "inventive": true, "first": false, "tree": "[]"}, {"code": "B41M5/262", "inventive": true, "first": true, "tree": "[]"}, {"code": "B41M5/262", "inventive": true, "first": true, "tree": "[]"}]
Family ID: 44062281