氟磺酸盐
化合物列表

| 化学式 | 名称 | 颜色 | 分解温度（°C） | 分解产物 | 晶体结构 | 参考资料 |
| --- | --- | --- | --- | --- | --- | --- |
| LiSO3F | 氟磺酸锂 |  |  |  | C2/m a=8.54 b=7.62 c=4.98 β=90.0 V=81 |  |
| Be(SO3F)2 | 氟磺酸铍 |  |  | SO3 |  |  |
| CF3(SO3F) | 氟磺酸三氟甲酯 |  |  |  |  |  |
CF2(SO3F)2: 
CF(SO3F)3: 
| C(SO3F)4 | 氟磺酸碳 |  |  |  |  |  |
| NH4SO3F | 氟磺酸铵 |  |  |  | 正交晶系 Pnma a=8.97 b=6.00 c=7.54 V=101.4 Z=4 |  |
| N(CH3)4SO3F | 四甲基氟磺酸铵 |  |  |  | 正交晶系 Pnma a=8.38 b=8.38 c=5.86 V=102.88 Z=4 |  |
| NOSO3F | 氟磺酸亚硝酰 |  | 熔点 156 |  | 密度 1.96 |  |
| NO2SO3F | 氟磺酸硝酰 |  |  |  |  |  |
| S2O6F2 | 过氧化氟磺酰 |  |  |  |  |  |
| NaSO3F | 氟磺酸钠 |  |  |  | 六方晶系 a=5.4812 b=5.4812 c=6.5172 V=169.57 Z=2 密度 2.390 |  |
| Mg(SO3F)2 | 氟磺酸镁 |  |  | SO3 |  |  |
Al(SO3F)2.3CH3CN: 
| Al(SO3F)3 | 氟磺酸铝 | 白色 |  |  | 聚合物，氟磺酸根是二齿桥接配体 |  |
| Si(SO3F)4 | 氟磺酸硅 |  |  | S2O5F2 SiO2 |  |  |
| PO(SO3F)3 | 氟磺酸磷(V)酰 |  |  | S2O5F2 |  |  |
| PO(SO3F) | 氟磺酸磷(III)酰 |  |  |  |  |  |
| ClSO3F | 氟磺酸氯 |  |  |  |  |  |
| ClO2SO3F | 氟磺酸氯酰 | 红或浅黄 | 低熔点 |  |  |  |
| KSO3F | 氟磺酸钾 |  |  |  | Pnma a=8.62 b=5.84 c=7.35 V=92.5 |  |
| Ca(SO3F)2 | 氟磺酸钙 |  |  | CaF2 SO3 |  |  |
| Ti(SO3F)4 | 氟磺酸钛 |  |  | S2O5F2 |  |  |
| VO(SO3F)3 | 氟磺酸氧钒 | 深红色液体 |  |  |  |  |
| CrO2(SO3F)2 | 氟磺酸氧铬 | 绿或棕 |  |  |  |  |
| Mn(SO3F)2 | 氟磺酸锰(II) |  |  |  |  |  |
| MnO(SO3F) | 氟磺酸氧锰(III) | 深棕 |  |  |  |  |
| Mn(SO3F)3 | 氟磺酸锰(III) |  |  |  |  |  |
| Mn(CO)4(SO3F) | 四羰基氟磺酸锰 |  |  |  |  |  |
| Mn(CO)5(SO3F) | 五羰基氟磺酸锰 |  |  |  |  |  |
Rb2Mn(SO3F)5: 
Cs2Mn(SO3F)5: 
| Fe(SO3F)3 | 氟磺酸铁 | 灰绿色 | 230 | S2O5F2 SO3 FeF3 |  |  |
| CoO(SO3F) | 氟磺酸氧铬 | 巧克力色 |  |  |  |  |
| Ni(SO3F)2 | 氟磺酸镍 |  |  |  |  |  |
Ni(py)4(SO3F)2 py=吡啶: 
| NiO(SO3F) | 氟磺酸氧镍 | 深灰色 |  |  |  |  |
| Cu(SO3F)2 | 氟磺酸铜 | 浅黄或白 | 210 | S2O5F2 SO3 CuSO4 CuF2 |  |  |
Cu(py)4(SO3F)2 py=pyridine: 
Cu(SO3F).CH3CN: 
| Zn(SO3F)2 | 氟磺酸锌 | 白色 | 280 | SO3 ZnF2 |  |  |
Zn(py)4(SO3F)2 py=pyridine: 
| Ga(SO3F)3 | 氟磺酸镓 | 白色 | 240 | SO3 | 聚合物 |  |
| As(SO3F)3 | 氟磺酸砷 |  |  | S2O5F2 |  |  |
AsF2(SO3F)3: 
AsF3(SO3F)2: 
| BrSO3F | 氟磺酸溴 | 红色液体 |  |  |  |  |
| RbSO3F | 氟磺酸铷 |  |  |  | 正交晶系 Pnma a=8.7812 b=6.0318 c=7.5108 V=397.82 Z=4 密度 3.081 |  |
| Sr(SO3F)2 | 氟磺酸锶 |  |  | SO2F2 |  |  |
MoO2(SO3F)2: 
| Nb(SO3F)5 | 氟磺酸铌 | 无色溶液 | 25 | SO3 |  |  |
| NbO(SO3F)3 | 氟磺酸氧铌 | 黄色液体 |  |  |  |  |
| Ru(SO3F)3 | 氟磺酸钌 | 非常深的红 |  |  |  |  |
| CsRu(SO3F)4 |  | 深棕色 |  |  |  |  |
| ClO2Ru(SO3F)4 |  | 黑色 |  |  |  |  |
| CsRu(SO3F)5 |  | 红棕色 |  |  |  |  |
| Cs2Ru(SO3F)6 |  | 亮橙色 |  |  |  |  |
| K2Ru(SO3F)6 |  | 亮橙色 |  |  |  |  |
| Rh(SO3F)3 | 氟磺酸铑 | 亮橙色 | 190 |  |  |  |
| Pd(SO3F)2 | 氟磺酸钯(II) | 紫色 | 250 | SO3 PdF2 |  |  |
| Pd(SO3F)3 | 氟磺酸钯(III) | 深棕色 | 180 |  |  |  |
| Pd(CO)2(SO3F)2 |  | 黄色 |  |  |  |  |
| c-Pd2(μ-CO)2](SO3F)2 |  | 橙色 |  |  | 单斜晶系 C2/c a=11.495 b=8.255 c=9.556 β =91.94 Z=8 |  |
| AgSO3F | 氟磺酸银(I) |  |  |  | P21/m a=5.413 b=8.174 c=7.544 β=94.60 V=83.17 Z=4 |  |
| Ag(SO3F)2 | 氟磺酸银(II) | 深棕色 | 室温 >120时反应迅速 | Ag3(SO3F)4 SO3F• | 单斜晶系 a=10.5130 Å, b= 7.7524 Å, c = 8.9366 Å, β = 117.867° V =643.88 Å3, Z = 4 密度 3.15 gcm−3 |  |
| Ag2O(SO3F)2 |  | 黑色 |  |  |  |  |
| AgI2AgII(SO3F)4 | 氟磺酸银(I,II) | 黑色 |  |  |  |  |
| KAgI2AgII(SO3F)5 |  |  |  |  | 正交晶系 P 2221, a  = 6.4736 b  = 7.3915 c  = 17.7736 |  |
| RbAgI2AgII(SO3F)5 |  |  |  |  | 正交晶系 P 2221, a  = 6.4828 b  = 7.3551c  = 18.0262 |  |
| RbAg(SO3F)3 |  |  |  |  | 单斜晶系 P 21/m , a  = 15.815 b  = 15.486 c  = 17.021 β  = 101.513 |  |
| CsAg(SO3F)3 |  |  |  |  | 三斜晶系 P1_ , a  = 14.9241 b  = 9.7046 c  = 17.8465 α  = 109.116°, β  = 84.655° γ  = 119.171° |  |
| Cd(SO3F)2 | 氟磺酸镉 |  |  |  |  |  |
| In(SO3F)3 | 氟磺酸铟 |  |  |  | 聚合物 |  |
| Sn(SO3F)4 |  |  |  | S2O5F2 |  |  |
SbF4SO3F: 
Sb(SO3F)2.2CH3CN: 
| Cs[Sb(SO3F)6] | 六(氟磺酸根)合锑(V)酸铯 |  |  |  | 三方晶系 R3̄ a = 12.0317 Å, c = 12.026 Å, Z = 3 |  |
TeF5SO3F: 
| ISO3F | 氟磺酸碘 |  |  |  |  |  |
ICl2SO3F: 
| IBr2SO3F |  | 锈棕色 | 90 | ISO3F, Br2 |  |  |
| IO2SO3F | 氟磺酸碘酰 | 黄色 | 100 |  |  |  |
| IF3(SO3F)2 | 二(氟磺酸根)三氟化碘 |  |  |  |  |  |
FXe(SO3F): 
| Xe(SO3F)2 | 氟磺酸氙(II) |  |  |  |  |  |
| F5Xe(SO3F) | 氟磺酸五氟化氙 |  |  |  |  |  |
| CsSO3F | 氟磺酸铯 |  |  |  | l41/a a=5.611 b=5.611 c=14.13 V=111.3 Z=4 |  |
| Cs[H(SO3F)2] | 氟磺酸氢铯 |  |  |  |  |  |
| Ba(SO3F)2 | 氟磺酸钡 |  |  | BaSO4 SO2F2 |  |  |
| Ho(SO3F)3 | 氟磺酸钬 |  |  |  |  |  |
| Ta(SO3F)5 | 氟磺酸钽 | 无色溶液 |  |  |  |  |
| TaO(SO3F)3 | 氟磺酸氧钽 | 黄色液体 |  |  |  |  |
| WO(SO3F)4 | 四(氟磺酸根)氧钨 | 无色液体 |  |  |  |  |
| ReO2(SO3F)3 | 三(氟磺酸根)二氧铼 | 白色固体 |  |  |  |  |
| ReO3(SO3F) | 氟磺酸三氧铼 | 黄色液体 |  |  |  |  |
Re(CO)5(SO3F): 
| Os(SO3F)3 |  | 亮绿色 | 130 |  |  |  |
| Ir(SO3F)3 | 氟磺酸铱(III) |  |  |  |  |  |
| Ir(SO3F)4 | 氟磺酸铱(IV) |  |  |  |  |  |
Cs2Ir(SO3F)6: 
BaIr(SO3F)6: 
(ClO2)2Ir(SO3F)6: 
| mer-Ir(CO)3(SO3F)3 |  | 无色 |  |  | 单斜晶系 P21/c, Z = 4, a = 8.476 b = 12.868 c = 12.588  β = 108.24°, V = 1304.0 |  |
| Pt(SO3F)4 | 氟磺酸铂 |  |  |  |  |  |
| Cs2[Pt(SO3F)6] | 六(氟磺酸根)合铂(IV)酸铯 |  |  |  |  |  |
| Pt(CO)2(SO3F)2 |  | 奶油色 |  |  |  |  |
AuICO(SO3F): 
| AuII(SO3F)2 | 氟磺酸金(II) | 黄红色 |  |  |  |  |
| AuIII(SO3F)3 | 氟磺酸金(III) |  |  |  |  |  |
| Cs[Au(SO3F)4] | 四(氟磺酸根)合金(III)酸铯 |  |  |  | 单斜晶系 C2/c a = 17.725 Å, b = 5.822 Å, c = 14.624 Å, β = 102.120°, Z = 4 |  |
| Hg(SO3F)2 | 氟磺酸汞 |  |  |  | 密度 3.715 |  |
| TlSO3F | 氟磺酸铊(I) |  |  |  | 正交晶系 a=5.2205 b=5.5141 c=13.4378 V=386.83 Z=4 密度 5.210 |  |
| TlO(SO3F) | 氟磺酸氧铊(III) | 棕色 |  |  |  |  |
| Tl(SO3F)3 | 氟磺酸铊(III) |  |  |  |  |  |
| Pb(SO3F)4 | 氟磺酸铅(IV) |  |  |  |  |  |
Bi(SO3F)3: 
| Th(SO3F)4 | 氟磺酸钍 |  |  |  |  |  |
| U(SO3F)2 | 氟磺酸铀(II) | 黄色 |  |  |  |  |
| U(SO3F)3 | 氟磺酸铀(III) | 绿色 |  |  |  |  |
| U(SO3F)4 | 氟磺酸铀(IV) | 肉色 |  |  |  |  |
Na2U(SO3F)6: 
| UO(SO3F)2 | 氟磺酸铀(IV)酰 |  |  |  |  |  |
| UO2(SO3F)2 | 氟磺酸铀(VI)酰 |  |  |  |  |  |