自修复材料
引用

↑   Caruso, M.; Davis, Douglas A.; Shen, Qilong; Odom, Susan A.; Sottos, Nancy R.; White, Scott R.; Moore, Jeffrey S. (2009). "Mechanically-Induced Chemical Changes in Polymeric Materials". Chem. Rev. 109 (11): 5755–5758. doi:10.1021/cr9001353.
↑  Caruso, M.; Davis, Douglas A.; Shen, Qilong; Odom, Susan A.; Sottos, Nancy R.; White, Scott R.; Moore, Jeffrey S. (2009). "Mechanically-Induced Chemical Changes in Polymeric Materials". Chem. Rev. 109 (11): 5755–5758.
↑  Bergman, S.D.; Wudl, F. (2008). "Mendable Polymers". Journal of Materials Chemistry 18: 41–62
↑  Armstrong, G.; Buggy, M. (2005). "Hydrogen-bonded supramolecules polymers: A literature review". Journal of Materials Science 40 (3): 547. Bibcode:2005JMatS..40..547A. doi:10.1007/s10853-005-6288-7.
↑  Bergman, S.D.; Wudl, F. (2008). "Mendable Polymers". Journal of Materials Chemistry 18: 41–62. doi:10.1039/b713953p.
↑  Chujo, Y.; Sada, K.; Saegusa, T. (1990). "Reversible Gelation of Polyoxazoline by Means of Diels-Alder Reaction". Macromolecules 23 (10): 2636–2641.
↑   Schiraldi, D.A; Liotta, Charles L.; Collard, David M.; Schiraldi, David A. (1999). "Cross-Linking and Modification of Poly(ethylene terephthalate-co-2,6-anthracenedicarboxylate) by Diels−Alder Reactions with Maleimides". Macromolecules 32 (18): 5786–5792
↑  Wudl, F.; Dam, MA; Ono, K; Mal, A; Shen, H; Nutt, SR; Sheran, K; Wudl, F (2002). "A Thermally Re-mendable Cross-Linked Polymeric Material". Science 295 (5560): 1698–1702
↑  Saegusa, T.; Sada, Kazuki; Naka, Akio; Nomura, Ryoji; Saegusa, Takeo (1993). "Synthesis and redox gelation of disulfide-modified polyoxazoline". Macromolecules 26 (5): 883–887.
↑  Blaiszik, B.J.; Kramer, S.L.B.; Olugebefola, S.C.; Moore, J.S.; Sottos, N.R.; White, S.R. (2010). "Self-Healing Polymers and Composites". Annual Review of Materials Research 40 (1): 179–211.
1 2  Pang, J. W. C.; Bond, I. P. (2005). "A Hollow Fibre Reinforced Polymer Composite Encompassing Self-Healing and Enhanced Damage Visibility". Composite Science and Technology 65 (11–12): 1791–1799.
1 2 3  Olugebefola, S. C.; Aragon, A. M.; Hansen, C. J.; Hamilton, A. R.; Kozola, B. D.; Wu, W.; Geubelle, P. H.; Lewis, J. A. et al. (2010). "Polymer Microvascular Network Composites". Journal of Composite Materials 44 (22): 2587–2603.
↑  Williams, H R; Trask, R S; Bond, I P (2007). "Self-healing composite sandwich structures". Smart Materials and Structures 16 (4): 1198–1207.
↑  White, S.R.; N. R. Sottos, P. H. Geubelle, J. S. Moore, M. R. Kessler, S. R. Sriram, E. N. Brown & S. Viswanathan (2001-02-15). "Autonomic healing of polymer composites". Nature (PDF) 409 (6822): 794–797
↑  White, S. R.; Delafuente, David A.; Ho, Victor; Sottos, Nancy R.; Moore, Jeffrey S.; White, Scott R. (2007). "Solvent-Promoted Self-Healing in Epoxy Materials". Macromolecules 40 (25): 8830–8832.
↑  Grubbs, R.; Tumas, W (1989). "Polymerization and Organotransition Metal Chemistry". Science 243 (4893): 907–915.
↑  Hayes, S.A.; Jones, F.R.; Marshiya, K.; Zhang, W. (2007). "A self-healing thermosetting composite material". Composites Part A: Applied Science and Manufacturing 38 (4): 1116–1120. doi:10.1016/j.compositesa.2006.06.008. ISSN 1359835X.
↑  Thostenson, E. T.; Chou, T.-W. (2006). "Carbon Nanotube Networks: Sensing of Distributed Strain and Damage for Life Prediction and Self Healing". Advanced Materials 18 (21): 2837–2841. doi:10.1002/adma.200600977. ISSN 09359648.
图示 1. 均裂 甲基丙烯酸甲酯（PMMA）
图示 2 乙二醇的异裂
图示3 自修复高分子通过狄尔斯—阿尔德反应在呋喃或者顺丁烯二酰亚胺的条件下，发生交联。
图示4 在呋喃—丁二烯二酰亚胺条件下，高分子交联网状结构的降解。
图示5  可逆交联高分子通过二硫键连接.
关于胶囊修复机制的描述. 粉红色圆圈代表单体胶囊，紫色小点代表催化剂。
图示六. DCPD的通过格拉布催化剂进行ROMP反应