Piala Raja Spanyol 2020–2021
Babak 32 besar > Pertandingan

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| 16 Januari 2021 | Peña Deportiva (3) | 1–4 (p.w.) | Valladolid (1) | Santa Eulària des Riu |  |
| 12:00 |  Andrada  13'  | Laporan |  Míchel  62' (pen.)  Mesa  96' (pen.), 112'  Plano  116'  | Stadion: Municipal  Wasit: David Medié Jiménez  |     |
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| 16 Januari 2021 | Almería (2) | 5–0 | Alavés (1) | Almería |  |
| 12:00 |  Sadiq  8', 45+1'  Aketxe  45'  Battaglia  52' (b.d.)  Villar  81' (pen.)  | Laporan |  | Stadion: Juegos Mediterráneos  Wasit: Javier Alberola Rojas  |     |
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| 16 Januari 2021 | Girona (2) | 2–0 | Cádiz (1) | Girona |  |
| 16:00 |  Valery  48', 58'  | Laporan |  | Stadion: Montilivi  Wasit: Valentín Pizarro Gómez  |     |
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| 16 Januari 2021 | Fuenlabrada (2) | 1–1 (p.w.) (2–4 a.p.) | Levante (1) | Las Rozas |  |
| 18:00 |  Garcés  68'  | Laporan |  Glauder  19' (b.d.)  | Stadion: La Ciudad del Fútbol  Wasit: Santiago Jaime Latre  |  |
|   |   | Adu penalti |  |  |  |
|   |  Iribas   Pinchi   Garcés   Cristóbal   |   |   Roger   Melero   León   Duarte  |  |  |
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| 16 Januari 2021 | Leganés (2) | 0–1 (p.w.) | Sevilla (1) | Madrid |  |
| 20:00 |  | Laporan |  Ocampos  96'  | Stadion: Wanda Metropolitano  Wasit: Pablo González Fuertes  |     |
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| 16 Januari 2021 | Rayo Vallecano (2) | 2–0 | Elche (1) | Las Rozas |  |
| 22:00 |  Bebé  36'  Catena  78'  | Laporan |  | Stadion: La Ciudad del Fútbol  Wasit: Isidro Díaz de Mera Escuderos  |     |
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| 17 Januari 2021 | Málaga (2) | 1–2 | Granada (1) | Málaga |  |
| 12:00 |  Quintana  76'  | Laporan |  Fede  16'  Molina  28'  | Stadion: La Rosaleda  Wasit: Carlos del Cerro Grande  |     |
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| 17 Januari 2021 | Espanyol (2) | 0–2 | Osasuna (1) | Cornellà de Llobregat |  |
| 12:00 |  | Laporan |  Martínez  9'  Barja  29'  | Stadion: RCDE Stadium  Wasit: Mario Melero López  |     |
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| 17 Januari 2021 | Sporting Gijón (2) | 0–2 | Real Betis (1) | Gijón |  |
| 16:00 |  | Laporan |  Canales  28' (pen.)  Rodri  31'  | Stadion: El Molinón  Penonton: 300 Wasit: Ricardo de Burgos Bengoetxea  |     |
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| 17 Januari 2021 | Navalcarnero (3) | 3–1 | Eibar (1) | Navalcarnero |  |
| 16:00 |  Jaimez  30' (pen.)  Esnáider  61', 79'  | Laporan |  Muto  16'  | Stadion: Mariano González  Wasit: Adrián Cordero Vega  |     |
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| 17 Januari 2021 | Tenerife (2) | 0–1 | Villarreal (1) | Santa Cruz de Tenerife |  |
| 17:00 |  | Laporan |  Niño  90'  | Stadion: Heliodoro Rodríguez López  Wasit: César Soto Grado  |     |
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| 17 Januari 2021 | Alcorcón (2) | 0–2 | Valencia (1) | Las Rozas |  |
| 18:00 |  | Laporan |  Koindredi  12'  Vallejo  77'  | Stadion: La Ciudad del Fútbol  Wasit: Xavier Estrada Fernández  |     |
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| 20 Januari 2021 | Córdoba (3) | 0–2 | Real Sociedad (1) | Córdoba |  |
| 19:00 |  | Laporan |  Willian José  57', 84'  | Stadion: Nuevo Arcángel  Wasit: Guillermo Cuadra Fernández  |     |
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| 20 Januari 2021 | Alcoyano (3) | 2–1 (p.w.) | Real Madrid (1) | Alcoy |  |
| 21:00 |  Solbes  80'  Juanan  115'  | Laporan |  Militão  45'  | Stadion: El Collao  Wasit: José María Sánchez Martínez  |     |
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| 21 Januari 2021 | UD Ibiza (3) | 1–2 | Athletic Bilbao (1) | Ibiza |  |
| 19:00 |  | Laporan |  R. García  52'  Núñez  90+1'  | Stadion: Can Misses  Wasit: Pablo González Fuertes  |     |
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| 21 Januari 2021 | Cornellà (3) | 0–2 (p.w.) | Barcelona (1) | Cornellà de Llobregat |  |
| 21:00 |  | Laporan |  Dembélé  92'  Braithwaite  120+1'  | Stadion: Nou Camp Municipal  Wasit: César Soto Grado  |     |
↑  Mengingat ketidakmungkinan untuk dapat memainkan pertandingan di stadion Fernando Torres di Fuenlabrada akibat badai "Filomena".
↑  Mengingat ketidakmungkinan untuk dapat memainkan pertandingan di stadion Butarque di Leganés akibat badai "Filomena".
↑  Mengingat ketidakmungkinan untuk dapat memainkan pertandingan di stadion Vallecas di Madrid akibat badai "Filomena".
↑  Mengingat ketidakmungkinan untuk dapat memainkan pertandingan di stadion Santo Domingo di Alcorcón akibat badai "Filomena".