> The only outcomes of this thought experiment are one of: 1. denying that physicalism is true, or 2. denying that quale are facts, 3. accepting that Mary would be able to deduce her quale, 4. concluding that the thought experiment contains some inherent contradiction.

No, you left out one:

5. Denying that there is any difference, from the standpoint of testing whether physicalism is true or false, between Mary "deducing" her quale and Mary "triggering" her quale with a red LED or surgery or by imagining.

Basically you are trying to make an argument by redefining words to make arbitrary distinctions that don't have any bearing on whether physicalism is true or false. First you want to limit what Mary has to "knowledge", but nothing in physicalism requires all physical things to be "knowledge" or requires that all physical things must be reachable from "knowledge". Then you want to limit Mary to only having "factual knowledge", but nothing in physicalism requires all physical things to be "factual knowledge" or to be reachable from "factual knowledge". Then you want to limit Mary to only having "third-party objective physical facts", but nothing in physicalism requires that all physical things are "third-party objective physical facts". Then you want to limit Mary to only be able to "deduce" her quale instead of triggering it or imagining it, but nothing in physicalism requires someone to have to "deduce" their quale in order to know what it is like without having been subjected to the normal external stimulus (in this case the image of a red apple on Mary's retina) that would trigger it. Physicalism simply does not make or require any of these distinctions you keep making.

The claim of physicalism is simple: Mary's quale "seeing red" is a physical thing. (Or "process", or "fact", or whatever you want to call it; the substance of the claim remains the same.) The only way to disprove that would be to show that her quale being a physical thing somehow leads to a contradiction. The Knowledge Argument does not do that. It does not even claim to do that. It simply constructs a straw man version of "physicalism" that is vulnerable to refutation by this particular argument even though actual physicalism is not.

When you look at what physicalism actually says, the so-called Knowledge Argument boils down to a bare assertion. The premise is that Mary has all the physical information. The claim is that she learns something when she sees the red apple, implying that she did not have the information about what it would be like to see the apple beforehand, when she had all the physical information. But the claim simply does not follow from the premise; it is a non sequitur. The only way to get to the claim from the premise is to add an additional premise that having all the physical information does not include having the information about what it is like to see the red apple. But of course that is just arguing in a circle; it is simply assuming that physicalism is false in order to "prove" that physicalism is false.

The whole point of physicalism is that having all the physical information is having all the information, so it includes knowing what it is like to see red, to taste wine, to feel the sun shining on you, etc., etc., etc.. So any thought experiment that claims that Mary, who has all the physical information, will learn something when she sees the red apple is simply based on a false premise according to physicalism. Which makes it obvious that no such argument can refute physicalism.