##Instruction:
Database: toxicology
Total Tables: 4
Total Columns: 11

Table Schemas:

Database: toxicology
Total Tables: 4
Total Columns: 11

Table Schemas:

Table: atom (3 columns)
-----------------------
• atom_id (text): the unique id of atoms
• molecule_id (text): identifying the molecule to which the atom belongs
  Values: commonsense evidence:
TRXXX_i represents ith atom of molecule TRXXX
• element (text): the element of the toxicology
  Values:  cl: chlorine
 c: carbon
 h: hydrogen
 o: oxygen
 s: sulfur
 n: nitrogen
 p: phosphorus
 na:...

Table: bond (3 columns)
-----------------------
• bond_id (text): unique id representing bonds
  Values: TRxxx_A1_A2:
TRXXX refers to which molecule
A1 and A2 refers to which atom
• molecule_id (text): identifying the molecule in which the bond appears
• bond_type (text): type of the bond
  Values: commonsense evidence:
-: single bond
'=': double bond
'#': triple bond

Table: connected (3 columns)
----------------------------
• atom_id (text): id of the first atom
• atom_id2 (text): id of the second atom
• bond_id (text): bond id representing bond between two atoms

Table: molecule (2 columns)
---------------------------
• molecule_id (text): unique id of molecule
  Values: "+" --> this molecule / compound is carcinogenic
'-' this molecule is not / compound carcinogenic
• label (text): whether this molecule is carcinogenic or not

##Evidence:
Chlorine refers to element = 'cl'; type of bond refers to bond_type

##Role Access Policy (Column-Level):
Role: MolecularDataEntry
Accessible Columns: molecule: molecule_id, label; atom: atom_id, molecule_id, element; bond: bond_id, molecule_id, bond_type

Based on the above schema and your role's column-level access policy, generate a SQL query to answer the question. If your role does not have access to the required columns, respond with: "Sorry, I cannot answer."


Question: What are the different types of bonds that chlorine atoms form, ranked by their frequency, and how many non-chlorine atoms are involved in each bond type?
Evidence: Chlorine refers to element = 'cl'; type of bond refers to bond_type
Answer: Sorry, I cannot answer.
Permission: denied (Missing column permissions: connected: atom_id, bond_id)
Gold SQL: WITH ChlorineAtoms AS (
    SELECT atom_id, molecule_id
    FROM atom
    WHERE element = 'cl'
),
ChlorineBonds AS (
    SELECT DISTINCT b.bond_id, b.molecule_id, b.bond_type
    FROM bond b
    JOIN connected c ON b.bond_id = c.bond_id
    JOIN ChlorineAtoms ca ON c.atom_id = ca.atom_id
),
BondStats AS (
    SELECT 
        bond_type,
        COUNT(*) AS bond_count,
        COUNT(DISTINCT molecule_id) AS molecule_count,
        RANK() OVER (ORDER BY COUNT(*) DESC) AS popularity_rank
    FROM ChlorineBonds
    GROUP BY bond_type
)
SELECT 
    bs.bond_type,
    bs.bond_count,
    bs.molecule_count,
    CASE 
        WHEN bs.popularity_rank = 1 THEN 'Most Common'
        WHEN bs.popularity_rank = 2 THEN 'Second Most Common'
        ELSE 'Less Common'
    END AS popularity,
    (SELECT COUNT(DISTINCT a.atom_id) 
     FROM atom a 
     JOIN connected c ON a.atom_id = c.atom_id
     JOIN bond b ON c.bond_id = b.bond_id
     WHERE b.bond_type = bs.bond_type AND a.element != 'cl') AS non_chlorine_atoms_in_bond
FROM BondStats bs
ORDER BY bs.popularity_rank ASC