On 26 May 2001, Bolocco married former Argentine president Carlos Menem in La Rioja, Argentina, whom she met while interviewing him at the Casa Rosada presidential house in Argentina.
Pada 26 Mei 2001, Bolocco menikah dengan mantan Presiden Argentina Carlos Menem di La Rioja, Argentina, tokoh yang ditemuinya ketika wawancara di Kediaman Presiden Argentina Casa Rosada.