The periodic table and a natural number for each element
What were Mendeleev's assertations concerning the first periodic table?
Atomic number
The periodic table and a natural number for each element. Loosely speaking, the existence or construction of a periodic table of elements creates an ordering of the elements, and so they can be numbered in order. Dmitri Mendeleev claimed that he arranged his first periodic tables in order of atomic weight ("Atomgewicht"). However, in consideration of the elements' observed chemical properties, he changed the order slightly and placed tellurium (atomic weight 127.6) ahead of iodine (atomic weight 126.9). This placement is consistent with the modern practice of ordering the elements by proton number, "Z", but that number was not known or suspected at the time. A simple numbering based on periodic table position was never entirely satisfactory, however. Besides the case of iodine and tellurium, later several other pairs of elements (such as argon and potassium, cobalt and nickel) were known to have nearly identical or reversed atomic weights, thus requiring their placement in the periodic table to be determined by their chemical properties. However the gradual identification of more and more chemically similar lanthanide elements, whoise atomic number was not obvious, led to inconsistency and uncertainty in the periodic numbering of elements at least from lutetium (element 71) onwards (hafnium was not known at this time). [[File:Henry Moseley.jpg|140px|thumb|Henry Moseley helped develop the concept of atomic number by showing experimentally (1913) that Van den Broek's 1911 hypothesis combined with the Bohr model nearly correctly predicted atomic X-ray emissions.]]