South Dakota Administrative Rules › Title 74 - Department of Environment And Natural Resources › Article 74:51 - Surface water quality › Chapter 74:51:01 - Surface water quality standards › Appendix B - Toxic Pollutant Criteria

Current through Register Vol. 51, page 10, July 15, 2024
SOUTH DAKOTA SURFACE WATER QUALITY
				STANDARDS(1)
FOR TOXIC POLLUTANTS - ARSD
				74:51:01
Pollutant
CAS Number
Human Health Value Concentrations in µg/L
Freshwater Aquatic Life Value Concentrations in µg/L Uses
				2-3-4 - 5-6-9
Use
1(2)
Uses
2-3-4 - 5-6-9(3)
Acute (CMC)
Chronic (CCC)
Acenaphthene
83329
70
90
Acenaphthylene (PAH)(6)
208968
Acrolein
107028
3
400
3
3
Acrylonitrile(4)
107131
0.061
7.0
Aldrin(4)
309002
0.0000007 7
0.0000007 7
3.0
Alpha-Hexachlorocyclohexane
(HCH)(4)
319846
0.00036
0.00039
Anthracene (PAH)(5)
120127
300
400
Antimony
7440360
5.6
640
Arsenic(4)
7440382
0.018(11)
0.14(11)
340
150
Asbestos(4)
1332214
7,000,000 fibers/L
alpha-BHC(4)
319846
0.0026
0.0049
beta-BHC(4)
319857
0.0091
0.017
Benzene(4)
71432
0.58
16
Benzidine(4)
92875
0.00014
0.011
Benzo(a)Anthracene(4)
56553
0.0012
0.013
Benzo(a)Pyrene(4)
50328
0.00012
0.00013
Benzo(b)Fluoroanthene(4)
205992
0.0012
0.0013
Benzo(k)Flouroanthene(4)
207089
0.012
0.013
Beryllium
7440417
4
beta-Hexachlorocyclohexane (HCH)
319857
0.0080
0.014
Bis(2-Chloro-1-methylethyl) Ether
108601
200
4,000
Bis(2-Chloroethyl) Ether(4)
111444
0.030
2.2
Bis(2-Ethylhexyl)Phthalate(4)
117817
0.32
0.37
Bis(Chloromethyl) Ether(4)
542881
0.00015
0.017
Bromoform(5)
75252
7.0
120
Butylbenzyl Phthalate(4)
85687
0.10
0.10
Cadmium
7440439
1.8(7)
0.72(7)
Carbon Tetrachloride(4)
56235
0.4
5
Chlordane(4)
57749
0.00031
0.00032
2.4
0.0043
Chlorine
7782505
19
11
Chlorobenzene
108907
100
800
Chlorodibromomethane(4)
124481
0.80
21
Chloroform(4)
67663
60
2,000
Chlorophenoxy Herbicide (2,4-D)
94757
1,300
12,000
Chlorophenoxy Herbicide (2,4,5-TP) [Silvex]
93721
100
400
2-Chloronaphthalene
91587
800
1,000
2-Chlorophenol
95578
30
800
3-Methyl-4-Chlorophenol
59507
500
2,000
Chromium(III)
16065831
570(7)
74(7)
Chromium(VI)
18540299
16
11
Chrysene(4)
218019
0.12
0.13
Copper
7440508
1,300
13(7)
9.0(7)
Cyanide
57125
4(8)
400(8)
22(12)
5.2(12)
Diazinon
333415
0.17
0.17
4,4'-DDD(4)
72548
0.00012
0.00012
4,4'-DDE(4)
72559
0.000018
0.000018
4,4'-DDT(4)
50293
0.000030
0.000030
1.1
0.001
Dibenzo(a,h)Anthracene(4)
53703
0.00012
0.00013
1,2-Dichlorobenzene
95501
1,000
3,000
1,3-Dichlorobenzene
541731
7
10
1,4-Dichlorobenzene
106467
300
900
3,3'-Dichlorobenzidine(4)
91941
0.049
0.15
Dichlorobromomethane(4)
75274
0.95
27
1,2-Dichloroethane(4)
107062
9.9
650
1,1-Dichloroethylene
75354
300
20,000
2,4-Dichlorophenol
120832
10
60
1,2-Dichloropropane(4)
78875
0.90
31
1,3-Dichloropropene(4)
542756
0.27
12
Dieldrin(4)
60571
0.0000012
0.0000012
0.24
0.056
Diethyl Phthalate
84662
600
600
2,4-Dimethylphenol
105679
100
3,000
Dimethyl Phthalate
131113
2,000
2,000
Di-n-Butyl-Phthalate
84742
20
30
Dinitrophenols
25550587
10
1,000
2-Methyl-4,6-Dinitrophenol
534521
2
30
2,4-Dinitrophenol
51285
10
300
2,4-Dinitrotoluene(4)
121142
0.049
1.7
1,2-Diphenylhydrazine(4)
122667
0.03
0.2
alpha-Endosulfan
959988
20
30
0.22
0.056
beta-Endosulfan
33213659
20
40
0.22
0.056
Endosulfan Sulfate
1031078
20
40
Endrin
72208
0.03
0.03
0.086
0.036
Endrin Aldehyde
7421934
1
1
Ethylbenzene
100414
68
130
Fluoranthene
206440
20
20
Fluorene(5)
86737
50
70
Heptachlor(4)
76448
0.0000059
0.0000059
0.52
0.0038
Heptachlor epoxide(4)
1024573
0.000032
0.000032
0.52
0.0038
Hexachl orob enzene(4)
118741
0.000079
0.000079
Hexachl orobutadi ene(4)
87683
0.01
0.01
gamma-Hexachlorocyclohexane (HCH) [Lindane]
58899
4.2
4.4
0.95
Hexachlorocyclohexane (HCH) -
				Technical(4)
608731
0.0066
0.010
Hexachlorocyclopentadiene
77474
4
4
Hexachl oroethane(4)
67721
0.1
0.1
Indeno( 1,2,3 -cd)pyrene(4)
193395
0.0012
0.0013
Isophorone(4)
78591
34
1,800
Lead
7439921
65(7)
2.5(7)
Mercury
7439976
0.050
0.051
1.4
0.77(8)
Methyl Chloride(5)
74873
Methylmercury
22967926
0.3 mg/kg
Methoxychlor
72435
0.02
0.02
0.03
Methyl Bromide
74839
100
10,000
Methylene Chloride(4)
75092
20
1,000
N-Nitrosodimethylamine(4)
62759
0.00069
3.0
N-Nitrosodi-n-Propylamine(4)
621647
0.0050
0.51
N-Nitrosodiphenylamine(4)
86306
3.3
6.0
Nickel
7440020
610
4,600
470(7)
52(7)
Nitrobenzene
98953
10
600
Nonylphenol
84852153
28
6.6
Pentachlorobenzene
608935
0.1
0.1
Pentachlorophenol
87865
0.03
0.04
19(6)
15(6)
Phenanthrene(5)
85018
Phenol
108952
4,000
300,000
Polychlorinated Biphenyls,
PCBs(4)(9)
0.000064
0.000064
0.014
Pyrene
12900
20
30
Selenium
7782492
170
4,200
(10)
5.0(8)
Silver
7440224
3.2(7)
1,2,4,5-Tetrachlorobenzene
95943
0.03
0.03
2,3,7,8-Tetrachlorodibenzo-p-dioxon
				(Dioxin)(4)
1746016
5.0E-9
5.1E-9
1,1,2,2-Tetrachloroethane(4)
79345
0.2
3
Tetrachloroethylene(4)
127184
10
29
Thallium
7440280
0.24
0.47
Toluene
108883
57
520
Toxaphene(4)
8001352
0.00070
0.00071
0.73
0.0002
1,2-Trans-Dichloroethylene
156605
100
4,000
1,2,4-Trichlorobenzene
120821
0.071
0.076
1,1,1-Trichloroethane
71556
10,000
200,000
1,1,2-Trichloroethane(4)
79005
0.55
8.9
Trichloroethylene(4)
79016
0.6
7
2,4,5-Trichlorophenol
95954
300
600
2,4,6-Trichlorophenol(4)
88062
1.5
2.8
Vinyl Chloride(4)
75014
0.022
1.6
Zinc
7440666
7,400
26,000
120(7)
120(7)
SOUTH DAKOTA
Surface Water Quality
	 Standards
(1)
for Toxic Pollutants
(1) The aquatic life values for arsenic,
	 cadmium, chromium (III), chromium (VI), copper, lead, mercury (acute), nickel,
	 selenium, silver and zinc given in this document refer to the dissolved amount
	 of each substance unless otherwise noted. All surface water discharge permit
	 effluent limits for metals shall be expressed and measured in accordance with
	 §
									74:52:03:16.
(2) This human health value is based on two
	 routes of exposure - ingestion of contaminated aquatic organisms and drinking
	 water.
(3) This human health value is based on one
	 route of exposure - ingestion of contaminated aquatic organisms only.
(4) This substance is classified as a
	 carcinogen with the value based on an incremental risk of one additional
	 instance of cancer in one million persons
	 (10-6).
(5) Those chemicals which are not
	 individually classified as carcinogens but which are contained within a class
	 of chemicals with carcinogenicity as the basis for the criteria derivation for
	 that class of chemicals; an individual carcinogenicity assessment for these
	 chemicals is pending.
(6) For pH-dependent criteria, the value
	 given is an example only and is based on a pH of 7.8. Criteria for each case
	 must be calculated using the following equation taken from National Recommended
	 Water Quality Criteria: 2002 (EPA-822-R-02-047, November 2002):
Pentachlorophenol (PCP), ug/L
Chronic =
e
[1.005(pH) - 5.134] Acute =
e
[1.005(pH) - 4.869]
(7) For hardness-dependent criteria in ug/L,
	 the value given is an example only and is based on a
	 CaCO3 hardness of 100 mg/L. Criteria for each case must
	 be calculated using the following equations taken from National Recommended
	 Water Quality Criteria:
http://water.epa.gov/scitech/swguidance/standards/criteria/current/index.cfm#hhtable
:
Cadmium, ug/L
Chronic = (*CF)
e
(0.7977[ln(hardness)]-3.909)
Acute = (*CF)
e
(0.9789[ln(hardness)]-3.866)
*Conversion factors are hardness-dependent. The values shown are with a
	 hardness of 100 mg/L as calcium carbonate (CaCO3).
	 Conversion factors (CF) (from total to dissolved) for any hardness can be
	 calculated using the following equations:
Chronic: CF = 1.101672 - [(ln hardness)(0.041838)]
Acute: CF = 1.136672 - [(ln hardness)(0.041838)]
Chromium (III), ug/L
Chronic = (0.860)
e
(0.8190[ln(hardness)]+0.6848) Acute =
	 (0.316)
e
(0.8190[ln(hardness)]+3.7256)
Copper, ug/L
Chronic = (0.960)
e
(0.8545[1n(hardness)]-1.702) Acute =
	 (0.960)
e
(0.9422[ln(hardness)]-1.700)
Lead, ug/L
Chronic = (*CF)
e
(1.273[ln(hardness)]-4.705)
Acute = (*CF)
e
(1.273[ln(hardness)]-1.460)
*Conversion factors are hardness-dependent. The values shown are with a
	 hardness of 100 mg/L as calcium carbonate (CaCO3).
	 Conversion factors (CF) (from total to dissolved) for any hardness can be
	 calculated using the following equations:
Acute and Chronic: CF = 1.46203 - [(ln hardness)(0.145712)]
Nickel, ug/L
Chronic = (0.997)
e
(0.8460[ln(hardness)]+0.0584) Acute =
	 (0.998)
e
(0.8460[ln(hardness)]+2.255)
Silver, ug/L
Acute = (0.85)
e
(1.72[ln(hardness)]-6.59)
Zinc, ug/L
Chronic = (0.986)e(0.8473[ln(hardness)]+0.884) Acute =
	 (0.978)
e
(0.8473[ln(hardness)]+0.884)
(8) These criteria are based on the
	 total-recoverable fraction of the metal.
(9) This criterion applies to total pcbs,
	 (e.g. the sum of congener or all isomer or homolog or Aroclor analyses).
(10) The (0.996)CMC = 1/[fl/CMC1) +
	 (f2/CMC2)] where f1 and f2 are the fractions of total selenium that are treated
	 as selenite and selenate, respectively, and CMC1 and CMC2 are 185.9 l2lg/L and
	 12.82 0g/L, respectively.
(11) This criterion for arsenic refers to
	 the inorganic form only.
(12) This criterion for cyanide is expressed
	 as free cyanide.