Arizona Administrative Code › Title 9 - HEALTH SERVICES › Chapter 14 - DEPARTMENT OF HEALTH SERVICES - LABORATORIES › Article 6 - LICENSING OF ENVIRONMENTAL LABORATORIES › Table 6.2.B - Approved Methods and Method Fees for Wastewater Parameters

Current through Register Vol. 30, No. 28, July 12, 2024
1. Microbiology of Wastewater and Sewage
							 Sludge
Description
Reference
Method/s
Fee Per Method
Ascaris lumbricoides
C8
10550
$228
P3
UofA2000
$228
Coliforms, Fecal, number per 100 ml or number per
							 gram dry weight, by Membrane Filter
C
9222D (2006)
$228
Coliforms, Fecal, by Multiple Tube Fermentation (may
							 be used for sewage sludge), number per 100 ml by MPN
C
9221C, E (2006)
$228
Coliforms, Total, by Membrane Filter
C
9222B (2006)
$228
Coliforms, Total, by Multiple Tube
							 Fermentation
C
9221B (2006)
$228
Control of pathogens and vectors in sewage
E3
625/R-92/013
$76
Cryptosporidium
A4.32
1622
$381
Cryptosporidium
and
Giardia
E. coli
, number per 100 ml, MPN
							 multiple tube
A4.39
1623
$381
C
9711B (2011)
$381
P2
600/R-95/178
$381
C
9222B (2006)
$228
E. coli
, number per 100 ml, MPN
							 multiple tube/multiple well
C
9223B (2004)
$228
E. coli
by m-ColiBlue
C1 and Z6
Hach 10029
$228
Enterococci
, number per 100 ml
							 MF
C
9230C (2007)
$228
Escherichia coli
by Colilert MPN, in
							 conjunction with SM 9221B and 9221C
C
9223B (2004)
$152
Escherichia coli
in conjunction with
							 SM 9221B and 9221C
C
9221F (2006)
$152
Entamoeba histolytica
C
9711C (2011)
$228
Enteric viruses
I
D4994-89
$381
Enteric viruses in sewage sludge
E3
EPA 625/R-92/103
$381
Fecal Coliforms by Colilert-18 (APP and Reuse
							 only)
C
9020B (2005)/9223B (2004)
$152
Fecal Coliforms by Colilert-18 (NPDES-ATP Permits
							 only)
C
9020B (2005)/9223B (2004)
$152
Fecal Coliforms in sewage sludge by MTF
Z1
EPA 1681
$228
Helminth Ova in sludge
Z4
600/1-87-014
$381
Salmonella
in sludge MPN
E5
9260D (1988)
$228
Salmonella
in Sewage Sludge
							 (Biosolids) by Modified MSRV
A4.34
1682
$228
Streptococcus, Fecal, by Membrane Filter
C
9230C (2007)
$194
Streptococcus, Fecal, by Multiple Tube
							 Fermentation
C
9230B (2007)
$194
Viruses
C
9510 (2011)
$381
P
Methods for Virology
$381
P2
600/R-95/178
$381
2. Wastewater Inorganic Chemistry, Nutrients
							 and Demand
Acid Mine Drainage
A4.27
1627
$303
Acidity
C
2310B (2011)
$39
Alkalinity, Total
A
310.2 (1974)
$19
C
2320B (2011)
$19
Ammonia
A2
350.1 (2.0)
$39
C
4500-NH3 B (2011)
$39
4500-NH3 C (2011)
$39
4500-NH3 D (2011)
$39
4500-NH3 E (2011)
$39
4500-NH3 G (2011)
$39
C1
Hach 10205
$39
Ammonia in sludge only
E5
4500-NH3B&C (1990)
$39
Biochemical Oxygen Demand/Carbonaceous Biochemical
							 Oxygen Demand
C
5210B (2011)
$152
C3
Hach 10360
$152
Boron
A1 A4.10
200.7 (4.4)
$10
200.8 (5.4)
$26
200.5 (4.2)
$10
C
4500-B B (2011)
$76
Bromide Calcium
A2
300.0 (2.1)
$26
A5
300.1 (1.0)
$26
A1
A4.10
200.7 (4.4)
$10
200.8 (5.4)
$26
200.5 (4.2)
$10
C
3111B (2011)
$26
3500-Ca B (2011)
$39
Carbon, Total Organic (TOC)
C
5310 B (2011)
$39
5310 C (2011)
$39
5310D (2011)
$39
Chemical Oxygen Demand
A
410.3 (1978)
$39
A2
410.4 (2.0)
$76
C
C1
5220 B (2011)
$39
5220 C (2011)
$39
5220 D (2011)
$76
Hach 8000
$39
Chloride
A2
300.0 (2.1)
$26
A5
300.1 (1.0)
$26
C
4500-Cl B (2011)
$39
4500-Cl C (2011)
$39
4500-Cl D (2011)
$39
4500-Cl E (2011)
$39
Chlorine, Total Residual
Color
Cyanide, Available
Cyanide, Free
C
4500-Cl B (2011)
$39
4500-Cl C (2011)
$39
4500-Cl D (2011)
$39
4500-Cl E (2011)
$39
4500-Cl F (2011)
$39
4500-Cl G (2011)
$39
C1
Hach 10014
$39
C
2120 B (2011)
$32
C
4500-CN G (2011)
$76
E7
Kelada-01
$76
Y
OIA-1677-09 (8/99)
$76
Y
OIA-1677-09 (8/99)
$76
Cyanide, Total
Fluoride
A2
335.4 (1.0)
$76
A6
QuickChem 10-204-00-1-X (2.1)
$76
C
Combination of 4500-CN B (2011) and 4500-CN C (2011),
							 followed by 4500-CN D (2011), 4500-CN E (2011), or 4500-CN F (2011)
$89
E7
Kelada-01
$76
A2
300.0 (2.1)
$26
A5
300.1 (1.0)
$26
C
4500-F B (2011)
$39
4500-F C (2011)
$39
4500-F D (2011)
$39
4500-F E (2011)
$39
Hardness
A
130.1 (1976)
$10
A1
A4.10
200.7 (4.4)
$10
200.8 (5.4)
$26
200.5 (4.2)
$10
C
2340B (2011)
$39
2340C (2011)
$39
Kjeldahl, Total Nitrogen
A
351.1 (1978)
$76
A2
351.2 (2.0)
$76
C
Z9
Combination of 4500-NH3 B
							 (2011) and either 4500-Norg  B (2011) or
							 4500-Norg C (2011)
$115
4500-NH3 C (2011)
$39
4500-NH3 D (2011)
$39
4500-NH3 E (2011)
$39
4500-NH3 F (2011)
$39
4500-NH3 G (2011)
$39
4500-NH3 H (2011)
$39
PAI-DK01 (12/94)
$76
Z10
PAI-DK02 (12/94)
$76
Z11
PAI-DK03 (12/94)
$76
Methylene Blue Active Substances
C
5540C (2011)
$39
Nitrate (as N)
Nitrate-Nitrite (as N)
Nitrite (as N)
A
352.1 (1971)
$76
A2
300.0 (2.1)
$26
A5
300.1 (1.0)
$26
C
3500-NO3 D (2011)
$39
A2
300.0 (2.1)
$26
353.2 (2.0)
$76
A5
300.1 (1.0)
$26
C
4500-NO3 E (2011)
$76
4500-NO3 F (2011)
$76
4500-NO3 H (2011)
$76
A2
A5
300.0 (2.1)
$26
353.2 (2.0)
$76
300.1 (1.0)
$26
C
4500-NO2 B (2011)
$76
4500-NO3 E (2011)
$76
4500-NO3 F (2011)
$76
Oil and Grease and Total Petroleum
							 Hydrocarbons
A4.24
1664 Rev B
$76
C
5520B (2011)
$76
Orthophosphate
A
365.3 (2.0)
$76
A2
300.0 (2.1)
$26
365.1 (2.0)
$76
A5
300.1 (1.0)
$26
C
4500-P E (2011)
$76
4500-P F (2011)
$76
Oxygen-consumption Rate (SOUR)
C
2710B (2011)
$39
Oxygen, Dissolved
pH (Hydrogen Ion)
C
C1
4500-O B (2011)
$26
4500-O C (2011)
$26
4500-O D (2011)
$26
4500-O E (2011)
$26
4500-O F (2011)
$26
4500-O G (2011)
$26
1002-8-2009
$26
C3
Hach 10360
$26
A
150.2
$39
C
4500-H B (2011)
$39
Phenols
A
420.1 (1978)
$116
A2
420.4 (1.0)
$116
C
A
5530 B (2010)
$116
5530 D (2010)
$116
Phosphorus, Total
365.3 (1978)
$76
365.4 (1974)
$76
A1
200.7 (4.4)
$10
A2
365.1 (2.0)
$76
C
A1
C
4500-P B (2011)
$76
4500-P E (2011)
$76
4500-P F (2011)
$76
4500-P G (2011)
$76
4500-P H (2011)
$76
Potassium
Residue, Filterable (TDS)
Residue, Nonfilterable (TSS)
200.7 (4.4)
$10
200.8 (5.4)
$26
3111B (2011)
$26
3500-K B (2011)
$26
C
2540C (2011)
$39
E8
I-1750-85
$39
C
2540D (2011)
$39
Residue, Settleable Solids
C
2540F (2011)
$39
Residue, Total
C
2540B (2011)
$39
Residue, Volatile
Silica, Dissolved
Sodium
A
160.4 (1971)
$39
C
2540E (2011)
$39
A1
A4.10
200.7 (4.4)
$10
200.8 (5.4)
$26
200.5 (4.2)
$10
C
4500-SiO2 B (2011)
$76
4500-SiO2 C (2011)
$76
4500-SiO2 E (2011)
$76
4500-SiO2 F (2011)
$76
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
A4.10
200.5 (4.2)
$10
C
C
3500-Na B (2011)
$26
3500-Na D (2011)
$26
3111B (2011)
$26
Sodium Azide
4110C (2011)
$76
Specific Conductance
A
120.1 (1982)
$39
C
2510B (2011)
$39
Sulfate
Sulfide (includes total and soluble)
Sulfite
A2
300.0 (2.1)
$26
375.2 (2.0)
$76
A5
300.1 (1.0)
$26
C
4500-SO4 C (2011)
$76
4500-SO4 D (2011)
$76
4500-SO4 E (2011)
$76
4500-SO4 F (2011)
$76
4500-SO4 G (2011)
$76
4500-S2- B (2011)
$39
C
4500-S2- D (2011)
$76
4500-S2- F (2011)
$39
4500-S2- G (2011)
$39
C1
Hach 8131
$39
C
4500-SO3 B (2011)
$76
Temperature, Degrees Celsius
C
2550B (2010)
$13
Total, Fixed and Volatile Solids in Solid and
							 Semisolid Samples in Sludge
C
2540G (2011)
$39
Turbidity, NTU
A2
180.1 (2.0)
$39
C
2130B (2011)
$39
3. Metals in Wastewater
a. Sample Preparation for Metals in
							 Wastewater
Acid Extractable Metals
C
3030C (2004)
$7
Digestion for Metals
C
3030D (2004)
$7
Microwave Digestion
E6
CEM Microwave Digestion
$7
Nitric Acid
C
3030E (2004)
$7
Nitric Acid/Hydrochloric Acid
C
3030F (2004)
$7
Nitric Acid/Perchloric Acid
C
3030H (2004)
$7
Nitric Acid/Perchloric Acid/Hydrofluoric Acid
C
3030I (2004)
$7
Nitric Acid/Sulfuric Acid
C
3030G (2004)
$7
Preliminary Filtration
C
3030B (2004)
$7
b. Methods to Analyze Metals in
							 Wastewater
Aluminum
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3113B (2010)
$26
3111D (2011)
$26
Antimony
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
A4.25
1638
$26
C
3111B (2011)
$26
3113B (2010)
$26
Arsenic
A
206.5 (1978)
$39
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3113B (2010)
$26
3500-As B (2011)
$76
Barium
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
A4.10
200.5 (4.2)
$10
C
3111D (2011)
$26
3113B (2010)
$26
Beryllium
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3111D (2011)
$26
3111E (2011)
$26
3113B (2010)
$26
Cadmium
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
A4.25
1638
$26
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
3500-Cd D (2011)
$76
Chromium (VI) Hexavalent
Chromium, Total
A1
218.6 (3.3)
$26
C
3500-Cr B (2011)
$39
3111C (2011)
$26
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
3500-Cr B (2011)
$76
Cobalt
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
Copper
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
A4.25
1638
$26
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
3500-Cu B (2011)
$76
3500-Cu C (2011)
$76
Gold
A
231.2 (1978)
$26
A1
200.8 (5.4)
$26
C
3111B (2011)
$26
Iridium
A
235.2 (1978)
$26
C
3111B (2011)
$26
Iron
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
3500-Fe B (2011)
$76
Lead
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
A4.25
1638
$26
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
3500-Pb B (2011)
$76
Lithium
A1
200.7 (4.4)
$10
Magnesium
A1
A4.10
200.7 (4.4)
$10
200.8 (5.4)
$26
200.5 (4.2)
$10
C
3111B (2011)
$26
Manganese
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3111B (2011)
$26
3113B (2010)
$26
3500-Mn B (2011)
$76
Mercury
A
245.2 (1974)
$52
A1
A4.17
200.7 (4.4)
$10
245.1 (3.0)
$52
1631E
$152
A4.23
245.7 (2.0)
$15
C
3112B (2011)
$52
Molybdenum
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
A4.10
200.5 (4.2)
$10
C
3111D (2011)
$26
3113B (2010)
$26
Nickel
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
A4.25
1638
$26
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
Osmium
A
252.2 (1978)
$26
C
3111D (2011)
$26
Palladium
A
253.2 (1978)
$26
C
3111B (2011)
$26
Platinum
A
255.2 (1978)
$26
C
3111B (2011)
$26
Rhodium
A
265.2 (1978)
$26
C
3111B (2011)
$26
Ruthenium
A
267.2 (1978)
$26
C
3111B (2011)
$26
Selenium
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3113B (2010)
$26
3114B (2011)
$76
Silver
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3111B (2011)
$26
3111C (2011)
$26
3113B (2010)
$26
Strontium
A1
200.7 (4.4)
$10
C
3111B (2011)
$26
3500-Sr B (2011)
$26
3500-Sr C (2011)
$20
3500-Sr D (2011)
$26
Thallium
A
279.2 (1978)
$26
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
A4.25
1638
$26
C
3111B (2011)
$26
Tin
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
200.9 (2.2)
$26
A4.10
200.5 (4.2)
$10
C
3111B (2011)
$26
3113B (2010)
$26
Titanium
A
283.2 (1978)
$26
A1 C
200.7 (4.4)
$10
200.8 (5.4)
$26
3111D (2011)
$26
Vanadium
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
A4.10
200.5 (4.2)
$10
C
3111D (2011)
$26
3500-V B (2011)
$76
Zinc
A
289.2 (1978)
$26
A1
200.7 (4.4)
$10
200.8 (5.4)
$26
A4.10
200.5 (4.2)
$10
A4.25
1638
$26
C
3111B (2011)
$26
3111C (2011)
$26
3500 Zn B (2011)
$76
4. Aquatic Toxicity Bioassay of
							 Wastewater
Toxicity, Acute
M1
EPA/600/4-90/027F
$194
Z12
821-R-02-012
$194
Toxicity, Chronic
N1
EPA/600/4-91/002
$194
Z2 Z13
821-R-02-013
$194
Lozarchak, J. 2001
$194
5. Organic Chemicals of
							 Wastewater
Volatile Organics for Pharmaceuticals
D3
524.2 (4.1)
$152
Purgeable Hydrocarbons
E
601
$76
Purgeable Aromatics
E
602
$76
Acrolein and Acrylonitrile
E
603
$76
624
$152
Phenols
E
604
$116
Benzidines
E
605
$116
Phthalate ester
E
606
$116
Nitrosamines
E
607
$116
Organochlorine Pesticides and PCBs Nitroaromatics and
							 Isophorone
E
608
$152
E2
608.1
$152
608.2
$152
E4
608 (3M)
$152
E
609
$116
PAHs
E
610
$116
Haloethers
E
611
$116
Chlorinated Hydrocarbons
E
612
$116
2, 3, 7, 8-Tetrachlorodibenzo-p-Dioxin
E
613
$457
Chlorinated Herbicides
E2
615
$116
Organohalide Pesticides and PCB
E2
617
$116
Triazine Pesticides
E2
619
$116
Thiophosphate Pesticides
E2
622.1
$116
Purgeables
E
624
$152
Base/Neutrals and Acids (all analytes excluding
							 pesticides)
E
625
$152
Base/Neutrals and Acids (pesticides only)
E
625
$152
Carbamate and Urea Compounds
E2
632
$116
Tetra- through Octa-Chlorinated Dioxins and
							 Furans
A4.22
1613 Rev B (10/94)
$258
VOCs by Isotope Dilution GC/MS
E
1624B
$152
Semivolatile Organic Compounds by Isotope Dilution
							 GC/MS
E
1625B
$152
Organophosphorus Pesticides
VOCs Specific to the Pharmaceutical Manufacturing
							 Industry by Isotope Dilution GC/MS
E1
1657
$116
E2
614
$116
614.1
$116
622
$116
K1
1666 (A)
$152
Herbicides
C
6640B (2006)
$116
Ethylene Glycol
K
BLS-188
$152
6. Radiochemistry of Wastewater
Alpha-Total pCi per liter
C
7110B (2011)
$206
L
900.0
$206
Alpha Counting Error, pCi per liter
C
7110B (2011)
$206
Beta-Total pCi per liter
C
7110B (2011)
$206
L
900.0
$206
Beta Counting Error, pCi
C
7110B (2011)
$206
Radium, Total pCi per liter
C
7500-Ra B (2011)
$206
L
903.0
$206
Radium
C
7500-Ra C (2011)
$206
L
903.1
$206