I need to add new menu item to the top level menu of QGIS Desktop (2.7.0);
I.e. it shall be on same level as "Project", "Edit", "View", "Layer" etc.

As far as I know there is pretty nice way how hide menu items (Settings->Customization)
Plus using QgisInterface (http://qgis.org/api/classQgisInterface.html) I can add new items to Menus already defined in QGIS (addLayerMenu, addPluginToDatabaseMenu etc) from my plugin code.

But I need new Menu item on top layer (this is req from customer):
will very appreciate if any ideas how can I make so

Thanks!


Question: The Acidity of the Hydrated Iron (III) Ion
Answer: When a water molecule coordinates to $\ce{Fe^3+}$, one non-bonded $sp^3$ hybrid orbital (with one of the 2 lone pairs) of oxygen overlaps with an empty $d$ or $p$ orbital of $\ce{Fe^3+}$. Electron density is transferred from oxygen to iron, and due to the electronegativity of oxygen, the polarization of the $\ce{O-H}$ bond in the water ligand is increased (more electron density is "pulled" from $\ce{H}$ towards $\ce{O}$). The hydrogens are more positively polarized than in a free (uncoordinated) water molecule, and this increases their electrophilic character and acidity to the point that they are readily abstracted by solvent (non-coordinated) $\ce{H2O}$ in aqueous solution:

$$\ce{Fe(H2O)6^3+ + H2O \rightleftharpoons  Fe(H2O)5(OH)^2+ + H3O+}$$

$$\ce{Fe(H2O)5(OH)^2+ + H2O \rightleftharpoons  Fe(H2O)4(OH)2^+ + H3O+}$$

Further deprotonation results in the neutral complex $\ce{Fe(H2O)3(OH)3}$, from which $\ce{Fe(OH)3}$ precipitates.

The aqueous solution of $\ce{Fe^3+}$ aquo complexes is fairly acidic, wth a pH of up to 1.5 depending on iron concentration. The first dissociation equilibrium lies mainly on the product side, which can also be seen in the color of the solution: Pure $\ce{Fe(H2O)6^3+}$ is pale violet and found in crystals of some hydrated $\ce{Fe(III)}$ salts, while aqueous solutions get their orange color from $\ce{Fe(H2O)5(OH)^2+}$.

You have mentioned ion charge (oxidation state) and charge density (which is proportional to ion size) of the metal center as potential factors of influence. One can expect that with increased charge and/or charge density, the polarization of the water ligands also increases, and thus the aquo complex should be more acidic. This is true for many aquo complexes; however, there are also some deviations from this rule, like $\ce{Cr(H2O)6^2+}$ and $\ce{V(H2O)6^2+}$ (reference).