García de Toledo Osorio, 4th Marquis of Villafranca
García Álvarez de Toledo y Osorio, 4th Marquis of Villafranca del Bierzo( 29 August 1514 – 31 May 1577), was a Spanish general and politician.
Pedro de Alcántara Álvarez de Toledo, 13th Marquis of Villafranca
Pedro de Alcántara Álvarez de Toledo y Palafox, 12th Marquis of Molina, 13th Marquis of Villafranca( 11 May 1803 – 10 January 1867) was Spanish Minister of Naval affairs, mid-19th century, reign of Isabella II of Spain counting amongst other political achievements the construction and launch in the Royal Dockyards of Ferrol, of Spain's first steam propelled ship in 1858.
The ship was named after the Spanish monarch( i.e.: Isabel II).
Medina Sidonia was succeeded by his son José Joaquín Álvarez de Toledo, 18th Duke of Medina Sidonia.
José Selva Mergelina
José Selva Mergelina, 5th Marquis of Villores( 1884–1932) was a Spanish Carlist politician.
Francisco de Borja Álvarez de Toledo, 12th Marquis of Villafranca
Francisco de Borja Álvarez de Toledo y Gonzaga, 12th Marquis of Villafranca
( 9 June 1763 – 12 February 1821) inherited the title of Marquis of Villafranca from his elder brother José Álvarez de Toledo, Duke of Alba in 1796, as well as 14th Marquis of Cazaza, 12th Marquis of Villafranca del Bierzo, 12th Duke of Bivona and 12th Marquis of Los Vélez.
He was married in Madrid, on 28 January 1798, to María Tomasa Palafox y Portocarrero( 1780 – 1835), the daughter of Felipe Antonio de Palafox Croy and Maria Francisca de Sales de Guzmán, Grandee of Spain and Condesa de Montijo,( 1763 – 1821).
They had six children, two girls and four boys, the eldest boy, Francisco, dying aged 16.< br> he was succeeded by his second son Pedro( 1803 – 1867).
Pedro de Toledo Osorio, 5th Marquis of Villafranca
Pedro de Toledo Osorio y Colonna or Pedro Álvarez de Toledo Osorio, 5th Marquis of Villafranca del Bierzo,( Naples, 6 September 1546 – 17 July 1627), Governor of the Duchy of Milan, 1616- 1618, Prince of Montalbano, 2nd Duke of Fernandina was a Spanish- Italian nobleman and a Grandee of Spain.
He was the son of García de Toledo Osorio, 4th Marquis of Villafranca, and Vittoria Colonna di Paliano.
His mother was the niece of Vittoria Colonna.
He was Commander in chief of an army in Naples, General of Cavalry of Spain in 1621.
His success in Milan was awarded with the honorable Grandeza de España title in 1623.
In 1625 he participated in the successful Defense of Cadiz against the attacks from the Anglo- Dutch fleet under the command of Sir Edward Cecil.
The expulsion of the Spanish moriscos since 1610 increased the Ottoman naval attacks in the West Mediterranean, especially when young Ahmed I became Sultan.
Pedro Alvarez set up an extensive defensive engineering program, with Italian engineers working in Italy, Spain and the Caribbean in America.
On 7 June 1576 he married Elvira de Mendoza, daughter of Íñigo Lopez de Hurtado de Mendoza, III Marquess of Mondéjar, 4th count of Tendilla, Viceroy of Naples, 1575- 1579, a.k.a. Iñigo López de Mendoza y Mendoza, 1512- 1580), and Maria de Mendoza.
They had four children.
José Álvarez de Toledo, Duke of Alba
Don José Álvarez de Toledo Osorio y Gonzaga, 11th Marquis of Villafranca, Grandee of Spain," jure uxoris" Duke of Alba de Tormes, Grandee of Spain( 16 July 1756 – 9 June 1796) was a patron of the artist Francisco Goya.
Pavel Golovin
Pavel Golovin( 26 April 1909, Naro- Fominsk — 27 April 1940) was a Soviet polar aviation pilot, colonel.
José Joaquín Álvarez de Toledo, 18th Duke of Medina Sidonia
Don José Joaquín Álvarez de Toledo y Silva, 18th Duke of Medina Sidonia, 14th Marquis of Villafranca del Bierzo, 14th Marquis of los Vélez, 12th Duke of Fernandina, 13th Marquis of Molina and 22nd Count of Niebla, Grandee of Spain, Knight of the Real Maestranza de Caballería de Sevilla and of the Order of Alcántara( Madrid, Spain; 14 August 1826 – 15 February 1900) was a Spanish aristocrat and politician who served as Superior Chief of the Palace from 1885 until his death.
García de Toledo Osorio, 6th Marquis of Villafranca
García de Toledo Osorio or García Álvarez de Toledo Osorio, 6th Marquis of Villafranca,( 25 April 1579 in Naples – 21 January 1649 in Madrid), Prince of Montalbano, 3rd Duke of Fernandina was a Spanish- Italian nobleman, military and a Grandee of Spain.
He was the son of Pedro de Toledo Osorio, 5th Marquis of Villafranca, and Elvira de Mendoza .< br>
As a child he was already Trece( thirteen) in the Order of Santiago, Prince of Montalbano and Duke of Fernandina.
He joined the navy in 1606 on a galley under the command of his father and in 1623 became" Captain General of the Galleys" of Spain.
In this capacity, he participated in the successful Defense of Cadiz in 1625, and won a victory against France when he conquered the Lérins Islands( 1635).
During the Catalan Revolt, in 1641 he won the important Battle of Tarragona( August 1641) against the French fleet under Henri de Sourdis, thus lifting the siege of the city.
He was Captain General of the Council of State and Council of War of King Philip IV of Spain, becoming one of his most trusted men.
Count- Duke of Olivares deposed him from office and locked him up in the castle of Villaviciosa de Odon.
After the fall of Olivares, Garcia was reinstated in all his functions and he was given 400,000 ducats as a compensation for having been punished unjustly.
Fadrique de Toledo, 1st Marquess of Valdueza
Fadrique de Toledo or Fadrique Álvarez de Toledo y Osorio, 1st Marquess of Valdueza( Naples, May 30, 1580 – Madrid, December 11, 1634), was a Spanish noble and admiral.
He was a Knight of the Order of Santiago and Captain General of the Spanish Navy at the age of 37.

Question: Did Pedro De Toledo Osorio, 5Th Marquis Of Villafranca and Pavel Golovin share the same nationality?
Answer: no