Sinha and Bhattacharjee developed a green version of this reaction which used a molybdenum-4-tetroxide complex and dripped in hydrogen peroxide, while Alfa Aesar developed an alternative that used xenon diflouride.
Sinha and Bhattacharjee developed a green version of this reaction which used a molybdenum-4-tetroxide complex and dripped in hydrogen peroxide, while Alfa Aesar developed an alternative that used xenon diflouride. In one modification of this reaction, using a 2:1 ratio of reagent to reactant allows the formation of esters instead of the usual product, while a modification by Cristol and Firth uses mercuric oxide. one version creates acetic acid and a lithium salt as a side product. A similar reaction using tributyltin hydride is named for Barton, while the aforementioned modification using iodine is named for Simonini. Another version it using lead-4-acetate was developed by Kochi. This reaction uses silver as a counterion, which allows the formation of an oxygen-bromine bond which cleaves homolytically. For 10 points, name this radical reaction which transforms a carboxylic acid to an alkyl halide, named for a German.
Sinha and Bhattacharjee developed a green version of this reaction which used a molybdenum-4-tetroxide complex and dripped in hydrogen peroxide, while Alfa Aesar developed an alternative that used xenon diflouride.
{Hunsdiecker} reaction