One type of this reaction proceeds via the formation of a dimethyl chlorosulfonium intermediate and creates a dimethyl sulfide by product, and that reaction improved upon another one of these which was first observed in nucleosides and used DCC.
One type of this reaction proceeds via the formation of a dimethyl chlorosulfonium intermediate and creates a dimethyl sulfide by product, and that reaction improved upon another one of these which was first observed in nucleosides and used DCC. In addition to the Pfitzner-Moffat and Swern types of these reactions, another type of this reaction occurs in either dichloromethane or chloroform and uses the Dess-Martin periodinane to complete one of these reactions, while N-chlorosuccinimide is used in the Corey-Kim type of these reactions. MCPBA can be used in this type of reaction, which is exemplified by the production of lactones from cyclic ketones in the Baeyer- Villiger form of this reaction. It can also be performed using pyridinium chlorochromate and the much stronger chromic acid is used in the Jones type of these reactions. For 10 points, name this type of reaction yields ketones, aldehydes, or carboxylic acids from alcohols, and is more commonly associated with the loss of electrons from a carbon atom.
One type of this reaction proceeds via the formation of a dimethyl chlorosulfonium intermediate and creates a dimethyl sulfide by product, and that reaction improved upon another one of these which was first observed in nucleosides and used DCC.
{Oxidation} reactions