The oxidative Namiki pathway contrasts with this reaction's classic mechanism offered by John Edward Hodge.
The oxidative Namiki pathway contrasts with this reaction's classic mechanism offered by John Edward Hodge. Boronate affinity chromatography is specific for products of this reaction. Pentosidine and pyrraline, which are formed by this reaction, have been implicated in Alzheimer's disease. This reaction forms furfural at low temperatures and acrylamide at high temperatures. The first half of this reaction opens a hemiacetal, then dehydrates it to give the enamine, then rehydrates it to reform a six-membered ring, which is the (*) Amadori rearrangement. Advanced endproducts called AGEs can be formed by a Strecker degradation at the end of it. Hb1Ac is hemoglobin that has undergone this reaction. Sterilizing LB too long in an autoclave causes the media to undergo this reaction and turn dark brown. For 10 points, name this condensation of amino acids and reducing sugars, which occurs when you bake bread.
The oxidative Namiki pathway contrasts with this reaction's classic mechanism offered by John Edward Hodge.
Maillard reaction [my-YARD] [or glycation or word forms; prompt on Amadori rearrangement until it is read]