Both the Schmidt reaction and the Stieglitz rearrangement produce them, and aromatic ones can be used to form quinolines in the Povarov reaction.
Both the Schmidt reaction and the Stieglitz rearrangement produce them, and aromatic ones can be used to form quinolines in the Povarov reaction. They can also be used to form tetrahydropyridines when reacted with a dienc, and as cations, they can be reduced by sodium cyanoborohydride in reductive amination. When the heteroatom is connected to aryl or alkyl groups, the compound is known as a Schiff base. They are most often synthesized by reacting a primary amine with an aldehyde or ketone under acidic conditions. FTP, give the general term for these molecules, all of which contain a carbon atom double bonded to a nitrogen atom.
Both the Schmidt reaction and the Stieglitz rearrangement produce them, and aromatic ones can be used to form quinolines in the Povarov reaction.
{imine}s