Context and question: In the aftermath of John's death William Marshal was declared the protector of the nine-year-old Henry III. The civil war continued until royalist victories at the battles of Lincoln and Dover in 1217. Louis gave up his claim to the English throne and signed the Treaty of Lambeth. The failed Magna Carta agreement was resuscitated by Marshal's administration and reissued in an edited form in 1217 as a basis for future government. Henry III continued his attempts to reclaim Normandy and Anjou until 1259, but John's continental losses and the consequent growth of Capetian power in the 13th century proved to mark a "turning point in European history".
Until when did Henry III continue his attempts to reclaim Normandy?
Answer: 1259
Context and question: Submission was initially a large factor in professional wrestling, but following the decline of the submission-oriented catch-as-catch-can style from mainstream professional wrestling, the submission largely faded until the rise of the legitimate sport of mixed martial arts. Despite this, some wrestlers, such as Chris Jericho, The Undertaker, Ric Flair, Bret Hart, Kurt Angle, Ken Shamrock, Dean Malenko, Chris Benoit, and Tazz, became famous for winning matches via submission. A wrestler with a signature submission technique is portrayed as better at applying the hold, making it more painful or more difficult to get out of than others who use it, or can be falsely credited as inventing the hold (such as when Tazz popularized the kata ha jime judo choke in pro wrestling as the "Tazzmission").
What legitimate sport related to wrestling began to become popular?
Answer: mixed martial arts
Context and question: There are many important organozinc compounds. Organozinc chemistry is the science of organozinc compounds describing their physical properties, synthesis and reactions. Among important applications is the Frankland-Duppa Reaction in which an oxalate ester(ROCOCOOR) reacts with an alkyl halide R'X, zinc and hydrochloric acid to the -hydroxycarboxylic esters RR'COHCOOR, the Reformatskii reaction which converts -halo-esters and aldehydes to -hydroxy-esters, the SimmonsSmith reaction in which the carbenoid (iodomethyl)zinc iodide reacts with alkene(or alkyne) and converts them to cyclopropane, the Addition reaction of organozinc compounds to carbonyl compounds. The Barbier reaction (1899) is the zinc equivalent of the magnesium Grignard reaction and is better of the two. In presence of just about any water the formation of the organomagnesium halide will fail, whereas the Barbier reaction can even take place in water. On the downside organozincs are much less nucleophilic than Grignards, are expensive and difficult to handle. Commercially available diorganozinc compounds are dimethylzinc, diethylzinc and diphenylzinc. In one study the active organozinc compound is obtained from much cheaper organobromine precursors:
What is the zinc equivalent of the Grinard reaction?
Answer:
The Barbier reaction