Question: Information: - Philippe Antoine Francoise Barbier (2 March 1848 18 September 1922) was a French organic chemist. He is considered the father of organometallic chemistry having synthesized the first organomagnesium compound in 1899. He is most famous for the Barbier reaction. - Aluminium or aluminum (in North American English) is a chemical element in the boron group with symbolAl and atomic number13. It is a silvery-white, soft, nonmagnetic, ductile metal. Aluminium is the third most abundant element in the Earth's crust (after oxygen and silicon) and its most abundant metal. Aluminium makes up about 8% of the crust by mass, though it is less common in the mantle below. Aluminium metal is so chemically reactive that native specimens are rare and limited to extreme reducing environments. Instead, it is found combined in over 270 different minerals. The chief ore of aluminium is bauxite. - The Barbier reaction is an organic reaction between an alkyl halide and a carbonyl group as an electrophilic substrate in the presence of magnesium, aluminium, zinc, indium, tin or its salts. The reaction product is a primary, secondary or tertiary alcohol. The reaction is similar to the Grignard reaction but the crucial difference is that the Barbier reaction is a one-pot synthesis whereas a Grignard reagent is prepared separately before addition of the carbonyl compound. Barbier reactions are nucleophilic addition reactions that usually take place with relatively inexpensive and water insensitive metals or metal compounds in contrast to Grignard reagents or organolithium reagents. For this reason it is possible in many cases to run the reaction in water which makes the procedure part of green chemistry. The Barbier reaction is named after Victor Grignard's teacher Philippe Barbier. - Organolithium reagents are organometallic compounds that contain carbon lithium bonds. They are important reagents in organic synthesis, and are frequently used to transfer the organic group or the lithium atom to the substrates in synthetic steps, through nucleophilic addition or simple deprotonation. Organolithium reagents are used in industry as an initiator for anionic polymerization, which leads to the production of various elastomers. They have also been applied in asymmetric synthesis in the pharmaceutical industry. Due to the large difference in electronegativity between the carbon atom and the lithium atom, the C-Li bond is highly ionic. This extremely polar nature of the C-Li bond makes organolithium reagents good nucleophiles and strong bases. For laboratory organic synthesis, many organolithium reagents are commercially available in solution form. These reagents are highly reactive, and are sometimes pyrophoric. History and development. Studies of organolithium reagents began in the 1930 and were pioneered by Karl Ziegler, Georg Wittig, and Henry Gilman. These chemists found that in comparison with Grignard reagents, organolithium reagents can often perform the same reactions with increased rates and higher yields, such as in the case of metalation. Since then, organolithium reagents have surpassed Grignard reagents in usage. Ongoing research focuses on the nature of carbon-lithium bonding, structural studies of organolithium aggregates, chiral organolithium reagents and asymmetric synthesis, and the role of organolithium reagents in the preparation of new organometallic species. - Zinc is a chemical element with the symbol Zn and atomic number 30. It is the first element in group 12 of the periodic table. In some respects zinc is chemically similar to magnesium: both elements exhibit only one normal oxidation state (+2), and the Zn and Mg ions are of similar size. Zinc is the 24th most abundant element in Earth's crust and has five stable isotopes. The most common zinc ore is sphalerite (zinc blende), a zinc sulfide mineral. The largest workable lodes are in Australia, Asia, and the United States. Zinc is refined by froth flotation of the ore, roasting, and final extraction using electricity (electrowinning). - Organometallic chemistry is the study of chemical compounds containing at least one bond between a carbon atom of an organic compound and a metal, including alkaline, alkaline earth, transition metal, and other cases. Moreover, some related compounds such as transition metal hydrides and metal phosphine complexes are often included in discussions of organometallic compounds. The field of organometallic chemistry combines aspects of traditional inorganic and organic chemistry. - Carbon (from "coal") is a chemical element with symbol C and atomic number 6. It is nonmetallic and tetravalentmaking four electrons available to form covalent chemical bonds. Three isotopes occur naturally, C and C being stable, while C is a radioactive isotope, decaying with a half-life of about 5,730years. Carbon is one of the few elements known since antiquity. - Tin is a chemical element with the symbolSn (for ) and atomic number50, is a post-transition metal in group 14 of the periodic table. It is obtained chiefly from the mineral cassiterite, which contains tin dioxide, SnO. Tin shows a chemical similarity to both of its neighbors in group 14, germanium and lead, and has two main oxidation states, +2 and the slightly more stable +4. Tin is the 49th most abundant element and has, with 10 stable isotopes, the largest number of stable isotopes in the periodic table, thanks to its magic number of protons. It has two main allotropes: at room temperature, the stable allotrope is -tin, a silvery-white, malleable metal, but at low temperatures it transforms into the less dense grey -tin, which has the diamond cubic structure. Metallic tin is not easily oxidized in air. - Indium is a chemical element with symbolIn and atomic number49. It is a post-transition metal that makes up 0.21parts per million of the Earth's crust. Very soft and malleable, Indium has a melting point higher than sodium and gallium, but lower than lithium and tin. Chemically, indium is similar to gallium and thallium, and it is largely intermediate between the two in terms of its properties. Indium was discovered in 1863 by Ferdinand Reich and Hieronymous Theodor Richter by spectroscopic methods. They named it for the indigo blue line in its spectrum. Indium was isolated the next year. - Magnesium is a chemical element with symbolMg and atomic number12. It is a shiny gray solid which bears a close physical resemblance to the other five elements in the second column (Group 2, or alkaline earth metals) of the periodic table: all Group 2 elements have the same electron configuration in the outer electron shell and a similar crystal structure. - Francois Auguste Victor Grignard (6 May 1871 in Cherbourg 13 December 1935 in Lyon) was a Nobel Prize-winning French chemist. - Philippe A. Barbier ( 1848 -- 1922 ) was a French organic chemist . He is considered the father of organometallic chemistry having synthesized the first organomagnesium compound in 1899 . He is most famous for the Barbier reaction . Barbier was Victor Grignard 's supervisor during his PhD . A method to prepare reactive Grignard reagents such as allylic magnesium halides is known as the Barbier method , where the Grignard reagent is made in situ with the other reagent . What is the relationship between 'philippe barbier' and '2 march 1848'?
Answer:
date of birth